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Composites: Part B
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Department of Civil and Environmental Engineering, MIT, 77 Massachusetts Avenue, Room 5-336, Cambridge, MA 02139, USA
Department of Civil and Environmental Engineering, MIT, 77 Massachusetts Avenue, Room 1-280, Cambridge, MA 02139, USA
a r t i c l e
i n f o
a b s t r a c t
Article history:
Received 21 June 2010
Received in revised form 15 September
2010
Accepted 2 November 2010
Available online 11 November 2010
Fiber reinforced polymer (FRP) retrot systems for concrete structures have been widely used, and studies on their short-term debonding behavior have been extensively conducted. Nevertheless, long-term
performance and durability issues regarding debonding behavior in such strengthening systems still
remain largely uncertain and unanswered. Due to its composite nature, the effectiveness of the strengthening system largely depends on the properties of the interface between the three constituent materials,
namely concrete, epoxy, and FRP. Many factors can cause degradation of the interface properties, especially environmental exposure during service life. In this study, effects of moisture on concrete/epoxy/
FRP bond system is characterized by means of the tri-layer fracture toughness, which can be obtained
experimentally from peel and shear fracture tests. An irreversible weakening in bond strength has been
observed in fracture specimens under moisture cyclic condition. Based on the experimental results of
fracture specimens under variable moisture conditions, an empirical model can be developed to predict
service life of FRP-strengthening system.
2010 Elsevier Ltd. All rights reserved.
Keywords:
B. Debonding
B. Environmental degradation
B. Interface/interphase
B. Fracture toughness
1. Introduction
Fiber reinforced polymer (FRP) materials have become materials of choice for strengthening and retrotting of civil infrastructures as a result of design code revision, physical aging,
environmental deterioration, and catastrophic events. Compared
to conventional repair materials, such as steel, FRP has higher
strength-to-weight ratio and provides additional corrosion resistance to the structure. Its ease of application results in little or
no trafc disruption. Several strengthening techniques, including
FRP plate bonding and column wrapping, have been widely applied
in practice as a result of extensive study and ample experimental
results on the mechanical behaviors of the systems [13]. For exural strengthening of reinforced concrete (RC) elements such as
beams and slabs, FRP laminates in the form of rigid plates or exible sheets are externally bonded to the tension faces of the elements using epoxy adhesive as in dry or wet lay-up processes.
The current design guidelines are provided by the ACI Committee
440 [4], which employs design principles similar to that of typical
steel reinforced concrete beams. Nonetheless, premature failure by
debonding of the concrete/epoxy/FRP bond system may occur,
Corresponding author. Tel.: +1 617 715 4204.
E-mail addresses: ctuakta@mit.edu
Bykztrk).
1
Tel.: +1 617 253 7186.
(C.
Tuakta),
obuyuk@mit.edu
1359-8368/$ - see front matter 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.compositesb.2010.11.002
(O.
146
represent real service conditions. These include continuous moisture ingress, moisture reversal, and moisture cyclic condition, from
which a prediction can be made of the life-cycle of FRP-concrete
bonded joint in a FRP-strengthened RC beam. Corresponding material characterization under continuous moisture ingress, moisture
reversal, and moisture cyclic condition was also performed to obtain moisture-affected material properties, which were used in
the calculation of the tri-layer fracture toughness. The paper is organized as follows. First, the tri-layer fracture toughness and the
conguration of the fracture specimens are discussed. The methodology of the three types of test is then explained, followed by the
corresponding experimental results and discussions.
147
Fig. 2. (a) Idealization of loading state in FRP in the vicinity of a crack and (b) peel and shear fracture specimens for opening and shearing mode of loading.
148
Table 1
Diffusion coefcients of concrete, CFRP, and epoxy.
Material
Temperature (C)
Solubility (wt.%)
Concrete
23
50
23
50
23
50
3.24
3.24
0.068
0.081
0.023
0.048
7.71
7.76
0.34
0.9
2.58
5.42
CFRP
Epoxy
Fig. 5. (a) Concrete compressive specimen conguration, (b) epoxy tensile specimen conguration and (c) moisture sorption test specimen for concrete and epoxy.
149
internal pore pressure [20]. It is believed that internal pore pressure is developed on the water molecules in the pores in wet concrete due to external loads. Since the migration of water in a pore is
not free when adjacent pores are also lled with water and, due to
capillary action, the hindered adsorbed water produces a very high
disjoining pressure between the contacting cement gels. The pore
pressure may be responsible to increase the stress intensities of
the micro-crack tips and hence promotes crack propagation under
external loads. Both phenomena may lead to weaker concrete with
the presence of moisture as shown by the experimental results.
F D
@C
@x
where F is the rate of transfer per unit area of section, C the concentration of water, x the spatial coordinate normal to the section, and
D the diffusion coefcient. For one-dimensional diffusion, the rate
of diffusion follows Ficks second law of diffusion:
@C
@
@C
D
@t @x
@x
150
In nite element analysis, moisture diffusion is driven by a concentration gradient with normalized concentration being the nodal
variable of an element. Three-dimensional models of the peel and
shear fracture specimens were created with exactly the same
dimensions for the analysis by a general purpose nite element
program [21]. Eight-node mass diffusion elements were used
throughout the models. The boundary condition was specied as
100% moisture concentration to represent the total submersion
of the specimens under water. Time integration of the transient
diffusion analysis was conducted with backward Euler method because it is unconditionally stable for this type of linear problem.
The average moisture content in terms of weight percentage corresponding to various conditioning durations are shown in Table 2
for the tri-layer fracture specimens. As expected, under higher
temperature moisture diffuses more into the bond line of the
fracture specimens. These values were used to obtain the corresponding mechanical properties of the epoxy and concrete by
curve-tting the results from the tension and compression tests.
It is worth mentioning that the moisture uptake curves for coupon
specimens of epoxy and concrete obtained from the nite element
analysis was in most part comparable to those obtained experimentally by the gravimetric sorption test. Nonetheless, there is a
sudden jump in the initial slope of moisture uptake curve from
the sorption test, which is not captured by the simulation. This
high rate of diffusion in the rst few days may be due to the porosity that may have been produced during mixing of the epoxy and
microcracking that may have resulted from cutting thin specimens
of concrete. The actual moisture content in the bond line of the
peel and shear fracture specimens was believed to be consistent
with the simulation result.
4.2.3. Peel and shear fracture toughness under continuous moisture
ingress
Fig. 10a and b show the effect of moisture on the peel and shear
fracture toughness, respectively. The mechanical properties of the
constituent materials were obtained from the material characterization discussed previously. The values of fracture toughness
shown in the gures are the average values from three specimens
in each condition group. Signicant reduction in facture toughness
after moisture conditioning in both peel and shear fracture specimens indicated that moisture had detrimental effect on the
strength of the bond system. More than 50% of the initial bond
strength is reduced by the exposure to moisture, even after an initial duration of 2 weeks. For both peel and shear fracture specimens, there was a shift in the failure mode from concrete
delamination in dry specimens, to epoxy/concrete interface separation in wet specimens, at both room and high temperatures
(Fig. 11). This indicates the weakening of the interface due to the
presence of moisture. It is observed from Fig. 10 that the fracture
toughness reaches an asymptotic value after 4 weeks for peel fracture specimens and less than 2 weeks for shear fracture specimens.
These bond strength values were used as reference values when
investigating the effect of moisture reversal and moisture cyclic
condition.
Table 2
Moisture content (wt.%) at the interface in peel and shear fracture
specimens from nite element simulation of moisture diffusion.
Duration (weeks)
2
4
6
8
10
50 C
0.41
0.77
1.01
1.29
1.41
0.87
1.63
2.14
2.71
3.26
Fig. 10. Effect of moisture on bond strength of peel (a) and shear (b) fracture
specimens.
151
Fig. 11. Failure mode shift in peel and shear fracture specimens: (a) thin layer of concrete delamination and (b) interface separation.
152
Fig. 14. Comparison between moisture-affected fracture toughness and residual fracture toughness for peel fracture test at room (a) and elevated temperature (b).
Fig. 15. Comparison between moisture-affected fracture toughness and residual fracture toughness for shear fracture test at room (a) and elevated temperature (b).
153
5. Conclusion
The effects of variable moisture conditions on the fracture
toughness of concrete/FRP bonded system are studied by means
of the peel and shear fracture toughness determined from the conditioned test specimens. Moisture conditions can result in degradation as follows:
Prolonged exposure to moisture condition can result in signicant degradation of the CFRP/concrete bond strength. Degradation can be as much as 70% for specimens conditioned for
8 weeks.
After a certain period of time, the bond strength approaches a
certain value. No further signicant degradation may occur
thereafter. This asymptotic fracture toughness is the minimum
bond strength a concrete concrete/FRP bonded system can
retain after a very long moisture exposure.
In addition, moisture reversal and cyclic moisture conditioning
tests showed that the adhesive bond cannot regain its original
bond strength after successive wetdry cycles. The residual
bond strength decreases when the number of wetdry cycles
and the intermediate conditioning duration increases.
Fig. 17. Effect of cyclic moisture condition on Youngs modulus of epoxy at room
temperature (a) and 50 C (b).
In all cases, the failure mode changes were observed in specimens exposed to moisture, linking the degradation of concrete/
FRP bond with the weakening of the interface between concrete
and the epoxy. This behavior can be considered during design process and maintenance planning for an FRP-strengthening system
by developing and incorporating a predictive life-cycle model
based on the experimental results under moisture cyclic condition.
Fig. 18. Effect of number of wetdry cycles on the residual fracture toughness of peel specimens.
Fig. 19. Effect of number of wetdry cycles on the residual fracture toughness of shear specimens.
154
Fig. 20. Varying degrees of residual concrete debris on epoxy surface in fracture specimens under wetdry cycles (peel specimens at room temperature are shown).
Acknowledgements
This research was supported by the National Science Foundation (NSF) CMS Grant No. 0510797. The authors are grateful to
the program manager, Dr. Lawrence C. Bank, for his interest and
support for this work.
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