Unitbch 1 L 3

Science 30 2007 Alberta Education (www.education.gov.ab.ca). Third-party copyright credits are listed on the attached copyright credit page.
1.3 Impact of Acid Deposition on Ecosystems
Figure B1.26: Data collection is an important process toward developing an understanding of the interactions of substances within ecosystems.
The study of environmental chemistry involves more than just the detection
of substances. Scientists who study the environment conduct investigations
to determine whether there is evidence of change in the environment. The
area of the forest shown in Figure B1.26 has very little vegetation on the
ground. Is there a connection between the dropped needles covering the forest
floor and the amount of plant growth beneath these trees? Is the lack of plant
growth related to the soil pH? Studies performed by environmental scientists
in the field are a critical link toward understanding the changes that occur in
ecosystems versus those that might be predicted.
Predictions currently being made by scientists rely upon the knowledge
that comes from careful study of interactions within the environment. As many
scientists will tell you, the complexity of interactions within an ecosystem
Figure B1.27: Some mushroom species and some
plant species can grow in the soil directly underneath
makes the current level of understanding limited. Since the environment is
pine trees.
the one thing that all organisms share, research is necessary to understand its
ability to cope with stress from pollution.
In this lesson you will expand your knowledge of the complexity of ecosystems and the chemical interactions that can
occur. Before you continue, however, do you have a hypothesis that describes the relationship between the presence of
emissions in the environment and their effects? What kinds of experiments would you need to conduct to test and support
your hypothesis? Do you have an idea of what you might expect to observe?
Given all that you have learned about the ability of some substances within emissions to react with water, does a
relationship exist between the presence of these substances in water and the waters acidity? In a previous investigation,
the emissions from burning coal acidified water. Do similar reactions occur in nature? In the next investigation you will
have the opportunity to analyze data and gain further insight into this question.
188
Unit B: Chemistry and the Environment
Testing a Hypothesis
Purpose
You will investigate the relationship between the presence
of substances in rainwater and the pH of rainwater.
Science Skills
Analyzing and Interpreting
Communication and Teamwork
Background Information
In previous courses you described the relationship between two variables as a direct variation, an inverse variation,
or having no relationship. In this investigation you will analyze the data collected from rainwater and determine
which type of relationship is demonstrated. The data provided are from rainfall monitoring sites throughout Alberta.
Included in the data are information about the quantity of rainfall, pH, total acidity of rainfall, and the nitrate and sulfate
concentrations. Each of these headings is considered to be a variableinformation that was measured and recorded
during this study.
Pre-Lab Questions
1. Identify a relationship between two of the variables (sets of information) listed in the
background information.
2. Describe the relationshipdirect variation, inverse variation, or no relationshipyou
feel exists between the two variables defined in question 1. Explain why you chose
this relationship.
3. Predict what you think the trends within the data for these two variables will show.
4. Repeat questions 1 to 3 for other combinations of variables you feel will demonstrate
a direct variation, an inverse variation, or no relationship.
Materials
computer with a spreadsheet program (e.g., Excel)
printer
Procedure
direct variation: a
relationship between two
related variables where an
increase in the magnitude
of one variable results in an
of the related variable
inverse variation: a
relationship between two
related variables where an
of one variable results in a
decrease in the magnitude
of the related variable
no relationship: a situation
where no recognizable
pattern is demonstrated
between two variables
Open the Rainfall Data spreadsheet on the Science 30 Textbook CD.

Check with your teacher for directions about how many areas within
this spreadsheet you will be analyzing. Complete the following steps for each set of data you analyze.
step 1: Identify the headings listed in the background information as they appear on the spreadsheet.
step 2: Graph two or more variables shown in the data. Use appropriate titles and axes labels. Then save your graph.
step 3: Repeat step 2 for other data you may want to investigate or for other areas your teacher instructs you to
analyze. Save any additional graphs.
step 4: On each graph, use a text box to insert the hypothesis between the variables graphed.
step 5: Describe any trends on each graph. Add labels and descriptive text to your graphs that indicate these regions.
step 6: On each graph, write an explanation of how the trends or patterns demonstrated by the data support or do not
support the hypothesis.
step 7: Create a new document that includes each of the graphs analyzed. At the front of this document, create a
summary table that lists the variables that were compared and the relationships identified. Ensure that the
order in which the graphs appear is logical and easy to reference from the summary table.
step 8: Below the summary table described in step 7, write a brief commentary indicating whether the relationships
between variables you investigated were consistent with the relationships you predicted earlier. Indicate how
these relationships are consistent with or differ from what you know about acid deposition.
step 9: Print a copy of the document containing the summary table, commentary on trends and relationships between
variables, and the annotated graphs you prepared during your analysis.
Chapter 1: Acid Deposition
189
Utilizing Technology
Wind Patterns
The Testing a Hypothesis investigation provided an opportunity for you to use data to test a hypothesis you developed. As you
may have expected, higher levels of sulfates and nitrates in rainwater result in a higher concentration of hydronium ions in the water
(direct variation) and, thus, results in a lower pH (inverse variation). These types of relationships are consistent with what is known
about the effect of natural and human-made sources of emissions and their respective roles in the production of acid rain.
As mentioned earlier, many other factors can have an influence within an environmental system. One of these factors is
wind. Weather in Alberta can be quite variable. There is a saying, If you dont like the weather in Alberta, wait five minutes.
One day it is excessively hot; the next day you are sure it is going to snow. In the next activity you will look at a major feature
of the weather patterns across North America. As you complete this activity, remember to consider what influences weather
patterns might have on acid deposition.
Prevailing Wind Patterns
Science Skills
Procedure
Part A: Map of Canada and the US
Cold front
Warm front
High pressure
Low pressure
Figure B1.28: Precipitation and wind are weather patterns that influence
acid deposition.
Purpose
You will examine the prevailing wind patterns in Alberta
and in Canada.
Have you completed a field study where you measured
wind speed and direction? Wind is an abiotic factor of
an ecosystem. Wind enables the movement of matter,
whether it is water vapour in clouds, solid matter eroded
by winds, or gases within atmospheric currents. The
jet stream is the most influential wind current in North
America. In this activity you will be asked to locate,
download, and assemble information about wind
patterns. The maps you create in this activity will be used
in other activities within this lesson to further investigate
issues related to acid deposition.
Materials
computer with Internet connection
handouts from the Science 30 Textbook CD
Map of Canada and the US
Map of Alberta (2 copies)
190
step 1: Search the Internet for images of daily,

monthly, and seasonal patterns of the
jet stream.
step 2: Draw a line representing an approximate average
location for the jet stream across North America.
step 3: Determine the direction of the winds in areas
north and south of the jet stream. Use vector
arrows to indicate the direction of the winds on
your map.
Part B: Map of Alberta

step 1: Search the Internet for images of daily,
monthly, and seasonal wind patterns in
Alberta.
step 2: Use vector arrows to indicate the direction of
the winds in Alberta. Note: If you notice there is
a change in the direction of wind patterns in the
province during different seasons, use additional
maps to identify these patterns. Ensure that all
maps are properly labelled.
Analysis
1. Define the term jet stream. State the general direction
of the jet stream.
2. Explain the effect the jet stream has on weather and
climate in western Canada.
3. Comment on the statement, Wind patterns in Canada
and Alberta are always the same.
4. From your analysis of wind patterns, does Canadas
position in the northern hemisphere ensure that air
transported by currents, such as the jet stream, are
relatively clean and unpolluted?
Wind patterns like the jet stream provide a way for acid deposition to be transported. As you will see later, acid deposition can
be transported short and long distances. The predictability of wind patterns provides a way to trace the path of acid deposition
back to its source. What happens to an ecosystem when acid deposition settles? How would it affect the plants, soil, and water
it touches? Maybe the next activity will help you answer these questions.
Investigation
Acid Deposition and Its Effect on
Simulated Lake WaterDemonstration
Science Skills
Performing and Recording
This demonstration should be performed only by

your teacher. Avoid exposure to sulfur dioxide.
Do not handle any of the solutions used in this
demonstration.
Purpose
You will see a demonstration of the effect of acid
deposition on simulated lake water.
Data Collection
step 1: Construct a data table with the headings
Cylinder, Initial Colour of Contents, SO2(g) Added,
Water Spray Added, CaCO3(s) Added, and
Relative Time for Colour Change.
step 2: Observe the colours of the contents of each
cylinder before adding the SO2(g). Record each
colour in your table.
step 3: Record which cylinders had SO2(g) added, which
had CaCO3(s) added, and which received water
spray.
step 4: To simulate the mixing effect made by waves
and by water currents, swirl the contents of each
flask once during each 10-min interval. Observe
changes to colour and other aspects over the
next 50 min. Record any changes that occur over
each 10-min interval.
Analysis
Materials
5 large graduated cylinders
simulated lake water
bromocresol green indicator
calcium carbonate, CaCO3(s)
spray bottle containing water
sulfur dioxide (prepared prior to demonstration)
stopwatch
Experimental Design
Samples of simulated lake water will be placed into
each cylinder. A small piece of calcium carbonate will be
added to two of the cylinders. To test the cylinders, sulfur
dioxide gas will be added. A spray bottle of water will be
used with some of the cylinders to simulate precipitation.
All cylinders will be monitored for changes that occur and
the length of time over which the changes occur.
1. Earlier, you discovered the importance of experimental

controls. Identify the cylinders that were experimental
controls. Briefly describe their purpose. In some
experiments, only one control is used. Why are two
control cylinders used in this experiment?
2. Identify the samples of simulated lake water that were
exposed to wet acid deposition, that were exposed
to dry acid deposition, and that were not exposed to
acid deposition.
3. Describe the effect that CaCO3(s) had on the simulated
lake-water samples. Support your answer using the
evidence collected during the experiments and, if
possible, a balanced chemical equation.
4. This demonstration was designed to simulate
conditions that could occur in nature. List natural
sources of CaCO3(s). Explain how CaCO3(s) could
come into contact with lake water to form a chemical
system.
191
The Jet Stream and Acid Deposition
Effects of Acid Deposition on the Environment and Ecosystems

Acid deposition can affect the pH of water.
The hydronium ions formed during the chemical
reaction between acids and water not only act to
lower the pH of a body of water, but can react
with other substances in the system. Carbonate
ions, CO32-(aq), are a naturally occurring base
present in many bodies of water and in the soil.
In Alberta, the pH of most lakes is above 7 and
can be as high as 8.3. The slightly alkaline pH of
the lake water is due to the presence of dissociated
carbonate ions that enter the water from
dissolving minerals, such as calcium carbonate
and magnesium carbonate present in limestone.
land transport and deposition

by water, wind, and ice
weathering and erosion
Figure B1.29: Erosion caused

by the action of water
over the layers of
sedimentary rock
deposits
ocean
minerals
transport and
in soil
deposition by
currents and
chemical precipitation
alkaline: having the properties of a base

mineral: a solid, inorganic chemical compound
produced by natural chemical processes
burial and lithification

into sedimentary rock
Major Rock
Categories
Sedimentary
Sedimentary
and Volcanic
Volcanic
Metamorphic
Intrusive
Figure B1.30: Geological events have resulted in a variety of rock types in Canada.
Figure B1.31: Soil contains small particles (a component of which is shown in this magnified sample) of eroded rocks from layers of exposed sedimentary rock.
The chemical composition of the rock within a region influences the sensitivity of soil and lakes to acid deposition.
192
Reaction of Hydronium Ion and Carbonate Ion

loses a hydrogen ion
H3 O + (aq) + CO32 - (aq)

acid
base
H2 O (l)
conjugate
base
+ HCO3 - (aq)
Practice
Obtain a copy of the handouts Potential
of Soils and Bedrock to Reduce Acidity
and Major Rock Categories from the
Science 30 Textbook CD. Use these maps
to answer questions 29 to 36. In developing your
answers, consult both maps and look for similarities,
differences, and correlations.
29. Do all areas of Canada have similarities in their
ability to neutralize acid deposition?
30. Indicate regions in Canada that have the highest
potential to reduce acid deposition.
31. Do all of the areas with the highest potential to
reduce acid deposition have a similar rock type?
If so, identify it.
32. Indicate regions in Canada with the least ability to
reduce acid deposition.
33. Do all of the areas with the lowest potential to
reduce acid deposition have similar rock types?
If so, identify the types of rock found in these
regions.
34. Do all regions of Alberta have equal potential to
reduce acid deposition? Support your answer.
35. Predict the effect of acid deposition on the pH of
soil and the pH of lake water in Canada. Do you
expect the pH values to increase, decrease, or
remain constant? Explain why there may be more
than one answer.
36. Within the map depicting the potential of soils to
reduce the acidity from the atmosphere, there is
a table describing aquatic sensitivity by province.
Use this information to answer questions 36.a.
to 36.d. Note: Zooming in on this table on your
computer monitor will provide a clear view of the
information.

a. Identify the province with the largest

percentage of lakes with a high sensitivity to
acid deposition.
b. Identify the province with the lowest

percentage of lakes with a high sensitivity to
acid deposition.
c. Is there a correlation between the sensitivity of

lakes to acid deposition and the sensitivity to
soil within a province? Explain whether there
is a direct variation, indirect variation, or no
relationship between the sensitivity of lakes
and soils to acid deposition.
d. Hypothesize a reason for the relationship you

identified in question 36.c.
conjugate
acid
gains a hydrogen ion
Only a small percentage of soils in Canada have a high

potential for neutralizing acid deposition. Much of the soil
within the province of Alberta has a high potential, mainly
due to the presence of carbonate.
193
The area now

called Alberta
has undergone
many geological
changes. Many
times throughout
its history, Alberta
has been covered
by water. The
coral reefs that
developed at the
bottom of these
oceans were made
up of calcium
carbonate, CaCO3(s).
Over time, the layers of
calcium carbonate formed
into limestonea type of
sedimentary rock. As limestone
undergoes erosion, small crystals
of calcium carbonate present in the
limestone form particles in the soil.
The chemical components of soil
have a great impact on its sensitivity to acid deposition. In
the acid deposition demonstration earlier, the acid deposited
into some of the cylinders containing simulated lake water
was neutralized. Recall that the reaction between hydronium
ions and carbonate ions involves the transfer of a hydrogen
ion. The carbonate ions, acting as acceptors for hydrogen
ions, convert hydronium ions into water molecules, thereby
neutralizing the acid.
Buffering and Buffering Capacity

The neutralization of acid deposition by bases, such as calcium carbonatewhether present in
buffering: a
the soil, bedrock, or lake waterprevents the accumulation of hydronium ions. An increase in the
chemical reaction to
minimize a change
concentration of hydronium ions makes a solution more acidic and lowers the solutions pH. As
to the hydronium-ion
you will soon see, pH is an important factor that contributes to the viability of ecosystems; and
concentration in soil
changes in pH can have drastic effects on the survival of many organisms. The neutralization of
or water
acids by bases that prevents any change to the pH of soil or lake water is called buffering.
buffering capacity:
As you may expect, some areas exposed to acid rain for longer periods of time eventually
the relative ability of
a substance to resist
develop soil or surface water with lower pH values. In these situations, the accumulation of
change to its pH
hydronium ions is due to an absence of basic substances within the soil or water. Buffering
despite the addition
capacity is a measure of the amount of acid that can be neutralized by soil or surface water. In
of an acid or base
the acid deposition demonstration you observed earlier, which samples of lake water had the
highest buffering capacity? If you look back at The Potential of Soils and Bedrock to Reduce the Acidity of Atmospheric
Deposition map, can you predict which regions have higher, moderate, and lower buffering capacities?
Response of Plants to pH
Plants respond to the level of acidity in a variety of ways. The
area directly underneath conifers is often lacking any other
plant growth. As needles fall from pine and spruce trees to
the ground, acids from the needles are transferred to the soil.
This results in acidification of the soil. Few species of plants
can tolerate the low pH of the soil immediately underneath
these trees. Similarly, crop plants used in agriculture have
limited tolerance for variation in pH. Therefore, it is important
for farmers to select crops best suited to the pH of the soil.
Soil exposed to acid deposition or to certain crops can
become acidified and, as you will learn later, must be properly
managed to remain fertile.
DID YOU KNOW?
The dark patches on

this potato are potato scabs,
the result of an infection by
bacteria that live in the soil.
Although the infection does
not affect the taste of the
potato, farmers often choose
to plant potatoes in soils with
a pH below 5.3 to prevent the
development of potato scabs.
The bacteria cannot tolerate a
pH this low.
194
agricultural plants and soil pH

for optimal growth
Plant
Soil pH for Optimal Growth
alfalfa
6.5 to 7.0
barley
6.3 to 6.5
blueberries
4.5
canola
5.5 to 8.3
clover
5.8 to 6.2
corn
5.8 to 6.2
oats
5.8 to 6.2
pasture grass
5.5 to 6.2
sugar beets
6.5 to 8.0
potatoes
5.2 to 8.0
wheat
5.5 to 6.5
DID YOU KNOW?
Canola
is a variety of the
rapeseed plant. Canola
was developed by
selective plant breeding
technologies to produce
an oil with specific
properties.
Reactions between acids and minerals in the soil are important

to the cycling of matter as described in biogeochemical cycles.
In previous science courses you examined cycles that describe
the conversions of carbon, oxygen, nitrogen, and water in the
environment. Reactions involving other elements are of equal
importance to environmental scientists. Calcium ions, Ca2+(aq),
are one of the required nutrients for plant growth. The reaction of
CaCO3(s) that neutralizes acids present in rainfall is one manner
in which calcium ionsnormally bound to carbonate and other
ionsbecome available to plants.
Other nutrients are listed in Figure B1.32, along with their
function. One of these functions is the production of chlorophylthe
molecule essential for photosynthesis and for influencing a plants growth
or reproduction.
biogeochemical cycle: a diagram representing the

movement of elements and compounds between
living and non-living components of an ecosystem
REQUIRED PLANT NUTRIENTS

Type
macronutrients
(essential nutrients
needed in large
quantities)
micronutrients
(essential elements
needed in small
quantities)
Element
Forms Used by Plants
Function
calcium
Ca2+
important for root growth

component of cell walls
magnesium
Mg2+
essential for chlorophyl formation
nitrogen
NH4+, NO3-
phosphorus
PO43-, HPO42-, H2PO4-
potassium
K+
boron
BO33-, B4O72-
chlorine
Cl-
copper
Cu+, Cu2+
iron
Fe2+
required for the production of chlorophyl

and oxygen
manganese
Mn2+
required in reactions to make sugars and

chlorophyl
molybdenum
MoO42-
zinc
Zn2+
essential for proper leaf and stem growth

protein synthesis
important for germination and growth
of seeds, root growth, flower, and fruit
production
promotes quick growth and disease
resistance
required for transporting matter within
plant and for reproduction
may affect use and production of sugars
by plant
important in plant reproduction
required for reactions that convert nitrogen

in the atmosphere into forms that plants
can use
required for protein synthesis and
reactions involving sugars
Figure B1.32: Some plant nutrients may take a variety of forms; but each nutrient is involved in an important role in plant growth, function, or reproduction.
195
Plant Nutrients, Metal Leaching, and pH
Plants absorb
nutrients from the soil
through their roots.
Prior to planting,
farmers may conduct
a soil analysis to
determine the mineral
and nutrient content
of the soil. Plants have
an optimal pH for
growth. In addition to
pH, many plants also
have specific nutrient
requirements.
Figure B1.33: The yellow leaves of the
Acid deposition
soybean plant in this photo are the result of
can present another
chlorosisnutrient deficiencies in the soil.
problem that
complicates the ability to grow plants or crops. Nutrients
must be in a form that allows them to be absorbed through
the roots of plants.
A change in soil pH can result in the formation of insoluble
forms of these nutrients, making them unattainable by roots.
Chlorosisthe yellowing of plant leaves due to a lack of
chlorophylis caused by nutrient deficiencies in soil. The
yellow appearance of plant leaves is one indicator that a
plant may have been exposed to acid deposition. As shown in
Figure B1.34, the availability of nutrients is affected by pH.
Can you identify a general trend regarding the availability
of the nutrients over the pH range shown?
The addition of acids to the soil can make metal ions, like
Ca2+ and Mg2+, available to plants. Hydronium ions present in
soil, as a result of prolonged acid deposition, can react with
other compounds in the soil. One effect of prolonged acid
deposition is the leaching of aluminium ions, Al3+(aq), and
mercury(II) ions, Hg2+(aq).
leaching: extracting a substance from a solid
by dissolving it in a liquid; the removal of metal
ions from topsoil that allows for their movement
into lower levels of soil or into surface water
Within soil, aluminium ions are normally bound to

hydroxide ions as aluminium hydroxide, Al(OH)3(s). Since
aluminium hydroxide does not dissolve in water easily, very
little dissociation occurs. This keeps the concentration of
aluminium ions in the soil very low. When exposed to acids,
the chemical reaction between aluminium hydroxide and
hydronium ions allows aluminium ions to exist as dissociated
ions in the soil. Unless precipitated by a reaction with
another substance in the soil, the concentration of aluminium
ions will accumulate over time. Higher concentrations of
aluminium ions can affect plants and soil in many ways,
including

decreasing the growth of roots

preventing the absorption of calcium
reducing the population of soil bacteria involved in
the decomposition of dead plant matter
Higher concentrations of aluminium ions in lakes and

streams are toxic to fish. Exposure to aluminium ions has
been known to damage the gills of older fish and
Nutrient Availability and pH in Soil
increase the number of deaths of young fish.
Soil pH
Mercury is another metal found in soil, but
4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0
in very small amounts. In acidic soils, a reaction
between hydronium ions and compounds
nitrogen
containing mercury can occur, resulting in the
phosphorus
leaching of mercury(II) ions, Hg2+(aq). Once in
potassium
the water or in the soil, micro-organisms convert
mercury(II) ions into methyl mercurya
sulfur
substance that is rapidly absorbed by other
calcium
organisms. Mercury has no real function in
magnesium
living things and cannot be excreted. Since it
is not removed, mercury tends to accumulate
iron
within cells and tissues of exposed organisms
manganese
over their lifetime, often to levels that can be
boron
toxic to the organism itself and to any other
copper and zinc
organism that consumes it.
molybdenum
Note: The thickness of the bar indicates the relative
concentration of the nutrient available to plants.
Figure B1.34: Soil pH influences the availability of nutrients. The thickness of the bars
indicates where soil concentrations of each nutrient (in forms that plants can absorb) are
highest and lowest.
196
Sun
seal
(3.0 g/g body mass)
polar bear
(15 g/g body mass)
phytoplankton
krill
fish (0.081 g/g body mass)
Figure B1.35: The transfer of energy within a food chain can also be used to demonstrate biomagnification of mercury.
Biomagnification can occur with a variety of substances. Regardless of the substance, bioaccumulation occurs because of
the inability of an organism to use or eliminate the substance. In a situation where biomagnification occurs, the concentration
of mercury within the body of each organism is higher than the concentration of mercury in its environment. Also, as you
compare the concentration of mercury at each successive level of the food chain, you will see that there is a significantly
higher concentration in the tissues of a predator than in its prey. Can you estimate the magnitude of the change?
Mercury poisoning occurs when the concentration of mercury within an organism reaches a toxic level. In many
ecosystems, an organism suffering from mercury poisoning tends to be high up in the food chain. Where do humans fit in a
food chain? Do you think information about the bioaccumulation of mercury in food chains would be useful to Aboriginal
communities, many of whom have retained their traditional diets?
Acid deposition can cause other metals to have toxic effects on an ecosystem through leaching. These metals include lead,
zinc, copper, cadmium, chromium, manganese, and vanadium.
biomagnification: the tendency of a pollutant to appear at higher concentrations at higher levels in a food chain
197
Concentration of Mercury in Body Tissue
In environmental science, the concentration of a substance is expressed in many ways. You have seen that hydrogen-ion
concentration can be expressed as mol/L or as pH. Because the concentrations of substances that bioaccumulate are very low,
units like mg/g of body mass, parts per million, parts per billion, and even parts per trillion are used. The formula to calculate
parts per million is in the Science Data Booklet. You can adapt this formula to parts per billion by replacing 106 with 109 or to
parts per trillion by replacing 106 with 1012.
Practice
37. The plant in this photograph was grown in soil with a
pH of 5.5.
40. Scientists sampled fish from one lake over a ten-year

period and collected data on the concentration of
mercury within the bodies of the same species of fish
of various sizes. The graph given summarizes the
data they collected.
Mercury Levels in Fish

40
a. State the name that describes the yellowing of

the plant leaves.
b. Explain why the plant leaves are yellowing.
c. Indicate a possible cause for the condition of the

plant.
d. Explain the relationship between soil pH and the

yellowing of the plant leaves.
Mercury Level (ppm)
Expressing Concentration
b. The concentration of mercury in krill is 1000 times

greater than that of phytoplankton. Calculate the
concentration of mercury in phytoplankton.
198
<10
1520
2025
2530
3035
10
Length of Fish (cm)
39. Use the information in Figure B1.35 to calculate

concentration levels of mercury in other organisms
in the arctic food chain.
a. Fish concentrate mercury to a level 500 times
greater than the concentration of mercury in the
krill they consume. Calculate the approximate
concentration of mercury in krill.
20
38. The term biomagnification refers to the progressive

buildup of heavy metals (or other substances)
in successive levels of a food chain. Use the
concentrations of mercury in Figure B1.35 (on
page 197) to calculate ratios of the concentration
of mercury in a seal and a polar bear relative to
their prey. Explain how the ratios you calculated
demonstrate that bioaccumulation is occurring.
30
The scientists who conducted the study concluded

that mercury levels are higher in older fish.
a. How does the data support this conclusion?
b. Concisely explain why the older fish most likely

have a higher concentration of mercury in their
bodies than the younger fish.
c. Identify one experimental control used in the

study. Explain the importance of this control.
Effect on Biotic Factors
Effects of Acid Deposition
on Ecosystems
Purpose
You will examine information describing the effects of
acid deposition on ecosystems in Montserrat and in
eastern Canada.
Science Skills
Procedure
In your study of ecosystemsand maybe even during a
field studyyou may have measured temperature, moisture
content of soil, amount of sunlight, soil pH, and other abiotic
factors. The pH of soil within an ecosystem can determine
the type of plants that will grow. In turn, the types of plants
present can determine the types of animals that exist within
the community. Changes to the abiotic factors, especially
those brought about by acid deposition, have an impact on
the biotic factors within an ecosystem.
Recall that soil bacteria can be directly affected by
acid deposition or indirectly affected by changes to the
concentration of metal ions due to leaching. Besides
affecting a plants ability to produce chlorophyl, causing
chlorosis, acids that directly contact plants damage the
protective waxy coating on leaves. The loss of this coating
permits further damage to the leaf, either by additional acid
or by disease.
Aquatic organisms also demonstrate sensitivity to changes
in pH. These changes are summarized in the Sensitivity of
Aquatic Organisms to pH handout on the Science 30
Textbook CD. Because ecosystems involve complex
interactions between many organisms, any change
that impacts the health and survival of one organism
affects the biodiversity of the whole ecosystem. How would
you use the information in this table if you were asked to
investigate whether acid deposition was affecting the area
where you live? In the next investigation you will look at
some locations where acid deposition has occurred and read
about the effects.
The information for this activity is located

on the Science 30 Textbook CD. Obtain the
document Case Study: Eastern Canada.
Read the case study; and use the information, along
with what you have learned in this lesson, to answer
questions 1 to 3.
Analysis
1. Are the changes to the environment in eastern
Canada the result of acid deposition only? Identify
any other sources that may have contributed to
these effects.
2. Describe the type of data used in the material
you read. Was adequate information provided
regarding the effects acid deposition had on
these ecosystems?
3. Evaluate the descriptions provided about the
changes to the environment in eastern Canada.
Are the descriptions and claims consistent
with what you learned about the effects of acid
deposition? Identify any similarities.
abiotic factor: a physical, non-living part of the environment

biotic factor: a living organism in the environment
biodiversity: the variety of life in all its forms, including the
genetic diversity and numbers and types of organisms within
an ecosystem
199
Try This Activity

Assessing Factors Involved in Acid Deposition in Alberta
Science Skills
Throughout this chapter you examined activities that produce emissions

related to acid deposition. The major processes that produce emissions
of SO2(g) and NOx(g) in Alberta include
Performing and Recording

the production of electricity by the combustion of coal, natural

gas, or biomass

upstream petroleum and gas production, including the processes of exploration, extracting, and processing
(refining) petroleum and natural gas such as
sour gas flaring
sweetening or removal of sulfur from sour natural gas
removal of sulfur from crude oil

oil sands (tar sands) production

transportation

use of fossil fuels as a heat source in homes or in industry (considered as stationary sources)
You also discovered that wind and quantity of precipitation can be major factors in determining where deposition
of acidic particles or solutions will occur. In addition, you studied how the role that soil components, including calcium
carbonate from limestone, can have in neutralizing acids. You also saw how acid deposition affects abiotic and biotic
components of the environment and how this may impact the balance that exists within ecosystems.
With what you know about acid deposition, it is logical to wonder about Albertas situation.
Purpose
You will research emissions related to acid deposition to obtain a clearer picture of the impact of acid deposition.
Procedure
Obtain the following handouts from the Science 30 Textbook CD.

Map of Alberta
Canadian and US Crude Oil Pipelines and Refineries
Gas Flaring and Venting in Alberta
All Generating Stations by Fuel Used (1997)
Sour Gas Facilities in Alberta
Note: Zooming in on this data on

your computer monitor will provide
a clear view of this information.
step 1: Consult with your teacher regarding the magnitude of the area for which you are required to collect information.
Is it only for your local area? province? country?
step 2: Gather information (from this textbook, the Internet, or other materials) about the following topics:

potential of soils to reduce effects of or neutralize acid deposition

direction of prevailing winds
locations of electrical power generation facilities
locations of gas wells, flares, and sour gas processing facilities
locations of oil wells, flaring, and oil refining
locations of tar sands (oil sands) processing
amount of precipitation, both as rain and as snow
pH of rainfall
locations of major bodies of water (including rivers and lakes)
step 3: On a map of Alberta, record in an organized manner the information you collected. If codes, colours, or
symbols are used, be sure to include a legend.
Analysis
Use the information on your map to identify locations in Alberta where you either

(1) consider acid deposition to currently be a problem
(2) predict acid deposition will be a problem in the future
Justify your answer.
200
1.3 Summary
In this lesson you learned about the complexity of the environment by studying the effect acid deposition has on soil
and on the living components of ecosystems. You were introduced to the effects weather patterns (e.g., prevailing
winds and precipitation) have on the transfer and deposition of acidic substances. You examined the chemical
interactions between substances in the soil and hydronium ions and how these interactions can result in buffering or
in leaching of metal ions. Leaching metals can be a problem associated with acid deposition. Leaching may result in
the loss of nutrients from soil or an increase in the concentration in either the soil or water of certain metals that can
be toxic. Mercury is an example of one metal that may biomagnify within a food chain when leached from soil. You
then looked at examples from eastern Canada where acid deposition has occurred. Finally, you were asked to analyze
a number of factors and apply your understanding to the situation in Alberta. In the next lesson you will examine the
processes used to monitor and study acid deposition.
1.3 Questions
Knowledge
1. Define the following terms.

a. jet stream
b. alkaline
c. minerals
d. buffering
e. buffering capacity
f. biogeochemical cycles
g. leaching
h. biomagnification
i. biodiversity
2. State the type of relationship that exists between the concentration of sulfur dioxide, SO2(g), in the atmosphere and
the pH of rain.
3. a. Name the type of rock that has a high buffering capacity.

b. Identify the chemical compound present in the rock type identified in question 3.a.
c. Write the chemical equation between the hydronium ions and the chemical substance identified in question 3.b.
4. List factors that contributed to the occurrence of acid deposition in eastern Canada.
5. Is acid deposition entirely the result of human activity? Support your answer.
201
Applying Concepts
6. At the start of this lesson you were asked to develop a hypothesis describing a relationship between the presence of
emissions in the environment and their effects.

a. State a hypothesis that describes a relationship between the presence of emissions in the environment and their
effects.
b. List experiments you need to conduct to test and support your hypothesis.
c. The people within a community who are closely connected to the local surroundings are often the first to notice
environmental change. Identify a societal group you can consult with to determine whether they have noticed
environmental changes.
d. Which type of information will you collect from the sources identified in question 6.c.? Explain how this information
would help you understand the relationship between emissions and their effects on the environment.
7. Use your knowledge of soil pH to explain how it is possible for soil to be rich in nutrients but unable to support good
plant growth.
8. In a study of soil exposed to acid rain, measurements of calcium ions and aluminium ions were taken at regular intervals.
Ratios of the concentrations of calcium ions to aluminium ions are shown in the following table.
Ratio
Soil Sample
[Ca2+] : [Al3+]
1
(pre-acidification)
1:1
concentrations of calcium ions and aluminium

ions similar to control soil samples
2
(early stages of acidification)
2:1
signs of stress observed in some plant species
3
(late stages of acidification)
0.2 : 1
extreme stress observed in many plant species
Comments
a. Explain why the level of calcium ions present in soil changed.
b. It was hypothesized that the concentration of aluminium ions in soil would increase as the soil became acidified.
Explain whether the ratios listed in the table support this statement.
9. Aluminium is often present in the soil as aluminium hydroxide, Al(OH)3(s).
a. Write the balanced chemical equation that occurs between hydroxide ions in the soil and hydronium ions in acid rain.
b. Explain how the reaction of hydroxide ions with hydronium ions could bring about the leaching of aluminium ions
into stream and lake water.
10. A study investigating biomagnification sampled the different tissues of fish, seals, and polar bears in an arctic food chain.
Concentration of Mercury
(mg/g body mass)
Tissue Sample
Fish
Seal
Polar Bear
muscle
0.079
0.25
0.07
liver
0.080
3.0
15
kidney
0.080
1.2
15
a. Explain how the data demonstrates that mercury biomagnifies within a food chain.
b. Hypothesize why differences may exist in the concentration of mercury in different tissues in some organisms.
c. Explain how the results of this study may impact the work of other scientists.
11. The accumulation of acid deposition in soil and water can result in a lowering of pH, which causes a decrease in the
number of bacteria that decompose plant and animal matter in an ecosystem. Explain how a decrease in the number
of bacteria that decompose plant and animal matter would negatively affect an ecosystem.
202
Photo Credits and Acknowledgements

All photographs, illustrations, and text contained in this book have been created by or for Alberta Education, unless noted herein or
elsewhere in this Science 30 textbook.
Alberta Education wishes to thank the following rights holders for granting permission to incorporate their works into this textbook.
Every effort has been made to identify and acknowledge the appropriate rights holder for each third-party work. Please notify Alberta
Education of any errors or omissions so that corrective action may be taken.
Legend: t = top, m = middle, b = bottom, l = left, r = right
188 (t) Bryce Kroll/iStockphoto (br) Courtesy of iStockphoto.
com 192 (bl) NASA (br) Jim White/shutterstock 194 (br) Cesair/
shutterstock (b) Ewa Brozek/shutterstock 195 sierpniowka/
shutterstock 196 (t) Reid Frederick, USDA, ARS, Ft. Detrick, MD 198
(tl) David B. Langston, University of Georgia, United States (br)
Roberto Bottazzi/iStockphoto 199 (tl) Mike Norton/shutterstock (br)
Joan Kimball/iStockphoto 201 Photodisc/Getty Images

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1.3 Impact of Acid Deposition on Ecosystems

Unit B: Chemistry and the Environment

Open the Rainfall Data spreadsheet on the Science 30 Textbook CD.

Chapter 1: Acid Deposition

Unit B: Chemistry and the Environment

step 1: Search the Internet for images of daily,

Part B: Map of Alberta

This demonstration should be performed only by

1. Earlier, you discovered the importance of experimental

Chapter 1: Acid Deposition

The Jet Stream and Acid Deposition

Effects of Acid Deposition on the Environment and Ecosystems

land transport and deposition

Figure B1.29: Erosion caused

alkaline: having the properties of a base

burial and lithification

Unit B: Chemistry and the Environment

Reaction of Hydronium Ion and Carbonate Ion

H3 O + (aq) + CO32 - (aq)

a. Identify the province with the largest

b. Identify the province with the lowest

c. Is there a correlation between the sensitivity of

d. Hypothesize a reason for the relationship you

gains a hydrogen ion

Only a small percentage of soils in Canada have a high

Chapter 1: Acid Deposition

The area now

Buffering and Buffering Capacity

DID YOU KNOW?

The dark patches on

Unit B: Chemistry and the Environment

agricultural plants and soil pH

Soil pH for Optimal Growth

DID YOU KNOW?

Reactions between acids and minerals in the soil are important

biogeochemical cycle: a diagram representing the

REQUIRED PLANT NUTRIENTS

Forms Used by Plants

important for root growth

essential for chlorophyl formation

PO43-, HPO42-, H2PO4-

required for the production of chlorophyl

required in reactions to make sugars and

essential for proper leaf and stem growth

required for reactions that convert nitrogen

Chapter 1: Acid Deposition

Plant Nutrients, Metal Leaching, and pH

Within soil, aluminium ions are normally bound to

decreasing the growth of roots

Higher concentrations of aluminium ions in lakes and

Unit B: Chemistry and the Environment

fish (0.081 g/g body mass)

Chapter 1: Acid Deposition

Concentration of Mercury in Body Tissue

40. Scientists sampled fish from one lake over a ten-year

Mercury Levels in Fish

a. State the name that describes the yellowing of

b. Explain why the plant leaves are yellowing.

c. Indicate a possible cause for the condition of the

d. Explain the relationship between soil pH and the

Mercury Level (ppm)

b. The concentration of mercury in krill is 1000 times