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Vapor-Liquid Separation
Product loss requirements may vary over a wide range. Provisions to reduce
product losses have far less effect on the cost of an evaporator system than does
heat transfer surface. Product losses in evaporator vapor occur as a result of
entrainment, splashing, or foaming. Foaming properties of the liquid may at
times dictate the selection of evaporator type.
ENTRAINMENT
Losses from entrainment result from the presence of droplets in the vapor
that cannot separate because of the vapor velocity. Entrainment is thought to be
due mainly to the collapse of the liquid film around vapor bubbles. This collapse
projects small droplets of liquid into the vapor. The extent of entrainment is a
function of the size distribution of the droplets and the vapor velocity. Little
information is available regarding size distribution of the droplets that are
formed or the influence of evaporator type and liquid properties on size.
Entrainment may be generated from atomization at a liquid surface by a
high gas velocity, from a spray contacting operation, or from the disengaging of
gas and liquid in a contacting operation. This latter mechanism is the most
common.
Bubbles breaking the surface cause drops of different sizes to be propelled
upward. The smaller ones are caught in the upward flowing gas and carried overhead as entrainment, while the larger ones return to the surface. The largest
drop carried up is dependent on the gas velocity and density, and on other
physical properties. At very high gas velocities, large drops produced at the
surface are shattered into smaller droplets and all the generated entrainment
is carried overhead, flooding the device. This breakup phenomenon occurs when
the inertial forces, which cause a pressure or force imbalance, exceed the surface
tension forces which tend to restore a drop to its natural spherical shape. The gas
153
154
where
0.7[(Pl
vgf
=
=
=
=
PI
Pv
Cl
is the flooding
Pb/P21 14
velocity
and is given by
(14.1)
Equipment
containing
both gases and liquids in which the gas flows vertically
upward will be flooded at velocities exceeding that predicted
from the equation above. In practice, most equipment
is designed to operate well below the
flooding limit. Factors such as disengaging height, convergence effects, and nonuniform gas velocities prevent operation
at velocities exceeding roughly half the
flooding velocity.
The amount of entrainment
from an upward flowing gas can be estimated
and is a function
of gas velocity, gas and liquid densities, and surface tension.
Actual entrainment
rates can be from 0.1 to 2.5 times what is estimated
by
various correlations.
Entrainment
can be separated from a gas stream with a variety of mechanisms, including gravity, inertial impaction,
interception,
centrifugal
force, and
Brownian
motion.
Separators can be classified according to mechanism,
but it
is more useful to categorize them by construction
type. Separators in common
use include:
(I 1 flash tanks
(2)
vane impingement
(3)
separators
(4)
Karbate
strut separators
(5)
centrifugal
(6)
cyclones
separators
(7)
special separator
types.
Vapor-Liquid Separation
155
physical properties. Except for the cyclone and some special separators, there
is a recognized and predictable maximum allowable velocity. The following
equation is commonly used:
vm = F[(PI where v,
F
PI
Pv
=
=
=
=
P~VP,I *
(14.2)
This equation, and Equation 14.1, indicate that the term VP,* is of primary importance in separator sizing. The flow area must be carefully specified to
avoid any ambiguity in application of Equation 14.2.
FLASH TANKS
The simplest approach to disentraining liquid is the flash tank. The velocity
is reduced to a value which permits the droplets to settle rather than to be
carried by the vapor. Evaporator bodies are generally sized such that particles
larger than a certain size will be disentrained. Flash tanks may be either vertical
or horizontal. Vertical separators are usually more economical when the diameter is less than 8 feet; for larger sizes, horizontal separators may be less
expensive.
Vertical vapor bodies may be sized using a value of 0.2 for F in Equation
14.2. Horizontal vapor bodies should be sized with a target value of F = 0.15
based on the surface area at the gas/liquid interface. Recommended vertical
flash tank dimensions are shown in Figure 14-1. Liquid holdup requirements
may control the size of flash tanks. In such cases, the tank should be oversized
with respect to the gas flow in order to acheve practical vessel dimensions. A
height-todiameter ratio of 2 to 5 is usually economical.
Operation of horizontal flash tanks is improved when a distribution pipe
is provided. Distributors can be installed normal to the tank axis with perforations directing the flow horizontally. Alternatively, the distributor pipe can
be installed parallel to the tank axis with perforations directing the flow perpendicular to the tank axis. The inlet nozzle should always be located well
above the maximum liquid level.
Both vertical and horizontal flash tanks are susceptible to low frequency
motion induced by sloshing. Consequently they should be rigidly supported.
Often it is not practical to provide a vapor body large enough to accomplish
the desired disentrainment. Entrainment separators are frequently used to
reduce product loss. A number of proprietary designs are available.
156
Q
1.5
.75 D min.
d
(Note
I)
?
1.5
Vm
d min.
LI
Hote
ddard
Note
I -
If wire
top of
Note
2 -
If erosion
distributor
Note
3 -
Size
Note
4 -
Provide
antiswirl
mesh is installed,
change
mesh pad D/Z below outlet
is
from V = .2q
m
for
it will
sometimes
not
minimum of
be fouled
washed
depends
while
on wire
droplets
one minute
Standard
to remove
holdup
from
D to D and install
with a perforated
tangential
inlets.
impinge
between
solids.
Any
significant
of liquid
replace
Avoid
.75
level
taps.
or plugged
in service
from
baffle
ft/s
Figure 14-1:
where
dimension
nozzle.
suspected,
omit baffle
or
pipe with horizontal
holes.
volume
Vapor
flows
Wire
mesh is
corrosion
of a knitted
easily through
will
wire mesh
the mesh
drop away from the bottom of the demister pad. Vapor velocity is of major
importance
in obtaining best performance.
Highest efficiency
is obtained within
certain limits. Knitted
mesh has very good separation characteristics
when the
Vapor-Liquid Separation
157
gas density is low and poor characteristics when it is high. Separator efficiency
(percent of inlet entrainment removed) can be expected to increase from 80% at
2 ft/sec to 95% at 3 ft/sec to 99+% at 5 ft/sec. The maximum velocity is determined by flooding of the mesh. Knitted mesh separators are generally sized
by using a value of F = 0.35 in Equation 14.2.
Pressure drop is typically 0.1 to 1.0 inch of water. It can be conservatively
estimated at 100 velocity heads per foot of mesh thickness, based on superficial velocity through the pad. High pressure drops for properly sized pads
indicate that the pad is probably either plugged or flooded, or both.
A mesh pad can be of one-piece construction (for diameter less than 3
feet) or it can be fabricated in strips for installation through a manway or large
nozzle. This latter construction is usually preferred in order to facilitate pad
replacement. Mesh pads should be supplied with both top and bottom support
grids to increase mechanical integrity. Pads larger than 6 feet in diameter will
require support beams. The pad should be placed on a support ring, welded
around the vessel circumference. The pad should be anchored to this ring. The
bottom grid is anchored to the ring with tie wire supplied with the pad. For
severe services, the mesh should be anchored with J bolts rather than tie wire.
The pad, grids, and tie wire (or J bolts) will be supplied by the mesh vendor.
Support beams and rings should be part of the vessel fabrication.
VANE IMPINGEMENT
SEPARATORS
0URG5SS
SMl-fU
PEERLESS
-TOP
VIEW
OF S;PAtZAlOQ
(FLOW
FROM
LEFT
Figure 14-2:
10
Vane impingement
ELEMENTS
r21c1-1~)
separator elements,
158
Handbook of Evaporation
Technology
- t
~
TYPICAL VARILINE
LINE SEPARATOR
SEPARATOR
1~
too--.,
"-
t"""
~n-~
,-,..,.-.".-.,
;,--
~AL
GASSEPAMT~-
INTERNAL SEPARATOR
Figure
14-3:
Types
of vene impingement
separators.
Vapor-Liquid Separation
159
Vane impingement
separators are generally purchased from the vendor on a
performance
basis. Sizes will vary somewhat from one manufacturer
to another;
consequently,
the exact size cannot be determined
before selection of the manufacturer. The pressure drop across vane impingement
separators is approximately
0.25 psi plus 1.5 velocity heads based on the nozzle velocity. The total pressure
drop will usually be less than 0.5 psi.
Liquid loading is limited to roughly 5 to 10% of gas mass flow. Pockets can
plug with solids and are difficult to clean unless the vanes are removable.
CENTRIFUGAL
SEPARATORS
Centrifugal
separators impart a spin or rotation to the entrainment
laden
gas. Blades or a special passage are used to impart the rotation and the resultant
centrifugal
force. Entrained liquid collects on the wall and flows through a drain
connection.
Centrifugal
separators are distinguished
from cyclones because they
have a somewhat
different
configuration
and must usually be purchased from
the manufacturer
on a performance
basis. Centrifugal
separators are usually
line-type separators, but other configurations
are available. Centrifugal separators
can be installed inside a vapor body by attaching it to the outlet nozzle as shown
in Figure 14-4.
Centrifugal
separators cannot be sized with the F factor approach used with
other types of separators because the maximum
allowable velocity is a weaker
function
of gas density than the square root dependence
in the F factor correlation. Maximum
velocities for centrifugal
separators depend upon the design
and are different for each of the several manufacturer
units. Pressure drop varies
from 1 to 10 velocity heads depending upon the manufacturer.
Velocity
head
should be based on inlet (outlet) nozzle velocity.
Centrifugal
separators have lower separation efficiency than vane separators.
They must be provided with a trap device for liquid collection,
and have a
limited liquid handling capacity.
Line-type
units can be operated with velocities as low as 30 ft/sec without significant loss in separation efficiency.
CYCLONES
Cyclone separators admit entrainment
laden gas through a tangential
inlet.
The gas then spirals around the central tube, called a vortex finder, and finally
exists through
it. Cyclone separation efficiency
is not as good as with other
separators, but it is reasonably
good. There is no well-defined
upper limit on
the cyclone
inlet velocity;
but it appears prudent to limit the velocity to a
maximum
of approximately
300 ft/sec. The pressure drop across a cyclone can
be estimated
as 8 velocity heads, based on the inlet velocity. Good separation
in a cyclone usually results in high velocities with resultant high pressure drops.
In evaporator
design, pressure drop results in a loss of available temperature
difference
decreasing the efficiency
of the system or requiring additional
heat
transfer surface. Recommended
cyclone configuration
is shown in Figure 14-5.
160
DRAIN
Figure 14.4:
arator.
(a) Typical
line centrifugal
separators.
(b) Typical
internal
plp5S
centrifugal
sap-
Vapor-Liquid Separation
TVPE
TYPE
vapor
Outle:
-1
Vapor
inlet
D-
Vapor
Inlet
II
Drain
Vapor
Outlet
Ir.let
?,
d
Diameter,
incies
Diameter.
ifiches
Shell
D.
h,
incnes
a
:
8
l-l/Z
2
1:
21
28
42
60
10
14
::
:
10
12
14
16
18
20
24
z:
;z
98
112
I26
140
I68
::
60
66
78
:
NCTES
I.
Antiswirl
be
2.
baffle
prwided
drail
nozzle.
Type
A cyclcne
have
for
will
somehat
efficiency
should
the
higher
than Type
CYClOtV.
Figure 14-5:
Standard
cyclone configuration.
161
162
OTHER SEPARATORS
Other
separator
(1)
streamline
(2)
banks of tubes
struts
(3)
zig-zag baffles
(4)
packed
beds
(5)
fibrous
filters
(6)
pockets)
COMPARISON
Table
14-l
offers a comparison
of various entrainment
separators.
SOLIDS DEPOSITION
Industrial experience with separator fouling and plugging has
qualitative
observations.
Vertical
collection
surfaces stay cleaner
horizontal
surfaces because of better liquid drainage. Intermittent
sprays is beneficial,
but the detail design of the washing unit and
procedure
vary with each specific case. The wash represents a
evaporation
efficiency also.
Guidelines include:
(1)
deposition
rate decreases
(2)
deposition
greater
(3)
(4)
small droplets
rate
decreases
yielded some
longer than
washing with
the operating
reduction
in
liquid
film
thickness
becomes
in eddies which
Vapor-Liquid
Table 14-1:
Separator
.
TypeI
Vane
Ina Separator)
I.
Nigh Efficiency
2.
3. Relatively
inexpensive
4.
I.
Better efficiency
separator
2.
3. Will
separate
at
In a variety
2.
Pockets
2.
Difficult
vancs are
3.
Relatively
In
of
solids
to clean unless
removable
plplng
can
to clean unless
removable
expensive
1. Very susceptible
2.
Inexpensive
if installed
existing
vessel
3. Available
materlals
with
1. Generally
good efficiency
low pressure
2.
I.
slugs
erh Separator
Disadvantages
3. Difficult
vanes are
than line
llquld
163
of Separators
Advantages
.
Vane
Jart 101 Gas
Separator)
Comparison
Separation
to plugging
3. Highly susceptible
corrosion
to
lfflclency
2.
3.
I.
Only available
in Karbate
2.
Llquld
llmtted
3.
Somewhat dlfflcult
4. A trap
llquld
I.
1. lncxpens Ive
Centrifugal
(Line)
loading
Lower cfftclency
1 ine separators
than.vane
Cyclone
to clean
I.
Can be designed
2.
Less susceptible
than other types
In-house
to plugging
handling
1. Lower efflclency
than
vane I ine separators
2.
A trap
device
Is usually
164
FALLING
FILM
For falling
Droplets
EVAPORATORS
film
ejected
evaporators,
from
on the opposite
disentrainment
the film
side. Consequently,
apparently
by the film
systems.
FLASHING
Entrainment
losses from
point
if adequate
flashing
may
and is introduced
occur
Excessive entrainment
control
of liquid
in evaporators.
If the feed is
level, entrain-
during
SPLASHING
Splashing losses can be prevented by providing adequate distance between
the liquid level and the top of the vapor body. The required distance depends
upon the nature of the boiling. A distance of 8 to 12 feet is generally adequate
for short-tube vertical evaporators
in which the two-phase mixture is traveling
upward.
with
Deflectors
caution
other
types where
the mixture
designed.
but they
Less distance
enters tangentially
should
is usually
or is otherwise
be used
needed
directed
in
away
losses often
startup
result
mixture
or when
from
suddent
liberation
of large volumes
of
FOAMING
Foam
often
sants, or finely
sometimes
Other
impingement
Frequent
the foam
is carried
rupting
The
out
of colloids,
foam
include
at high velocities
surface tension
Antifoam
impingement
against
depres-
baffles,
at low liquid
jetting.
causes of foaming
presence of dissolved
rator,
presence
by a surface blowdown.
of combatting
levels, ultrasonic
the
be removed
methods
surface,
results from
divided
This
the
liquid
level or the
When foam begins to build in an evapoto grow until it fills the evaporator
can sometimes
be stopped
by momentarily
and
inter-
evaporation.
designer
should
distinguish
between
liquid
carryover
resulting
from
entrainment
phenomena
and that resulting from foam. Foam cannot be broken
with conventional
entrainment
separators unless the foam is highly unstable. The
Vapor-Liquid Separation
following generalizations on foam formation
tentially troublesome situations:
765
(6) Small bubbles form more stable foams than large bubbles.