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Laboratory Report
[Determination of Equilibrium Constant for
triiodide constant]
ABSTRACT
This experiment was conducted to determine the equilibrium constant for tri-iodide
and the effect of different concentration on the value of equilibrium constant. The effect of
different iodine concentration in an iodine-triiodide equilibrium system is investigated by
redox titration with sodium thiosulphate and stoichiometric calculation. The Kc value for both
experiments is then calculated via I-C-E table. Our result shows that the Kc value for 10 gL-1
Iodine-KI solution system is recorded at 105 with a difference of 13 unit in comparison to the
Kc value of 5 gL-1 iodine-KI system (Kc = 118) at 283K. Experimental errors like
equilibrium was not fully established, slight differences in experiment temperature, and
titration errors had contributed to the deviation of the experimental result from our
hypothesis.
(124 words)
1.0
Experiment no. 3
INTRODUCTION
the law of mass action which states that " In a system at equilibrium, at a fixed temperature,
the products of equilibrium concentration of the products divided by the product of the
concentration of reactant each raised to the coefficient of the substance in the equation must
be equal to a constant (The Equilibrium Law 2012).
The ionic equation and the equilibrium expression for Iodide-triiodide equilibrium
can be depicted in Equation 1.0 and 2.0 below:
I- + I2 I3-
(Equation 1.0)
(Equation 2.0)
As the
can be calculated through acid base titration, the [I2]aq at equilibrium
can then be determined through the distribution coefficient. Similarly, the initial [I2]aq can be
calculated via acid base titration. Hence, the concentration change of iodine, iodide and
triiodide ion can be determined easily via an ICE table.
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Experiment no. 3
temperature will change the rate of both the forward and reverse reactions at different extents
and the equilibrium moves to a new equilibrium constant (Chemical Equilibrium 2012).
1.1
OBJECTIVES
The first objective in this experiment is to determine the equilibrium constant of triiodide equilibrium. The second objective is to determine the effect of different initial
concentration on the equilibrium constant value.
2.0
EXPERIMENTAL SECTION
0.150 M potassium iodide solution was measured. Both solutions were mixed in a 500 mL
separation funnel. The initial temperature of the solutions was recorded (refer to Appendix
A). The solution mixture was shaken for 10 minutes. The stopcock of the funnel was released
occasionally to equalize the vapor pressure. The solution was left to stand for 10 minutes to
reach thermal equilibrium. The aqueous layer was collected into a 250 mL conical flask and
the organic layer was collected into a 100 mL conical flask. Fifty milliliters of aqueous layer
was then pipette into a clean 250 mL conical flask. The aqueous layer was then titrated with
0.10 M sodium thiosulphate solution until the color has changed to pale yellow. Few drops of
starch were added as an indicator and the titration process was continued until it turned
colorless (please refer to Appendix A for the titer value).
About 20 mL of deionized water, 0.5 g solid KI and 2 drops of 3.0 M sulfuric acid 5
mL of the organic layer was mixed into a clean 100 mL conical flask. The organic layer was
titrated with 0.02 M sodium thiosulphate solution with starch added as indicator (please refer
to Appendix A for the titer value). These two titrations were repeated for the remaining
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2E2/Delon
Experiment no. 3
aqueous and organic layer after it has been remixed into the separator funnel and shaken for 5
minutes. Two consecutive layers were then collected and pipette identically to the first trial.
gL iodide in light petroleum and diluted with 25 mL of light petroleum prepare 5.0 gL-1
iodine solution in petroleum ether.
3.0
(Equation 3.0)
The value of !7
(Equation 4.0)
(Equation 5.0)
96:
2;
<= 8 38
(Equation 6.0)
By using Equation 3.0, Equation 4.0, Equation 5.0 and Equation 6.0, the value of
!7 at initial can be calculated as well. Equation 7.0 is used for the calculation of
concentration difference between initial I2(aq) and equilibrium I2(aq), which can further
determined the concentration of !7 at equilibrium as shown below:
!7 ! 7@"A@B
!7
!"
C !7 7@"A@B
Page 4 of 11
(Equation 7.0)
2E2/Delon
Experiment no. 3
(Equation 8.0)
The calculations was repeated for Part B (Please refer to Appendix B for the
calculation steps). The results were tabulated in an ICE table in Table 1.0 and Table 2.0
respectively. The values of both trials are then calculated with Equation 2.0.
Table 1.0: ICE table for Part A
(aq)
(aq)
(aq)
[Initial]
0.00690
0.150
0.000
[Change]
-0.00647
-0.00647
+0.00647
[Equilibrium]
0.000429
0.144
0.00647
For Part A,
0.00647
,0.144/,0.000429/
=105
(aq)
(aq)
(aq)
[Initial]
0.00395
0.150
0.00
[Change]
-0.00373
-0.00373
+0.00373
[Equilibrium]
0.000216
0.146
0.00373
For Part B,
0.00373
,0.146/,0.000216/
=118
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2E2/Delon
4.0
Experiment no. 3
DISCUSSION
The equilibrium constant value, Kc obtained when the initial concentration of the I2 is
0.00690 M, is determined at 105 while the equilibrium constant value, O obtained when the
initial concentration of the I2 is 0.00395, is 118. There is no doubt that the value of Kc will
fulfil the law of mass action provided that the equilibrium temperature is undisturbed
(Equilibrium 2011).
The biased result might have been caused by several experimental errors. The
difference in Kc value has been caused by the inconsistent reaction temperature during the
experiment. Temperature would play a key role in a chemical equilibrium and affects the
value (Zumdahl and Zumdahl 2003, 641). When the temperature of an equilibrium system
is not constant, the rates of the forward and reverse reactions will change as well (Anderton
et. al 2004, 289). The formation of triiodide ion is an exothermic reaction. Thus when the
temperature is decreased by 0.5C for part B, the rate of both forward and reverse reaction
increases with the rate of reverse reaction (endothermic reaction) increases more prominently,
causing the Kc value to increase as depicted in Equation 9.0 below:
(Equation 9.0)
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5.0
Experiment no. 3
CONCLUSION
In conclusion, the value of the tri-iodide equilibrium is 105. The effect of different
concentration of reactant on the value was an increase of 13 units. While two readings are
immensely close, it did not support the prediction made as some errors occurred during the
experiment.
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Experiment no. 3
REFERENCES
Anderton John D. , Patrick J. Garnett, Bob Liddelow, Ric K. Lowe, Larry Manno. 2004.
Foundations Chemistry. 2nd ed. Malaysia: Pearson Education Australia
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2E2/Delon
Experiment no. 3
APPENDIX A
Titration Data of the Experiment:
Part A
27.5 C
Part B
27.0 C
Part A
Part B
Final
7.00
13.90
3.90
7.90
Initial
0.00
7.00
0.00
3.90
Titre
7.00
6.90
3.90
4.00
Part A
Part B
Final
8.20
16.30
3.10
5.00
Initial
0.00
8.20
1.10
3.10
Titre
8.20
8.10
4.20
4.00
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Experiment no. 3
APPENDIX B
CALCULATION OF THE DATA
Part A.
a. The mean titre value of organic layer
U.
V$U.#V
=8.15ml
The titration chemical equation:
2
%
& ' (
% 2
) * + *
#
0.005W =0.0000815
W = 0.0163
[
=0.0163
Using the distribution coefficient,
V.V#(
38=
2;
!7 0.000429
b. The mean titre value of aqueous layer
X.VV$(.UV
=6.90ml
The titration chemical equation:
2
%
& ' (
% 2
) * + *
#
0.005W =0.0000345
W = 0.0069
Initial [
!7 =0.0069
Using the distribution coefficient,
c. !7 ! 7@"A@B 2 D E C 2 D DFEGF
= 0.00690-0.000429
=0.00647
d. C !7 ! 7@"A@B C D E C 3C D DFEGF
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2E2/Delon
Experiment no. 3
= 0.150-0.00647
= 0.144
(aq)
(aq)
(aq)
[Initial]
0.00690
0.150
0.00
[Change]
-0.00647
-0.00647
+0.00647
[Equilibrium]
0.000429
0.144
0.00647
V.VV('X
,V.#'X/,V.VVV'
Y/
=103
Part B
a. The mean titre value of organic layer
'.
V'.VV
=4.10ml
The titration chemical equation:
2
%
& ' (
% 2
) * + *
#
0.005W =0.00041
W = 0.0820
[
=0.0820
Using the distribution coefficient,
38=
V.VU
V
2;
!7 0.000216
b. The mean titre value of aquoues layer
.YV$'.VV
=3.95ml
The titration chemical equation:
2
%
& ' (
% 2
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) * + *
#
Experiment no. 3
{50mL)W =
,V.#/,.YZ/
W = 0.00395
Initial [
!7 =0.00395
c. !7 ! 7@"A@B 2 D E C 2 D DFEGF
=0.00395-0.000216
=0.00373
C
(aq)
(aq)
(aq)
[Initial]
0.00395
0.150
0.00
[Change]
-0.00373
-0.00373
+0.00373
[Equilibrium]
0.000216
0.146
0.00373
V.VVX
,V.#'(/,V.VVV
#(/
=118
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