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ABSTRACT
The influence of fluid viscosity on flow is especially important
in petroleum reservoirs. Gas is now a highly desirable
hydrocarbon resource. An accurate prediction of transport
properties of natural gases is very important in the design and
operation of fluid transportation, production, and processing.
Viscosity is one of these properties. Many viscosity
correlations are available but each has limitations in the range
of applicability1-7. Only the Carr et al8-12. charts include the
correction for gas impurities and reservoir pressure and
temperature. Using Carr et al. charts you have to follow five
steps to find the natural gas viscosity at any condition. As a
results, some errors and inaccurated will occur and more time
will be consumed. Standing13,14 proposed a convenient
mathematical expressing for calculation the viscosity of the
natural gas at atmospheric pressure and reservoir temperature,
1. Standing also presented equations for describing the effects
of impurities on 1. Dempsey15 expressed the viscosity ratio
(the viscosity at high pressure to the viscosity at 1 atm), by
using reduced pressure and temperature.
Using the Standing equation and the slightly revised Dempsey
equation, the natural gas viscosity at high pressure can be
found by one step only. It includes all corrections for gas
impurities. Its also includes any condition at the reservoir
pressure and temperature.
Background
Natural gas is a homogeneous fluid of low density and
viscosity. The high pressure and temperature cause a decrease
in viscosity even at temperatures above the critical. The
variation in viscosity with molecular weight of gases at
atmospheric pressure is opposite to the variation for liquids,
the viscosity decreases with increase in molecular weight of
gases. The natural gas properties may be obtained from
laboratory measurements. The rolling ball viscosimeter is used
for measuring viscosity, with the ball forcing the fluid through
the crescent between the ball and tube wall. The rolling ball
viscosimeter can give erroneous results when used with low
density fluids, because of turbulent flow through the crescent.
( y
1 = 34 (10
1 =
)*
(T r ) 9
, for Tr >1.5
m = 5 . 4402
(T c )
5
2
( MW a ) ( Pc )
Dean and Stiel recommended the following equation for
calculating the natural gas viscosity at reservoir condations.
g = 1 +
0 .5
Where:
r =
0 . 27 P r
ZT r
g = 10 4 * K * exp X * g
62 .4
where: K =
(9 . 4 + 0 . 02 M a )T 1 .5
209 + 19 * M a + T
986
X = 3 .5 +
T
+ 0 . 01 M
Y = 2 . 4 . 02 X
11
T C' = T C
P C' =
TC + y H
13
P C T C'
2 S (1 y H
= 120(( yCO 2 + y H 2 S )
0.9
2S
0.5
y H 2 S ) 14
4
20
1 = (1 )uncorrecte d + ( )co + ( )N + ( )H
2
( 1 ) uncorrecte d = (1 . 709 * 10
(T 460 ) + 8 . 188 * 10
2 . 062 * 10
6 . 15 * 10
* log( g )
2S
15
* g ) * 16
( ), N 2 = y N 2 * 10 [8 . 48 * log( g ) + 9 . 59 ]
3
17
18
19
g 1 = f ( M , T ...or .GasGravity )
g
= f ( Pr , T r )
g1
In 1954 Carr et8 developed graphical correlations for
estimating the viscosity of natural gas as a function of
temperature, pressure and gas gravity or molecular weight.
The ratio (g 1) of the viscosity at high pressure to the
viscosity at 1 atm is shown as a function of the reduced
pressure Pr and the reduced temperature Tr.
Where: T r = T/Tc and Pr = P/Pc
g
LnTr = a0 + a1Pr + a2 Pr2 + a3Pr3 + Tr (a4 + a5Pr + a6 Pr2 + a7 Pr3 )
1
and,
g
Ln
1
= X
Where:
(X)=
+ T 2 (a + a P + a P2 + a P3 ) + T 3 (a +a P + a P2 + a P3 ) Ln(T )
r
r
11 r
12
13 r
14 r
15 r
r 8 9 r 10 r
Conclusions
1. Many errors will be eliminated and time will be saved by
using the new charts and the spread sheet program.
21
g
= e
(X )
g1 = 1*e ( X )
22
23
Nomenclatures
g = Gas viscosity at reservoir pressure and temperature, cp
1= Gas viscosity at atmospheric pressure and reservoir temperature, cp
r = Reduced gas density as defined by:
g = Ib/ft3, =cp, Ma= molecular weight of gas, and T=
R.
T
g
'
c
-2.46211820
2.970547414
-0.286264054
0.00805420522
2.080860949
-3.49803305
0.3603702
-0.01044324
a8
a9
a10
a11
a12
a13
a14
a15
-0.793385648
1.39643306
-0.149144925
0.00441015512
0.0839387178
-0.18648848
0.0203367881
-0.000609579263
References:
1. Kumar Sanjay,:"Gas Production Engineering" volume (4) Chapter
(1) Gulf Publication Company, Houston, Texas 1987.
2. Ikoku Chi U.,:"Natural Gas Production Engineering", Jone Wiley
& Sons Inc., Canada, Toronto, 1984.
4. Yaws C., Lin X., and Li Bu: "Calculate Viscosities for 335
liquids Using the Temperature and A starting Point", Chemical
Engineering, April 1994.
5.
7.
8.
9.
18. Lee, A.L., Gonzalez, M.H., and Eakin, B.E.:The Viscosity of Natural
Gases, JPT (Aug. 1966) 997-1000, Trans., AMIE, 37.
19. Lee, J., and Wattenburger, R.A., Gas Reservoir Enginerring, SPE,
Richardson, TX, 1996.
20. Bicker, L.A., and Katz, D.L.,:Viscosity of Natural Gases, Trans.
AMIE, 155: 754 (1943).
21. Comings, E. W. , and Egly, R. S., :The Viscosity of Gases and Vapors
at High Pressure Ind. Eng. Chem., 32: 714 (1940)
22. Abd-El-Fattah Kh. A.,: "A New Equations computers the
Pseudo-Critical Temperature and Pressure for Natural Gases",
Journal of Engineering and Applied Science, Vol. 45. NO. 5,
Oct. 1998. PP 857-864, Faculty of Engineering, Cairo
University.
10
0.018
10
15
20
Viscosity at 1 atm, cp
0.016
0.014
0.012
0.010
0.008
0.006
0.004
0.002
50 oF
100 oF
150 oF
200 oF
250 oF
300 oF
350 oF
400 oF
Pr
0.000
0
20
40
60
80
0.8
100
0.012
0.010
0.008
0.006
0.004
0.002
50 oF
100 oF
150 oF
200 oF
250 oF
300 oF
350 oF
400 oF
3
10
2
8
1
6
0.014
N. Gas Viscosity, cp
Viscosity at 1 atm, cp
0.016
4
15
0.10
0.01
0.000
0
20
40
60
80
100
0.5
1.5
Molecular Weight
Fig. (2) Viscosity of the Natural Gases at 1.0 atm. with Impurities Corrections.
2.5
0.070
Sp.Gr.= 0.8
612
1225
1837
4900
6125
9187
2450
3062
3675
0.060
0.050
Pressure, psi
N . G as Viscosity
N. g as Visco sity, cp
1.00
0.10
0.040
0.030
0.020
0.01
0.010
200
400
600
800
Dempsey
1000
Lee
Temperature, oF
0.000
0
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
0.060
0.080
Sp.Gr.=0.7
Sp.Gr.=0.9
0.050
0.070
0.060
N. Gas Viscosity
Viscosity, cp
0.040
0.030
0.020
0.010
0.050
0.040
0.030
0.020
Dempsey
Lee
Dean & Stiel
Dempsey
0.010
0.000
Lee
0
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
0.000
0
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
Fig. (6) Viscosity versus Temperature for Different Preesures at 0.7 Sp.Gr.
Fig. (8) Viscosity versus Temperature for Different Pressures at 0.9 Sp.Gr
0.120
Sp.Gr.=1.2
0.090
Sp.Gr.=1.0
0.100
0.080
0.070
0.080
Gas Viscosity, cp
Gas Viscosity, cp
0.060
0.050
0.040
0.060
0.040
0.030
0.020
0.020
0.010
Dempsey
Dempsey
Lee
Lee
Dean & Stiel
0.000
0.000
0
1000
2000
3000
4000
5000
6000
7000
8000
9000
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
Pressure, psi
Fig. (11) Viscosity versus Temperature for Different Preesures at 1.2 Sp.Gr.
Fig. (9) Viscosity versus Temperature for Different Preesures at 1.0 Sp.Gr.
0.100
0.120
Sp. Gr. 1.1
Sp.Gr.=1.3
0.090
0.100
0.080
0.080
0.060
Gas Viscosity
N. Gas Viscosity
0.070
0.050
0.040
0.030
0.060
0.040
0.020
Dempsey
0.010
0.020
Lee
Dean & Stiel
Dempsey
8000
Lee
0.000
0
1000
2000
3000
4000
5000
6000
7000
9000
0.000
Pressure, pai
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
Fig. (10) Viscosity versus Temperature for Different Preesures at 1.1 Sp.Gr.
Fig. (12) Viscosity versus Temperature for Different Preesures at 1.3 Sp.Gr.
0.140
Sp.Gr=1.4
0.120
Gas Viscosity, cp
0.100
0.080
0.060
0.040
Dempsey
0.020
Lee
Dean & Stiel
0.000
0
1000
2000
3000
4000
5000
6000
7000
8000
9000
Pressure, psi
Fig. (13) Viscosity versus Temperature for Different Preesures at 1.4 Sp.Gr.
Table (1) Spread Sheet Program for Calculate Natural Gas Viscosity by Dempsey Correlation.
Step 1
Step 2
Step 3
0.05
0.05
YCO2
YH2S
28.09
3675
4900
0.2
0.6
Tc
358.55
Pc
672.87
T'c
330.46
P'c
612.48
or
Mw
17.4
1837
2450
3062
612
Pr
1225
10
15
20
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
ln(g/g1)
330
0.27
0.79
1.23
1.58
1.86
2.07
2.32
2.40
2.33
2.70
397
1.2
0.16
0.52
0.83
1.09
1.30
1.47
1.70
1.82
1.89
2.14
463
1.4
0.09
0.34
0.55
0.74
0.90
1.03
1.24
1.38
1.55
1.72
529
1.6
0.05
0.21
0.36
0.49
0.61
0.72
0.90
1.05
1.28
1.41
595
1.8
0.03
0.14
0.24
0.33
0.42
0.51
0.67
0.81
1.06
1.19
661
0.03
0.10
0.17
0.24
0.31
0.38
0.51
0.64
0.90
1.03
727
2.2
0.03
0.08
0.14
0.19
0.25
0.30
0.42
0.53
0.77
0.92
793
2.4
0.04
0.08
0.12
0.17
0.22
0.26
0.35
0.45
0.66
0.84
859
2.6
0.04
0.07
0.11
0.15
0.19
0.23
0.31
0.38
0.57
0.76
925
2.8
0.03
0.06
0.09
0.12
0.15
0.19
0.25
0.31
0.48
0.66
0.00
0.02
0.04
0.06
0.08
0.11
0.16
0.23
0.39
0.53
Step 4
12250
ln(g/g1)
991
9187
Tr
6125
612
1225
1837
2450
3062
3675
4900
6125
9187
Pr
10
15
Tr
(g/g1)
(g/g1)
(g/g1)
330
1.31
2.21
397
1.2
1.17
1.69
463
1.4
1.09
1.40
529
1.6
1.05
1.24
595
1.8
1.03
661
1.03
12250
20
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
3.42
4.87
6.42
7.91
10.17
11.07
10.30
2.70
2.30
2.98
3.68
4.36
5.48
6.17
6.65
2.14
1.74
2.09
2.45
2.81
3.45
3.96
4.70
1.72
1.43
1.64
1.84
2.05
2.46
2.84
3.58
1.41
1.15
1.27
1.40
1.53
1.67
1.95
2.24
2.90
1.19
1.10
1.19
1.27
1.36
1.46
1.67
1.90
2.45
1.03
Continues Table (1) Spread Sheet Program for Calculate Natural Gas Viscosity by Dempsey Correlation.
T
Tr
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
(g/g1)
727
2.2
1.03
1.09
1.15
1.21
1.28
1.36
1.52
1.69
2.15
0.92
793
2.4
1.04
1.08
1.13
1.18
1.24
1.30
1.43
1.56
1.94
0.84
859
2.6
1.04
1.08
1.12
1.16
1.21
1.26
1.36
1.47
1.77
0.76
925
2.8
1.03
1.06
1.09
1.13
1.17
1.20
1.28
1.37
1.62
0.66
991
1.00
1.02
1.04
1.06
1.09
1.11
1.18
1.25
1.47
0.53
Step 5
612
1225
1837
2450
3062
3675
4900
6125
9187
12250
Pr
10
15
20
Tr
330
0.0206
0.0349
0.0539
0.0767
0.1011
0.1246
0.1602
0.1744
0.1622
0.0426
397
1.2
0.0197
0.0284
0.0387
0.0501
0.0619
0.0732
0.0921
0.1037
0.1118
0.0360
463
1.4
0.0195
0.0250
0.0310
0.0373
0.0438
0.0501
0.0616
0.0706
0.0840
0.0307
529
1.6
0.0199
0.0234
0.0271
0.0309
0.0349
0.0388
0.0466
0.0537
0.0677
0.0266
595
1.8
0.0206
0.0229
0.0253
0.0279
0.0305
0.0333
0.0389
0.0447
0.0578
0.0237
661
0.0216
0.0232
0.0249
0.0267
0.0287
0.0307
0.0351
0.0398
0.0515
0.0216
727
2.2
0.0228
0.0240
0.0253
0.0267
0.0283
0.0299
0.0335
0.0373
0.0475
0.0203
793
2.4
0.0239
0.0250
0.0261
0.0274
0.0286
0.0300
0.0329
0.0361
0.0448
0.0193
859
2.6
0.0250
0.0260
0.0270
0.0281
0.0292
0.0304
0.0328
0.0354
0.0427
0.0182
925
2.8
0.0259
0.0267
0.0276
0.0285
0.0294
0.0303
0.0323
0.0345
0.0408
0.0166
991
0.0263
0.0268
0.0273
0.0279
0.0285
0.0292
0.0309
0.0329
0.0386
0.0140
10
Table (2) Spread Sheet Program for Calculate of the Existing Correlations for Natural Gas Viscosity
YN2
0.05
Sp. Gr.
YCO2
0.05
YH2S
0.2
0.6
600
Tc
358.55
0.0127
Standing
Pc
672.87
0.0121
T'c
330.46
0.0122
Tr
P'c
1.82
ABS.
28.09
T oF =
140
612.48
0.047581
Lee
125.760
Pr
Program
LN(mg)
g(Dempsey)
g(Lee)
g(Dean)
X
Y
5.317
1.337
2000
2500
3000
3500
4000
4500
5000
5500
6000
6500
7000
7500
3.265
4.082
4.898
5.714
6.531
7.347
8.163
8.980
9.796
10.613
11.429
12.245
0.681
0.876
1.178
1.320
1.411
1.482
1.540
1.590
1.634
1.672
1.708
1.740
1.000
1.000
0.999
1.000
1.000
0.999
0.999
1.000
1.000
1.000
1.000
1.000
0.713
0.693
0.618
0.644
0.688
0.737
0.788
0.840
0.892
0.944
0.995
1.047
-4.107
-4.031
-3.958
-3.889
-3.822
-3.758
-3.697
-3.639
-3.585
-3.533
-3.485
-3.440
0.016
0.018
0.019
0.020
0.022
0.023
0.025
0.026
0.028
0.029
0.031
0.032
7.574
9.736
13.096
14.677
15.687
16.478
17.123
17.676
18.160
18.592
18.982
19.339
0.017
0.020
0.024
0.027
0.029
0.031
0.032
0.034
0.035
0.036
0.037
0.038
0.017
0.019
0.024
0.027
0.029
0.031
0.033
0.034
0.036
0.037
0.039
0.040
8000
13.062
1.769
1.000
1.098
-3.399
0.033
19.667
0.039
0.041
Micro
Dempsey