You are on page 1of 40

NARAYANA IIT/PMT ACADEMY

JEE ADVANCE : 2013


(PAPER II)
This booklet contains 40 printed pages XYZ

CODE: 0
Test Booklet Code

PAPER -1 : PHYSIC, CHEMISTY & MATHEMATICS


Please Read the Instructions carefully You are allotted 5 minutes specifically for

this purpose
Important Instructions:
INSTRUCTIONS

A General :
This booklet is your Questions Paper Do not break the seals of this booklet before being instructed to do
so by the invigilators
The question paper CODE is printed on the right hand top corner of this sheet and on the back page
(Page No 44) of this booklet
Blank spaces and blank pages are provided in the question paper for your rough work No additional
sheets will be provided for rough work
Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers and
electronic gadgets are NOT allowed inside the examination hall
Write your name and roll number in the space provided on the back cover of this booklet
Answers to the questions and personal details are to be filled on a two part carbon less paper, which
is provided separately These parts should only be separated at the end of the examination when
instructed by the invigilator The upper sheet is machine gradable objective Response Sheet (ORS)
which will be retained by the invigilator You will be allowed to take away the bottom sheet at the end of
the examination
Using a black ball point pen darken the bubbles on the upper original sheet Apply sufficient pressure so
that the impression is created on the bottom duplicate sheet
DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET
On breaking the seals of the booklet check that it contains 44 pages and all the 60 questions and
corresponding answers choices are legible Read carefully the instruction printed at the beginning of
each section and TOTAL MARKS 180
B, Filling the right part of the ORS
The ORS also has a CODE printed on its left and right parts
Check that the CODE printed on the ORS (on both sheets) is the same as that on this booklet and put
your signature affirming that you have verified this
IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF THE BOOKLET

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(PAPER II)

CODE: 0

PART I : PHYSICS
SECTION -1 : (One or more options correct Type)
The section contains 8 multiple choice questions Each question has four choices (A), (B), (C) and (D)
out of which ONE and MORE are correct
1
The figure below shows the variation of specific heat capacity (C) of a solid as a function of
temperature (T) The temperature is increased continuously from 0 to 500 K at a constant rate
Ignoring any volume change, the following statement(s) is (are) correct to a reasonable
approximation
(A) the rate at which heat is absorbed in the range 0-100 K varies linearly with temperature T
(B) heat absorbed in increasing the temperature from 0-100 K is less than the heat required for
increasing the temperature from 400-500 K
(C) there is no change in the rate of heat absorption in the range 400-500 K
(D) the rate of heat absorption increases in the range 200-300 K

100 200 300 400 500


T(K)

Ans
Sol:

A, B, C, D
dQ CdT and C varies linearly with T
(A) is correct
Area under the graph in the range O-100 k is less than area under 400-500 K range
(B) is correct
In the range 400 500 K, C is constant
(C) is correct
In the range 200 300 K, C is increasing
(D) is correct
The radius of the orbit of an electron in a hydrogen-like atom is 45 a0, where a0 is the Bohr
3h
radius Its orbital angular momentum is
It is given that h is Planck constant and R is Rydberg
2
constant The possible wavelength(s), when the atom de-excites, is (are)
9
9
(A)
(B)
32R
16R
2

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
9
5R
A, C
aon2
4.5 ao
Z
nh 3h
2
2
n 3, z 2
(C)
Ans
Sol:

Ans

1 1
x12 x 22
Possible wavelengths are
9
9
1
,
and
5R 32R
3R
Using the expression 2d sin = , one calculates the values of d by measuring the corresponding
angles in the range 0 to 90o The wavelength is exactly known and the error in is constant
for all values of As increases from 0o
(A) the absolute error in d remains constant
(B) the absolute error in d increases
(C) the fractional error in d remains constant (D) the fractional error in d decreases
D

Sol:

Now,

CODE: 0

(PAPER II)
4
(D)
3R

Rz 2

2sin
d

cos ec cot
2
d
Now
cot
d
As increases, fractional error decreases
Two non-conducting spheres of radii R1 and R2 and carrying uniform volume charge densities +
and , respectively, are placed such that they partially overlap, as shown in the figure At all
points in the overlapping region,
(A) the electrostatic field is zero
(B) the electrostatic potential is constant
(C) the electrostatic field is constant in magnitude (D) the electrostatic field has same direction

R1

R2

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(PAPER II)
Ans
Sol:

CODE: 0

C, D
In the overlapping region
r1
r2
E
3 o 3 o
r

r1

r2

Ans
Sol:

C and D are correct


3 o
A steady current I flows along an infinitely long hollow cylindrical conductor of radius R This
cylinder is placed coaxialy inside an infinite solenoid of radius 2 R The solenoid has n turns per
unit length and carries a steady current I Consider a point P at a distance r from the common axis
The correct statement (s) is (are)
(A) In the region 0 < r < R, the magnetic field is non-zero
(B) In the region R < r < 2R, the magnetic field is along the common axis
(C) In the region R < r < 2R, the magnetic field is tangential to the circle of radius r, centered on
the axis
(D) In the region r > 2R, the magnetic field is non-zero
A, C, D
B Bhollow
Bsolenoid
E

conductor

B due to hollow conductor is zero inside the conductor and non-zero outside (co-axial) while B
due to solenoid is zero outside the solenoid and non-zero inside the solenoid (axial)
R

Ans

2R

A, C & D
Two vehicles, each moving with speed u on the same horizontal straight road, are approaching
each other Wind blows along the road with velocity w One of these vehicles blows a whistle of
frequency f1 An observer in the other vehicle hears the frequency of the whistle to be f2 The
speed of sound in still air is V The correct statement (s) is (are)
(A) If the wind blows from the observer to the source, f2 > f1
(B) If the wind blows from the source to the observer, f2 > f1
(C) If the wind blows from observer to the source, f2 < f1
(D) If the wind blows from the source to the observer, f2<f1
A, B
v w vo
f 2 f1
v w vs
A & B are correct
4

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
7

Ans
Sol:

(PAPER II)
CODE: 0
Two bodies, each of mass M, are kept fixed with a separation 2L A particle of mass m is
projected from the midpoint of the line joining their centres, perpendicular to the line The
gravitational constant is G The correct statement(s) is (are)
(A) The minimum initial velocity of the mass m to escape the gravitational field of the two
GM
bodies is 4
L
(B) The minimum initial velocity of the mass m to escape the gravitational field of the two
GM
bodies is 2
L
(C) The minimum initial velocity of the mass m to escape the gravitational field of the two
2GM
bodies is
L
(D) The energy of the mass m remains constant
B,D
1
2GMm
mve2
0
2
L
GM
ve 2
L
M

ve

A particle of mass m is attached to one end of a mass-less spring of force constant k, lying on a
frictionless horizontal plane The other end of the spring is fixed The particle starts moving
horizontally from its equilibrium position at time t = 0 with an initial velocity u0 When the speed
of the particle is 05 u0, it collides elastically with a rigid wall After this collision,
(A) the speed of the particle when it returns to its equilibrium position is u0
(B) the time at which the particle passes through the equilibrium position for the first time is
m
t
.
k

4
m
.
3 k
(D) the time at which the particle passes through the equilibrium position for the second time is
m
t
.
3 k
A, D
3u
using v
A2 x 2 , we get x
2
(x : distance between mean position & the wall)
Now using x = A sin t
5
(C) the time at which the maximum compression of the spring occurs is t

Ans
Sol:

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

2
3

m
k

time for option (B) =

2
3

m
k

2
3

time for option (C)

4
3

m
k

m
2 k

time for option (D) =

7
6

m
k

m
k

4
3
7
6

m
2 k

m
k
m
k

5
3

m
k

SECTION 2 : (Paragraph Type)


This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate to
four paragraphs with two questions on each paragraph Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D)
A small block of mass 1 kg is released from rest at the top of a rough track the track is a circular arc of
radius 40 m the block slides along the track without toppling and a frictional force acts on it in the
direction opposite to the instantaneous velocity The work done in overcoming the friction up to the point
Q, as shown in the figure below, is 150 J (Take the acceleration due to gravity, g = 10 ms2)
y
R
o

30

Q
O

Ans
Sol:

10

Ans
Sol:

The speed of the block when it reaches the point Q is


(A) 5 ms1
(B) 10 ms1
(C) 10 3ms 1
(D) 20ms 1
B
From work-kinetic energy theorem
1 2
mgR sin 30o Wf
mv
2
v = 10 m/s
The magnitude of the normal reaction that acts on the block at the point Q is
(A) 75 N
(B) 86 N
(C) 115 N
(D) 225 N
A
At Q:
6

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

N mg cos 60o

mv
R

N 7.5N

Paragraph for questions 11 and 12


A thermal power plant produces electric power of 600 kW at 4000 V, which is to be transported to a
place 20 km away from the power plant for consumers usage It can be transported either directly with a
cable of large current carrying capacity or by using a combination of step-up and step-down
transformers at the two ends The drawback of the direct transmission is the large energy dissipation In
the method using transformers, the dissipation is much smaller In this method, a step-up transformer is
used at the plant side so that the current is reduced to a smaller value At the consumers end, a stepdown transformer is used to supply power to the consumers at the specified lower voltage It is
reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power
factor unity All the currents and voltages mentioned are rms values
11

Ans
Sol

If the direct transmission method with a cable of resistance 04


dissipation (in%) during transmission is
(A) 20
(B) 30
(C) 40
(B)
P 600 103 watt
Vrms 4000 volt
Total resistance R = 04 20 = 80
2
PL I rms
R
Power lost
2

So % loss

12

P
600 103
R
Vrms
4000
= 180000 watt
= 180 kW
180
=
100 30
600
= 30%

km-1 is used, the power


(D) 50

In the method using the transformers, assume that the ratio of the number of turns in the primary
to that in the secondary in the step-up transformer is 1 : 10 If the power to the consumers has to
be supplied at 200 V, the ratio of the number of turns in the primary to that in the secondary in
the step-down transformer is
(A) 200 : 1
(B) 150 : 1
(C) 100 : 1
(D) 50 : 1

Ans (A)
Sol Step up

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

NP

NS
VS=?

For Step down

4000V
VS
10
4000 1

VS

40, 000 volt

NS Vout
200
N P Vinput
40, 000
NP : NS = 200 : 1

So

1
200

Paragraph for Questions 13 and 14


A point charge Q is moving in a circular orbit of radius R in the x-y plane with an angular velocity
This can be considered as equivalent to a loop carrying a steady current

A uniform magnetic field


2
along the positive z-axis is now switched on, which increases at a constant rate from 0 to B in one
second Assume that the radius of the orbit remains constant The application of the magnetic field
induces an emf in the orbit The induced emf is defined as the work done by an induced electric field in
moving a unit positive charge around a closed loop It is known that, for an orbiting charge, the magnetic
dipole moment is proportional to the angular momentum with a proportionality constant
13

The magnitude of the induced electric field in the orbit at any instant of time during the time
interval of the magnetic field change is
BR
BR
(A)
(B)
(C) BR
(D) 2BR
4
2

Ans(B)
Sol Induced emf =

d
dt

dB
R2
dt
e B R2
E.2 R B. R 2
BR
E
2
e

14

The change in the magnetic dipole moment associated with the orbit, at the end of the time
interval of the magnetic field change, is

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
(A)

BQR 2

BQR
2

(B)

(C)

BQR
2

(D) BQR 2

Ans (C or B)
Sol

B 2
R
t
B 2
E.2 R
R
t
B R2
E
2 R. t
L
t
m
L
QBR 2
m
2
Sign may be taken as +ve/-ve also depending upon direction of angular velocity
e

Paragraph for questions 15 and 16


The mass of a nucleus AZ X is less than the sum of the masses of (A-Z) number of neutrons and Z number
of protons in the nucleus The energy equivalent to the corresponding mass difference is known as the
binding energy of the nucleus A heavy nucleus of mass M can break into two light nuclei of masses m1
and m2 only if (m1 + m2) < M Also two light nuclei of masses m3 and m4 can undergo complete fusion
and form a heavy nucleus of mass M ' only if (m3 + m4) > M ' The masses of some neutral atoms are
given in the table below :
1
1

1007825 u

2
1

2014102 u

3
1

6
3

Li

6015123 u

7
3

Li

7016004 u

70
30

151919803 u

206
82

205974455 u

209
83

152
64

15

Gd

Pb

Zn
Bi

3016050 u

4
2

69925325 u

82
34

208980388 u

210
84

He

Se
Po

4002603 u
81916709 u
209982876 u

The correct statement is


(A) The nucleus 36 Li can emit an alpha particle

(B) The nucleus 84210 Po can emit a proton


(C) Deuteron and alpha particle can undergo complete fusion
(D) The nuclei 3070 Zn and 8234 Se can undergo complete fusion
Ans (C)
Sol from data given only option C is correct
m3 m 4 M '

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
16

(PAPER II)
The kinetic energy (in keV) of the alpha particle, when the nucleus
decay, is
(A) 5319
(B) 5422
(C) 5707

CODE: 0
210
84

Po at rest undergoes alpha


(D) 5818

Ans (A)
Sol From data given
Po 210 82 Pb 206 2 He 4
84
m=00058184 u
E = 0005818 932
=5422376 MeV
E 206
KE of particle
210
= 5319 MeV = 5319 KeV

SECTION 3 : (Matching List Type)


This section contains 4 multiple choice questions Each question has matching lists
The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct
17

One mole of a monatomic ideal gas is taken along two cyclic processes E F G E and
E F H E as shown in the PV diagram The processes involved are purely isochoric,
isobaric, isothermal or adiabatic

Match the paths in List I with the magnitudes of the work done in List II and select the correct
answer using the codes given below the lists

P
Q
R

List I
G E
G H
F H

1
2
3

List II
160 P0 V0 ln2
36 P0 V0
24 P0 V0
10

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
S
Codes :
P Q
(A) 4 3
(B) 4 3
(C) 3 1
(D) 1 3

R
2
1
2
2

CODE: 0

(PAPER II)
4
31 P0 V0

S
1
2
4
4

Ans (A)
Sol
= 5/3
FH is steeper therefore it is adiabatic process FG is isothermal
PF VF PH VH
FH

(32P0 )V0 PH VH
PFVF = PGVG
(32P0)V0 = P0VG

FG

8V0

VG = 32 V0

GE

Isobaric Process
Work = P V = P0 (32V0 V0) = 31 P0V0

GH

Work = P0 (32V0 8V0) = 24 P0V0


P V P V (32P0 )V0 P0 8V0
Work 1 1 2 2
36P0 V0
1
5/3 1
V
Work PF VF ln G 32P0 V0 ln 32 160 ln 2
VF

FH
FG
18

VH

Match List I of the nuclear processes with List II containing parent nucleus and one of the end
products of each process and then select the correct answer using the codes given below the lists
List I
List II
15
P
Alpha decay
1
O 157 N ....
8
238
Q
2
decay
U 90234 Th ....
98

Codes :
P Q
(A) 4 2
(B) 1 3
(C) 2 1
(D) 4 3

Fission

185
83

Bi

Proton emission

239
94

Pu

R
1
2
4
2

184
82
140
57

Pb ....
La ....

S
3
4
3
1
11

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
Ans
Sol

(C)
1 158 O

19

15
7

238
92

234
90

185
83

Bi

184
82

239
94

Pu

0
1

Th

4
2

Pb

1
1

140
57

La

x is

particle

x is

99
47

particle

X is Proton

Fission

A right angled prism of refractive index

is placed in a rectangular block of refractive index

, which is surrounded by a medium of refractive index 3 , as shown in the figure A ray of


light e enters the rectangular block at normal incidence Depending upon the relationships
between 1, 2 and 3 , it takes one of the four possible paths ef, eg, eh or ei
2

Match the paths in List I with conditions of refractive indices in List II and select the correct
answer using the codes given below the lists :
List I
List II
P
1
e f
2 2
1
Q
2
e g
and 2
2
1
3

Codes :
P Q
(A) 2 3
(B) 1 2
(C) 4 1
(D) 2 3
Ans (D)
Sol
S-1

R
1
4
2
4

and

S
4
3
3
1

e i case of TIR
which is possible only when

45o is

ic
12

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

sin iC

if

, iCis 45o

Q3

R4

e
h is 1
prism, (prism
e
f 1

P2
20

g is [

2
2

] rays undergo undeviated for any angle of incidence

and not undergoing (TIR) light ray bends towards base of


block)
and 2
3 (Snells law)

Match List I with List II and select the correct answer using the codes given below the lists :
List I
Boltzmann constant
Coefficient of viscosity
Planck constant
Thermal conductivity

P
Q
R
S
Codes :
P Q
(A) 3 1
(B) 3 2
(C) 4 2
(D) 4 1

R
2
1
1
2

1
2
3
4

List II
[ML2T-1]
[ML-1T-1]
[MLT-3K-1]
ML2T-2K-1]

S
4
4
3
3

Ans (C)
Sol

energy
ML2 T 2
= ML2T-2K-1
Kelvin
K
Planks constant = energy time = ML2T-2 T = ML2T-1
F
MLT 2
ML 1T 1
Co-efficient of viscosity =
L LT 1
L2 T 1
Energy Length
Thermal conductivity =
MLT-3K-1
Area Kelvin Time
P
4
Q 2
R
1
S
3
Boltzmann constant =

13

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

PART II : CHEMISTRY
SECTION 1 : (One or more options correct Type)
This section contains 8 multiple choice questions Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct
21

Ans
Sol

22

Ans
Sol
23

Ans
Sol

The carbon-based reduction method is NOT used for the extraction of


(A) tin from SnO2
(B) iron from Fe2O3
(C) aluminium from Al2O3
(D) magnesium from MgCO3CaCO3
(C), (D)
Al is extracted by electrolytic reduction
MgCO3, CaCO3 are extracted by electrolytic reduction
The thermal dissociation equilibrium of CaCO3 (s) is studied under different conditions
CaCO3 (s)
CaO (s) + CO2 (g)
For this equilibrium, the correct statement(s) is(are)
(A) H is dependent of T
(B) K is independent of the initial amount of CaCO3
(C) K is dependent on the pressure of CO2 at a given T
(D) H is independent of the catalyst, if any
(A), (B), (D)
Conceptual
The correct statement(s) about O3 is(are)
(A) O O bond lengths are equal
(B) Thermal decomposition of O3 is endothermic
(C) O3 is diamagnetic in nature
(D) O3 has a bent structure
(A), (B), (C), (D)
(A) bond length are equal due to resonance
+

O
O

No unpaired electrons so diamagnetic


24

Ans
Sol

In the nuclear transmutation


9
X 84 Be Y
4 Be
(X, Y) is(are)
(A) , n
(B) p, D
(A), (B)
8
1
(A) 94 Be
4 Be 0 n

(C) n, D

(D)

,p

14

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
9
4

(B) Be
25

8
4

Be

2
1

The major product(s) of the following reaction is(are)


OH
aqueous Br2 3.0 equivalents

SO3H
OH
Br

Ans

OH
Br

Br

Br
SO3H

Br

Br

Br

Br

(A) P
(B)

Br

Br
SO3H

(B) Q

(C) R

(D) S

OH

OH

Br

Br

aqueous Br2 3.0 equivalents

Sol.

Br

SO3H

26

OH

OH

Br

Br

After completion of the reactions (I and II), the organic compound(s) in the reaction mixtures
is(are)
O

Reaction I: H3C

CH3

Br2 1.0mol
aqueous NaOH

1.0 mol

Reaction II: H3C

CH3

Br2 1.0mol
CH3COOH

1.0 mol

O
H3C

CH2Br

Ans

O
H3C

O
CBr 3

Br 3C

O
CBr 3

CH2Br

Q
R
S
(A) Reaction I: P and Reaction II : P
(B) Reaction I : U, acetone and Reaction II: Q, acetone
(C) Reaction I: T, U, acetone and Reaction II: P
(D) Reaction I: R, acetone and Reaction II: S, acetone
(C)

O
CH2Br H3C

O
ONa H3C

ONa

15

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
O

Sol

Reaction I: 1/3 mole of CH C CH react with 1 mole of Br2 to give Bromofarm and sodium
3
3
acetate and 2/3 mole of acetone itself
Reaction II: Mono bromination at -carbon in acidic medium

27

The Ksp of Ag2CrO4 is 11 10-12 at 298 K The solubility (in mol/L) of Ag2CrO4 in a 01 M
AgNO3 solution is
(A) 11 10-11
(B) 11 10-10
(C) 11 10-12
(D) 11 10-9
(B)
Ag 2CrO4
2Ag
CrO42

Ans
Sol

s'
0.1 2s '
Ksp = (01 + 2s )2 s
11 10-12 = 10-2 s
s = 11 10-10
28

s'

In the following reaction, the product(s) formed is(are)


OH
CHCl3
OH

CH3
OH
CHO

O
CHO

CH3

Ans
Sol

OH

OH

CHO

H3C

CHCl 2

H3C

Q
P
(A) P (major)
(B) Q (minor)
(B), (D)
It is Reimer Tiemann Reaction

CHCl 2

R
(C) R (minor)

CH3

S
(D) S (major)

OH

CHO

So

H3C

CHCl 2

is minor and

is major
CH3

16

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

SECTION 2 : (Paragraph Type)


This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate
to four paragraphs with two questions on each paragraph Each question of a paragraph has only one
correct answer among the four choices (A), (B), (C) and (D)
Paragraph for Questions 29 and 30
An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate
(P) and a filtrate (Q) The precipitate P was found to dissolve in hot water The filtrate (Q) remained
unchanged, when treated with H2S in a dilute mineral acid medium However, it gave a precipitate (R)
with H2S in an ammoniacal medium The precipitate R gave a coloured solution (S), when treated with
H2O2 in an aqueous NaOH medium
29
Ans
Sol
30
Ans
Sol

The precipitate P contains


(A) Pb2+
(B) Hg 22
(C) Ag+
(A)
Salt will be of PbCl2 as it is soluble in hot water
The coloured solution S contains
(A) Fe2(SO4)3
(B) CuSO4
(D)
Cr3+ + H2S/NH4OH, NH4Cl
Cr(OH)3 + H2O2 + NaOH

(C) ZnSO4

(D) Hg2+

(D) Na2CrO4

Cr(OH)3
Na2CrO4
(yellow colour)

Paragraph for Question 31 and 32


P and Q are isomers of dicarboxylic acid C4H4O4 Both decolorize Br2/ H2O On heating, P forms the
cyclic anhydride
Upon treatment with dilute alkaline KMnO4, P as well as Q could produce one or more than one from S,
T and U
31

Compounds formed from P and Q are, respectively


(A) Optically active S and optically active pair (T, U)
(B) Optically inactive S and optically inactive pair (T, U)
(C) Optically active pair (T, U) and optically active S
(D) Optically inactive pair (T, U) and optically inactive S

31

(B)

17

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
Sol

P and Q are
H

H
C

HOOC

COOH

COOH

HOOC

(Fumaric -acid)

(Maleic -acid)

Baeyers reagent, ie dilute alkaline KMnO4 will give syn addition product of alkene
COOH
H

H
C

HOOC

COOH

KMnO4/OH

OH

dilute

OH
COOH

(cis)

(meso)
COOH
COOH

H
C

HOOC

KMnO4/OH

H
HO

dilute

COOH

OH

HO

H
COOH

(trans)

32

H
OH
COOH

(Racemic mixture)

In the following reaction sequences V and W are, respectively

Q
+ V

AlCl3 (anhydrous)

H 2 / Ni

1. Zn-Hg/HCl
2. H3PO4

O
O and

(A)

W
CH2OH

and

(B)
CH2OH

18

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
O
O and

(C)

HOH 2C

(D)

and
CH2OH

CH 2OH

Ans

(A)
O
HOOC

H2/Ni
O

Sol.
COOH

Fumaric acid
(Q)

(V)

O
O

AlCl3

CH2

anhydrous

CH2
HO

1. Zn-Hg/HCl
2. H3PO4

Paragraph for Question 33 and 34


A fixed mass m of a gas is subjected to transformation of states from K to L to M to N and back to K
as shown in the figure
L

K
Pressure

N
Volume

19

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
33

Ans
Sol

(PAPER II)
CODE: 0
The succeeding operations that enable this transformation of states are
(A) Heating, cooling, heating, cooling
(B) Cooling, heating, cooling, heating
(C) Heating, cooling, cooling, heating
(D) Cooling, heating, heating, cooling
(C)

K
Pressure

N
Volume

34

The pair of isochoric processes among the transformation of states is


(A) K to L and L to M
(B) L to M and N to K
(C) L to M and M to N
(D) M to N and N to K

Ans
Sol

(B)
According to following graph the proven L

M isochoric and N

K also isochoric

Paragraph for Question 35 and 36


The reactions of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two
(different) oxoacids of chlorine, P and Q, respectively The Cl2 gas reacts with SO2 gas, in presence of
charcoal, to give a product R R reacts with white phosphorous to give a compound S On hydrolysis, S
gives an oxoacid of phosphorus, T
35

P and Q, respectively, are the sodium salts of


(A) hypochlorus and chloric acids
(B) hypochlorous and chlorous acids
(C) chloric and perchloric acids
(D) chloric and hypochlorous acids

Ans
Sol

(A)
Cl2 + cold NaOH(aq)
Cl2 + (hot) NaOH

Cl2 + SO2 + Coke

NaCl + NaOCl, (oxiacid HOCl) hypochlorous acid


NaCl + NaClO3, (oxiacid HClO3) chloric acid
P HOCl
Q HClO3
SO2Cl2 P
PCl5 H O H3PO4
4

20

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(PAPER II)
36

Ans

R, S and T, respectively, are


(A) SO2Cl2, PCl5 and H3PO4
(C) SOCl2, PCl3 and H3PO2

CODE: 0

(B) SO2Cl2, PCl3 and H3PO3


(D) SOCl2, PCl5 and H3PO4

(A)

SECTION 3 (Matching List Type)


This section contains 4 multiple choice questions Each question has matching lists The codes for the
lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct
37

An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List I The


variation in conductivity of these reaction is given in List II Match List I with List II and select
the correct answer using the code given below the lists:
List I
P (C2H5)3N + CH3COOH
X
Y
Q KI(01M) + AgNO3(001M)
X
Y
R CH3COOH + KOH
X
Y
S NaOH + HI
X
Y
Code :
P
Q R S
(A) 3 4 2 1
(B) 4 3 2 1
(C) 2 3 4 1
(D) 1 4 3 2

List II
1 Conductivity decreases and then increases
2 Conductivity decreases and then doest not
change much
3 Conductivity increases and then does not
change much
4 Conductivity does not change much and then
increases

Ans

(A) Factual

38

The standard reduction potential data at 250C is given below


E0 (Fe3+, Fe2+) = +077 V
E0 (Fe2+, Fe) = 044 V
E0 (Cu2+, Cu) = +034 V;
E0 (Cu2+, Cu) = +052 V
E0[O2(g) + 4H+ + 4e
2H2O] = +123 V
E0[O2(g) + 2H2O + 4e
4OH ] = +040V
0
3+
E (Cr , Cr) = 074 V;
E0 (Cr2+, Cr) = 091 V;
Match E0 of the redox pair in List I with the values given in List II and select the correct answer
21

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
using the code given below the lists:
List I
P E ( Fe , Fe)
0

List II

3+

Q E (4H2O
4H + 4OH )
0
2+
R E (Cu + Cu
2Cu+)
S E0 (Cr3+, Cr2+)
Code :
P
Q R S
(A) 4 1 2 3
(B) 2 3 4 1
(C) 1 2 3 4
(D) 3 4 1 2
Ans
Sol

(D)
(P) E0 (Fe3+, Fe)
Fe3+ + e
Fe2+ + 2e
Fe3+ + 3e
G3
3E

0
3

E30

G1

Fe2+
Fe
Fe

1
2

018 V
04 V

3
4

004 V
083 V

E10

0.77V

0
2

0.44V

E 30

G2

1 0.77 (2 0.44)
0.11
0.0366
0.04 V
3

(Q) E0 (4H2O
2H+ + 4OH )
2H2O
O2 + 4H+ + 4e
O2 + 2H2O + 4e
4OH
4H+ + 4OH

4H2O

(R) E0 (Cu2+ + Cu
2Cu+)
Cu2+ + 2e
Cu
+
2(Cu
Cu + e) E0 = 052 V

E0 = 123 V
E0 = +04 V
E0 = 083 V

E0 = +034 V

Cu2+ + Cu
2Cu+
0
3+
2+
(S) E (Cr , Cr )
Cr3+ + 3e
Cr
2+
Cr + 2e
Cr

E0 = 034 052 = 018 V

Cr3+ + e

E 30

G3

G1

Cr2+

E10 = 074 V
E 02 = 091V

G2

22

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
0
3

E = 3

(074)

( 2

091)

E = 222 182
0
3

E 30 = 04V

39

The unbalanced chemical reactions given in List I show missing reagent or condition (?) which
are provided in List II Match List I with List II and select the correct answer using the code
given below the lists
List I
List II
P PbO2 + H2SO4

PbSO4 + O2 + other product

1 NO

Q Na2S2O3 + H2O

NaHSO4 + other product

2 I2

R N2H4
S XeF2
Code :
P
(A) 4
(B) 3
(C) 1
(D) 3

3 warm

N2 + other product

4 Cl2

Xe + other product

Q
2
2
4
4

R
3
1
2
2

Ans

(D)

Sol

(i) PbO2 + H2SO4

S
1
4
3
1

warm

PbSO4 + H2O2

H2O +

1
O2
2

Cl
(ii) Na2S2O3 + H2O
2NaHSO4 + NaCl
I
(iii) N2H4
N2 + 2HI
(iv) XeF2 + NO
Xe + NOF
2

40

The unbalanced chemical reactions given in List I show missing reagent or condition (?) which
are provided in List II Match List I with List II and select the correct answer using the code
given below the lists
List I

P.

Cl

Q.

ONa

List II
1 (i) Hg(OAc)2; (ii) NaBH4

OEt

OH

2 NaOEt
3 Et Br

R.
23

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
4 (i) BH3; (ii) H2O2/NaOH
S.
OH

Code :
P
(A) 2
(B) 3
(C) 2
(D) 3
Ans

Q
3
2
3
2

R
1
1
4
4

S
4
4
1
1

(A)

Sol. P.

Q.

Cl

NaOEt
Elimination

ONa

Et-Br
Substitution

(i) Hg(OAc)2

R.

(ii) NaBH4

OEt

OH

Follows
markownikov's
product

(i) BH3

S.

(ii) H2O2/NaOH
Follows
antimarkownikov's
product

OH

24

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

PART III : MATHEMATICS


SECTION 1 (Only or more options correct Type)
This section contains 8 multiple choice questions Each question has four choices (A) (B), (C) and (D)
out of the which ONE or MORE are correct
41

Let

be a complex cube root of unity with

Ans

Then P2
(A) 57
(B,C,D)
2

(B) 55

1
2
2

Sol

pij

be a n n matrix with pij

i j

0 , when n =

1
2

1 and P

...
...

1
...

(C) 58
2

... ...

...
...

1
2

...

.....

1
2

...
...

...
...

...

...

(D) 56

... ...

.....

...

...

Clearly P2 will be O if n is a multiple of 3, then only, the elements of P2 will be reduced to


2
1
0
2
If P 0 n is not multiple of 3
42

The function y

2 | x | | x 2 | | x 2 | 2 | x | has a local minimum or a local maximum at x =

(A) 2
Ans
Sol

(A, B)
y 2| x | | x 2| | x
x
2
Case (i)
y 2x x 2
y
3x 2 | x
y
2x 4
Case (ii) 2 x 0
y
x 2 | 3x
2
So
for x
3
y 2x 4

(B)

2
3

(C) 2

(D)

2
3

2| 2| x |

| x 2 2x |
2|
(1)
2|

(2)
25

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
And

for x

2
,0
3

(3)
y 4x
Case (iii) 0 x
y 2x x 2 | x 2 2x |
y 3x 2 | x 2 |
For
0 x 2
(4)
y 4x
And for, x 2
(5)
y 2x 4
So graph is

4
y = 2x +

(0,8)
y= -2x-4

y=

(-2, 0)

4
2x+

y= -

4x

(-2/3,0)

(0,8/3)
(0, 0)

y=4x
x
(2,0)

From graph
x
2,0 , are point of minimum,
2
& x
is point of maxima
3
43

Ans
Sol

3 i
1
n
: n 1, 2,3,... Further H1
and P
and
z C : Re z
2
2
1
, where C is the set of all complex numbers If z1 P H1 , z 2
H2
z C : Re z
2
and O represents the origin, then z1O z 2
2
5
(A)
(B)
(C)
(D)
2
6
3
6
(C, D)

Let w

H2

26

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

Clearly from the figure,


44

Ans
Sol

2
5
or or
3
6

z1Oz 2

If 3x

4 x 1 , then x =
2 log 3 2
2
(A)
(B)
2 log 3 2 1
2 log 2 3
(A, B, C)
3x 4x 1
Taking log both sides with base 3
log3 3 log3 4x 1

x log3 3
x
x

1
1 log 4 3

(D)

2 log 2 3
2 log 2 3 1

x 1 log 3 4

x 1 log 3 4
x log 3 4 log 3 4

log 3 4

(C)

x log 3 4 1

log3 4
log3 4 1
2log3 2
2log3 2 1

3x 4x 1
Taking log both sides with base 4
log 4 3x log 4 4x 1
x log 4 3 x 1
1 x x log 4 3

1
or x
1 log 4 3

x 1 log 4 3

2
2 log 2 3

27

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
45

Ans
Sol

Two lines L1 : x
value(s)
(A) 1
(A, D)
x 5
y
L1 :
0
3
x
y
L2 :
0
1
5
0

0
0
5,

3
5;6 5

5
1

(B) 2

are coplanar Then

(C) 3

can take

(D) 4

z
2
z
2
0
2

3
1

5,

CODE: 0

(PAPER II)
z
y
z
and L2 : x
,
2
1 2

2
2
2

2 0

4 0
4 0
1, 4,5

46

Ans
Sol

47

1
Further the incircle of the triangle touches
3
the sides PQ, QR and RP at N, L and M respectively, such that the lengths of PN, QL and RM
are consecutive even integers Then possible length(s) of the side(s) of the triangle is (are)
(A) 16
(B) 18
(C) 24
(D) 22
(B, D)
1
Cos P
3
2
2
2
4n 2
4n 4
4n 6
1
3
2 4n 2 4n 4
n 4 or n
1
Hence, the possible length of side of PQR will be 18, 20 or 22
For a R (the set of all real numbers), a
1,
In a triangle PQR, P is the largest angle and cos P

Lt

n 1

(A) 5
Ans

a 1

1a

2a .... n a

na 1

na 2

...

(B) 7

na n

1
then a =
60

(C)

15
2

(D)

17
2

(B, D)

28

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(PAPER II)

CODE: 0

Sol

ra

Lt

r 1

n 1

a 1

na r
r 1

na

Lt

n 1

r 1
n

a 1

r
n
a

r 1

r
n
a

na

Lt

n 1

a 1

1 n r
nr1 n
1 n
r
a
nr1
n
a

Lt

1
n

a 1

1 n r
nr1 n
1 n
r
a
nr1
n

x a dx
0
1

a x dx

1
60

2a 2 3a 119 0

17
2
Circles(s) touching x axis at a distance 3 from the origin and having an intercept of length
2 7 on y-axis is (are)
(A) x 2 y 2 6x 8y 9 0
(B) x 2 y 2 6x 7y 9 0
(C) x 2 y 2 6x 8y 9 0
(D) x 2 y 2 6x 7y 9 0
(A, C)
Let circle be
x 2 y 2 2gx 2fy c 0
a

48

Ans
Sol

7, a

g2 c, 2 f 2 c 2 7
g
3,c 9,f
4
So circle will be
x 2 y 2 6x 8y 9 0

29

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

SECTION 2 (Paragraph Type)


This section contains 4 paragraphs each describing theory, experiment, data etc Eight questions relate to
four paragraphs with two questions on each paragraph Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D)
Paragraph for Questions 49 to 50
R (the set of all real numbers) be a function Suppose the function f is twice

Let f : 0,1

differentiable, f 0 f 1 0 and satisfies f x 2f ' x


49
Which of the following is true for 0 < x < 1 ?
1
1
(A) 0 f x
(B)
f x
2
2
Ans (D)
e x f " x 2f ' x e x e x f x 1
Sol
e xf " x

f' x e

e xf ' x

d
d
e xf ' x
e xf x
dx
dx
d d
e xf x
1
dx dx
Let e x f x g x
g" x

e xf x

f x

(C)

f x

1
4

f x

0,1

(D)

f x

Since g 0 g 1 0 and g" x


Possible graph for g(x) is

positive

1
O
Since g x

0for x

0,1

Therefore f x is negative for x


f x

Which satisfies
50

If the function e x f x

0,1

assumes its minimum in the interval {0, 1] at x

1
, which of the
4

3
4

1
4

following is true?
(A) f ' x

f x ,

1
4

(B) f ' x

f x ,0 x

30

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
(C) f ' x
Ans

(C)

Sol

For x

0,

e xf ' x
f' x

f x ,0 x

1
4

1
4

g' x
e xf x

f x for x

(D) f ' x

f x ,

3
4

x 1

0,

1
4

Paragraph for Question 51 and 52


Let PQ be a focal chord of the parallel y 2 4ax. The tangents of the parabola at P and Q meet at a point
lying on the line y 2x a, a 0.
51
Ans
Sol

Length of chord PQ is
(A) 7a
(B) 5a
(B)

(C) 2a

(D) 3a

(at2, 2at)
P

y=2x+a
(0, 0)
(-a, -a)

Q
a 2a
Q 2,
t
t
2

1
PQ a t
(i)
t
Eq of tangent at P
ty x at 2
As it passes through (a, a)
at = a + at2
t2 + t 1 = 0
5 1
(for p, t > 0)
t
2
2

PQ

5 1
2

2
5 1

5 1
5 1

31

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
5 1
2

5 1
= 5a
2

If chord PQ subtends an angle at the vertex of y 2 4ax, then tan


2
2
2
2
(A)
(B)
(C)
(D)
7
5
7
5
3
3
3
3
(D)
2
m1 = slope of OP
5 1
t
m2 = slope of OQ
2t
5 1

52

Ans
Sol

m1 m2
2
5
3
1 m1m2
Where is Acute angle between line OP and OQ but as
2
tan
5
3
tan

POQ obtuse

Paragraph for Question 53 and 54


Let S

S1

S2

S1

:z

S3

: Re z

53

Ans
Sol

S3 , where

4 ,

S2

: Im

z 1 3i
1 3i

0 .

Area of S =
10
(A)
3
(B)

(B)

20
3

(C)

16
3

(D)

32
3

|z|=4

600
B
A (1, -3)

3x

32

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
S1 represent the inside part of circle |z| = 4
3x y 0
By putting z = x + iy, we get S2
S3 represent the right part of y-axis
S is the shaded region in above diagram
r2 2 r2
r 2 20
Now A
4
3 4
3 4
3
54

min 1 3i z
z

(A)
Ans
Sol

(B)

(C)

2
2
2
(C)
Min |1 3i z| = minimum distance of point A 1, 3 z
= AB distance in diagram
3 3 3 3

(D)

3
2

S from region S

2
Paragraph for Question 55 and 56

A box B1 contains 1 white ball, 3 red balls and 2 block balls Another box B2 contains 2 white balls, 3 red
balls and 4 black balls A third box B3 contains 3 white balls, 4 red balls and 5 black balls
55

Ans
Sol

56

Ans
Sol

If 1 balls is drawn from each of the boxed B1, B2 the probability that all 3 drawn balls are of the
same colour is
82
90
558
566
(A)
(B)
(C)
(D)
648
648
648
648
(A)
Required probability
1 2 3 3 3 4 2 4 5
6 9 12 6 9 12 6 9 12
82
648
If 2 balls are drawn (without replacement) from a randomly selected box and one of the balls is
white and the other balls is red, the probability that these 2 balls are drawn from box B2 is
116
126
65
55
(A)
(B)
(C)
(D)
181
181
181
181
(D)
Required probability

33

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

1
3
1
3

C1. C1
6
C2

C1. C1
9
C2

C1. C1
9
C2

55
181

C1. C1
12
C2

SECTION 3: (Matching list Type)


This section contains 4 multiple choice question Each question has matching lists The codes for the lists
have choice (A), (B), (C) and (D) out of which ONLY ONE is correct
57
P

List-I
Volume of parallelepiped determined by vector
a, b and c is 2 Then the volume of the
parallelepiped determined by vectors
2 a b , 3 b c and c a is

List-II
100

Volume of parallelepiped by vectors a, b and c is 2


5 Then the volume of the parallelepiped determined
by vectors 3 a b , 3 b c and 2 c a is

30

Area of a triangle with adjacent sides determined


by vectors a and b is 20 Then the area of the
triangle with adjacent sides determined by vectors
2a 3b and a b is

24

Area of a parallelogram with adjacent sides


determined by vectors a and b is 30 Then the area
of the parallelogram with adjacent sides determined

60

by vectors a b and a is
Codes

Ans
Sol

P
Q
R
S
(A)
4
2
3
1
(B)
2
3
1
4
(C)
3
4
1
2
(D)
1
4
3
2
(C)
(P) volume of parallelepiped = 2
Volume

2 a b . 3 b c
6 a b .

b c .a c

c a
b c .c a

34

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(PAPER II)

CODE: 0

6 a b . abc c
2

6 abc
= 24
(Q) a b c
Volume

3 a b .

b c

2 c a

6 a b . b c b a c a
= 60
(R) Area of triangle

40

1
a b
2

a b

Required area

1
2a 3b
2

a b

1
2a a 2a b 3b a 3b b
2
= 100
(S) Area of pallelogram a b

30

a b

Required area

a b

a a b a
0 a b
= 30
58

x 1 y z 3
x 4 y 3 z 3
and the planes
, L2 :
2
1
1
1
1
2
P1 : 7 x y 2 z 3, P2 : 3 x 5 y 6 z 4. Let ax by cz d be the equation of the plane passing
through the point of intersection of lines L1 and L2, and perpendicular to planes P1 and P2
Match List-I with List-II and selected the correct answer using the code given below the lists:
List-I
List-II
P
a=
1
13
Q
b=
2
3
R
c=
3
1
S
d=
4
2
Consider the lines L1 :

Codes
35

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

Ans
Sol

59

P
Q
R
S
(A)
3
2
4
1
(B)
1
3
4
2
(C)
3
2
1
4
(D)
2
4
1
3
(A)
Point of intersection of the lines L1 and L2
x 1 y z 3
x 4
r1
2
1
1
1
x = 2r1 + 1
y = - r1
z = r1 3
2r1 + 1 = r2 + 4
2r1 r2 = 3
(i)
- r1 = r2 - 3
(ii)
Solving (i) and (2) r1 = 2, r2 = 1
So point is (5, - 2, -1)
Now the equation of the plane is
a(x 5) + b(y + 2) + c(z + 1) = 0
Also this plane is perpendicular to P1 & P2
So 7a + b + 2c = 0
3a + 5b 6c = 0
a b c
1 3 2
- 1(x 5) + 3(y + 2) + 2(z 1) = 0
- x + 3y + 2z + 13 = 0
x 3y 2z = 13
by comparing
we get, a = 1, b = - 3, c = - 2, d = 13

y 3 z 3
1
2
x = r2 + 4
y = r2 3
z = 2r2 3

r2

Match List I with List II and select the correct answer using the code given below the lists
List-I
List-II
1/2
P
1
2
1 5
1
1
13
1 cos tan y y sin tan y
4
y
2 3
2
1
1
y
cot sin y tan sin y
Q

If cos x cos y cos z 0 sin x sin y sin z then


x y
possible value of cos
is
2
If
cos

x cos 2 x sin x sin 2 xsexx cos x sin 2 x sec x

1
2
36

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
cos

x cos 2 x then possible value of sec x is

If cot sin

1 x2

sin tan

x 6 ,x

0, then

possible value of x is
Codes

Ans

(A)
(B)
(C)
(D)
(B)

P
4
4
3
3

Q
3
3
4
4

R
1
2
2
1

S
2
1
1
2

Sol

(P)

1 cot tan y y sin tan y


y 2 cot sin 1 y tan sin 1 y

1/2

y4

1/2

1
y2

y2

1 y2

1 y2

1 y
y

1 y2

y4

y
1 y2
1/2

1 y2
1
y2 1 y2 y2

y4

=1

y 1 y2
(Q) cos x + cosy = - cos z, sin x + sin y = - sin z
cos 2 x cos 2 y 2 cos x cos y cos 2 z
sin 2 sin 2 y 2sin x sin y sin 2 z
1 1 2cos x y

1
2
x y
2 cos 2
1
2
x y
1
cos 2
2
4
x y
1
cos
2
2

cos x y

1
2

37

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
(R) cos 2 x

cos 2 x

cos x
2

2 sin x

cos x sin x
sec

cot cos

60

sin x cos x
2
2
2sin x cos x
cos x sin x
cos x
2

sin 2 x 1

1 x2

x
1 x

CODE: 0

(S) cot sin

(PAPER II)
sin x
sin 2 x sec x cos x sin x
2

sin tan

sin sin

x 6 .

x 6
6 x2 1

6
2

P
4
3
1
1

Q
1
4
3
3

1 x
6x 1
12x2 = 5
1 5
x
2 3
A line L : y mx 3 meets y-axis at E(0, 2) and the arc of the parabola y2 = 16x, 0 y 6 at the
point F(x0, y0) The tangent to the parabola at F(x0, y0) intersects the y-axis at G(0, y1) The slop m
of the line L is chosen such that the area of the triangle EFG has a local maximum
Match List I with List II and select the correct answer using the code given below the lists:
List-I
List-II
P
m=
1
1
2
Q
2
4
Maximum area of EFG is
R
y0 =
3
2
S
y1 =
4
1

Codes

Ans
Sol

(A)
(B)
(C)
(D)
(A)

R
2
1
2
4

S
3
2
4
2

38

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)
(0, 3)

(0, 3)E

F(x0 , y 0)
G

(0, y 1)
0, 0

y2 =16x

Let Co-ordinate of F= (x0, y0) = (4t2 8t)


Co-ordinate of E = (0, 3) given
Equation of tangent at F ty = x + 4t2
Co-ordinate of G (0, 4t)
0 3 1
1
0 4t 1
Area of EFG
2 2
4t 8t 1

1
12t 2 16t 3
2
Let
1
t
12t 2 16t 3
2
1
' t
24t 48t 2
2
1
' t 0
t
2
1
" t
24 96t
2
1
1
1
"
24 96
12
2
2
2
Since (4t2, 8t) lies on the lie y = mx + 3
8t 3
m
4t 2
1
At t =
2
We get m 1
Maximum area will be at t = 1/2
maximum area of triangle = 1/2
y0 = 8t = 4
y1 = 4t = 2

at t

8t

1
t will be maximum
,
2
4mt 2 3

39

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

NARAYANA IIT/PMT ACADEMY


JEE ADVANCE : 2013
CODE: 0

(PAPER II)

Answers Key
PHYSICS

CHEMISTRY

MATHEMATICS

Q. No.

Answer

Q. No.

Answer

Q. No.

Answer

A, B,C,D

21

C,D

41

B,C,D

A,C

22

A,B,D

42

A,B

23

A,B,C,D

43

C,D

C,D

24

A,B

44

A,B,C

A,C,D

25

45

A,D

A,B

26

46

B,D

BD

27

47

B,D

A,D

28

B,D

48

A,C

29

49

10

30

50

11

31

51

12

32

52

13

33

53

14

C or B

34

54

15

35

55

16

36

56

17

37

57

18

38

58

19

39

59

20

40

60

40

NARAYANA GROUP OF EDUCATIONAL INSTITUTIONS - INDIA

You might also like