OPERATION OF

STATIC CRYOGENIC VESSELS

IGC Document 114/09/E
Revision of IGC Doc 114/03/E

EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL

AVENUE DES ARTS 3-5 B 1210 BRUSSELS
Tel : +32 2 217 70 98 Fax : +32 2 219 85 14
E-mail : info@eiga.eu Internet : http://www.eiga.eu

Doc 114/09

OPERATION OF
STATIC CRYOGENIC
VESSELS
PREPARED BY:
Herv BARTHLMY

Air Liquide

Dany BOURDEAUDHUY

Praxair

Jean-Louis JOLIVET

Air Liquide

Udo KOHL

Messer

Klaus KRINNINGER

IGV

David TEASDALE

BOC Gases UK

Andy WEBB

EIGA

Stuart WILLIAMS

Air Products

Disclaimer
All technical publications of EIGA or under EIGA's name, including Codes of practice, Safety procedures and any other technical
information contained in such publications were obtained from sources believed to be reliable and are based on technical
information and experience currently available from members of EIGA and others at the date of their issuance.
While EIGA recommends reference to or use of its publications by its members, such reference to or use of EIGA's publications by
its members or third parties are purely voluntary and not binding.
Therefore, EIGA or its members make no guarantee of the results and assume no liability or responsibility in connection with the
reference to or use of information or suggestions contained in EIGA's publications.
EIGA has no control whatsoever as regards, performance or non performance, misinterpretation, proper or improper use of any
information or suggestions contained in EIGA's publications by any person or entity (including EIGA members) and EIGA expressly
disclaims any liability in connection thereto.
EIGA's publications are subject to periodic review and users are cautioned to obtain the latest edition.

EIGA 2009 - EIGA grants permission to reproduce this publication provided the Association is acknowledged as the source
EUROPEAN INDUSTRIAL GASES ASSOCIATION AISBL
Avenue des Arts 3-5 B 1210 Brussels
Tel +32 2 217 70 98
Fax +32 2 219 85 14
E-mail: info@eiga.eu Internet: http://www.eiga.eu

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Table of Contents
1

Introduction ...................................................................................................................................... 1

Scope and purpose .......................................................................................................................... 1

2.1
2.2

Scope ........................................................................................................................................ 1
Purpose .................................................................................................................................... 2

Definitions ........................................................................................................................................ 2

Putting into Service .......................................................................................................................... 2

4.1 Checking the markings ............................................................................................................. 3
4.2 Checking the completeness of the handover documents......................................................... 3
4.3 Checking the equipment ........................................................................................................... 3
4.4 Checking the installation ........................................................................................................... 3
4.4.1 General considerations .......................................................................................................... 3
4.4.2
Indoor installation .............................................................................................................. 4
4.4.3 Outdoor installation ................................................................................................................ 5

Inspections ....................................................................................................................................... 5
5.1 At time of filling ......................................................................................................................... 6
5.2 Inspection during putting into service and periodic inspections ............................................... 6
5.2.1 Inspection of the vessel ......................................................................................................... 6
5.2.2 Inspection of safety relief devices .......................................................................................... 7

Taking out of service ........................................................................................................................ 7

Maintenance and repair ................................................................................................................... 8

Putting Back Into Service ................................................................................................................. 9

Appendix 1 - SAFETY CHECKS FOR VACUUM INSULATED STORAGE TANKS...................... 10

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DOC 114/09

Introduction

Static cryogenic vessels are used for the supply of industrial gases to customers. These vessels
are part of the industrial gas supply system for the customer and are filled by tank vehicles once
or several times a month. The vessels are installed at a customers premises and are normally
owned and operated by the industrial gas company.
Vessels that are used for the storage of cryogenic liquids consist of an inner pressure vessel,
insulation and an outer jacket; the space between the inner and the outer jacket has a vacuum.
Vessels that are used for the storage of refrigerated liquids e.g. Carbon Dioxide can be stored in
a vessel suitable for cryogenic liquids, or in a vessel that consists of an inner pressure vessel
with foam insulation.
The industrial gases are supplied in a liquid or gaseous state to the customers point of use. The
supply is normally achieved by pressure where the vessel and its contents are at a higher pressure
than the customer. To achieve this, the vessels are fitted with a vaporizer, normally called the
pressure build up coil and a pressure regulator that keeps the pressure in the vessel at a
given value. Therefore the pressure cycling of static cryogenic vessels is low.
Static cryogenic vessels are not subject to corrosion of the inner pressure vessel as cryogenic
gases at storage conditions are not corrosive to the materials used. The space between outer
jacket and inner vessel is held under vacuum so that the outer surface of the inner vessel and
the inner surface of the jacket are also protected against chemical attacks from the
environment. The outer surface of the jacket is protected with a paint system.
Static cryogenic vessels are designed and manufactured according to a pressure vessel code
using materials that are proven for cryogenic use.
The lifetime of a static cryogenic vessel is as such not subject to the typical failure mechanisms
e.g. corrosion, erosion or fatigue.
It is specific for the use of static cryogenic vessels that these vessels will be moved from time to
time because the gas consumption of the customer changes and a different size of vessel
has to be installed or the contract between gas company and customer has ended. Experience
shows that each vessel is moved every 6 years on average.
2

Scope and purpose

2.1

Scope

This document specifies the procedures for putting into service, inspections, requalification
according to the PED, taking out of service, maintenance and repair of static cryogenic vessels
designed for a maximum allowable pressure of more than 0.5 barg.
The vessels are used for the storage of the following gases and mixtures such as:

Asphyxiant gases (neon, argon, helium, krypton, nitrogen, carbon dioxide)

Oxidising gases (air, oxygen, nitrous oxide)

Flammable gases (ethylene, ethane, hydrogen, methane, natural gas)

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DOC 114/09

Purpose

The purpose of this document is to describe the operation of static cryogenic vessels, putting into
service, inspections, taking out of service, maintenance and repairs and includes:

How the user operates the vessel

How local authorities and competent persons inspect these vessels to get common
agreement about the operation that allows free movement within Europe without
additional approvals.

The essential parts of this document are also included in EN 13458-3, Operational
requirements.
3

Definitions

Static cryogenic vessel

A thermally insulated vessel intended for use with one or more cryogenic fluids, consisting of an
inner vessel, an outer jacket and the associated piping system. This static cryogenic vessel is
not intended to be transported full. It may be transported empty or containing marginal residues
of cryogenic fluid or gas from one static location to another, at less than 2 barg. This static
cryogenic vessel represents a complete assembly, functional whole, ready to put into service.
Inner vessel
The pressure vessel intended to contain the cryogenic fluid.
Outer jacket
The air tight enclosure which supports the inner vessel, holds the insulation and enables the
vacuum to be established.
Putting into service
The operation by which a vessel is prepared to be put into service, it applies to either a new
vessel used for the first time or a vessel which has been taken out of service and brought back
into service.
Competent person
A person e.g. from the gas company, who is experienced, trained and nominated for the
intended task.
PED
Directive 97/23/EC of the European Parliament and of the council of May 29, 1997 on the
approximation of the laws of the Member States concerning pressure equipment.
USER
In this document the user is considered to be the customer who uses the product contained in
the cryogenic vessel for their process.
4

Putting into Service

The following tests and inspections shall be carried out by a competent person before putting
into service a static cryogenic vessel the first time or at each subsequent time.
This operation shall follow a written procedure and the results of the steps involved should be
recorded (e.g. in a check list). Such lists should be retained by the operating company.
Vessel and accessories shall be checked in accordance with 5.2.
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The vessel shall be purged with an appropriate gas until the gas emerging from the vessel is
sufficiently dry and pure.
The vessel shall be cooled down according to the manufacturer's recommendations or the
operating gas companies procedures. Steps shall be taken to avoid uncontrolled pressure rise
due to rapid liquid evaporation following the introduction of liquid into a warm vessel that has not
been cooled sufficiently with cold gas prior to the introduction of liquid.
4.1

Checking the markings

Marking and labelling of new static cryogenic vessels shall be in accordance with EN 134581:2002.
4.2

Checking the completeness of the handover documents

In addition to the manufacturer's documentation, where necessary the cryogenic vessel shall be
accompanied by vessel specific documents and instructions for all items supplied including:
Operation
Auxiliary equipment
Inspection records
These documents shall be retained by the owner or user of the vessel.
The user shall have appropriate operating instructions available. Such instructions may be
attached to the vessel in a permanent manner, or supplied in paper or electronic form.
4.3

Checking the equipment

Checking the equipment covers:

Checking the safety relevant measuring devices for their availability and appropriate
choice in respect of the suitability of the measuring range and, in so far as possible, for
performance/correct operation

Checking the safety relevant shut-off devices for availability, appropriate choice and
arrangement in respect of pressure and temperature and, in so far as possible, for
performance/correct operation

Checking other safety relevant fittings, gauges and controlling devices in particular with
regard to the medium to be supplied and vented; where these are automatically driven
or controlled, also their performance in the event of a power cut or loss of pneumatic
supply
The vessel's connections are to be tested for leak-tightness before putting into service.

4.4 Checking the installation

4.4.1 General considerations

Vessels shall be installed and operated in such a way that employees, customers and the public
are not endangered.
Safety distances shall be observed.
Vessels shall be installed so that the name plate is easily readable.
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The installation should allow the inspection of vessels on all sides.

All vessel controls shall be capable of being operated safely.
Vessels shall be installed in such a way that its filling operation can be carried out safely.
Vessels shall be erected on suitable foundations, and considering, static loadings, wind and
other external forces e.g. snow such that the integrity of the vessel and its foundations are not
compromised.
Any gas from pressure relief devices or vents shall be discharged to a safe place.
Appropriate warning signs shall be displayed.
Vessels shall be installed in locations where there is sufficient ventilation such that the formation
of dangerous explosive gas-air mixtures or an oxygen deficient/enriched atmosphere is avoided.
Vessels shall be installed in such a way that adequate space is provided for maintenance and
cleaning, as well as for the operation of all equipment.
The adequate space for maintenance and cleaning should be at least 0.5m around the
installation. Vessels shall not be installed in corridors, passages or thoroughfares, generally
accessible lobbies, stair-wells or near steps. Vessels should not be installed close to the
aforementioned areas either, if traffic routes, escape routes or accessibility are limited.
Access by unauthorised persons should be prevented.
The floor under vessels as well as below detachable connections and fittings on the liquid
phase on oxidising gases shall be of non-flammable materials and free of oil, grease and other
flammable contaminants.
Consideration shall also be given to the need for similar precautions on liquid hydrogen and
liquid helium installations where significant air liquefaction may occur around uninsulated
equipment.
Pressure relief devices shall be provided to prevent overpressure of the equipment connected
down stream of the vessel's outlet.
If this connected equipment is not designed for low temperatures, safety devices shall be
provided to protect it against possible low operating temperatures or the equipment
performance shall be specified to prevent the down stream equipment seeing unacceptable low
temperatures.
4.4.2

Indoor installation

Vessels shall be installed outdoors wherever reasonably possible. If an indoor installation has to
be carried out the following safety precautions shall apply, there shall be a particular risk
assessment.
The entrance of rooms in which vessels are installed shall be labelled. Reference shall be made
to the hazardous properties of the gas.
Rooms shall:

Have self-closing doors, where these do not lead directly outside

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Consist of materials which are fire resistant or non-combustible, with the exception of
windows and other closures of apertures in external walls
Be separated from other rooms in accordance with a fire resistance class of 30 min
Be separated in a gas-tight manner and without any apertures, from rooms normally
occupied by the public
Have adequate ventilation; gas release from the trycock valve shall be taken into
account when assessing the ventilation requirements

Precautions/procedures shall be implemented to ensure that personnel entering or within the

rooms are not exposed to hazardous atmospheres.
Rooms containing vessels shall not be used in any other way which may be a danger to the
vessels due to mechanical effects, fire or explosion.
Filling connections shall be hard piped to an outdoor location.
Manual vent and relief system vents shall be piped so that the outlet is in a safe outdoor
location.
In rooms there shall be no:

Air intake openings for the ventilation of other rooms

Open ducts
Duct inlets unprotected against the ingress of gas
Open shafts
Openings to lower rooms

4.4.3 Outdoor installation

The drainage of surface water from the place of installation shall be ensured.
In sloping sites an installation may be necessary to prevent gas from spreading across the site
and penetrating into lower rooms, ducts, shafts or air intakes; this may be a wall for example.
Vessels and their components shall be protected against mechanical damage, e.g. by vehicle
buffer bars, enclosures, safety distances. The protection of outer vessel supports against leaking
cryogenic fluid should be considered.
5

Inspections

Users of vacuum insulated storage tanks have a duty of care to ensure the equipment is
operated safely on their site.
Gas suppliers assist in the provision of operating manuals and training of operation staff.
It is also the responsibility of the user to ensure that this training and awareness is ongoing and
current.
Gas suppliers carry out checks when making deliveries but more regular routine checks should
be carried out by the user.
Safety may be compromised when such checks are not routinely performed leading to potential
equipment failure and possible personal harm.

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5.1

DOC 114/09

At time of filling

Static cryogenic vessels shall be inspected just before filling by the driver of the tank vehicle.
This inspection has to be carried out according to a written procedure.
The inspection should consist of

Data plate/product identification label

Correct coupling for the product
Condition of fittings (not damaged, dirty, excessively iced)
A functional check of main valves
Leak tests of the filling line under operating conditions
Assessing any changes of the operational conditions of the installation and its
surroundings
Visual consisting of:
1. An external visual inspection of the vessel and equipment to ensure that the vacuum
between inner vessel and outer jacket remains intact (Annex 1 gives detailed information
to recognize if a vessel has lost vacuum). If the vessel has lost vacuum, the owner of
cryogenic liquid storage tank shall immediately investigate the cause of the vacuum loss.
2. Where a vacuum loss is believed to be associated with an internal pipe failure, for
example vapour escaping from the vacuum relief device(s), then the cryogenic tank must
be made safe by immediately reducing the pressure to atmospheric and emptying all
cryogenic liquid in a safe manner. The reduction of pressure is the most significant
action to reduce the level of hazard
The inspection should be recorded.
5.2

Inspection during putting into service and periodic inspections

5.2.1 Inspection of the vessel

Prior to putting into service owners of cryogenic liquid storage tanks, fitted with an economiser
circuit, shall consult the tank manufacturer to consider the operation of the economiser piping
within the vacuum space. Tank manufacturers shall consider the piping configuration (flexibility),
temperature range (thermal expansion) and tank dimensions to ensure that the operation of the
economiser circuit will not result in unacceptable stresses which could initiate a fatigue crack in
service. This assessment shall consider the effects of a full constraint of the pipework designed
to accommodate any thermal expansion.
Static cryogenic vessels shall be inspected during putting into service and periodically by a
competent person
The inspection shall consist of:

An external visual inspection of the vessel and equipment to ensure that the vacuum
between the inner vessel and the outer jacket remains
A functional check of valves
Leak tests under operating conditions
Assessing any changes of the operational conditions of the installation and its
surroundings

The inspection intervals are to be determined by the competent person after considering the
operating conditions and the recommendations of the manufacturer.
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The inspection shall be recorded.

5.2.2 Inspection of safety relief devices
The examinations and the inspection intervals are to be determined by the competent person
according to the operating conditions, taking into consideration the recommendations of the
manufacturer, and the periods detailed in EN 13458 -3.
Material properties, corrosion by the medium or from the outside, possible plugging shall be
considered. An alternative to the performance test of the safety valves is to replace it.
Pressure relief devices for oxidising fluids must be free of oil and grease (see also EN
12300.1999). According to the requirements of EN 12300 they shall be suitably certified and
marked.
The certificates/marking shall be examined by a competent person against manufacturer's
declaration/data:

Conformity with drawings, specifications, type approval

Identification, type approval/marking
Suitability (medium, size, temperature pressure, setting)

Within the visual inspection the following should be checked

General condition
Installation/orientation
Leak tightness
Vent location
Unobstructed discharge piping

If a performance test has to be made the following parameters should be checked:

Set pressure
Lift/stroke
Leak tightness
The inspection can be made with the valve installed or on the test bench. The results of the
tests must be recorded and kept at least until the next inspection.
Bursting discs should have a fitment date not greater than the required change out date or
should be replaced. The set pressure shall be less than tank test pressure minus one bar.
6

Taking out of service

This operation shall follow a written procedure and the results of the steps involved should be
recorded. If the vessel is intended for further service, such records should be retained by the
operating company.
The procedure shall include the following:

Depressurisation and emptying of the vessel

When depressurising the vessel, it shall be verified that the valve used for
emptying is not obstructed

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The process shall be checked by monitoring pressure and mass, if necessary
Due consideration should be given to the properties of the product involved

If the vessel is intended to be taken into service again later, the following additional points shall
be considered:

The purging of the vessel and all piping and accessories with inert gas
If the vessel is to be transported or stored, protective caps should be fitted on all open
connections
When in store, a slight positive pressure of dry inert gas shall be maintained in the
vessel and the vessel shall be labelled accordingly
Any problem with the equipment found on removal shall be recorded on the removal
paperwork

If the vessel is to be scrapped, it shall be purged with air and labelled accordingly.
7

Maintenance and repair

Maintenance is required to ensure that equipment remains in a safe serviceable condition. The
responsibility for the maintenance and repair shall be established between the contracting
parties (e.g. owner, user, filler). Following maintenance, the vessel shall comply with the current
approval documentation.
The issue of work permits shall be considered e.g. for hot work, modifications, works on
electrical equipment.
Maintenance generally comprises:

Checking the condition of the vessel, piping and accessories,

Checking the operability of valves,
Minor repairs, e.g. changing of seals,
Cleaning external surfaces.

Maintenance operations shall only be carried out by personnel of the vessel owner trained for
the task, and in line with the original manufacturers design.
Equipment shall not be taken out of service for repair until all pressure has been released.
Carbon dioxide vessels shall be released using a written procedure.
Note: Liquid Carbon dioxide vessels that have lost pressure have to be pressurized using a
written procedure. The material properties of the vessel shall be considered.
Any leakage shall be rectified promptly and in a safe manner. Only original spare parts should
be used. If this is not possible the suitability of the spare part shall be approved by a competent
person. Modifications in design, materials and equipment or repairs shall be approved by a
competent person and documentation updated accordingly (see also EN 13458-1).
Hot work (welding, soldering, heat treatment etc.) shall be carried out to the same procedures
(fabrication, qualification of personnel, testing, certification etc.) as during manufacture.
Where repair or modification have been carried out which may have affected the integrity of the
pressure vessel, the vessel shall be inspected and tested in accordance with the pressure
vessel regulations.
The test shall be carried out by a competent person.
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Vessels and pipe work shall be internally clean, dry and free from particulate matter and
contaminants; vessels for oxidising fluids shall be free from oil and grease, (see also EN
12300).
8

Putting Back Into Service

Vessels that have to be in service again shall be taken out of service according clause 6,
maintained and repaired if necessary according clause 7 and taken into service again according
clause 4.

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Appendix 1 - SAFETY CHECKS FOR VACUUM INSULATED

STORAGE TANKS

Check system for damage.

Any sign of damage to the tank or installation
shall be reported to the operators responsible
person and gas supplier immediately.

Relief valves are not continually venting

Relief valves may vent periodically under

normal operating conditions. However, if
they are venting continually this shall be
reported to the operators responsible
person and gas supplier immediately.
Typical tank relief
valves

Check for abnormal frosting on tank surface

Under normal use frosting and ice will

develop around pipes, valves, controls and
vaporisers as shown in picture 1 opposite.
The operator should inspect the outer skin
of the tank for any new or abnormal signs of
frosting.
The frosting indicated in picture 2 opposite
is an example of an advanced and serious
interspace pipework failure. Abnormal
condensation that can't be ascribed to
morning frost, dew or weather conditions
may appear at the first instance of a failure
before heavy localised frosting develops.
If any abnormal frosting is found, it shall
immediately be reported to the gas supplier.

10

Examples of acceptable and

abnormal icing.

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Check gas is not venting from any part of the

tank surface or connections to it.

Vacuum insulated tanks are fitted with a

device to prevent the outer jacket being
pressurised in the event of a leak from the
inner vessel or interspace pipework. The
operation of this device may be visible
and/or audible as escaping gas from a port
or connection on the outside of the tank and
is an indication of a serious internal problem
with the tank, this must urgently be reported
to the gas supplier.

Examples of vacuum protection

devices

This picture shows gas venting

from a vacuum protection device

General condition and security of the system is

satisfactory.

Check area is clear of debris, general

housekeeping and security is good and that
delivery vehicle access is clear.
NB for liquid oxygen it is essential that the
area around the installation is kept clear of
all combustible material.

Vessel pressure and contents indication is

functioning

In case of doubt report to the operators

responsible person and gas supplier.

Safety warning signs in place

Signage should be in good condition, visible

and kept up to date.

11