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INVESTIGATORY
PROJECT
DETECTING METALS PRESENT
IN INDIAN COINS
XII-A
ROLL NO.:-
INDEX
S. NO.
TOPIC
1.
CERTIFICATE
2.
ACKNOWLEDGMENT
3.
4.
THEORY
5.
APPARATUS REQUIRED
6.
CHEMICALS REQUIRED
7.
8.
CONCLUSION
9.
PRECAUTIONS
10.
BIBLIOGRAPHY
CERTIFICATE
THIS IS TO CERTIFY THAT MST. GAURAV
BHADULA OF CLASS XII, SECTION- A HAS
COMPLETED THE CHEMISTRY PROJECT
ENTITLED: DETECTING METALS PRESENT IN INDIAN COINS
UNDER MY GUIDANCE AND TO MY SATISFACTION.
ACKNOWLEDGEMENT
AIM:-
TO DETECT THE
METALS
PRESENT IN
INDIAN COINS.
INTRODUCTION
A
Coin
is
piece
of
hard
metal
that
is
Coins that
For
example,
coin
maybe
in
excellent
corrosive
wear
properties.
resistance
and
anti-
Achieving
this
goal
THEORY
An alloy is a homogenous mixture of two or more
metals and a non-metal. An alloy is a mixture
of metals or
mixture
of
metal
and
elements
or
mixture
of
metallic
to
suit
the
requirements
which
the
APPARATUS REQIRED
1. test tube
2. beaker
3. test tube
4. tripod stand
holder
5. burner
6. sand paper
CHEMICALS
REQUIRED
1.Hydrochloric acid (Hcl)
2.Sodium Hydroxide (NaOH)
3.Hydrogen Sulphide Gas
4.Nitric Acid (HNO3 )
5.Ammonium Acetate
6.Potassium Iodide
7.Potssium Chromate
8.Potassium Ferrocyanide
9.Ammonium Hydroxide
10.Ammonium Chloride
11.Potassium sulphocyanide
12.Potassium Nitrite
13.Nesslers reagent
14.Ammonium Phosphate
PROCEDURE
&
OBSERVATION
1. Preparation of Aqua Regia:
Take a clean beaker and add 3 test tubes
of concentrated HCl to it.
To this add one test tube of concentrated
HNO 3 , and stir.
2. Take five beakers put equal amounts of Aqua
Regia in them.
3. Clean the coins using a sand paper and put
them in the beakers and let them remain
there for three days.
4. After the coins are dissolved, add half beaker
of water in each, and detect the presence of
the basic radicals present in each coin one by
one.
Confirmatory:
2K 2 [Hgl 4 ] + NH
(Nesslers reagent)
OBSERVATION:
COINS
1
2
5
10
NaOH Test
NEGATIVE
NEGATIVE
NEGATIVE
NEGATIVE
INFERENCE:
None of the Coins contain NH 4 + ion.
Nesslers Reagent
NEGATIVE
NEGATIVE
NEGATIVE
NEGATIVE
white ppt.
PbCl 2 (white ppt.) + H+
Confirmatory:
White ppt. + Kl
PbCl 2 + 2Kl
Yellow ppt.
Pbl 2
+ 2KCl
OBSERVATION:
COINS
1
2
5
10
NEGATIVE
NEGATIVE
NEGATIVE
NEGATIVE
INFERENCE:
None of the Coins contain Pb2+.
Potassium Iodide
Test
NEGATIVE
NEGATIVE
NEGATIVE
NEGATIVE
{Cu(NH 3 ) 4 }2+
(Deep Blue solution)
Chocolate
Cu 2 {Fe(CN) 6 }4K+
OBSERVATION:
COINS
1
2
5
10
NH 4 OH Test
Potassium Ferrocyanide
Test
NEGATIVE
NEGATIVE
NEGATIVE
NEGATIVE
BLUE SOLUTION CHOCOLATE BROWN
PPT.
BLUE SOLUTION CHOCOLATE BROWN
PPT.
INFERENCE:
5 Coin contains Cu2+.
10 Coin contains Cu2+.
(Reddish brown
Fe(OH) 3 + 3NH 4 +
Confirmatory:
1. Brown ppt. Is dissolved in HCl (aq.)
Fe(OH) 3 + HCl (aq.)
FeCl 3 + H 2 O
2. To the above solutions add Pot. Ferrocyanide sol.
Prussian blue colouration is obtained.
4FeCl 3 + 3 K 4 [Fe(CN) 6 ]
12KCl + Fe 4 {Fe(CN) 6 } 3
OBSERVATION:
COINS
1
2
5
10
NH 4 OH + NH 4 Cl
Test
Reddish Brown
ppt.
Reddish brown
ppt.
NEGATIVE
NEGATIVE
INFERENCE:
1 Coins contain Fe3+.
2 Coins contain Fe3+
Potassium Ferrocyanide
Test
Prussian Blue colouration
Prussian Blue Colouration
NEGATIVE
NEGATIVE
NiS
Black ppt.
(black ppt.)
CoCl 2 (pink) +
NiCl 2 (greenish)
Confirmatory:
1. For CO 2+ ion:
CO2+ (aq.) + 2KSCN
acetone
OBSERVATION:
COINS
1
2
5
10
Ni
POSITIVE
NEGATIVE
POSITIVE
POSITIVE
INFERENCE:
1 and 5 coins contain Ni2+.
2 coin contains Co2+.
CO
NEGATIVE
POSITIVE
NEGATIVE
NEGATIVE
Ca2+ + CO 3 2-
white
OBSERVATION:
COINS
1
2
5
10
INFERENCE:
None of the coins contain any of the metals of group V.
OBSERVATION:
COINS
1
2
5
10
INFERENCE:
None of the coins contain Mg2+.
CONCLUSION
The metals present in Indian Coins are:
COINS
1
2
5
10
Metal present
NICKEL & IRON
IRON & COBALT
NICKEL & COPPER
PRECAUTIONS
ALWAYS WEAR LAB COAT AND GLOVES.
DO NOT DISTURB THE SOLUTION FOR 3
DAYS.
CLEAN THE COINS BEFORE DOING TEST.
DO NOT SHAKE THE AQUA REGIA
VIGOROUSLY.
THE APPARATUS TO BE USED SHOULD BE
CLAENED THOROUGHLY.
BIBLIOGRAPHY
N.C.E.R.T. Chemistry for Class
XII
Comprehensive Practical
Chemistry for Class XII
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