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TERMODINMICA

2)

U= q-w

Datos

a) Como el proceso es adiabtico q=0

No. De moles: 1.5 moles


Y U=-w nCv T
T1= 15*C= 288.15 K
P1= 9 atm

V1= nRT1/P1= (1.5 mol)(0.0821atm.L./mol.K)(288.15K)/(9 atm)


V1= 3.94 L

V 1= ?

V = V2-V1

T2= ?

V2= V+V1 = (1.5L)+(3.94L)= 5.44L

P2= 1.5 atm

T2= P2V2/nR= (1.5 atm)(5.44L)/(1.5 moles)(0.0821atm.L/mol.K) = 66.26


K

V 2= ?
Cv=28.8 J/mol.K

d) T= T2-T1= (66.26K)-(288.15K)= -221.89 K


V=1500 cm = 1.5 L
c) U=nCv T=(1.5 moles)(28.8J/mol.K)(-221.89K)= -9,585.64J
3

Proceso adiabtico

b) w= - U= -(-9,585.64J)= 9,585.64 J
e) S=0 ya que no hay calor reversible

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