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ChemE
Thermodynamics
Flash
Calcula:on
Bruno
A.
Calfa
[1]
Modeling
(I/II)
Total
mole
balance
Component
mole
balance
Phase-equilibrium
ra:o
In
general,
the
K-values
(Ki)
depend
on
composi:on,
T,
and
P.
[2]
Modeling
(II/II)
Combining
equa:ons
and
given
that
yields:
This
is
a
nonlinear
algebraic
equa:on.
Note
that
only
zi
is
specied.
If
the
K-values
are
independent
of
composi:ons
(e.g.,
Raoults
Law
assump:on),
then
a
simple
itera:ve
solu:on
approach
can
be
used
to
solve
for
the
ra:o
V/F.
Root-nding
methods,
such
as
Newton-Raphson
and
bisec:on,
can
be
employed.
Numerical Example
Rigorous
Method
Aspens
ash
unit
opera:on
with
an
appropriate
rigorous
thermodynamic
model.
Approximate
Method
See
MATLAB
script
M-le
FlashExampleApproximate.m.
Solu:on
V/F
=
0.656
f(V/F)
=
2.583
108
Component
yi
xi
methanol
0.427
0.348
1-propanol
0.116
0.360
acetone
0.457
0.292
Rigorous
Method
Add
components.
Rigorous
Method
Select
thermodynamic
model.
Use
Method
Assistant.
NRTL
seems
to
be
appropriate.
Go
to
the
subfolder
Parameters
under
Methods
to
conrm
that
you
will
be
using
Aspens
built-in
binary
interac:on
parameters.
Rigorous
Method
Switch
to
Simula:on
environment.
Add
ash
unit
opera:on
(Flash2).
You
may
rename
the
block
(right
click
->
Rename
Block).
Rigorous
Method
Click
on
Material.
Red
arrows
are
mandatory.
Blue
arrows
are
op:onal.
10
Rigorous
Method
Draw
streams.
You
can
rename
streams
(right
click
->
Rename
Stream).
11
Rigorous
Method
Congure
feed
stream.
Go
to
folder
Streams,
then
1
(feed
stream).
Use
same
condi:on
of
feed
for
this
example.
12
Rigorous
Method
Congure
ash
unit.
Go
to
folder
Blocks,
then
B1.
13
Rigorous
Method
Run
simula:on.
Click
on
blue
play
bukon.
It
converged!
We
are
not
performing
economic
evalua:ons
at
this
point,
so
click
Close.
14
Rigorous
Method
Check
results
(Stream
Summary).
15
Rigorous
Method
To
see
molar
frac:ons,
go
to
folder
Setup
->
Report
Op:ons
->
Streams.
Check
Mole
for
Frac:on
basis.
16
Rigorous
Method
Rerun
simula:on.
View
Streams
(Custom).
Remember
that
stream
2
is
the
vapor
stream,
and
stream
3
is
the
liquid
stream.
17
V/F
Approximate
Rigorous
0.656
0.756
Component
yi
xi
0.427
0.427
0.348
0.318
1-propanol
0.116
0.128
0.360
0.422
acetone
0.457
0.445
0.292
0.260
References
[1]
Green,
D.
W.
(Editor).
(2008).
Perrys
Chemical
Engineers
Handbook.
McGraw-Hill
Professional.
New
York,
NY.
USA.
[2]
Seader,
J.
D.;
Henley,
E.
J.;
&
Roper,
D.
K.
(2011).
Separa:on
Process
Principles:
Chemical
and
Biochemical
Opera:ons.
John
Wiley
&
Sons,
Inc.
Hoboken,
NJ.
USA.
19