Professional Documents
Culture Documents
Arithmetic method:
This method assumes that the rate of growth will be constant
P=Population
t = time
dp /dt = K
K = arithmetic growth constant
K = {P2 - P1} / {t2 - t1}
Or
Pn = P + nIa
N=Design Period
P= current Population
Ia= Average increment in population per decade
Pn = Estimated population at the end of design period
Geometric method:
This method assumes that the rate of growth will be proportional to the population
P=Population
t = time
dP/dt = K*P
K = geometric growth constant
K = {Ln P2 - Ln P1} / {t2 - t1}
OR
Pn = P [1 + Io/100]n
Io= average of %age increment
Pumping plant: to meet maximum day demand (if feeding into reservoirs) Distribution
system: to meet maximum hour demand or (maximum fire demand + fire demand) whichever
is greater.
Need for testing water quality:
For drinking water:
To assess safety and palatability of water for consumption
For raw water sources:
To select treatment systems; to establish pollution control monitoring systems
For wastewaters:
To select type and degree of treatment; to control treatment plant operation
For receiving waters:
To evaluate their ability to accept pollution loads; to monitor self-purification
Types of Examination:
Physical examination:
to determine aesthetic quality
Chemical examination:
To test for chemicals which affect the water quality and/or which are indicative of
pollution
Bacteriological examination:
To test for the presence of bacterial indicators of pollution and hence safety for
consumption
Biological examination:
To determine the causes of objectionable odours, clogging of filters, etc.
Some salient water quality parameters:
Temperature
Turbidity
Odours and Tastes
Colour
pH
Alkalinity and Acidity
Chlorides
Nitrogen compounds (organic N, ammonia N, nitrite N, nitrate N)
Hardness
Fluorides
Acidity:
Less significant when compared to alkalinity
Acid rain, water becoming acidic in some treatment processes, etc.
Chlorides
Chlorides are present in all water sources.
Chlorides get into water from:
mineral deposits
domestic wastewater discharges
industrial wastewaters
Irrigation drainage
Human excreta (urine) contains chloride, about 6g/capita. d
Significance:
Undesirable taste
Contributes to non-carbonate hardness
In industrial waters: deposits, corrosion under boiler conditions, affects ice,
undesirable for beverages and food products
Natural waters have a uniform chloride content. An increase above the normal
chloride level is an index of pollution by domestic wastewaters.
Nitrogen Compounds
Refer to Nitrogen Cycle.
Forms of nitrogen:
Organic nitrogen
Ammonia nitrogen
Nitrite nitrogen
Nitrate nitrogen
The presence of various nitrogen forms throw light on the pollution history of the carrying
water.
Organic nitrogen:
Animal tissue is richer in nitrogen than plant tissues. So, higher concentration
indicates pollution by wastes of animal origin.
Characteristic of recent pollution
Ammonia nitrogen:
Initial product of decomposition, and hence indication of recent pollution
Always found in sewage polluted waters
Toxic to fish
Nitrite nitrogen:
Oxidation product of ammonia nitrogen (Intermediate product)
Nitrites are easily and rapidly converted to nitrates, hence indication of active
biological processes
Nitrate nitrogen:
End product of decomposition of organic matter
Nitrates
Occurs in water from:
fertilizer use
decayed vegetable and organic matter
domestic effluents
sewage sludge disposal to land
industrial discharges
leachate from solid waste landfills
atmospheric washouts
Significance:
infantile Methaemoglobinaemia
carcinogenicity of nitrosamines
Eutrophication of lakes
Hardness
Common in groundwater.
Water is hard when it does not readily form lather with soap.
Hardness in water is due to:
calcium (Ca) and magnesium (Mg)
Carbonate hardness: due to carbonates and bicarbonates of Ca and Mg
Non-carbonate hardness: due to chlorides and sulphates of Ca and Mg
Significance:
scale build-up in boilers and hot water systems
excessive soap usage
fuel wastage
poor cleaning of clothes and reduced fabric life
health effects: minor: dishpan hands, laxative effects. Soft water: cardiovascular
diseases?
Iron and Manganese
Common in groundwater
Iron
is the most important single criterion indicating the sanitary condition of water.
Water deficient in DO is likely to be polluted with organic matter (Groundwater ?)
Significance:
Measure
of
the
impact
of
oxidizable
wastes
in
water
Lack
of
DO
affects
fish
and
aquatic
life
Measure
of
progress
of
self-purification
in
rivers
Influences solution and precipitation of metals like Al and Fe
For determining biochemical oxygen demand of wastewaters
Biochemical Oxygen Demand (BOD)
BOD is a measure of the DO required for the utilization of organic matter as food by
the
aerobic
microorganisms.
BOD test evaluates the loss of oxygen that accompanies the decomposition induced
and
maintained
by
the
aerobic
organisms.
BOD is measured by DO determination before and after an incubation period of 5
days
at
20oC
BOD is an indirect measure of the amount of readily biodegradable organic matter.
It
is
a
measure
of
the
strength
of
wastewater.
Carbonaceous and nitrogenous BOD ?
Significance:
Pollutional
strength
of
domestic
and
industrial
wastewaters
In
stream
pollution
control
activities
Evaluation
of
self-purification
capacity
of
receiving
waters
Assessing efficiency of wastewater treatment processes
Taste
Laxative
Indication
of
Waters with high TDS not desirable for industries
effects
hardness
Ferrous sulphate leads to formation of heavy, easily settling floc. Its application may be
preferred in lime-soda softening or iron/manganese removal.
Chlorinated copperas
When chlorine is used to oxidize the Fe(OH) 2 to Fe(OH)3, its called treatment with
chlorinated copperas.
First, the FeSO4 reacts with Cl2 to yield Ferric sulphate - Fe2(SO4)3 and ferric chloride - FeCl3.
3FeSo4 + 1.5Cl2
Fe2(SO4)3 + FeCl3
2Fe(OH)3 + 3CaSO4
2Fe(OH)3 + 3CaCl2
Coagulation with chlorinated copperas is effective over a wide pH range of 4.0 to 11.0. It is
used to advantage in plants practising pre-chlorination.
Ferric sulphate - Fe2 (SO4)3:
Ferric sulphate can be used as a coagulant, and it reacts with alkalinity (as shown above)
giving ferric hydroxide.
In very small plants (in rural areas), the turbulence created through the following simple
devices could be used to achieve rapid mixing:
Flow
over
Hydraulic
Venturimeter
in
Suction and delivery ends of pumps
a
jump
pressure
weir
pipes
=
dynamic
V=volume
of
G= velocity gradient (s-1 )
input
viscosity
tank
(m
(W)
(N.s/m2)
)
A good dispersal of coagulant is achieved for values of G between 700 s -1 and 1000 s1
.
Power
Input:
The power input creates the turbulence, and the degree of turbulence is proportional to
the power input. The power input (or requirement) under turbulent conditions is
computed by Rushton's formula:
P = k . . n3 . D 5
where
P
=
power
k
=
a
constant
(based
on
=
mass
density
n
=
revolutions
D = diameter of the impeller (m)
input
the
type
of
of
fluid
per
(W)
the
impellor)
(kg/m 3)
second
This formula is applicable for values of Reynold's Number greater than 10000.
R = (D2 . . n)/
Values of k in Rushton Formula:
Type of Impeller
0.32
1.00
6.30
4.80
1.65
1.08
1.12
Flocculation accomplishes the formation of readily settleable flocs from the destabilized
colloids. In a treatment plant, flocculation is achieved through a slow and gentle mixing of
the coagulated water, generally in paddle flocculators.
Paddle Flocculators:
These are tanks in which paddles mounted on horizontal or vertical shafts provide the
required agitation.
DESIGN PARAMETERS:
Detention
time:
The flocculators are sized to provide a detention time of 10 - 40 minutes. (NOTE:
detention time t = V/Q)
Velocity
Gradient:
The stirring action generates velocity gradients. Velocity gradient is the rate of change
of velocity per unit distance normal to the section. The velocity gradient G is related
to power input as follows:
G = { P/( V)}1/2
where:
P=
power
=
dynamic
V=volume
of
G= velocity gradient (s-1 )
input
viscosity
tank
(m
(W)
(N.s/m2)
)
P = (1/2)CD. A. . v3
where
P
=
power
CD
=
(1.20
for
paddle
length
1.50
for
paddle
length
1.90
for
paddle
length
to
=
mass
density
v
=
relative
velocity
of
A = area of paddles (m)
input
(W)
Drag
coefficient
to
width
of
5:1
to
width
of
20:1
width
more
tha
20:1
of
fluid
(kg/m 3)
paddle
in
fluid
(m/s)
v =
70 - 80% of paddle
tip speed
v f (without
vf
=
2
r
n
where r = radius of the paddle wheel, and n = revolutions per second.
stators)
In flocculators without stator blades, paddle area at any corss-section should not
exceed
20%
of
the
cross-sectional
area
of
the
tank.
Flow-through velocity in flocculators range from 15 cm/min to 45 cm/min.
Tapered flocculation (from G = 75 s-1 to 20 s-1) is recommended.
Baffled
Basins
as
Types: 'Around-the-end' type and 'over-and-under' type.
Flocculators:
The changes imposed by the channels on the direction and velocity of flow of water
generate the velocity gradients required for turbulence.
Sedimentation is the process in which the velocity of the flowing water is reduced so as to
permit the suspended matter to settle out under the influence of gravity.
In water treatment, sedimentation may be applied as plain sedimentation, sedimentation
following coagulation and flocculation, or for chemical precipitation.
Sedimentation reduces the load on filters, increases the filtter runs, and improves filtration
efficiency.
Factors affecting settling velocity of particles:
Specific
gravity
Flow
velocity
Temperature
of
Shape, agglomeration and concentration of particles
of
of
particles
water
water
Newton's Law:
vt = [ (4/3) g {p - f } d/ {CD f } ]1/2
where
vt
=
Terminal
settling
velocity
(m/s)
2
g
=
gravitational
constant
(m/s
)
p and f = density of particle and fluid respectively (kg/m3
d=
diameter
of
particle
(m)
CD = Drag coefficient
where
CD = 24/Re (Laminar; Re is less than or equal to 1.0)
CD = {24/Re } + {3/(Re )1/2 } + 0.34 (Transitional)
CD = 0.4 (Turbulent; Re is equal to or more than 104 )
Re = Reynolds Number = vt f d/
= dynamic viscosity (N.s/m2 )
Stoke's Law:
vt = g {p - f } d2 /18
Ideal Sedimentation Basin:
Concept
of
surface
loading
(surface
overflow
rate)
Efficiency of settling basin as a sole function of settling velocity of particles and
surface
loading
(or
surface
area
of
basin)
Limitations in real practical basins
Measurement of Settling Characteristics:
Discrete
particle
settling
Flocculent particle settling
Types of settling basins:
Rectangular horizontal-flow, circular radial-flow/spiral-flow, upflow, etc.; Tube settlers;
Sludge blanket type basins; Solids contact clarifiers
Design parameters (for conventional basins):
Detention time: 2 - 8 h
Surface loading: 20 - 50 m3/m2.d
Number of basins: minimum 2
attraction
Chlorination:
Chlorine reacts with water as follows:
Cl2 + H2O
HOCl
HOCl + H+ + Cl-
H+ + OCl-
NH2Cl + H2O
NH2Cl + HOCl
NHCl2 + H2O
NHCl2 + HOCl
NCl3 + H2O
points
of
application:
It does not maintain an adequate residual in water, and chlorine is, therefore, added as a
secondary disinfectant to ozonated water.
Softening:
Lime-Soda Process:
The lime-soda softening process converts the soluble compounds responsible for hardness
into insoluble compounds which can be precipitated out in settling basins.
Reactions:
CO2 + H2
CaCO3 + H2O
Ca(HCO3 )2 + Ca(OH)2
Mg(HCO3
)2
MgCO3 + Ca(OH)2
MgSO4
+
CaSO4 + Na2CO3
MgCl2
+
CaCl2 + Na2CO3
CaCO3 + 2H2O
Ca(OH)2
CaCO3 + Mg(OH)2
Ca(OH)2
CaCO3 + Na2SO4
Ca(OH)2
CaCO3 + 2NaCl
CaCO3
MgCO3
H2O
Mg(OH)2
CaSO4
Mg(OH)2
CaCl2
NOTE:
CO2 requires lime.
Lime reacts with carbonate hardness; Mg requires 2 equivalents of lime.
Non-carbonate hardness requires addition of of Na2CO3
CaCl2 and CaSO4 require only Na2CO3; but MgCl2 and MgSO4 require additional lime.
Precipitation of Mg requires higher pH, hence the need for excess lime
Practical limits of lime-soda softening: 30 - 40 mg/L of CaCO3 and 10 mg/L of Mg(OH)2
Lime softened water is supersaturated with CaCO 3. Recarbonation is used to prevent afterprecipitation by keeping the excess CaCO 3 in solution as bicarbonate.
CaCO3 + CO2
Ca(HCO3 )2
It
also
Ca(OH)2 + CO2
neutralizes
CaCO3 + H2O
the
excess
lime:
Softening:
+
Na2Z
MgZ + 2NaHCO3
CaZ
2NaHCO3
CaSO4
+
Na2Z
MgSO4 + Na2Z
MgZ + Na2SO4
CaZ
Na2SO4
CaCl2
+
Na2Z
MgCl2 + Na2Z
MgZ + 2NaCl
CaZ
2NaCl
Na2Z
CaCl2
Regeneration:
CaZ
+
MgZ + 2NaCl
2NaCl
Na2Z + MgCl2
NOTE:
Ion exchange softening can achieve 100% hardness removal.
Not suitable for water with Fe or Mn.
Commonly used in industries and individual residences.
Other Treatment Processes:
Odour and taste control
Water stabilization
Iron and manganese removal
Fluoridation
De-fluoridation
Desalination
Objectives of Wastewater Treatment:
Prevent/reduce spread of communicable diseases
Prevent pollution of surface and ground waters
Choice of Processes and Degree of Treatment:
Plant location & nature of present and future surroundings
oxygen
Oxygen
demand
Demand
solids
solids
Kjeldahl
nitrogen
Industrial wastewaters vary widely in their characteristics based on the raw materials
and processes used.
in
the
grit
chamber.
The primary sedimentation basin removes organic matter in solution and in
suspension.
SECONDARY TREATMENT:
The secondary treatment is in the form of biological treatment (e.g. trickling filter and its
secondary settling basin).
A trickling filter (or an aerator in the activated sludge process) converts organics into
biomass.
The biological slimes or sludges discharged from these units settle down in secondary
sedimentation basins.
TERTIARY TREATMENT:
The tertiary treatment provides for advanced treatment like nutrient removal and or a higher
degree of suspended or dissolved solids removal.
Screens:
Function: To remove large objects which may damage the equipment, cause clogging of
pipes, and accumulate in settling basins.
Bar Racks (or bar screens):
Bar racks consist of bars spaced 10 to 50 mm apart and are usually mechanically cleaned. The
screens are placed in rectangular channels. The raking, done by means of endless chains on
sprockets, moves the debris (screenings) upward and drops in a collection bin.
The screenings are odorous and also attract flies. They are disposed by incineration or land
filling or by returning to the wastewater flow after shredding (using comminuters).
Grit Chamber:
Grit: Inert and inorganic material (sand, gravel, road grit, metal pieces, bone chips, glass
pieces, etc) in the wastewater
Function: To protect equipment from abrasion, to prevent pipe clogging, and to prevent
accumulation in settling basin, digestors, etc.
Design principle:
The grit chamber must be designed to remove only grit and not organic matter. Organic
matter will be kept in suspension, and any organic matter that might settle must be
resuspended
by
scour.
Grit with a specific gravity of 2.65 has a settling velocity of 30 mm/s. Organic particle with a
specific
gravity
of
1.10
has
a
settling
velocity
of
3
mm/s.
The design of a grit chamber exploits the difference in settling velocities of these particles.
Horizontal-flow, velocity-controlled grit chambers:
In a horizontal-flow, velocity controlled grit chamber, the velocity of wastewater flow is
maintained at 0.30 m/s so that only grit will settle out. This grit chamber will have to be
designed to maintain constant velocity of 0.3 m/s.
Maintaining a constant velocity of 0.3 m/s can be achieved in:
a channel of parabolic cross-section, controlled by a downstream standing wave
flume, or
a channel of rectangular cross-section, controlled by a proportional-flow weir at the
outlet
The grit chambers are narrow channels also with a length to depth ratio of 20:1. The detention
time is about 1 min.
Aerated grit chambers are also used for grit removal.
The grit, removed by mechanical collectors, is disposed of by burial or used as a fill material.
If it still contains organic material, it is sent to sanitary landfills.
Many
times
faster
than
anaerobic
decomposition
Production of large amount of cell material (more sludge)
ANAEROBIC DECOMPOSITION:
Nither molecular oxygen nor nitrates used as electron acceptors; Sulfates, carbon-dioxide
and
organic
compounds
serve
as
electron
acceptors.
End products: carbon-di-oxide, methane, and water; Others are ammonia, hydrogen
sulfide
and
mercaptons
(foul
smell).
Low cell yield (low sludge production)
ANOXIC DECOMPOSITION:
Absence of molecular oxygen, and nitrate is the electron acceptor
End products: nitrogen gas, carbon-di-oxide, water and new cell material
Cell yield high but less than aerobic decomposition
Trickling Filters (Attached Culture System):
Function: Biological oxidation of organic matter present in settled wastewater (in solution or
as suspended matter) by bringing it in contact with biological agents developed on the surface
of a contact medium
Trickling filter is not 'filter'. It is a biological contact bed.
It is a filter-like structure with contact media on the surface of which biological agents form
slimes. It has a system to apply the settled wastewater to come into contact with the
biological slimes. The organisms in the slime use organics in wastewater as food and convert
them into biological cells. The effluent is collected by an under drainage system for further
treatment in a secondary settling basin.
The trickling filter is usually circular, and the contact medium consists of crushed stones (5075 mm) or synthetic media. The settled wastewater is applied on the surface of media by
rotating distributors.
The pore space, the method of distribution of wastewater, the natural ventilation due to the
temperature differential between wastewater and ambient temperatures, and the partial-flow
conditions in the under drainage system facilitate the air circulation and hence maintenance
of aerobic conditions in the trickling filter.
As the wastewater trickles down, the microorganisms grow into a slime over the surface of
the contact media. The development of the slime is gradual over a period of several weeks
(ripening period). The microorganisms in the slime feed on the organic matter in the
wastewater trickling over them. Over the time, excess slimes and also dead slimes from the
media are flushed out along with the effluent. This discharge of slime, known as sloughing, is
influenced by the hydraulic and organic loading rates. The suspended solids content in the
filter effluent will, therefore, be very high and needs to be removed by passing it through a
secondary settling basin.
Recirculation:
Returning a portion of the effluent to the inflow to filter is known as 'recirculation'.
Recirculation dilutes the influent to the trickling filter and provides a seeding with active
microorganisms. It helps to dampen variations in flow and in maintaing a desirable hydraulic
loading. It reduces clogging of contact media and minimizes the problem of psychoda fly
nuisance.
Organic or BOD loading: expressed as kg of BOD per day per m 3 of contact media
volume, kg/m3.d
BOD loading = {wastewater flow rate, Q * BOD of settled wastewater}/Volume of
filter
media
NOTE: BOD of settled wastewater = 65-70% of BOD of raw wastewater
Hydraulic loading: expressed as m3 of wastewater applied per day per m 2 of surface
area of trickling filter
Hydraulic loading = {wastewater flow rate, Q + Recirculation flow rate, Q R}/Surface
area of filter
Recirculation ratio = QR/Q
Typical
loadings:
Low-rate trickling filters: BOD loading = 0.25 kg/m3.d ; Hydraulic loading = 2-5
m3/m2.d ; Recirculation ratio = 0
High-rate trickling filters: BOD loading = 0.75 kg/m 3.d ; Hydraulic loading = 10-30
m3/m2.d ; Recirculation ratio = 0.5-3.0
Design Formulae: National Research Council (NRC) formulae for a single-stage rock-filled
trickling filter and for a two-stage filter.
Bio-tower, Rotating Biological Contactor (RBC)
Activated Sludge Process (Suspended Culture System):
Function: Biological oxidation of organic matter present in settled wastewater (in solution or
as suspended matter) by mixing it with biological sludge and subjecting the mixture to
aeration
The biological sludge (called 'Activated Sludge') is the sludge derived from settling a
wastewater which has been subjected earlier to thorough mixing, agitation and oxygen intake
created by an injection of air.
The activated sludge process uses an aerator and a secondary settling basin. In the aerator the
injected air provides oxygen for growth of aerobic organisms and also provides a good
mixing of the raw wastewater and the activated sludge. This mixture, termed as 'mixed
liquor', flows into a secondary settling basin where the 'activated sludge' settles out. A portion
of this activated sludge, which contains a luxurient growth of microorganisms, is returned to
the aerator and the remaining sludge (Waste Activated Sludge - WAS) is wasted to the sludge
treatment system.
Extended aeration
High-rate aeration
Contact stabilization
Pure-oxygen
Oxidation ditch
Process Parameters:
Hydraulic detention time
Mean cell residence time (MCRT)
Mixed liquor suspended solids (MLSS)
Mixed liquor volatile suspended solids (MLVSS)
Food to microorganism ratio (F/M)
Specific utilization rate (U)
Sludge volume index (SVI)
Organic loading rate
Sludge Treatment and Disposal:
Primary Sludge:
Primary settling removes 40-60% of influent (raw wastewater) suspended solids.
The quantity of primary sludge, i.e., the mass of primary solids (on a dry mass basis)
removed , can be computed using the flow rate, suspended solids content of raw wastewater,
and the removal efficiency of the primary settling basin.
Secondary Sludge:
The secondary sludge contains suspended solids remaining after primary settling and also
solids resulting from conversion of dissolved organics into cellular material in the biological
treatment unit.
The quantity of secondary sludge can be computed using the flow rate, the BOD removed by
secondary treatment, and a biomass conversion factor.
The sludge have a water-content of about 97%, and the sludge treatment involves mostly
dewatering and stabilization.
The treatment of sludge involves a combination of some of the following processes:
Sludge thickening (gravity thickeners, dissolved air flotation)
Sludge conditioning (chemical conditioning, heat treatment)
Sludge stabilization (anaerobic digestion, aerobic digestion)
Sludge dewatering (vacuum filtration, pressure filtration, drying beds)
Disposal of sludge has the following alternatives:
Incineration
Disposal at a sanitary landfill
Land spreading (farmland, land reclamation)
Advanced Wastewater Treatment:
Advanced wastewater treatment may be required when the effluent from secondary treatment
is not of an acceptable quality under the given conditions.
This advanced treatment is also referred to as 'tertiary treatment'.
Advanced treatment is incorporated for:
Nutrient removal (nitrogen, phosphorous)
Solids removal (suspended solids, dissolved solids)