DOI:10.14158/j.cnki.1001-3814.2014.05.

004

2014 3 43 5

2.25Cr-1Mo-0.25V

( 300387)

2.25Cr-1Mo-0.25V

54 J -60 54 J -40
P Mo
2.25Cr-1Mo-0.25V
TG157

1001-3814(2014)05-0031-03

Experimental Study on Welded Metal of 2.25Cr-1Mo-0.25V Steel by

Step-cooling Heat Treatment
SONG Liping, SUN Ronglu
(Tianjin Polytechnic University, Tianjin 300387, China)
Abstract2.25Cr-1Mo-0.25V steel was used for hydrogenation reactor. The temper embrittlement was evaluated as the
shift of 54 Joule transition temperature(vTr54) by Charpy v-notch impact test. A series of 2.25Cr-1Mo-0.25V steel welds were
prepared using manual arc. The weld metals were analyzed in the post weld heat treatment (PWHT) and PWHT followed by
step-cooling (SC) heat treatment condition. The weld metals were measured by welding rod of the same trademark but
different batch have distinct different tendency of brittleness. In the post-weld heat-treated (PWHT), the notch toughness
required for weld metal is 54 J which is not more than -60, PWHT condition followed by step-cooling (SC), 54J is not more
than -40. The results show that the low impact welding seam may relate to content of Mn. the reason for temper brittleness
is that the content of phosphorus and carbonization segregation on the grain boundary. The impact toughness of the samples
corresponding to intergranular fracture is lower. The reason for temper brittleness is that the carbide and oxide of phosphorus,
manganese and molybdenum segregation on the grain boundary.
Key words 2.25Cr-1Mo-0.25V; step-cooling; temper brittleness

2.25Cr-1Mo 2.25Cr-1Mo-0.25V

[4] 2.25Cr-1Mo-0.25V

2.25Cr-1Mo

1963

2.25Cr-1Mo-0.25V

Cr-Mo

2.25Cr-1Mo

2.25Cr-1Mo

454

20 80 2.25Cr-1Mo

[1-2]

2.25Cr-1Mo 2.25Cr-1Mo

[3]

(2.25Cr-1Mo-0.25V 2.25Cr-1Mo-0.25V-Cb-Ca)

Q235
180230 A 2428

:2013-06-04
:(1977- ),,,,,:
;:13752583072;E-mail:liping_song@163.com

V 250350 mm/min 180

180250

31

Hot Working Technology 2014, Vol.43 , No.5

( 300350 1 h

25

20

50

(PWTH705 8 h) Socal

Fig.1 Schematic diagram of chemical composition

analysis sample

(SC) GB/T229-2007

AB C D

V (10 mm10 mm55 mm)

V JB-30B

-75-60-45-30-180204060

GB2106280 GB410

9284

VTr54+3VTr540

1 1

VTr54 V

1
Tab.1 Chemical composition of weld metal and parameters of temper brittleness

A
B
C
D

(%)

Si

Mn

Cr

Ni

Mo

Cu

Nb

Ti

As

0.07
0.07
0.07
0.08

0.30
0.35
0.28
0.32

1.23
1.18
1.02
0.90

0.003
0.002
0.003
0.002

0.007
0.006
0.006
0.007

2.48
2.40
2.46
2.27

0.01
0.01
0.01
0.02

1.06
1.07
1.03
0.96

0.02
0.04
0.04
0.03

0.29
0.30
0.29
0.28

0.01
0.02
0.02
0.02

0.009
0.003
0.002
0.003

0.001
0.0008
0.0008
0.0009

0.002
0.002
0.001
0.001

Sn

VTr54 VTr54 VTr54+3VTr54

/
/
Sb Si+Mn /

0.002 0.001
0.002 0.002
0.003 0.001
0.002 0.001

1.53
1.53
1.30
1.22

-24.5
-47.4
-56.7
-70.5

33.5
25
19.1
6.9

76
28.6
0.6
-49.8

54J VTr54

2.25Cr-1Mo-0.25V

V 54J

54 J

VTr54

-60 54 J

-40

200

54 J

150

100
50
0

B C D

250

VTr54= -70.5 VTr54=6.9

200

/ J

D 4 D
VTr54+3VTr54= -49.8 0

VTr54=-56.7 , VTr54=19.1 ,

50
(b) B

-100

-50

50

T/
250

PWTH
PWTH+SC

200

PWTH
PWTH+SC

150
100
50

50
0

100

50

100

-100

32

0
T/

150

VTr54+3VTr54=0.6

(a) A
-50

PWTH
PWTH+SC

150

/ J

2 A

PWTH
PWTH+SC

/ J

200
/ J

(c) C
-50

0
T/

50

(d) D

0
-100

-50
T/

2
Fig.2 Relation curve of impact value and test temperatures

 2014 3 43 5

P [5] 2.25Cr-1Mo-0.25V

at%
C1
O1
Fe1
Mo1
P1

0.6%1.8% (

100

300 500 700

E / keV
5

Mn )
Mn P
[6] 2.25Cr-1Mo Mn P
Mn
Si

Fe Si

Si Mn
2.25Cr-1Mo-0.25V [7] Si+Mn1. 2%
SiMn SP
Mn Si

Si +Mn1. 3%
-30 A
26 J
3

( 4)
(

5) P
MoCO Fe
P Mo

Fe
Fe
Fe
O

Mn

Mo

CPS

Mn

Fe

SnSb

46.8
30.4
14.4
7.5
0.9

900

Fig.5 Composition analysis on the fracture surfaces by Auger

electronspectrometer

Mo P
Mo

Mo Mo-P
Mo
Mo Mo
Mo-P
Mo

Mo 2.25Cr-1Mo
0.5%1.0% Mo
P P
[8] [9] Mo P
Mo P Mo

Ding P Mo
P Mo
[10] Mo Mo
P
PMo C
P Mo

Mo

3
1

3 -30 26J

Fig.3 Fracture morphology of

26J impact samples at -30

Fig.4 Microstructure in
dark field

Cr-Mo Mo

3 2.25Cr-1Mo-0.25V

Mo Mo

54 J

-60 54 J 37

33

 2014 3 43 5
x

TiAl3 TiB2

Ti Ti

TiB2

[1]

Ti

[J] 2005 34 12 71-76

[2]

TiB2
AlTiB

TiAl3
TiB2 Ti

[3]

aluminum with titanium

Jones G P The mechanism of nucleation of liguid aluminum By

[5]

Mohanty P S Gruzleski J E Mechanism of grain refinement in

Al-Ti-B alloys [C]//ProcintTrondheim norway 1985 213

aluminum [J] ACTA Metallurgica ET Materialia 1995 43(5)
2001-2012
[6]

refinement practice[J] Materials Science and Technology 1998

14(5) 394-401
[7]

TiB2 Ti TiAl3

Quested T E Understanding mechanisms of grain refinement of

aluminium alloys by inoculation [J] Materials Science and
Technology 2004 20(13) 1357-1369

[8]

3 AlTiB TiAl3

Al Ti

Schumacher P Greer A L Worth J et al New studies of

nucleation mechanisms in aluminium alloys implications for grain

2 TiB2

[J] Metallurgical and Materials

[4]

1 Ti TiB2

Mccartney D The role of boron in the grain refinement of

Transactions a 1988 19(2) 385-387

TiB2

Al_Ti_B [J]
2001 5 801- 805

Ti/B Ti TiB2

Schaffer P L Miller D N Dahle A K Crystallography of engulfed

and pushed TiB2 particle in aluminum [J] Scripta Materialia
2007 57(12) 1129-1132

[9]

Schaffer A L Miller D N Dahle A K Crystallographic study of

grain refinement in aluminum alloys using the edge-to-edge

-Al

matching model [J] Scripta Materialia 2007 (57) 1129-1132

[10] Wang Chun-lei Wang Ming-xing Yu Ben-hai et al The grain
refinement behavior of TiB2 particle prepared with in situ

33 -40

technology [J] Materials Science and Engineering A 2007 459

(1/2) 238-243

[5]

boundary segregation and hardness on the ductile-to brittle

transition for a Cr-Mo low-alloy stee [J] Materials Science and

P Mo Mn
P P

Engineering A 2005 394 53-59

[6]

metals[J] Transactions of the Japan Welding Society 1985 16

MoMn P

57-63
[7]

[8]
[9]

2.25Cr-1Mo-0.25V [J]
2003 20(11) 36-42

Guttmann M Equilibrium segregation in a ternary solution A

model for temper embrittlement [J] Surface Science 1975 53

[J]

213-227

2006 27(5) 8-13

[4]

2 1/4Cr-1Mo [J]
1980 (6) 39-44

[J]
2009 30(1) 28-31

[3]

2009 (5) 30-33

[J]
2004 (1) 1-3

2.25Cr-1Mo-0.25V [J]

[2]

Okumura M Yurioka N Imai K et al Grain boundary segregation of solute elements in embrittled 225Cr-1Mo electroslag wed

[1]

Shen D D Song S H Yuan Z X et al Effect of solute grain

[10]

Ding R Knott J Grain boundary segregation of phosphorus and

molybdenum in 2.25Cr-1Mo steel [J] Materials Science and
Technology 2008 24 1189-1194

37