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Cite this article as: Chin J Anal Chem, 2007, 35(10), 14551458.
RESEARCH PAPER
Key Laboratory of Gas Geochemistry, Chinese Academy of Sciences, Lanzhou 730000, China
State Key Laboratory of Earth Surface Processes and Resource EcologyCollege of Resource Science and Technology, Beijing Normal
University, Beijing 100875, China
Abstract: The studies of dissolved inorganic carbon (DIC) have important scientific significance and wide applications. In this study,
a series of DIC samples with different concentrations were prepared by using NaHCO3. In this experiment, a novel method was
established to analyze DIC carbon isotope compositions. The results achieved by the method were stable and reliable, and the different
concentration samples showed only 0.20.5 of deviation between the DIC sample and the NaHCO3. By referring to the results of
the control group, this method proved to be effective to prevent the interference from atmospheric CO2 and other organic materials,
which ensured the accuracy of the test results. Besides these, the method has the advantage to meet the requirements of DIC research in
the absence of specialized equipments, and it can be done under the conventional conditions in the lab. The method also does not
require the pretreatment equipments and can be easily done offline. Therefore, the operation is simple, fast, and low cost, and it is
applicable to the various DIC samples in nature, particularly for a lot of DIC samples.
Key Words: Dissolved inorganic carbon (DIC); Carbon isotope composition; Gas chromatography/conventional isotope-ratio mass
spectrometry
Introduction
Experimental
2.1
Principle
13C =
2.3
Reagents
Sample preparation
Experimental procedure
Table 1 13C Values with different concentrations and different balance time (PDB)
Sample
1
7.3 ~ 7.6
7.4
7.3 ~ 7.6
7.5
7.4 ~ 7.8
7.7
7.2 ~ 7.5
7.4
A
B
C
D
E
Range
Difference value
Balance time / h
4
8
7.1 ~ 7.6
7.6 ~ 8.0
7.2
7.9
7.2 ~ 7.7
7.3 ~ 7.6
7.6
7.4
7.0 ~ 7.5
7.5 ~ 7.8
7.3
7.6
7.2 ~ 7.6
7.4 ~ 7.8
7.5
7.6
24
7.6 ~ 8.3
7.4
7.8 ~ 8.1
7.9
7.6 ~ 8.0
7.7
7.7 ~ 8.1
7.8
0.3
0.4
0.5
0.3
0.7
0.8
0.6
0.3
Range
Difference value
0.8
0.2
0.5
0.3
0.4
0.5
0.4
0.4
Range a are the values of samples with the same concentration and different balance time; range b are the values of samples with the same balance time and different
concentrations. Difference value a was the 24-hour sample value deviation from 13CNaHCO3, and the difference value b was the same balancing time sample deviation from
13CNaHCO3.
A-2
B-2
C-2
9.8
9.6
9.2
10.2
9.9
10.8
3
11.1
10.5
10.0
4
10.5
11.2
9.5
Average
9.6
10.2
9.7
10.2
10.3
9.8
acquired.
Acknowledgments
We thank two anonymous reviewers for their valuable
comments that improved an earlier version of the manuscript.
We also thank Dr. Taofik, who is from Nigeria, and Li Jing
from Beijing Normal University for their constructive
comments to improved the manuscript.
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