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This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
1. Figure shows a system of two blocks of 10 kg and 5 kg mass, connected by ideal strings and pulleys.
Here ground is smooth and friction coefficient between the two blocks is = 0.5. A horizontal force
F is applied on lower block as shown. The minimum value of F required to start sliding between the
blocks is: (Take g = 10 m/s2)
2. The state of an ideal gas is changed through an isothermal process at temperature T 0 as shown in
figure. The work done by gas in going from state B to C is double the work done by gas in going
P
from state A to B. If the pressure in the state B is 0 , then the pressure of the gas in state C is.
2
P0 P0 P0 P0
(A) (B) (C) (D)
8 2 4 16
E F
A B
D a C
4. A uniform solid sphere of mass m = 1kg is lying at rest between a vertical wall and a fixed inclined
plane as shown. There is no friction between sphere and the vertical wall but coefficient of friction
1
between sphere and the fixed inclined plane is = . Then the magnitude of frictional force exerted
2
by fixed inclined plane on sphere is : (g is acceleration due to gravity)
5. The position of a particle moving rectilinearly is given by x = t3 3t2 10. The distance travelled by
the particle in the first 4 seconds starting from t = 0 is
(A) 6 (B) 12 (C) 24 (D) 36
48 48 24 24
(A) g (B) g (C) g (D) g
5 3 3 5
7. An insect at point P sees its two images in the water mirror system as shown in the figure. One
image is formed due to direct reflection from air water interface and the other image is formed due to
refraction, reflection & again refraction by water mirror system in order. Find the separation between
4
the two images in cm. Mirror m has focal length 60 cm. water =
3
9. In the pulley system shown in figure, block C is going up at 2 m/s and block B is going up at 4 m/s,
then the velocity of block A on the string shown in figure, is equal to n m/s. Find the value of n.
10. A hemisphere of radius R and of mass 4m is free to move with its base on a smooth horizontal table.
A particle of mass m is placed on the top of the hemisphere. The angular velocity of the particle
relative to hemisphere at an angular displacement when velocity of hemisphere has become v is
2v 3v 5v 5v
(A) (B) (C) (D)
R cos R sin R cos R sin
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONE or MORE than ONE is/are correct.
11. A sphere of mass m moving with speed v collides elastically with a stationary sphere of mass km,
where k is some numerical factor. Let their resulting velocities be v1 and v2 respectively. Then pick
up the correct statements:
(A) If the collision is oblique, v2 must be perpendicular to 2v1 + (k 1)v2
(B) If the collision is oblique, v2 must be perpendicular to v1 + (2k 1)v2
1 k
(C) If the collision is headon, v1 = v2
2
(D) If the collision is headon, v1= (1 2k ) v2
12. A particle falls freely near the surface of the earth. Consider a fixed point O (not vertically below
the particle) on the ground. Then pickup the correct alternative or alternatives.
(A) The magnitude of angular momentum of the particle about O is increasing.
(B) The magnitude of torque of the gravitational force on the particle about O is decreasing.
(C) The moment of inertia of the particle about O is decreasing.
(D) The magnitude of angular velocity of the particle about O is increasing.
15. Two particles, one with constant velocity 50m/s and the other start from rest with uniform
acceleration 10m/s2, start moving simultaneously from the same position in the same direction. They
will be at a distance of 125m from each other after
16. For the system as shown in the figure, the image of O formed by the concave mirror
(A) will have speed greater than the speed of the object
(B) will have speed lesser than the speed of the object
(C) will have speed greater than the speed of the mirror
(D) moves away from the mirror.
2sin
(A) tan =
1 + 2 cos
2 cos
(B) tan =
1 + 2sin
mv 2
(C) Final kinetic energy of system ( 5 + 4 cos )
6
2
(D) loss of kinetic energy mv 2 (1 cos )
3
18. Consider a sphere of radius R with a power source inside it. The power of source is P. In steady
state temperature of surface of the sphere is T 0 . The sphere is now covered with a spherical
shell of radius 2R (Assume that no radiations are incident from outside & all surfaces are black
body). Select the correct alternatives.
(A) Power of the source is 4 T04 R 2
T0
(B) Temperature of inner sphere after covering is
2
T0
(C) Temperature of outer spherical shell in steady state is
2
(D) Temperature of inner sphere after covering is T0 21/ 4
20. A metal rod of length L whose coefficient of linear expansion = 103 / 0 C is heated such that its
temperature increase by 1000K. Assuming its is constant during the temperature change.
[Take e 2.7]
(A) Final length of the rod is greater than 2L
(B) Final length of the rod is greater than 2.5L
(C) Final length of the rod is greater than 3L
(D) Increase in the length due to heating is L
11. (AC) 12. (ACD) 13. (BD) 14. (AB) 15. (AB)
16. (AC) 17. (ACD) 18. (ACD) 19. (AC) 20. (AB)
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
=
[Data: =
log 2 0.3, =
log 3 0.48, log 5 0.7 ]
21. 9 moles of D and 14 moles of E are allowed to react in a closed vessel according to given
reactions. Calculate number of moles of B formed in the end of reaction, if 4 moles of G are present
initially in reaction vessel. (Percentage yield of reaction is mentioned in the reaction)
80%
Step - 1 3D + 4E 5C + A
50%
Step - 2 3C + 5G 6B + F
(A) 2.4 (B) 30 (C) 4.8 (D) 1
22. A mixture contains Fe 2 O 3 and FeO in 1:2 ratio. Calculate the heat released per mole of initial
mixture to change the ratio to 2:1 by reacting the mixture with sufficient oxygen.
(Given f H Fe2O3 =
200 kJ / mole , f H FeO =
60 kJ / mole )
(A) 32 kJ (B) 53.33 kJ (C) 16 kJ (D) None
23. In PH and NH , the atomic/hybrid orbitals of central atom which takes part in bonding
3 3
respectively are
(A) sp 3 , sp 3 (B) p, sp 3
(C) p, p (D) sp 3 , p
CH3
27.
How many hyper conjugated structures contribute to the stability of above free radical?
(A) 5 (B) 6 (C) 3 (D) 4
, , , ,
O OH
NO 2
NO 2 Br
OH HO O
OH SO3H C
, , ,
OCH3 OH
How many of the above compounds liberate CO 2 on reaction with aqueous solution of NaHCO3 ?
(A) 6 (B) 7 (C) 8 (D) 9
COOH COOH
CH3
HC C COOH HOOC COOH
, , ,
COOH
How many of the above compounds are more acidic than benzoic acid ?
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONE or MORE than ONE is/are correct.
31. 1 millimole of A 5H 2 O(s) and 1 millimole of A 3H 2 O(s) are introduced in a 1 L vessel containing
moist air of relative humility 80% at 1 atm & 300 K. Neglecting volume of solids and considering
the reaction A.5H 2 O ( s ) A.3H 2 O ( s ) + 2H 2 O ( g ) K p = 400 mm 2
1
(R = lt atm / mol K )
12
Which of the following is / are CORRECT? (aq tension of H 2 O at 300 K = 85 mm of Hg)
(A) final pressure of water vapour = 30 mm of Hg
(B) final pressure of water vapour = 20 mm of Hg
(C) if relative humility is 40% A.3H 2 O will not act as drying agent at 300 K.
(D) if relative humility is 20% A.5H 2 O will show efflorescence at 300 K.
32. Which of the following is / are INCORRECT for trend in hydration energy?
(A) going the group hydration energy increases
(B) going a period hydration energy for cation
(C) going a period hydration energy for anions
(D) LiF is expected to be less soluble than BeF2
33. An ideal gas is allowed to expand under adiabatic reversible conditions. What is zero for
such a process?
(A) DG = 0 (B) DT = 0
(C) DS = 0 (D) D G, D T, D S all are Zero
37. Which of the following compounds are CORRECTLY named as per IUPAC system?
O Cl
C
(B) OH 2-hydroxy-5-methylbenzenecarbonylchloride
H3C
COOH
(C) 4-methylhexanoicacid
CH3
NH2
(D) 3-methylphenylamine
CH3
Me
Br
(C) Ag+[BF4]-
C4H9Li (2 equivalents)
(D)
40. Pick out CORRECT order of Resonance energy (magnitude) of following compounds.
21. (A) 22. (C) 23. (B) 24. (C) 25. (A)
26. (B) 27. (A) 28. (A) 29. (A) 30. (B)
31. (AD) 32. (A) 33. (C) 34. (CD) 35. (ABD)
36. (BCD) 37. (ABD) 38. (ABC) 39. (ABCD) 40. (AC)
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
42. The number of six letter words that can be formed by using the alphabets of IITIAN is
(A) 120 (B) 24 (C) 720 (D) 66
( )
100
C m ( x 3)
100 m
43. The coefficient of x 53 in the expansion of 100
. 2 m is
m =0
(A) 100
C 47 (B) 100
C53 (C) 100 C 53 (D) 100
C100
45. The number of triangles whose vertices are at the vertices of an octagon is
(A) 24 (B) 52 (C) 48 (D) 56
47. If the lines 2 x + y + 3 = 0 and x + 2 y + 13 =0 intersects the coordinate axes at FOUR concyclic
points then the value of can be
(A) 1 (B) 2 (C) 4 (D) None of these
x2 y2
50. If F 1 and F 2 be the feet of the perpendicular from the foci S 1 and S 2 of an ellipse + = 1 on the
5 3
tangent at any point P on the ellipse, then (S 1 F 1 ) (S 2 F 2 ) is equal to
(A) 2 (B) 3 (C) 4 (D) 5
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONE or MORE than ONE is/are correct.
51. The coefficient of three consecutive terms in the expansion of (1 + x )n are in the ratio 1 : 7 : 42, then
(A) n is divisible by 5 (B) n is divisible by 7
(C) n is divisible by 11 (D) n = 45
10
k
53. If the term independent of x in the expansion of x 2 is 405, then value of k must be
x
(A) 3 (B) 3 (C) 9 (D) 9
54. ( )
The focal radius of the point 4 3 , 5 on the ellipse 25 x 2 + 16 y 2 = 1600 may be
(A) 7 (B) 6 (C) 13 (D) 11
55. If a line passing through the point (2, 11) touches the circle x 2 + y 2 = 25 , the slope of the line is
4 4 24 24
(A) (B) (C) (D)
3 3 7 7
60. (
If n is a positive integer, then in the trinomial expansion of x 2 + 2 x + 2 )
n
coefficient of
(A) x is 2 n . n (B) x 2 is n 2 . ( 2n 1 )
(C) x 3 is 2 n . n +1C 3 (D) none of these
46. (C) 47. (Bonus) 48. (D) 49. (A) 50. (B)
51. (AC) 52. (CD) 53. (AB) 54. (AC) 55. (AC)
56. (ABD) 57. (A) 58. (ACD) 59. (ACD) 60. (ABC)