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Ionization energy
The energy required to remove an electron from an atom is ionization
energy
Ionization energy and atomic radius are inversely proportional
Removing electrons
endothermic
Electron affinity
Electron affinity is the energy change that occurs when an atom gains
an electron
Where ionization energy is always endothermic, electron affinity is
usually exothermic but not always
Electron affinity is exothermic if there is an empty or partially empty
orbital for an electron to occupy (group 2 and 18)
If there are no empty spaces, a new orbital or PEL must be created,
making the process endothermic
Metallic character
This is simple a relative measure of how easily atoms lose or give up
electrons
Electronegativity
Electronegativity is a measure of an atoms attraction for another
atoms electrons
Transfer electrons
The higher the electronegativity, the higher reaction
Scale that ranges from 0 to 4 and units are Paulings
Generally, metals are electron giver and have low electronegativity
(Left ion is +)
Nonmetals are electron takers and have high electronegativities (Right
ion is -)
The most reactive metals are the largest since they are the best electron
givers
The most reactive non-metals are the smallest ones, the best electron takers
Types of ions
Monoatomic ions from single atoms
Polyatomic ions a group of atoms that behaves as a unit and carries a net
electrical charge
Ex. NH4+ (ammonium ion), SO42- (sulfate ion), OH- (hydroxide ion)
How do atoms behave in a material?
Kinetic molecular theory
Explained the behaviour of solids, liquids and gases
Metals
High densities
High melting and boiling point
High conductivities
Malleable and ductile
Metallic bonding
The array of cations are held together by the strong attraction between
cations and electrons
How do atoms combine to form other compounds?
Ionic bonds
Covalent bonds
Lewis
Bonding pair is 2
Formula is AX2
Trigonal Planar
Bonding pair is 3
Formula is AX3
Tetrahedral
4 surfaces
Bonding pair is 4
Formula is AX4
Bent
Pyramidal
*dipoles
Polarity of Molecule
*Polar molecules are also called dipoles and tend to attract one another
*Molecules without dipoles are nonpolar molecules
Determining Polarity of molecules
Nonpolar molecules contains nonpolar bonds, however, molecules containing
polar bonds is not necessarily polar molecules
The shape of a molecule and the polarity of its bonds together determine
whether the molecule is polar or nonpolar
*look at the central atom to know its shape
Linear
Trigonal planar
Tetrahedral
Pyramidal
Bent/angular
Lone pair
0
0
0
1
2
1
Bonding pair
2
3
4
3
2
2
formula
AX2
AX3
AX4
AX3
AX2
*Boron will only need 6 electrons to complete it and the valence is only 3
Polar 2 different elements
Nonpolar same element