Professional Documents
Culture Documents
DECLARATION
I hereby declare that the project work entitled
1.EFFICIENCY
WITH
DIFFERENT
GCV
OF
COAL
AND
EFFICIENCY
IMPROVEMENT IN BOILER
2. COLOUR AND ODOUR REMOVAL FROM WASTE WATER USING COAGULANT
AND LOCALLY AVAILABLE COMERCIAL GRADE LIME
is an authentic record of my own work carried out at IOL Chemical and Pharmaceuticals
Pvt.ltd as requirements of six months project semester for the award of degree of B.E.
(Chemical Engineering), Thapar University, Patiala under the guidance of Dr.Damandeep
Singh and Dr.Neetu Singh during 1st July to 30th December 2016.
Date: ______________
(Signature required)
Prabhjot Singh Tinna
101301042
Certified that the above statement made by the student is correct to the best of my
knowledge and belief.
(Signature required)
Dr. Neetu Singh
Assistant Professor
Department of Chemical Engineering
Thapar University, Patiala 147004
2
ACKNOWLEDGEMENT
The completion of this undertaking could not have been possible without the
participation and assistance of so many people whose names may not all be enumerated.
Their contributions are sincerely appreciated and gratefully acknowledged. However, I
would like to express my deep appreciation and indebtedness particularly to the following:
Dr. Damanjit Singh(HEAD UTILITY) Mr. Ajaypal Singh for guiding me in
boiler efficiency and helping me in suggesting methods to improve it.
Mr. Shiv Kumar(PLANT HEAD D.M PLANT) in helping out the in DeMineralised water plant and Helping me suggest a project on colour removal and all the
other staff in utility section.
And special thanks to Dr. Neetu Singh, my faculty mentor for supporting me
throughout the project.
TABLE OF CONTENTS
Declaration
Acknowledgement
ii
Abstract
12
20
27
31
31
32
32
34
36
38
39
42
3.10 CONCLUSION
45
Chapter 4: Color and odor removal from waste water using natural coagulant and locally
available commercial grade lime.
4.1 INTRODUCTION
46
4.2 OBJECTIVES OF THE PROJECT
47
4.3 SAMPLING
47
48
49
50
55
56
ABSTRACT
In these six months I worked on two projects in Utility section,
1. EFFICIENCY WITH DIFFERENT GCV OF COAL AND EFFICIENCY
IMPROVEMENT IN BOILER
Purpose of this was to measure the performance of boiler which can be measured by
calculating the efficiency as it reduces with time duetopoorcombustion,heattransfer
foulingandpooroperationandmaintenance.Deteriorationoffuelqualityandwaterquality
alsoleadstopoorperformanceofboiler.Efficiencytestinghelpsustofindouthowfarthe
boilerefficiencydriftsawayfromthebestefficiency.Anyobservedabnormaldeviations
couldthereforebeinvestigatedtopinpointtheproblemareafornecessarycorrectiveaction.
Henceitisnecessarytofindoutthecurrentlevelofefficiencyforperformanceevaluation,
whichisaprerequisiteforenergyconservationactioninindustry.
2. COLOURANDODOURREMOVALFROMWASTEWATERUSING
COAGULANTANDLOCALLYAVAILABLECOMERCIALGRADELIME
In industrial wastewater, the advanced treatment of color removal such as chemical
coagulation may be used as pretreatment in order to enhance the biodegradability of
wastewater during the biological treatments. Chemically enhanced wastewater treatment is
attracting substantial interest among the currently employed chemical unit processes in
wastewater treatment. Coagulation-flocculation has received considerable attention for
yielding high pollutant removal, especially color removal. This project presents a
formulation of coagulation- flocculation for color removal of a industrial wastewater and
illustrates its efficiency. The results show that the novel formulation can remove color
content from wastewater efficiently. The treated waste water removed color by
flocculation / coagulation treatment by using coagulant. The present study was performed
using jar test apparatus with Moringaoleifera(M.O) as coagulant. It was used to increase
the size of flocs at various pH values and at various chemical doses and different coagulants
like alum. After the process, the residual color, as well as transmittence of water were
measured. The results showed a significant increase in color removal to the extent.
Company was established in 1986, IOLCP is India's one of the leading generic
pharmaceutical company, and is significant player in the Organic chemicals space. IOLCP
has wide presence across various therapeutic categories like, Pain Management, Antidiabetic, Anti hypertensive, Anti Convulsants, etc.
Currently with an annual revenue of INR 600 Crores/- it is the one of the largest chemical
and pharmaceutical industry in INDIA.
IOLCP, one of largest producers of APIs, Ibuprofen and speciality chemicals in india. The
company has commenced that the manufacturing operations at its new plant of IBB having
annual capacity of 6600 Mt to ensure ready availability of basic raw material for successful
pharmaceutical product.
IOLCP has through its quality-focus, dedication to technical excellence & an unwavering
commitment to its customers, developed a wide network of satisfied clientele. Having
established a strong domestic presence, company is serving the international market with its
high quality products. With in a short span of time, IOLCP has penetrated the market in 56
countries across the globe and is in continues efforts of expanding its horizons.
IOLCP
PHARMACEUTICALS
CHEMICALS
25%
Revenue mostly comes from
International
Domestic
market
With dealership of 57% in Chemicals and 43% Bulk Drugs
75%
Domestic
IBUPROFIN :- largest manufacturer in India. IBUPROFEN is a well known nonsteroidal, anti-inflammatory, Antipyretic and analgesic drug and is also used in other
medical drugs.
ETHYL ACETATE :- Applications in paints, packaging, adhesives, photographic films,
flavors, surface coatings and thinners.
ACETIC ANHYDRIDE :- Applications in pharma, agro-chemicals, perfumes ,dyes and
pigments.
MCA (MONO-CHLORO ACETIC ACID) and ACETIC ACID :- Second largest
producer in the country. Both are used by the company as a raw material for the production
of IBUPROFIN.
ISOBUTYL BENZENE(IBB) :- Used as raw material for the production IBUPROFIN
ISOBUTYL ACETOPHENONE(IBAP):- Used as a raw material for the production of
IBUPROFIN
ACETIC ACID:- Applications in petroleum refineries, pharma, food processing industry,
vinegar, tanning, printing, pesticides, ester, etc.
CO-GENERATION PLANT :- Generation of 17 MW(14 MW+ 3MW) power for
industrial usage
IOLCP CHEMICALS
ETHYL ACETATE
87000 TPA
ISO-BUTYL BENZENE
9000 TPA
MONOCHLORO ACETIC
ACID(MCA)
5200TPA
Monochloro acetic acid plant and acitic acid plant, both are inter-related to each other
because the HCl which is produced as a by-product during the production of mono chloro
acetic acid can be used in the production of acetic acid and acetyl chloride. Acetic acid
produced during the production of acetyl chloride can be used in the production of mono
Chloro-acetic acid.
This thing can be elaborated by the following two reactions:Cl2
CH3COOH
CHLORINE
(CH3CO)2
ACETIC
ANHYDRIDE
ACETIC ACID
HCl
HYDRO CHLORIC
ACID
CH2ClOOH
CH3COCl
ACETYL
CHLORIDE
HCl
HYDRO CHLORIC ACID
CH3COOH
ACETIC
ACID
Mono chloro Acetic acid plant is operated and controlled by the DCS (distributive control
system)system and is established in 2009.The interesting thing about mono chloro acetic
acid plant is that the acetic acid which is used as a raw material for MCA production can be
introduced in the reactor at the establishment time which is approximately 20 tonne and till
now only that 20 tonne is regenerated and is used in future as well i.e. no further need of
introducing acetic acid.
IBB (ISOBUTYL BENZENE) PLANT :Isobutyl benzene is a totally DCS system plant. Isobutyl benzene is indirectly
used for the production of the main product of the company i.e. ibuprofen but directly used
for the production of the IBAP i.e. Isobutyl acetophenone which can be shown by the
following reaction:IBB
ACETYL CHLORIDE
IBAP + HCl
PROPYLENE
Na+
CRUDE IBB
Crude isobutyl benzene is impure kind of IBB which is further purified to get maximum
purity of 99.8%.Propylene is basically we get from crude oils purifying process or during
the distillation in petroleum refineries i.e. from the atmospheric distillation unit of refinery.
The critical thing about this plant is that sodium (Na) should not come in contact with water.
If it happens then blast will take place and will be very dangerous to the manpower
working around the plant. So to prevent this phenomena before adding the water into the
reaction mixture we firstly add methanol to the reaction mixture which actually helps in
neutralizing the sodium.
IBU (IBUPROFEN) PLANT:As the major product of the company is ibuprofen and hence is manufactured in
the IBU plant of the company.
Raw material required for the production of IBU are:- aldehyde, sodium dichromate, H2SO4,
and acetone (CH3COCH3).The IUPAC name of IBB is 2-4 isobutyl phenyl propanoic acid.
Now in order to produce IBU, firstly there is a need to produce the raw materials i.e. IBAP
(isobutylacetophenone), IPCA(isopropylchloroacetate), SPO (sodiumpropoxide).
ISOBUTYL BENZENE + ACETYL CHLORIDE
IPA + MONOCHLORO ACETIC ACID
IPA + Na FeCl3
NaCl
ESTER + NaOH
HCl
ISOPROPYLCHLORO ACETATE + H2O
ISOBUTYLACETOPHENONE+
COMPLEX + IPA
ESTER
CO2 + CH3CHOCH3
Initially during the start of the plant in 1996,three products were manufactured
i.e ethyl acetate, acetic anhydride and acetic acid. But now only ethyl acetate is produced
due to some reason.30-40 % of the income of the company basically comes from this plant.
Ethyl acetate plant is a totally DCS system plant i.e. (Distributive control system). The
major reaction is as follow:-
C2H5OH
Raw
mate
ETHYL
ALCOHOL
CH3COOH
PTSA
ACETIC
ACID
CH3COOC2H5
H2O
ETHYL
ACETATE
WATER
Raw material which we used during the production of ethyl acetate are bought from other
companies.The catalyst which we use in the reaction is in the solid form and generally 30
kg PTSA(para toluene sulphonic acid) is used per shift i.e. approx.. 90 kg per day. The
pumps which are used in this plant are liquid ring vaccum pump i.e. a kind of reciprocating
pump. The utilities which we used in this plant are pressurized process air (low pressure
steam 4.5 kg),city water ,cooling water etc.
According to the practical data the reaction is endothermic, but theoretically it is an
exothermic reaction. One of the interesting thing about this plant is that the heat exchanger
which is used in this plant is CAMPA BLOCK HEAT EXCHANGER which costs around
Rs.1crore .Its a foreign technology and even its maintenance cost is too high. But the
advantage is that it can handle the load of whole plant.
IPCA( ISOPROPYL CHLORO ACETATE) PLANT:IPCA is used as raw material for the production of the main product IBUPROFEN.
The reaction for this is as follow:IPA +
MCA
IPCA + WATER
The catalyst which is used in the reaction is sulphuric acid (H2SO4). Amount of raw material
used is as follow:- MCA(MONO CHLORO ACETIC ACID) = 9000 kg, IPA = (0.71*MCA)
= 6390 kg and H2SO4 = (MCA* 0.28) =2520 kg. This is a batch process. One need to
maintain a 9 hr. reaction time. After 9 hr. agitation, we will give 1.5 hr. settling time. After
settling 2 layers will be formed, one is send for IPCA recovery and other is send for
washing. In IPCA recovery we provide steam at 140 degree Celsius. Earlier operation was
provided with a vaccum and operated at 130 degree Celsius. For moisture content we have
fresh IPA < 0.2%, Recovered IPA < 1.5%, After steam < 1.1% and for MCA moisture
content should be less than 0.2%. After the quality check we again agitate for 2 hrs. and
again give 2 hrs. for settling. The recovered IPCA is again put in the batch as recirculation
and the fresh IPCA we get as 24 ton/day. This is stored in daily storage tank and transferred
to IBU plant whenever required.
POLY ALUMINIUM CHLORIDE PLANT (PAC):As discussed earlier that during the production of isobutylacetophenone
(IBAP) some amount of by-product is also formed in the quencher unit of the IBAP plant
which is nothing but polyaluminum chloride (PAC). In quencher, quenching of the reaction
mass is actually takes place which results in formation of two layers, one is organic layer
and the other is polyaluminum chloride layer. Earlier this PAC from IBAP plant will be
transferred to some other companies at low rate because of lot of impurities present in it.
As polyaluminum chloride has a lot of applications in industry as well as in daily use.
Therefore in order to sell that PAC at higher rate, plans are made to increase the
concentration of polyaluminum chloride by estabilishing a separate unit for it. Therefore
polyaluminum chloride from IBAP plant is transferred to polyaluminum plant of the
company where concentration of polyaluminum chloride can be increased according to the
sale specification set by the authorities. As PAC is the result of hydrolysis of aluminum
chloride which is an exothermic reaction too. Therefore concentration can be increased by
inputing more aluminum chloride into the polyaluminum chloride which we are getting
from the IBAP plant. One of the major cause of impurities in the polyaluminum is the
presence of solvent trichloroethene in it due its water solubility.
The first step is to make a detailed analysis of raw water for various parameters
including organics, colour, suspended solids, iron, manganese besides other dissolved
solids. The analysis of raw water shall be carried out throughout the year to determine its
profile variations with the change of seasons. Sufficient margin in various constituents of
water may be kept in order to take care of variations in the coming years based on yearly
seasonal variations in water analysis. The tubewell water composition does not vary much
with the season, so in that case, it becomes easier to fix up the design parameters of water
analysis; but in surface water, fluctuations are quite high, so it becomes difficult to arrive at
the designed analysis. However, a proper assessment has to be made for fixingup
designedwateranalysis.
InthePlant,Rawwaterisactuallyundergroundwater.Analysisofrawwaterisbelowinthe
table:
COMPONENT
RAWWATER(mg/l)
BOILERFEEDWATER(mg/l)
Na*
15.3
<1.5
Mg*
11.3
<0.1
Ca*
15.7
<0.1
Cl*
11.7
<0.1
SO4*
37.4
<2
Si*
8.32
<0.5
TotalHardness
105.8
TDS
800
<10
*Dissolvedcomponent
standardsforboilerfeedwateraspermanufacturer.
TABLE1:WATERQUALITIESOFRAWWATERANDBOILERFEEDWATER
The next step is to properly pretreat the raw water to obtain water suitable for feeding into
Co-generation plant as the ion exchange resin used in demineralization plant are susceptible
to various constituents commonly present in water including iron, manganese, colour ,
suspended solids, residual chlorine, etc. The feed water for Co-generation plant shall be free
from chlorine, organics, iron, manganese, suspended solids within 2 to 3 Mg/l. It shall also
be free from oil and grease to ensure long life of the working of Boiler. All these
considerations have to be kept in view in the design of a demineralization plant.
Following is the flow-chart of D.M WATER TREATMENT PLANT:
RAW WATER TANK
BASKET STRAINER
ULTRA FILTERATION(UF)
UF PERMEATE STORAGE
TANK
Reject Flow-0
CARTRIDGE FILTER(5
SIZE)
R.O BLOCK
Reject flow:0
MIXED BED
Media Filters used in water & Waste water treatment are either pressure or gravity filters
depending upon the flow of water. Water is pumped through a pressure filter while water
flows by gravity in a gravity filter .They employ granular media like sand, anthracite or
activated carbon either alone or in combination as the filter media. Filters with special
media are also used to remove iron and or manganese that may be present in some bore well
waters.
Dual media filter contain anthracite along with fine
the
Working
Principle: The
media in a
arranged so
media with
largest
anthracite.
rest of the
Basket Strainer: Basket strainers are used as a first stage filter to remove the large debris
and followed by a filter bag housing or cartridge type filter to remove smaller particles of
contamination. Not only do liquid strainers keep water clean, they also protect pumps and
Strong Acid Cation (SAC): SAC (T42H) resins can neutralize strong bases and convert
neutral salts into their corresponding acids. These resins are utilized in most softening and
full demineralization applications. SAC resins derive their functionality from sulfonic acid
groups (HSO3). When used in demineralization, SAC resins remove nearly all raw water
cations, replacing them with hydrogen ions, as shown below:
Strong Base Anion: SBA resins(A23) derive their functionality from quaternary
ammonium functional groups. Two types of quaternary
ammonium groups, referred to as Type I and Type II, are used.
Type I sites have three methyl groups:
As with the cation resins, these reactions are reversible, allowing for the regeneration of the
resin with a strong alkali, such as caustic soda, to return the resin to the hydroxide form.
when flue gas is passed through it all particulate matter gets attached to it and the process of
hammering starts in ESP which makes the whole matter which is harmful for atmosphere
hammered down and the rest of gas is sent into the atmosphere. Flue gases are further used
in APH for pre-heating the ambient air to a particular temperature and also used for preheating the DM water.
ECONOMISER
SUPERPREHEATER
FD (Forced
draft) FLOW
STEAM DRUM
TURBINE
APH
BED-COILS
PROCESS
BOILER
WATER WALL
MEMBRANE
(RISER)
T= 500C
BOILER
Steam to process units
FLUE
GAS
STEAM
DRUM
ECONOMIZER
DE AERATOR
DM Water
T=120C
AIR at 35C
DM water T=220 C
FLUE
GAS
Air at 123 C
APH(AIR PRE
HEATER)
Air T=35C
FD FAN
FLUE
GAS
ESP(ELECTROSTAT
IC PRECIPITATOR)
FLUE
GAS
ID FAN CHIMNEY
Boiler: A boiler or steam generator is used wherever a source of steam is required. A boiler
incorporates a firebox or furnace in order to burn the fuel and generate heat. The generated
heat is transferred to water to make steam, the process of boiling. This produces saturated
steam at a rate which can vary according to the pressure above the boiling water. The higher
the furnace temperature, the faster the steam production. The saturated steam thus produced
can then either be used immediately to produce power via a turbine and alternator.
Fuel Used: Rice Husk, Indian Coal, Indonesian Coal, South African Coal, Pet Coke.
Temperature: 500C, All the Co-generation has been set up by ABB.
Economiser: The economizer also prevents flooding of the boiler with liquid water that is
too cold to be boiled given the flow rates and design of the boiler. A common application of
economizers in steam power plants is to
capture the waste heat from boiler stack gases
(flue gas) and transfer it to the boiler
feedwater.
In our steam boiler, it is a heat ex-changer
device that heats up fluids or recovers
residual heat from the combustion product i.e.
flue gases in thermal power plant before
being released through the chimney. Flue gases are the combustion exhaust gases produced
at power plants consist of mostly nitrogen, carbon dioxide, water vapour, soot carbon
monoxide etc. Hence, the economiser in co-generation plant is used to economise the
process of electrical power generation. The recovered heat is in turn used to preheat the
boiler feed water, that will eventually be converted to super-heated steam. Thus, saving on
fuel consumption and economising the process to a large extent.
Air-Pre heater: An air preheater (APH) is a general term used to describe any device
designed to heat air before another process (for example, combustion in a boiler) with the
primary objective of increasing the thermal efficiency of the process. They may be used
alone or to replace a recuperative heat system or to replace a steam coil.
The purpose of the air preheater in plant is to recover the
heat from the boiler flue gas which increases the thermal
efficiency of the boiler by reducing the useful heat lost in
the flue gas. As a consequence, the flue gases are also
conveyed to the flue gas stack (or chimney) at a lower
temperature, allowing simplified design of the conveyance
system and the flue gas stack.
Electro-Static precipitator(ESP):
An electrostatic precipitator (ESP) is a
filtration device that removes fine
particles, like dust and smoke, from a
flowing gas using the force of an
induced electrostatic charge
minimally impeding the flow of gases
through the unit.
In this precipitator, it contains a row
of thin vertical wires, and followed by a stack of large flat metal plates oriented vertically,
with the plates typically spaced about 8 cm apart. The air stream flows horizontally through
the spaces between the wires, and then passes through the stack of plates.
A negative voltage of several thousand volts is applied between wire and plate. If the
applied voltage is high enough, an electric corona discharge ionizes the air around the
electrodes, which then ionizes the particles in the air stream.
The ionized particles, due to the electrostatic force, are diverted towards the grounded
plates. Particles build up on the collection plates and are removed from the air stream.
pH
6.0-9.0
EQUILIZATION
TANK
ANAEROBIC
TANKS
SEDIMENTATION
PRESSURE
TUBE
CLEAN
CARBON
SETTLER
WATER
SAND
CONTRACTOR
FILTERS
TANKS
FLOW CHART OF ETP
SLUDGE
V-NOTCH
DRYING
CHAMBER
BED
EQUILIZATION TANK: Waste water quantity and quality discharged during the day is
not constant flow and quantity depends upon the type of industrial process and on its
velocity during the day.
In order to feed it is necessary to make water to be treated as homogenized as possible form
point of view of both quantity and quality, in order to guarantee to bacteria a constant
feeding (that is necessary for their survival) and consequently high performance in the
abatement of pollutant substances.
Volume of tank: 1105 m3
ANAEROBIC TANKS: Anaerobic digestion is a process in which microorganisms break
down biodegradable material in the absence of oxygen. Anaerobic digestion is the process
for the reduction of sludge without the use of air or elemental oxygen. In anaerobic
digestion, organic pollutants are converted by anaerobic micro-organisms to a gaseous
product (including methane gas) that has the potential for reuse. It is a very low energy
process, that produces a fraction of the waste sludge generated through aerobic biological
processes.
After the pressure sand filters and carbon contractors, water is sent to
v-notch chamber further from where water is discharged into watering of
plants. Sludge left in sludge drying area is sent to a particular disposed
area.
Compare with the different GCV of coal to find out the proper fuel selection of fuel. There
are different parameters regarding to the boiler system which helps to improve boiler
efficiency.
using Microsoft excel the repeated calculations are being quite easy and time saving. Just
change the various values and at the last you got the result immediately without any
handwritten time consuming paperwork.
Here calculation has been done for the 40THP boiler, fuel having GCV of 5800 kcal/kg and
4300 kcal/kg respectively for indian bituminous coal and Indonesian coal. Both coals have a
different chemical composition and properties.
There are lots of possibilities to improve boiler efficiency by taking necessary steps for
different parameters which are directly affected to the boiler efficiency. By considering
them it gives an opportunity to improve boiler efficiency.
heat output
= heat input 100
1. Direct method :-
Q( hghf )
100
qGCV of Fuel
2. In-direct method:
By this method, efficiency could be measured easily by measuring all the losses
occurring in the boiler.
The following losses were applicable to all the fuel used, weather it is solid, liquid or
gas fired boiler.
L1 loss due to dry flue gas
L2 loss due to hydrogen in fuel
L3 loss due to moisture in fuel
L4 loss due to moisture in air
L5 loss due to CO formation
L6 loss due to un-burnt fuel in fly ash
L7 loss due to un-burnt fuel in bottom ash
L8 loss due to radiation and convection (surface loss)
=100(1+2+3+4+5+6+7+8)
11.6C+34.8 H 2
O2
+4.35 S
8
Kg/Kg
100
of fuel
Where H2, O2, C, S are percentage of carbon hydrogen oxygen and suphur present in
fuel.
Step 2. % excess air requirement
O2
*100
21O2
( CO 2 ) t(CO 2 ) a
CO 2
100()t
( CO 2 ) a
7900
Step3.Actualair(totalair)requirement
Actual air (total air) requirement (AAR)= Theoretical air * (1+EA/100 ) kg of air/kg
of fuel
Step4.Findallheatloss
1.Dryfluegasloss=% heat loss due to dry flue gas=
mCp( Tf Ta )100
GCV OF FUEL
= mass of CO2 +mass of SO2 + mass of N2 + mass of O2 (water vapor mass is neglected)
C
s
44
64
( AAR Ta)44
100
100
AAR77
+
+
+
12
100
100
12
)(
)(
)(
m=massofdryfluegas(kg/kgoffuel);AAR=actualairrequired(kg/kgoffuel)
o
9H 2{ 584+Cp ( Tf Ta ) }
GCV OF FUEL
3Heatlossduetoevaporationofmoistureinfuel
=
4.
%convectionloss=
Step5:findsumofallheatlosses
totallosses=sumofallheatlosses=1+2+3+4+5+6+7+8
Indian Bituminous
Indonesian coal
40000 kg/hr.
40000 kg/hr.
rate
Operation hours
8640 hrs./year
8640 hrs./year
Steam pressure
Steam temperature
32 kg/cm2
380O C
32 kg/cm2
380oC
5846 kg/hr.
4300 kg/hr.
GCV of fuel
4300 kcal/kg
5800 kcal/kg
150 m2
150 m2
Humidity factor
Ambient
Steam Generation
temperature
Wind velocity
Surface temperature
33 C
33 C
3.9 m/s
3.9 m/s
210 oC
210
220 oC
180 ppm
7.1
220 oC
180 ppm
7.1
600oC
8.12%
600oC
8.12%
11.6%
11.6%
0.42%
0.42%
37%
2.9%
1.1%
4.5%
36%
17%
1.5%
59%
3.1%
1.1%
10.4%
12.1%
12.9%
1.4%
D. ASH analysis
GCV of BOTTOM ASH
GCV of FLY ASH
Bottom ash to fly ash
ratio
700 kcal/kg
150 kcal/kg
45:55
700 kcal/kg
150 kcal/kg
45:55
By using the above values and using excel to get results from the formulas,
efficiency was calculated.
INDIAN
COAL
INDONESIAN COAL
7.5313
7.5313
Method 1
10.25%
63.34 %
Method 2
11.30%
64.85 %
8.303
12.302
8.845
13.243
8.245%
6.112 %
4.814%
5.146 %
2.625%
1.477 %
0.3248%
0.3567%
1.727%
2.041%
0.2321%
0.3442 %
0.8863%
0.6571 %
6078.301
6078.3
Surface loss
3.626%
3.655 %
Efficiency
77.51
80.20 %
DIRECT METHOD :
Direct method
79.05
79.68
Indirect method
77.51
80.20
Direct method
79.05
79.68
Various forms of contaminations arise with water and they must be removed before feeding
to the boiler system by proper water treatment. Otherwise they moves with water and
concentrate in the boiler, as a result deposition and scales are form which may reduce the
heat transfer, reduce the boiler efficiency, increase the operation & management cost and
damage the tubes.
I. TDS control
Total dissolves solids comes with feed water into the boiler, water is heated and converted
into the steam bur TDS are remaining in the boiler and concentrated, and eventually reach at
a level where their solubility in the water in the water is exceeded and they deposit from the
solution. Thus they form scale and reduce heat transfer and also overheat the tubes and
puncture those tubes. Thus TDS control is essential by manual blow down or automatic
blow down system.
II. pH control
pH is the measure of how acidic or basic the feed water. Feed water must be neutral which
save the energy. pH is controlled by either removing impurities or adding other chemicals to
neutralized the water or by blow down of water.
Proper fuel preparation:
Fuel contaminants (dirt, dust, suspended particles, moisture etc.) , they must be removed by
proper fuel treatment otherwise, they forms the scales and reduces the heat transfer rate or
excessive moisture uses a lot of energy as required to change the phase and this energy
carried over with flue gas as loss. A quality feed into the boiler raise the efficiency level of
boiler and also reduce the maintenance costs.
Fuel selection:
The proper fuel specification can also have a effect on efficiency. In the case of gaseous
fuel, the higher the hydrogen content, the more water vapor is formed during combustion,
which leads higher heat loss due to evaporation of water form by hydrogen in fuel. To get
an accurate efficiency calculation, a fuel specification that represents the job site fuel to be
fired must be used.
is supplied to the burner to provide a safety factor above the actual air required for
combustion. A quality design will allow firing at minimum excess air levels of 15% (3% of
O2). O2 represents oxygen in the flue gas. Excess air is measured by sampling the O2 in the
flue gas. If 15% excess air exits, the oxygen analyzer would measure the O2 in the excess
air & shows a 3% measurement.
The optimum excess air level is depending on burner design & type, furnace design, fuel
and process variables. It can be estimated by conducting various performance tests with
different fuel/air ratios.
Boiler load fluctuation:
The load on the boiler is fluctuating in nature. The efficiency of boiler varies according to
load. As load is suddenly increased, steam demand is also increased and pressure will be
dropped. Burner is start to fire at its full rate to meet this demand, but pressure continues to
drop because boiler is taking some time to respond. Similarly, if load is suddenly decreased,
steam demand is reduced and steam pressure is increased, burner immediately lower the
firing rate, but again it will take some time, so that steam pressure over shoots the relief
valve setting. The maximum efficiency of boiler will occur at nearly 70-85% of full load.
Beyond or under this load limits, the efficiency will be decreased
As the load falls, the fuel & air supply is reducing; hence mass of flue gas will be reduced.
The reduction in flow rate of flue gas for some heat transfer area will also reduce the exit
flue gas temperature. These all raise the efficiency of boiler.
As the load falls below 50%, most combustion appliances need more excess air to burn the
fuel completely. This increases the sensible heat loss and lowers the boiler efficiency.
Thus, boiler should be operated near to full load for achieving the maximum efficiency
3.10 CONCLUSION
Conclusion derived from the data related to the boiler, if higher GCV coal is used,
then the efficiency should be increased. Ash and Moisture content inside the fuel will affect
the efficiency. Here by using semi bituminous coal efficiency is 80.20% because of its high
heating value and less moisture and ash content, while Indian lignite coal gives 77.51%
efficiency on the same boiler because of it has a more ash and moisture contents than the
semi bituminous coal. From this Indirect Method mathematical model, the efficiency should
be easily calculated. Simulation should be carried out by the adding different value of
data.With the help of simulation, necessary changes should be carried out for the improving
boiler and steam system efficiency. Parameters which can be improved the boiler efficiency
is gives a best rest, if they are applies to the boiler system
Industrial wastewaters are clarified to remove turbidity and color from chemical industry. In
a water treatment chemical treatment that will remove, color and turbidity present in raw
water in the form of flocs. Coagulants neutralize the repulsive electrical charges (typically
negative) surrounding particles allowing them to "stick together" creating flocks.
Flocculants facilitate the sticking of the coagulated particles to form larger floccules and
thereby fasten gravitational settling. Coagulation is the destabilization of colloids by
neutralizing the forces that keep them apart. Cationic coagulants provide positive electric
charges to reduce the negative charge of the colloids. As a result, the particles collide to
form larger particles (flocks). Rapid mixing is required to disperse the coagulant throughout
the liquid.
The enormous use of water in industries has caused a serious problem of drainage of
industrial waste water. Effluents from industries are deteriorating the surface and
underground water quality through seepage, due to chemical constituents of undesirable
concentration and thus creating water pollution. Heavy metals are groups of pollutants
which are non biodegradable and tend to accumulate in living organisms. Heavy metals are
toxic because they cannot be degraded biologically into harmless Products, hence they
cause serious health hazards. All heavy metals at high concentrations have strong toxic
effects and are an environmental threat . The pollutants of wastes chemical are of inorganic,
organic and toxic nature and require elaborate treatment before disposal to prevent physical,
chemical and biological pollution of the receiving body of water. Wastewater with high
concentration of dissolved solids, suspended solids, chloride, color, chromium etc. were
being discharged every day in the receiving water.
Coagulation and flocculation processes are intended to form particles large enough to be
separated and removed by subsequent sedimentation, or alternative clarification processes.
The coagulation stage occurs when a coagulant, such as alum, is added to the water to
neutralize the charges on the colloidal particles in the raw water, thus bringing the particles
closer together to allow a floc to begin to form. The flocculation process, following
coagulation, allows smaller particles formed during the rapid coagulation stage to stick into
larger particles to form settle able and/or filterable floc particles. Numerous substances have
been used as coagulant and flocculation aids, including alum[Al2(SO4)3,18H2O], ferric
chloride [FeCl3/6H2O], ferrous sulfate [FeSO4.7H2O] and calcium carbonate [CaCO3].
As the chemical method helps to remove turbidity, color and chemical oxygen
demand reduction. The present study is on the performance of coagulation and flocculation.
An approach of this technology is made for chemical waste water also for different
4.3 SAMPLING:
Sampling of waste water is done at the main collection sump of effluent treatment plant
from industry and using grab sampling method, the sampling bottle was of 40 litre capacity
which are cleaned several times with tap water, then with distilled water and rinsed fully
with 1N HNO3 for removal of living micro-organisms, pathogens and odour of the
sampling bottle. Immediately the sample is aided with 15ml/l of 2N HNO3 is added for
preservation of the sample. After collecting preserving the sample Initial parameters of the
sample like ph, colour, odour, turbidity, transmittance, absorbance, TDS and conductivity
were tested. The sample was basic in nature (ph 8) and it is brought to acidic condition (pH
5) by adding 1 drop of 1N H2SO4.
S.N
PARAMETERS
INITIAL VALUES
pH
7.5-8
TDS
19730ppm
Conductivity
97.5ms/cm
Transmittance
2%
Odour
Objectionable
o.
colour
Brownish pink
Absorbance
1.23
Turbidity
49 NTU
INITIALWASTEWATERCHARACTERISTICS
4.4MATERIALSANDMETHODS
Effectofnaturalcoagulantsinwastewatertreatment:
Naturalcoagulantsarethemostwidelyusedintreatmentofwastewaterandithas
provenqualityintreatmentofvariouswastewatersfromindustries.Researchsays
thatwhenalumwasincludedalongwiththenaturalcoagulantstoknowtheimpact,
alumgavearelativelyhigheffectivenessinremovingthedyeandthatm.oalong
withalumisanrealalternativecoagulantfortheremovalofinorganicmetalsalts.It
wasalsoconcludedfromtheirstudiesthatM.Oisnoteffectiveincaseoflowturbid
samplesbecauseofthelowinterparticlecontact.ThehigherdosageofM.Owill
leadtoincreasetheresidualturbidity,anditwilleventuallyleadtothesaturationof
polymerbridgessitesandcausedestabilisationofparticlesduetoaninsufficient
numberofparticlestoformmoreinterparticlebridges.SeedofM.Ocontains
materialsthatareeffectiveascoagulant,anddirectfiltrationofwaterwithM.Oseed
ascoagulantbringsaboutasubstantialimprovementinitsaestheticandmicrobial
quality.Experimentsshowedahighcoagulationactivityforthehighturbiditywater.
Thecoagulationactivitywaslowforlowturbiditywater,whileusingnatural
coagulants,influenceofthephonthesystemfoundtobesignificantonturbidity
removal.Thestudyclearlyindicatesthatatoptimumphsystemconditions,thereis
significantreductionincoagulantdoserequiredandinsomecasesafurtherincrease
inturbidityremoval.AproteinextractedfromM.Oleiferaseedhasdemonstratedits
effectivenessinwastewatersystemsremoving99%ofsuspendedsolidswithout
changingthephofthewater.It is concluded that Moringaoleiferaseeds acts as a
4.5Solutionpreparation:
Moringa olifera (drum stick) seed was taken and dried in sunlight for few days till it
looses all its fluid contents and then it is powdered to get fine particles. Then it is
sieved using 75 micron sieve. 20gms of seed powder was weighed and mixed with
250ml of distilled water. It was filtered using filter paper and the extract is used as
coagulant. 15gms of coagulant aids like alum, ferrous sulphate, calcium carbonate
were mixed with 250ml of distilled water.
200ml of preserved sample is taken in a clean 500ml glass beakers and dosages of
5ml, 6ml, 7ml, 8ml of various coagulant combinations were given to the samples.
alum+moringaolifera
alum+lime
lime+moringa
lime+ferroussulphate
coagulation process. Then the samples with coagulants are placed in jar testing
apparatus. Initially flash mixing is done for 10 seconds and normal mixing of
150rpm is given to the samples for 10 minutes. Then the detention time of 30minutes
is given. Final parameters of the samples were checked after 30minutes of detention
time after removing the sample from jar test apparatus.
4.6RESULTSANDDISCUSSION:
The below table portraits by varying the dosage of coagulants the change in
initial parameters of waste water is drastically changed to lower acceptance
satisfactory limits. The conductivity is reduced to 70.2ms/cm, Transmittance is
increased to 76% and neutral ph is achieved.
Effectofalum+moringaolifera
S .no
Dosage
Conductivity ms/cm
ph
Transmittance %
Initial
Final
Initial
Final
Initial
Final
97.5
83.2
31
97.5
82.7
32
97.5
79.6
38
97.5
77.7
42
Dosage
pH
Conductivity ms/cm
Transmittance %
Initial
Final
Initial
Final
Initial
Final
97.5
76.7
19
97.5
75.8
21
97.5
72.3
22
97.5
70.7
27
Dosage
Mg/L
Conductivity ms/cm
pH
Transmittance %
Initial
Final
Initial
Final
Initial
Final
97.5
84.6
16
97.5
82.7
21
97.5
80.6
23
97.5
80.6
25
Effectoflime+ferroussulphate
S .no
Dosage
pH
Conductivity ms/cm
Transmittance %
mg/l
Initial
Final
Initial
Final
Final
97.5
88.3
24
97.5
94.9
33
97.5
95.6
62
97.5
82.1
76
Effect of moringa olifera and lime aided with some chemical coagulants
4.7 CONCLUSION:
Thus it was proven that natural coagulants can treat chemical industry waste water
efficiently. Moringa olifera (drum stick) seeds are available abundantly in India. And also
by using moringa olifera seed extract as coagulant sludge volume index in treatment
operation will be reduced
When compared to other treatment processes and coagulants. Transmittance was increased
to 76% . Color and odor were removed completely. Other initial parameters were also
reduced drastically. Lime is also available and it has proven quality in removing hazadrous
elements in waste waters. Fig 1-4 represents the change in pH concentration from acidic
conidition (pH 5) to a neutral pH range (pH 6). Fig 5-8 represents the change in
conductivity of the waste water and it is reduced to accepted level. Fig 9-12 represents the
change in transmittance value from 2% to 76%. These results prove the effectiveness of
natural coagulant and lime in colour and odor removal of leather tanning industry
wastewater. So, this can be applied for large scale treatment process in effluent treatment
units for color and odour removal.
Chapter 5: References