Professional Documents
Culture Documents
Science
Under Choice Based Credit
System
Chemistry Core Course
(Honours)
2015
Department of Chemistry
College of Basic Science &
Humanities
Bhubaneswar - 751003
Content
Year
First
Core Course - I
Core Course - I Practical
Core Course - II
Core Course - II Practical
II
Secon
d
III
Core Course - IV
Practical
Core Course - V
Core Course - V
Practical
Core Course - VI
Core Course - VI
Practical
Core Course - VII
IV
Third
Core Course - X
Practical
Skill Enhancement
Course II
Core Course - XI
Core Course - XI
Practical
Core Course - XII
Core Course - XII
Course
Code
Course Title
Page
No.
CHC(T)110
1
CHC(P)110
1
CHC(T)110
2
CHC(P)110
2
CHC(T)120
3
CHC(P)120
3
CHC(T)120
4
CHC(P)120
4
CHC(T)230
5
CHC(P)230
5
CHC(T)230
6
CHC(P)230
6
CHC(T)230
7
CHC(P)230
7
CHS2301
Physical Chemistry I
5
6
7
10
11
13
17
21
CHC(T)240
8
CHC(P)240
8
CHC(T)240
9
CHC(P)240
9
CHC(T)241
0
CHC(P)241
0
CHS2402
Physical Chemistry IV
23
24
CHC(T)351
1
CHC(P)351
1
CHC(T)351
2
CHC(P)351
Inorganic Chemistry
IV
Inorganic Chemistry
Lab IV
Organic Chemistry
IV
Organic Chemistry Lab
31
12
16
17
19
19
21
25
26
27
28
29
32
33
35
VI
Practical
Discipline Specific
Elective Course I
Discipline Specific
Elective Course I
Practical
Discipline Specific
Elective Course II
Discipline Specific
Elective Course II
Practical
Core Course - XIII
Core Course - XIII
Practical
Core Course - XV
Core Course - XIV
Practical
Discipline Specific
Elective Course III
Discipline Specific
Elective Course III
Practical
Discipline Specific
Elective Course IV
2
CHD(T)350
1
CHD(P)350
1
IV
Polymer Chemistry
35
37
CHD(T)350
2
CHD(P)350
2
Industrial Chemicals
and Environment
Industrial Chemicals
and Environment Lab
38
CHC(T)361
3
CHC(P)361
3
CHC(T)361
4
CHC(P)361
4
CHD(T)360
3
CHD(P)360
3
Physical Chemistry V
42
43
45
CHD3604
Dissertation
50
39
44
46
48
First Year
Semester I
Course outline and Credit
structure
Course Opted
Core Course - I
Core Course - I
Practical
Core Course - II
Core Course - II
Practical
Total
Course
Code
CHC(T)11
01
CHC(P)11
01
CHC(T)11
02
CHC(P)11
02
Course Title
Physical Chemistry I
Physical Chemistry Lab
I
Inorganic Chemistry
I
Inorganic Chemistry
Lab I
Credit
s
4
Mark
s
75
25
75
25
12
200
UNIT 2
Liquid State (8 Periods)
Structure of liquids ( qualitative description only) Structural difference
between solid, liquid and gas; Vapour Pressure, Surface tension, parachor
and its applications, viscosity; Liquid crystals, difference between liquid
crystal, solid and liquid; classification.
Colligative Properties (8 Periods)
Lowering in vapour pressure, Raoults law, Osmotic pressure and the
laws of osmotic pressure, lowering of freezing point and elevation of
boiling point of solution,thermodynamic derivations of colligative
properties determination of molecular weight by these methods,
anomalous molecular weight of solutes due to dissociation and
association. Isotonic solutions.
UNIT 3
Solid State (10 Periods)
The Study of crystal, types of crystal, space lattice, unit cell, crystal systems;
laws of crystallography, law of constant interfacial angle, law of rational
indices, law of symmetry, symmetry elements in crystal; Lattice planes and
dimension, X-ray diffraction by crystal, Braggs equation; crystal structure
of NaCl, KCl ionic solids ( AB type), lattice energy and its calculation.
Qualitative treatment of Band theory of solids, Point defects in solids
(Frenkel and Schottky defects).
UNIT 4
Chemical Kinetics (14 Periods)
Rate of a reaction, factors affecting rate of a reaction, order and
molecularity, Kinetics of Zero, 1st and 2nd order reaction, radioactive decay
as a 1st order reaction, pseudo first order, half life period, determination of
order of reaction- differential method, method of integration, fractional
6
Books Recommended
1.
2.
3.
4.
5.
6.
7.
5
5
Books Recommended
1.
2.
3.
4.
5.
UNIT 2
Periodicity of Elements (14 Periods)
s , p, d, f block elements, the long form of periodic table. Detailed
discussion of the following properties of the elements, with reference to s
& p-block.
(a) Effective nuclear charge, shielding or screening effect, Slater rules,
variation of effective nuclear charge in periodic table.
(b) Atomic radii (van der Waals)
(c) Ionic and crystal radii.
(d) Covalent radii (octahedral and tetrahedral)
(e) Ionization enthalpy, Successive ionization enthalpies and factors
affecting ionization energy. Applications of ionization enthalpy.
(f) Electron gain enthalpy, trends of electron gain enthalpy.
(g) Electronegativity, Pauling's/ Mulliken's/ Allred Rachow's/ and
Mulliken-Jaff's electronegativity scales. Variation of electronegativity
with bond order / partial charge, hybridization, group electronegativity.
Sanderson's electron density ratio.
UNIT 3
Chemical Bonding (18 Periods)
(i) lonic bond: General characteristics, types of ions, size effects,
radius ratio rule and its limitations. Packing of ions in crystals. BornLand equation with derivation and importance of
Kapustinskii
expression for lattice energy. Madelung constant, Born-Haber cycle
and its application, Solvation energy.
(ii) Covalent bond: Lewis structure, Valence Bond theory (HeitlerLondon approach). Energetics of hybridization, equivalent and nonequivalent hybrid orbitals. Bent's rule, Resonance and resonance
8
UNIT 4
Oxidation Reduction (6 Periods)
Redox equations, Standard Electrode Potential and use of redox potential
data. Its application to inorganic reactions. analysis of redox cycle, redox
stability in water Frost Latimer and Pourbaix diagrams. Principles
involved in the extraction of the metals.
Books Recommended
1.
2.
3.
4.
5.
Viva
Books Recommended
1. Vogels Text Book of Quantitative Inorganic Analysis, A. I. Vogel.
2. Vogels Text Book of Quantitative Organic Analysis, A. I. Vogel.
3. Practical Chemistry, Sharma and Acharya.
10
First Year
Semester II
Course outline and Credit
structure
Course Opted
Core Course - III
Core Course - III
Practical
Core Course - IV
Core Course - IV
Practical
Total
Course
Code
CHC(T)12
03
CHC(P)12
03
CHC(T)12
04
CHC(P)12
04
Course Title
Credit
s
4
Mark
s
75
25
75
25
12
200
Physical Chemistry II
11
UNIT 2
Thermodynamics I (10 Periods)
Definition of thermodynamic terms; System, surrounding, extensive and
intensive properties, state and path functions and their differentials;
Thermodynamic processes, concept of heat, work, zeroth law of
thermodynamics; 1st law of thermodynamics; statement and scope, heat
content, internal energy and heat capacity; Isothermal and adiabatic
changes; Calculation of w, q, dU and dH in the expansion of ideal gas
under isothermal and adiabatic condition; Adiabatic relations; JouleThomson effect, Joule- Thomson coefficient for an ideal and real gas.
Thermochemistry (5 Periods)
Heat changes in chemical reactions, heat of formation, heat of
neutralization, laws of thermochemistry, Hesss law of constant heat
summation, bond energy, Kirchoffs equation.
UNIT 3
Thermodynamics II (12 Periods)
2nd law of thermodynamics; statement, scope, Carnot theorem, Carnot
cycle, efficiency of heat engine, thermodynamic scale of temperature,
concept of entropy, entropy change in reversible and irreversible
processes, entropy change in an ideal gas, variation of entropy with
temperature, pressure and volume, free energy and work function,
conditions of equilibrium, Gibbs- Helmholtz equation, Maxwells
relations, Clapeyron Clausius equation.
12
UNIT 4
Surface Chemistry (6 Periods)
Adsorption and its types, factors affecting adsorption, Freundlichs
adsorption isotherm, Langmuir adsorption isotherm, Gibbs adsorption
isotherm. Introduction to BET theory of multilayer adsorption (derivation
not required).
Colloidal State (5 Periods)
Definition of colloids, classification of colloids, Solids in liquids (sols)properties-kinetic, optical and electrical; stability of colloids, protective
action, Hardy-Schulze rule, gold number and its significance.
Books Recommended
1. Principles of Physical Chemistry, Revised Edition, Puri, Sharma and
Pathania.
2. Modern College Chemistry, Physical ,Achraya and Sharma
3. Thermodynamics by Glasstone.
4. Physical Chemistry, Atkins
Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra, Mishra
and Sharma.
2. An advanced course of Practical Chemistry, Nad, Ghoshal&Mohapatra
13
UNIT 2
Stereochemistry (14 Periods)
Configurational analysis: Fischer Projection, Newmann and Sawhorse
Projection formulae and their interconversions; Geometrical isomerism:
cistrans and, syn-anti isomerism E/Z notations with C.I.P
rules.Geometrical isomerism in Oximes, Alicyclic, Dienes and Conjugated
dienes. Optical Isomerism: Optical Activity, Specific Rotation,
Chirality/Asymmetry, Enantiomers, Molecules with two or more chiralcentres, Distereoisomers,Threo and Erytro compounds meso compounds,
Racemic mixture and resolution. Relative and absolute configuration: D/L
and R/S designations.
Confirmational analysis: Conformation analysis of alkanes: Relative
stability: Energy diagrams of cyclohexane: Chair, Boat and Twist boat
forms; Relative stability with energy diagrams.
UNIT 3
Aliphatic HydrocarbonsI (Carbon-Carbon sigma bonds) (4 Periods)
Chemistry of alkanes: Formation of alkanes, Wurtz Reaction, Wurtz-Fittig
Reactions, Free radical substitutions: Halogenation -relative reactivity and
selectivity.
Chemistry of cycloalkanes: Types of cycloalkanes and their relative stability,
Baeyer strain theory
Aliphatic Hydrocarbons II (Carbon-Carbon pi bonds) (10 Periods)
Formation of alkenes and alkynes by elimination reactions, Mechanism of
E1, E2, E1cb reactions. Saytzeff and Hofmann eliminations. Electrophilic
additions their mechanisms in alkene; Markownikoff and Anti
Markownikoff addition, mechanism of oxymercuration-demercuration,
hydroborationoxidation, ozonolysis, catalytic and chemical reduction, syn
14
UNIT 4
Aromatic Hydrocarbons (9 Periods)
Aromaticity, Hckels rule, aromatic character of arenes, cyclic
carbocations / carbanions and heterocyclic compounds with suitable
examples. Electrophilic aromatic substitution: halogenation, nitration,
sulphonation and Friedel-Crafts alkylation/acylation with their
mechanism. Directing effects of the groups.
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
15
Record
Viva
5
5
Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra,
Mishra and Sharma.
2. A Text Book of Practical Organic Chemistry (Qualitative); I. Vogel.
3. Modern approach to practical chemistry, Y.R.Sharma.
4. Hand book of Organic Analysis-Qualitative & Quantitative; H.
Clarke, Adward Arnold.
16
Second Year
Semester III
Course outline and Credit
structure
Course Opted
Core Course - V
Core Course - V
Practical
Core Course - VI
Core Course - VI
Practical
Core Course - VII
Core Course - VII
Practical
Skill Enhancement
Course
Code
CHC(T)23
05
CHC(P)23
05
CHC(T)23
06
CHC(P)23
06
CHC(T)23
07
CHC(P)23
07
CHS2301
Course Title
Physical Chemistry III
Physical Chemistry Lab
III
Inorganic Chemistry
II
Inorganic Chemistry
Lab II
Organic Chemistry
II
Organic Chemistry Lab
II
Pesticide Chemistry
17
Credit
s
4
Mark
s
75
25
75
25
75
25
50
Course I
Total
20
350
UNIT 2
Electrochemistry II (14 Periods)
Arrhenius theory of electrolytic dissociation; Ostwalds dilution law;
Strong and weak electrolytes; Interionic attraction theory; Onsagers
conductance equation and its validity (derivation not required); DebyeHuckel limiting law (derivation not required); Activity coefficient; Transport
number and its determination by Hittorf and Moving boundary method.
UNIT 3
Electrochemistry III (18 Periods)
Galvanic cell and cell reaction; Types of reversible electrodes and electrode
reaction; emf of reversible cells; Relation between cell emf, H, G, S
and expression for single electrode potential, Polarization and over voltage
(elementary idea); Reference electrodes; Standard oxidation potential,
electrochemical series; Concentration cells with and without transference;
Application of emf measurement- determination of transport number,
valency of ions, activity coefficient, solubility of sparingly soluble salts, heat
of reaction ; pH; Hydrogen, Quinhydrone and glass electrode; Dissociation
constant of weak monobasic acids; Ionic product of water, degree of
hydrolysis.
18
UNIT 4
Ionic equilibrium (10 Periods)
Acid and bases: theory of acids and bases, relative strengths, solvent and
substituent effect on strength; Dissociation constant of acids and bases.
pH.Salt hydrolysis, degree of hydrolysis. Buffer solutions, action, range,
capacity; Hendersons equation; Buffers in the body- buffer of tissue
fluids and carbonate-bicarbonate buffer. Theory of acid and base
indicators, range, choice of indicators; Neutralization curves, elementary
knowledge about other types of indicators.
19
Books Recommended
1. Physical Chemistry, Atkins; Oxford University Press
2. A text book of Electro Chemistry, S. Glassstone.
3. The Elements of Physical Chemistry, P.W. Atkins.
Books Recommended
UNIT 2
Non Aqueous Solvents (8 Periods)
The properties of non- aqueous solvent, classification of solvents; Liquid
NH3; solution of metal in liquid NH 3, Reaction in liquid NH3: metathetical
reaction, ammonation reaction, acid base reactions and ammonolysis.
Advantages and disadvantages of liquid ammonia as solvent. Liquid SO 2:
auto ionisation, solvolytic reaction, precipitation reaction and acid base
reaction.
General Principles of Metallurgy (6 Periods)
Use of redox potential data - analysis of redox cycle, redox stability in
water - Pourbaix diagrams, Principles involved in the extraction of
elements.General principles of metallurgy, occurrence of metals with
special emphasis on mineral wealth of India, calcination, roasting,
smelting, bessemerization, various methods of concentration, purification
and refining (such as parting process, zone refining, oxidation refining,
electrolytic refining and solvent extraction) metallurgy of important metals
like Ag, Au, Zn, Cu, Ni.
UNIT 3
Principles in qualitative analysis (14 Periods)
Theory of precipitation: ionic product, solubility product, co-precipitation,
post-precipitation, purification of precipitates.Chemistry of analysis of
various groups of basic and acidic radicals, chemistry of identification of
acid radicals in typical combinations.Chemistry of interferences of acid
radicals such as fluoride, borate, oxalate and phosphate and their removal
in the analysis of basic radicals.Choice of group reagents for analysis of
cations.
UNIT 4
Nuclear Chemistry (8 Periods)
Nature of radiation from radioactive substances, Composition of Nuclei,
structure of nucleus, forces operative within nucleus, nuclear stability and
mass energy equivalence (binding energy). Radioactive disintegration
series, kinetics of radioactive disintegration. Nuclear reactions: Types of
nuclear reactions, thermonuclear reactions including fusion and fission
reactions, radiation detection and measurement, semi-conductors
detectors. Artificial transmutation of elements, Radio-carbon dating,
synthetic elements. Activation analysis, isotopic dilution and radioactive
titration.
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Books Recommended
1. Vogel, A.I. A text book of quantitative inorganic analysis, ELBS
1978.
UNIT 2
Alcohols, Phenols, Ethers and Epoxides (12 Periods)
Alcohols: preparation, properties and relative reactivity of 1, 2, 3
alcohols, Bouvaelt-Blanc Reduction; Preparation and properties of glycols:
Oxidation by periodic acid and lead tetra acetate, Pinacol-Pinacolone
rearrangement; Phenols: Preparation and properties; Acidity and factors
effecting it, Ring substitution reactions, ReimerTiemann and
KolbesSchmidt Reactions, Fries and Claisen rearrangements with
mechanism; Ethers and Epoxides: Preparation and reactions with acids.
Reactions of epoxides with alcohols, ammonia derivatives, LiAlH4 Grignard
and Organolithium reagents.
UNIT 3
Carbonyl Compounds (14 Periods)
Structure, reactivity and preparation; Nucleophilic additions, Nucleophilic
addition-elimination reactions with ammonia derivatives with mechanism;
Mechanisms of Aldol and Benzoin condensation, Knoevenagel
condensation, Claisen-Schmidt, Perkin, Cannizzaro and Wittig reaction,
Beckmann and Benzil-Benzilic acid rearrangements, haloform reaction and
Baeyer Villiger oxidation, -substitution reactions, oxidations and
reductions: Clemmensen, Wolff-Kishner, LiAlH4, NaBH 4, MPV, PDC and
PGC; Addition reactions of unsaturated carbonyl compounds: Michael
addition. Active methylene compounds: Keto-enol tautomerism.
Preparation and synthetic applications
of diethyl malonate and ethyl acetoacetate
UNIT 4
Carboxylic Acids and their Derivatives (12 Periods)
Preparation, physical properties and reactions of monocarboxylic acids:
Typical reactions of dicarboxylic acids, hydroxy acids and unsaturated acids:
succinic/phthalic, lactic, malic, tartaric, citric, maleic and fumaric acids;
Preparation and reactions of acid chlorides, anhydrides, esters and amides;
Comparative study of nucleophilic sustitution at acyl group -Mechanism of
acidic and alkaline hydrolysis of esters, Claisen condensation, Dieckmann
and Reformatsky reactions, Hofmann bromamide degradation and Curtius
rearrangement.
Sulphur containing compounds (3 Periods)
Preparation and reactions of thiols, thioethers and sulphonic
acids.Mustard gas:Preparation from ethylene,Oxidation and chlorination of
mustard gas.
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
24
15
1.
2.
3.
4.
5.
6.
7.
Picric Acid
Nitrobenzene
Ethyl Benzoate
Aspirin
Methyl orange
Acetylation of one of aniline/ p-toluidine by conventional method
Benzolyation one of aniline/ p- toluidine by Schotten-Baumann
reaction
8. Hydrolysis of amides and esters.
The solid samples must be collected and may be used for recrystallization,
melting point and TLC.
Record
5
Viva
5
Books Recommended
1. Small Scale Organic preparations; P. J. Hill
2. Organic Synthesis, Vol. III; Clarke.
UNIT 2
UNIT 3
Book Recommended
Second Year
Semester IV
Course outline and Credit
structure
Course Opted
Core Course - VIII
Core Course - VIII
Practical
Core Course - IX
Core Course - IX
Practical
Core Course - X
Core Course - X
Practical
Skill Enhancement
Course II
Total
Course
Code
CHC(T)24
08
CHC(P)24
08
CHC(T)24
09
CHC(P)24
09
CHC(T)24
10
CHC(P)24
10
CHS2402
Course Title
Credi
ts
4
Mark
s
75
25
75
25
75
25
50
20
350
Physical Chemistry IV
26
degree
of
UNIT 2
Photochemistry (12 Periods)
Difference between thermal and photochemical reaction; Laws of
photochemistry; Grotthus Draper law; Stark- Einstein law; Beer
Lamberts law; Quantum yield and its determination-actinometry,
mechanism and kinetics of decomposition of HI; Photochemical
combination of hydrogen and bromine & hydrogen and chlorine reactions;
Jablonski diagram; Radiative and non-radiative processes; Fluorescence,
phosphorescence,
resonance
fluorescence,
chemiluminescence,
bioluminescence,
photosensitization and photosynthesis (elementary
idea).
UNIT 3
Elementary Quantum Mechanics (14 Periods)
Black body radiation, Plancks radiation law, photoelectric effect, heat
capacity of solids, Bohrs model of hydrogen atom (derivation not
required) and its limitations, Compton effect , de-Broglie equation,
Heisenbergs uncertainty principle, Hamiltonian operator, Schrodinger
wave equation and its derivation, physical interpretation of the wave
function, Postulates of quantum mechanics (Problems based on algebra of
operators excluded), Schrodinger wave equation for H-atom, separation
into three equations (derivation not required), quantum numbers and their
importance, Hydrogen like wave functions, elementary idea on radial and
angular wave functions (derivation not required).
UNIT 4
Molecular Spectroscopy (10 Periods)
Scope; Molecular spectra; Born- Oppenheimer approximation ; Brief idea
about various types of molecular spectra; Rotational( Micro wave) spectra
of diatomic molecules, energy levels of a rigid rotator, selection rules ,
spectral intensities, vibrational spectra (IR) of diatomic molecules, energy
levels of a simple harmonic oscillator; Anharmonicity; Electronic spectra of
diatomic molecules; FranckCondon principle.
27
Books Recommended
1.
2.
3.
4.
Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra, Mishra
and Sharma.
2. An advanced course of Practical Chemistry, Nad, Ghoshal&Mohapatra
28
UNIT 2
Chemistry of Transition elements (12 Periods)
General group trends with special reference to electronic configuration,
colour, variable valency, magnetic and catalytic properties, and ability to
form complexes. Stability of various oxidation states and e. m. f.
Comparison of properties between first, second and thirdrow transition
series.
Chemistry of Ti, V, Cr, Mn and Co in various oxidation states (excluding
metallurgy).
UNIT 3
Coordination Chemistry (14 Periods)
Werners theory, experimental verification of Werners theory,
coordination number, IUPAC nomenclature, factors influencing the
formation of complexes, valence bond interpretation of common
octahedral, tetrahedral and square planar complexes; electricalneutrality
principle and back bonding. Limitationsof VBT, Crystal field theory,
splitting of d-orbitals in octahedral and tetrahedral fields. CFSE in weak
and strong fields.Ligand field theory.
Isomerism in coordination compounds, stereochemistry of complexes with
4 and 6 coordination umbers, chelate effect, polynuclear complexes.
Elementary idea about labile and inert complexes.
UNIT 4
Chemistry of Inner Transition Elements (10 Periods)
Lanthanides: electronic configuration, oxidation states and ionic radii and
lanthanide contraction, complex formation, occurrence and separation of
lanthanides (ion-exchange method only).
Actinides: electronic configuration and oxidation states, separation of Np,
Pu and Am from U, comparison between properties of actinides and
lanthanides.
Books Recommended
29
1.
2.
3.
4.
5.
6.
7.
8.
9.
Books Recommended
1. Vogel, A.I. A text book of quantitative analysis, ELBS 1986.
30
UNIT 2
Heterocyclic Compounds (14 Periods)
Classification and nomenclature, Structure, aromaticity in 5-numbered and
6-membered rings containing one heteroatom; Synthesis, reactions and
mechanism of substitution reactions of Furan, Pyrrole Paal-Knorr
synthesis, Knorr pyrrole synthesis, Hantzsch synthesis, Thiophene, Pyridine
Hantzsch synthesis), Pyrimidine, Structure elucidation of indole, Fischer
indole synthesis and Madelung synthesis), Structure elucidation of
quinoline and isoquinoline, Skraup synthesis, Friedlanders synthesis,
Knorr quinoline synthesis, DoebnerMiller synthesis, Bischler-Napieralski reaction, Pictet-Spengler reaction,
Pomeranz-Fritsch reaction; Derivatives of furan: Furfural and furoic acid.
UNIT 3
Alkaloids (10 Periods)
Natural occurrence, General structural features, Isolation and their
physiological action, Hoffmanns exhaustive methylation, Emdes
modification, Structure elucidation and synthesis of Hygrine and Nicotine.
Medicinal importance of Nicotine, Hygrine, Quinine, Morphine, Cocaine,
and Reserpine.
Terpenes (3 Periods)
Occurrence, classification, isoprene rule; Elucidation of stucture and
synthesis of Citral, Neral and -terpineol.
UNIT 4
Polynuclear Hydrocarbons (7 Periods)
Reactions of naphthalene phenanthrene and anthracene Structure,
Preparation and structure elucidation and important derivatives of
naphthalene and anthracene; Polynuclear hydrocarbons.
Phase Transfer Catalyst (6 Periods)
31
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
Chromatography
1. Separation of a mixture of two amino acids by ascending and
horizontal paper chromatography
2. Separation of a mixture of two sugars by ascending paper
chromatography
3. Separation of a mixture of o-and p-nitrophenol or o-and paminophenol by thin layer chromatography (TLC)
Isolation of natural products
1. Isolation of caffeine from tea leaves.
2. Isolation of casein from milk.
3. Isolation of lactose from milk.
Record
Viva
5
5
Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra,
Mishra and Sharma.
2. Hand book of Organic Analysis-Qualitative & Quantitative; H.
Clarke, Adward Arnold.
3. Vogels Text Book of Quantitative Chemical Analysis;
J.Mendham, R. C Denney, J. D. Barnes, M. J. K. Thomas; Pearson
Education Publishers, 6th Edition.
4. Vogels Text Book of Quantitative Organic Analysis, A. I. Vogel.
32
UNIT 2
Solid Fuel Coal (6 Periods)
Uses of coal (fuel and nonfuel) in various industries, its composition,
carbonization of coal. Coal gas, producer gas and water gas- composition
and uses. Fractionation of coal tar, uses of coal tar bases chemicals,
requisites of a good metallurgical coke, Coal gasification (Hydro
gasification and Catalytic gasification), Coal liquefaction and Solvent
Refining.
UNIT 3
Liquid Fuel Petroleum (8 Periods)
Composition of crude petroleum, Refining and different types of
petroleum products and their applications. Fractional Distillation
Principle and process, Thermal and catalytic cracking, Reforming
Petroleum and non-petroleum fuels: LPG, CNG, LNG, Bio-gas, fuels
derived from biomass, fuel from waste, synthetic gaseous and liquids fuels,
clean fuels. Petrochemicals: Vinyl acetate, Propylene oxide, Isoprene,
Butadiene, Toluene and its derivatives Xylene.
Books Recommended
1. E. Stocchi: Industrial Chemistry, Vol-I,Ellis Horwood Ltd.UK
2. P.C. Jain, M.Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi.
3. B.K.Sharma: Industrial Chemistry, Goel Publishing House, Meerut.
33
Third Year
Semester V
Course outline and Credit
structure
Course Opted
Core Course - XI
Core Course - XI
Practical
Core Course - XII
Core Course - XII
Practical
Discipline Specific
Elective Course I
Discipline Specific
Elective Course I
Practical
Discipline Specific
Elective Course II
Discipline Specific
Elective Course II
Practical
Total
Course
Code
CHC(T)35
11
CHC(P)35
11
CHC(T)35
12
CHC(P)35
12
CHD(T)35
01
CHD(P)35
01
Course Title
CHD(T)35
02
CHD(P)35
02
Inorganic Chemistry
IV
Inorganic Chemistry
Lab IV
Organic Chemistry IV
Credi Mark
ts
s
4
75
2
25
75
25
75
25
75
25
24
400
34
UNIT 2
Organometallic Chemistry (14 Periods)
Definition and classification of organometallic compounds on the basis of
bond type, concept of hapticity of organic ligands. Metal carbonyls: 18
electron rule, electron count of mononuclear, polynuclear and substituted
metal carbonyls of 3d series. General methods of preparation (direct
combination, reductive carbonylation, thermal and photochemical
decomposition) of mono and dinuclear carbonyls of 3d series. Structures
of mononuclear and binuclear carbonyls of Cr, Mn, Fe, Co and Ni using
VBT.Pi-acceptor behaviour of CO (in light of MO of CO), back bonding of
metal-CO. Elementary idea of metal alkyls and ferrocene.
UNIT 3
Catalysis (4 Periods)
Catalysis
by
organometallic
compounds:
Wilkinsons
hydroformyltion, Wacker process and Fischer Tropsch reaction.
catalyst,
UNIT 4
Group Theory (8 Periods)
Basic idea about group and classes, symmetry elements, symmetry
operations present in a molecule, point groups.
35
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
5
5
Books Recommended
1. Vogel, A.I. A text book of quantitative inorganic analysis, ELBS
1978.
36
UNIT 2
Pericyclic Reactions (10 Periods)
Classification of pericylic reactions, Woodward- Hoffmann correlation
diagram.FMO treatment. Electrocyclic reactions:Conrotatory and
disrotarory reactions. 4n, 4n+2 and allyl system. Cycloadditions
antaraficial and suprafacial addition. 4n, 4n+2 system, 1,3 dipolar
cycloaddition and cheleotropic reactions.
Photochemistry (6 Periods)
Principles of organic photochemistry,Photochemical reactions of carbonyl
compounds (Norrish type-I and II reaction,Paterno-buchi reaction),di methane rearrangement.
UNIT 3
Name Reactions (12 Periods)
Principle, mechanism and applications: Michael condensation,
Reformatsky reaction, Benzidine rearrangement, Wagner-Meerwien
rearrangement. Houben-Hoesch reaction, Vilsmeier-Haack reaction,
Lossen rearrangement, Sharpless epoxidation,Demjanov rearrangement
and Favorskii rearrangement.
Synthetic Reagents (4 Periods)
37
UNIT 4
Protection and deprotection techniques in organic synthesis (4 Periods)
Protection and deprotection of carbonyl groups, Amino groups and
double bonds
Oxidation and Reduction methods (10 Periods)
Oxidations with Chromium(VI),Manganese(VII) ,Peroxides and Peracids,
Ozone , DMSO, NBS and DDQ
Reductions: Catalytic hydrogenation, hydrides transfer reaction, Dissolving
metal reduction.
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
38
15
5
5
Books Recommended
1. Macroscale and Microscale Organic Experiments;
Williamson, D. C. Heath.
2. Small Scale Organic preparations; P. J. Hill
K.
I.
UNIT 2
Kinetics of Polymerization (8 Periods)
Mechanism and kinetics of step growth, radical chain growth, ionic chain
(both cationic and anionic) and coordination polymerizations, Mechanism
and kinetics of copolymerization, polymerization techniques.
39
UNIT 3
Nature and structure of polymers (12 Periods)
Structure Property relationships; Determination of molecular weight of
polymers (Mn, Mm, etc.) by end group analysis viscometry, light scattering
and osmotic pressure methods. Molecular weight distribution and its
significance; Polydispersity index; Glass transition temperature (Tg)and
determination of Tg, Free volume theory, WLF equation, Factors affecting
glass transition temperature(Tg).
UNIT 4
Properties of Polymers (12 Periods)
Brief introduction to preparation, structure, properties and application of
the following polymers: polyolefins, polystyrene and styrene copolymers,
poly vinyl chloride and related polymers, poly vinyl acetate and related
polymers, acrylic polymers, fluoro polymers, polyamides and related
polymers. Phenol formaldehyde resins Bakelite, Novalac, polyurethanes,
silicone polymers, polydienes. Polycarbonates, Conducting Polymers
polyacetylene, polyaniline, poly para phenylene sulphide, polypyrrole,
polythiophene.
Books Recommended
1. Malcohm P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed.
2. Harry R. Allcock, Frederick W. Lampe and James E. Mark,
Contemporary Polymer Chemistry, 3rd ed. Prentice_Hall (2003)
3. Feed W. Billmeyer, Textbook of Polymer Science, 3rd ed. WileyInterscience (1984)
4. Joel R. Fried, Polymer Science and Technology, 2nd ed. Prentice-Hall
(2003)
5. Petr Munk and Tejraj M. Aminabhavi, Introduction to
Macromolecular Science, 2nd ed, ;John Wiley & Sons (2002)
6. L.H. Sperling, Introduction to Physical Polymer Science, 4th ;ed. John
Wiley & Sons (2005)
7. Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed.
Oxford Univesity Press(2005)
8. Seymour/ ;Carrahers Polymer Chemistry, 9th ed. By Charles E.
Carraher, Jr. (2013)
40
Books Recommended
1. Malcohm P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed.
2. Harry R. Allcock, Frederick W. Lampe and James E. Mark,
Contemporary Polymer Chemistry, 3rd ed. Prentice_Hall (2003)
3. Feed W. Billmeyer, Textbook of Polymer Science, 3rd ed. WileyInterscience (1984)
4. Joel R. Fried, Polymer Science and Technology, 2nd ed. PrenticeHall (2003)
5. Petr Munk and Tejraj M. Aminabhavi, Introduction to
Macromolecular Science, 2nd ed, ;John Wiley & Sons (2002)
6. L.H. Sperling, Introduction to Physical Polymer Science, 4th ;ed.
John Wiley & Sons (2005)
7. Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed.
Oxford Univesity Press(2005)
8. Seymour/ ;Carrahers Polymer Chemistry, 9th ed. By Charles E.
Carraher, Jr. (2013)
41
UNIT 2
Industrial Metallurgy (3 Periods)
Preparation of metals (ferrous and nonferrous) and ultrapure metals for
semiconductor technology.
Energy & Environment (6 Periods)
Sources of energy: Coal, petrol and natural gas. Nuclear Fusion / Fission,
Solar energy, Hydrogen, geothermal, Tidal and Hydel, etc. Nuclear
Pollution: Disposal of nuclear waste, nuclear disaster and its management.
Biocatalysis (3 Periods)
Introduction to biocatalysis: Importance in Green Chemistry and
Chemical Industry
UNIT 3
Environment and its segments I Air Pollution (14 Periods)
Ecosystems. Biogeochemical cycles of carbon, nitrogen and sulphur. Major
regions of atmosphere. Chemical and photochemical reactions in
atmosphere. Air pollutants: types, sources, particle size and chemical
nature; Photochemical smog: its constituents and photochemistry.
Environmental effects of ozone, Major sources of air pollution.
Pollution
by SO2, CO2, CO, NOx, H2S and other foul smelling gases. Methods of
estimation of CO, NOx, SOx and control procedures. Effect of air pollution
on living organisms and vegetation. Greenhouse effect and Global
warming, Ozone depletion by oxides of nitrogen, chlorofluorocarbons and
Halogens, removal of sulphur from coal. Control of particulates.
42
UNIT 4
Environment and its segments II Water Pollution (14 Periods)
Hydrological cycle, water resources, aquatic ecosystems, Sources and
nature of water pollutants, Techniques for measuring water pollution,
Impacts of water pollution on hydrological and ecosystems. Water
purification methods. Effluent treatment plants primary, secondary and
tertiary treatment. Industrial effluents from the following industries and
their treatment: electroplating, textile, tannery, dairy, petroleum and
petrochemicals, agro, fertilizer, etc. Sludge disposal. Industrial waste
management, incineration of waste. Water treatment and purification
(reverse osmosis, electro dialysis, ion exchange). Water quality parameters
for wastage water; industrial water and domestic water.
Books Recommended
1. E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd.UK
2. R.M. Felder, R.W. Rousseau: ;Elementary Principles of Chemical
Processes, Wiley Publishers, New Delhi.
3. J.A. Kent: Riuegels Handbook of Industrial Chemistry, CBS
Publishers, New Delhi.
4. S. S. Dara: A Textbook of Engineering Chemistry, S. Chand &
Company Ltd. New Delhi.
5. K. De, Environmental Chemistry: New Age International ;Pvt., Ltd,
New Delhi
6. S. M. Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd.,
New Delhi
7. S.E. Manahan, Environmental Chemistry, CRC Press (2005)
8. G.T. Miller, Environmental Science 11th edition. Brooks/ Cole (2006)
9. A. Mishra, Environmental Studies. Selective and Scientific Books,
New Delhi (2005).
15
1.
2.
3.
4.
5.
8. Preparation of borax.
9. Estimation of SPM in air sample.
10.
Study of some common bio-indicators of pollution.
Record
Viva
5
5
Books Recommended
44
Third Year
Semester VI
Course outline and Credit
structure
Course Opted
Core Course - XIII
Core Course - XIII
Practical
Core Course - XV
Core Course - XIV
Practical
Discipline Specific
Elective Course III
Discipline Specific
Elective Course III
Practical
Discipline Specific
Elective Course IV
Total
Course
Code
CHC(T)36
13
CHC(P)36
13
CHC(T)36
14
CHC(P)36
14
CHD(T)36
03
CHD(P)36
03
Course Title
Credit
s
4
Mark
s
75
25
75
25
75
25
CHD3604
Dissertation
100
24
400
Physical Chemistry V
45
UNIT 2
UNIT 3
Statistical Thermodynamics (14 Periods)
Phase space, unit cells, micro and macro state. Statistical weight factor,
configuration, distribution, distribution number, complexion and
combination. System, assembly and ensemble- Canonical, grand canonical
and micro canonical ensembles. Concept of distribution, thermodynamic
probability and most probable distribution. Most probable distribution and
Maxwell- Boltzmann distribution law of energy.
UNIT 4
Kinetics of Fast Reactions (4 Periods)
General features of fast reactions. Study of fast reactions by flow and
relaxation method.
Macromolecules (4 Periods)
Types of polymers, mechanism of polymerization, kinetics of addition
polymerization.
Micelles (4 Periods)
Surface active agents, classification of surface active agents, micellization,
critical micellar concentration (CMC), factors affecting the CMC of
surfactants.
Books Recommended
1. Modern College Chemistry, Physical by Achraya and Sharma
2. Thermodynamics by Glasstone.
46
Books Recommended
5
5
47
UNIT 2
NMR Spectroscopy (6 Periods)
Basic principles of Proton Magnetic Resonance, chemical shift and factors
influencing it; Spin Spin coupling and coupling constant; Anisotropic
effects in alkene, alkyne, aldehydes and aromatics, Interpetation of NMR
spectra of simple compounds.
Mass Spectroscopy (8 Periods)
The molecular ion and determination of molecular mass. Recognition of
the parent peak. Fragmentation ions. Metastable ions. MacLaffertys
rearrangement. Important features of the mass spectra of the following
organic compounds: n-Dodecane, n-Propyl cyclohexane, Pentene,
cyclohexene, acetylene, Benzene, n- Butanol, sec- Butyl alcohol, Phenol,
Ethyl amine, Ethyl chloride.
UNIT 3
Application of spectroscopy (4 periods)
Combined problems using UV, IR, PMR and mass spectral data, for the
structure elucidation of simple organic compounds
Dyes (8 Periods)
Classification, Colour and constitution; Mordant and Vat Dyes; Chemistry
of dyeing; Synthesis and applications of: Azo dyes Methyl Orange and
Congo Red (mechanism of Diazo Coupling); Triphenyl Methane Dyes
-Malachite Green, Rosaniline and Crystal Violet; Phthalein Dyes
48
UNIT 4
Carbohydrates (14 Periods)
Occurrence,
classification
and
their
biological
importance.
Monosaccharides: Constitution and absolute configuration of glucose and
fructose, epimers and anomers, mutarotation, determination of ring size
of glucose and fructose, Haworth projections and conformational
structures; Interconversions of aldoses and ketoses; Killiani-Fischer
synthesis and Ruff degradation; Disaccharides Structure elucidation of
maltose, lactose and sucrose. Polysaccharides Elementary treatment of
starch, cellulose and glycogen.
Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
Books Recommended
49
UNIT 2
Optical methods of analysis I (12 Periods)
Origin of spectra, interaction of radiation with matter, fundamental laws
of spectroscopy and selection rules, validity of Beer-Lamberts law. UVVisible Spectrometry: Basic principles of instrumentation, choice of source,
monochromator and detector for single and double beam instrument;
Basic principles of quantitative analysis: estimation of metal ions from
aqueous
solution,
geometrical
isomers,
keto-enol
tautomers.
Determination of composition of metal complexes using ;Jobs method
of continuous variation and mole ratio method. Infrared Spectrometry:
Basic principles of instrumentation, choice of source, monochromator &
detector for single and double beam instrument; sampling techniques.
Structural illustration through interpretation of data Effect and importance
of isotope substitution.
UNIT 3
Optical methods of analysis II (10 Periods)
Flame Atomic Absorption and Emission Spectrometry: Basic principles of
instrumentation (choice of source, monochromator, detector, choice of
flame and Burner designs. Techniques of atomization and sample
introduction Method of background correction, sources of chemical
interference and their method of removal. Techniques for the quantitative
estimation of trace level of metal ions from water samples.
Electroanalytical methods (4 Periods)
50
UNIT 4
Separation techniques (14 Periods)
Solvent extraction: Classification, principle and efficiency of the technique.
Mechanism of extraction extraction by salvation and chelation. Technique
of extraction: batch, continuous and counter current extractions.
Qualitative and quantitative aspects of solvent extraction: extraction of
metal ions from aqueous solution, extraction of organic species from the
aqueous and nonaqueous media. Chromatography: Classification,
principle and efficiency of the technique. Mechanism of separation:
adsorption, partition & ion exchange. Development of chromatograms:
frontal, elution and displacement methods. Qualitative and quantitative
aspects of chromatographic methods of analysis: IC, GLC, GPC, TLC and
HPLC. Stereoisometic separation and analysis: Measurement of optical
rotation, calculation of Enantiomeric Excess (ee)/diastereometic excess
(de) ratios and determination of enantiomeric composition using NMR,
Chiral solvents and chiral shift reagents. Chiral chromatographic
techniques using chiral columns in GC and HPLC
Books Recommended
1. Vogel, Arthur I: A Test book of quantitative Inorganic Analysis (Rev.
by G.H. Jeffery and others) 5th Ed. The English Language Book
Society of Longman.
2. Willard, ;Hobert H.et.al.: Instrumental Methods of Analysis, 7 th Ed.
Wardsworth Publishing Company, Belmont, California, USA, 1988
3. Christ ian, Gary D; Analytical Chemistry, 6 th Ed. John Wiley & Sons,
New York, 2004.
4. Harris, Daniel C: Exploring Chemical Analysis, Ed. New Yord,
W.H.Freeman,2001.
5. Khopkar, S.M. Basic Concepts of Analytical Chemistry. New Age,
International Publisher, 2009.
6. Skoog, D.A., Holler F.J. and Nieman, T.A. Principles of Instrumental
Analysis, ;Thojmson Asian Pvt. Ltd. Singapure.
7. Mikes, O. & Chalmes, R.A. Laboratory Hand Book of
Chromatographic & Allied Methods, Elles Harwood Ltd. London.
8. Ditts, R.V. Analytical Chemistry - ;Methods of separation.
51
Books Recommended
1. Vogel, Arthur I: A Test book of Quantitative Inorganic Analysis (Rev.
by G.H. Jeffery and others)5th ;Ed. The English Language Book
Society of Longman.
2. Willard, Hobert H.et.al: Instrumental Methods of Analysis, 7th Ed.
Wardsworth Publishing Company, Belmont, California, USA,1988.
3. Christan, Gary D; Analytical Chemistry, 6th Ed. John Wiley & Sons,
New ;York, 2004.
4. Harris, Daniel C: Exp[loring Chemical Analysis, Ed. News York, W.H.
Freeman, 2001.
5. Khopkar, S.M. Basic Concepts ;of Analytical Chemistry. News Age,
International Publisher, 2009.
6. Skoog, D.A. ;Holler F.J. and Nieman, T.A. P:rinciples of Instrumental
Analysis, Thomson Asia Pvt. Ltd. Singapore.
7. Mikes, O.& Chalmes, R.A. Laboratory ;Hand Book of
Chromatographic & Allid ;Methods, Elles Harwood Ltd. London.
52
53