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Acids
Properties of Acids
1. Aqueous solutions have a sour taste
2. Some acids react with active metals to release hydrogen:
Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g)
3. Acids react with bases to produce salts and water:
HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l)
4. Acids conduct electric current
5. Acids change the color of acid-base indicators:
Blue litmus turns red
Methyl orange turns red
6. Have a pH of less than 7
7. Donate protons, H+
8. React with carbonates
9. Neutralize bases
Bases:
Properties of Bases:
1. Aqueous solutions of bases have a bitter taste
2. Bases change the color of acid-base indicators
Turns red litmus blue
Turns phenolphthalein magenta/purple
3. Dilute aqueous solutions of bases feel slippery
4. Bases react with acids to produce salts and water
5. Bases conduct electric current
6. Are proton, H+, acceptors
7. Have a pH value of greater than 7
8. Neutralize acids
2. Sodium Hydroxide
- The chloralkali process (also chlor-alkali and chlor alkali) is an industrial
process for the electrolysis of NaCl. It is the technology used to produce
chlorine and sodium hydroxide (caustic soda), which are commodity
chemicals required by industry.
- Three production methods used:
a. Membrane Cell
The most common chloralkali process involves the electrolysis of aqueous
sodium chloride (a brine) in a membrane cell. Saturated brine is passed
into the first chamber of the cell where the choride ions are oxidized at the
anode, losing electrons to become chlorine gas:
2Cl Cl2 + 2e-
At the cathode, positive hydrogen ions pulled from water molecules are
reduced by the electrons provided by the electrolytic current, to hydrogen
gas, releasing hydroxide ions into the solution: 2H2O + 2e
H2 + 2OH
The ion-permeable on exchange membrane at the center of the cell allows
the sodium ions (Na+) to pass to the second chamber where they react
with the hydroxide ions to produce caustic soda(NaOH). The overall
reaction for the electrolysis of brine is thus:
2NaCl + 2H2O Cl2 + H2 + 2NaOH
A membrane cell is used to prevent the reaction between the chlorine and
hydroxide ions. If this reaction were to occur the chlorine would be
disproportionated to form chloride and hypochlorite ions:
Cl2 + 2OH Cl + ClO + H2O
Above about 60 C, chlorate can be formed:
3Cl2 + 6OH 5Cl + ClO3 + 3H2O
Because of the corrosive nature of chlorine production, the anode (where
the chlorine is formed) must be made from a non-reactive metal such as
titanium, whereas the cathode (where hydroxide forms) can be made from
a more easily oxidized metal such as nickel.
b. Diaphragm Cell
In the diaphragm cell process, there are two compartments separated by
a permeable diaphragm, often made of asbestos fibers. Brine is
introduced into the anode compartment and flows into the cathode
compartment. Similarly to the Membrane Cell, chloride ions are oxidized
at the anode to produce chlorine, and at the cathode, water is split into
caustic soda and hydrogen. The diaphragm prevents the reaction of the
caustic soda with the chlorine. A diluted caustic brine leaves the cell. The
caustic soda must usually be concentrated to 50% and the salt removed.
This is done using an evaporative process with about three tonnes of
steam per tonne of caustic soda. The salt separated from the caustic brine
can be used to saturate diluted brine. The chlorine contains oxygen and
must often be purified by liquefaction and evaporation.
c. Mercury Cell
In the mercury-cell process, also known as the Castner-Kellner proess, a
saturated brine solution floats on top of a thin layer of mercury. The
mercury is the cathode, where sodium is produced and forms a sodium-
mercury amalgam with the mercury. The amalgam is continuously drawn
out of the cell and reacted with water which decomposes the amalgam
into sodium hydroxide, hydrogen and mercury. The mercury is recycled
into the electrolytic cell. Chlorine is produced at the anode and evaporates
out of the cell. Mercury cells are being phased out due to concerns about
mercury poisoning from mercury cell pollution.
Strength of Acids
- Strong acids completely ionize in solution. (100%)
- Weak acids ionize only slightly and are weak electrolytes.(<5%)
Strength vs. Concentration
- Strength refers to ionization in solution.
- Concentration refers to the amount of solute in solution.
- It is possible to have a concentrated solution of a weak acid or base.
- It is also possible to have dilute solution of a strong acid or base.
Organic Acids
- Organic acids all contain the carboxyl group, sometimes several of them.
- The carboxyl group is a poor proton donor, so ALL organic acids are weak
acids.
- Examples of organic acids:
a. Citric acid in citrus fruit
b. Malic acid in sour apples
c. Deoxyribonucleic acid, DNA
d. Amino acids, the building blocks of protein
e. Lactic acid in sour milk and sore muscles
f. Butyric acid in rancid butter
Strength of bases
- Strength of ionic bases in related to solubility:
High solubility = strong base
Low solubility = weak base
- Molecular bases tend to be weak regardless of solubility.
Types of Acids
1. Monoprotic Acids can donate one H atom
Examples: HC2H3O2 ; HCl
2. Polyprotic Acids
a. Diprotic Acids can donate two H atoms
Example: H2SO4
b. Triprotic Acids can donate 3 H atoms
Example: H3C6H5O7 ; H3PO4
Lewis Acids and Bases
- Lewis Acid:
An atom, ion or molecule that accepts an electron pair to form a covalent
bond
- Lewis Base:
An atom, ion or molecule that donates an electron pair to form a covalent
bond
- Lewis Acid-Base Reaction:
The formation of one or more covalent bonds between an electron-pair donor
and electron-pair acceptor. This definition can be applied to phases other than
aqueous reactions.