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JEE MAIN ONLINE PAPER (12.04.2014)

PART A : PHYSICS
1.

From the following combinations of physical constants

(expressed thr ough their usual symbols) the only
combination, that would have the same value in different
systems of units, is:
(a)

(b)
(c)

5.

ch
2peo2

(a)

2pe o Gme2

(me = mass of electron)

3.

1
mv 2
2

(b) mv2

1 2
1
mv
mv 2
(d)
3
6
A particle is moving in a circular path of radius a, with a
constant velocity v as shown in the figure. The centre of
circle is marked by C. The angular momentum from the
origin O can be written as:

(c)

m o eo G

6.

c2 he 2

2p m o eo h
G
ce 2
A person climbs up a stalled escalator in 60 s. If standing on
the same but escalator running with constant velocity he
takes 40 s. How much time is taken by the person to walk up
the moving escalator?
(a) 37 s
(b) 27 s
(c) 24 s
(d) 45 s
Three masses m, 2m and 3m are moving in x-y plane with
speed 3u, 2u and u respectively as shown in figure. The
three masses collide at the same point at P and stick together.
The velocity of resulting mass will be:
(d)

2.

coefficient of friction between the block and the table is 0.3,

how far will the block slide approximately?
(a) 0.19 m
(b) 0.379 m
(c) 0.569 m
(d) 0.758 m
A spring of unstretched length l has a mass m with one end
fixed to a rigid support. Assuming spring to be made of a
uniform wire, the kinetic energy possessed by it if its free
end is pulled with uniform velocity v is:

y
O

(a) va (1 + cos 2q)

(c) va cos 2q
m1
v1 v2
7.

m, 3u

Two hypothetical planets of masses m1 and m2 are at rest

when they are infinite distance apart. Because of the
gravitational force they move towards each other along the
line joining their centres. What is their speed when their
separation is d?
(Speed of m1 is v1 and that of m2 is v2)
(a) v1 = v2

60

3m, u
(a)

(b)

u
i - 3j
12

)
)

u
u
-i + 3j
-i - 3j
(d)
12
12
A bullet of mass 4g is fired horizontally with a speed of 300
m/s into 0.8 kg block of wood at rest on a table. If the

(c)
4.

u
i + 3j
12

(b) va (1 + cos q)
(d) va
m2

2m, 2u
60

(b)

v1 = m 2

2G
d ( m1 + m 2 )

v 2 = m1

2G
d ( m1 + m 2 )

2
(c)

(d)

8.

9.

(c)

11.

12.

13.

14.

15.

reflected from ground of frequency nearly: (Speed of sound

= 343 m/s)
(a) 2150 Hz
(b) 2500 Hz
(c) 1800 Hz
(d) 2400 Hz
16. A spherically symmetric charge distribution is characterised
by a charge density having the following variations:

2G
d ( m1 + m 2 )

v 2 = m2

2G
d ( m1 + m 2 )

v1 = m 2

2G
m1

v2 = m 2

2G
m2

r ( r ) = ro 1 - for r < R
R
r(r) = 0 for r R
Where r is the distance from the centre of the charge
distribution ro is a constant. The electric field at an internal
point (r < R) is:

Steel ruptures when a shear of 3.5 108 N m2 is applied.

The force needed to punch a 1 cm diameter hole in a steel
sheet 0.3 cm thick is nearly:
(a) 1.4 104 N
(b) 2.7 104 N
4
(c) 3.3 10 N
(d) 1.1 104 N
A cylindrical vessel of cross-section A contains water to a
height h. There is a hole in the bottom of radius a. The time
in which it will be emptied is:
(a)

10.

v1 = m1

2A
pa

h
g

2 2A h
pa 2 g

(b)

(d)

2A h
pa 2 g
A
2

h
g

2pa
Two soap bubbles coalesce to form a single bubble. If V is
the subsequent change in volume of contained air and S
change in total surface area, T is the surface tension and P
atmospheric pressure, then which of the following relation
is correct?
(a) 4PV + 3ST = 0
(b) 3PV + 4ST = 0
(c) 2PV + 3ST = 0
(d) 3PV + 2ST = 0
Hot water cools from 60C to 50C in the first 10 minutes and
to 42C in the next 10 minutes. The temperature of the
surroundings is:
(a) 25C
(b) 10C
(c) 15C
(d) 20C
A Carnot engine absorbs 1000 J of heat energy from a
reservoir at 127C and rejects 600 J of heat energy during
each cycle. The efficiency of engine and temperature of sink
will be:
(a) 20% and 43C
(b) 40% and 33C
(c) 50% and 20C
(d) 70% and 10C
At room temperature a diatomic gas is found to have an
r.m.s. speed of 1930 ms1. The gas is:
(a) H2
(b) Cl2
(c) O2
(d) F2
Which of the following expressions corresponds to simple
harmonic motion along a straight line, where x is the
displacement and a, b, c are positive constants?
(a) a + bx cx2
(b) bx2
(c) a bx + cx2
(d) bx
A source of sound A emitting waves of frequency 1800 Hz
is falling towards ground with a terminal speed v. The
observer B on the ground directly beneath the source receives
waves of frequency 2150 Hz. The source A receives waves,

(a)

ro r r 2

4e o 3 4R

(c)

ro r r 2
3e o 3 4R

(b)

ro r r 2

e o 3 4R

(d)

ro r r 2
12e o 3 4R

17. The space between the plates of a parallel plate capacitor is

filled with a dielectric whose dielectric constant varies
with distance as per the relation:
K(x) = Ko + lx (l = a constant)
The capacitance C, of the capacitor, would be related to its
vacuum capacitance Co for the relation :
(a)

C=

ld
Co
ln (1 + K o ld )

(b)

C=

l
Co
d.ln (1 + K o ld )

(c)

C=

ld
Co
ln (1 + ld / K o )

(d)

C=

l
Co
d.ln (1 + K o / ld )

18. The circuit shown here has two batteries of 8.0 V and 16.0 V
and three resistors 3 W, 9 W and 9 W and a capacitor of 5.0
mF.

I
5 mF

3W

9W
9W

8.0 V
I1

16.0 V
I2

How much is the current I in the circuit in steady state?

(a) 1.6 A
(b) 0.67 A
(c) 2.5 A
(d) 0.25 A
19. A positive charge q of mass m is moving along the + x
axis. We wish to apply a uniform magnetic field B for time Dt
so that the charge reverses its direction crossing the y axis
at a distance d. Then:

3
(a)

B=

mv
pd
and Dt =
qd
v

(b)

B=

mv
pd
and Dt =
2qd
2v

(c)

B=

2mv
pd
and Dt =
qd
2v

21.

22.

23.

m1

m1

(c)

2mv
pd
and Dt =
qd
v
Consider two thin identical conducting wires covered with
very thin insulating material. One of the wires is bent into a
loop and produces magnetic field B1, at its centre when a
current I passes through it. The ratio B1 : B2 is:
(a) 1 : 1
(b) 1 : 3
(c) 1 : 9
(d) 9 : 1
A sinusoidal voltage V(t) = 100 sin (500t) is applied across a
pure inductance of L = 0.02 H. The current through the coil
is:
(a) 10 cos (500 t)
(b) 10 cos (500t)
(c) 10 sin (500t)
(d) 10 sin (500t)
A lamp emits monochromatic green light uniformly in all
directions. The lamp is 3% efficient in converting electrical
power to electromagnetic waves and consumes 100 W of
power. The amplitude of the electric field associated with
the electromagnetic radiation at a distance of 5 m from the
lamp will be nearly:
(a) 1.34 V/m
(b) 2.68 V/m
(c) 4.02 V/m
(d) 5.36 V/m
The refractive index of the material of a concave lens is m. It
is immersed in a medium of refractive index m1. A parallel
beam of light is incident on the lens. The path of the emergent
rays when m1 > m is:

(d)

20.

B=

m
m1
m1

(d)

24.

m1
(c)
25.

m
m1

30

(a)

(a)

21

m
m1

Interference pattern is observed at P due to

superimposition of two rays coming out from a source S as
shown in the figure. The value of l for which maxima is
obtained at P is:
(R is perfect reflecting surface)

26.
m1

(b)

27.

l=

l=

2nl

(b)

3 -1

( 2n - 1) l

4 2- 3

(d)

l=

l=

( 2n - 1) l
2

3 -1

( 2n - 1) l
3 -1

In an experiment of single slit diffraction pattern, first

minimum for red light coincides with first maximum of some
other wavelength. If wavelength of red light is 6600 , then
wavelength of first maximum will be:
(a) 3300
(b) 4400
(c) 5500
(d) 6600
A beam of light has two wavelengths of 4972 and 6216
with a total intensity of 3.6 103 Wm2 equally distributed
among the two wavelengths. The beam falls normally on an
area of 1 cm2 of a clean metallic surface of work function 2.3
eV. Assume that there is no loss of light by reflection and
that each capable photon ejects one electron. The number
of photoelectrons liberated in 2s is approximately:
(a) 6 1011
(b) 9 1011
11
(c) 11 10
(d) 15 1011
A piece of bone of an animal from a ruin is found to have 14C
activity of 12 disintegrations per minute per gm of its carbon

28.

29.

30.

content. The 14 C activity of a living animal is 16

disintegrations per minute per gm. How long ago nearly did
the animal die? (Given half life of 14C is t1/2 = 5760 years)
(a) 1672 years
(b) 2391 years
(c) 3291 years
(d) 4453 years
For LEDs to emit light in visible region of electromagnetic
light, it should have energy band gap in the range of:
(a) 0.1 eV to 0.4 eV
(b) 0.5 eV to 0.8 eV
(c) 0.9 eV to 1.6 eV
(d) 1.7 eV to 3.0 eV
For sky wave propagation, the radio waves must have a
frequency range in between:
(a) 1 MHz to 2 MHz
(b) 5 MHz to 25 MHz
(c) 35 MHz to 40 MHz (d) 45 MHz to 50 MHz
In the experiment of calibration of voltmeter, a standard cell
of e.m.f. 1.1 volt is balanced against 440 cm of potential wire.
The potential difference across the ends of resistance is
found to balance against 220 cm of the wire. The
corresponding reading of voltmeter is 0.5 volt. The error in
the reading of volmeter will be:
(a) 0. 15 volt
(b) 0.15 volt
(c) 0.5 volt
(d) 0.05 volt

PART B : CHEMISTRY
31.

(a)

1 e2
2 r

(b)

e2
r

me2
1 e2
(d) r
2 r
The de-Broglie wavelength of a particle of mass 6.63 g moving
with a velocity of 100 ms1 is:
(a) 1033 m
(b) 1035 m
31
(c) 10 m
(d) 1025 m
What happens when an inert gas is added to an equilibrium
keeping volume unchanged?
(a) More product will form
(b) Less product will form
(c) More reactant will form
(d) Equilibrium will remain unchanged
The amount of BaSO4 formed upon mixing 100 mL of 20.8%
BaCl2 solution with 50 mL of 9.8% H2SO4 solution with 50
mL of 9.8% H2SO4 solution will be:
(Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16)
(a) 23.3 g
(b) 11.65 g
(c) 30.6 g
(d) 33.2 g
The rate coefficient (k) for a particular reactions is 1.3 10
4
M 1 s 1 at 100C, and 1.3 10 3
1
M s1 at 150C. What is the energy of activation (EA) (in
kJ) for this reaction? (R = molar gas constant = 8.314 JK 1
mol1)
(a) 16
(b) 60
(c) 99
(d) 132
How many electrons would be required to deposit 6.35 g of
copper at the cathode during the electrolysis of an aqueous
solution of copper sulphate? (Atomic mass of copper = 63.5
u, NA = Avogadros constant):

33.

34.

35.

36.

NA
10

NA
NA
(d)
5
2
37. The (S) of the following substances are:
CH4 (g) 186.2 JK1 mol1
O2 (g) 205.2 JK1 mol1
CO2 (g) 213.6 JK1 mol1
H2O (g) 69.9.JK1 mol1
The entropy change (DS) for the reaction :
CH4(g) + 2O2(g) CO2(g) + 2H2O(l) is:
(a) 312.5 J K1 mol1
(b) 242.8 J K1 mol1
(c) 108.1 J K1 mol1
(d) 37.6 J K1 mol1
38. The conjugate base of hydrazoic acid is:

(a) N3
39.

40.

(c)

32.

(b)

(c)

If m and e are the mass and charge of the revolving electron

in the orbit of radius r for hydrogen atom, the total energy of
the revolving electron will be:
(a)

NA
20

41.

42.

43.

44.

(b)

N3-

(c) N -2
(d) HN3In a monoclinic unit cell, the relation of sides and angles are
respectively:
(a) a = b c and a = b = g = 90
(b) a b c and a = b = g = 90
(c) a b c and b = g = 90 a
(d) a b c and a b g 90
The standard enthalpy of formation (Df H 298) for methane,
CH4 is 74.9 kJ mol1. In order to calculate the average
energy given out in the formation of a C H bond from this
it is necessary to know which one of the following?
(a) The dissociation energy of the hydrogen molecule, H2.
(b) The first four ionisation energies of carbon.
(c) The dissociation energy of H2 and enthalpy and
sublimation of carbon (graphite).
(d) The first four ionisation energies of carbon and electron
affinity of hydrogen.
Which of the following xenon-oxo compounds may not be
obtained by hydrolysis of xenon fluorides?
(a) XeO2F2
(b) XeOF4
(c) XeO3
(d) XeO4
Excited hydrogen atom emits light in the ultraviolet region at
2.47 1015 Hz. With this frequency, the energy of a single
photon is:
(h = 6.63 1034 Js)
(a) 8.041 1040 J
(b) 2.680 1019 J
18
(c) 1.640 10 J
(d) 6.111 1017 J
Which one of the following exhibits the large number of
oxidation states?
(a) Ti (22)
(b) V (23)
(c) Cr (24)
(d) Mn (25)
Copper becomes green when exposed to moist air for a long
period. This is due to:
(a) the formation of a layer of cupric oxide on the surface
of copper.
(b) the formation of a layer of basic carbonate of copper
on the surface of copper.
(c) the formation of a layer of cupric hydroxide on the
surface of copper.

45.

46.

47.

48.

49.

(d) the formation of basic copper sulphate layer on the

surface of the metal.
Among the following species the one which causes the
highest CFSE, D0 as a ligand is:
(a) CN
(b) NH3
(c) F
(d) CO
Similarity in chemical properties of the atoms of elements in
a group of the Periodic table is most closely related to:
(a) atomic numbers
(b) atomic masses
(c) number of principal energy levels
(d) number of valence electrons
Which of the following arrangements represents the
increasing order (smallest to largest) of ionic radii of the
given species O2, S2, N3, p3?
(a) O2 < N3 < S2 < p3
(b) O2 < p3 < N3 < S2
(c) N3 < O2 < p3 < S2
(d) N3 < S2 < O2 < p3
Global warming is due to increase of:
(a) methane and nitrous oxide in atmosphere
(b) methane and CO2 in atmosphere
(c) methane and O3 in atmosphere
(d) methane and CO in atmosphere
Hydrogen peroxide acts both as an oxidising and as a
reducing agent depending upon the nature of the reacting
species. In which of the following cases H2O2 acts as a
reducing agent in acid medium?
(a)

MnO-4

(b)

(d)
52.

53.

54.

55.

56.

Cr2 O72-

(c) SO32(d) KI
50. Which one of the following complexes will most likely absorb
visible light?
(At nos. Sc = 21, Ti = 22, V = 23, Zn = 30)
(a) [Sc(H2O)6]3+
(b) [Ti(NH3)6]4+
(c) [V(NH3)6]3+
(d) [Zn(NH3)6]2+

57.

58.
59.

CH2 CH = CH2

51.

CH2 COOH

60.
on mercuration-demercuration produces the major product:
(a)

(b)

(c)

CH2 CH CH3
OH

PART C : MATHEMATICS

CH2 CH2 CH2 OH

61.

A relation on the set A = {x : |x| < 3, x Z },

where Z is the set of integers is defined by
R = {(x, y) : y = |x|, x 1}. Then the number of elements in
the power set of R is:
(a) 32
(b) 16
(c) 8
(d) 64

62.

Let z i be any complex number such that

CH2 CH CH3
OH

In the Victor-Meyers test, the colour given by 1, 2 and 3

alcohols are respectively:
(a) Red, colourless, blue
(b) Red, blue, colourless
(c) Colourless, red, blue
(d) Red, blue, violet
Conversion of benzene diazonium chloride to chlorobenzene
is an example of which of the following reactions?
(a) Claisen
(b) Friedel-craft
(c) Sandmeyer
(d) Wurtz
In the presence of peroxide, HCl and HI do not give antiMarkownikoffs addition of alkenes because:
(a) One of the steps is endothermic in HCl and HI
(b) Both HCl and HI are strong acids
(c) HCl is oxidizing and the HI is reducing
(d) All the steps are exothermic is HCl and HI
The major product obtained in the photo catalysed
bromination of 2--methylbutane is:
(a) 1-bromo-2-methylbutane
(b) 1-bromo-3-methylbutane
(c) 2-bromo-3-methylbutane
(d) 2-bromo-2-methylbutane
Which of the following molecules has two sigma (s) and
two pi (p) bonds?
(a) C2H4
(b) N2F2
(c) C2H2Cl2
(d) HCN
Which one of the following acids does not exhibit optical
isomerism?
(a) Lactic acid
(b) Tartaric acid
(c) Maleic acid
(d) a-amino acids
Aminoglycosides are usually used as:
(a) antibiotic
(b) analgesic
(c) hypnotic
(d) antifertility
Which of the following will not show mutarotation?
(a) Maltose
(b) Lactose
(c) Glucose
(d) Sucrose
Phthalic acid reacts with resorcinol in the presence of
concentrated H2SO4 to give:
(a) Phenolphthalein
(b) Alizarin
(c) Coumarin
(d) Fluorescein

OH

imaginary number.
Then z +

1
is:
z

z-i
is a purely
z+i

63.

64.

(a) 0
(b) any non-zero real number other than 1.
(c) any non-zero real number.
(d) a purely imaginary number.
The sum of the roots of the equation,
x2 + |2x 3| 4 = 0, is:
(a) 2
(b) 2
(c)
(d) - 2
2
If
a2

b2

c2

(a + l) ( b + l) (c + l)
( a - l )2 ( b - l )2 ( c - l )2
2

a2

b2

66.

67.

68.

71. If f (x) = x2 x + 5, x >

kl a

c ,l 0

(a)

1
3

1
13

(b)

1
1
(d) 3
13
72. Let f and g be two differentiable functions on R such that f
(x) > 0 and g(x) < 0 for all x R . Then for all x:
(a) f (g (x)) > f (g (x 1))
(b) f (g (x)) > f (g (x + 1))
(c) g(f (x)) > g (f (x 1))
(d) g(f (x)) < g (f (x + 1))

(c)

(b) 4labc
(d) 4l2

y
6
1 2 x
If A =
and B = x be such that AB = ,

8
3 - 1 2
1

then:
(a) y = 2x
(b) y = 2x
(c) y = x
(d) y = x
8-digit numbers are formed using the digits 1, 1, 2, 2, 2, 3, 4,
4. The number of such numbers in which the odd digits do
no occupy odd places, is:
(a) 160
(b) 120
(c) 60
(d) 48

If 2 +

1
, and g(x) is its inverse function,
2

then g(7) equals:

c2

then k is equal to:

(a) 4labc
(c) 4l2
65.

1
x sin , x 0
f (x) =
x
, and g(x) = x f(x)
0,
,x = 0

Statement I: f is a continuous function at x = 0.

Statement II: g is a differentiable function at x = 0.
(a) Both statement I and II are false.
(b) Both statement I and II are true.
(c) Statement I is true, statement II is false.
(d) Statement I is false, statement II is true.

55

is expanded in the ascending powers of x and

the coefficients of powers of x in two consecutive terms of

the expansion are equal, then these terms are:
(a) 7th and 8th
(b) 8th and 9th
(c) 28th and 29th
(d) 27th and 28th
Let G be the geometric mean of two positive numbers a and
b, and M be the arithmetic mean of

1
1
1
: G is 4
and . If
a
b
M

69.

: 5, then a : b can be:

(a) 1 : 4
(b) 1 : 2
(c) 2 : 3
(d) 3 : 4
The least positive integer n such that

70.

2 2
2
1
1 - - 2 - .... - n -1 <
, is:
3 3
100
3
(a) 4
(b) 5
(c) 6
(d) 7
Let f, g: R R be two functions defined by

73. If 1 + x4 + x5 =

a i (1 + x )

i =0

(a) 4
(c) 8

(c)

sin 2 x cos2 x
sin 3 x + cos3 x

(1 + cot x)
3

, for all x in R, then a2 is:

(b) 6
(d) 10

74. The integral

(a)

sin 3 x

1 + cos3 x

dx is equal to:

+c

(b)

+c

(d)

+c

+c

3 1 + tan 3 x

cos3 x

3 1 + sin 3 x

75. If [ ] denotes the greatest integer function, then the integral

p

[ cos x ] dx

is equal to:

(a)

p
2

(c) 1

(b) 0
(d)

p
2
t

76. If for a continuous function f(x),

( f ( x ) + x ) dx = p2 t2,

-p

p
for all t p, then f - is equal to:
3

7
(a) p

(b)

85.

p
2

p
p
(d)
3
6
The general solution of the differential equation, sin 2x

dy

- tan x - y = 0 , is :
dx

(a)
78.

79.

80.

81.

y tan x = x + c

(b)

y cot x = tan x + c

(c) y tan x = cot x + c (d) y cot x = x + c

If a line intercepted between the coordinate axes is trisected
at a point A(4, 3), which is nearer to x-axis, then its equation
is:
(a) 4x 3y = 7
(b) 3x + 2y = 18
(c) 3x + 8y = 36
(d) x + 3y = 13
If the three distinct lines x + 2ay + a = 0, x + 3by + b = 0 and
x + 4ay + a = 0 are concurrent, then the point (a, b) lies on a:
(a) circle
(b) hyperbola
(c) straight line
(d) parabola
For the two circles x2 + y2 = 16 and
x2 + y2 2y = 0, there is/are
(a) one pair of common tangents
(b) two pair of common tangents
(c) three pair of common tangents
(d) no common tangent
Two tangents are drawn from a point ( 2, 1) to the curve,
y2 = 4x. If a is the angle between them, then |tan a| is equal
to:
(a)

1
3

(b)

86.

87.

(b)

x - b - a y -1 z - d - c
=
=
a
1
c

(c)

x-a y-0 z-c

=
=
b
1
d

88.

(b) 3

(c)

3 3

(d) 6

Let X and M.D. be the mean and the mean deviation about

(b)

X, M.D.

X + 5, M.D.

(d) X + 5, M.D. + 5
(c) X, M.D. + 5
A number x is chosen at random from the set {1, 2, 3, 4, ....,
100}. Define the event: A = the chosen number x satisfies

Then P (A) is:

(a) 0.71
(c) 0.51
Statement I

(b) 0.70
(d) 0.20
The equation

(sin 1

(cos1 x)3 ap3 = 0 has a solution for all a

x) 3

1
.
32

Statement II: For any x R ,

sin -1 x + cos-1 x =

(d) x - b - a = y - 1 = z - d - c
b
0
d
84. If the distance between planes, 4x 2y 4z + 1 = 0 and 4x
2y 4z + d = 0 is 7, then d is:
(a) 41 or 42
(b) 42 or 43
(c)
41 or 43 (d)
42 or 44

3
2

( x - 10 )( x - 50) 0
( x - 30 )

p
and
2

p
9p2

0 sin -1 x -
4
16

(a) Both statements I and II are true.

(b) Both statements I and II are false.
(c) Statement I is true and statement II is false.
(d) Statement I is false and statement II is true.

ellipse

x - b y -1 z - d
=
=
a
1
c

(a)

(a)

(c)
(d) 3
3
82. The minimum area of a triangle formed by any tangent to the

(a)

X of n observations xi, i = 1, 2, ........, n. If each of the

observations is increased by 5, then the new mean and the
mean deviation about the new mean, respectively, are :

x 2 y2
+
= 1 and the co-ordinate axes is:
16 81
(a) 12
(b) 18
(c) 26
(d) 36
83. A symmetrical form of the line of intersection of the planes x
= ay + b and z = cy + d is

x + y + y + z + z + x

(c)
77.

y and z are three unit vectors in three-dimensional

If x,
space, then the minimum value of

89.

cos q

1
- cos q and
If f(q) = - sin q
-1
sin q
1

A and B are respectively the maximum and the minimum

values of f(q), then (A, B) is equal to:
(a) (3, 1)
(c)
90.

(2 +

2, 2 - 2

(b)

(d)

( 4, 2 - 2 )
( 2 + 2, -1)

Let p, q, r denote arbitrary statements. Then the logically

equivalent of the statement p ( q r ) is:
(a)
(b)
(c)
(d)

(p q) r
( p q) (p r )
( p ~ q ) ( p r )
( p q) (p ~ r)

HINTS & SOLUTION

Physics
1.

(b)

Let the velocity when they stick = v

Then, according to question,
Y
2m, 2u

The dimensional formulae of

e = M0 L0T1A1

j sin 60

e0 = M -1L3T 4 A 2

j
m, 3u

-1 3 -2

G = M L T

1 0 0
and me = M L T

Now,

()

e2

M0 L0 T1A1

2 p M -1L-3T 4 A 2 M -1L3T -2 M1L0 T 0

3
3
mui - mui muj = 6m v
2
2

1
3
- mui muj = 6m v
2
2

4.

(b)

1
e2
is dimensionless thus the combination
2p
2 pe 0 Gm e2
would have the same value in different systems of units.

1 "escalator"
60 second
Standing the escalator without walking the speed is

Persons speed walking only is

u
- i - 3j
12
Given, m1 = 4g, u1 = 300 m/s
m2 = 0.8 kg = 800 g, u2 = 0 m/s
From law of conservation of momentum,
m1u1 + m2u2 = m1v1 + m2v2
Let the velocity of combined system = v m/s
then,
4 300 + 800 0 = (800 + 4) v
v=

1200
= 1.49 m / s
804
Now, m = 0.3 (given)
a = mg
a = 0.3 10
= 3 m/s2
then, from v2 = u2 + 2as
(1.49)2 = 0 + 2 3 s
v=

1 "escalator"
40 second
Walking with the escalator going, the speed add.
1
1
15 "escalator"
+
=
60 40 120
second
So, the time to go up the escalator (seconds per escalator)

So, the persons speed is

s=

120
= 24 second.
5
From the law of conservation of momentum we know

(d)
that,
m1u1 + m2u2 + .... = m1v1 + m2v2 + ....
Given m1 = m, m2 = 2m and m3 = 3m
and u1 = 3u, u2 = 2u and u3 = u

i
i
3
3mui - 4mu - 4mu
j - 3mu
2
2
2

3
+ 3mu
j = 6m v
2

3.

+ 3 m u -i cos 60 + jsin 60 = (m + 2m + 3m) v

1
=
2p

is t =

2pe 0 Gme2

T 2 A 2

=
2 p M 0 L0 T 2 A 2

(c)

X
i cos 60
(j) sin 60

3m, u

m 3u i + 2m 2u -i cos 60 - jsin 60

T 2 A 2

=
-1-1+ 2 -3+ 3 4 - 2 2

2p M
L
T A

2.

60
60 i

(1.49 )2
6

2.22
6
= 0.379 m
s=

5.
6.

(d)
(a)

(take g = 10 m/s2)

9
7.

(b) We choose reference point, infinity, where total energy

of the system is zero.
So, initial energy of the system = 0

= 3.297 104 ; 3.3 10 4 N

9.

(b)

1
1
Gm 1m 2
m 1 v12 + m 2 v 22 2
2
d
From conservation of energy,
Initial energy = Final energy

Final energy =

\0=

Initially at t = 0 ; h = h
t=t;h=0

dt = -

1
1
Gm 1 m 2
m 1 v12 + m 1 v 22 =
or
2
2
d
By conservation of linear momentum

...(1)

A
pa

2 gh

dh
dt

dh
2
Then, A - = pa .v
dt

1
1
Gm 1 m 2
m 1 v12 + m 2 v 2 2 2
2
d

dh

[Q velocity of efflux of

liquid v = 2 gh ]
Integrating both sides

v1
m
m
= - 2 v2 = 1 v1
v2
m1
m2

m1v1 + m 2 v 2 = 0 or

Let the rate of falling water level be -

dt = -

Putting value of v2 in equation (1), we get

A
2 g pa 2

-1 2

dh

m v
2Gm1m 2
m1v12 + m 2 - 1 1 =
d
m2

m1m 2 v12

m12 v12

m2

2Gm 22

v1 =

d ( m1 + m 2 )

= m2

2G
d (m1 + m 2 )

10. (b)
11. (b)

2G
d ( m1 + m 2 )

Similarly v 2 = - m1

8.

2Gm1m 2
d

dFmax =

By Newtons law of cooling

50 - 42
50 + 42

= -K
- q0
...(ii)
10
2

Dividing equations (i) by (ii) we get

55 - q0
1
=
0.8 46 - q0

Shearing strain is created along the side surface of the

punched disk. Note that the forces exerted on the disk are
exerted along the circumference of the disk, and the total
force exerted on its center only.
Let us assume that the shearing stress along the side surface
of the disk is uniform, then

2A h
pa 2 g

60 - 50
60 + 50

= -K
- q0
...(i)
10
2

Again, it cools from 50C to 42C in next 10 minutes.

surface

t=

where q0 is the temperature of surrounding.

Now, hot water cools from 60C to 50C in 10 minutes,

F>

[t]

q1 - q2
q + q2

= -K 1
- q0
t
2

(c)

h1 2
=.

2 g pa 2 1 2 h

t
0

s max dA = smax

surface

D
= s max .A = smax .2p h
2
8 1
-2
-2
= 3.5 10 10 0.3 10 2p
2

surface

dA

10 55 - q 0
=
8 46 - q 0

460 - 10q0 = 440 - 8q0

2q0 = 20
q0 = 10c
12. (b) Given :

Q1 = 1000 J
Q2 = 600 J
T1 = 127C = 400 K
T2 = ?
h=?
Efficiency of carnot engine,

10
h=

W
100%
Q1

or,

h=

Q2 - Q1
100%
Q1

or,

h=

343 + 55.83
=
1800
343 - 55.83
= 2499.44 2500Hz
16. (b) Let us consider a spherical shell of radius x and
thickness dx.

1000 - 600
100%
1000
h = 40%

Q 2 T2
Now, for carnot cycle Q = T
1
1

dx
x
Shell

T
600
= 2
1000 400
600 400
1000
= 240 K
= 240 273
T2 =

\ T2 = -33C
13. (a)

C=

(1930 )

Charge on this shell

dq = r.4px2dx = r0 1 - .4px 2dx

R
\ Total charge in the spherical region from centre to r (r < R) is
r

3RT
M

q = dq = 4pr0 1 - x 2dx
R
0

x3 x 4
= 4pr0
3 4R 0

3 8.314 300
=
M

3 8.314 300
2 10 -3 kg
1930 1930
The gas is H2.
14. (d) In linear S.H.M., the restoring force acting on particle
should always be proportional to the displacement of the
particle and directed towards the equilibrium position.
i.e., F x
or F = - bx where b is a positive constant.
15. (b) Given f A = 1800Hz
vt = v
fB = 2150 Hz
M=

r3 r 4
= 4pr0
3 4R

1 r
= 4pr0 r3 3 4R
\ Electric field at r, E =

Reflected wave frequency received by A, f A = ?

Applying dopplers effect of sound,
f =

vs f
vs - v t

f
here, v t = vs 1 - A
fB

1800
= 343 1
2150
vt = 55.8372 m/s
Now, for the reflected wave,
\

v + vt
f A = s
fA
vs - v t

1 .q
4pe 0 r 2

1 4pr0 r3 1 r
.

4pe 0
r 2 3 4R

r r r2
= 0
e0 3 4R
17. (c)

The value of dielectric constant is given as,

K = K 0 + lx
d

And, V = Edr
0
d

V=

s
dx
K

1
= s ( K + l x ) dx
0
0

11
=

s
ln ( K 0 + ld ) - ln K0
l

\ Bqv =

s
ld
= l ln 1 + K

2mv
qd
Time interval for which a uniform magnetic field is
applied

=
=

Q
V

s.s

s
ld
ln 1 +

l K0

c=

18. (b)

ld
ln 1 +

ld
ln 1 +
K 0

(Q in vacuum e0 =1)

5m F
I1

20. (b)

m 0 nI
2a
where, a is the radius of loop.

For loop B =

m 2 3 ( I / 3) p ( a / 3 )
B2 = 0 .
4p
( a / 3)3

9W
16.0 V

I2

In steady state capacitor is fully charged hence no current

will flow through line 2.
By simplyfing the circuit
9W

3W

16.0 V

8.0 V

m0 I
2a

m I 2nA
Now, for coil B = 0 .
4p x 3
at the centre x = radius of loop

line 3
I

pd
2v

Then, B1 =

here, C0 =
d

. C0

line 2

line 1

8.0 V

Dt =

ld

3W

21. (b)

m 0 .3I
2a

B1
m I / 2a
= 0
B2 m0 .3I / 2a

B1 : B2 = 1: 3
In a pure inductive circuit current always lags behind

the emf by

p
.
2

If v ( t ) = v0 sin wt

Hence resultant potential difference across resistances will

be 8.0 V.
Thus current I =

V
R

and I0 =

2
or,
I = = 0.67 A
3
The applied magnetic field provides the required
centripetal force to the charge particle, so it can move

in circular path of radius

then I = I0 sin wt -

2
Now, given v(t) = 100 sin (500 t)

8.0
8
=
=
3 + 9 12

19. (c)

d
Dt = 2
v
(particle reverses its direction after time Dt by covering
semi circle).
p.

s.s
(Let surface area of plates = s)
v

d
= sl.
d

B=

or,

Now it is given that capacitance of vacuum = C0.

Thus, C =

mv2
d/2

d
2

E0
100
=
[Q L = 0.02H ]
wL 500 0.02

I0 = 10sin 500t -
2

I0 = -10cos ( 500t )
22. (b) Wavelength of monochromatic green light
= 5.5 105 cm
Intensity I =

Power
Area

12
=

100 ( 3 /100 )
4p ( 5 )

l = 4400

26. (b)

3
Wm -2
=
100p
Now, half of this intensity (I) belongs to electric field and half
of that to magnetic field, therefore,

2I
or E 0 = e C
0

6
30
25

7.2

3.6 10-3
2
= 1.8 103 Wm2
work function f = hv

If fa is the focal length of lens in air, then

1
1
1
= ( a m l - 1)
fa
R1 R 2

f m ( a ml - 1)
=
fa ( m ml - 1)
If m1 > m, then fm and fa have opposite signs and the nature
of lens changes i.e. a convex lens diverges the light rays and
concave lens converges the light rays. Thus given option (a)
is correct.
24. (c)
25. (b) In a single slit experiment,
For diffraction maxima,

l
2
and for diffraction minima,
a sin q = ( 2n + 1)

a sin q = nl
According to question,
l
= 1 6600
2

(Q l R = 6600 )
6600 2
3

hc
l

6.62 10-34 )( 3 108 )

(
=

\
E 0 = 2.68 V / m
23. (a) If a lens of refractive index m is immersed in a medium of
refractive index m1, then its focal length in medium is given
by
1
1
1
= ( m m l - 1)
fm
R1 R 2

l=

and I = 3.6 10 -3 Wm -2
Intensity associated with each wavelength

3
2
p
100
1

3 108

9
4p 9 10

( 2 1 + 1)

and l 2 = 6216

I 1
= e0 E 02 C
2 4

Given, l1 = 4972

12.4 103
ev
l
for different wavelengths

f1 =

12.4 103 12.4 103

=
= 2.493 eV
l1
4972

= 3.984 1019 J
f2 =

12.4 103 12.4 103

=
= 1.994 eV
l2
6216

= 3.184 1019 J
Work function for metallic surface f = 2.3 eV (given)
f2 < f
Therefore, f2 will not contribute in this process.
Now, no. of electrons per m2-s = no. of photons per m2-s
no. of electrons per m2-s =

1.8 10-3
3.984 10

-19

(Q1 cm

10-4

= 10-4 m 2

= 0.45 1012
So, the number of photo electrons liberated in 2 sec.
= 0.45 1012 2
= 9 1011
27. (b) Given, for 14C
A0 = 16 dis min1 g1
A = 12 dis min1 g1
t1/2 = 5760 years
Now, l =
l=

0.693
t1/ 2

0.693
per year
5760

Then, from, t =

A
2.303
log10 0
l
A

13
=

pressure of each reactant and product remains the

same. Hence no effect on the state of equilibrium.

2.303 5760
16
log10
0.693
12

34. (a)

2.303 5760
log10 1.333
=
0.693

2.303 5760 0.1249

= 2390.81 2391 years.
0.693
Energy band gap range is given by,

28. (d)

Eg =

=
=

-7

: 7 10

-7

98 g

233 g

73 g

23.3 g

7.3 g

According to Arrhenius equation

1=

7 10-7
19.8 10-26

36. (c)

7 10 -7
2.8 10-19

Ea 1 1
k2
=
k1 2.303R T1 T2

1.3 10-3
1.3 10

-4

Ea
1
1

2.303 8.314 373 423

Ea
2.303 8.314

1
1
373 - 423

Ea = 60 kJ / mole
Cu++ + 2e
Cu
i.e, to deposit 1 mole of Cu at cathode from Cu 2+ SO42
solution = 2 moles of electrons are required
i.e, To deposit 6.35g =

1.6 10-19

Eg = 1.75 eV
29. (b) Sky wave propagation is suitable for frequency range
5 MHz to 25 MHz.
30. (d) In a voltmeter
V l
V = kl
Now, it is given E = 1.1 volt for l1 = 440 cm
and V = 0.5 volt for l2 = 220 cm
Let the error in reading of voltmeter be DV then,
1.1 = 400 K and (0.5 DV) = 220 K.

6.35
2 1
2 = = moles
63.5
10 5

Thus total no. of electrons required =

37. (b)

+ 2HCl

9.8 g

log

6.6 10 -34 3 108

BaSO 4

208 g

log

+ H 2SO 4

20.8 g

hc
l

For visible region l = 4 10

Eg =

35. (b)

BaCl 2

NA
5

D S = SCO 2 + 2 SH 2O - SCH 4 + 2 SO 2

= (213.6 + 2 69.9) (186.2 + 2 205.2)

= 242. 8 J K1 mol1.
38. (b)

N3- + H +

N 3H

Hydrazoic acid

i.e, conjugate base of hydrazoic acid is N3.

1.1 0.5 - DV
=
440
220

39. (c)
40. (a)

DV = -0.05 volt

(i)

To calculate average enthalpy of C H bond in

methane following informations are needed
dissociation energy of H2 i.e.

(ii)

1
H 2 ( g )
H( g ); DH = x ( suppose )
2
Sublimation energy of C(graphite) to C(g)

CHEMISTRY
31. (d)

Total energy of a revolving electron is the sum of its

kinetic and potential energy.
Total energy = K.E. + P. E.

Given

e 2 e2
=
+-
2r r
=-

32. (a)

C( graphite)
C( g ); DH = y ( Suppose )
C( graphite ) + 2H 2 ( g )
CH 4 ( g ); DH = 75 kJ mol - 1

41. (d)

e
2r

De Broglie wavelength (l) =

Partial

XeF6 + 2H 2 O
XeO2 F2 + 4HF

h
mv

Compute

42. (c)

- 34

33. (a)

Partial

XeF6 + H 2 O
XeOF4 + 2HF

6.63 10
= 1033
6.63 10-3 100
On adding inert gas at constant volume the total
pressure of the system is increased, but the partial

43. (d)

XeF6 + 3H 2 O XeO3 + 6HF

E = hn
= 6.63 1034 2.47 1015
= 1.640 1018 J
Maganese exhibits the large number of oxidation states.
The most common oxidation states of Mn are +2, +3,
+ 4, + 6 and +7.

14
44. (d)
45. (d)

46. (a)

47. (a)

48. (a)

49. (a)

Copper when exposed to moist air having CO2. It gets

superficially coated with a green layer of basic
carbonate CuCO3. Cu (OH)2.
Following is the order of increasing value of Do for the
ligands.
I < Br < Cl < F < H2O < Py = NH3 < en < NO2 <<
CN < CO
If elements are arranged in order of their increasing
atomic numbers, element coming at intervals of 2, 8, 8,
18, 18, 32 and 32 will have similar physical and chemical
properties and thus grouped in one particular group.
For isoelectronic species ionic radii decreases as the
charge on ion decreases. Further on moving down in a
group ionic radii increases. Hence the correct order is
O2 < N3 < S2 < P3
The main gas responsible for the global warming is
carbon dioxide. Other contributors include methane
released from landfills and agriculture, nitrous oxide
from fertilizers etc.
H2O2 acts as a reducing agent only in presence of
strong oxidising agents (i.e., MnO4) in acidic as well
as alkaline medium.
2KMnO4 + 3H 2SO 4 + 5H 2O 2

51. (a)

(i) Hg(OAC)2

52. (b)

53. (c)

RCH 2 NO2
R - C - NO2 Blood red colour
||
NOH

NO2

C6 H 5 N 2 Cl

CuCl/HCl

54. (a)

55. (d)

or Cu + HCl

C6H 5Cl +
Chloro benzene

CH3
|
Br2
CH3 - CH 2 - CH - CH3

2-methyl butane

CH3
CH3
|
|
CH3 - CH 2 - C H - CH 2 Br + CH3 - CH 2 - C - CH3
|
1-Bromo-2methyl butane
Br
(minor)
2-Bromo-2-methyl butane
(major)

56. (d)

58. (a)
59. (d)

p, s

N
s
p
i.e 2 p and 2 s bonds.
Optical isomers contain an asymmetric (chiral) carbon
atom (a carbon atom attached to four different atoms
or groups). Therefore all except maleic acid exhibit
optical isomerism.
The aminoglycosides are among the oldest antibiotics.
Sucrose does not contain a free aldehydic or ketonic
group hence it does not show mutarotation.
HO

60. (d)

R
AgNO
HNO
> CHI
R > CHNO2

N2

The above reaction is known as Sandmayers reaction.

Anti-Markownikoff addition is possible only in case
of HBr and not in HCl and HI. In HBr both the chain
initiation and propagation steps are exothermic, while
in HCl, first step is exothermic, and second step is
endothermic and in HI, no step is exothermic. Hence
HCl and HI do not undergo anti-Markownikoff s
addition.
The order of substitution in different alkanes is
3 > 2 > 1
Thus the bromination of 2-methyl butane mainly gives
2-Bromo - 2 - methyl butane

COOH
+2
COOH

Nitrolic acid

HI R
(ii) RCHOHR
R

blue colour

KOH

Benzene
diazoniumchloride

HI
AgNO 2
HNO 2
(i) RCH 2 OH
RCH 2 NO 2

RCH 2 I

KOH

KOH

HNO

CH2CHCH3
OH
Victor Meyers test: The various steps involved are

NO

2 No reaction Colourless

57. (c)

(ii) NaBH 4

NO2

H O NO
H2O

HI
AgNO 2
HNO 2
(iii) R 3 COH
R 3 CI
R 3 CNO 2
N.R.

50. (c)

CH2-CH=CH2

K 2SO 4 + 2MnSO 4 + 8H 2 O + 5O 2

The absorption of visible light and hence coloured

nature of the transition metal cation is due to the
promotion of one or more unpaired - d - electron from
a lower to higher level withing same d-subshell. Hence
higher will be the number of unpaired electron higher
will be the absorpion in visible light.
The electronic configuration of the given elements is
Sc3+ (18) = 1s2 2s2 2p6 3s2 3p6 3d0 4s0 - no unpaired e.
Ti4+ (18) = 1s2 2s2 2p6 3s2 3p6 3d0 4s0 - no unpaired e.
V3+ (20) = 1s2 2s2 2p6 3s2 3p6 3d2 4s0 - Two unpaired e.
Zn2+ (28) = 1s2 2s2 2p6 3s2 3p6 3d10 4s0 - no unpaired e.
hence [V(NH3)6]3+ will most likely absorb visible light.

KOH

C - NO2 Blue colour

Conc. H2SO 4
OH

15

(2 x - 3) if
|2x 3| =
- (2 x - 3) if

O
C
O

3
, x2 + 2 x - 3 - 4 = 0
2
x2 + 2x 7 = 0

for x >
+ H2O

HO

3
2
3
x<
2
x>

OH

x=

Fluorescein

-2 4 + 28
-2 4 2
= -1 2 2
=
2
2
3

2 2 - 1 <
2

Here x = 2 2 - 1

Mathematics
61.

62.

(b)

(c)

3
2
x2 2x + 3 4 = 0
x2 2x 1 = 0

x=

for x <

A = {x : |x | < 3, x Z }
A = {2, 1, 0, 1, 2}
R = {(x, y) : y = |x |, x -1}
R = {(2, 2), (0, 0), (1, 1), (2, 2)}
R has four elements
Number of elements in the power set of R
= 24 = 16
Let z = x + iy

x 2 + ( y + 1) 2
x2 + y2 -1
x 2 + ( y + 1) 2

2 xi
x 2 + ( y + 1) 2

for pure imaginary, we have

x2 + y2 -1
x 2 + ( y + 1) 2

x2 + y2 = 1
(x + iy) (x iy) = 1

x + iy =

and

1
= x iy
z
z+

1
=z
x - iy

1
= ( x + iy ) + ( x - iy ) = 2 x
z

z + is any non-zero real number

z
63.

(c)

64.

(c)

Let D =

x2 + 2 x - 3 - 4 = 0

a2

b2

c2

(a + l)2

(b + l )2

(c + l ) 2

(a - l)2

(b - l )2

(c - l ) 2

Apply R2 R2 R3
a2

b2

c2

2
2
2
2
2
2
D = (a + l ) - ( a - l) (b + l) - (b - l) (c + l) - (c - l)

(a - l )2

(b - l)2

(c - l )2

a2

b2

c2

4al

4bl

4c l

(a - l )2

(b - l ) 2

(c - l ) 2

=0

Sum of roots : (2 2 - 1) + (1 - 2) =

x - 2ix ( y + 1) + xi ( y - 1) + y - 1

(1 - 2) <

Here x = 1 - 2

z-i
is purely imaginary means its real part is zero.
z+i

x + iy - i
x + i ( y - 1) x - i ( y + 1)

=
x + iy + i
x + i ( y + 1) x - i ( y + 1)

2 4+4 2 2 2
=
= 1 2
2
2

(Q ( x + y )2 - ( x - y )2 = 4 xy )
Taking out 4 common from R2

a2

b2

al

=4
2

c2

bl
2

cl

a + l - 2al b + l - 2bl c + l 2 - 2cl

Apply R3 [R3 (R1 2R2)]

16
a2

b2

c2

= 4 al bl

cl

l2

l2

l2

x
rth term = 255 55Cr
6

1
Coefficient of xr is 255 55Cr r
6

Taking out l common from R2 and l2 from R3.

a2

b2

c2

2
= 4l ( l ) a
1

b
1

c
1

a2

b2

c2

= kl a
1

b
1

c
1

x
(r +1)th term = 255 55Cr +1
6

(a)

68.

6
12
and y =
5
5
y = 2x
In 8 digits numbers, 4 places are odd places.
Also, in the given 8 digits, there are three odd digits
1, 1 and 3.
No. of ways three odd digits arranged at four even

x=

(a)

G=

4 P3 4!
=
2! 2!
No. of ways the remaining five digits 2, 2, 2, 4 and
5!
4 arranged at remaining five places =
3!2!
Hence, required number of 8 digits number

4! 5!
=

= 120
2! 3!2!
Let rth and (r + 1)th term has equal coefficient

2 +
3

55

x
= 255 1 +
6

ab

M=

55

a+b
2ab
1
:G = 4 :5
M

Given that
2ab
(a + b) ab

places =

(a)

1
r +1

1 1
+
M= a b
2

6
y + 3x
8 = 3 y - x + 2

y + 3x = 6 and 3y x = 6
On solving, we get

67.

= 255 55Cr +1

1
1
1
=
.
r 55 - r r + 1 54 - r 6
6 (r + 1) = 55 r
6r + 6 = 55 r
7r = 49
r=7
(r + 1) = 8
Coefficient of 7th and 8th terms are equal.

y
x
1 2 x
Let A = 3 -1 2 and B =

6
y + 2x + x
8 = 3 y - x + 2

(b)

255 55Cr

y
1 2 x
x
AB = 3 -1 2
1

66.

r +1

1
55 55
Cr +1. r +1
Coefficient of xr+1 is 2
6
Both coefficients are equal

k = 4l2

65.

a+b
2 ab

5
4

a + b + 2 ab

5+ 4
5- 4
a + b - 2 ab
{Using Componendo & Dividendo}

( a )2 + ( b ) 2 + 2 ab
2

9
1

9
b+ a 3

=
1
b- a 1

( a ) + ( b ) - 2 ab

b + a

b - a

4
5

b+ a+ b- a

3 +1
=
3 -1
b+ a- b+ a
{Using Componendo & Dividendo}

17
= 02 a finite quantity between 1 and 1
=0

b
4
= =2
a
2

1
RHL = lim h2 sin = 0
+
h
h 0

b
4
=
a
1
a
1
=
a:b=1:4
b
4

69.

(b)

1-

71.

(c)

2 2
2
1
- 2 .... n-1 <
3 3
100
3

1
19

=y
x - +
2
4
1

x -
2

1 1

1 - 2 n - 1

1
3 3
<

1
100
-1
3

x-

3n - 1
1
1- 2
<
n
2.3 100

x=

x=

1
1
1 -1 + n <
100
3
100 < 3n
Thus, least value of n is 5

g(x) =

and g ( x) = x f ( x )
For f (x)

g(7) =

h 0

(b)

73.

(a)

1
=0
h

Also, f (0) = 0
Thus LHL = RHL = f(0)
\ f (x) is continuous at x = 0
1
2
x sin , x 0
x
g(x) =
0,
x=0

For g(x)

1
LHL = lim - h 2 sin
h
h 0

1
2

1
19
+ x2
4
1
2 x-

72.

19
4

1
19
+ y2
4

g(x) =

RHL = lim+ h sin

= y-

1
19
y2
4

1
x sin , x 0
f (x) =
x
0,
x=0

1
LHL = lim- - h sin -
h
h 0
= 0 a finite quantity between 1 and 1
=0

1
19
= y2
4

As x >

3n - 1
1
1-
<
n
3 100

(b)

1 1
- +5 = y
4 4

x2 x +

2 1 1
1
1
1
1- +
+ + ...
<

2
3
1
n3 3 3
3
3 100

70.

Also g(0) = 0
\ g(x) is continuous at x = 0
f (x) = y = x2 x + 5

19
4

1
19
2 74

1
28 - 19
2
2

1
3

Since f (x) > 0 and g(x) < 0, therefore

f (x) is increasing function and g(x) is decreasing
function.
f (x + 1) > f (x) and g (x + 1) < g (x)
g [f (x + 1)] < g [ f (x)] and f [g (x + 1)] < f [g (x)]
Hence option (b) is correct.
5

1+ x + x =

i= 0

ai (1 + x)i

1
2
3
= a0 + a1 (1 + x) + a2 (1 + x ) + a3 (1 + x )

+ a4 (1 + x )4 + a5 (1 + x )5

1 + x 4 + x5
= a0 + a1 (1 + x) + a2 (1 + 2 x + x 2 ) + a3 (1 + 3 x + 3 x 2 + x3 )

18
+ a4 (1 + 4 x + 6 x 2 + 4 x3 + x 4 ) + a5 (1 + 5x + 10 x 2 + 10 x3 + 5x 4 + x5 )

1 dt 1 -2
= t dt
3 t2
3

\I=

1 + x 4 + x5

1 t -2+1
-1 1
+c
I = 3 -2 + 1 + c =
3 t

2
= a0 + a1 + a1 x + a2 + 2a2 x + a2 x + a3 + 3a3 x

+3a3 x 2 + a3 x3 + a4 + 4a4 x + 6a4 x 2 + 4a4 x3 + a4 x 4 + a5

+5a5 x + 10a5 x 2 + 10a5 x3 + 5a5 x 4 + a5 x5

or I = -

1 + x 4 + x5
= (a0 + a1 + a2 + a3 + a4 + a5 ) + x(a1 + 2a2 + 3a3 + 4a4 + 5a5 )
2

(d)

Let I =

a3 = +6 ...(6)

sin 2 x cos 2 x

76.

(a)

I=

- 1dx (Q [ x ] + [ - x] = -1 if x Z )

dt
3tan x sec 2 x

-p

( f ( x ) + x)dx = p2 t2

f ( x )dx +

-p
t

-p

t
-p

xdx = p2 t2

t 2 p2
f ( x )dx + - = p2 t2
2
2

-p

f ( x )dx =

d t
3 d 2 2
f ( x)dx =
(p - t )

-p
dt

2 dt

dt
2

3 tan x sec 2 x

dt
d
- f ( -p) ( -p) = 3t
dt
dt
f (t) = 3t
f (t ).

1 sin 2 x.sec 4 x
dt

2
2
3
sin x
t
sec2 x
cos 2 x

dt
1 sin 2 x.sec4 x

= 3
2
2
t
sin x sec 4 x

-p
2

3 2 2
(p - t )
2
differentiating with respect to t

Put 1 + tan 3 x = t

Let

sin x.sec 2 x
=
dx
(1 + tan3 x )

sin x.sec x

[cos x ] + [ - cos x]dx

I=

dx
cos3 x (1 + tan 3 x)

\I=

2I = - x 0 = -p

sin x.cos x
I = 3
dx
sin x + cos3 x

2I =

(sin 3 x + cos3 x)2 dx

Now, from (1), (5) and (6), we get

a2 = 4

dt = 3tan 2 x sec2 x dx or dx =

[ - cos x ]dx

2I =

sin x. cos x

[cos x]dx + [ - cos x]dx

2I =

a4 = -4 ...(5) from (1), (3) & (5), we get

On adding (1) and (2), we get

from (1) & (2), we get

...(1)

[cos(p - x )]dx =

a3 + 4a4 + 10 a5 = 0 ...(3) and a2 + 3a3 + 6 a4 + 10a5 = 0 ...(4)

I=

[cos x]dx

I=

a5 = 1 ...(1) ; a4 + 5a5 = 1 ...(2);

Let I =

+c

+ x 4 (a4 + 5a5 ) + x5 (a5 )

On comparing the like coefficients, we get

(b)

3(1 + tan 3 x)

75.

+ x (a2 + 3a3 + 6a4 + 10a5 ) + x ( a3 + 4 a4 + 10a5 )

74.

p
p
f - = -3 - = p
3
3
77.

(d)

dy

Given, sin 2 x - tan x - y = 0

dx

...(2)

19
or,

dy
y
+ tan x
=
dx
sin 2 x

or,

dy
- y cosec2 x =
dx

...(1)

tan x

- cosec2 x
Now, integrating factor (I.F) = e

or, I.F =

1
- log|tan x|
e 2

= e

log

tan x

) -1

= cot x
tan x
Now, general solution of eq. (1) is written as

y (I. F.) =

80.

Q(I.F.) dx + c

\ y cot x =

\ y cot x =

1.dx + c

tan x . cot x dx + c

\ y cot x = x + c

78.

(d)

81.

(d)

(b)

C(0, b)
2

A(4, 3)

x + 4ay + a = 0
...(3)
Subtracting equation (3) from (1)
2ay = 0
ay = 0 y = 0
Putting value of y in equation (1), we get
x+0+a=0
x=a
Putting value of x and y in equation (2), we get
a+b=0
a=b
Thus, (a, b) lies on a straight line
Let, x2 + y2 = 16 or x2 + y2 = 42
radius of circle r1 = 4, centre C1 (0, 0)
we have, x2 + y2 2y = 0
x2 + (y2 2y + 1) 1 = 0 or x2 + (y 1)2 = 12
Radius 1, centre C2 (0, 1)
|C1C2 | = 1
| r2 r1| = |4 1| = 3
| C1C2| < |r2 r1|
no common tangents for these two circles.
The locus of the point of intersection of tangents to
the parabola y2 = 4 ax inclined at an angle a to each
other is
tan2a (x + a)2 = y2 4ax
Given equation of Parabola y2 = 4x {a = 1}
Point of intersection (2, 1)
tan2a (2 + 1)2 = (1)2 4 1 (2)
tan2a = 9
tan a = 3
|tan a| = 3

1
82.

O (0, 0)
B(a, 0)

(d)

81
A 0,
k
(h, k)

A divides CB in 2 : 1

1 0 + 2 a 2a
4 =
=
1+ 2
3
a = 6 coordinate of B is B (6, 0)
1 b + 2 0 b
3 =
=
1+ 2 3
b = 9 and C (0, 9)
Slope of line passing through (6, 0), (0, 9)
9
3
=slope, m =
-6
2
Equation of line y 0 =

79.

(c)

16
B , 0
h

Let (h, k) be the point on ellipse through which

tangent is passing.
Equation of tangent at (h, k) =

-3
( x - 6)
2

2y = 3x + 18
3x + 2y = 18
x + 2ay + a = 0

...(1)

x + 3by + b = 0

...(2)

at y = 0, x =

16
h

at x = 0, y =

81
k

Area of AOB =

xh yk
+
=1
16 81

1 16 81 648
=
2 h k hk

20
A2 =

(648)2

h2k 2
(h, k) must satisfy equation of ellipse

Distance between them is 7 =

...(1)

h2 k 2
+
=1
16 81
16
(81 - k 2 )
81
Putting value of h2 in equation (1)

h2 =

A2 =

81(648) 2
16 k 2 (81 - k 2 )

d -1
= 7
6
d = 42 + 1
or 42 + 1
i.e. d = 41 or 43.

(b)

( x + y + z)2 0

3 + 2 S x. y 0

2 S x. y -3

85.

a
81k 2 - k 4

= 6 + 2 S x. y 6 + ( -3)

-1

(162k - 4 k 3 )
2AA = a
2
81k - k 4

2AA = 2A (81k 4k3) A= 81k 4k3

Put A = 0
162k 4k3 = 0, k (162 4k2) = 0

k = 0, k =

86.

(b)

2
A = (81 12k2)
For both value of k, A = 405 > 0

will be X + 5 and new M.D. about new mean will

2
87.

(a)

( x - 10)( x - 50)
0 " x [10, 30)
x - 30
Total value of x between 10 to 30 is 20.
Total values of x between 50 to 100 including 50 and
100 is 51.
Total values of x = 51 + 20 = 71

Given two planes :

x ay b = 0 and cy z + d = 0
Let, l, m, n be the direction ratio of the required line.
Since the required line is perpendicular to normal of
both the plane, therefore l am = 0 and cm n = 0
l am + 0.n = 0 and 0.l + cm n = 0

and 4 x - 2 y - 4 z + d = 0
They are parallel.

( x - 10)( x - 50)
0
( x - 30)

x - 50
0, " x [10, 30)
as
x - 30

P (A) =

(c)

Given

Let x 10, x 50 equation will be true " x 50

648 2
Area of triangle AOB =
= 36 sq unit
2 2 9

l
m
n
=
=
a - 0 0 +1 c - 0
Hence, d.R of the required line are a, 1, c.
Hence, options (c) and (d) are rejected.
Now, the point (a + b, 1, c + d) satisfy the equation
of the two given planes.
\ Option (b) is correct.
Given planes are
4x - 2 y - 4z + 1 = 0

x
=
Q
Mean

ni

i =1

be M.D.

h = 2 2

84.

Let xi be n observations, i = 1, 2, ...n

about X .
If each observation is increased by 5 then new mean

16
(81 - k 2 ) = 8
h =
81

(b)

2
2
2
x + y + y + z + z + x 3

Let X be the mean and M.D be the mean deviation

83.

16 + 4 + 16

2
2
2
Now, x + y + y + z + z + x

differentiating w.r. to k

Area will be minimum for k =

d -1

88.

(a)

71
= 0.71
100

p p
sin -1x - ,
2 2
-

p p
3p -1
sin x -
4
4 4
2

9
p

0 sin -1 x - p 2

4
16

Statement II is true
3
(sin -1 x)3 + (cos -1 x )3 = ap

..(1)

21

(sin -1 x + cos -1 x) (sin -1 x + cos -1 x ) 2 - 3 sin -1 x cos -1 x

= ap3

p
- 3sin -1 x cos -1 x = 2ap2
4

sin

-1

89.

(c)

=
2

p
-1
p2
sin x - =
(32a - 1)

4
48
Putting this value in equation (1)

0 32a - 1 27
1
7
a
32
8
Statement-I is also true.

Let f (q) =

- sin q

- cos q

-1

sin q

= 1 + sin q cos q + sin q cos q + cos2 q - sin 2 q + 1

= 2 + 2sin q cos q + cos 2q
= 2 + sin 2q + cos 2q
...(1)
Now, maximum value of (1)

p2
p2
(8a - 1) +
12
16

9
p2
0
(32 a - 1) p 2
48
16

= (1 + sin q cos q) - cos q( - sin q - cos q) + 1( - sin 2 q + 1)

p2
x - sin -1 x =
(1 - 8a )
2

12

p
-1
sin x -

cos q

is 2 + 12 + 12 = 2 + 2
and minimum value of (1) is
90.

(b)

2 - 12 + 12 = 2 - 2 .
Given statement is

p (q r ) which is equivalent to
( p q) ( p r )