Thermodynamic Properties of Nitrogen From The Freezing Line To 2000K at Pressures 1000MPa

Thermodynamic Properties of Nitrogen from the Freezing Line to 2000 K at Pressures to 1000 MPa Richard T Jacobsen, Richard B, Stewart, and Malid Jahangiti Contr for dppod Thersodyans Statin, Coleg of Baghnnts Unies of he enn Ras 02049 ‘A new fundamental equation explicit in Helmholtz energy for thermodynamic properties of nitrogen from the fecring line to 2000 Kt preanarce to 1000 MPa is yreouates "New independent equations forthe vapor pressure and forthe saturated liquid and vapor {densities as functions of temperature ar also included. The fundamental equation was selected from a comprehensive function of 100 terms on the basis ofa statistical analysis of the quality of the it. The coefficients of the fundamental equation were determined by a ‘weighted least-squares ft to selected Pp-T" data, saturated liguid, and saturated vapor density data to define the phase equilfbrium criteria for coexistence, and veleity of sound ‘ata, The fundamental equation ond the derivative function for calculating internal ener 43, enthalpy, entropy, isochoric heat capacity (C,), isobaric heat capacity (C, ), and velocity of sound are included, Tables of thermodynamic properties of nitrogen ate given {for liquid and vapor states within the range of validity ofthe fundamental equation, The fundamental equation reported here may generally be used to ealeulate pressures and densities with an uncertainty of + 0.1%, heat capacities within + 3%, and velocity of sound values within -: 1%. Comparisons of calculated properties (o experimental data dod to verify the acouraey ofthe formulation ‘Key words: density; enthalpy and entropy, equation of state nitrogen; hes capacity; property table thermodynamic properties; velocity of sound. ‘The Determination of the Fundamental Equa- eter 1 eater 12._TiefisdisinalqatintrNtgen 73 Sara besnid 2. Experimental Data for the Single-Phase Region 739 a\ Preparation of Experimental Property rear pans ts Danner EE atari Cac. BB ieee a 2 Wiper bee 7 33, TheRindannal aon is Be VisuGetcens 19 Sk Del homedics 25 Ena Dea 2 & Sonim ote Fl ete Fae cers me * a 6 at Gatcinehe 1 6” Empat sic nana Bk Tpcon 1" fon hr Da 1 2. Eve iL Cae oe eae keto m Pee a 12. Vopr Reon reaper 3.1. ‘The Vapor Pressure Equation west TAT Below the Critical Temperature. 756 32. Reem or te Sil Vapor 13, Fa agen eters Diais 1 Avec Gul Teapene 76 sa, BEB rie dl 614. Rots Net Ce Deny 1s Tompri 1 aa, memati Spice TS aa enc i 4. litsciea Cyc 3 a1 Eecicla Gacy hs 2 tere pcg TS 63, Seog Soa m Vial ai gyre ean cnmmsnnetttrititan Ten il Cc a Tecra ee Aone niente eS by ms een eee Oh, SIRI! Vigra 7 (047-2690/06/020735-175/815.00 4 Phys. Chem. Ret. Date, VoL. 15, No.2, 1906736 68, 69. ‘The Critical Region Estimated Accuracy of Calculated Prop- 7. Acknowledgments 8. References Appendix. List of Tables 1. Summary ofexperimental Pp-T' data for nitro- BEM srs 2 Soma fesperienal ochre apc: ity data for nitrogen ees 3. Summary of experimental isberie heat capac ity data for nitrogen 4. Sommary of experimental eat capacity data oF saturated iguid for nitrogen vor 5. Summary of experimental velocity of sound ata for niteogen.. 6 Summary of virial couiticats for ultsgun 7. Summary of enthalpy data for nitrogen 8. Summary of heat of vaporization data for nito- gen 9. Crtical-point parameters for nitrogen 10. Measurements ofthe triple point pressure for nitrogen 11, Summary of vapor pressure data for nitrogen = 12. Coefficients for liquid-vapor coexistence prop erty equations for nitrogen. 13. Summary of saturated liquid density data for nitrogen. 14. Coeficients of the melting pressure equation for nitrogen 15. Coociene for the ideal gas heat capacity Eq (4.1 forniteogen {from Angus etal. (Ref. 2)] 16, Parameters considered in the determination of the equation of state for nitrogen 17. Functions for fitting the fundamental equations of state to various data Form on 18. Coefcients for the fundamental equation [Eq, (5.9) for nitrogen (cooficients not listed are 2r0) 19. Summary comparisons to Pip-T data not included in graphical comparisons. 20. Second virial coefcients for nitrogen 21, Thermodynamic properties of saturated nitro- 22M : a 22. Thermodynamic propertica of nite Liet of Figures 1. Nitrogen Pip-T' data (part 1, selected data) .... 2. Nitrogen Pip-T data (part 2, data not selected from same soweees a8 Fig, 1) Nitrogen Pyp-T data (part 3, data not selected) Nitrogen Pp-T data (part, datanot selected) . Nirogen Pp-T date (art the real ron. Nitrogen heat capacity a8 nnn 4. Phys. Chom. Ret. Data, Vo. 15, No.2, 1986, ns 786 13 793 704 40 ma m8 oy ur “7 148 751 153 753 154 755 755 756 73 798 ey mL ma 72 a2 43 Ms 1 2 13. 2s, 6, n 28, JACOBSEN, STEWART, AND JAHANGIRI Nitrogen velocity of sound data ‘Comparisons of vapor pressure values calculated from Eq, (3.1) toda ‘Comparisons of vapor pressure values calculated from Eq, (3.1) to data near the critical point. Comparicone af saturation temperature ealow lated from Eq. (3.1) to data ‘Comparisons of saturation temperature calcu lated from Eq. (3.1) to data near the critical point ‘Comparisons of saturated vapor density values, calculated from Eq. (3.2) to data Comparisons of saturated vapor density values calculated from Eq. (3.2) to data near the ert cal point ‘Comparisons of saturated liguid density values calculated from Eq, (3:3) to data 5. Comparisons of saturated liguid density values calculated from Eq. (3.3) to data near the ert {el points ‘Comparisons of calculated values of density to data for theliquid below the critical temperature . Comparisons of calculated values of density to data for the vapor below the erica temperate ‘Comparisons of calculated values of density to data for Nuid states above the critical tempera- ‘Comparisons of calculated values of density to data near the critical temperature (1, = 126.193 K, p_ = 11.177 mol/ém*) >. Coimparisons of calculated values of isochoric heat capacity, C0 data oor ‘Comparisons of calculated value of heat capac ity, Cy, to data ‘Comparisons of calculated values of isobaric heat capacity, C,, to data (isobaric data) ‘Comparisons of calculated values of isobaric heat capacity, C,, to data (isothermal data) ‘Comparisons of calculated values of velocity of sound to data... Comparisons of calculated valuas ofthe valocity of sound at saturation to data ‘Comparisons of calculated second virial coe ints with values fom Levelt Senge e (Ref $2) Comparisons of selected coexistence property data and values calculated from Eq, (5.7) using the Macoal esiterion (equal area prinsiple) with calculated values from Eqs. (3.1), (32), and (3.3) Comparisons of ealculated vas of enthalpy to data of Dawe and Snowdon (Ref. 63) Comparisons of calculated values of heat of va- pporization from Eq. (5.7) 10 data ne Comparisons of Pp-T" dats for nitrogen in the critical region .. ‘Comparisons of calculated values of pressure (0 ‘the experimental data in the critical region 145 748 749 149 150 150 781 152 181 761 762 m 16 76 ™ 1 7 182 mm 784 786 786 180 788‘THERMODYNAMIC PROPERTIES OF NITROGEN. 737 32, Pressure deviations of equation of state and Pp tion in the critical region. (The zero deviation 1 data from the revised and extended scaling lines the formulation of Jahangir and Jacobsen equation in the eiical region. (The zero dev (Ref.7).) wo ation line isthe formulation of Jahangir and Ja- 34, Comparisons of ealulated derived properties cabsen (Ref.7)-] 790 om this work (isothermal lines) to values from 33, Density deviation ofequation ofstateand Pp-T the sealed formulation (Ref. 7) (baseline of data from the revieed and extnded ealing equa plot) ame es 72 Nomenclature Symbol Physical quantity Unit T ‘Temperature K P Pressure MPa 2 Density mol/dm* ° Molar volume dan'/a0} z CCompressibinty actor, = /pk1 v Internal energy Yoo, 4 Helmholtz energy Sasol @ Gite enorey Vaso H Enthalpy Yast s Entropy I/(om01 K) G Tsobaric het capacity I (anol K) C ssoenone neat expacty Srcmo1) c Two-phase heat capacity I/(ao} K) r Heat capacity ratio W Velocity of sound m/s B Second viral coficient émn'/mo! c Third vil coefficient (ém/mel)? D Fourth virial coeficient (am'/mol)* (Pip) Isotherm derivative ay Payot (arian), Tsochore derivative MPo/K R Gas constant (8.314 34) Imo K) ” Moe 1 weight of nitrogen (28.0134) @ Reduced Helboltz energy, t= A /RT 70 Reduced temperature, r= 7./T 6 Rediuced densiy, = p/p, Superscript 5 Ideal gas property Subscripts ° Reference state property : CCitical-pont property ° Property at saturation ® Triple point property i Calesnted wring an equation data Experimental vlue hp ‘Norma boiling point sv Saturated vapor SL Saturated liguid wv Triple pont (vapor) ol Triple pont (liquid) Additional abbreviations exp Exponential fanction ° Diterence “4. Phys. Chem. Rt. Data, Vol. 16, No.2, 1086738 JACOBSEN, STEWART, AND JAHANGIRI Fixed Points for Nitrogen Quantity 1. Introduction Nitrogen is produced commercially in large-scale plan au is widely usea for selentine and maustnal pur poses. Accurate tables of thermodynamic and transport properties of nitrogen are essential for industrial equipment design, safe cryogenic storage, and equitable enstdy trans fer. ‘Throughout this manuscript the word “data” is used to refer to experimental measurements, The term “formula: ‘on’ refers to the equation or equations necessary to caleu- late fuid properties from a correlation. The term “funda- ‘mental equation” is used to describe the equation of state used inthis work. The eal gue heat capacity epresentation is an integral part of the fundamental equation, A separate equation for ideal gas heat capacity is also given. Ancillary equations for the vapor pressure, saturated liquid density, and saturated vapor density are used to calculate values to Aefine lquid-vapor coexistence states in the development of the fundamental equation. These ancillary equations are also ‘cet ag setimating functions for defining eaturatod stator using the Maxwell criterion for phase equilibrium. 1.1. Prior Correlations of Nitrogen Properties ‘A comprehensive correlation and evaluation of nitro- agen data was reported by Jacobsen and Stewart’ in 1973. ‘This work was th basis for an international table of proper- les ormtrogen pupiisnea oy Angus erai"in 19/¥, his Work thas been the accepted standard for thermodynamic properties of nitrogen since its publication Jacobsen and Stewart! and Angus of al disewssed sew- eral correlations published prior to 1973. Although these correlations are of historical interest, they are not discussed in detail here. These earlier correlations, especially that of ‘strobridge,” provided interim properties of nitrogen for use in commerce, and perhaps more significantly, created an awareness of the need for more accurate experimental property measurements and more accurate correlation methods, |. Phys. Chem. Ret Data, Vol. 15, No.2, 1986, Critical pressure Critical density “Triple point temperature ‘Triple point pressure Triple point density (vapor) ‘Triple point density (liquid) Normal boiling point emperature Normal boiling density (vapor) ‘Normal boiling density (liquid) Keterence temperature Reference enthalpy at 7, Reference entropy at Ty, Value 126.193 K 3.3978 MPa HAT? moV/ém? 648K 0.012 52 MPa 0.024 10 mol/dm* 31.016 mol/da? T1M8K 0.1650 mol/ém? 28.794 mol/dm* 298.15 K £8669 J/mol 191.502 J/mol K Jacobsen and Stewart! extended the ranges of validity of the prior correlations for nitrogen in temperature and pressure sand introduced a 32tarm pressure anplict equation of otate {or nitrogen. This pressure-expicit equation form has been Widely used for correlating properties of other fluids. This equation of state was also used in the National Bureau of Standards (NBS) Technical Note No. 648," which was published for engineering use in customary engineering (Brit- ish) units. Based upon comparisons of calculated properties ‘of nitrogen from those prior correlations to experimental ‘data, it was recognized that improvements in theaccuracy of the equation of state were needed forthe critical region and ‘the low-temperature liquid and vapor regions. This work ‘represents an improvement over prior correlations in these repions. An additional reason for this new formulation is the availablity of new data for various thermodynamic properties, and the development of new techniques of correlation. 1.2. The Fundamental Equation for Nitrogen ‘The fundamental equation used in this work is explicit in reduced Helmholtz energy. Other thermodynamic properties are derived from the fundamental equation by dffer- ‘citation The eveiclens of de fundamental equation were ‘determined using a least-squares regression procedure™ for selection of an optimum group of terms from an initial bank ‘of 100 proposed terms. The rance of validity of the funda- ‘mental equation for nitrogen i fom the freezing line to 2000 K at pressures to 1000 MPa. With a few exceptions, the ‘equation presented here represents the selected experimental Pop-T data wo within the estimated accuracies of these data. ‘Throughout this paper, comparisons of calculated properties to experimental data are used as the basis for validity and estimated accuracy ofthe correlation. In all comparisons given, percentage deviations are defined as [an — Kage )/ Mane) 100, ‘whore Xie the property compared. Det aay led comparisons of,‘THERMODYNAMIC PROPERTIES OF NITROGEN 739 caleulated thermodynamic properties to experimental data are given in See 6 Tn addition to the fundamental equation, ancillary functions including a vapor pressure equation, equations for the density ofthe saturated liquid and saturated vapor, and ‘an equation forthe ideal gas heat capacity are given. Sum- mates of the wvallable data for coexistence propertics of ni trogen are given, and the ranges ofthese data are tabulated. ‘The fundamental equation may be used for the calculation of accurate tables of thermodynamic properties of nitro- {gen within its range of applicability. This equation may also be readily used for systems analysis where iterative solutions are required to solve the equation for variable pairs other ‘than density and temperature. The fundamental eyustio ‘was developed to conform to the Maxwell criterion for lig- tid-vapor phase equilibrium. The fundamental equation given here is acentatein the critical region to within 0.1% in pressure, However, for accurate property determination in the critical region, the revised and extended scaling formulation of Tahangiri and Jacobsen” should be used. ‘ihe thermoaynamic property correlation for nitrogen reported here includes specific improvements over that of Jacobsen and Stewart! Saturated liquid and vapor densities ‘consicent with the best single-phase data in adjacent regions Ihave been used in the development of the formulation. The ‘techniques first applied in the correlation of thermodynamic properties of ethylene by Jahangiti er a.* to improve the accuracy of calculated properties inthe critical region were used in the development ofthis formulation for nitrogen, ‘The accuracy of derived properties including heat capacities and velocity of sound has been improved from that of Jacob sen and Stewart." 2. Experimental Data for the Single-Phase Region ‘The available experimental data for nitrogen are summarized in the flowing sections. These data were the basis for the development of the new thermodynamic property formulation reported here. Some of the data in the selected datasets were not usd in determining the coefficients forthe fundamental equation. However, all avaiable data. were ‘compared to values calculated with the formulation. Sources for experimental property data with temperature, pressure tnd dencity ranges, uncerteintice, end eermple uring ane tabulated. The data forthe coexistence states (liquid-vapor and solid-liguid) are discussed and summarized in Sec. 3 and 4 24. Prp-T Data ‘Theexperimental P.p-T data for nitrogen are summar- {ed in Table 1. The distribution of these data is shuwa i Figs. 1-5. Five separate graphs were used to illustrate these data because of the large numberof available Pp-T data for nitrogen. The data selected forthe determination ofthe coefficients of the fundamental equation are illustrated in Fig. 1 ‘Data from the same sources as those in Fig. | that were not used inthe ft are illustrated in Fig. 2. The data illustrated in Figs. 3 and 4 were not used in the tt. Further discussion of the data selections given in Sec. . Forclariy of llustration, Pp-T data or nitrogen in the critical region are shown sep rately in Fig. 5. 2.2. Isochoric and Isobaric Heat Capacity “The reported measurements of the isochoric heat capacity, isobaric heat capacity, and heat capacity ofthe satu rated liqui for nitrogen are summarized in Tables 2, 3, and 4, Figure 6 shows most of the recent experimental heat capacity data for nitrogen on P-T coordinates, including the values ofsaturated liquid heat capacity from several authors. 2.8. Velocity of Sound Data Extensive measurements of the velocity of sound for nitrogen have been reported, especially in the vapor region. ‘The sources of these data are summarized in Table 5, and ‘Fig. / shows the aistripuuon oF inese aata on P= coordl- 2.4 Virial Cantisiante ‘There are many published values for the second virial ‘couflicients of nitrogen for temperatures from 70 to 1000 K.. {Ie the opinion of the authors. the most reliable second virial coefficients available are those of Levelt Sengers et al” Dis- crepancies ofthe values from other sources with the selected data may be attributed to the associated experimental and correlating procedures and to cousiderations of impusiies ‘and adsorption. Table 6 summarizes the sources for the vi- il cocficients for nitrogen. Only the values of Levelt Sengers et al compiled and recorrelated from other sources were used for comparisons in this work. 28. Enthalpy Data ‘The sources of enthalpy data considered in this work are summarized in Table 7. These values have been used only {or comparison to calculated values. 2.6. Heat of Vaporization Data ‘There are few reported experimental values ofthe heat OF vaprization (latent Veal) for nitvygens These data are summarized in Table 8. 2.7.Critieal Point ‘The difficulties of experimental determination of the critical parameters are the cause of considerable differences. among the results obtained by the various investigators. The critical density cannot be defined accurately by experiment ‘because ofthe infinite compressibility at the critical point and the associated dificulty of reaching thermodynamic ‘equilibria, Therefore, reported values forthe eitcal den- sily are generally calculated either by extrapolation of recti- linear diameters utilizing measured saturation densities, ot by correlating single-phase data close to the critical point. Recent reported temperature, pressure, and density measurements forthe critical point of nitrogen are isted in Table 9. “The ertical parameters given by Zovulys wud Blagoi™ 4. Phys. Chem. ef. Data, Vol 18, No.2, 1986,740 JACOBSEN, STEWART, AND JAHANGIRI Tnearaingyucercavtycetaay he TTR RT ete sty mpeg age we 38 amare foivors sco eee uaa (UD fetter 4 otto isk wet ECO) fonom bore aetna f@) as) Ninaliegimes § sit naka ass (0) oa) ay fee boo ahkwaetas 0 0 (om) rer walt agin 2seo aah 02 a mat eo ea eso artes (0s) (H) Memes eat ese em (aaa) oa morse Tey ae (02) 0.01 tee tame a. foros f Turban mde Fete eS ee er) oo rant wt Soom aaa ee os} Tomer we eae Lom sure” ss iota (oat) 0.) (01) vay eerie 60 tea(02) a) (o.can) ee (0.20) whe ae nas (ao (0.8) 198.385 Srett &staele? 36) a os) on a aa tor ayaa tutte t tatoe Lash am (0.1 oss Gemertion Euan? 3969 17D eth (o.ta $85 enon wD (os as 9839 ratarast §wine"™ ass osama) 0.3) (o.00) ratoroe ean wim tae 008) (ocean Bu pontine wos (02) am eng 2 a) ca (o.00 eet ws 8 mean (ose) toss} (eso) testye 8 ws 570 wma reat we 08 ons 99.90 igor, tam ‘eo. be pote ot 1,4 ” Howe ot (oat (o.con) 9.98 Serty tones lem a Got aS oa fo.0h) 98.09 ferris bite! ise taes6D aso cos 96 4 Phys. Chom, Ret Data, Vol 18, No.2, 1985‘THERMODYNAMIC PROPERTIES OF NITROGEN 744 1000. 2 3R 5 8 A 8 5 8 8 8 8 8 aor PRESSURE (MPa) acted 33) ° OP ay Fe Salon? TEMPERATURE (K) 1g. Narogen ip at (part 1 sleet) 1000. 3 Ea haste PRESSURE (MPa) oo. "800, ° 800. “1000. 2000. TEMPERATURE (K) 10.2 Nhs Py dae (pt 2; aa nacht fa ae oe Fig 1) “4 Phys. Chem. Ret. Data, Vol. 1, No.2, 1868JACOBSEN, STEWART, AND JAHANGIRI 742 | —- ¢ if ie w w 4 sf 85 8s Ee - < <= ga sac a5 8g 2 a i ai se eB i i 3 gi i i é ‘ : é ‘ : 4 de se : i a = = - z ¢ (ed) aYNSS3ud (dW) SYNSSAed 4 Phys, Chem. Ret Dats, Vl. 16, No.2, 1886‘THERMODYNAMIC PROPERTIES OF NITROGEN © Seen a gites* PRESSURE (MPa) 7 3 @ 10 i 1 3 Ww 143 15 DENSITY (mol/dm) 5. Ntrogen Mp dt (pr 5, te elo), TWhte 2, Samiry of speriantl fschoric Mat captcty dite for attrogen Dncreatety Weersiny eeretnty Pry source ear ante ptnte "rangey | acge temperature denity sa oti) TTS pelenty SR werity area ma cr se) a ein ata 8, hata ». Vorou ee ale? Is nan gs come ate ae mtb ata maaso 0.000.085, 9.99 ineusing 45 potas on saturation Tine between 78 ard 125 te Phys. Chem. Ret. Data, Vol. 15, No.2, 1966,744 JACOBSEN, STEWART, AND JAHANGIRI Tle 4. Summary of experiaental heat capacity ote of saturated Tiguta for nitrogen owes ree pete Pramas Meera at ‘No. of data Tenperature (e)_{rercant) ‘Source Year ‘points: range erase meckey®® 1820 cs 3823 ol este? 1983, wt Ode 98.98 Peeioeeae Pr Drive comntcatin w Wake & Brean, i rE odd Slee DEG aS A WartPerreryy bof a ne 8 Leste. Pod = een : 3 ec poo 6 SN tio ia TEMPERATURE (K) ic. 6, Nitrogen bat capacty dat 4: Phys. Chem. Ret Data, Vol. 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN 745: 1000. 3 Sone © TOS etre ae ; w tj 3 i 5 Bo. Qn a c = out: ot 0.04 ‘so 180 20 30 so TEMPERATURE (K) ac. 7. Nitrogen veloc of und data woe 5, Sumary of experinantal velocity of sound dita for nitrogen ‘reeriainey ncervetnty Parity of tuber of Pressure Tengertre “tn ‘fn source ear deta points "Tange "Fange WP cempetacure _sangte (vrs) os tn percent) Teeson & Wa OTe oe on Lameren!®* Ven Teverbeek et 21.195 19098 a8 ae a Verhaegen et a1! 19522 GOL-O.T TT 0S Von Ieeerbesk et a1e39% 1957 122 O25 227-258 ep, Iekerbggh & 158 2k. 77-90 an it SS : 7 Ven teerbpgh & isi kez a3-80 1 on ares van eerbegt & 19626 kT 7 ! ‘en beet seen a Yan Oael et ai 1966 97 Os01B-3.3 eS os 8.85 Pine? 16500077 ou ot Younglove & vecarty®? 1980 255 O.02-1.6 DIE «0.03 0.008-0.05 _59,99988 4: Phys. Chem. Ref. Dat, Vol 15, No.2, 1886748, atborn & oto! see JACOBSEN, STEWART, AND JAHANGIRI Table 6. Sumary of virial coefficients for nitrogen fetborn & otto! see atborn & otto"? 128 Kanertingh Ones ven Urk!*3926 verschayle!? 1s Wicnele et a1. 134 Wichels a a 28 1936 Fetednan?® 1980 Sind et al 2 1960 Wichels et ah 7 1951 Van Ttterbeck ot a 1987 sauret®® 1988 Pook et at. 162 Canfield et at. 1962 iuonshy & mittee? 3909 Yoower et a1.22 1964 crate & Soneagl2? 1966 toe? ws Levelt Sengers et aT. 1972 Ter of Temperature a * ie man wee avon wan meas mon 209 m mm ro-1s0 eestor ase ima mez 156-251 100-1400 Be Bc ‘a1 0 8, a Be 8c Be Be a 0 T= fourth virial coef sare var a ate saree et 8 as? me alt Sabet anatsnat shah ea ee ee ee mo seus 4 Phys. Chem. Ref, Dat, Vol 16, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN m7 — wr ete Facet Regweial WIE To pollo wnt 6 BEE Ko areconsstent with the single-phase Pip-T datain the critical region. These values were used in the development of the fundamental equation in this work and forthe revised and extended scaling equation of Jahangiri and Jacobsen.” 2.8. Triple Point ‘The tiple point temperature fornitrogenisa secondary reference point uf the Inletuatiousl Practical Temperatuse ‘Scale of 1968 (IPTS-68) with a value of 63.148 K.*© Sources of triple point pressure for nitrogen are listed in Table 10. ‘The selected temperature and pressure forthe triple point this work are 63.148 K and 0.012 53 + 0.00001 MPa, respectively. le te Smary of vapor prea 3, Liquid-Vapor and Solid-Liquid Coexistence Properties ‘A new vapor pressure equation and equations for the density of the saturated liquid and the saturated vapor as functions of temperature have been developed to include the critical-region data. The functional forms forthe ancillary equations reported here are similar to those reported by ‘Wagucr and Ewers"™ and by Pentermann and Wagner." 3.1. The Vapor Pressure Equation ‘The Functional form for the vapor pressure equation is Pine crita( tase te ie 4 sree Suto), an ata for attrogen Unceratnty Uncertainty rests . tener of Tengeature hn ‘empersture (oy cy romeriel= ws wi cae? 8 ous oat forte fern 15052 sorizt edge boavis®? agar 30 wei os Glaugue § clayton’? 190318 sere 0.001 65.66 4 10-5 Yo Friednn & vital? 1850 20 108 3.6 Michels et 210195510 vrse Arastrong!?? ws 2x08 me 539 99.575 nous et 2122 196532 001 2.67 x 10- Hea 5.88 ener? an 9 o.oo 2.8 10" Wee TSAH8 gna wa 68 00 bt? TSAe8 4. Phys. Chem. Ref. Data, Vol. 16, No.2, 1986748 JACOBSEN, STEWART, AND JAHANGIRI Table 12, Gaettictente for igutceepor cgeststance Drapery wsuattans for aitrogent apr Pressure equation (3.1 ete Saturates auld Density Equation (3.2) hy = outta «ue WS cizooeeas «1 TS 2 tee ie So acieseenes RS intone oe WSS Sc toeenoe ee i ‘trated vapor Destty Equation (3.3) Me > ocereisaedst x 102 2 Gcoseezer 102 Nf ogi 8 SSIORALE Ee Ia > “otaecste x tt ‘TeaeiViciots aoe Tetad ave teres where += [(7./T) ~ 1). P, and 7, ate the eiical pres: sure and eriical temperature, respectively. The values of P, and T, for nitrogen used for this equation are 3.3978 MPs and 136.193 K, respectively, from Zozulya and Bagi" Ta- ‘le 11 is a summary of available vapor pressure data for nitrogen. Coefcients for Eq. (3.1) are given in Table 12. The data selected for the development ofthis equation were the ata of Wagner fom 63 to 118 K and those of Zozulya'™ ‘rom 121 te 126.14 Ke, Comparisons of this equation 4 the ‘vapor pressure data for nitrogen are given in Figs. 8-11 3.2. The Equation for the Saturated Vapor Density ‘The functional form of the equation for the saturated ‘vapor density is mie Fr engine ss, 8.2) me where r= [1 ~ (T/T,)], = T./T, and p" isthe density ofthe saturated vapor. The data used inthe determination of the coeficients for Eq, (3.2) for temperatures between 103, and 120 K were obtained by the intersection of the vapor preceure Bq. (3-1) anda fundamental equation repeetenting selected vapor phase data. Tisequation ofstatefor nitrogen vapor is discussed in Jacobsen eral." Also, saturated vapor density values calculated from the virial surface of Young love and McCarty” were used for states at temperatures 0.20 z m EE ae es ast * Od ete 6 0.10 4 Be ot cost Had Speed EF oo otteett (SF porte oye 0.004 > Ro ating PERCENT DEVIATION IN VAPOR PRESSURE 0.10 xx ° ° o ene 7 cost THRU on Se 8 1.2 _ TEMPERATURE (K) ie. 8, Comparisons of vapor presure values caleultd fom Eg, (3.1) to dt 4 Phys. hem. Ret. Data, Vol 15, No.2, 198‘THERMODYNAMIC PROPERTIES OF NITROGEN 749 4 teen eg 6 ea ms 3 se 3 Baile ee totes Ss ht Oa — leee fms tenes PERCENT DEVIATION IN VAPOR PRESSURE -0.204 i a gga aig ce) utc ee) gies cic TEMPERATURE (X) 9. Couprions fpr pes ins cbt om (1) at ete ie pot. 0.10 m if a a A an 0.05 ao e Ss a 'g 3 8. 7 8 Qe 8.057 eesti? geay oo) Ge on BP ice 8 Hiya © ee 8 Ulam stores Sittin to nvisat 8 pears 2 Stes te dr Sheen te. catatne ite aah Pitre & here faye eee oa = te? Sada att te aa TEMPERATURE (kK) 1 Comperion of ation epee om (21) oa. 4.Phye Chem. Ota, Vl 1, No.2, 1888750 Taata Teale () Fro, PERGENT DEVIATION IN €ATURATED VAPOR DENSITY JACOBSEN, STEWART, AND JAHANGIRI 0.08 0.00, 0.104 120 tat 122. Frtednan & ange) ches et a1! forterss perry!) reser sere Tonya? Galeutates fron Revises & Extended Seating” Guat fon” cattuiaues fan tape aestune Feuation oF ageer™™ aie of Toorature in Tre Temeratre or oy tt Geren) Thetis Boones aoe 78 Yan eerpeer ts aes cocker tal? 9680 93.998 ‘rlenn & Sersel™® 8330 a ots sna, Beaune >® we ot 93.98 Reaoserich 8 mies? gna 4 oe ks s8.097 Ely Seraty)* we Toaulge Hstager” ss 6 0.0005 0.08 SAB a8.T ayees a1? st a8 00s ots TS 58.99 rt bLaoretre™? sr 19 0.01 0,09 o/s? strate 8onier!® ara pr eo) nibeguergie ee ale! 1999 6 ows 1 Phys. Chem, Ret Data, Vol. 15, No.2, 1986,752 JACOBSEN, STEWART, AND JAHANGIRI ee a ° i 8 1 4.8 Ft . ° g . 7 ° 3.8 Y a =e Ppa ge ae +e as ° oon eT bo og = a gab 7 ty 5 Carano 7! ° a z . rou 8 " = 8 Ey Tstraey j ae, S fner eee yw & 2 Seeker CR Eth fers < & Straty & ontvert™ 5 Yon Heerbeee& ygrbeke™> & B lorutga b Bagot?® B -0.2 : Galestane trae Revises & . santeny, Tete SFT iSlebow! z . 8 pestan Bohan & -.sL.98 & a 7 ee wes se TEMPERATURE (K) ie Coc of etre nna rm g (22) tte See 2 8 y 5 as ee 2 olka : gE acety : s ’ $ ° i ee pe eee @ “vy z 5 E 6 ye stetgt = 2 fajnes et 8 5 © Straty Bott ier®® a 8 deaulya Bagot 2 4S ieufbees tram Revises & 5 ‘Stenaea Sealing euntion? 8 § ne s 120 121 12 123 184 185 126 127 TEMPERATURE (K) ‘io. 15.Compaiton of arte gd dems vats calculate rom Eg (3.3) wo ds near thecal point. ‘J.Phys. Chem. Ret. Data, Vol. 15, No. 2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN 753 from 63 to 103 K, and the data of Zozulya and Blagoi*® were used from 121 to 126.13 K, ‘The coeficents for Ea. (3.2) are given in Table 12. The deviations of this equation from data are illustrated in Figs. Mand 13. 3.3. The Equation for the Saturated Liquid Density ‘Thefimetional form of the equation for satented Hii density for nitrogen is SNP Nac? + Ns IN(O), G3) where r= [1 — (T/T,)],0=T./T,p' isthe density ofthe satenteHqhid, and n. = 11 177 mal/Am. the critical dene sity from Zozulya and Blagoi* Table 13 is a summary of saturated liquid density data for nitrogen. The data used in the determination ofthe coefcients for Eq. (3.3) are one ‘pomt trom bly ana Straty"" near the tnpte point, tne data ot Straty and Diller from 85 to 115K, and the data of Zozulya and Blagoi® from 120 to 126.14 K. The coeficents for G1 ae given in Table 12. Deviations of sanneated Fiquid density values calculated using this equation from data va ‘ues are given in Figs. 14 and 15. 3.4. The Melting Pressure Equation Presures on the melting curve in this work are deter- ‘mined from the melting curve equation given by Watson at the National Engineering Laboratory in Scotland in a pri- vvate communication as reported by Angus et a? ENG) ‘The coefficients N, are listed in Table 14. N,, P,, and T, are the triple point temperature given by Watson as 0.012 53 MPa and 63.148 K, respectively. ‘Measurements of the liquid density on the melting save ete pulls ir septs Uy Orly aud Mills” i 1957, whose measurements cover the range 65 K (7.78 MPa) to 120K (348.3 MPa), andby Cheng” over the range 837 K (124 MPa) to 193 K (1020 MP2). Where these two ‘sets of data overlap, they differ by about + 0.2% in density. on Re snes Bes ate 4, Ideal Gas Heat Capacity In the calculation of thermodynamic properties of nitrogen. an equation forthe ideal cas heat capacity. C2. is ‘sod in the ealelation of real fuid enthalpy, entropy, heat capacities, and velocity of sound. The equation previously reported by Angus al” hasbeen incorporated nthe funde- ‘ema! equa reported itp works Te eyuaion font suggested by Bureau! was ited tothe data from Barieau ‘and Tully up to 500K and from NBS Circular No. S68! from 50 to 2500 K. The data of Barieau and Tully" were ven greater weight than those from NBS Circular No. 564" at temperatures below 500 K. The equation is a where C; isthe ideal gus heat capacity, Tis the temperature smkelving, and U = N9/T. The coeticients for Eq. (4.1) are given in Table 15. As indicated in Angus eral from $0 to 1100 K, the maximum diference between values of C5/R given in sither of the two data cources from thors calculated using Eq. (4.1) isless than 0.000 15, At higher temperatures the diference increases to a maximum of + 0.000 26 at 2500 K. 5. The Determination of the Fundamental Equation for Nitrogen ‘This workisa more accurate representation ofthe ther- mod ynamic property data for nitrogen than the prior formu- Jaton by Jacobsen and Stewart! for state inthe eiical re gion. In the development of the new formulation, a new Fenctional foem forthe fundamental equation and new tech sigue for correlation have been used which resulted in improvements in the representation of the thermodynamic surface. The new form ofthe equation of state includes terms suggested by Schmidt and Wagner."*’ 4 Phys. Chem. Ret. Data, VoL. 15, No.2, 18756 JACOBSEN, STEWART, AND JAHANGIRI 5.1. Stepwise Least-Squares Technique with Search Procedure ‘The eorication presented in this work was developed using a stepwise least-squares technique with a search and. selection procedure that was introduced by Wagner® and ‘modified for use on equations of state by de Reuck and Arm- strong.* The selection procedure selects an optimum group of terms from a proposed bank of terms based on statistical evaluation of the significance of individual terms. 5.2, Preparation of Experimental Property Data for Nitrogen for Use inthe Correlation ‘The units adopted for this work were (MPs) for pres sure, (mol/dm’) for density, (K, IPTS-68) for temperature, fiat) fin eueigy. Unio uf te cayenne date wore on ‘verted as necessary fom those of the orignal publications to these units. All temperatures were converted tothe Interna tional Practical Temperature Scale of 1968 (IPTS-68), as suggested by Douglas" ach data point used in the least-squares determination ofthe coefficients of the equation of state was assigned reg cin Unsed pear eatin ues of de ‘atiables reported bythe experimenter. In most cases these estimated uncertainties were taken from assessments ofthe overall accuracy ofthe datasets, Where reliable estimates of ‘uncertainties were not available, estimated accuracies were ‘determined by comparison to a preliminary least-squares representation ofthe surface. The weights used in the iting process were calculated using the ez propagation formula (Sometimes called the theorem of propagation of variance). “The function for weighting were calculated by making use ofa preliminary formolation fr the partial derivative functions required for estimating variances by the error propags- tion formula. The determination of estimated variances uses the standard approximations for simple functions given by ‘Ku. Further details ofthe methoa used for weighting data are piven by Jacobsen" and Jahangir" In several in- stances the error propagation Weights were modified by the Scignmont af ahitrary mntinlietive factors t inereate oF lesten the effect ofa particular dataset onthe overall epresentation ofthe surface. 5.3. The Fundamental Equation ‘The Helmholtz energy is given by the fundamental equation A pT) =A" (pT) +AC pT, (ey ‘where A” (7) isthe ideal gas contribution to the Helm- hholtz energy of any state. The term 4( p,7) isthe contribution represented by the compressibility ofthe rel gas. ‘The pressure derived from this expression is 2(d4 pap (# 52 oe (52) ‘The Heol energy forthe ideal esis given by AH RT TS" (33) 4. Phys. Chem. Ret Data, Vol. 15, No.2, 1886, ‘The ideal gas enthalpy is given by ra ot T, 4) where #75 = 8669 J/mol isthe datum value at Ty = 298.15 K, based upon a zero reference point forthe ideal crystal at abpulute evo temperature, The ideal gas entropy i given by TC} 7 casg+[ Sar—rm(£Z), 55 sass Sa (& 65) ‘where $5 = 191.502 J/(mol K) isthe datum value for entropy at Ty = 298.15 K and P,=0.101 225 MPa, based ‘upon a zero reference point of the ideal crystal at absolute ‘zero (emperatuse, The Helusblz encsgy forthe ideal gas is sven by ‘The equation for the ideal gas heat capacity used with Eq. (5.6) to develop the complete expression for "is given in Sec. 4. The functional form used for the tunaamental equation for nitrogen is a nondimensional potential function, (5.7) =A p.D/(RT) = a (6,r) + B57), (5.7) Hir_ Si br or S94 in Se RT, ar (gest eale (ea Lf Sarst [Sa 58) E[Fe+i [FS (3.8) T./Tsto=Te/Tw8 = piper 80 Polpesthe tie tome $‘THERMODYNAMIC PROPERTIES OF NITROGEN 755 ene a gu dys Top thar se ie isepritte Perce ee Sa eerie eapcasas aeasa canta ane men teh Fe $b deren Soy and P,, and R is the gas constant 0.008 314 34 (MPa dm*)/_ and grt rng 3 eS cumwrest here tht te ect oft enamel en Sain curaneroer are eeetaeeen eee eee oe aieater scarten iarscainraied aes es ciency dares daa siyamurbaget ia taantmecar ete Terie Siar creea gra Toe Se ic ted ae ddr trance ere nal na friaaind Serpe snchenans ayn ageless om Ta lin ning he nda onto er cecparereiees onesies ae termes & at) criterion = WpelA My) = 01511 = Mallet) By =F Spore aah, ah] issue sea «fag sere ee) = ale ah tnt or te tesa eon (68) Tet Cat ne te Se hE i i Siew ee omer regions ofthe surface. The experimental PT data selected for this work are illustrated in Fig. 1. Also. smoothed values, cof the two-phase equilibrium properties calculated from Eqs. (3.1), (3.2), and (3.3) wereincluded in the Pp-T data set. The experimental values for velocity of sound data are ‘those of Younglove and Mecary,”” Van Iterbeek and Vs Deel," and the saturated liquid values of Van Dal era."? ‘The Coefficients of Eq. (5.9) given in Table 18 were determined by a least-squares fit to 2112 selected data points. 5.4, Derived Thermodynamic Properties ‘The functions used for calculating pressure, compress- ‘bility factor, internal energy, enthalpy, entropy, isochoric heat capacity, isobaric heat capacity, Gibbs energy, and the velocity of sound from Eq, (5.7) are given as Eqs. (5.10)- (5.18). These functions were used in calculating the tables of thermodynamic properties of nitrogen given in the Ap- pendix ‘The compressibility factor Z = P /pRT is given by the (10) «ay le expressions fo rived properticn Ege (5.10)-(5.) he sep fre ropereselt oss reg feretton oma 4: Pye. Chem. Ret. Data, Vol 15, No.2, 1908756 JACOBSEN, STEWART, AND JAHANGIRI simula, rey S_ (00° 27) a $a1(E + B)-0-@, (513) H _ (at, 82) , 430 Fea) 02a, sy a rane ( 5.18 ote s(%), (58) & dat oe = #2) qe -7 (SE +33), (516) az 5, 227 1452257 abot) esa) 18) Saturation entries in the isobar tables were calculated using temperatures determined from the vapor pressure equation, ‘The densities for the saturated liquid and saturated vapor were calculated iteratively from the fundamental equation. ‘The derived properties for saturation states were calculated > functions uf temperature aia Ueusiy ung suaadat ‘modynamic relations. Table entries for the iquid-vapor saturation table were calculated usin the vapor pressure equa tion to determine P, at the table value of 7. Densities and Gerived properties Were calculated using the methods de- scribed above for saturation entries in th isobar tables. 3. Comparisons of the Fundamental Equation to Data ‘This section mcludes comparisons of properties caleu- Jated using the fundamental equation for nitrogen with experimental data including P-p-T" data, C,, Cyy C,, heat of vaporization, velocity of sound, second virial cotficients, ‘coexistence property data, and enthalpy. Separate comparisons to Prp-T, C,, and velocity of sound data in the critical region are given. 6.1. Comparisons of the Fundamental Equation to Pep-T Data ‘Comparisons of values of density calculated using the fundamental equation with selected experimental densities (including some values not used i the determination ofthe coef of te Fa equation) ate iuuluded it this section. The coordinates ofthe graphs were selected to illustrate the quality of the ft in four regions: (1) liquid and (2) vapor states at temperatures below the critical tempera ture, (3) states atthe temperatures above the critical region «1. Phys. Chem. Ref, Dat, Vol 18, No.2, 1986 ‘boundary (140 K), and (4) states near the critical tempera- ‘ure, Dats reported by experimenters on isotherms ae illus trated on those isotherms. Other data including those reported on pseudovisochores are grouped for arbitrary ranges of temperature. Deviations of data not included in eraphical ‘comparisons are summarized in Table 19. 6.1.4. Liquid Region ‘igure 16 ustrates comparisons of density values calculated with the fundamental Eq. (5.7) with liquid P-p-T ‘data of nitrogen. Data points below 124 K with deviations ‘exconding 4-0 80% im density arn nated an the grape 6:12. Vapor Region for Temperatures Below the Crtcal ‘Temperature Figure 17 illustrates comparisons of density values from the fundamental Eq (5:7) with vapor data for nitrogen ‘below 124 K. Calculated values agree wit these data generally wt 0.37% ln density. 16.1.3, Fuld Region for Temperatures Above the Criteal Temperature Figure 18 illustrated comparisons of the data above the critical temperature with values from Eq. (5.7). These values generally agree within 0.59 in density. (6.1.4. teotherms Near the Crea! Temperature Figure 19 illustrates comparisons ofthe calculated and somanusea density values in the temperature ange of 124.6 140 K at densities between 0 and 40 mol/ém?, These comparisons indicate agreement of calculated and experimental values generally within 2% in density. As shown in Fig. 19, there is good agreement of values calculated using Eq. (5.7) withthe available data except in the range of &-14 mol/dm”, ‘The predicted values at densities from 8 to 14 mol/dm ex- bic deviatis a0 lenge ao 276 in deity fron Un data vol> ‘ues, This behavior is expected for classical analytic equations of state in the critical region. A more detailed discussion of the behavior of Ea. (5.7) in the critical region is included in See. 68.08 0.8 ° ° -0.8 Latent ernest -068 Ftd si ti esti 65.05 K Bn 77.9 K z-° “oa 0 et GB 0:8 Less retires —esi ——=0.8 Prva ereif ssid = oe 67-70.5 K “ 7e.1¥_K 0 re ° om E -e cet tstih—estid——-008 Laveen iessnnd est a na. 14-84.58 1 a8 ve Bai © we tay — ° Te etree -828 Frere rere rer evi kb Gees eu Kk Gio oo 0 = = 2 | ii ow Tr.34_K 24.99 K ° Stag ° — 30.8 Leet esi teni titi 0.8 Lesh een eset ti fs 77.35 ie 25K ° ° . 0.8 2 2 0 Oye = ee ‘THERMODYNAMIC PROPERTIES OF NITROGEN 757 eu.ou K PRESSURF (MPa) © Van Itterbeck & Verbeke®Ss37 @ Street, & Staveley? & Gibbons*® AN Grilly & mi11s32 ode ilo Sot te th ito. Tob. PRFSSURF (MPa) © Golubey & Dobrovol 'skii*? G Weber 8? X Cockett et al? © Straty & Ditler®? ie Compare af notte nn fay ater the gd en the ia pete 4 Phys. Chem. Ref. Data, Vol 16, No.2, 1086,758 JACOBSEN, STEWART, AND JAHANGIRI oe 98-87 k oe est 0 ne 0 Boras 0.8 ot essd—ivid—essid 068 fread teste ts oe 29-09.5 oe 95.2 K ° oe z doy * : oe ime G 2.8 Lei resindrcindei —-0.8 essere —essind 2 cs 90.~90.1K oe 96-97. K <0 Sms o |e eg_® Frills lsetenmmeten neste -ataliecsd macmeene termes 99,25-90.5 k 98-29 K 0.8 wags: 0.8 a 9 [Zoints off © 7 > sale? 8 8 oa Fe -0.8 L aint si rit tei =008 Lassi tne Si std oe 90.58 1 aan inn x Zz Ww 7 0 Zo &e QO oo 060 ot ro 5 os 08 4o0.01 2 Ww o a OD -o.8 -0.8 7 i Wi 0.8 0.8 a oO o -0.8 “0.8 0.8 0.8 101-108 snssuee | U Fe to o " 30.8 besarte -0.8 tt ite. Bo. ot bite iB. PRESSURE (MPa) PRESSURE (MPa) @ Benedict?? © Van Itterbeek & Verbeke?5>37 MS. Grilly & Mil1s32 B fodosevich & Miller’? @ Strestt & staveleye® & colubey & Dobroyol 's B tenors M Corbett at ates & Sraty inti iars Cheng®? ic, 16. Comparisons of cleulted values of density to dat for thei below the critical temperatre—contined ‘4. Phys. Chem. Ret. Data, Vol. 15,No. 2, 1886,‘THERMODYNAMIC PROPERTIES OF NITROGEN 759 0.8 103.18 K co 119.14 K ° ° ° 1% 0.8 Lessing ot =0.8 Lesnnd—essnnt—evinh—essne oe _ 113.7 « z? 0 XW Ste © -08 vd 0.8 |-sssnnh—tesinl—tstinh std = a 114.09 <70 ° = Toy Zo soil -0.8 Lessn-esn esis O oe oe 11.99 > 0 ° 5 FE oe Lense eid “008 tid Bus 108-108 oo 115.68 a ° a 0 ft eet oe tals seem esa 020 Lees essa asim + aso b 109.99 K 116 K 5 oe 0.8 io 0 omhee | y wah 8 eter] ~0.8 Leet tt ttt Woe 110.09 « 116.3 K a int yy ¥ 3 ¥y wring [LPO Nae off scate®® -0.8 Leth etn idtttid 0.8 2 118-119.98 0.8 0.8 Tie ° ° ° — 0.0, rome ceeii| =.) nen irc Ot Tb to, Oa itt, PRESSURE (MPa) PRESSURE (MPa) Rodoseyich & MiTlers? & Gritty & Minls®? Y 0a Poste et al. 5? © Weber?” Golubev & Dobroyal 'skii*? # Cheng®! & Serecte a storghey? © Surety & Dinter toeulye @ otayoi Cockett et al, Fic 16, Comparisons of celts ale of density data forthe ged below the cre! empereare—sontinued Phys. Chem. ef. Data, Vol. 16, No.2, 1986760 JACOBSEN, STEWART, AND JAHANGIRI 120K -0.8 0.8 -0.8 og ——____# eee -0.8 PERCENT DENSITY DEVIATION PRESSURE (MPa) ™ Benedict?” \ Grilly & Mills?? 1D Weber®? : © Golubev & Dobrovol 'skii*? @ Streett & Staveley"? © Straty & Diller®° + Tozulya & Blagor*” T Da Ponte et al.%° ic. 16, Comparisons of clued vale of ent o data othe iui below the real tenperature—continoed, 4. Phys. Chem. Ret. Dat, Vol 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN 761 eok os 110,025 k 2 points off scale?°| ° [ ° tc = -0.8 -0.8 me 20K ae 113.145 K . oF _— 6 a8 0.6 = 90 K 118.99 K 0.6 0.8 E T point off scate®® Zio a - > -0.8 a ae 90.046 120.018 > 0 »———_ ° bo & sel 0.8 LQ oe 100 a 120.99 K WO te — : “ a O68 “0.0 5 os 100.027 An 122K ty oo je o }— +H Q v0 0.6 109.157 K 122.98 Be apoio scare] o o * -0.8 -0.6 oe 110 K 129.98 K 0 moors o +4 +380 -0.8 -0.8 Ope tae ena eaves mony DENSITY (mol/dms) X Younglove & MecartyS? IS Friedman’? ot? eu s 67 DENSITY (mol/dm3) D fall & Canfield’? + Tozulya & Blagot > "ic 17. Comparisons of calealate vals fens to data for he vapor bw the etic temperstare. 41 Phys. Chom. Re. Data, Vol. 15, No.2, 1966762 JACOBSEN, STEWART, AND JAHANGIRI at tuo K 0.5 | 150 k co | afi, o * -0.5 -0.5 ous we K os ts0.na_K ory o [wee Oo eé Sy aa W3I-NWGIIK og g 150.99 K + fae wo 0 ge} potme ort scate 3 points off scale2® “0.5 -0.5 oe 143.14 K aa 158 K 0 geese Po gy 0 foeeeng afiommmemes -0.5 -0.8 oe WWS.1UIULOK gg 158.2 K 1 point off scale! PERCENT DENSITY DEVIATION Holborn & otto! KanerTingh Ones. & van urkes Younglove & MeCarty5? 0 2 0.5 0.5 14s K a gg -0.5 on 148-148.15 K ms _? off scale? OU -0.5 co 19.99 K 0 er BO eeert een ey eee et bireenterenpenteteeeed oto" 20) "'30'* uo" 'so 102030 WD 0 DENSITY (mol/dm?) DENSITY (mol/dm?) Ol Benedict??»28 a Straty, & Ditters? X Canfield et al.3¢ & Weber? © Cantield et al.?? + cozulya & Blagots® Y Cheng?! &S Friedman’? @ Crain*? * oes? 3 x 8 Fic 18 Comparisons of clued values af dest to data fo aid stats above the erica temperature. 4 Phys. Chem. Ret. Data, Vol 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN 763 os 170 K os 183.2 K oO | Sa oO | -0.5} -0.5 0.5 im k 0.5 188 K 1 point off scale!® o ee g -0.5 -0.5 z 172 K 190 K So as 0.5 ——____#0 K__ Eo oo 0 *¥— sem — Sc 0.5 a 7 D3 points off 2 points off scale’ > 8 pe ea vie & -os -0.5 a O.5 175K os 192.7 K a 5 oe = 0 freee B05 -0.5 Z os 175.8 K ae eiteok Oo ‘na ° Ne c © points off scaie®! WwW -0.5 0.5 oe 180 K as 198, 18-200. K . . 1 point off, scale?® 0 Tice oO sem 5 oot 0.5 -0.5 ee 181.9 K a) 200.1 K Owe ° -0.5 0.5 oto 2030 Wo" 50 0100 30° Wo S0 DENSITY (mol/dm3) DENSITY (mol/dms) Gl Benedict?7.28 RoeS® Y thong?! B Straty £ or11or60 \ Friedman3? X Younglove & McCarty®? © Holborn & Otto!* © Canfield et al.*? © Kamer! fnghonmes& Fic. 18 Comparisons of ulculated values deny to dat for Bid tates ove th cre tempersture—conined 4 Phys. Chem. Ret. Data, Vol. 15, No.2, 1986764 JACOBSEN, STEWART, AND JAHANGIAL a 208.2 ae (228.1-208.9 0 tebe ee 0 att a : "1 point off scale™ -0.5 “0.5 an 200.7 K ae 223.18 K 0 0 by, 0.5 0.5 S 0s 205.5 K ns 228.18 K = o - 0 0 A ei ar = 705 -0.5 imarete 210 kK a 230 K Oo — ‘ * 0 > oe & -os “0.5 Q os —_@is k a6 234 K Ww 0 pee a 0.5 5 ait “s wi 2 pointe Q 9 | —$$$— 0 off scales? "Pg WwW -0.5 “0.5 a os 221.9 K 0.5 240 x 2 points “7 0 0 eae or scate® “0.5 -0.5 ae 222.9 K ae HSS ° if 0 30 points off scales 0.5 0.8 oto 20 S050 oto 2030 uo S0 DENSITY (mol/dm3) DENSITY (mol/dm3) A Bartlett et al?! © straty & pitlerst Y chengS! X Younglove_& eCarty®? ® Crain’? Benedict?” »2° © Holborn & otto! X Canfield et ai.2° © KanerVingh omnes & © Canfield et,at.?? van Ure! B Liebenderg®® + Roe? Fic 18. Comparisons ofcleultd valu des to data for Bid sate above the crcl emperture— 34 points off scales® - -05 0.5 aes pua.aa 272.15 K Zz 7 e We 0 tise o So 0.5 0. ane -0. -0.5 b Zz os 2s0_K os 273.15 K ia on) fT 0 ¥ 0-5 -0.5 a 0.5 co 252.6-253.15 K os 273.15 K point o 0 off scale>! B 0.5 0.5} a5 ee K 0.5 273.15 K_ - a 3 points Q & oka et 2 “os “os off scale’ 002030" wo 50 0 wo so DENSITY (mol/dm3) DENSITY vas 4 Bartlett et al. 2) x Youngiove, & Mecarty®? Y Cheng! DB Amagat? 1° BS Friedman3® Z Canfield et at .38 eB i mi . Canfield et al? ris: ie’ Crain®) © Kamerlingh Onnes & © Holborn & Ottg!? 131s wae & tevse @ outee® 02! © Straty & Diller®? Fic. 1. Comparnons of cleitedvalas odes to data for ld stats sve the etal tmperature—cotinned 4. Phys, Chem, Ret ta, Vol. 15, No.2, 1066766 JACOBSEN, STEWART, AND JAHANGIRI at 273.15 K os 263.15 K 0 ean 0 Pe -0.5 -0.5 AG 273.15 K ae 0 teeny ts “at a -0.5 -0.5 zo. tisk a Eo eee Sr — S -05 “0.5 Ww 0.5 273.19 K 0.5 291.4 K a 2 points off scale! > o(é a FE -os oc 273.3 K ae 292.7 K 8 os o Q a 43 points off scale%® E -05 Zz 277K 293.14 K wi O.s 0 pee iv WwW -o.5 - os 280 K 293. 14-293.18 K o er -0.5 0.5 281 K 293.6 K 0.5 -———rvg os 6K 2 points . =e 0 ff = ints of 56 cuss [oa 2tt seal = 10 points off scale’ o 10 20 30 4O so o 10 20 30 uo 50 DENSITY (mol/dm?) DENSITY (mol/dm?) & Bartlett!® otto et al.2? Bartlett et al.}9.21 D Rivkin®* © Benedict??.28 # Rae? Y Cheng>! @ Straty & djqters? @ Liebenbderg®® @ Verschoyle!? Michels et al.2*»26 O Amagat? +10 B Morris & wylie®! X Younglove & McCarty59 © Kenerlingh omnes & van Urk}S ‘ie 18. Comprion of elated valor of dont to data for ui sate hove he xii tmpeatre—continond 4 Phys. Chem. Ret, Data, Vol. 16, No.2, 1906‘THERMODYNAMIC PROPERTIES OF NITROGEN. 767 0.8 ww 298.8 K a4 297.4 K Z 7 potnes off 0 ° “hig Scat! os 19 points off scate®® a 297.5 6 ° 1 point off scale?® 0.5 9 points oft scales® 5 -0. 3 2.5 os 298.-298.15 K fs aan =, Eo agg 0 mann 2a DS HOS deeb eee bere beter -0.5 > W os ae _ 298.15 K > 0 - ° ae 13 points off scate™ E -o5 -0.5 a 4 ie 205. K os 208.5 « w 0 0 geese HH. a E -0.5 -0.5 fa 0.5 0.5 300 K 4 o w o ea 13 points off scale a Wi -o.5 -0.5 |b 7 os 308.1 K 4 fF scales® i joints off scale a 0.5 42,86 0.5 0.5 ead) 0.5 ° ob pepeines “ons 7 points off scale vous bow Off semtest oto 20" 30" uo" 50 DENSITY (mol/dm?) Chengs? Liebenberg®® Halter et at Tsiklis 4, Polyakov" Benedict? Friednan?° Michela ct 01.24.76 xvooen< oto" 2030" Yo" 50 DENSITY (mol/dm?) Morris & Wylie® Otto et al? Rober tsar & potas Straty @ piller®? Townsend? Younglove & HeCartyS? xopant ic 18 Comparions of aed vals fdas to dt fo Bu tats bore th eral enpeatre—coninoed 4 Phys. Chem. Ret. Dat, Vol. 15, No.2, 1986768 PERCENT DENSITY DEVIATION 0.5 0.5 0.5 JACOBSEN, STEWART, AND JAHANGIRI 8.0K os 323.16 K oom oP ——4 -0.5 300.5 K os 999.9 K joints off scale®® 5p scale ae -0.5 320.7 K os 330_K 14 points off scale®® E o -0.5 322.88 K 05 347.9 K — of 0.5 322.9 K o. 3ue.1 K = + Oe aeons -u.s 323.14 K 0.5 348.4 K 1 paint a aah nae off scale? or S23.18-923.18 K 9,5 350 _K a o @ points off scale i -0.5} 323.16 K ns 372.6-372.8 K fee oS es oo 20300 oo 2030 Wo 50 DENSITY (mol/dm3) DENSITY (mol/dm’) @ Amagat? +! X otto et_al.2? A Bartlett et al.!? © Tsiklis?! @ Ronedi ct 28 © Tawncond3? © Holborn & Otto!t.13 O Rivkin®* D Liebenderg®® X Younglove & Mccarty$? Michels et a1.2%,26 Fi. 18. Comparisons of clued value of density to dal for Bud sae shove thecal emperature—coatinud 4: Phys. Chem. Ref. Dat, Vol 15, No.2, 1986PERCENT DENSITY DEVIATION 0.5 05 0.5 0.5 -0.5 o.5 uo ‘THERMODYNAMIC PROPERTIES OF NITROGEN 769 372.8 K os 397.5 & forum 0 eee -0.5 373. K 0.5 390.2 1 point off scate!® oa — \ 373.15 K 398.2 K od ° -0.5 ee K O5 423K cal ° be 5 points off scale?! -0.5 373.2 K Be 429k i= me | -0.5 373.2 K os 423.13 K to Of seers 70.5 373.4 K Ae 423. 15-425.17 K See ee i oF a -0.5 ° _ 373.5 K os 423.17 ie a oF coints off scale?! ot 2030 Wo 0 010 20300 DENSITY (mol/dm3) DENSITY (mol/dm*) & Bartlett et al.!? Rivkin ® Benedict?® @ Robertson & Babb"? © Holborn & otto! 3 © isis! ‘ Michels et 21.24.26 ® Saurel** otto et al? {0 1%, Comparsons facut ales of ens to dt for Bid sates above the exit emperntare—contnud 4 Phys. Chem. Ret, Data, Vol 15, No.2, 1986770 PERCENT DENSITY DEVIATION 0.8 0.5 OS 0.5 0.5 -0.5 0.5 0.5 -0.5 o6 JACOBSEN, STEWART, AND JAHANGIRI @ Bartlett, et at.!? Benedict”* © Holborn & otto! ‘& Malbrunot &, Yodar*” Nalbrunot™ 423.4 K ae 473.19 K 0 og 0.5 ae 473.4 K of 0.5 472.1-"72.7_K ne 573. ~573.22 K 3 points oft scale? 5 He -0.5 473.0 K ae $73.22 K 6 points off dh scatet?s%® — ° a 4 points BGP wort scale -0.5 pee ae Ee. 473.16 K a 573.5 K 0 i" ge -0.5 473.18-273.16 K gg 872 K . 2 4 points off ° scale’? *6 “0.5 473.19 K 673.13 K ~ 0.5 AT 1 point 5 a ee xe2 x off scale™ a -0.5 473.19 K ae a 9 points off scale"7+¥ ne ° a7 ? n.d 01 2030 «uO 80 0 10 2 30 40 50 DENSITY (mal/dm3) DENSITY (mol/dm3) © fmagat? © Rivkins+ I Robertson & Babb! © Tsiklis, & Polyakov" ® Saurei* Fic 18. Comparion of alcalatad valves of dent to data or fi stat hove he rite tampeatre—coatiaued 4. Phys. Chem. Ret. Data, Vol. 15, No. 2, 1988,‘THERMODYNAMIC PROPERTIES OF NITROGEN mm A 673.22 K 16 points off scale o _ Homo —_| “0.5 ae 673.5 K ; | -0.8 a An 762.53 K oo é 3 = -05 & a 113.22 S a 27 points off scalet?»"® w “ O -o5 > os 873.3 K = 24 potnts orr scare"?>"* o ° 2 S Z -0s 4 O os 973.5 K E points off scale*?>"® Fo ee Wh -0,5 benebpereelnertereetereed & os 1073.8 K yoy 25 points off scaler?" ® “0.5 ae 17W1 K 25 points off scale*?»*® ° -0.5 A. oie 2030 wo 50 ae 1274.4 K 27 points off scale*?»*® ° -0.5 4 oie 2030" Wo 50 DENSITY (mol/dm3) a are lete et al) 2 Robertson & Babb*S & Malbrunet & Yoder? © THElts & potyakov'* albrunot*® ‘ie Compara f xed nls af dey ot fr a ate sone the ‘al tenpeatrecontined ‘Phys. Chem. Ret. Data, Vol. 15, No, 2, 1908,™m PERCENT DENSITY DEVIATION JACOBSEN, STEWART, AND JAHANGIRI 2.0 124.6 K 2.0 126 K o [44 2 points off scate?s : o -2.0 72.0 AO 121.08 ae 126.01 K Oo je 9 | S——_______ 2.0 2.0 2.0 125.2 K 2.0 126.0366 K 0 jk 0 oe 2.0 i 2.0 2.0 125.487 K 2.0 126.086 K o ne o $+. _| -2.0 -2.0 Ag 125.66 K 20 128.096 K o |e 0 x -2.0 eal -2.0 2.0 125.73 K 2.0 126.1166 K ; 2 points off scate!™ 3 2 -2.0 ~2.0 2.0 125.886 K 2.0 126.1466 K 0 + 0 0 2.0 2 points off scale’s A 125.986 K 2.0 126.17 K o bape ° 2 otal “2.0 2 points off scale’? oO 8 16 au 32 uo o 8 16 au 32 4O DENSITY (mol/dm) + Tozulya & stagoi®® A. kamerlingh Onnes & van Unk DENSITY (mol/dms) ‘S Friedgan?? O weber®® ‘ic. 18. Comparisons ofclelted values of density to data near the ric temerstie. (7, 126.193 K,p, = 1177 mold) ‘J.P, Chem. ef, Data, Vol 16, No 2, 1886,PERCENT DENSITY DEVIATION ‘THERMODYNAMIC PROPERTIES OF NITROGEN mm 2.0 126.197 K 2.0 x 126.987 K fs aoe ee a tte 2 Points off seate™= 7 -2.0 -2.0 2.0 126.21 K AG 127.900 K 0 beg 0 Le fan 7 points off scare™ -2.0 -2.0 a ___ 128.227 i ize K 0 be ° Persanscroe. = ze 7 points off scale a -2.0 -2.0 Pe 126.247 a - 128.708 K 0 Lereggt he o Lima FS points off scale -2.0 -2.0 20 178.287 20 129.987 K 0 art ——_—____ 0 arte per | “points off seate®® -2.0 -2.0 20 126.387 K 20 130K 0 wets 0 fe % 5 points off scale’ -2.0 te -2.0 20 p87 a 131.14 K 0 fate tee o staan | -2.0 ‘¢ -2.0 bo 126.849 K bo 131.639 K o Lumet o fates 6 points off scale! “2.0 -2.0 oe 18 ay 32 40 DENSITY (mol/dm3) + Zozulya & BlagotSS ‘A Kamer! inah Onnes & van linet 1 Weber? oe ie au se uo DENSITY (mol/dms) © ccheng>* X Younglove & McCarty? © Straty & nition 6 ia, 19. Comparisons of lelted values of density to data near the ec empertre (F, = 126193 K,p, = 1.177 mol?) contin 4 Phys. Chem, Ret Dats, Vol. 16, No.2, 088m7 JACOBSEN, STEWART, AND JAHANGIRI a cagectt 1 | aol | 2.0 134K ; 0 ete ggenes PERCENT DENSITY DEVIATION 2.0 ao 136K 0 gsc 2.0 ata 138 K a oon 2.0 an 139.991 K 0 essen -2.0 oe 16 2 se wo DENSITY (mol/dm3) © Tozulyg & Blagoi®S Gotuder & pobroygl 'skit*? © weber?® # Straty'@ viiters® @ Canfield et a1.3? "a. 18, Comparisons of cel aes of density to data ner thecal temperature Coe Dete Ka = 11 179 melanin J: Pys. Chem. 3. Data, Vo 18, No.2, 1986,‘THERMODYNAMIC PROPERTIES OF NITROGEN 2,Heat Capacity Comparisons of values of the isochoric and isobaric heat capacity of nitrogen calculated with the fundamental equation to data values are shown in Figs. 20-22. The caleulated values of heat capacity from Eq, (5.7) generally are in agreement within -¢24 with available data. Maximum de- vations are larger for data near the critical point. (62:1. Ieochorl Heat Capacty FFigure 20 indicates that agreement of the calculated values from the fundamental equation with the available data for the isochoric heat capacity is within + 2%. For temperatures close to ., the deviations ofthe heat capacity values on the critical isochore from Vorone!® and Chashkin etal are in excess of 2% (between $% and 20% for Vor- ‘nol ef af! and up to SO% for Chaikin of al™). These values are not included in Fig. 20. ‘Comparisons ofthe specific heat of the saturated liquid, Cy» with calculated values from Eq. (5.7) are shown in Fig, 21 Agreement ofthese data with Eq (5.7) is generally within 42%. (6.22.leobaric Heat Capacity Figures 2 and 2 illustrate comparisons of the isobaric ‘heat capacity data for nitrogen with calculated values from Eq, (5.7). These Agures indicate agreement between calc lated and data values generally within + 3% in isobaric heat capacity 6.3. Velocity of Sound Figure 24illustrates the comparisons between calculat- cd values of velocity of sound from Eq. (5.7) and data val- vues. Figure 25 isa similar comparison for saturated liquid and saturated vapor velocity of sound data. Calculated values from Eq. (5.7) are generally in agrooment within = 196 in velocity of sound with the availabe data. Figure 25 illustrates agreement ofthe saturated liquid velocity of sound data and calculated values from Eq, (5.7) within 2% in velocity of sound. The deviations of the saturated liquid values calculated from Eq. (5.7) increase as ‘temperature approaches both the critical temperature and the triple point temperature. 6.4, The Second Virial Coefficient Figure 26 illustrates comparisons between calculated value of the second virial coefcient from Eq. (5.7) and the selected correlated values of Levelt Sengerser a" from 100 10 1500 K. Ladle 2 iss Values of the second viral coem- cient for nitrogen, The values ofthe second virial coeficients calculate from Eq, (5.7) agree with those of Levelt Sengers ral within showt 8 lowe S00 K. The tare erer- ‘ances at higher temperatures shown in Fig. 25 and Table 10 are not explained. Extrapolation of the fundamental ‘equation beyond the range ofthis correlation isnot recom- ‘mended, 78 6.5. Maxwell Criterion Figure 27 illustrates comparisons of values of vapor preswure, saturated liquid density, and saturated vapor dea sity with values calculated from Eas. (3.1), (3.2),and (3.3), respectively. In addition, Fig, 27 includes comparisons to saturation properties calculated from Eq, (5.7) using the “Maxwell eriterion, The values calculated from Eq. (5.7) using the Maxwell criterion are in good agreement (within + 0.01%) with values calculated from Eqs. (3.1), (32), and (3.3), and with selected data. 6.6.Enthalpy ‘The comparisons af data with caloulated valuncofenth. apy from Eq. (5.7) given in Fig. 28 indicate that Eq. (5.7) ‘may be used to predict values of enthalpy accurately except in the critical region. No claim for accuracy in the critical region is made 6.7. Enthalpy of Vaporization Figure 29 illustrates comparisons with data of values of the enthalpy of vaporization (latent heat) calculated from Eq, (5.7) using saturation densities calculated from Eq, (.7) by applying the Maxwell eriterion at the data tempera: ture, The deviations of calculated and experimental values are generally within ++ 2%. Deviations of calculated values, ‘of the enthalpy of vaporization at states near the critical point areas large as + 3%. 6.8. The Critical Region “The critlal region for the equation of state for nitrogen is arbitrarily defined to include states at temperatures between 124.5 and 140 K at densities from 7.5 to 15 mol/ dm? The revised and extended scaling model of Jahangir land Jacobsen” is considered to be the most accurate repre- Sentation of available data fr nitrogen in this region. The fundamental Eq. (5.7) was determined by least-squares ft- tngof selected data with constrained temperature, pressure density, (AP /dp) and (4*P /dp") at the critical point. ‘The critca-point parameters of the Fundamental equation nee ientical a the given hy Zemlya and lagi. as required bythe constraints. ‘Comparisons of calculated and measured density val ‘ues in the critical region are included in Fig. 19. Additional Compansons of #p-1 daa in the critical region are given tn Figs. 30-33. Figures 32 and 33 illustrate comparisons of values of pressure and density calculated from Eq. (5.7) with lies from the rrved and extended scaling equation of Sahangir and Jacobsen,” The range of validity of the model of Jahangir and Jacobsen” is between 7 and 15 mol/am’. The Pp-T graphs ofthis section extend beyond this range of valiytolustrate te relate agreement win data Outsice the critical region Significant discrepancies in calculated density values sem aprarent in Fig ¥8. Agreement of ealenlated wales of Aerived properties including C,,C,,enthalpy, internal ener- 1, entropy, and velocity of sound with values from the revised and extended formulation of Jahangii and Jacobsen” ‘was not expected. The anomalous benavior of ealonmetnc 4. Phys. Chem. Ret. Data, Vol 18, No.2, 186676 JACOBSEN, STEWART, AND JAHANGIRI eat ora Ty HOL/ONS zo 2 oT me SZ coleman 2B eo 23.7 WL/OK a o {4 [ 20 Zou a Ooo (@——————— & fi ae 2 a ° Re ee a tae ide ste Meso 300 380 TEMPERATURE (K) © wee + teste 1.20. comuion ees sissy on oe 5.0 Say Zz 3.0 g 2.0 y ° & of d¥c00% 0 o,8 5 a0 a ce Blot 3 eo % -3.0 Q “4.0 & slo 4 2 a 60 69 W 85 gy 103° «ttl 120 TEMPERATURE (kK) Keston & Kamer ingh Ornes! ‘Fie. 21, Comparisons of alee vals of het capacity, Co data ‘J.hys. Chem. Re. Data, Vo. 15, No.2, 1986THERMODYNAMIC PROPERTIES OF NITROGEN ™ oO 0.101 HPA a 13.66 HPA g FF EF 0 tr 4.0 + ae 1.01 MPA Ao 20.27 HPA o foot a a eecEre 4.0 is 2.03 HPA 7 30.40 HPA ° : ° ° z wot FFG 1.0 baretecostenn 4.0 z 2.75 HPA 40.53 HPA 4.0 4.0 2 = of ° as ee) “4.0 Sao 4.05 HPA a 50.66 HPA ao 0/2 5 o 7 oo ar fb -4.0 + + HAO beveeteren soteeed Z uo 5.07 HPA ata 60.80 HPA a ° zipsinelore anaes - a RET no re ag 8.10 HPA a 70.93 NPR 0 Le peo 0 eae 4.0 pees -u.0 | AG 10,13 MPR _ 81.08 HPA ° = ¥e 44% 7 a al ou a + o +0 beeeterreteertpereeterestorseterne} 100 150 200 250 300 350 400 450 TEMPERATURE (K) Mackey & Krage?? Mage et al.’> =O bevestereeteiceteenrteretnreetetee] 100 180 200 250 300 960 400 USO TEMPERATURE (K) % van Kasteren & celaenrust% ic. 22. Compersons ofan valve fash et capacity, Gy to data Gare date) ‘Phys. Chem, Ret Data, Vol. 15, No.2, 1966778 3.0 3.0 -3.0 PERCENT DEVIATION IN C 3.0 -3.0 3.0 a -3.0 9, JACOBSEN, STEWART, AND JAHANGIAI 172. K . coal 3.0 333.14 K ° + 0 are resisters) ~3.0 Leer —eesni tinct 199.88 K 3.0 373.2 K L point off o 7 o sealers * = oo OT a “— wa Ht 4 of 227.62 K omer ° 2 + ° e a °o oom Lisette reseed 9.0 br esnd seem ete rind 273.15 K a W23.22 K rosin a on ; : To El Meet sof 3. 299,14 K Bo a eG, ti : : : PRESSURE (MPA) 303.09 K Che be etter tm tse ri 303.69 K sR Partie petninh erie tt 323.08 K | Lineinb—ertint retest fon Tio. PRESSURE (MPA) © Faulkner 100 & Workman®® + Bloomer & Rao?! krase & Mackey? X Lestz®? ‘0.23, Compartons of cake vale ofits best apa, Ct data (thermal dt. 1 Bhp Pham Bet‘THERMODYNAMIC PROPERTIES OF NITROGEN 779 3.0 auu K 3.0 78.4 K o }-—— 0 sh -3.0 Hl 73.0 kee Ha al ee 66.3 K 3.0 79.2 K ° 0 faa 5.0 Let Pit amr ssn = 2.0 3.0 69.5 K 2.0 a0. K 0 0 La xX x QR -3.0 a alaliad amanda -3.0 was veh of 3.0 7100 K 3.0 ea. Kk ofa © tau 3.0 Feet taste ti = 3.0 Le tn tt An 73.8 K a 87.3 K o + ° x room | ~3.0 Lessin ti tint tt tid ~3.0 3.0 TMK ae 90. 6 ° 5 at ° 4 -3.0 = 3.0 festa sinh sti sa a0 71.8 K an 80.1 K 0 B 21008 0 X xogiet -3.0 nt st ssi 3.0 td Ht hi Bt 77.8 K 90.3 K PERCENT DEVIATION IN VELOCITY OF SOUND CT A A TO PRESSURE (MPa) PRESSURE (MPa) X Van Itterbeek § Van Dag} ?9,110,111 1S Keeson & Van_Lanneren A Younglove & McCarty®? Fic. 24, Comparisons of cali values of vec of sound to dats 4. Phys, Chem, Ret ata, Vo. 15, No.2, 18867 s JACOBSEN, STEWART, AND JAHANGIRI 3.0 90.4 K an 190. K Do 0 eat —_____| z 5 -3.0 =3.0 Lettie tit Os. 9 20 2.0 uo? 0 Oo 730 73.0 Leet ese rit > 80 3.0 227.8 K ao ° ee 8 -3.0 =3.0 feet ess ti st a su 3.0 329.2 6 a) ° Sg -3.0 28.0 Letra tctintt scm stidi 2 oo 3.0 230. K S ° ° sect z= 0 ~8..0 Fertitta < 30 3.0 240.7 6 So 0 | —scemmoaese iff OQ -30 ~30 et ttn a 30 Ba 2ua.t K Zoo 0 i 30 Less ~3.0 Lent m 3.0 3.0 ee etl Sl -3.0 -3.0 ofr Lar tb et ith, RT tb ater tho, PRESSURE (MPa) PRESSURE (MPa) 1K Vou TuLerbeck el at. 1% @ Van Itterbeek & Van ael!!! \ Keesom & Yan Lanmeren! 0% A Younglove & McCarty 59 Fic. 24. Comparuns oss valu of veeity of sound to datacom 1.Phys. Chem. Ret, Data, Vo. 15, No.2, 1986,‘THERMODYNAMIC PROPERTIES OF NITROGEN 781 3.0 270. « 3.0 323.1 K Boo ba wast ° at DD -3.0 best tent wf =8.0 ws 8 AD 273.16 3.0 30. K 0} —setpeomema 5 eel Le Oo -3.0 vet mt il wet -3.0 wt al Ht — > 80 273.15 K An 3u8.1 K Eo . 0 wan SF s.o Lene 3.0 Leet rss fey 3.0 290. K 3.0 350. K w wood pawns o > ze tk seh ~3.0 th = 293.8 K an 373.15 K Zz sc 0 eee 2.0 Lessant renin trs seit ese 3.0 Lees cues = _ 298.1 K BG 398.2 K So | age} io | i 2 points off scale’? CD -3.0 Heit essnnl esi trim eiimd —— —3.0 asi 80 298.7 K 2.0 423.2 K = 0) rem 0 Wu 1 point off scale’? 9 > oO 30 Hat v= ond aad “i 3.0 Hate ied Ht « 3.0 310. K 3.0 uus.2 K 2 ° even 0 S 2 points off scale®? o -3.0 : ito stk i ec soa +0 wf O01 Ot te 10. 100. 1000, O01 Ot te 10, 100. 1000, PRESSURE (MPa) PRESSURE (MPa) X Van Itterbeek et al, !08 &\ Keesom & Van_Lanmeren?®* A Younglove & McCarty? © Voronoy et ai,!!* ‘Re. 24, Comparitons of seule ale of lacy of sod to dats continue Phys. Chem. Ret. Data. Vol 15. No. 2.188878 JACOBSEN, STEWART, AND JAHANGIRI Bp Zq 53323 oxy Ege + e eee ape. ¢ a BOS yh ww yer % + O>eE br eet tea at SEG o pat Zoe xe Hor aid eag<7! a a> -2 so 6700680) 90s«100.-—«satd.—s«a20.—«130 TEMPERATURE (K) & Pine! 13 & Van Itterbeek et at. '0% © Van Itterbeek!® + Van Dael et_al.!!? X Van [tterbeek & Van Dael!°? Yy Verschoyle!? Fc. 25 Campus of alealsta alae ofthe velo of sound st satraton od 3.00 2.00 1.00 0.00 -1.00 -2.00 -3.00 Byata Begn’om/mol) 500 900 1300 TEMPERATURE (K) 4. Phys, Chem, Ret Data, Vo. 15, No.2, 1966‘THERMODYNAMIC PROPERTIES OF NITROGEN 783 Table 20. Second virial coefficients for nitrogen SS Tenperature (cm? /no1) Levelt Senger ) Equation (5.7) et al® 109 158.03 12 nese 106 a4 105 Ties 109 136.05 ito Tass ue estos us Hele 20 Hises a oes ia rise iB 2 $8 6 > 89 1 fast ia 2s is = 125 is 2 tee 160 Deis iss sits 8 ot 1a 2 06 10 ie aa 2 iio ie 12S 20 2 ios a TBe oo 2 isto io se 2 = 1082 Ea 2 Tae So tae i 2 so ier x00 ra n a ito Sa ‘ca Bae so iis ‘00 18.59 i.00 0 2 19's0 io 2s 2:30 an 38 330 500 ae 33.10 1000 ae Sots a bie B00 4: Phys, Chem. Ref. Data, Vol 16, No 2, 1986,784 JACOBSEN, STEWART, AND JAHANGIRI 0.10 : © ¥ dahangirt & dacobsen? x calculated fram 4. (5.7) 23 Magner? ‘Using the Ravwell Geiterton onerai33 XXX 0.05 See 2 to VAPOR PRESSURE Calculated fron the Vapor oO O Pressure eg, tron wagner? A Calculated froa Eq. (5.7) Using ‘the Maxwell Criterion 7 730 87) 95 108s 1d > Calculated from Fundamental Eq, of State — (5.7) & Vapor Pressure Eq. (3.1) 3 O.4 ‘X Calculated from Virial Surface of Younylove & a McCarty®? & Vapor Pressure Eq. (3.1) < 9.0 2 1 Zozulyal*? = -0.4 Y dahangirt & Jacobsen? PERCENT DEVIATION SATURATED z 2 Ely & Straty! 3 0-6 ge ae Ea Y Jthangiri & Jacobsen? e°2 9.3 x Calculated fron €q. (5.7) Using ES © ay Go $ 0.0 Doiounhesstoo ot 63 71 79 87 95 103 111 TEMPERATURE (kK) a9) One ooe 105 1111) ic. 27.Comparions osc coexistence property data and ales oleate rn Eq (3.7) sing the Maxwell een (equal eea race) with Caled values fom Eas (3:1), (32) ad G2. 4. Phys. Chem. Ret. Data, Vol. 1, No.2 1988‘THERMODYNAMIC PROPERTIES OF NITROGEN 785 ° 3 1B Zozulya? sealing Eq, of Jahangiri & Jacobsen” © Keane! Y Calculated fron Revised & Extended 2 & ¥ Y X Calculated from Eq. (5+7) Using XXXXX xxx X% the Maxwell Criterion 70.05 calevlated fron, the Vaoor Pressure fay of agner®* SATURATED VAPOR PRESSURE ° 2 8 -0.10 120 121 122 123 124 125 126 127 0.8 1 rorya)? a Y Falrslated from Revised 2 Futended vy Ou Scaling eq. of Jahangit & dacopsen? y A calculates fran Ea. (567) Using Y ‘the Hoxwel | eriterton, SATURATED VAPOR DENSI'Y a o PERCENT DEVIATION OO n aaa -0.4 v y -0.8 120 121 122 129 12h 125 126 127 0.9 + © Ely & Straty!* Y Y eh 0.64 2 Stray fgiers y 9 ig Y Calculated from Revised & Extended Y 7 o [mo no a -o.3 A = ae 425.73 198.197 K Z 0 be * 0 ft Qo -os -0.3 E 0.3 125.89 K 0.3 126.21 K Seo - ahtor 0 fh ee We os -0.3 aD 125.98 K ae 126.23 K = . z 0 Hoye ee eee m7) QO 23 -0.3 & os 126.08 K be 126.28 K O 0 bene ~ 0 -0.3 -0.3 7 126.09 K Oa 126.29 K of eee — 0 po 0.3 -0.3 Votre an te te rr ar ar rr DENSITY (mol/dm*) DENSITY (mol/dm°) + Zozulva & BlaqoiS® © Straty & Diller’? O Friedman? 4 Phys. Chem. Ref, Data, Vol. 15, No.2, 1888‘THERMODYNAMIC PROPERTIES OF NITROGEN 739 os 126.99 0.3 132. 0 [pt] 8 pegore oF “0.3 -0.3 128.59 K = 193.14 K . oe Woo [A ttesseret et} 0 =x SG ws “ws Bos 126.99 K - 134K dr + a 3 34 127.99 1 194.89 1 Z 089 . SG le tee, ++ 5 [tt treet tte z ee 6 as -0.3 = os 128 K 03 136 K ao 2 0 > Boo o Goo o i 3 ore 129.99 130 bE atm, eet 5 oo — 0 = os of; 130K a 139.99 K Wig 2, Dt ae ee eet a “0.8 .3 03 131.98 K 03 140 K ts + ° tht 4 * 0 FOS oe “0.3 7 8 Mm 438 tS 17 DENSITY (mol/dm?) 4 Lozulya & BlagoiS> © Straty & Diller®® D x ° a 13 tsa? ENSITY (mol/dm3) Canfield ot a1.39 Weber °° Fo. 3. Compan of ablated ales of presse othe experimen atin theca egion—conine, «1 Phys. Chem, Rel. Dat, Vol. 16, No.2, 1806JACOBSEN, STEWART, AND JAHANGIRI 0971 nh Ca PD wore gan X Pies O setobeia x Skinzor (etup/low) ALISNAG el 21 (1 of 6 8 2 ‘O1"O- 5 f[S0°O- i “+000 wsprg2t = so°O oro St fl €t et It OF L wearszt = 1 St hl el 21 it or x s2te2t = 1 FYNSS3Aed NI NOILVIASG LNZ04Ad 2 woo Suet pepons pe ponoy aw Me Poa woNEtD jo soKOp aNBeHA ZO eel? 3 plauive) O SYNSSAYd NI NOILWIASG LN30uad 4 Phys. Chem, Ret Data, Vol. 1, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN beep yn Seas papas pu pt agn ny mp. f-y puss Jo onIMksosuoRNoD ASEH CE DLL vgooer me uunye aoa 438] 9] DAEPOHNAE| wD BHAT u beg Yen inz 9a oe UPEPALI A sot0Beta 9 eXLnzO: + cgoing 1 REDS (guip/low) ALISNAG (eupsjow) ALISNAC Gian ct cW nt OU) cee st hl ef 21 it ol 6 8 ¢& worse a 7 st nt €1 2t it of 6 8 waerazt = 2 ALISNAG Ni NOILVIARG LN30uad ALISNAG NI NOILWIASG LNA0uSd 4. Phys. Chem. Ret. Data, Vol 18, No.2, 1886JACOBSEN, STEWART, AND JAHANGIRI 792 100 89; LJP) eS poe yp WoNSENE (en TEAR) HOM NWO SnD PALAPYE 30 aoNAwAAED yf OL (gupsiow) ALISNSG (ppnow) ALISNSG sloRT et Tt Ot 8 L < st ht er WW ol 8 Z O1- A 3 ston - 9 ve smt, 3 _d a i 3 2 g o K ; 23 ae oz @ 2G § BS oe & 2 z 8 a cs g q a ae a e4 5 ¢ 3 £3 5 =3 2 s g 2 z 5 g : s : ec i 3 38 : ~2 z 4 or ~ i 5‘THERMODYNAMIC PROPERTIES OF NITROGEN 793 7. Acknowledgments ‘This work was partially supported by the National Bu- eau of Standards Utice of Standard Keference Data (NBS- SRD] under Grant No. NBSONADA 1048, The efforts of Dr. Howard J. White, Jr. of NBS-OSRD as technical moni- tor for this grant are recognized and appreciate 8. References *R.THacobsenand RB Sew Phys Cham, Ref Data 2,757 (197. 2S Angun 1M. Ge Rese B Arman. R.T Jcobern and RB Stewart trata Thermodymae Tie the Pid Stet Ni trogen, nteratinal Un of Presb ppb Chemistry, Chen Dats Series No-20 (Pergamon, Oxford, 1979). SFR Siobridee, Nall Bur Stand. 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Thermodynamic Properties of Nitrogen Saturation entries for isobar tables are calculated using temperatures determined by iterative solution of the vapor pressure Eq, (3:1). The densities for the saturated liquid and ‘vapor are calculated feranvely using the equation of state, Eq, (5.7). Table entries fr the iquid~vapor saturation table are calculated using the vapor pressure equation to deter- ‘mine P, atthe table value of T,. Densities and derived properties ate calculated using the same methods as those for the saturation entries in the isobar tables.‘THERMODYNAMIC PROPERTIES OF NITROGEN 795 Table 21. Thermodynamic properties of saturated nitrogen Temperature Pressure Uensity Enthalpy Entropy G, —G,_—_Velockey of Sound K MPa mol /én? J/mol J/mol K J/mol K J/mol K m/s 63.15 0.01253 31.066 -4227.5 67.89 31.29 56.56 1022 0.02412 180613 163.43 23.94 33.27, 159 66 0.01460 30.915 =4179.3 68.64 31.21 56.49 1010 0.02776 © 1828.8 162.52 24.10 33.51, 160 65 0.01741 30.760 -4122.8 69.52 31.12 56.43 996 0.03264 1854.8 161.48 24.30 33.82 161 88 0.02083 a-BU3 -4UB9.9 70.98 24.09 98.40, 02 0.03816 188016 160.48 24.50 34.12 162 67 0.02432 30.450 -4009.8 71.23 30.93 56.39 970 006439 “I¥u810 159152 2al7D Sala 163 68 0.02850 30.294 -3953.4 72.06 56.39 958 0.05137 1931.2 158.60 36.76 164 69 0.03324 30.137 -3896.9 72.88 56.42 945, 0.05917 1956.0 157.71 35.05, 165 70 0.03887 29.980 -3840.3 73.70 56.46 933 0.06784 1980.5 156.85 35.36 166 71 0.04456 29.871 =a789.7 74.50 56.59 901 0.07745 "2004.7 156.02 35.67 167 72 0,05125 29.662 -3727.0 75.29 56.59 910 A0RROR —-702R'S 158 29 35.97 168 73 0.05870 29.502 ~3670.2 76.07 56.68 398, 0.08978 © 2051.8 134.45 36.27 169 Te 0.06696 29.341 -3613.3 76.84 56.78 887 0.11264 © 2074.8 153.70 36.57 170 75 0.07610 29.179 556.9 77.60 36.90 076 0.12671 2097.3 152.98 36.87 170 76 0.08617 29.016 =3499.1 78.35 57.02 864 0.14208 211913 152.28 37:17 am 77 0,09723 28.852 -3441.8 79.09 57.16 853 0.15881 2140.9 151.60 37.46 72 78 0.10935 28.686 -3384.3 79.83, 57.31 842 0.17699 2162.0 150.94 37.75 73 s 28.520 -3326.7 80.56 57.48 832 0.19670 2182-6 150.30 38.04 173 80 0.13699 28.351 -3268.9 81.28 57.65 821 0.21801 220217 149.67 38.34 174 4 Phys. Chem. Re. Dats, Vol 16, No 2,19796 JACOBSEN, STEWART, AND .IAHANGIRI Table 21. Thermodynamic properties of saturated nitrogen-Continued ‘Tenperature Pressure Density Enthalpy Entropy ©, Velocity . . P of Sound x Mpa mol/én?—J/mol_J/aol KS/aol K S/mol K/e 81 0.15265 28.182 -3210.8 81.99 29.53 57.84 810 o.2a100 222212 1a9l07 20100 38.03 173 82 0.16961 28.011 -3152.6 82.70 29.42 58.04 799 0.26578 2241.1 148.48 26.67 38.92 175 83 0.18795 27.838 -3094.1 83.40 29.32 $8.26 788 0.25242 2258.5 147.90 26.73 39.22 176 86 0.20773-27.664 ~3035.4 84.10 29.22 $8.48 78 0.32102 2277.2, 147.36 26.78 39.52 176 85 0.22903 27.488 -2976.5 84.78 29.12 $8.72 767 0.38169 2294.2 146.79 26.83 39.84 7 86 0.25181 27.310 -2917.3 85.47 29.02 58.98 756 a akasy 9410 uK 9K RR LOT 177 87 0.27644 27.131 -2857.8 86.14 28.92 59.26 146 0.41961 2326.3 145.73 26.92 40.49, 178 88 0.30270 26.950 -2798.0 86.82 28.83 59.55 735 0.45709 2341.2 145.22 26.95 460.84 178 89 0.33074 26.766 -2737.9 7.48 28.78 59.86 724 0.03707 2555.4 1h. 71— 26.99 41.21 173 90 0.36066 26.581 -2677.4 BB.15 28.64 60.18 73 0.53967 2368.6 144.22 27:02 41.59, 179 91 0.39252 26.393 -2616.7 88.80 28.55 60.54 702 0.58503 2381.6 143.73 27.08 42.01 179 92 0.42639 26.203 -2555.5 89.46 28.48 60.91 692 0.63329 © 239311 143.25 27.08 42.44 180 93 0.46235 28.011 -2496.0 90.11 28.37 32 681 0.68459 2403.9 142.78 27-11 131 180 96 0.50047 25.816 -2632.1 90.76 28.29 61.74 670 0.73909 261318 1421312714 4542 180 95 0.54082 25.619 -2369.7 91.40 28.21 62.20 658 0.79696 2422.6 141.85 27.18 43.96, 180 96 0.58349 25.418 -2306.9 92.04 28.19 62.69 647 0.85838 © 2630.5 141.39 27.22 44.55 180 97 0.62855 25.215 2243.6 92.68 28.05 63.22 636 0.92353 2437.4 160.96 27.26 45.19 181 oR TKN OR OAR =DITA ROA A 97.OR 63.79 626 0.99262 "2443.1 160.49 27.31 45.88 181‘THERMODYNAMIC PROPERTIES OF NITROGEN. ‘Table 21 Thermodynamic properties of saturated nitrogen-continuea Temperature Pressure Density Enthalpy Entropy Cy, 6, Velocity of Sound K mea mol/dn?— J/mol_ © J/mol K J/nol K J/mol K m/s 99 0.72613 24.798 2115.5 93.94 27.91 64.41 613 1.0659 2447.6 140.04 27.36 46.63, 181 100 0.77881 24.584 2050.5 94.58 27.84 65.09 601 1.1436 2451.0 139.59 27.43 47.46 181 101 0.83419 24.367 -1985.0 95.21 27.78 65.82 389 1.2259 245310 139.15 27149 48.36 181 aoa 0.89294 an.ans -a018.7 95.09 27.73 6.62 377 1.3132 245318. 138.70 27.57 49.35 181 103 0,95334 23.919 -1851.8 96.46 27.68 67.49 565 akose a4s911 198.26 87165 S0144 80 104 «1.0173 23.688 -1784.1 97.09 27.64 68.44 552 4.5061 2451.0 137.81 © 27.75 51.65 180 105 1.0842 23.452 1715.5. 97.72 27.60 69.50 540 1.6083 2447.2 137.37 27:85 52.98 180 106 1.1843. 23.210 =1646.0 98.35 27.57 70.67 527 1.7191 244119 136.92 27.97 $4.47 180 107 1,2275 22.961 1575.5 98.98 27.55 71.97 514 16368243417 13648 28110 58.13 180 108 1.3040 22.706 -1504.0 99.62 27.54 73.42 500 1.9620 2425.6 136.00 28.26 57.98 173 109 -1,3839 22.443 --1431.2 100.25 27.54 75.06 487 2.0954 2414.6 135.54 28.40 60.08. 179 M0 1.4672 22.172 -1357.1 100.90 27.55 76.90 473 2.2377 © 240113135107 28.57 62.45 178 AML 1.5540. 21,892 1281.6 101.54 27.57 79.01 458 2.3898 © 238516 134138 28176 «65115, 78 112—-1.6445 21,600 1204.5 102.20 27.61 81.42 4h 208897 99K7 7A «134.09 R AT «BRI. 7 113«1,7387 21.297 1125.5 102.86 27.67 84.21 429 2.7275 2346.3 133.59 29.21 71.87, 7 114 1.8367 20.981 -1044.5 103.54 27.75 87.48 413. 2.9156 2322.1 133.07 29.46 76.09, 176 115 —1,9387 20.649 -961.08 104.22 27.86 91.34 397 3.189 2294.4 132153 29.75 81.10 475 116 2.0448 20.299 -875.01 104.92 28.00 95.97 381 3.9995 2262.7 191.97 30:06 87.12 75 797 “Phys. Chem. Ref. Data, Vol 15, No 2, 1986,798 JACOBSEN, STEWART, AND JAHANGIRI Table 21. Thermodynamic properties of saturated nitrogen-Continued Temperature Fressure vensity snthalpy Entropy G, —_Velocsty of Sound K MPa mol /én? Jmol J/mol K J/mol K J/mol K m/s 117--2.1551 19.927 -785.81 105.66 28.18 101.6 364 3.5800 2226.5 131139 30.42 94.49 174 118 2.2697 19.531 -692.94 106.38 28.40 108.6 346 3.8661 2185.0 130.77 30.81 103.7 473 119 -2,9088 19.205 -595.71 107.15 28.69 117.4 328 4.1363" 2137.3 13011231126 11515 a2 120° -2.5125 18.643 -493.19 107.95 29.06 128.9 309 e.aoszZuBd.11zylal 31178 13112 i 121 -2,6410 18.135 =384.13 108.80 29.54 144.6 289 4.8339 2017.4 128.65 32.38 153.0 370 122 2.7747 17.569 =266.70 109.70 30.16 167.1 269 5.2630 1940.3 127.79 33.09 185.4 169 123° -2,9136 16.924 -137.89 110.69 30.99 202.9 248 5.7768 1846.0 126.82 33.96 238.2 167 126 3.0582 16,160 B17 111.80 32.14 269.9 225 6.4168 1724.9 125165 35.08 340.3 165 125 3.2089 15.170 187.06 113.16 33.88 450.3 200 7.3111 1553.0 124109 36.66 620.2 163 126 3.3664 13.304 495.38 115.53 37.66 168 9.1698 1194.9 121.08 39.64. 159 126.19 3.3978 11.177 834.55 118.20 # triple point Critical point 4 Phys. Chem. Ret, Data, Vl. 15, No.2, 1988‘THERMODYNAMIC PROPERTIES OF NITROGEN 799 Table 22. Thermodynamfe properties of nitrogen ‘Temperature Density Internal Enthalpy Entropy C, c, Velocity Energy of Sound K nol/da> J/nol —J/mol_~— J/mol K J/mol K J/nol K m/s 63.15 31.047 ~4227.9 ~4227.3 67.89 31.29 56.56 1022 64 301915 417918 417912 68.64 «3122-649 1010 * 65.81 30.634 -4077.4 -4076.8 70.22 31.04 56.40 986 * 65.81 0.03709 1336.5 1875.8 160.67 24.47 34.07 162 66 0.03697 1341.2 1882.1 160.76 24.23 33.7 163. 68 0.03581 1388.7 1947.2, 161.73 22.52 31.57 166 70 0.03474 © 1433"4 2009116263 21.69 30.50 169 72 003374 «1476.7 2069.5 163.48 21.27 29.96 172 78 103200 1319.4 2129.2 16819021106 23.68 374 76 0103191 1561.7 2188-4 165.09 20.95 29.53, 7 78 0.03108 1603.8 2247.3 165.85 29.44 179 eu Ulu3uzs 464317230011 188.00 23139 toa 82 0.02953 1687.7 2364.9 167.32 29136 184 Ba 0.02882 172915 2423.6 168.03, 29.33 186 86 0.02813 1771.4 © 2482.2 168.72 29.32 188 88. 0.02749 1813.2 2540.9 169.40 20.83 29.30 191 90 0.02687 1855.0 2599.5 170.05 20.83 29.29 193, 92 0.02627 1896.8 2658.0 170.70 20.82 29.28, 195 94 0102871 1938.6 2716.6 171.33 20:82 29127 197 36 0.02517 1980.4 © 2775.1 171.9% 20.82 29.26 199 98 0.02665 2022.1 2833.6 172.55 201 100 002615 2063°9 28921 173.14 203 102 0.02367 2105.6 2950.6 173.72 3 205 104 0.02321 214774 © 300911 174.28 29.24 207, 106 0.02277 2189.1 3067.6 174.84 29.23 210 108 0.02234 2230.8 3126.0 175.39 20.81 29.22 au io 0102193 227216 3184.5 175.92 20.81 29.22 213 39 anise 94142 39470 47K aR On'AY 90°91 238 14 0.02116 2356.0 3301.3. 176.97 20.81 29.21 217 ie 0102079 2397.7 3359.7 177.48 20.81 29.20 219 ais 9.02043 230.4 9128.2 177.97 20.81 29.20 par 120 0.02009 2481.1 3476.5 178.46 20.81 29.20 223 122 0101976 2522:8 3534.9 178.95 20.81 29.19 225 126 9.01944 2564.5 3593.3 179.42 20.81 29.18 227 128 0.01883 2647.8 3710.1 180.35 20.81 29.18 230 130 0.01854 2689.5 3768.4 180.80 20.81 29.18 232 332 0.01625 2731.2 3826.8 181.25 20.61 29.18 238 134 0.01798 2772.8 © 3885.1 181.69 20.80 29.17 236 136 0.01772 281415 3943.5 182.12 20.80 29.17 238 4. Phys. Chem. ef. Data, Vol 18, No.2, 1986800 JACOBSEN, STEWART, AND JAHANGIRI Table 22, Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Gy ©, Velocity ‘Energy of Sound x mol/da? J/sol —J/mol_-S/mol K J/mol K J/aol K m/s 138 0.01746 2656.1 4001.8 182.54 20.80 29.17 239 Teo oroiy2a 200710 focols 408-96 © 90:00 «B9.47 Bad 142 0.01696 2939.5 4118.5 183.38 20.80 29:16 243 Ws 0.01673. 2981-1 4176.8 183.78 20.80 29:16 24h 146 0.01650 3022.8 4235-1 184.19 20.80 29:16 246 148 0.01627 3064.4 4293.4 184.58 20.80 29.16 248 3500101606 3206.1 4351'8 184.98 20.80 29.16 250 155 0.01556 3210-2 -4497.5 185.93 20.80 29:15 254 teUULUIS03 3316.2 Go4s'3 WSO 2UL8D NTIS 288 165 0.00459 3418-3 478910 187-75 20.80 29:15 262 170 0.01416 3522.4 4934.8 188.62 20.80 29.14 266 75 0.01376 3626-5 30805 189/47 20:80 29:14 © 20 380 010133737305 $226.2 190.29 20.80 29:16 273 385 0.01301 3834.6 5371.8 191.09 20.80 29:16 4277 190 0.01267 39386 $517.5 191.86 20.80 29:13 281 195 0.01236 4042.7 $663.2 192.62 20.80 29.13 285 200 «0.01203 4146.7 $808.9 193.36 20.80 29.13 288 210 0.01146 4354.8 6100.2 194.78 20.80 29.13, 295 220 0101094 45628 63915 196.14 20:80 2813302 230 0.01046 4770.9 6682.7 197.43 20.80 29,13 309 240 fain bar @ KOLA ORT HAD 7019 250 0.00962 5187.0 7265.2 199.86 20.80 29.13 322 260 0.00825 $395.0 7556.5 201.00 20.80 29.13 328 270 0.00891 5603.1 "7 202110 20.80 29113335 280 000859 S611. 0 208116 20°80 2913 Ba 290 0.00830 6019.3 8430.3 206.18 20.81 29.13 347 300 0.00802 6227.4 8721.6 205-17 20.81 29:13 «353 310000796 Gaasl6 901310 a0esas 0188 BIA 30 320 0.00752 6643.8 9304.4 207.05 20.82 29.14 365 330 0.00729 6852.2 9595.9 207.95 20.83 29:15 370 340 0.00707 7060.5 9007.5 200.02 20.08 29.16 376 350 0.00687 7269.0 10179. 20966 20.85 29.17 381 360 0.00668 7477.6 10471. «210.48 20.86 © 29.18 387 370 0.00650 7686.4 10763. 212.28 20.88 28.20 392 380 000633789513 12055. 212.06 20.90 -29.21 397 390 0.00617 8104.3 11347. 212.82 20.91 29.23 402 $00 0.00601 8313.6 11640. 213.56 20.93 29.25 407 zy ULUUS/3 732.8 Lez) Zi y ZLB au a 440 0.00547 9153.0 12812. 216.36 21.04 28.36 427 460 0,00523 9574.5 13399. 217.66 21.11 29.42 436 480 0.00501 9997.4 13989. 218.92 21.18 29.50 as $00 0.00481 10422. 14579. 220.12 21.27 29.5854 520 0.00463 10848. «15172. 221.28 21.36 29.67 463, $40 0.00645 11276. 15766. 222.41 21.46 «29.77 472 360 00063011707. e363. 225189 21136 2888 80 4. Phys. Chem. Ref. Data, Vol. 16, No.2, 1986‘THERMODYNAMIC PROPERTIES OF NITROGEN Table 22, Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy Velocity Energy of Sound K mol/dn? J/mol —J/mol.-— J/mol K J/mol K J/nol K w/s 580 0.00415 12139. 16962. 224.54 21.68 29.99 488 600 0.00401 12574. 17563. 225.56 21.80 30.11 196 620 0.00388 13011. 18166. 226.55 21.92 30.23 504, 640 0.00376 13451. 18772, 227.51 22.05 30.36 512 660 0.00364 13893. 2228.45 22117 30.49 519 680 0.00354 14338. 19992. 229.36 22.31 30.62 526 700 0.00344 14785. 20606. 230.25 22-44 30.76 534 720 0.00334 15235. 21222. 231.12 22.58 30.89, 541 740 0.00328 15688. © 21841. 231.97 22713103 Sus 760 0.00316 16144. 22463. 232-79 22.85 31.16 555 780 9.00308 233.61 22.98 31.30 562 300 000301, 236.40 23:12 31.44 568 850 0.00283 25295. 236.32 23.45 31.77 585 900 0.00267 26892, 238.14 23.78 32.09 600 950 0.00253, 28504. 239.88 24.09 32.40 616 1000 0.00241 30132. 261.55 24.38 32.70 631 1050 0.00229 31774. 26316 24.66 © 32.98 646 yo 900919 33429. 266.70 24.93 33.26 660 1150 0.00209, 35098. 246.18 25.18 33.49 674 1200 9.00200, 36778. 247.61 25.41 33.72 688, 1250 0.00192, 3RU70. 248.99 78.63 33.94 701 1300 0.00185 40172, 250.33 25.83 34.15 ne 1350 000178 41885. 251.62 26.02 34.34 727 1400 0.00172 43606. 252.87 26.20 34.52 740 1450 0.00166 45336, 254.09 26.37 34.69 752 1500 0.00160 47075. 255.26 26.53 34.84 765 1550 0.00155, 48820. 256.41 26.68 34.99. 7 1600 000150, 50573. 257.52 26.81 35.13 789 1650 0.00146 52333. 258.60 26.94 35.26 301 1700 0.00141 54099. 259.66 27.07 35.38, 812 1730 0.00197 93072, 260.69 27.18 99.49 024 1800, 0.00134 42682. 57649. 261.69 27.29 35.60 835 1850 0.00130 44049. 59431. 262-66 © 27.39 35.70 846 1900 0.00127 45421. 61219. 263.62 27.49 35.80 857 isu viuviZs se/ys. suit) Zemls> ZB 3 Lay B03, 2000 0.00120 48179. 64808. 265.46 27.66 35.98 879 * 63.15 64 66 68 31.048, 30.917 30.607 30.296 4228.0 4180.0 4067-2 -3956.6 0.04 MPa Isobar 4226.7 741788 ~4065.9 ~3953.1 67.89 68.64 70.38 72:06 31. 31 31 30: 30 22 03 56. 56. 56. 56. 56 49 40 39 1022 1010 983, 958 801 4. Phys. Chem. Ret, Data, Vol 15, No.2, 186802 JACOBSEN, STEWART, AND JAHANGIAI Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy Velocity Energy of Sound K mol/dn? J/mol J/nol_ J/nol K S/mol K J/mol K — a/s 70 29.980 -3861.6 3840.3 73.70 30.64 56:46 933 # 10.25 29.940, -3827.6 -3826.2 73.90 30.62 56.48 930. 70:28 O.67014 “idde'$ “1986.6 SeLoe 25128 Blak Te. 72 0106824 1460.0 2046.2 157.48 23.32 32.87 370 Th (006625 1506.4 2110.2 158.36 22.15 31.33 173 76 0.06439 1550.8 2172.0 159.18 21.55 30.53. 176 78 0.08266 1594.1 223015 159.97 21126 30:10 178 80 0.06102 1636.9 2292.5 160.72 21.07 29.86 181 89 ninsgu71479°4 -9959'0 141 aR 909R 99°79 aa 84 0.05800 1721.7 2411.4 162.17 20.93 29.63 185 8§ 0.05661 1763.9 2470.6 162.87 20.90 29.57 188 88 01055288061 25297 62185 20188 29183380 90 0.05401 1848.2 2588.7 164.21 20.87 29.50 192 92 0.05281 18902 2647.7 164.86 20.87 29.47 194 9% (0.05165 1932.2 2706.6 165.50 20.86 29.45 197 96 0.05055 1974.2 2765.5 166.12 20.86 29.43 199 98 0.04949 2016.2 2824.3 166.72 20.85 29.41 201 100 0.04848 2058.1 2883.1 167.32 20.85 29.40 203 3020104751 21001029419 167190 20185 29.98 205 10s 0104658 2141.9 3000.7 168.47 20.84 29.37 207 106 0.04568 2183.8 3059.4 169.03 20.84 29.36 © 209 iv Uivawoe 222317 S118] 409138 20.64 23133 aa M0 0.06399 2267.6 3176.8 170.12 20.84 29.34 213 112 070432023094 3235.4 170.64 20.84 29.3225 4140108243 2351.3 3294.1 171116 20.83 29.32 217 116 0.04168 2393.1 3952.7 171.67 20.83 29.31 219 118 004097 2434.9 3411.3 172117 20.83 29.30 221 120 0.04027 2476-7 3469-9 172.67 20.83 29.29 223 122 0703961231875 35287517535 20:83 29:28 225 124 003896 2560.3 3587.0 173.63 20.83 29.27 «227 126 0.03833 2602.1 3645.6 174.09 20.82 29.27 228 128 0103773264319 37061 174.55 20.82 29.26 © 230 1300103714 2685.6 3762.6 175.01 20.82 29.25 232 1320103657 272774 3821.1 175.46 20.82 29.25 234 134 0103602276911 3879.6 175.89 20.82 29.24 = 236 136 0.03549 2810.9 3938.1 176.33 20.82 29.26 237 138 0103497 2852.6 3996.6 | 176.75 20.82 29.23 239 MA A nakum ADL LOSSO 9974890182 29123 Da 142 0.03397 2936.1 4113.5 177.59 20.81 29.22 243 144 0703350297718 4171.9 178.00 20.81 29.22, 2h 1s 0.03304 2019.8 4230.4 178.40 20.81 79.7228 148 0.03259 3061.2 4288.8 178.80 20.81 29.21 248 150 0103215 3103.0 4347.2 179119 © 20.81 29.21 249 155 003110 3207.2 44932 180.15 20.81 29.20 254 120 ogo 2aiz.4 4690.2 de1l08 © 20.81 ap.19 as «Phys. Chom. Ret. Data, Vol 15, No.2, 1886‘THERMODYNAMIC PROPERTIES OF NITROGEN 803 Table 22. Thermodynamic properties of nitrogenContinued ‘Temperature Density Internal Enthalpy Entropy Cy C, Velocity Energy of Sound K mol/dn? J/nol. —J/mol.--J/mol K J/mol K J/mol K —/s 165 0.02921 3415.6 4785.2 181.97 20.81 29.19 262 a0 O.o7R34 351918 «4931.1 182.85 20.81 29.18 266 15 0.02753 3624.0 $0770 183.69 20.81 29.18 270 180 0.02676 3728.2 5222.8 184.51 20.80 29.17 273 185 0,02604 3832.3 5368.7 185.31 20.80 29.17 277 190 0.02535 3936.4 5514.5 186.09 20.80 29.16 281 195 0.02470 4040.6 $660.3 186.85 29:36 285 200 0.02408 4144.7 5806.1 187.59 29:16 288 210 olozz99 495819 Goa7.7 309101 29135 20s 220 0.02188 © 4561:1 6389.1 190.36 29:15 302 230 0.02093 4769.2 6680.6 191.66 29.16 309 200 bl02003 497718 997210 192.90 zol1e bie 250 0.01925 $185.5 7263.4 194.09 29.16 322 260 0.01851 $393.6 7554.8 195.23 29.16 329 270 0.01782 5601.8 7846.2 196.33 29.14 335 280 0.01718 $809.9 8137.6 197.39 29.14 341 290 0.01659 6018.1 8429.0 198.41 2 29.14 347 300 0.01604 6226.3 8720.4 199.40 20.81 29-14 353, 310 001552 643415 9011.8 200-36 = Z0.8Z 29.15, 339 320 0.01503 6642.8 9303.3 201.28 20.82 29.15, 365 330 0.01458 6851.1 9594.9 202.18 20.83 29.16 370 340 0101415 7059'6 9886.5 203.05 20.84 © 29.17 376 350 0101375 7268.1 10178. 203-90 20.85 29.18 3a1 360, 0.01336 7476.7 10470, 206.72 © 20.87 29.19 387 370 0101300 7685.5 10762, 205.52 20.88 + 29.20 392 380 0.01266 894.4 11054. 206.30 20.90 29.22, 397 390 0.01233 8103.5 11346. 207.06 20.91 29.24 402 400 0.01203 8312-8 11639. 207-80 20.94 29.26 407 420 Olo1145 873211 12225. 209123 20:98 ©2930, 417 440 0.01093 9152.4 12811. 210.58 21.04 © 29.36 427 480 0.01002 9996.8 13988. 213.15 21.18 29.50, 446 500 0.00962, 10621. 14579. 214.36 21.27 29159 454, 520 0.00925 10848. «15172. 215.52 29.68 463 510 olnngas 12276. 15366. 216-64 20178 132 560 0.00859 11706. 16363. 217.73 21.57 29.88 480 580 0.00829 12139. 16962. 218-78 21-68 + 30.00 488 00 oloos0a 2579. 17569. 19.00 © 21.60 30.32 496 620 0.00776 13010. 18166. 220.78 21.92 30.24 504 640 0.00752 13450. 18772. 221.75 «22.05 «30.36 512 660 0.00729 19892. 19381. 222.68 30.49 519 680 000707 14337. 19992. 223.60 30.62 526 700 0.00687 14785. 20606. 224.48 30.76 534, 720 0.00668 15235. 21222. 225.35 30:89, 541 740 0.00850 15688. 21841. 226.20 3103 348 4: Phys. Chem. Ref. Data, Vol 16, No.2, 1886JACOBSEN, STEWART, AND JAHANGIRI Table 22, Thermodynamic properties of nitrogen-Continued Temperature pensity Internal Enthelpy Entropy Gy, Sp Velocity Energy of Sound K mol/én? J/mol J/mol- J/mol K J/mol K J/mol K m/s. 760 0.00633 16143. 22463. 227.03 22.85 51.16 555 780 0.00617 16602: 23088. 227.86 22:98 31.30 562, 200 0.00601 17063: ag735. BeoLce 39:12 Bales 360 850 0.00566 18227. 25296. 230.55 23.45 31177585, 900 0.00534 19408. 26892. 232.38 «23.78 «32.0961 930 0.00506 20605. 28505. 296,12 26.09 32.4016, 1000 0.00481 21817. 30132. 235779 24.38 32.70 631 1050 0.00458 23043. 31774. 237.39 24.65 32.98 646 1100 0.00437 24283. «33430. 238.93 241933324 660 1130 .00418 25536. 35098. Za0.42 25.18 3349 1200 0.00401 26800. 36779. 241.85 25.41 33.72 688 1250 0.00385 28076. 38471. 24312325163 «33.94 701 1sou —U.uu370 29508! UOI7S! Fae lSe 25183 5S TG 1350 0.00356 30660. 41885. 245.86 26.03 34134 727 1400 200366 31965. 43607, 247.11 26.20 34.52 TO 1450 0.00332 33280. 45337. 248.32 26.37 34.69 752 1500 0.00321 34802. 47075. 249150 26.53 34.84 765 1550 0.00310 35833. 48821. 250.65 26.68 34.9977 1600 0.00301 37270. $0574. 251.76 26.81 35.13 789 1650 0.00292 38614. 52334. 252/84 26:94 35126 BOL 1700 0.00283 39964. $4100. 253.90 27.07 35.38 812, 1750 0.00275 41320. $5872. 2541922718 35150824 1800 0.00267 42682. 57649. 255.82 27129 35.60 835, 1850 0.00260 44049. $9432. 256.90 27.38 35.70 BMS 1900 0.00253 45421. 61220. 257.86 «2714935180857 1950 0.00247 46798. 63012. 258.79 27.58 35.89 868, 2000 0.00261 48179. 64809. 25970 2765 «35.98 «89 21.048 30.918 30.608, 30.296 29.981 29.663, 29.476 o.i0282 0.10049 0.09752 viusary 9.09224 0.08984 ~aoae. 24180. ~4067 =3954. 3841. 3728 -3662. isso: 1488. 41537. 1627. 1670. 4: Phys. Chem. Re. Data, Vol. 16, No.2, 1086 0.06 MPa Isobar ° 68. 10, 72. 73: 15. 76 238! 154. 155. 437. 357. 88 64 37 06 69 28 19 32 73 62 43 23 98 31.30 31.22 31.03, 30:84 30.64 30.46 30.33, bsi7e 24.58 22185 21.48 21:23 56.56 56.49 56.39 56.39 56.46 56.59 56.70 36132 34.78 32.46 94.29 30.60 30.23, 1022 1010 983, 958 936 910 896 rt 1% a7 180 182‘THERMODYNAMIC PROPERTIES OF NITROGEN Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy ©, Velocity 3 Energy of Sound K nol/éu? J/mol J/mol_~=-J/mol K J/mol K J/mol K m/s 84 0.08758 1713.6 2398.7 158.71 21.09 30.02 185 86 0108523 1756.2 245R& «1594Y 1.012988 187 88 0.08339 1798.8 2518.2 160.10 20.96 29.79 189 90 0108145 1841.1 2577.8 160.76 20.93 29.73 192 92 0107961 1883.5 2637.2. 161.42 20.91 29.68 194 94 0.07785 1925.7 2696.5 162.06 20.90 29.64 196 96 0.07616 1967.9 2755.7 162.68 20.89 29.61 198 98 0.07455 2010.1 2814.9 163.29 20.89 29.58 200 200 Olo7301 203212207811 163109 20.00 29.55 209 102 0.07153 2096.4 © 2933.1 164.47 20.88 29.53 205 104 0.07011 2136.4 2992.2 165.04 20.87 29.51 207 tue. UiveB/> Zuvels SuD4'2 de> ol 2018729109 209 108 0.06745 2220.5 3110.1. 166.16 20.87 29.47 211 310 0.06619 2262.5 3169.1 166.70 20.86 29.45 213, uz 0.06498 2304.5 3228.0 167.23 20.86 29.44 215 1g 0.06381 2346.5 3286.8 167.75 20.86 29.42 27 16 0.06268 2388.5 3345.6 168.26 20.85 29.41 219 118 0.06160 2430.4 3404-5 168.76 20.85 29.40 221 120 0.06055 24723 3463.2 169.26 20.85 29.38 223 122 0.05954 © 2514.3 3522.0 169.74 20.85 29.37 226 124, 0.05856 2556.2 3580.7 170.22, 20.84 29.36 226 126 0105761 259810 3639.4 170.69 20.84 29.35 228 128 0.05670 2639.9 3698.1 171.15 20.86 29.34 230 130 005581 2681.8 3756.8 171.61 20.86 29.33 232 132 0105495 2723.6 3815.4 172.06 20.86 29.32 234 134 0.05412 2765.5 3874.1. 172.50 20.83 29.31 235 136 0.05331 2807.3 3932.7 172.93 20.83 29.31 237 138 0105253 2R49'1 399113173136 201A 79130 239 140 0.05177 2890.9 4049.9 173.78 20.83 29.29 21 142 0.05103 2932.7 4108.5 174.20 20.83 29.28 242 ak 0.05091 2074.5 4167.0 174.60 20.09 9.28 ann 146 0.06962 3016.3 4225.6 175.01 20.82 29.27 246 148 0.06894 3058.1 428411 175.41 20.82 29.27 248 150 0.04828 3099.8 4342.7 175.80 20.82 29.26 249 as 0104670 320413 4400.9 «176.76 «201822125 259 160 0.04523 3308.6 4635.1. 177.69 20.82 29.24 258 165 0.04385 341310 4781.3 178.59 20.81 29.23 262 170 o0az55 3517.3 4927.8 179146 20181-29122 266 175 0.04132 3621/5 $073.5 180.31 20.81 29.21 269 180 0104017 3725'8 5219.5 181.13 20.81 29.20 273 105 0.03908 330.0 5365.5 181.93 20.81 29.20 277 130 0103804 3934.3 5511.5 182.71 20.81 29.19 281 195, 0.03706 4038.5 $657.4 183.47 20.81 29.19 285 200 0.03613 4162.7 5803.4 184.20 20.81 29.18 288 210 Ol034u0 435110 0951185163 2ULBD 2917 > 805 4. Phys. Chem. ef, Oata, Vo. 15, No. 2, 1986806 JACOBSEN, STEWART, AND JAHANGIRL Table 22. Thermodynamic properties of nitrogen-Continued ‘Temperature Density Internal Enchalpy Entropy Cy cp Velocity Energy of Sound K mol/én? 3/mol S/nol_--J/aol K J/mol K J/mol K m/s 20 0.03283 4559.3 6386.8 186.98 20.80 29.17 302 230 0.03140 4767.6 6678.5 188.28 20.80 29.16 309 240 003008 497518 6970.1 189.52 20:80 29.16 316 250 0.02888 5184.0 7261.6 190.71 20.80 29.15 322, 260 0.02777 5392.2 7553.1 191.86 20.80 29.15 329 270 0.02674 5600.4 7044.6 192.96 20.01 28.13 995 280 0.02578 5808.7 8136.1 194.02 20.81 29.15 3a 290 0.02489 6016-9 8427.6 195.04 20.81 29.15 347 300 0102406 6225.1 8719.1 196.03 20.81 29.15 353, 310 0102828 6433.4 9010.7 196.98 20.82 .29.16 353 320 0.02255 6641.7 9302.3 197.91 20.83 29.16 365 330 0.02187 6850.1 9593.9 198.81 20.83 29.17 370 340° ULU21Z2 705816 8BS.6 199LeS 20184 29.17 376 350, 0.02062 7267-2 10177. 200.52 20.85 28.18 381 360 0.02004 7475/8 10469. 201.35 20.87 29.20 387 370 0.01950 7684.6 10761. 202.15 20.88 29.21 392 380 0101899 7893'6 11053. 202.92 20.90 29.22 397, 390 0101850 8102.7 11346. 203.68 20.92 29.26 40a 4000101806 8312.0 11638. 204.42 20.9% 29.26 407, 420 OL01718 87311312224. 205185 20:98 2931 417 460 0.01640 9151.7 2812. 207.22 21.04 29.37 427 460 0101568 9573.2 13399. 208.52 21.11 29.43 436 480 0101503 9996.2 13988. 209.78 © 21.18 29.50 446 500 0.01643 10621. 14579. 210.98 © 21.27 29.59 456 520 0.01387 10847. «15172. 212115 21.36 29.68, 463 540 0.01336 11275. 15766. 213.27 21.46 29.78 472 560 0.01288 11706. 16363. 21413521157 29.89, 480 580 0.01244 12138. 16962. 215.40 21168 30.00 488 600 0.01202 12573. 17563. 216.42 21180 30.12, 196 620 O.01164 13010. 18166. 217.41 21192 30.24 504 640 0.01127 13450. 18772. 218.38 22.05 30.36 siz 60 0101009 igea2: — ipa03, 2991 aalle 3049, Bi 680 0.01061 14337. 19992. 220122 22131 30.63 527 700 0.01031 14784. 20606. 221/11 22.44 30.76 534 720 0.01002 15235. 21222, «221198 +2158 30.89. Bal 740 0.00975 15688, 21842, 222.83 22.71 31.03 548 760 0.00949 16143. 22466. 223.66 © 22/85 31.17 555 780 100925 16602. 23088. 224.47 22.99 31.30 562 euu Vive iyues) 238) Zusiae 251i Su laa 380) 850 0.00849 18227. 25296. 227.18 © 23.45 31.77 585 900 0.00802 19408. 26892. 229.01 23.78 32.09 601 30 000759 20803! 28303! 230175 24109 340 ele 1000 0.00721 21817. 30133. 232.42 24.38 32.70 631 1050 0.00687 23043. 31775. 234.02 24.66 © 32.98 646 1100 0.00656 24283. 33430. 235.56 24.93 33.26 660 “Phys. Chem, Ret Data, Vo. 16,No. 2, 1886‘THERMODYNAMIC PROPERTIES OF NITROGEN 807 Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy ¢, Cy Velocity Energy of Sound Kk mol/dn? J/mol J/mol_~-J/mol K J/mol K J/mol K m/s 1150 0.00627 25535. 35099. 237.06 25.18 33.49 67% 1200 0.00601 26800. 36779. 238.48 25.41 33.73 688 1250 0:00577 28076. 38471. 239.86 25.63 33.9% 701 1300 0:00555 29363. 40173. 241.19 25.83 34.15 714 1350 0.00534 30659. 41886. 242.48 26.03 34.34 727 1400 0.00515 31965. 43607. 243.7% 20.20 34.52 s40 1450 0:00498 33280. 45337. 244.95 26.37 34.69 752 1500 0:00481 34602. 47076. 246.13 26.53 34.84 765 1550 0.00466 35932. 48822. 247.27 26.68 34.99 77 1600 000451 37270: 50575. 248.39 26181 35113 789 1650 0.00437 38614. 52934. 249.47 26.94 35.26 801 1700 900424 39964. $4100. 250.52 27:07 35.38 a12 1750 0.00432 41320: 55872. 251.55 27118 35.30 824 1800 0.00401. 42682. 57650. 252.55 27.29 35.60 835 1850 0.00390 44049. $9433. 253.53 27.39 35.70 846 1900 0.00380 45421 61220. 254.48 27.49 35.80 857 1950 0.00370 46798 © 63012. 255.41 27.58 35.89 868 2000 0.00361 48179. 64809. 256.32 27.66 35.98 879 0.08 MPa Isobar % 63.16 31,049 4228.1 4225.5 67.88 31.30 56.56 1022 64 30.919 4180.5 -4177.9 68.63 31.22 56.48 1010 66 30.609 -4067:6 4065.0. 70.37 31.03 56.39 984 66 30:297 “9954.9 “9952.3 72105 30.84 56.90 950 70 291983 -3842.1 -3839.6 73.69 30.64 56.45 934 n 29.665 +3729.1 -3726.4 75.28 30.44 56.59 910 rs 231382 “301318 =3013.0 70103 3u:za 3870 207 * 75.40 29.114 -3536.3 -3533.5 77.90 30.10 56.95 a7 * 75.40 0.13268 1503.2 2106.1 152.69 26.04 36.99 i 76 0113143 151913 2128.0 152.98. 25.18 35.78 a2 78 0.12755 1569.4 2196.6 153.88 23.20 33.13 7s 80 [12399 1616.1 2261.3 154.69 22.17 31.73 79 82 0.12068 1661.0 © 2324.0 155.47. 21.63 30.96 181 Ba 0.11756 1704:9 2385.4 156.21 21.33 30.53 184 86 0.11462 1748.2 2446.2 136.92 21.16 30.26 186 88 0.11184 1791.2 2506.5 157.62 21.07 30.10 189 30 0:30820 183410 2366.6 | 158129 21/01 39199 ist 92 0.10668 1876.6 2626.5 158.95 20.98 29.91 193, 34 0.10429 191911 2686.2 159.59 20.95 29.84 196 96 10200 1961.6 . 2745.9 140.97 9.94 99174 yan 98 0.09982 2004.0 2805.4 160.83 20.93 29.75 200 100 0.09773 2046.3 2864.9 161.43 20:92 29.71 202 4. Phys. Chem. Ref. Data, Vo. 15, No.2, 1886,JACOBSEN, STEWART, AND JAHANGIRI Table 22. Thermodynamic properties of nitrogenContinued Temperature Deusity Tnterwel Euthalpy Entropy ©, Velocity Energy of Sound K mol/dn? J/mol —J/mol_-—-J/mol K J/mol K J/mol K — w/s 102 0.09573 2088.6 2924.3 162.02 20.91 29.68 208 30s 0.09382 2130.9 2983.6 162-60 20.90 29.65 206 306 0.09198 2175.1 301219 163-16 20:90 29162208 108 0.09021 2215.3 3102.1 163.72 20.89 29.60 210 110 0.08851 2257.5 3161.3 164.26 20.89 29.58 212 112 0.0608 2299.6 9220.4 164.79 20.08 29.5528 116 0108531 234117327915 165.32 Hl 29:53 216 1160108379 2383.8 3338-6 165.83 aotent 1 1218 118008233 2425.9 3397.6 166.33 20.87 29.50 220 120 Ulususz 240719 Saols lesl83 lay 29188 dae 122 0,07956 2510.0 3515.5 167.32 20.86 29.46 226 124 0.07825 2552-0 3574.4 167-80 20.86 29.45 226 12e —0107097 239410 363313 168127 20862910328 128 0.07574 2635.9 369211 168.73 20.86 29.42 230, 130 0.07455 267719375110 169119 20.85 29.41 252 132 (0.07340 2719.8 3809.8 169.63 20.85 29.40 233 134 0.07228 2761.8 3868.5 170.08 20.85 29.39 235 336 0.07120 2803.7 39273 170.51 20.85 29137237 138 0.07015 2845.6 3986.0 170.96 20.84 © 29.36 239 WO 0.06913 2887:5 ous 171136 20.84 29135 2a 142 0.06816 2929.3 4103.5 171.78 20.86 29.35 242. we 006717297112 416211172119 2018k 2934 146 0.06624 3023.1 4220.8 172.59 20-86 29.3326 143006533 3054.9 427915 172.99 20.83 29.32 247 150006445 3096.7 4338-1 173.39 20.83 29.31 249 155 0.06234 3201.3 4486.6 174.35 20.83 29.30 253 160 0.06037 3305.8 4631-1 175.28, 29:28 257 165 0.05851 3410.3 4777.4 176.18 29:27 261 3700108678 3514:7 4923.8 177.05, 29126 265 175 0.05514 3619.1 5070.0 177.90 29:25 268 180 0.05359 3723.4 5216.2 178.72 29.26 273 3630103239 302710 3962.4 179152 2912327? 390 0.05075 3932:1 5508.5 180.30, 29.22 281 195 0.04944 4036-4 5654.6 181.06, 29:21 284 200 0.04819 4140.6 5800.6 181.80 29.21 (288 210 0.04588 4349.1 6092.6 183.23 20.81 29.20 295 220 006379 4557.5 6384.5 186.58 20.81 29:19 302 230 «0.04188 4765.9 6676.3 185.88 20.81 29:18 309 260 0104012497412 GHOBL1 B12 BSL BILAy 518 250 003851518215 7259.8 188.31 20.81 29:17 322 260 0.03703 $390.8 7551.5 189.46 20.81 29.16 329 270 (0.03565 559911 7843.1 190.56 20.81 29.16 335 280 0.03437 5807.4 8134.7 191.62 20.81 29.16 341 290 0.03319 6015.7 8426.3 192.64 20.81 29.16 347 300 0.03208 6224.0 8717.9 193.63 20.82 29:16 353 4.Phy. Chem, Ret. Dats, Vo. 15, No.2, 1988‘THERMODYNAMIC PROPERTIES OF NITROGEN Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy ©, Velocity Energy of Sound K nol/da? J/nol —3/nol_-J/mol K J/mol K J/mol K —a/s 310 0.03104 6432.3 9009.5 194.59 20.82 29.16 359 Bon. p'nano? kann? aan tes si 20822817 36s 330 0.02916 6849.1 9592.9 196.41 20.83 29.17 370 340 0.02830 7057.6 © 9884.7 197.28 20.84 29.18, 376 350 0.02749 7266-2 10177. 198.13 20.85 29:19 381 360 0.02672 7474.9 10468. 198.95 20.87 29.20 387 370 0.02600 768318 10761. 199.75 20.88 29.21 392 380 0.02532 7892.8 11053. 200153 20.90 29123, 397, 350 0.02467 0101911945. 201129 20.92 29.25 402 400 0.02405 8311.3 11638. 202.03 20.94 29.27 407 420 0.02290 8730.6 12224. 203.46 20.98 29.31 a7 460 0.02091 9572.6 13398. 20613 21.11 29.43, 436 480 0.02004 9995.6 13988. 207.39 21118 29.51, 446 500, 0101924 10420. 14579. 208.59 21.27 29.59, 455 520 0.01850 10847, 15171. 209.75 21.36 29.68 463 540 0.01781 11275: 210788 21ke 29.78 472 560 0.01718 11705. 211.96 21157 29.89, 480 500 0.01658 12138. zisior — zil68 30,00 488 600 0101603 12572, 214.03 21.80 30.12 496 620 0.01551 13010. 215.02 21.92 30.24 504 eau 001303 13449! 21598 22105 30.37 512 660, 0.01457 13892 216.92 22:18 30.49, 519 680 0.01415 14336. 217.83 2213130163, 527 700° © 0.01374 14784. 218.72 22-44 30.76 534 720 0.01336 15234. 219.59 22.58 30.90 san 740 0.01300 15687 220.44 © 22.71 31.03, 548 760 0.01266 16143) 221.27 32.85 31.17 555, 780 0.01233 1660 222:08 2218831130 562 800 0.01202 17062. 222'87 23.12 31146 568, 850 0.01132 18227. 224.79 23.45 31.77 385 900 0.01069 19408. 226.61 23:78 32109 601 950 0.01013 20604. 228.36 24.09 32.40 616 1000 0.00962 21816. 230.03 24.38 32.70 631 1050 0.00916 23043) 251163 24.66 39.98 46 1100 0.00874 24283. 233.17 24.93 33.24 660 1150 0.00836 25535. 234.65 25:18 33.49 674 1200 annan? aaa Dena 98423373 a8 1250 0.00770 28076. - 237.46 25.63 33.94 701, 1300 0.00740 29363. 40174. 238.80 25.83 34.15 ns rasn 900713 aso. 2886. 240.00 26.09 24.34 727 1400 0.00687 31965. 43608. 241.36 26.20 34.52 7460 1450 0.00663 33280. 45338. 242156 26.37 34.69 753, 1500 0.00641 34602. 47076. 243.74 26.53 34.84 765 1550 0.00621 35932. 48822. 2h4 88 26.68 34.99 m7 809 “4. Phys. Chor, Ret. Data Vol. 15, No.2, 1986810 JACOBSEN, STEWART, AND JAHANGIRI Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthslpy Entropy G, Gp_—‘Velocity Enerey of Sound K mol/én? — J/mol J/mol J/mol K J/mol K J/mol K m/s 3600 0.00601. 37270. $0575. 246.00 26.81 35.13 789, 1650 0.00583 38614. $2535. 247108 26194 35.26 01 1700 0.00566 39964. Saio1. 2481132707 35138 la 1750 0.00550 41320, $5873. 249162718 35130, Bae 1800 0.00536 42682, 57650. 250.16 27.29 «35.60 «835 1850 0.00520 seo4y. s94ss. 251.18 27.99 35.70 846 1800 0.00506 542i. © G2z1. «252109 «27149 35.80 8S 1950 0.00493 46798. 63013. 253.02 «27158 35.89 868 2000 0.00481 48179 64810. © 253.93 27.66 33.98 «B78 0.10 MPa Iscbar * 63.16 31.050 4228.1 -4224.8 67.88 31.30 56.55 1022, 64 30.920 -4180.7 -4177.4 68.63 31.22 56.48 1010 66 30/611 -una7'R -unqn'a 90137102 «56.30 ban 68 30.299 73955.1 =3951.8 72.05 30.84 56.38, 958 70 29.984 -3842.3 3839.0 73.68 30.64 56.45 934 72 29.666 -3729.4 3726.0 75.28 30.46 56.58 910 % 29.344 -3616.0 -3612.6 76.83 30.24 56.78 887 76 29.017 -3502.3 -3498.8 © 78.35 30.06 57.02 865, *77.26 28.813 343117 3428.2 79.27 29.91 57.20 851 * 77:24 0.16208 1532.4 214610 151.4% © 26.26 37.53 172 78 0.16105 1553.1 2174.0 151.80 25.13 35.99 174, 80 0.15634 1603/5 2243.1 152.67 23.23 33.38 7 82 0115201 1650.3 2308-3 153.48 22.23 31.98 180 84 0114798 1695.7 237114 154.24 21.68 31.19 183, 86 0.14420 1739.8 2433.3 154.97 21.38 30.76 186 88 0.16063 1783.4 2494.5 159.67 21.21 30.46 188 30 0.13725 1826.6 2555.2 156.35 21.11 30.28 191 92 0.13405 186916 2615.6 157.02 21.05 30.15 193 34 0113099 191215 2675.9 157.67 21:01 30.06 195 56 0:12809 195512 273519 158130 20:98 29.99 197 98 0.12531 1997.8 2795.8 158.92 20.97 29.93 200 100 0.12266 2040.4 2855.6 159152 20.95 29.88 202 02 0:12012 2082:9 291514 16011 20:94 29.84 204 104 0111769 212513 2975.0 160.69 20.93 29.80 206 106 0111536 2167.7 3034.6 161.26 20.93 29.76 208 108 0.11313 2210.1 3094.0 161.81 20.92, 29.73 210 110 0111098 2252.4 3153.5 162136 20.91 29.70 212 uz 0.10891 2294.7 3212.8 162.89 20.91 29.67 214 14 010693 2336.9 3272/2 163.42 20.90 2965 216 16 0.10501 2379.2 3331.4 163.93 20.90 29.62 218 us 0.10317 2421.4 3390.6 164.4% 20.89 29.60 220 4 Phys. Chem. Ret, Data, Vol. 15, No.2, 1906‘THERMODYNAMIC PROPERTIES OF NITROGEN ait Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy 6, Weloctey Energy of Soun K mol/én? J/nol — J/mol._- J/mol K J/mol K J/nol K m/s 120 0.10138 2463.5 3449.8 164.94 20.89 29,58 222 122 0.09967 2505.7 3509.0 165.43 20.88 © 29.56, 226 124 0:09801 2547.8 3568.0 165.91 20.88 29.54 226 126 0109641 2589.9 3627.1 166.38 20.88 29.52 228 128 0.09486 2631.9 3686.1 166.84 20.87 29.50, 230 130 0.09336 2674.0 3745.1 167.30 20.87 29.49, 231 132 0.09191 2716.0 3804.1 167.75 20:87 29.47, 233, 134 0.09050 2758.0 3863.0 168.19 20.86 29.46, 235 136 n’naaie Ronn 3091" KR KAN 38 23 138 0.08782 2842.0 3980.8 169.06 20.86 29. 239 140 0.08653 2884.0 4039.6 169.48 20.85 29.42 240 yea Olo8sao 202519 4008.% 169190 Boles oad bea 1a 0.08608 2967.9 4157-2 170.31 20:85 29.40 26h 146. 0.08290 3009-8 © 4216-0 170.72 20.85 29.39 246 148 0.08176 3051.7 42748 171.12 20.84 29.38 247 150 0.08065 3093.6 4333.5 171.51 20.84 29.37 249 155 0.07800 3198-3 4480-3 172.47 20.86 29.35. 253, 160 0.07553 3303-0 4627-0 173.40 20.83 29.33 257 165 0.07321 3407-6 4773.6 174.91 20.83 29.31 261 170 0.07102 3512-1 4920-1 175.18 20.83 29.29 265 175 0.06897 3616.6 $066.5 176.03 20.82 29.28 269 180 0106703 372111 3212.9 178.88 20.82 29.27 zis 185 0.06520 382515 5359/2 177.66 20.82 29.26 277 190 0.06347 3929.9 5505.5 178.44 © 20.82 29.25 281 195 0.06183 4034.3 5651.7 179.20 20.82 29.24 284 200 0.06027 4138.6 5797.9 179.9% 20.81 29.23 288 210 0.05738 4347-2 609011 181.36 20.81 29.22 295, 220 0.05475 4555.8 6382-2 182.72 20.81 29.21 302 230 0.05236 4764.2 6674.2 184.02 20.81 2920 303, 240 0105016 4972.7 6966.1 185.26 20.81 29.19 316 250 0.06815 5181.1 7258.0 186.45 20.81 29.18 322 260 004629 5389:4 © 7549'8 187.60 201812918 323 270 0.00457 5597-8 7841.5 188.70 20.81 29.17 335 280 0.04297 5806-1 8133.2 189.76 20.81 29.17 341 290 0.06149 601415 8425.0 190.78 DN'RT— 94°17 aur 300 0.04010 6222.8 8716.7 191.77 20.82 29.17 353 310 0.03880 6431-2 9008-4 192.73 20.82 29.17 359 490 fanaa Read’ © ann’ 1a2'6e © 20183018 365, 330 0.03645 6848.1 9591.9 194.55 20.86 29.18 370 340 0.03537 7056.7 9883.7 195.42 20.84 29.19 376 350 0.03436 7265.3 10176, 196.27 20.86 29.20 381 360 0103360 747470 10468. 197.09 20.87 29.21 387 370, 0.03250 7682-9 10760. 197.89 20.88 29.22 392 380 0.03164 7891-9 11052. 198.67 20.90 29.23 397 390, 0.03089 101-1 11345. 199.43 20.92 29.25 402 “4. Phys. Chem. Ref. Data, Vol. 15, No.2, 1906JACOBSEN, STEWART, AND JAHANGIRI ynamie properties of nitrogen-Continued K 400 420 440 460 480 s00 520 540 560 600 620, 620. 660. 650 700 720 740 760 800 850 300, 950, 1000 1030 1100 1150 1200 120 1300 1350 1400 1450 1500 1550 1600 1650 1700 1750 1800 1850 1900 3950 2000 pensicy mol /aa? 03006 02863, 2733 202614 02505 02408 02312 02226 02147 02004 01939 ‘01878 01822 01768 01737 01670 01625 01582 01382 01503 o1ba4 01336 01266 01202 ons 01093 01046 01002 uosez ° ° 0 ° v 00925 0891 "00859 "00829 00802 00778 00752 00729 100707 00687 oos6s, 00650 00633 ‘00617 ‘00601 Tavernel Energy J/nol 8310.5 8729.9 91503 9572.0 9995.0 20420 10846. 11274. 11705. 32572. 13009. 33649) 33891. 14336. 14704. 15234. 15687. 16143 e001 17062. 18227; 19407! 20604. 21816. 23063. 24282. 25535. 26800 zevre. 29363. 30659 31965! 35280 34602. 35932. 37270. 38614. 39964. 31320: 42682. 44049) 45421. 46798. 48179) 4: Phys. Chem. Re. Data, VoL. 15, No.2, 1986 Euthalpy 3/nol 11637 12223. vain 13398 13987 14578 35171, 15766. 16363. 17563. 18166 is772. 19381. 19992. 20606. 21293. 21842. 22666. 23716. 25296 26893. 28506. 30133. ou77s. 33431. 35100. 36780. Seas2) 40174. 41887. 43008. 45338. 47077. 48823. 50576. 52336. 54102. 35876. 57651 59436. 61221. 63014 64810. Entropy S/mol K J/nol K J/mol K 200. 201 202 204. 205. 206 207 209 210 22 213. 2ie 215 215. 216 27 218 219 221 222 224 226 228 29 231. 232 234. 239: 236 238. 239) 240 261 243. 24 245, 246 247. 248 249) 250 231 252 17 160 97 227 153 x 3 wy he f3 106, 198 87 173 138 et 202 193 16 130 7 17 31 80 123 ter 94 24 49 270 18 03 ub 122 28 30 31 128 224 7 108 a, 20.94 20:99 2104 2111 21118 o 29 29 29 29 29 29 29. 29 29. 30 30. 30. 30. 30. 30 30. 31. 31 a a1 32! 32 32. 32 33 33. 33. 33 34. 34 3a 34: 34 34. 35. 35. 35. 35. 35. 35 35. 35. 35 227 '32 7 46 131 59 8 78 89 2 26 37 50 63 76 90 3 Sy Velocity of Sound ws 408 a7 227 436 446 455 463 472 480 496 504 532 519, 527 334 5a1 548, 555 568, 585 601 616 631 646 660, 676 688 101 ns 737 140 753, 765 a7 739, 801 812 824 835 846 357 868 879‘THERMODYNAMIC PROPERTIES OF NITROGEN. 813 Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy , Velocity Enerey of Sound K nolan? J/nol J/mol._~—-S/mol K J/mol K J/mol K —w/s * 63.16 31.050 -4228.1 -4224.8 67.88 31.30 56.55 1022 6h 301920 “4180.7 -4177.4 «686331776 KR TOTO. 66 30.611 4067.9 4064.6 70.37 31.03 56.39 986 68 30.299 -3955.1 -3951.8 72.05 30.84 56.38 958 70 291984 --3842.4 -3839.0 73.68 30.64 56.45 934 2 29.666 -3729.4 -3726.0 75.28 30.44 56.58 910 % 291344 © -3616.1 -3612-6 76.83 30.24 56.78 887 76 291018 3502.3 -3498.8 78.35 30.04 57.02, 865 A799 20.798 7342318 “342al98 79195 29190 57-21 050 #77135 0.16497 1534.1 2148.3 151.36 26.27 37.56 172 78 0.16330 1551.9 2172.4 151.67 25.29 36.22 174, 20. Vli5e30 keoz9 © 2242:0 52-39 23:92 33.32, 477 82 0.15411 1649.7 2307-2 153.36 22.28 © 32.06, 180, 84 0115002 1695.0 2370.5 154.12 21.71 31.25, 183, 86 0.14618 173913 2432-4 154.85 21.40 30.77 186 88. 0.26255 1782.9 2493.7 155.56 21.22 30.49 188 90 0.13912 1826.1 2554.4 156.24 21.12 30.30 190 92 0113587 1869.2 2614.9 156.90 21.05 30.17 193 34 0113277 19120 2675.2 157.55 21:01 30.08 195, 96. 0112987 1954.7 2735.2 158.18 20.99 30.00 197 98 0.12701 1997.4 2795.2 158.80 20.97 29.94 200 100 0112432 204010 285510 159/41 20:96 2989, 202 102 0.12174 2082.5 2914.8 160.00 20.95 29.85, 206 104 0.11928 2124.9 2974.4 160.58 20.94 29.81 206 106 011692 2167.4 3034.0 161.14 20.93 29.77 208 108 0.11465 2209.7 3093.5 161.70. 20.92 29.74 210 110 0.11247 225211 3153.0 162.25 Fi 29.71 212 hg 110k 790K" «47199147 7R— NT HR ote 4 0.10836 2336.6 3271.7 163.31 20.90 29.65 216 116 0.10642 2378.8 3331.0. 163.82 20.90 29.63, 218 ae w.aokss 2421.2 9290.2 164.29 20.89 29.60 220 120 0.10275 2463.2 3449.4 164.82 20.89 29.58 222 122 0.10101 2505.4 3508.5 165.31 20.88 29156 226 124, 0.09933 2547.5 3567.6 165.79 20.88 29.54 226 1n6 009770 250916 3626.7 166.27 20.88 29152, 228 128 0.09613 2631.7 3685.7 166.73 20.87 29.51 230 130 0.09461 2673.7 3744.7 167.19 20.87 29.49, 231 a2 0109934 2715.8 © 3003.7 167.64 20.07 29140 233 134 0109171 2757.8 3862.6 168.08 20.86 29.46 235 136 009033 2799.8 3921.5 168.52 20.86 29.45 237 4 Phys. Chom. Ret. Dat, Vol 15, No.2, 1986en JACOBSEN, STEWART. AND JAHANGIRI Table 22, Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy Cy Velocity 5 Energy of Sound K mol/dn? J/mol —J/mol_—J/nol K J/mol K J/mol K m/s 138 0.08899 2841.8 3980.4 168.95 20.86 29.43 239 tho. 108760 e636 403013. 160.37 30.85 29.43 240 142 008643 2925.7 4098.1 169.79 20.85 29.41 242 144 0.08520 2967.7 4156/9 170.20 20:85 29.40 244 146 0.08401 3009.6 4215.7 170.61 20.85 29.39 246 148 0.08285 3051.5 4274.5 171.01 20.85 29.38 247 150 0.08173 3093.4 4933.2 171.40 20.84 29.37 249 155 0.07904 3198.1 4480.0 172.36 20.84 29.35 253 ae viuress 33uzi8— Wozblsty31z9 U8 29133 Bi 165 0.07418 3407-4 4773.3 174.20 20.83 29.31 261 170 0.07197 3511.9 4919.8 175.07 20.83 29.30 265 1, 0.00989 3616/4 5086.3 175192 20.83 29.28 269 180 0106782 3720.9 5212.7. 176.7 20.82 29.27 273, 185 0.06607 3825.3 5359.0 177.55 20.82 29.26 277 190 0.06431 3929.7 $505.3 178.33 20.82 29.25 281 195, 0.06265 4034.1 5651.5 179.09 20.82 29.24 286 200 0.06107 4138.5 5797.7 179.83 20.82 29.23 288 210 0.05814 4347.1 6089.9 181.25 20.81 29.22 295, 220 0:05548 455516 638211 182.61 20.81 29121 302 230 0.05305 4764.1 6674.1 183-91 20.81 29.20 309 240 .0S0R 4977.6 KOK. TASS 70.81 79.39 ne 250 0.06879 $181.0 7257.9 186.34 20.81 29.18 322 260 0.04690 5389.3 7549.7 187-49 20.81 29.18 329 270 0.04516 $597.7 7841.4 188.59 20.81 29-17 335 Pao. 04354 $0610 © 81931218 KS 0A 29-17 sar 290 0.06204 6014.4 8424.9 190.67 20.81 29.17 347 300 0.04063 6222.7 8716.6 191-66 20.82 29.17 353, 310 olozssa 23.1 00813 oalea 20182-20397 350 320, 0103809 6639.6 9300.0 193.55 20.83 29.18, 365 330 0.03693 6848-0 959118 194.44 © 20.84 © 29718 370 240 0.0354 7056.6 9883.7 195.31 20.8% 29.19, 376 380 0103482 7265.2 10176. 196.16 20.86 29.20 381 360 0103385 74740 10468. 196.98 20.87 29.21 387 370 0.03293 7682.9 10760. 197.78 20.88 29.22, 392 380 0.03206 7891. 11052, 198156 20.90 29.24 297 390 0.03124 8101.1 11344. 199.32 20.92 29.25 402 400 0:03046 8310.4 11637. 200.06 20.94 29.27 408 aay vivayul sivis Lass) Zuslay uly 29132 uy 440 0.02768 9150.3 12810. 202.86 21-04 29.37 427 460 0.02648 9571.9 13398. 204.17 21-11 29.44 437 480 0.02538 9995.0 13987. 205.42 21.18 29.51 446 500 0.02436 14578. 206.63 21.27 29.59 455 520 0.02343 15171. 207.79 21.36 29.69 463 340 0.02256 35766. 208-91 21746 29.78 472 560 0.02175 16363. 21000 21:57 29.89 480 ‘4. Phys. chem. et. Data, Vol. 15,No, 2.1986‘THERMODYNAMIC PROPERTIES OF NITROGEN 815 Table 22. Thermodynamic properties of nitrogen-Continued Tenperature Density Internal Enthalpy Entropy G, Cy Velectty Energy of Sound K mol/da> J/nol —J/mol_-— J/mol K J/mol K J/mol K m/s 580 0.02100 12137. 16962. 211.05 21.68 30.00 488 600 0.02030 12572, «17563. «2120721780 30.12 486 620 0.01983 13009. 1ei86. 2130621192 30.24 508 eho 0.01903 134u9 18772 2140222105 «30.37 512 660 0.01846 13891. «19381 214.95 22/18 30.50 519 680 0.01791 14336. 19992. 215.87 22.31 30.63 527 700 0.01740 14784. 20606. 216.76 © 22.bu 30.76 534 720 0.01692 15234. 21223. 217162 22158 30.9054 140 0.01646 | 15687, 21842. 218147 2217131103548 760 0.01603 16143: akee? «21930 23785311785 780 0.01562 16601. 23089. 220.11 22.99 31.30 562 800 010152317063. 23716. 390191 3.12 31 ak Sa 850 © 0.01433 18227. 25296. 292182 3:65 31.7785 900 0.01354 19407. 26893. 224.65 23.78 32.09 601 950 0.01282 20604. 28506. © 226.38 24.09 «32.4016 1000 0.01218 21816. 30133. 228.06 24.38 32.70 6a 1050 010116023043! 51775. 229166 24.66 32198 646 1100 0.01108 24282, 33431. 25120 24.93 33.24 660, 1150 010105825535’ 35100! 252169 aie 33.49 eh 1200 0.01015 26800: «36780. 234.12 25.41 «33.73 688 1250 0.00975 28076. 38472. 235.50 25.63 33.94 701 1300 010093739363. Lou74!a3ele © a8e3 Bells 714, 1350 0.00902 3065941887. 2381132603, 34134727, 1400 0.00870 31965. 43608. 239.38 26.20 34152, 740 1450 0,00840 33280. 45338. | 240.59 26.37 34169753, 1500 0.00812 34602. «47077, 261.77 26.53 34.84 765 1550 0.00786 35932. 48823. 242.92 26.68 34199777, 1600 0.00761 37270. 50576. 24u.03 26.82 35113789 1650 0100738 34618. 52336. 243111 26.94 33:28 BL 1700 0.00717 39964. 54102. 246.17 27.07 «35.38 B12 1750 0.00696 41320. 55874. 247.20 27.18 35.50 ge teou —Uroues/Gzosz—S7e5t! 2481202729 35180835, 1850 0.00659 44049, 59434. 249.17 27:39 35.70 B46, 1900 0.00641 45421; 61221. © 250.13. -27:49 35180857, 1950 0.00625 46798. 63014. 251108 27.58 35.89 «868 2000 © 0.00609 48179. 64810. 251.97 27.66 35.98 879 0.15 MPa Isobar * 63.17 31.051 -4228.1 -4223.2 67.88 «31.30 96.55 1029 64 301923 -4181'2 4176.3 68.62 31.22 $6.48 1011 66 30.614 -4068-4 -4063:5 7036 31.03 56.38, 984 68 30.302 -3955.7 3950.8 72.04 © 30.84 56.37 959 4 Phys. Chem, Ret. Data, Vol. 15, No.2, 1986816 JACOBSEN, STEWART, AND JAHANGIAL ‘Thermodynamic properties of nitrogen-Continued Table 22 Temperature Density K nol/én? 70 29.988 72 291670 7 29.022, 78281690 80 28.953 * 80.84 28.210 * 80.86 0.23713, 82 (0.23289 bs OleRos? 86 0.22000 80121425 50 0120885 92 0.20376 9% 0119895 yo u.ayasy 98 0119002 100 0.18588, 102 0118193, 10s (0117815, 106 0.17453, 108 0.17107 Ho 8:18793, 12 0.16486 116 o:16149, né 0.15855 18 0.13571, 120 0.15298 199 temas 126 0.14780 126 0.14535 toa alacaea 130 0:14069, 1320113847 1360113632 136 0.13424 1380113223, to 0.13027 is 812000, Was 012654 16 0.12075, 148 0112302, 1500112133, 150111732, 160 111356 Incernal Energy J/nol -3843.0 -3730) 73503. 3388. 3273, 73225. 1586. 1618 1116. 1762. 1807 1851. 1895. 193s 1982 2025. 2068. aul: 2156 2196. 2239 2282. 2324, 2367 2409: 2452. 2537. 2579. 2621 2666. 2706. 2768. 2790. 2833. 2875.3 2959.6 3001.7 3043.7 3085.8 3190/9 3295.9 4: Phys, Chem. Ret. Data, Vol 16, No.2, 1866 Enthalpy J/aol 3838. 33725. TaKit 73497. ~3383. -3268.. -3220 2219, 2262 2398. 2462 2325 2587 2643 zn. 2771. 2832 2892 2953 3013. 3073 3133 3193. 3253) 3313. 3373, 3432 3552. 3611. 3671 3730. 3789. 3849 3908 3967. 4026 14a 4204, 4263. 4322, 4469 4616. Entropy S/wol K S/mol K I/mol K 73 m5 78 79) a1 81 149) 149. 350. 151 352 a2. 353. 154. 154, 355. 155 156. 157 157 158 158. 159 139 160, 160: 161. 162. 162. 163 163. 164, 164, 165 165 166. 160) 166: 167 367 168, 169 169 68 127 32 34 82 28 138 a 270 36 32 106 "76 245 ar .1 138 199 159 118 76 32 87 aL ‘3 46 197 47 96 245 93 39 85 131 75 19 162 05 47 88 29 t68 £09 05 199 6, 30. 30. 30. 29 29. 29. 26 26. 23 22. ai. zu 2a ai a. aa 21. ai ai a 20 20 20 20 20. 20. 20: 20. 20. 20 20 20. 20. 20 20 20. 20 20. 20 20 65 45 ak 04 83 63 4 59 36 28 30 78 48 31 20 as 08 06 04, 02, 00 99 98. 97 96 95 95 9m 93 93 92 91 91 90, 90, 89 39 89 00 88 38 87 187 20: 20: 86 86 % 36.46 56.57 56196 57.01 57:30 57.65 57/81 38.58 36.28 33189 32.48 31.69 bulza 30:30, 30:69 30.56 30.42 30.33, 30.25 30.18 30.12 30:07 30:02 29.98 29.93 29.89 29.86 29.82 30°70 29.76 29.74 29:71 29.68 29.66 29.64 29.62 29.60 29.58 29136 29.55 29.53 29/51 29.50 29.47 29.44 Velocity of Sound n/s 936 ou 865 843 ean 312 175 177 100 183, 186 169 191 19h 196 198 201 203 205 207 209 au 213 215 217 219 22a 994 225 227 229 231 233 235. 236 238 240 ae 243 205 267 249 253 257‘THERMODYNAMIC PROPERTIES OF NITROGEN Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy Cy c, Velocity ‘Energy of Sound K mol/da? J/mol —J/mol_ Jmol K J/mol K 3/nol K —w/s. 165 0.11005 3400.8 4763.9 170.89 20.85 29.41 261 ta. Asne7e Ranke — arn a—-179"77—9n'RE_ 8a 26s 75, 0.10364 3610.4 5057.8 172.62 20.84 29.37 269, 180 0110071 3715.1 5204.6 173.45 20.84 29.35 273, 385 0.09794 3819-8 5351.3 174.26 20.83 29.33 277 190 0.09533 3924.4 5497.9 175.04 20.83 29.32 281 195 0.09285 4029.0 5644.5 175.80 20.83 29.31 284 200 0109050 4133.5 5791.0 176.54 20.83 29.29 288 210 ologeis 434215 6083-8 177197 «20.82 29127 295, 220 0.08215 4551.3 6376.4 179.33 20.82 29.25 302 230 0.07858 4760.1 6668.9 180.63 20.82 29.24 309 250 0.07225 3177.4 725315183107 20.81 29.22 322, 260 0.06946 5385.9 7545.6 184.21 20.81 29.21 329, 270 0.06687 $394.4 7837.6 185.32 20.81 29.20 335 280 0.06447 5803.0 8229.6 186.38 20.82 29.20 341 290 0.06224 6011.4 842116 187.40 20.82 29.19 347 300 0.06015 6219.9 5 188.39 20.82 29.19 353 310 005821 642815, 3189135 20.83 29119 333 320 0.05638 6637.0 4 190.28 20.83 29.20 365 330 0.05667 6845.6 9589.4 191.17 20.84 29.20 370 340 0103305 7034.2 986114 192109 20.85 2920 378 350 0.05154 7263.0 10173. 192.89 20.86 29.21 381 360 0.05010 7471-8 10466. 193.72 20.87 29.22 387 370 0.04875 7680.8 10758. 194.52 20.88 29.23 392 380 0.04746 7889.8 11050. 195.30 20.90 29.25 397 390 0.04624 8099.1 11343. 196.06 20.92 29.26 403 400 0.04508 83085 11636. 196.80 20.94 29.28 408, 420 0.00294 872811 12222. 198123 201992933 18 440 0.04098 9148.6 12809. 199.59 21/04 29.38 427 460 0.03920 9570.4 13397. 200.90 21.11 29.45 437 480 0.03756 9993.5 13987. 202115 21119 29:52 he 500 0.03606 10418. 14578. 203.36 21.27 29.60 455, 520 0.03467 10845. «15171. 204.52 21136 29.69 463, 540 0.03339 11273. «15766. 205.65 21.46 29.79 472 560 0.03220 11703. 16362. 206.73. 21.57 29.89 480 580 003109 12136. 16961, 207.78 21.68 30.01 488 600 0.03005 12571. 17563. «2oR’RO 91 !RO 3019 496 620 0:02908 13008. 18166. 209.79 21192 30.25, 504 640 0102817 13448. ©1873. 210.75 22.05 30.37 512 660, fh n9797 aren soar) Ka Rag sta 680 0.02651 14335. 19993. 212.60 22.31 30.63, 527 700 0102576 14783. 20606. 213.49 22-44 30.76 534 720 0.02506 15233. 21223. 214.36 22.58 30.90 Sai yao 0102437 15686. 21842. 215.21 22.31 31.03 Sas. a17 4. Phys. Chem, Re. Data, Vo. 15, Ne. 2, 1906ate JACOBSEN, STEWART, AND JAHANGIRI Table 22. Thermodynamic properties of nitrogen-Continued Temperature Density Internal Enthalpy Entropy , Velocity Enerey of Sound K mol/én? J/nol Jmol S/mol K J/mol K J/mol K —/s 760 0.02372 16142. 22465. 216.04 22.85 31.17 355 780 0.02312 16600. 23088. 216.85 22.99 31/31 562 800. 0.02254 17061. 23717. 217164 «231123144 569 350 0.02121 18226. 25297. 219156 23.46 31.77 585 900 0.02003 19407, 26894. 221139 23.78 32.10 601 950, 0.01898 20604, 28507. 223.13 24.09 32.41 616 1000 0.01803 21816. 30134. 224.80 24.38 32.70 631 1050 0.03717 23042. 31776. 226.40 24.66 32.98 66. 1100 001639 47R2’ 34437” 297/94 948A 4475, 660. 1150 0.01568 25535. 35101. 228.43 25.18 33.49 674 1200 0.01503 26800. 36781. 230.86 25.41 33.73 688 1250 0.0143 28076. 38473. 232124 25.63 33.95 701 1300 0101387 29362. 40176. 233757 25183 34.15 m4 1350 0.01336 30659. 41888. 234.87 26.03 34.34 2 1400 0.01288 31965. 43610. 236.12 26.21 34.52, 740 1450 0.01244 33279. 45340. 237.33 26.37 34.69 753, 1500 0.01202 34602: 47078. 238.51 26.53 34.84 765 1550 0101164 35932. 48824. 239166 26.68 34.99 7 1600 0.01127 37270. 30577. 200.77 26.82 33.13 708 1650 0.01093 38614. 52337. 241.85 [94 38.26 801 1700 0.01061 39964. 54203. 262.91 27.07 35.38 812 1750 0.01031 41320. 55875. 243193 2711835150, 324 1800 0.01002 42682. 57653. 244.94 27129 35.60 835, 1850 000975 4uoug. $9435. 245.91 27.39 35.70 846 1900 0.00949 45421. 61223. 246.87 27.49 35.80 857 1950 0.00925 46798. 63015. 247.80 27.58 35.89 868, 2000 0.00902 48179. 64812. 248.71 27166 35.98 879 0.20 MPa Isobar * 63.18 31,053 4228.0 -4221.6 67.89 91.30 56.54 1023 6 30:927 -4181,7 | -4175.2 68.61 31.23 56.47 1011 66 30.617 4068.9 -4062.4 70.35 31108 56.37 985, 6a 30306 395613 -3949.7 72.03 «30.85 56.36 959 10 29,992 -3843.6 =3836.9 73.67 30.65 56.43, 935, 72 29.67% 3730.7 -3723.9 75.26 30.45 $6.56 su % passe e174 canin'e 7K 'R1 aN 9K KTS, Rae 16 29.026 | =3503.8 -3496.9 78.33 30.04 56.99. 866 78 28.695 3389.6 -3382.6 79.81 29.84 57.29 843 80 28.358 3274.8 -3267.7 81.27 29.63 57.63 821 82 28.014 3159.2 =3152.1 82.69 58.03 800 * 83,62 27.731 3065.1 -3057.9 83.83 58.39 782 * 83162 0.30985 1625.0 2270.5 147.55 39.41 176 4. Phys. Chem. Ret: Dat, Vol. 15, No.2, 1888

Thermodynamic Properties of Nitrogen From The Freezing Line To 2000K at Pressures 1000MPa

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