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COST 507
Definition of thermochemical and
thermophysical properties to provide a
database for the development
of new light alloys
Volume 2
EUR 18499 EN
EUROPEAN COMMISSION
COST 507
Definition of thermochemical and
thermophysical properties to provide a
database for the development
of new light alloys
Volume 2
Edited by
Ansara, A. T. Dinsdale, M. H. Rand
July 1998
EUR 18499 EN
LEGAL NOTICE
Neither the European Commission nor any person acting on behalf of the Commission
is responsible for the use which might be made of the following information.
A great deal of additional information on the European Union is available on the Internet.
It can be accessed through the Europa server (http://europa.eu.int).
Printed in Belgium
COST 507
COORDINATION GROUP C
There are 14 signatory countries to the Action, which had an official commence
ment date on January 1, 1990.
The rapid accessibility of such information will considerably assist the design,
manufacture and utilization of a wide range of different alloy types.
The alloy systems towards which the experimental and evaluation work is being
directed, together with some major applications, are listed below:
Al-Mg-Mn-Fe-Si : cans
EVALUATION PROCEDURE
Bearing in mind the alloy categories defined by industrial partners at the begin
ning of the Action, a matrix was drawn up to define the binary systems forming the
building blocks for the evaluation of higher-order systems. These binaries were then
allocated to the different partners in Group C for evaluation.
All partners made use of the selected data for the elements published by A.T.
Dinsdale ' on behalf of SGTE.
There was also agreement amongst partners with respect to the modelling of par
ticular phases so that consistency could be maintained on proceeding from binary to
higher-order systems combining evaluations originating from different laboratories.
All results were prepared in exactly the same format to facilitate exchange of data
and to provide a standard format for computer storage of the data by the database
manager, Dr.Ansara, in Grenoble.
Evaluations to produce optimized sets of coefficients were carried out using one or
' A . T . Hinsdale, Calphad, 15, 4, 317-425 (1991).
both of t h e two p r o g r a m s Bingss/Tergss w r i t t e n by Lukas 2 and Parrot developped
3
by Jansson contained in t h e Thermo-Calc d a t a b a n k system 4 .
T h e s e p r o g r a m s m a k e use of e x p e r i m e n t a l t h e r m o d y n a m i c and p h a s e d i a g r a m
d a t a , which are fed in as m e a s u r e d values with error limits. Using defined models for
t h e different phases of t h e s y s t e m s concerned, o p t i m i z e d coefficients a r e p r o d u c e d
which p e r m i t a self-consistent description of t h e t h e r m o d y n a m i c p r o p e r t i e s and t h e
p h a s e b o u n d a r i e s of t h e alloys.
2
H.L. Lukas, J. Weiss, and E.-Th. Henig, Calphad, 6, 229-251 (1982)
3
B. Jansson. Ph. D. Thesis, (1984), Div. Phys. Met., Royal Inst. Tech., Stockholm, Sweden.
"B. Sundman, B. Jansson, and J.-O. Andersson, Calphad, 2, 9, 153-190 (1985).
ACKNOWLEDGEMENTS
The members of Coordination Group C express their sincere thanks to the fol-
lowing sponsors of their work:
T h e r m o d y n a m i c Modelling 1
Binary Alloy S y s t e m s
Al -B 15
Al-C (revised) 18
-Ce (revised) 20
Al-Cr 23
Al-Cu 28
Al-Fe 34
Al-Li 40
-Mg (Round 1) 44
-Mg (revised) 48
Al-Mn (revised) 54
Al-Mo 59
Al-N 65
Al-Nb (new) 69
Al-Nd (revised) 75
-Si (revised) 79
Al-Sn 81
-Ta (new) 83
Al-Ti 89
Al- V 95
Al-Y 99
Al-W (new) 103
Al- Zn 109
Al-Zr 112
B-C 117
B-Hf (new) 120
B-N 123
B-Si 126
B-Ti 129
C-Si (revised) 132
C-Ti 134
Ce Mg 137
Cr-Cu (revised) 141
Cr-Mg 143
Cr-Mn 145
Cr-Si 149
Cr-Ti 153
Cr-V 156
Cr-Zn 158
Cr-Zr 161
Cu-Fe 165
Cu-Li 168
Cu-Mg (revised) 170
Cu-N 175
Cu-Si (revised) 178
Cu-Y 182
Cu-Zn (revised) 186
Cu-Zr 192
Fe-Mg 195
Fe-Mn 197
Fe-Si 200
Fe-Ti (new) 205
Hf-T (new) 208
Li-Mg 210
Li-Zr 213
Mg-Mn 215
Mg-Ni 218
Mg-Si (revised) 221
Mg-Y 224
Mg-Zn (revised) 227
Mg-Zr 234
Mn-Si 236
Mn-Ti 241
Mn-Zr 245
Mo-Ti (new) 249
N-Ti (revised) 253
Nb-Ti (new) 256
Ni-V 261
Si-Sn 264
Si-Ti 266
Si-V 270
Si-Y 274
Si-Zn 278
Si-Zr 280
Sn-Ti 284
Sn-Zn 288
Sn-Zr 290
Ta-Ti (new) 293
Ti - V 297
T i - W (new) 299
V-Zr (new) 303
T e r n a r y Alloy S y s t e m s
Al-C-Si 307
Al-Cu-Li 309
Al-Cu-Mg 311
Al-Cu-Si 315
Al-Fe-Mn 316
Al-Fe-Si 319
A]-Li T Mg 322
Al-Mg-Mn 325
Al-Mg-Si 327
Al-Mg-Zn 329
Al-Mn-Si 333
Al-Mo-Ti 336
l-N-Tj 339
Al-Nb-Ti 342
Al-Si-Zn 346
Al-Sn-Zn 347
Al-Sn-Zr 349
Al-Ta-Ti 351
Al-Ti-W 354
B-Hf-Ti 357
Cu-Mg-Y 359
Cu-Mg-Si 360
Cu-Mg-Zn 363
Appendices
Introduction
Standard CALPHAD procedures were used to assess the binary and ternary
systems defined in the COST507 project. In Round 1, binary systems have been
assessed. Several ternary systems have been analysed during Round 2.
In many ternary systems, the three pure elements exhibit different stable crystal
structure. Hence data for metastable binary solutions have been obtained and are
presented in the tables.
In these systems, there are also many binary phases stable on one binary edge
which extend into the ternary system but not all the way across to the other binary
edges, (for example, the Laves-C15 in the Cu-Mg-Zn system or the AIM-D0| 9 in
the Al-Ti-X (X=Mo, Nb, Ti, W) systems). Thus to model the intrusion of these
phases into the ternary systems, the Gibbs energies of the metastable counterparts
of the intruding phase must be defined in the other binary system(s). This means
that when the data of these binary systems are retrieved, there will be data for these
metastable "counterparts".
The main characteristics of each system are given in individual chapters which
include:
a summary of the various stable and metastable phases defined in the system,
the thermodynamic model used to decribe their thermodynamic properties,
the name of the assessor and the reference of the publication in which the
evaluation is described,
a table presenting the crystal structure for each phase in a given system, the
structural type, the Pearson Symbol and space group as well as the occupation
of the sublattices and comments when necessary. This information is taken
from Massalski et al. [90Mas] and Villars et al. [91 Vil].
Thermochemical Database for Light Metal A lloys
T h e r m o d y n a m i c Description
Elements
The Gibbs energy of the pure element i, Gf(T), referred to the enthalpy for its
stable state at 298.15 K, tff(298.15K), is denoted by GHSER,. This quantity is
described as a function of temperature by the following equation:
The first and second derivatives of this quantity with respect to temperature
are related to the absolute entropy and heat capacity of the compound at the same
temperature. Experimental values for heat capacities can thus be directly used in
the optimisation and will be related to the coefficients c,d,e,f,g and h.
For elements which display a magnetic ordering (Cr, Fe, Ni and ),the term
GHSER will be referred to a paramagnetic state. The magnetic contribution is
treated explicity. An additional term is thus added to the molar Gibbs energy of
the magnetic phase.
where is /' , T' being the critical temperature for magnetic ordering (Curie
temperature Tc for ferromagnetic materials or the Nel temperature TN for antifer
romagnetic materials), and the average magnetic moment per atom of the alloy
expressed in Bohr magnetons.
These equations were derived by Hillert et al. [78H1] from an expression of the
magnetic heat capacity C*s proposed by Inden [81Ind].
The value of depends on the structure. For example, is equal to 0.28 for fee
and hep metals and 0.40 for bee metals [81 Ind].
Thermochemical Datahase for Light Metal A lloys
For each element, equation 1 is taken from the SGTE database [91 Din]. These
equations and the magnetic parameters for pure elements are given in Appendices I
and II.
The function GHSER, is also often used to express the thermodynamic functions
of a structure " different from the stable structure of the pure element. The ex
pression G' V "(T) tf'*(298.15K) is equivalent to G%'v'(T) G'*(T) + GHSER,.
The term G'v (T) G (T) is often called the lattice stability of element i.
Binary Compounds
GA,Bb(T) -
#7*(298.15 K) 6 H0/(298.15 ) = f {) (3)
The term A /GA tBb(T) is the Gibbs energy of formation of the compound referred
to the stable elements at temperature T.
Gaseous species
Condensed phases
1: Substitutional solutions:
For magnetic alloys, the composition dependence of Tc and are expressed by:
2: Ordered Phases:
The use of the sublattice model, developed by Hillert and Staffansson [70]
based on Temkin's model for ionic solutions [45Tem] and extended by Sundman
and gren [8lSun], allows a variety of solution phases to be treated, in particular
ordered phases.
(A B ...)p(A B ...)....
where the species A, B , . . . can be atoms, vacancies or ions on the different sublattices
', ", .... The number of sites are p, q, ... If + q + ... = 1, then the thermodynamic
quantities are referred to one mole of sites.
number of sublattices and the species occupying them, is generally obtained from
crystallographical information.
This model also describes stoichiometric phases, in which case the sublattices
are occupied by a single atom, and substitutional phases which only contain one
sublattice.
The terms GQA : and GB.A represent the Gibbs energy of formation of the
stoichiometric compounds A P B, and B P A,, which may be stable or metastable.
The term G is related to the molar configurational entropy and is equal to:
d
G' = R T[p{y'A lny'A + y'Blny'B) + q{y"A lny"A + y'Blny'B)) (16)
xs
Finally, the excess Gibbs energy G is equal to
The terms L, J : , and L;;,,j represent the interaction parameters between the atoms
on one sublattice for a given occupancy of the other, and can be described by a
polynomial, as follows:
The above equations can be expressed for ternary systems and they become more
complicated when the number of species increases in each sublattice.
3. Orderdisorder transformation:
For the COST project, only the orderdisorder transformation relative to the
bcc.42 and bccB2 was considered. A unique function representing the Gibbs
energy is used to describe the thermodynamic properties of both phases as follows:
where A G^d(y') and GJa(x,) are respectively the ordering energy, equal to zero in
the disordered state, and G*"(x,) the molar Gibbs energy of the disordered phase.
&GZd{y') s equal to:
AG^(y,s) = T,EyWA aG
:f + RTL2y;\nyl + b2yr\nyA
i j V i i /
: L L
+' y. ' ',Ba + y'Ay'iiy'A - y'n) y' ',B
i i
L
+yXyB yi lZi + yWaiv - y) y XB
t '
r
+yAyByAyBA ,B:A,B (20)
To ensure stability of the disordered phase, the first derivative of G m with respect
to the site occupation must be zero for any given composition. This condition and
the fact that the ordering energy is zero for disorder leads to constraints between
the thermodynamic parameters describing ordering [88Ans]. Using these constraints
and converting the Gibbs energy of the disordered state into the sublattice formal
ism, allows to express the whole Gibbs energy of both phases (A 2 and P>2) in the
sublattice formalism as follows:
r2 _ 2 _ 1 r2,di
_
^A,B:B ^B:A,B ^ ,
[2 _ r2 _ 1 r2,.3
^CtA.B ^,:0 Ti ^ ,
2 _ 12 _ 1 r2,dis
/
:,0 ^A.CiB ^A,C
2 _ f2 _ 1 r2,d>3
^:,0 ^B,C:A Ti ^ B , C
2,citi ., rF r2,dia
1 / c r2,dia r2,dts ..
r, i2,(,a\
r2,dia\
16 ^, + ^A.C + Z ^B,C I
I / o r 2, , (. r2,dia , c r2,di5\
~ l Z ^A.B + ^A.C + ^B.C /
1 / o f2,di . o r2,d \
<A:A,B,C = A,B,
C :A = 32 l LA,B + *M,C J
1 r o r2,di . Q l2,di \
B:A,B,C = A,B,
C :B = 32 \ LA,B + J LB,C )
C:A,B,C = A,B,
C C: L 3 / 9 2.* Q / 9 2 * \
A,B:A,B,C = A,B,
C :A,B = 0
A,C:A,B,C = A,B,
C :A,
C = 0
B,C:A,B,C = >A,B,
C :B,B = 0
A,B,C:A,B,C = 0 (22)
Neverthless, the use of this sublattice formalism to describe the order disorder
transformation requires the conversion of the parameters of the disordered state into
the sublattice model which is cumbersome. A new treatment of the orderdisorder
transformation was introduced later on by Sundman [9lSun] where G m is expressed
as follows :
AG or,, *(x,X;) =
'
; &GZf' + RT f a ^ x . l n x . r ^ x . l n x , )
t j \ i i /
V^ r O,ord* . / \ V^ r l.ord
+ Z A ^ B 2 ^ Xi LA ,B:i + ^A^Bl^A ~ X) ^ Z ^A,B:i'
i i
V^ rO.ord* , / \ V^ r l.ord*
X L X
+ X A ^ B ^ :A,B + ^ A ^ B ( ^ A ^ B ) 2/ ' ^":,
i i A i B i A i B LA B:A B (26)
Hence, the disordered and ordered phases can be treated separately. The pa
rameters of the disordered phase, L"A B, and those describing the ordering AGAr.B*,
^ABi'i L"ArB* and L A B . A B are introduced as usual thermodynamic parameters of
the sublattice model and a special command then allows their combination to define
the expression of the orderdisorder sublattice following equation 23.
/^rord* A 0/rord
iO.ord rO.ord r O,ord
^i-.j = L-y.i = -Li,j:i ~~Li,r.) =-Li,j:k
LO,ord* rO.ord* rO.ord* / \
: = ~Lyi. = -Lk:i,3 = ij (27)
These relations are identical to 21 and 22 when disordered parameters are not
considered and subregular ordering terms are zero. The use of equation 23 allows
a simpler but mathematically equivalent description with only two ordering param
eters:
When such simplication is possible, the two descriptions (the original using equa
tions 27 and the modified using equations 28) are presented in this report.
For sake of uniformity, the descriptions using the sublattice model with the
constrainsts 21 and 22 were also converted for use of equation 23 in the simpler way
possible .
10 Thermochemical Database for Light Metal Alloys
Only the parameters derived from the simpler description are in the database.
In this report, they are presented in a frame. An example is shown hereunder for a
binary system.
Phase bcc-B2
Phase bcc-/42
Bibliography
System A l B
Solution Phases:
Liquid, fcc,41
Compounds:
A1B2, AIB,2L, A1B.2H
Modelling:
Phase A1B 2
Phase A1B, 2 L
G"{T) //i r '" r_/i, (298.I5 K) 12.0 // B ' /? r '"" nbo R (298.15 K) =
Phase , 2
Phase liquid
1
"A\M = - '2671.16 + 1.81016
/r'AilBUH = 31988.28
/'A'H"'"1 = 15873.74
3000
2600-
O
g 2000
*->
CD
CD
D . 1500
E
o
1000
600
1000
990-
980-
<D 960-
*->
CO 950
\ 940
o
o.
E 930
o
920
fccvl1 fcc- + A B j
910-
900
Al xB 1 0
System A l-B 17
AlB (Al) Cu M 4
Fm3 m
() /?rhomboB
System AlC
Solution Phases:
Liquid, fccyll
Compound:
AI<C3
Modelling:
P h a s e A1 4 C 3
Phase f e e A l
a" = 80
P h a s e graphite
^o.gr.phi,. = go
P h a s e liquid
3000 J I L J L
Liquid
2600-
<J> 2000-
3
+->
Q o
< graphite
Q_ 1500-
E
o
-
000-
fcc-
500
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 08 0.9 1.0
(C) graphite
System AlCe
Solution Phases:
Liquid, bcc,42, (cc-A l
Compounds:
Al,,Ce 3 , Al 3 Ce, AlCe, AlCe 2 , Al 2 Ce
Modelling:
Phase Al n C e 3
CC M
G(T) - 11.0 HA - (298.15 K) 3.0 H^*'(298.15 K) =
574000 + 179.3087 f 11.0 GHSERA, + 3.0 GHSERc
Phase Al 3 C e
1
G{T) - 3.0 /, (298.15 K) Hcc-A l (298.15 K) =
176000 I 54.97964 + 3.0 GHSERA, + GHSERC<:
Phase AlC e
CC M 0 CC M
G"{T) - HA - (298.15 K) H ~ (298.15 K) =
92000 + 33.90118 + GHSERA, + GHSERc.
System A l Ce 21
Phase AlC e 3
Phase LavesC 15
Phase fee/Il
rO.rcr/ti
'JA\,Cr:0 80
Phase Liquid
0,liquid
''Al,Ce 167593.1 + 84.87628
r 1,liquid
''Al.Ce - 36060 + 5.89346
^Ce Ce
22 Thermochemical Database for Light Metal A lloys
Table I Invariant R e a c t i o n s .
Laves-CIS AI2Ce
Al Ce (Al) Cu cF4 M 4
Fm3m
(Ce) Cu cF4 M 4
Fm3m
(Ce) W eli M 2
ImZm
Al2Ce Cu 3 Mg cF14 Ce 8
Fdm Al 16
AlCe3 - 0 AuCu 3 cP Al 1
Pm3m Ce 3
System A l- Cr 23
System AICr
Solution Phases:
Liquid, bcc/12, (cc-A \
Compounds:
AlGr 2 , Al 4 Gr, Al 8 Cr 5 L, Al 8 Cr 5 H, Al 9 Cr 4 L,
Al 9 Cr 4 H, AlCr 2 , Al 13 Cr 2
Modelling:
Assessor and D a t e :
N. Saunders, 1991
Publication:
based on the publication of N. Saunders and V.G. Riviin
in Z. fr Metallkde, 78, (11) 795801 (1987).
Phase AlC r 2
o,feeyli
G{T) - n (298.15 K) 2.0 // r bcc 42 ' para (298.15 K) =
32700.0 8.79 + GHSER A i + 2.0 GHSER Cr
Phase Al 4 C r
Phase Al 8 C r 5 L
Phase AI 8 C r 5 H
Phase Al 9 C r 4 L
Phase Al 9 C r 4
Phase Al u C r 2
Phase Ali 3 C r 2
Phase cc-Al
rO.frc
''AI,Cr:0 45900 + 6.0 T
Phase liquid
/
'A!cr,iH = 29000.0
^i!criH = -nooo.o
System Al Cr 25
Al ^Cr Cr
26 Thermochemical Database for Light Metal A lloys
(Cr) W c/2 M 2
/m3m
AlCr2 MoSi2 /6 Al 2
I4/mmm Cr 4
Al 4 Cr AlCr mP180
P2/m
AlgCrsL AlgCrs 26
R3m
AlgCr 4 L c/52
/43m
System AlCu
Solution Phases:
(stable) Liquid, bcc-A2, fcc-Al
(metastable) hcp-,4.3
Compounds:
(stable) AlCu-i, AlCu-f, AlCu-r,, AlCu-0, AlCu-7(D8 3 )
AlCu-7(H), AlCu-C
(metastable) Laves-C14, Laves-Cl5, Laves-C36
Modellin
Assessor and D a t e :
N. Saunders, 1991
Data relative to the Laves phases evaluated in Round IL
System Al-Cu 29
Phase AlCu
<7(T)2.0 UA f - (298.15 ) 3.0 ^-
c A l
(298.15 ) =
106700.0 + 3.0 + 2.0 GHSERA, + 3.0 GHSERCu
Phase AlCue
G"(T) - IfA -cc-M(298A 5 ) //'ufcc/ll(298.15 ) = G(ALGu) =
36976 + 1.2 + GHSERA, + GHSERc
G'() - 2.0 //"cuCC_j4I(2)8.15 ) = G(Cu:Cu) = 2.0 GBCCCu
'.I = 760024 T
. = -72000
Phase AlCur;
G{T) - llA cc-M(298.15 K) / Y ^ " 4 1 (298.15 K) = G(ALCu) =
40560.0 + 3.14 T + GHSERA, + GHSERCu
G(T) - 2.0 //ufcc_'41(298.15 K) = G(Cu:Cu) = 2.0 GBCCc
C f t = 2574020 T
Phase AlCu0
G(T) - 3.0 //A,fcc_/U(298.15 K) = G(A1:A1) = 3.0 GBCCAI
G(T) 2.0 HA !rc-A i(298.15 K) I$*~M(298.15 K) = G(Al:Cu) =
47406.0 + 6.75 T + 2.0 GHSER A, + 1.0 GHSERc
rO.AICu0 0 0 1
'^ -r,.
AhAI-.Cu il
Phase AlCuC
G(T)-9.0 r/i fcc_/,1 (298.15K)11.0 /7cVufcc'41(298.15 K) =
420000.0 + 18.0 T + 9.0 GHSERAi + 11.0 GHSERCu
Phase AlCu 7 (D8 3 )
G(T) - 5.0 HA {CC-A l(298.15 K) 8.0 //'Ufcc_/U(298.15 K) = G(Al:Al:Cu)
300716.0 + 390.0 T - 52 T InT + 5.0 GHSERA!
+ 8.0 GHSERc
G(T) - 4.0 HA fc-M(298.15 K) 9.0 /V^41 (298.15 K) = G(Al:Cu:Cu)
280501.0 + 379.6 T 52 T InT + 4.0 GHSER
+ 9.0 GHSERc
30 Thermochemical Database for Light Metal A lloys
Phase LavesC l4
L
Auc,uCi4 = 24000 + 2.44
Phase LavesCl5
Phase LavesC36
J I I 1 I I I L
Al ^Cu Cu
Phase bcc,42
. 73554 + 4.0
l,bcc-A2
y
AI,Cii:Q 51500 - 11.84
Phase fee-.41
rO.fcc-AI
53520 + 2
r 1,frc-/tl
'-Al.('ll:0 38590 - 2
r2.frc-.41
'AI,Cu:G 1170
32 Thermochemical Database for Light Metal Alloys
P h a s e liquid
r 0,liquid
',
66622 + 8.1 T
r 1,liquid
''Al.Cu 46800 - 90.8 T + 10 T InT
2,liquiH
L
A\,Cu 2812
(Cu) Cu cF4_ M 4
Fm3m
W e2 M 2
/m3m
o not considered
System A l-Cu 33
AlCui
R3m
AlCufl Al 2 Cu III2 Al 8
14/mem Cu 4
AlCu
3 m
AlCu7(H)
AICuCi hP42 Cl
C2/m
AlCuG C2
not considered
34 Thermochemical Database for Light Metal Alloys
System Al-Fe
Solution Phases
(stable) Liquid, fcc-^41, bcc-i42, bcc-?2,Al5Fe4
(metastable) cbcc-j412, cub-i413, hcp-j43
Compounds:
stable Al 2 Fe, Al 5 Fe 2 ,Al 13 Fe 4 ,
metastable AliiMn 4 , Ali 2 Mn, ALMn
Modelling:
Assessor a n d D a t e :
M. Seierstein, 1991
Comments:
AliiMn 4 , Ali 2 Mn and Al 6 Mn and the hcp-i43 phase
have been evaluated by A. Jansson and T.G.Chart
(1995) in the assessment of the Al-Fe-Mn system.
System A l-Fe 35
Phase fccyll
LAi%Al = - 76066.1 + 18.6758
Phase hcp^43
L
'ihFern'43 = 106903.0 + 20.0
Phase liquid
o.Hqmd _ _ 9 1 9 7 6 5 + 22.1314
L
M,F"id = - 5672.58 + 4.8728
j 2,liquid 1 9 1 Q
Phase Al2Fe
Phase Ali 3 Fe 4
G(T) 0.765 A icc~M (298.15 K) 0.235 //^ bcc 42 ' para (298.15 K) =
G(Al:Fe:Al) = 30714.4 + 7.44 T + 0.765 GHSERA, + 0.235 GHSERFe
G(T)0.6275 HA icc-M (298.15 K) 0.235 HCC~A 2'P(298.15 K) =
G(Al:Fe:a) = 27781.3 + 7.2566 T + 0.6275 GHSERA, + 0.235 GHSERFe
Phase Al5Fe2
Phase Al5Fe4
CC A 1
G(T) - HJ ~ (298.15 K) = 12178.90 4.813 + GHSERA,
G"(T) - HCC-A 2'P"*(298.15 K) = 5009.03 + GHSERFc
A Fe4
A'| Fe = 131649 + 29.4833
Ai^f* = 18619.5
Phase bccf2
0 CC A 1
G(T) - H A ' - (298.15 ) = G(A1:A1:G) = GBCCAI
G-(T) - 0.5 HA fc-A l (298.15 ) 0.5 tfF;bccyl2'para(298.15 ) = G(Fe:AlhO) =
37890.5 + 7.9972 + 0.5 GBCCA, + 0.5 GHSERFe
TFAM> = 521.5 i t o = 1.11
cc M cc_/l2 para
G(T) 0.5 Hli - (298.15 K) 0.5 //^ ' (298.15 K) = G(Al:Fe:D) =
37890.5 + 7.9972 + 0.5 GBCCA, + 0.5 GHSERFc
T^F% = 521.5 & % = 1.11
G(T) ^ c c 4 2 ' p a r a (298.15 K) = G(Fe:Fe:D) = GHSERF(!
r)bccB2
MW. = 1043K fep J
c,Al:F<=:a = 2.22
i0,bccB2 rO,bccB2
^AI,Fe:Al:D =
"AI:AI,Ffea = - 22485.07 + 7.9772
r l,bccB2 r l,bccB2
^Al,Fe:Al:D =
"AI:Al,Fe;0 368.15
rpO,bccB2 TiO,bccB2
i
c,Al,Fe:Al:G = J
c,AI:Al,Fe:Q 189.0
rril,bcc2 rpl,bcc-B2
i
c,Al,Fe:Al:0 r
- / c,AI:AI,Fe:G 63.0
r}0,bccB2 rjO,bccB2
KAI,Fe:AI:0 =
PA\:A\,
F c:a 0.0
TiO,bccB2 rnO,bcc-B2
1
c,AI,Fe:Fe:a ==
l c,Fe:Al,Fe:D = 189.0
o.l.bccBJ <jil,bccB2
1
c,AI,Fe:Fe:D == i
c,Fe:AI,Fe:D 63.0
r}0,bccB2 rjO,bccB2
PAI,Fe:Fe:D = PFe:AI,Fe:n 0.0
rO,bccB2 rO,bccB2
^Fe:Al,Fe:D =
^AI,Fc:Fc:D = - 24694.0 + 7.9772
r l,bccB2 r l,bccB2
Fe:AI,Fe:CI
Al,Fe:Fc:D 368.15
System Al-Fe 37
LM Fe = 30740 + 7.9972
Al Fe = 386.15
Phase b c c 5 2
G(T) - 0.5 W'| fCC_ ' 41 ( 298 15 ) 5 tfF;fcc"'",para(298.15 ) = G(Fe:Al:0) == 2.0 G|.Fc:D
Phase becA2
fO,bcc-A2 _ . n rO
L,
A\,Fe-.a 4 ^AI.Fe
r l , b c c A 2 _ o Un ri
^Al.FeiD ^AI.Fe
Al *>F. Fe
Table I Invariant R e a c t i o n s .
(Fe) Cu cF4 M 4
Fm3 m
(Fe) W cil M 2
mim
Al 2 Fc AI 2 Fe aP18
Fl
AI 3 Fe mC102 designated by
C2/m AI, 3 Fe 4
Al5Fe2 oC*
Cmcm
e c/16? designated by
Al 5 Fe 4
System AlLi
Solution P h a s e s
(stable) Liquid, bcc/42, fcc-A l
(metastable) hep,43
Compounds:
(stable) AlLi, A12L3, Al 4 Li 9
(metastable) AlMg/3, Al 2 Zr, Al 3 Zr, Al 3 Zr2,Al, 2 Mg, 7
Modellin SI
Phase hcp/43
L
\,u7oA3 = 27000.0 + 8.0
System A l-Li 41
Phase bcc/\2
AuTo42 = l.OE06
L2A^-aA2 = 3000.0
Phase fee,41
ujTa' = l.OE06
AU!TD2 = 3000.0 + 0.1
Phase liquid
Ai'!u'd = 41500.0 + 20.96
Ainuid = 10000.0 5.8
Phase AlLi
ACUL = 26000.0
= 2000.0
Phase Al 2 Li 3
Phase Al4Lig
Phase Al 2 Zr
Phase Al 3 Zr 2
1100- J I I I I I I I L
Liquid
1000-
Al Li
(Li) VV cI2 M 2
lmim
Al,Li 3 Ga 2 Te 3 hR15 Al 6
R3m Li, 3
Li2 6
System AiMg
Version I
Solution Phases:
(stable) Liquid, fcc,41, hep,43
(metastable) bcc,42
Compounds:
(stable) AMg- , A l M g t , AlMgC,Al 12 Mg, 7
(metastable) AlLi
Modellin SI
Phase AlMg/?
Phase AlMg
Phase AlMg
rO,All2Mg17
J
Mg:AI,Mg:Mg 17000
Phase AlLi
Phase bcc/42
.'2 = 4971.03.5
L\Z:-n
y
AI,M :Q g
= 900.0 + 0.423
-2.hrc-.-12
2
/,.
'AI.MgtO = 950.0
16 Thermochemical Database for A ghi Metal A lloys
Al ^Mg Mg
Phase fee-
A l
O.fccytl
I. A I , M g : 0 4971.03.5
r l.frcAI
' y AI,M g :D 900.0 + 0.423
2,fcc,41
AI,M g :D 950.0
Phase hcp,43
r 0,hepA3
/y
AI,Mg:a 1950.0 2.0
1, hep A3
/. AI,M g :D 1480.0 2.08
r 2,hcpA3
'AI,M g :D 3500.0
P h a s e liquid
r O.liquiH
'yAl,Mg 12000.0 + 8.566
1,liquid
/y
AI,Mg 1894.0 3.0
r 2,liquid
''AI.Mg 2000.0
System A l-Mg 47
(Mg) Mg 2 M 2
F6 3 /mmc
AI3oMg23 Co 5 Cr 2 Mo 3 53 Al, 18 f
(Mn 44 Si 9 ) 3 Al2 18
Al3 18
Al4 18
Al5 18
Mg, 3
Mg2 6
Mgs 6
Mg< 18
Mgs 18
Mg6 18
System Ai-Mg
Version II
Solution Phases:
(stable) Liquid, fcc-,41, hcp-,43
(metastable) bcc-,42, hcp-Zn
Compounds:
(stable) AlMg-/?, AlMg-e, AlMg-7
(metastable) I,aves-Gl4, Laves-G15, Laves-G36, Mg 2 Zn,,,
Mg 2 Zn 3 , MgZn, (^-phase, r-phase
Modelling:
Assessor and D a t e :
H.-L. Lukas
Comments:
The data for the Laves-C15 phase were evaluated by
T. Biihler for the thermodynamic assessment of the
Al-Cu-Mg system
System A l Mg 49
Phase liquid
12000
^'.' = + 8566 T
A!!MH = 18943
',' = 2000
Phase AlMg/?
Phase AlMg
rO,AI|jMg|7
''M g :Mg:AI.M g = 113100 14.5 T
Phase fcc,41
rO.fccAl
''AI,Mg:a 4971 3.5 T
r l,fccAI
iv
AI.Mg:D 900 + 0.423 T
r2,frcAI
' y AI,Mg:a 950
50 Thermochemical Database for Light Metal A lloys
Phase hcp,43
&a 3 = 19502
= 1480-2.08
r2,hcp-A3 Wff
''AI.MgtQ '30UU
Phase hcpZn
^ASUIO" = 19502
L h
'| Mg^Dn = 1480 2.08
r2,hcpZn _ Ocff
J 0 U U
''Al,Mg:D
Phase LavesGl4
'MgCU = 800
C X " = 8000
1 4
C ^ = 15000
Phase LavesGl5
rO,I.avesC15 1 cnnn
150
AI,Mg:Al = 0
Phase LavesG36
',,^ 36 = 15000
'A = 8000
' = 8000
'AI,Mg:M
. g = 15000
Phase Mg 2 Zn,i
G(T)- 11.0 irA! ~ (298.15 K ) - 2.0 //M'gcp_'43(298.15 K) =
cc Al
Phase Mg 2 Zn 3
Phase MgZn
1000 J I I I L
Al ^Mg Mg
Phase <>phase
Phase phase
(Mg) Mg h PI M 2
PSz/mmc
(MnSi9) R3 Al 2 18
Al 3 18
AL 18
Als 18
Mg, 3
Mg 2 6
Mg 3 6
Mg 4 18
Mgs 18
Mg 6 18
54 Thermochemical Database for Light Metal A lloys
System A l M n
Solution Phases:
Liquid, bcc,42, cbcc,412,
cub,413,fcc,41, hcp,43
Stoichiometric Compounds:
(stable) Al,,Mn 4 , Al 6 Mn, Al 4 Mn, Al 8 Mn 5 i>8,o
(metastable) Al 2 Fe, AlsFe,, Al 13 Fe 4
M o d e l l i n SI
Assessor and D a t e :
. Jansson
Publication:
TritaMac0462, May 1991, Materials Research Center,
The Royal Institute of Technology, Stockholm
Phase ,,.,
G(T) - 11.0 //'i icc /,, (298.15 K) 4.0 /'/' M 'f cc /,,2 ' p, ' ra (298.15 K) =
Phase Ali 2 Mn
Phase Al 4 Mn
G(T)- 4.0 rrA fc-A (298A 5 K) //M'fcc~/,,2'para(298.15 K) =
100005.0 + 30.0 + 4.0 GHSERA, + GHSERM
Phase Al e Mn
cA i
G(T) - 6.0 FfA f - (298A 5 K) r7M'fcc/U2,para(298.15 K) =
124564.3 + 53.6593 + 6.0 GHSERAI + GHSERM
Phase AI 8 Mn 5 D8i 0
G(T) - 22.0 HA CC-M (298.15 K) 4.0 //M^bcc/U2'psra(298.15 K) = G(Al:Mn:Al) =
308671 + 56.6488 + 22.0 GHSERA, + 4.0 GHSERMn
G(T)12.0 //ifcc_/U(298.15 ) 14.0 //M'fcc~'412'para(298.15 ) =
G(Al:Mn:Mn) = 596867 + 94.612 + 12.0 GHSERAI + 14.0 GHSERM
^A|AMnM,,Mn8' = 546234 + 387.348
Phase Al2Fe
Phase Al| 3 Fe 4
Phase ice-Al
r o,fee-Al r l.fcc ,41
, - 69300 + 25.0 ^Al.MtiiD 8800
Phase hcp-,43
rO,hcp-A3 r 1,hep-A3
'. - 108066 + 43.83 ^, = - 54519.8 + 40
Phase liquid
r 0,liquid
", 66174 +27.0988
1,liquid
'', 7509 + 5.4836
2,liquid
'-, 2639
J I I I I I I I L
1700-
Liquid
1500-
Al , -*
1100
1050-
i 1000-
O 950
i_
3
90 fcc-,41
oo
O
Q- 860-
0)
I 800-
750
700 I r-
0.0 005 0.1 0.15 0.2
Al ^Mn
58 Thermochemical Database for Light Metal A lloys
Mn W c/2 bcc,42
Inm
System AI-Mo
Solution Phases:
(stable) Liquid, bcc-,42, fcc-,41
(metastable) bcc-S2, hcp-,43
Compounds:
(stable) Al 12 Mo, Al 4 Mo, AI5M0, ^ , Al 8 Mo 3 , AlMo,
cub-,415
(metastable) AIM-DO,.,, AlTi-Llo
Modellin S
Assessor and D a t e :
N. Saunders (1996)
60 Thermochemical Database for Light Metal Alloys
3000
Al M*> Mo
1100- Liquid + A l , Mo
1000-
fcc-
Icc-AI + Al,, Mo
500- 1
0.0 0.005 0.01 0.015 0.02 0.025
Al -Mo
System A I-Mo 61
Phase AIi2Mo
Phase A l 4 M o
Phase Al5Mo
P h a s e 1 3 7
Phase Al8Mo3
P h a s e cub/115
Phase AlMo
. -, ^
' :, ^,: JUUU
Phase A1MD0, 9
G"(T) - 4.0 /7',fcc_j4I(298.15 ) = G(A1:A1) =
4.0 GHCPAI
G(T) - f{A cc-M(298A 5 K) 3.0 /7 M ' bcc_/,2 (298.15 K) = G(Mo:Al) =
64000 + 15.32 + GHCP A | + 3.0 GHCP M o
G(T) - 3.0 GHCP A , // M ' bcc_ ' 42 (298.15 K) = G(Al:Mo) =
64000 + 15.32 + 3.0 G H C P A I + GHCPMo
G(T) - 4.0 r/ M ' bcc ' 42 (298.15 K) = G(Mo:Mo) =
4.0 GHSERMO
Phase liquid
rO, liquid
, - 100000 + 35
r 1 .liquid
^, - 15000 + 6.3
Phase fcc-,41
rO,fccAl
',: - 92220 + 20
Phase bcc-/12
rO,bcc-A2
''AI.MorO - 75000 + 25
Phase b c c 2
cc A 1
G"(T) - HA f - (298.15 K) = G(A1:A1:D) = 0.0
G"(T) - 0.5 Hi$*-M(298.15 K) 0.5 // M ' bcc " 42 (298.15 K) = G(Mo:Al:D) =
7050 +
G"(T) - 0.5 HA icc-M(298A 5 K) 0.5 // M ' b ^ c 42 (298.15 K) = G(Al:Mo:D) =
7050 +
G"() - //M'oCC"'42(298.15 ) = G(Mo:Mo:D) = 0.0
o = 7050T
=
'':,: 7050 - T
5& = 7050 -T
CbMo":A|2D = 7050 T
System A I-Mo 63
Phase bccB2
G(T) - 0.5 HJcc-A l (298.15 K) 0.5 // M ' b c c " y 4 2 (298.15 K) = G(Al:Mo:D) = 2.0 G A i : M o : D
Phase bcc,42
AMO"=D2 = 75000 + 25
Phase hcp,43
rO,hcpA3
^,:0 85570 + 25 T
(Mo) W cI2 M 2
ImZm
50 AlsW hP12
P63
AI 23 V 4 A123V4 hP54
Pi/mmc
Al63Mo37
AlMo W cI2 M 2
Inm
System Al-N
Solution Phases:
(stable) Liquid, fcc-,41
(metastable) bcc-,42, hcp-,43
Compound:
A1N
Modelling:
Phase A1N
Phase bcc-/12
Phase ice-Al
3000- J L
gas
2600-
TC C .A1
500- -
0.0 0.1 0.2 0.3 0.4 0.6 0.6 07 0.8 0.9 1.0
Phase hcp,43
Phase liquid
System AlNb
Solution Phases:
(stable) Liquid, bcc,42, fccAl
(metastable) bccS2, hcp,43
Compounds :
(stable) AIMDO22, , AlNb 3 A15
(metastable) AlTiLl o ,AlM/J0 19
Modelling:
Assessor and D a t e :
N. Saunders, 1997.
70 Thermochemical Database for Light Metal A lloys
Phase AIMDO22
G(T) - 3.0 //A'| (298.15 K) tfifcc_/,1(298.15 K) =
fcc 41
Ai A Air7b D D 9 = 45760 + 20
r0,AIMD0, 9 4nf)n
^NbrAI.NbrO ^UUU
r o,AiM-Do lonnn
^AI.NbiNbiD 1UUU
5 = l.OE04
,2,AINb 3 AA15 1 onnn
^NbiAl.Nb ~ l^UUU
PhE
fcc_y4I
G(T) - 26.0 //;i (298.15 K) 4.0 H^CC~A 2 (298.15 K) = G(Al:Nb:Al) =
150000 + 96 + 26.0 GHSERA, + 4.0 GHSERNb
G(T) - 8.0 HA CC-A l(298.15 K) 22.0 H^CC~A 2 (298.15 K) = G(Al:Nb:Nb)
635250 + 60 + 8.0 GHSERAi + 22.0 GHSERNb
','., Nh
^A:Nb:AI,Nb = 990000 + 270
AINb.AI.Nb = 420000
System A l-Nb 71
Phase AlTiLln
^AiANb:fl = 80800 + 30
AiAA[.NbL1 = 80800 + 30
S10 = 37600
b'0 = 37600
Phase bcc,42
'|bNbTo2 = 104050 + 30
ANbTa2 = 91404
AlNbTa2 = 12000
Phase bccB2
^Nb:AI,Nb:D = 8650
1
LO,bec B2 0cn
Al,Nb:AI:G DOU ~ *
LO,bec B2 QCcfi
D 0 U _ l
AI,Nb:Nb:n
72 Thermochemical Database for Light Metal A lloys
Phase bccB2
G A , :Nb:0 = 8650 +
G(T) - 0.5 H^CC~A1 (298.15 ) 0.5 //' bcc "' 42 (298.15 ) = G(Nb:AI:G) = 2 Gl:Nb:n
Phase bcc,42
L
A'|bb"2 = !4050 + 30 T
A f e a 2 = 9140 4 T
4 = 12000
Phase fcc,41
u^o' = 113500+21.1 T
ifS^1
vAI,Nb:0 = 5000
C = 1000
Phase hcp,43
3 = 113500 + 21.1 T
A i * = 5000
n3
JAI,Nb:D = oooo
Phase liquid
Al'.Nbd = 91000 + 25
A" = 6000
ANb" = I5000
System Al-Nb 73
2800
Al XNb - * Nb
Table I - Invariant R e a c t i o n s .
Al 3 Nb-D0 22
Cr 3 Si-.415
74 Thermochemical Database for Light Meta] Alloys
(Nb) W ell M 2
ImZm
Al 3 Nb Al 3 Ti US Nb 2 AIM-DO22
4/mm3m Al, 2
Al, 42
System Al-Nd 75
System Al-Nd
Solution Phases:
Liquid, bcc-,42, dhcp
Compounds:
AlNd 3 -H, AlNd 3 -L, Al 3 Nd, AINd, AlNd 2 , AlNd 3 ,
Laves-C15
Modelling:
Phase A l n N d 3 - H
Phase A l , , N d 3 - L
rO.fcc- , ro.dhrp/
G(T) 0 UM (298.15 ) - 3.0 //d (298.15 ) =
548308.18 + 132.1646 + 11.0 GHSF,RA, + 3.0 GHSF,RNd
76 Thermochemical Database for Light Metal A lloys
Phase LavesGl5
Phase Al 3 Nd
Phase AlNd 2
Phase AINd
Phase bcc,42
rO.fcc- r.
',
Phase Liquid
/
Al,iN.H = 125909.87 + 56.16354 - 21805836 "'
2000
1800
^ 100-
Al ^Nd Nd
LavesC15 = Al 2 Nd
78 Thermochemical Database for Light Metal Alloys
(Nd) W eli M 2
Im5m
System AlSi
Solution Phases:
(stable) Liquid, fcc-A l
(metastable) hcp/13
Modelling:
Phase fcc,41
rO.fccAl
''AI,Si:D 3143.78 + 0.39297
Phase hcp,43
r O.hrpA.T
' y AI.Si:0 3143.78 + 0.39297
Phase diamond
r 0,diamond
'Al.Si 113246.1647.5551
Phase liquid
r 0,liquid
''Al.Si " 11340.1 1.23394
j 1 .liquid
'Al.Si 3530.93 + 1.35993
2.liquid
'Al.Si 2265.39
80 Thermochemical Database for Light Metal Alloys
L
2000-1 1 1 " 1 ' " ' '
dlomond
fcc-yt1
5 0 t
H 1 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Al Si
Table I Invariant Reactions.
System AlSn
Solution Phases:
(stable) Liquid, fcc-,41, bct-,45
(metastable) : hcp-,43
Modelling:
Phase bct-,45
r 0.bct-A5
U.hCt-
''Al.Sn
= 14136.95 - 4.71231
Phase fcc-,41
r O.frc-Al
''AI,Sn:0 = 45297.84 - 8.39814
Phase hcp-,43
r O.hrp-A.l
''ALSiirO = 0.00001
Phase liquid
r 0,liquid
''Al.Sn = 16329.85 - 4.98306
r 1 .liquid
'-Al.Sn = 4111.97 - 1.15145
r 2.liquiH
'-Al.Sn = 1765.43 -0.57390
82 Thermochemical Database for Light Metal A lloys
1000- J I I I I I I I L
Al ">Sn Sn
Table I Invariant Reactions.
System AlTa
Solution Phases:
(stable) Liquid, bcc,42, fcc-A l
(metastable) b c c 2 , hcp,43
Compounds :
(stable) A1MD0 22 ,
(metastable) AlTiLlo,AlMD0,9
Modelling:
Assessor and D a t e :
N. Saunders, 1997.
Phase A1MD0 2
CC_ 41 cc A2
G(T) - 3.0 /Y^
Al ^ o . i u c , H^ - (298.15
V(298.15K) K) =
130456 + 23 + 3.0 G H S E R A I + GHSER T a
M Thermochemical Database for Light Metal A lloys
Phase Al 3 Ta 2 H
Phase Al 3 Ta 2 L
/'.'1 = - 66000 + 20
' AI:AI, la:u
r0,AlM-D0,9 _ OQQQ
'':,: """
/,0A.l ,IH:
!-;"'
lit:U
9
= 20000
Phase
:... = lOE-4
.::,. = 300000
System A l-Ta 85
Phase AlTil 0
LMMJ~*!A = 30000
f-S'' = 20000
Phase bcc-,42
1\,'2 = - 89000 + 30
J
^ = -5000
2
'A = 15000
Phase bcc-/32
C = 8250-T
' w = 8250-T
'AS:O = 8250-T
86 Thermochemical Database for Light Metal A lloys
Phase b c c 2
G"() - 0.5 H]fc-M (298.15 ) 0.5 H^cc-A2 (298.15 ) = G(Ta:AI:D) == 2.0 G,.Ta:D
bcc,42
L 2 89000
,T^O = - + 30
2
iS = 5000
4 { w ! = 15000
Phase cc-A l
,1 = - 100000 + 30 T
Phase hep-A3
1
73 = - 100000 + 30 T
Phase liquid
AI,Tad = 108000 + 30
L
Al'Tad = 600
1700
AIS" =
System Al-Ta 87
2800
Al "'T. Ta
A1M-D022 = AI3Ta
88 Thermochemical Database for Light Metal Alloys
(Ta) W ell M 2
ImZm
AI3Ta2-L o"
Al3Ta2-II o'14
System A l-Ti 89
System AlTi
Solution Phases:
(stable) Liquid, bcc,42, fcc-A l, hcp,43, AIMDO, 9 , AlTiLl 0
(metastable) bcc2
Compounds:
A1MD0 22 , Al 2 Ti, Al,,Ti 5
Modelling:
Assessor and D a t e :
N. Saunders (1992)
Phase AlTiZ,l 0
'A'' = 30000
r2,AITi-.l0
, 20000
^AI A
ATT/''
'AhAI.'l = - 89892 + 44
1.AIT/.1
rAkMT, = 30000
LMMJZ,'AO = 20000
^ThT.T/', = 151342.36
/,'^" = 320004 T
Thvrio1 = 106561.332 T
Phase Al 2 Ti
Phase A1MD022
Phase bcc,42
r
-Mbj7a2 = 128500 + 39 T
'- 2 = 6000
'-,'42 = 21200
Phase bcc-D2
'Alho = 87501.25
Phase bccB2
G(T) 0.5 HA CC-A i (298.15 ) 0.5 //; hcp_/,3 (298.15 ) = G(Al:Ti:0) - 2.0 G AhTi:G
G"(T) - 0.5 Hcicc~M (298.15 K) 0.5 H^ hcp_,43 (298.15K) = G(Ti:Al:D) = 2.0 C A1 . Ti:D
Phase bcc,42
iM,TVa2 = - 128500 + 39
'''42 = 6000
4',2= 21200
Phase fcc-
LA^' = 128970 + 39
l\**r"
AI,Ti:0 = 5000
^Aijho' = 20000
Phase hep.43
0,73 = - 133500 + 39
LMJXC?3 = 750.0
I2MhT7a3 = 17500.0
System Al-Ti 93
Phase liquid
rU,liquid
'-. - _ 108250 + 38
1 .liquid
'-Al.Ti 6000 + 5
2,liquici
-'
', 15000
J I I I I
Al Ti
Table I - Invariant Reactions.
I MDO., = AI:iTi
94 Thermochemical Database for Light Metal A lloys
(Ti) Mg hP2 M 2
P&i/mmc
(Ti) W cI2 M 2
ImZm
AI5T3 IP32
14/mbm
S AI 3 Zr 1116 AITi5
from [91 Vil]
System Al-V
Solution Phases:
Liquid, bcc-,42, fcc-,41
Compounds:
A1,OV,A1TV, A123V4, A1M-D0 22 , Al e V 5
Modelling:
Assessor a n d E a t e :
N. Saunders (1991)
Phase A1,0V
Phase A1 23 V 4
Phase A1M-D0 2 2
Phase A17V
Phase A18V5
rO,bcc-A2
''AI.ViG 95000 + 20
j l,bcr-A 2
''AI,V:D 6000
Phase feeAl
I/,ca;0A = 69800 + 15
r 11.1er
. f e r - Al
= - 8000
',
Phase liquid
/-,|7 iH = - 50725 + 9
r 1 .liquid
'JAI,V 15000 + 8
A1MD0 22 .,
System Al-V 97
(V) W r/2 M 2
ImZm
AI23V4 A1S3V< 54
P6 3 /mmc
System Al-Y
Solution P h a s e s :
Liquid, bcc-,42, fcc-,41, hcp-,43
Compounds:
AI3Y, A12Y, A1Y, AljYa, A13Y5, A1Y2
Modelling:
Phase A1 2 Y
Phase A1 2 Y 3
( 7 ( T ) - 2 . 0 / / A l f r c - / U ( 2 9 8 . 1 5 K ) - 3 . 0 // Y ' h c p - 4 3 (298.15 K) =
- 373605.0 + 84.410 + 2.0 GIISF,RA, + 3.0 GIISFR>
100 Thermochemical Da<a/>a.se for Light Metal Alloys
Phase A13Y
G"(T) - 3.0 HA'I - (298.15 K) - 7/'v'hcp-'4:,(298.15 K) =
CC A1
Phase A1)Y5
G"(T) - 3.0 HAi ~ (298.15 K) -5.0 //Y'hcp_/,3(298.15 K) =
cc M
Phase A1Y
cc M
G(T) - irA! - (298.15 K) - II Y'Kcp-/13(298.15 K)
173810.0 + 40.86831 T + GIISFRA, + GHSERc
Phase AIY2
G"(T) - tlAicc-M (298.15 K) - 2.0 /7Y'hrp->l3(298.15 K) =
- 190908.0 + 44.38629 T + GHSERAI + 2.0 GIISFRy
System Al Y 101
Phase bcc-,42
'AI.Y:0 90 T
Phase hcp-,43
rO,hcp-A3
',: = 90
P h a s e liquid
rO,liquid
'. 202611.28 +4.63942
r 1,liquid
', 54350.11 + 0.28402
r 2,liquid
'', 83347.01 - 34.76401
r 3,liquid
', 15488.69 - 0.7988
,liquid
', ~
51205.9 + 30.2161
Table - Invariant R e a c t i o n s .
(Y) Mg hP2 M 2
Pfy^/mmc
(Y) W C2 M 4
ImZm
Al 3 Ya Ni3Sn hP8 Al 6
Pfo/mmc Y 2
, Cu, Mg cF24 Al 16
FdZm Y 8
System Al-W
Solution Phases:
(stable) Liquid, bcc-,42, fcc-Al
(metastable) bcc-B2, hcp-,43
Compounds:
(stable) A1,2W, A14W, AI5W, A177W23, A17W3, A12VV
(metastable) A1M-D0.9, AlTi-Llo
Modelling:
Assessor and D a t e :
N. Saunders, 1996.
104 Thermochemical Database for Light Metal Alloys
4000
Al ^w
W
Liquid 4- Al, W
1200-
Liquid + A I . W
Lkid t A I , , W
700- 1 1 1
0.0 0.005 0.01 0.015 0.02 0025
Al ^W
System -W 105
Phase A112W
Phase A14W
Phase A15W
Phase A12W
Phase A177W23
Acc 2
G(T)-77.0 HM'CC
A
~ (298.15K)-23.0 Iltf ~ (298.15 K) =
189300 400 + 77.0 GHSERAI + 23.0 GIISERw
Phase A17W3
Phase AIMDO 19
c M
<7(T)7.0 HA f - (298.15 K) 3.0 //wbcc_/12(298.15 K) =
frc /U
G"(T) - 4.0 //Ai34700 70 K)
(298.15 + 7.0
= G(A1:A1)
GHSERA=, + 3.0 GIISERw
4.0 G1IC PA1
G(T) - 1IM<CC-M(298.15 K) 3.0 //wbcc'42(298.15 K) = G(W:A1) =
12716+15.16 + GIICPA, + 3.0 GIICPW
G"(T) - 3.0 HA irc~M (298.15 K) // w bcc_/,2 (298.15 K) = G(ALW) =
12716 + 15.16 + 3.0 GIIGPAi + GIICPW
G"(T) - 4.0 //wbcc_/12(298.15 K) = G(W:W) =
4.0 GIISERw
106 Thermochemical Database for Light Metal Alloys
Phase bcc,42
L
Mbw7n2 = - 27000 + 25
1
C = 10000
Phase bccf2
Phase bccB2
GhWiO = lOE4
Phase bcc,42
L
A\yi7a2 = - 27000
+ 25
2
^ 7 = - 10000
System Al-W 107
P h a s e fcc-,41
rO.frr-Al
''AI.W:0 = - 19250 + 20.2
j .-r-Al _ - 10000
Phase hcp-,43
r l.hrp-,13
''Al,W:Q - 10000
Phase liquid
0.liquid
r
'AI.W - 70000 + 35
r 1i . .liquid
''AI.W
uqi
l.OE-4
-2,liquid
'AI,W 15000
(W) W cI2 M 2
ImZm
A1 5 W AlsW hP12
Pfk
System AlZn
Solution Phases:
(stable) Liquid, fcc-,41, hcp-Zn
(metastable) hcp-,43
Compounds:
AlOu-r/, Laves-Cl4
(melasi able)
Modelling:
Substitutional, Redlich-Kister
Liquid Substitutional, Redlich-Kister
fcc-,41 Substitutional, Redlich-Kister
hcp-,43 Substitutional, Redlich-Kister
hcp-Zn Stoichiometric, (Al)(7,n)
AlCu-r, Sublattice model, (Al,Zn) 2 (Al,7,n)
Laves- CI 4
Assessor and Date:
S. an Mey (1991)
Publication:
Z. fr Metallkde, 84, 7, 451-455 (1993).
Phase fcc-,41
O.frx- A 1
'., 7297.48 + 0,17512
r 1 .irr-,11
' , :Q 6612.88 -4.59110
r2.frr-Al _
''Al.ZnrO 3097.19 + 3.30635
Thermochemical Dafaoase for Light Metal Alloys
Phase hcp-,43
rO.hrp-A.T
',7,:0 = 18820.95 --8.95255
r 1,hep-A3
',: = l.OE-6
r2.hrp-.43
', = l.OE 6
,3,hcp-A3
', - 702.79
Phase hcp-Zn
r O.hrp7n
''AI.Zn:0 = 18820.95 -- 8.95255
r 1 ,hrpZn
', = 1.0F-6
r2,hrp-Zn
'. = l.OE-6
3,hepZn
''. - 702.79
Phase AlCu-r;
Phase LavesCl4
Phase liquid
Ai'.znid = 10465.553.39259
System Al Zn 111
1000 J I I I I I I I L
Al ^Zn Zn
Table I - Invariant Reactions.
Al Zn (Al) Cu cF4
FmZm
(Zn) Mg hP2
63/mm c
112 Thermochemical Database for Light Metal A lloys
System AlZr
Solution Phases:
Liquid, bcc,42, fcc,41, hcp,43
Compounds:
Al2Zr,Al2Zr3, Al3Zr, Al3Zr2, Al3Zr5,
Al4Zr5, AlZr, AlZr2, AlZr3
Modelling:
Assessor a n d D a t e :
N. Saunders (1991)
Phase Al2Zr
Phase Al2Zr3
Phase Al 3 Zr
Phase Al 3 Zr 2
Phase Al 3 Zr 5
CT - 3.0 nMtcc-A
(298.15 ) 5.0 /T^ hcp ' 43 (298.15 ) =
Phase Al 4 Zr 5
P h a s e AlZr
CT - IIA CC-A 1
(298.15 ) H^cp-A 3(298.15 ) =
Phase AlZr 2
CT - If0A cc-A l
(298.15 ) 2.0 ^~3 (298.15 ) =
/AKZr^ 2 = 15000
111 Thermochemical Database for Light Metal Alloys
Phase feeAl
r 0.rcc-.4l
". - 120000 + 30
I I .fee-AI
'". -10000
r2.fec-AI
', 15000
Phase hepA3
rO,hrp-A3
', - 122300 + 32
r 1,hep-A3
', -8000
r2.hrp-A3
''Al.ZnO 17000
Phase liquid
r 0,liquid
l'Ai 7r 125000 + 35
r 1,liquid
'.
10000 + 5.57
2,liquid
I.Al.Zr 15750
Al X7, - * Zr
System A l- Zr 115
(Zr) Mg hP2 M 2
P&s/mmc
(Zr) W cI2 M 4
ImZ m
InN2 hP6 Al 2
POa/mmc Zr, 2
Zr2 4
116 Thermochemical Database for Light Metal A lloys
Al3Zr4 3 4 hP7 Al 3
Zr, 1
Zr2 1
Zr3 2
System B-C
Solution Phases:
Liquid, graphite, /J-rhombo-B, R 4 C
Modelling:
5000
4500-
4000-
T T T T T T "
0.0 0.1 02 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Xc -" c
118 Thermochemical Database for Light Metal A lloys
Phase B<C
Phase /9rhomboB
Phase graphite
yo.gr.phu* = 34385 9 5 + 8 6792 T
Phase liquid
(C) graphite
System B-Hf
Solution P h a s e s :
Liquid, bcc-,42, hcp-,43
Compounds:
(stable) BHf, B2Hf
(metastable) BJIf 3
Modelling:
Assessor a n d D a t e :
II. Bitterman, Univ. Vienna, Austria
Phase BHf
P h a s e B,Hf 3
Phase bcc-A2
Phase hcp-,43
0,0rhombo
G(T)-0.5 HB (298.15K) - H^ncp_/,J(298.15K) =
- 44765.7 + 0.5 GHSERB + GHSERf
O.hrp-,1.1
,-.1 , .
l'Hf:H = 1-0-4
Phase liquid
L'l,7fuiH = -170625-4.85541
L'1;?;"'1 = -39128
2.1iqiiirl
I,H.ur 16331.1
122 Thermochemical Database for Light Metal A lloys
(Hf) Mg hP2 M 2
P&i/mme
(Hf) W c2 M 2
ImZm
System B N
Solution P h a s e s :
Liquid, gas
Compound:
BN
Modelling:
Assessor a n d D a t e :
II. Wen, and ILL. Lukas 1992
1 I 1 1 I I I I
gas _
400CH '-
1 5 0 0 /?rhomboB m gas
1000^
1 1 I I I I I
0.0 0.1 0.2 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
^
124 Thermochemical Database for Light Metal Alloys
T h e r m o d y n a m i c p r o p e r t i e s of t h e s o l u t i o n a n d c o m p o u n d p h a s e s ( J . m o l " 1 )
Phase BN
P h a s e liquid
BN hP4
P6^mc
126 Thermochemical Database for Light Metal A lloys
System BSi
Solution P h a s e s :
Liquid, diamond, /3rhomboB, BSi, B 3 Si, BSi
Modelling:
A s s e s s o r and D a t e :
S. Pries, and H.L. Lukas,
Publication:
"Cost507 New Light Alloys", Leuven Proceedings,
Ed. G. Effenberg (1991)
S
System fi Si 127
Phase B 3 Si
C(T) 12.0 //^" r , , " m b o " B (298.15 K) 2.0 // s ; diamond (298.15 K) = G(B:Si:B) =
112000 + 12.0 G I I S E R B + 2.0 GHSER s i
C(T) - 6.0 //'H' /5 rhombo B (298.15 K) 8.0 /7s'di,lmnd(298.15 K) = G(B:Si:Si) =
112000 + 6.0 G I I S E R B + 8.0^ GHSF.RS
'H:Si:H,si = " 2400475 + 240.0475
Phase BSi
C(T) - 25S.0 //' /3_r, '" n ' ho " B (208.15 ) 23.0 //; HiamonH (298.15 ) =
G(B:Si:B) = 729824.4 72.98244 + 258.0 GHSER B + 23.0 GIISER s i
C(T) 210.0 //B' r h " m b o B (298.15 K) 71.0 /7' di " mnnd (298.15 K) =
G(B:Si:Si) = 5451560545.456 + 210.0 GHSER B + 71.0 GIISERsi
f.H:s:H.s = 15715630 + 1571.563
Phase BSi
Phase / ? - r h o m b o - B
Phase diamond
t Cl,diamond C-70TO i c
'H.sr.a = 579/8.16
Phase liquid
x uicpnH _ _ 3 5 2 6 og + 0.3527 T
128 Thermochemical Database for Light Metal A lloys
BSi HR12
PZm
System B T i
Solution P h a s e s :
Liquid, bcc,42, hcp,43
Compounds:
BTi, B 4 Ti 3 , B 2 Ti
Modelling:
Assessor a n d D a t e :
C. Btzner, June 1994
Publication:
Thesis, Univ. Stuttgart, Germany (1994)
T h e r m o d y n a m i c p r o p e r t i e s of t h e s o l u t i o n and c o m p o u n d p h a s e s ( J . m o l ')
P h a s e BTi
Phase B4Ti3
(7(T) 4.0 //H ,/5 " rhomb "~ B (298.15K) 3.0 H^cp~A 3(298A 5K) =
660745.8 + 4.3472923 + 2.162216 InT
+ 4.0 G I I S E R B + 3.0 GIISER T i
P h a s e B 2 Ti
rhom, , B
C(T) - 2.0 // B '" " (298.15K) //T hrp ' 43 (298.15K) =
318253.47 2.5557 + 0.799221 InT
+ 0.002813367 2 + 2.0 GIISER B + GIISER Ti
130 Thermochemical Database for Light Metal A lloys
I 1 1 l i l i l
4000
Liquid
3600
3000
d)
2600
*->
CD
^^^bccyl 2
O 2000 /?rhomboB
. M
E
m
,> 1600 CD m
1000
hcp-A 3 _
600 1 1 1 I l l l l
0.0 0.1 0.2 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
Ti
Phase becA2
Phase hcp,43
,rhombrt
G'() - 0.5 (298.15) /rrincp>,J(298.15K) =
Phase liquid
r 0.liquid
'H.Ti 265414.4 + 15.543418
r 1l.liqi
.liquid
'H,T
134303.03 + 17.709482
r 2.liquid
'. 61691.479
*,', = 52656.13
System Ti 131
(Ti) Mg hP2 M 2
Pb^/mmc
(Ti) W cI2 M 2
ImZm
BTi Fe 0P8 4
Pnma Ti 4
B2Ti 2 hP3 2
P6/mmm Ti 1
BTi3 B 4 Ta 3 0II4
Immm
132 Thermochemical Database for Light Metal A lloys
System CSi
Solution Phases:
Liquid, diamond
Compounds:
SiC, Si 4 C 3 (metastable)
Modelling:
Assessor and D a t e :
J. Grbner, II. L. Lukas, and F. Aldinger.
Publication:
Calphad 20, 2 (1996) 247254.
P h a s e SiC
Phase A1 4 C 3 (metastable)
Phase liquid
":^'"" = 25644.976.381115
Phase diamond
U.rliamnnrl
'C.Si 93386.78
System C S i 133
graphite
1000- diamond *
500 I I I I I I I I I
0.0 0.1 0.2 0.3 0.4 0.6 0.6 0.7 0.8 0.9 1.0
Si
System CTi
Solution Phases:
Liquid, bcc,42, fcc-A l, hcp,43
Modellin Si
P h a s e fcc,41
graphite
C(T) - // (298.15 K) // Ti hrp >13 (298.15 K) = G(Ti:C) =
207709.0 + 307.438 48.0195 InT 0.00272 2
- 2.03E+09 3 + 819000 1
OS rc.-Al
''TWO 8 5 1 1 5 + 6.756
1. f r e Al
'TWO 129429 + 31.79 T
Phase bcc,42
G"(T) - 3.0 /7 c g r a p h i t e (298.15 K) Hr^cp~A 3 (298.15 K) = G(Ti:C)
2295533 + GIlSER T c + 2.0 GHSERc
\S^M = 2590609
P h a s e hep ,43
gn,phUe
G'() - 0.5 flc (298.15 ) Iltfcp-A 3(298.15 ) = G(Ti:C)
1432 4.1241 + 0.5 GHSER T c + 0.5 GHSERc
P h a s e liquid
5000- I I I I I I I I L
C x T i -> Ti
Table I - Invariant Reactions.
fcc-/11 T i r C i _ r
(Ti) Mg h PI M 2
Ps/mmc
(Ti) W 11 M 2
hnZm
136 Thermochemical Database for Light Metal Alloys
System C e M g
Solution Phases:
Liquid, bcc,42, fcc-A l, hcp,43
Compounds:
CeMg, CeMg2, CeMga, Ce 5 Mg 4 i, Ce 2 Mg 17 , CeMg, 2
Modellin S
Phase C e 2 M g i 7
Phase C e s Mg 4 1
Phase C e M g
C(T) - II^c-A i
(298.15 K) II^P'A 3 (298.15 K) =
46000.0 + 23.32 + G H S E R c + GHSER Mg
138 Thermochemical Database for Light. Metal A lloys
Phase CeMgi 2
C(T) - ll^-A i
(298.15 K) 12.0 //^hcp_'43(298.15 K) =
139880.0 + 84.5 + GHSERc + 12.0 GHSERMg
Phase CeMg 2
Phase CeMg3
r<*M* = 2 7 0 n n + 3.3 T
C i " = 15106.9
Phase feeA l
1500
f'cjulo = + 5 T
Phase hcp,43
Phase Liquid
. = 15106.9
System Ce-Mg 139
Ce ^Mg Mg
950 _i I I I L _ i I I I I I
940
920
2 910-
900
Ce,Mg,7
Q_ 890
E CeMgj+CejMg 4,
Q 880-
r-
870-
860-
B50 | | r | | r
0.8 0.82 084 086 0.88 0.9 0.92 0.94 0.96 0.98 1.0
Ce k
Mg
140 Thermochemical Database for Light Metal A lloys
(Ce) W eI2
ImZm
(Mg) Mg hP2
Pfts/mmc
CeMgj Cu 2 Mg cF24 Ce 8
FdZm Mg Hi
System CrCu
Solution Phases:
(stable) Liquid, bcc,42, fcc-A l
(metasi able) hcp.43
Modelling:
Assessor and D a t e :
Phase bcc,42
r0,t><-r-/t2
''Cr,Cu:0 = 200000
P h a s e feeAl
rO,{ec-A\
'Tr.Ciy.a 88112 30.38315
Phase hcp,43
, n.hrp,13
'Cr.CuiO 60000
Phase liquid
r 0,liquid
'Cr.Cii 35495.913 2 . 9 5 8
1 .lirpiifl
'Cr.Cii 1001.1765
, 2,l.|ui.l
'Cr.Cii 5704.648
112 Thermochemical Datahase for Light Metal Alloys
fcc-,41
750-
500 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cr *>Cu Cu
(Cu) Cu cF4
FmZm
System Cr-Mg 143
System CrMg
Solution Phases:
(stable) Liquid, bccA2, hcpA3
(metastable) cbccA12, fcc,41, hcpZn
Modelling:
Assessor and D a t e :
I. Ansara, 1991
Phase becA2
/"' = 80
P h a s e cbcc,412
,0.rl,cr-,412
'-C'r.Mg:a = 80
Phase fcc,41
rO.frc-^l
'-Cr,M g :a 80
Phase hcp,43
rO,hcp-/43
''Cr.M g :0 = 80
Phase h c p Z n
r O.hcpZn
Q o = 80 T
Phase liquid
r 0,liquid
'Tr.Mg 94500.0
12;
cMg = >000
1-1-1 Thermochemical Database for Light Metal A lloys
3000 4 i 1 1 1 1 " 1 1 1 L
Liquid' + Liquid"
2500
2000 Liquid"
Q_ 1500 bcc-A 2
E
>
000
hcpyl 3 *
600 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.6 0.6 0.7 0.8 0.9 1.0
Cr ^Mg Mg
(Mg) Mg hP2
Pb\/mme
System Cr Mn 145
System CrMn
Solution Phases:
Liquid, bcc,42, feeA l, hcp,43, cbcc,412,
cub,413, erL, -tt
Compound:
Cr 3 Mn 5
Modelling:
Publication:
Scientific Croup Thermodata Europe Database
Phase C r 3 Mn 5
0 hrc /,2 pa ,
C(T) - 3.0 ffc .; ' " (298.15 K) 5.0 r7 b c c A I 2 p a r a (298.15 K) =
72550.0 + 21.1732 + 3.0 GIISER C r + 5.0 GHSF.RMn
Phase feeAl
FO.frr
'C'r.Mii:0 - 19088 + 17.5423
Phase cbcc,412
^r'r.Mn"a'2 = - 36796 + 20.385
Phase liquid
r O.liquid
D.liqun
'C'r.Mn
15009 + 13.6587
r 1 .liquid
'Tr.Mn 504 + 0.9479
146 Thermochemical Database for Light Metal A lloys
Phase cub,413
cwLo 1 3 = 31260
+ 16.4919
Phase bcc,42
L
Cr b M:a 2 = " 2 0 3 2 8 + 187339
/X:o2mag = 0.48643
X'o2""18 = 0.72035
Ci""1 = 193265
-O, b e c - Al
c,Cr,Mn:a 1325
Ti2,bccv42 1 1 QQ
1 1 J J
c,Cr,Mn:a ~
3,1o = "10294
rp6,bcc-A2
O.Cr.MniO 26706
rc8cbrc,CMn1o = -28117
Phase L
G"[) - 8.0 ^ r bcc A2 ' para (298.15 ) 22.0 ffbccA12'para(298.15 ) =
G(Mn:Cr:Cr) = 65859.5 + 8.0 GFCCM + 22.0 GHSERcr
G(T) - 26.0 //bccA2'para(298.15 K) 4.0 tfbccA'2'par"(298.15 K) =
G(Mn:Cr:Mn) = 172946.0 + 69.0245 T + 8.0 GFCCMn + 4.0 GHSERc,
+ 18.0 GBCCM
MffrcLr:Cr,Mn = 1095771 + 862.0312 T
Phase oH
G(T) - 8.0 //C' ' ""(298.15 K) 22.0 ffM*bccA,2'par,,(298.15 K) =
bcc A2 p
Z*_ fccyll
Cr ^Mn Mn
Mn - c58 cbcc-,412
143m
Mn W c2 bcc-,42
ImZm
' Cr,Mni_ x HT 0
n" Crj-Mni-j LT -
System CrSi
Solution Phases:
Liquid, bcc-,42
Compounds:
Cr 5 Si 3 , CrSi,, Cr 3 Si-,415, CrSi 2
Modelling:
Phase liquid
r 0,liquid
Cr.Si 119216.90 + 16.11445
r 11 .liquid
.liquir:
'-Cr.Si
47614.70 + 12.17363
Phase bcc-,42
r0.bcc-/12
'Cr.Si - 104537.94 + 10.69527
r l.bcc-A2
''Cr.Si -47614.70 + 12.17363
150 Thermochemical Database for Light Metal A lloys
Phase C r 3 Si/115
bcc /,2 para
G"() - 4.0 //t; ' (298.15 ) = G(Cr:Cr) =
20000.0 + 10.000 + 4.0 GHSERc,
C(T) 3.0 //C'bccA2,para(298.15 K) //|;diamond(298.15 K) = G(Cr:Si) =
126369.35 + 4.15051 + 3.0 GHSERc, + GIISERsi
<7(T) // Cr bcc ' 42para (298.15 K) 3.0 //;diMnond(298.15 K) = G(Cr:Si) =
233507.47 74.15051 + GHSERc, + 3.0 GHSERSi
C(T) - 4.0 //s;Hiamond(298.15 K) = G(Si:Si) =
208000.0 80.000 + 4.0 GHSERsi
/<?&?:?, = r<6?M = 107840.95
Cr Xc, > Si
Cr Si (Cr) W cI2 M 2
ImZm
System CrTi
Solution Phases:
Liquid, bcc,42, hcp,43
Compounds:
LavesC14, LavesCl5
Modelling:
Phase L a v e s C l 4
r 0,l.avr--C
''Cr,ri:Cr = LCr,Ti:'l'i 60000.0
154 Thermochemical Database for Light Metal A lloys
Phase LavesC l5
r O,I,veC15 rO,LsvMC15
'Cr,Ti:Cr -Or.Ti-.T,
2100
1900
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cr , > Ti
Phase liquid
,., = 5 2 5 0
'Cr.T
{j** = 1500
Phase hep A3
gff3 = 32500
System Cr-Ti 155
Phase bcc-,42
I 0.bcc-,42
''Cr,Ti:D 19100
r 1,bcc-,42
''Cr,Ti:G 5500
r 2.bcc-,t2
-Cr.TiiQ 1750
Table I - Invariant R e a c t i o n s .
(Ti) Mg hP2
P6i/mmc
(Ti) VV cI2
ImZm
System C rV
Solution Phases:
Liquid, bcc,42
Modelling:
Publication:
Scientific Group Thermodata Europe Database
Phase bccA2
f'C%nM = 987A
2-mA T
Phase liquid
jMiquM _ _ 9874 _ g (gg,, j ,
^ = 1720 2.5237
System Cr-V 157
^ 2300- Liquid
Q)
v_
2200-
Q.
E
o bcc-j4 2
I 2100-
2000
1 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cr xv -* V
Table I - Crystal Structure and Phase Description.
System CrZn
Solution Phases:
(stable) Liquid, bcc,42, hcpZn
(metastable) fcc,41
Compounds:
CrZnin, CrZni7
Modelling:
Assessor and D a t e :
I. Ansara, 1992
2400 J L
2160
Liquid
1900
hepZn
400
0.0 0.1 02 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cr ^Zn Zn
System Cr Zn 159
Phase bcc,42
r O.bcc A2 rr,
''Cr.Zn:D - O 1
P h a s e fcc,41
70.1vx-.41
''C'r,7,n:D 80
Phase h c p Z n
r 0.hcpZn
'Cr,Zn:D = 80
Phase liquid
/,g:d = 19000
/ A ' = 1000
Reaction uncertain
Phase C r Z n ^
C(T) - llcc-A 2p
"*(298.15 K) 13.0 W^ h<:p " A3 298.15K)
Phase C rZn, 7
(Zn) Mg hP2
Pb~a/mmc
CrZn13 CoZn,3
CrZni7
System Cr-Zr 161
System CrZr
Solution Phases:
(stable) Liquid, bcc,42, hcp,43
(metastable) fcc-Al
Compounds:
LavesC14, LavesC15, LavesC36
Modelling:
Phase LavesC 14
J I I I I I I I L
2360-
2100-
1850-
O
1600-
CD
O 1350
O.
bcc-^4 2
<D 1100-
hcp-/t3
850-
B00 I 1 r^ 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cr x 7 , -* Zr
Phase Laves-Cl5
rO.Ijvr.-Cl5
''Cr,Zr:/,r = 70328
rn,I,ave.-C15
''CnCr.Zr = 62910
FO.LavM-CIS
''/,r:Cr,Zr = 62910
System Cr-Zr 163
Phase LavesC 36
ic\ZTrC36 = 52614
I<cl%iC3R = 29400
UZT = 2940
Phase liquid
\^ = 8025.96 0.74259
Phase bcc,42
l
-c^zr7a2 = 16555.47 + 4.92028
c'X"2 = 11365.57
Phase fcc,41
ttXa = 20000
Phase hcp,43
/CrXa43 = 15800
164 Thermochemical Database for Light Metal Alloys
(Zr) Mg hP2 M 2
Pb\/mmc
(Zr) W cl2 M 4
ImZm
System Cu-Fe
Solution Phase s
(stable) Liquid, fcc-Al, bcc-,42
(metastable) hcp-,43
Modelling:
Phase bcc-,42
0,bcc-,42
Cu,Fr:0 39258.0 - 4.14983
Phase fcc-,41
a,!cc-Al
'Cu,Fe:0 48232.5 - 8.60954
1,fcc-,41
''Cu,Fe:D 8861.88 - 5.28975
Phase hcp-,43
r 0,hcp-/t3
''Cu,Kr:0 48232.5 - 8.60954
l.hrp-.
''Cu.FriO 8861.88 - 5.28975
166 Thermochemical Database for Light Metal Alloys
P h a s e liquid
r ,
''Cu = 36088.0 - 2.32968
1,liquid
''Cu.Fe = 324.53 - 0.03270
2,liqilirl
''Cu.Fe = 10355.40 - 3.60297
J ' L
1900-
Liquid bccA2
1700-
1600-
4-> 1300-
-
)
. 1100-
-
I- 900-
*-fcc-Al' bccjl 2
700-
500 I I I I I I I I I
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 OB 0.9 1.0
Cu Fe
(Fe) Cu cF4
FmZm
(Fe) W cI2
ImZm
168 Thermochemical Database for Light Metal A lloys
System C uLi
S o l u t i o n Phases:
(stable) Liquid, bcc,42, fcc,41
Solution P h a s e s
(metast able) hcp,43
Modelling:
P h a s e becAl
O.hcc,42
'Cu.l.hO 50000
P h a s e fcc,41
,0,frc,4l
''Cu,l,i:a 2750 + 1 3 . 0
r l.rcc
''Cu.l.iiD 1000
Phase hcp,43
r0,hcp/t3
''Cu.l,i:D 2042 + 10.9617
Phase liquid
'Cu.qm.l _ 6 6 0 f ) 0 _ 4 4 7 2 3 j.
System Cu-IA 169
Cu Xu
(Li) W
ImZm
170 Thermochemical Database for Light Metal A lloys
System C u M g
Solution P h a s e s
(stable) Liquid, fcc-A l, hcp,43
(metastable) bccf2, hcpZn
Compound:
(stable) LavesC15, CuMg 2
(metastable) LavesCl4, LavesC36, CuZn7
MgZn, Mg 2 Zn 3 , Mg 2 Znn
Modelling:
A s s e s s o r and Date:
C.A. Coughnanowr, I. Ansara, R. Luoma,
M. Hmlinen, and H.L. Lukas
Publication:
. fr Metallkde., 82, 7, 574581 (1991).
Comments:
A new assessment was performed where the lattice
stabilities of Cu and Mg in the LavesCl5 structure were
taken equal to 15kJ/formula unit, in order
to ensure consistency in the database.
System Cu-M g 171
1500- J I I I I I L
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cu x Ma -> Mg
Phase liquid
r 0.liquid
'-Cu.Mg 36962.71 + 4.74394
r I .liquid
''Cu.Mg 8182.19
Phase f c c - A l
I n Sec-AI
''Cii.MgrO - 22059.61 + 5.63232
Phase hcp-,43
r O.hcp-^3
''Cu,MK:D 22500.0 - 3.0
172 Thermochemical Database for Light Metal A lloys
Phase hcpZn
'cu,Mg7on = 22500.03.0
Phase LavesC l4
rO,LavesC14 rO,Laves
C 14 C C OO
_
''Cu:Cu.Mg ^Mgt
C u.Mg t>O3.40
Phase LavesC l5
Phase Laves-C36
Phase C uZn7
K4 = 11552.71 1.67824
K5 = 15732.3 10.26575
K7 = 9000.0 1.5
C(T) - 7.0 / / f ^ 1 (298.15 ) 6.0 // ^ _3 (298.15 ) = G(Cu:Cu:Cu:Mg) =
13.0 4 + 2.0 5 + 6.0 7 + 7.0 GHSERcu + 6.0 GIISERMg
Phase Mg2Znn
C(T) 11.0 Hcicc~A 1 (298.15 K) 2.0 H$cp-A 3(298.15 K) = G(Mg:Cu) =
0.0 +11.0 GHSERcu + 2.0 GHSERMg
Phase Mg 2 Zn 3
C(T) - 3.0 if c f (298.15 K) 2.0 lQhgcp-A 3(298.15 K) = G(Mg:Cu) =
c 41
Phase MgZn
fcc_/U
C(T) - 13.0tfc'u (298.15 K) 12.0 ^-3 (298.15 ) = G(Mg:Cu) =
0.0 + 13.0 GHSERcu + 12.0 GHSERMg
Phase bccB2
CCu : Mg = 0.0
i,Cu,Mg = 2500
C(T) - ircicc~M (298.15 K) = G(Cu:Cu) = GBCCCu
C(T) - 0.5 /7c'ufcc/,1(298.15 K) H^cp-A 3 (298.15 K) = G(Cu:Mg) =
G*Cu : Mg + 0.5 C u M g + 0.5 GBCCC + 0.5 GBCCMg
174 Thermochemical Database for Light Metal A lloys
Phase bccB2
<^C:Mg = 0.0
Cu.Mg = 2500
Phase bcc,42
' o = 40 "Cu, Mg
System C u N i
Solution Phases:
(stable) Liquid, fccAl
(metastable) bcc,42, hcp,43
Modelling:
r0,bcc42
'Cii.Nha 8047.72 + 3.42217
Phase fcc,41
rO,fcc41
'Cu.Niia = 8047.72 + 3.42217
, l.tre-Al
'Cu.Nira = 2041.3 + 0.99714
jOJcc-Al
'c,Cu.NI:Q = 935.5
rpl.fcC-Al
'c.Cu.NI:D = 594.9
/oO.mag.fcc Al
>'Cu.Ni:n = 0.7316
ol.mag.fcc Al
''C,N:0 = 0.3174
176 Thermochemical Database for Light Metal Alloys
Phase hcp-,43
rO,hrp-,43
''Cu,N',:n 8047.72 + 3.42217
r l.hcp A3
''Cli,Ni:D 2041.3 + 0.99714
Phase liquid
r 0,liquid
''Cu.Ni 12048.61 + 1.29893
j 1,liquid
''Cu.Ni 1861.61 + 0.94201
20O0- J I I I I I I I L
Liquid
1750-
fcc-A\
750-
600 r~ 1 1 1 1 1 1 r
0.0 0.1 02 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
Cu Ni
(Ni) Cu cF4
FmZm
178 Thermochemical Database for Light Metal A lloys
System C uSi
Solution Phases:
(stable) Liquid, bcc,42, fcc,41
(metastable) hcp,43
Compounds:
(stable) C1156S117, Cu^Sie, CuigSieT? , CuMS7<S
(metastable) LavesCl5
Modellin SI
Assessor and D a t e :
M. Jacobs, 1991. Revised by T. Bhler et al. 1997
Phase bcc,42
r0.hccA2
'O..Si:G = 21740 + 3.9
r l.bccA2
''Cu.Si:0 = 40000 4.39
r2.bcr/12
''Cu.ShO = 100
Phase feeAl
rO.frc-Al
'Cii.Si:0 = 34105.96 1.908
System Cu-Si 179
J I I 1 I I I I L
1700-
Liquid
1500-
diamond -
600 1I 1 1 1 1 1 1
0.0 0.1 02 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Cu ! - Si
1200
1150
1100
a>
1
CO 1050
a.
E 1000-
o
950-
900
0.25
Cu -
180 Thermochemical Database for I/ight Metal A lloys
Phase hcpA3
wO.hcp-Al
''Cu,Si:D 19948 2.356
r 1.hcp,43
'Cu,Si:0 23800 1.97
r2.hrp-A*
''Cu.Siia 20
Phase liquid
r O.liqiliH
''Cu.Si 39688.86 + 14.27467
r 1 .liquid
''Cu.Si 49937.13 + 29.78960
r 2,liquid
''Cu.Si 31810.16 + 18.00804
P h a s e CU33S17S
(7() 33.0 //Cu "'"(298.15 ) 7 . 0 tfs'di,lmond(298.15 ) =
fcc
Mg hPI M 2 hcp,43
P63/mmc Cu 7 Si in [91 Vil]
S hPlI
1 /3Mn cPIO M, 8
P4,32 M2 12
W c/2 M 2 bcc,42
ImZm
182 Thermochemical Database for Light Metal Alloys
System Cu-Y
Solution Phases:
Liquid, bcc-,42, hcp-,43, Cu 6 Y
Compound:
CuY, Cu e Y, Cu 7 Y 2 , Cu 2 Y-R, Cu 2 Y-H, CuY
Modelling:
Phase bccA2
rO,bcc-,42
^Cu,Y:D 80.0
Phase hcp-,43
rO,bcp-A3
L
Cu,Y:a - 80.0
Phase liquid
r O.liquid
^Cu.Y - 88958.06 + 21.5667
r 1,liquid
^Cu,Y - 33607.31 + 3.10462
r 2,liquid
^Cu.Y 8083.16 - 0.74669
System Cu-Y 183
Phase fccAl
L-M = 80.0
Phase C u 2 YR
Phase C u 2 YH
Phase C u6Y
Phase C u 7 Y 2
Phase C uY
2000 J I I I I I L
1750 bcc-A 2
Liquid
^ 1600
O
i_
hcp,4 3
CO 1250
=PN.
Q. fccjt1
E 1000
03
750
500) 1 1 1 1 1 1 1
0.0 0.1 02 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
Cu
Table I Invariant Reactions.
(Y) W ell M 4
ImZm
(Y) Mg hPI M 2
P&3/mmc
Cu 7 Y 2 not in [91V1]
Cu 2 Y CeCu 2 olii Y 4
Imma Cu 8
System C u - Z n
Solution Phases:
(stable) Liquid, bcc-,42, bcc-B2, fcc-Al, hcp-A3(CuZn-c),
hcp-Zn
Solution Phases:
(stable) CuZn-7
(metastable) Laves-C14, Laves-C15, Laves-C36
Modelling:
Phase fccAl
L
c'SnA = - 42803.75 + 10.02258
Phase hcp,43
Phase liquid
L
c'u,zund = 40695.54 + 12.65269
cu,znd = 4402.72 6.55425
i
cSS d = 7818 1
3.25416
Phase b c c 2
Gcu:Zn:0 = 3085.0
cu.zn = 12898.97 + 3.26598
cu!zn = 945.265 0.80679
L
cu!zn = 1921.485 1.86969
C(T) - Hccc-A 1 (298.15 K) = G (Cu:Cu:D) = GBCCcu
C(T) - 0.5 Hcz-A 1
(298.15 K) 0.5 //^ hcp Zn (298.15 K) = G (Cu:Zn:0) =
Gcu:Zn + Cu.Zn + 0.5 G B C C C u + 0.5 GBCCzn
188 Thermochemical Database for Light Metal A lloys
rl,bccB2 rl,bccB2 M . , r, r2
L q U
Cu,Zn:Cu:D ^
C ut
C u.ZmO ^C u.Zn + - ^
C u.Zn
r2,bccB2 r2,bccB2 n
^Cu.ZniCuiD ^
C ui
C u.ZmO ^C u.Zn
rl,bcc-B2 _ rl,bcc-B2 _ r , n r2
^Cu.ZmZniG ^Zn:Cu,Zn:D ^Cu.Zn ~ 4 ^Cu.Zn
r2,bcc-B2 _ r2,bcc-B2 r 2
^Cu.ZniZniD ^ZniCu.ZmD -^Cu.Zn
rO,bcc-B2 _ 9 4 n I2
^Cu,Zn:Cu,Zn:D A ^C u.Zn
Phase bccB2
Gcu:Z:o = 3085.0
Cu.Zn = 12898.97 + 3.26598
Cu!zn = 945.265 0.80679
L
c,Zn = 1921.485 1.86969
Phase bcc,42
rO,bccA2 _ 44 n rO
^Cu.ZniO ^C u.Zn
,l,bccA2 _ j n ri
^Cu.ZniD U ^C u.Zn
= 16
^Cu,Zn:0 C u.Zn
System Cu-Zn 189
Phase C uZn7
K4 = 11552.71 1.67824
5 = 15732.3 10.26575
6 = 37289.2 13.05259
C(T) - 7.0 Hc'ucc-M(298.15 ) 6.0 //^ hcp_Zn (298.15 ) = G(Cu:Cu:Cu:Zn) =
13.0 4 + 2.0 5 + 7.0 GHSERcu + 6.0 GHSERZn
C(T) - 5.0 //c'ufcc/ll(298.15 ) 8.0 ^ h c p Z n (298.15 ) = G(Zn:Cu:Cu:Zn) =
13.0 K4 + 2.0 K5 + 2.0 6 + 5.0 GHSERC + 8.0 GHSERZn
C(T) - 5.0 Hccc~A l(298.15 ) 8.0 //^ hcp_Zn (298.15 ) = G(Cu:Zn:Cu:Zn) =
13.0 4 + 5.0 GHSERcu + 8.0 GHSERZn
C(T) - 3.0 H^"M (298.15 K) 10.0 tfZnhcpZn(298.15 K) = G(Zn:Zn:Cu:Zn) =
13.0 K4 + 2.0 K6 + 3.0 GHSERcu + 10.0 GHSERZn
Phase LavesC l4
Phase LavesCl5
Phase LavesC36
1600 J I I I I I I I L
+ hcpZn
Cu Xzn -* Zn
Table I Invariant Reactions.
(Zn) Mg hP2 M 2
P6s/mmc
W cI2 M 2 bcc-,42
ImZm
c Mg hP2 M 2
Pftjmmc CuZn-,43
7 Cu 5 Zn 8 c!52 Cu[ 8 Cu 5 Zn
I43m Cu 2 12
Zni 8
Zn2 24
192 Thermochemical Database for Light Metal Alloys
System CuZr
Solution Phases:
Liquid, bcc-,42, hcp-,43
Compounds:
Cu 5 Zr, Cu 5 iZrM, Cui 0 Zr 7 , CuZr, CuZr 2 , Cu 8 Zr 3
Modelling:
Assessor and D a t e :
K. Zong, and M. Hmlinen 1993
Cu >Zr Zr
System Cu Zr 193
T h e r m o d y n a m i c p r o p e r t i e s of t h e solution a n d c o m p o u n d p h a s e s ( J . m o l ')
P h a s e bcc-,42
2
4u,ZrTo = -7381.13
Phase fcc-
/ruXo = 2233
P h a s e hepA3
rct& = 11336.85
P h a s e liquid
L c ^ = -61685.53 + 11.29235
(Zr) Mg hP2 M 2
P6i/mmc
(Zr) W cl2 M 4
ImZm
Cu 8 Zr 3 CiieHfj oP44
Pnma
System Fe- Mg 195
System Fe-Mg
Solution Phases:
Liquid, fee-Al, bcc-,42, hcp-,43
Modelling:
Phase bcc-,42
,0,bcc-/t2
''FfMi-.D 65700.0
Phase fcc-,41
rO.frc-
'Ke, Mg: O = 65200.0
Phase hcp-,43
O.hrp-AI
/. Ke,Mg:0 92400.0
Phase liquid
r 0,liquid
''Kt.Mg 61343.0 + 1.5
r 1 .liquid
''Kr-.Mg 2700.0
196 Thermochemical Database for Light Metal A lloys
2500 J I I L J L
2300
Liquid' + Liquid"
2100
1900
bcc,4 2
1700
4"
1500
ca fcc^1
L.
d) 1300
a.
E 1100 LlquW"_^
900
700 ^ . b c c ^ 2 hcpj4 3 _ ^
500 I 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.8 0.7 0.8 0.9 1.0
Fe ^Mfl Mg
Table I Invariant R e a c t i o n s .
(Fe) W cI2
ImZm
(Mg) Mg hP2
P6/mmc
System Fe-Mn 197
System Fe-Mn
Solution Phases:
(stable) Liquid, bcc-,42, cbcc-,412, cub-,413, fcc-,41
Solution Phases:
(metastable) hcp-,43
Modelling:
Assessor and D a t e :
Scientific Group Thermodata Europe Database
Fe ^Mr\ Mn
198 Thermochemical Database for Light Metal A lloys
Phase bcc,42
TiU.bcc A2 1 OQ
i
r.Fr,Mu:0
^O.mag.brc A2 r.
u
r'Ke.MntO
Phase cbccA12
^MnTo4'2 = 10184
Phase cub,413
Tci = "2282
rlSni = -2068
r}0,mag,fcc^l _ n
/'Ke,Mn:Q ~
Phase liquid
/"'Fe,MUd = 3950
+ 48 9 T
1,liquid r
''Fr.Mn = 1145
Phase hep A3
A
/ 'Ke.Mn 1
= 5582 + 3.865
rl.hrp,4.1 n
''Ke.Mn ' 0
System Fe-Mn 199
(Fe) W eil
ImZm
7Mn Cu cF4
FmZm
Mn W ell
ImZm
200 Thermochemical Database for Light Metal A lloys
System FeSi
Solution Phases:
Liquid, bcc,42, bccB2, fcc-A l
Compounds:
Fe5S3, FeSi, Fe 2 Si, FeS2L, FeS2H
Modelling:
Assessor and D a t e :
J. Lacaze, and B. Sundman
Publication:
Met. Trans., 22A, (10), 22112223 (1991).
P h a s e Fe 2 Si
cc A 2 fMn
C(T) - 2.0 H^ - ' (298A 5 K) Hf'"uno'">(298.15 K) =
71256.6 10.62 + 2.0 GHSERpe + GIISER s i
System Fe-Si 201
P h a s e Fe 5 Si 3
P h a s e FeSi 2 L
P h a s e FeSi 2 H
C(T) - 3.0 // F ; bcc_/12 ' parB (298.15 K) 7.0 //s dismond (298.15 K) =
P h a s e FeSi
jUlquid _ 9 6 9 5 8
Phase fccAl
4^ s c .7 n A1 = 125247.7 + 41.166
f< c A1
L'' .
^Fe,Si:G
= 142707.6
Li'%-^
^Fe,Si:D = 89907.3
Phase bcc2
r2,bccB2 r2,bccB2
^Fe.ShSiiQ ^SiFe.SirG 3yu
Felino = 93360
rriO,bccB2 rpO,bcc-B2 1 0 Q
i y
IcFe.SitFetD c,Fe:Fe,S:0
Ti l , b c c B 2 Til,bccB2 co
D J
c,Fe,Si:Fe:a " c,Fe:Fe,Si:0
Ti 0 , b c c B 2 ^iO,bccB2 , 0 Q
_ _ l a
c,Fe,Si:Si:D c,Si:Fe,Si:D
Ti l , b c c B 2 Til,bccB2 fiq
l
c,Fe,Si:Si:D c,Si:Fe,Si:0
G(T) 0.5 H F ^ cc_ ' 42,para (298.15 K) 0.5 #|' diam nd (298.15 K) = G(Si:Fe:D) == 2 0 GYC,S\:0
Phase bcc,42
iO.bcc,42 . rO
n
qK)
^Fe,Si:D ^Fe.SI
r l.bcc A2 Q rl
^Fe.ShO ^Fe.SI
ml,bec Al co
t C,Fe,SI:Q 0
j 2,bcc-A2 _ fi n J 2
^Fe.Si:" i D u ^Fe.SI
System Fe-Si 203
Fe Si
(Fe) W el2
ImZm
FeSi cPS Fe 4
PliZ Si 4
Fe 5 Si 3 hPl6 Fe, 4
P63/ mmc Fe2 6
Si 6
System FeTi
Solution Phases:
Liquid, bcc,42, fcc,41, hcp,43
Compounds:
FeTi, LavesC14
Modelling:
Assessor and D a t e :
M.H. Rand 1995
Phase FeTi
cc A 2pnr
C(T) - ir - *(298.]5 K) //; hcp /13 (298.15 K) =
51584.05 + 238.686 44.858 InT 0.008493 2 + 100500 " 1
Phase L a v e s C l 4
bcc 3para
C(T) - 3.0 // F e " (298.15 K) = G(Fe:Fe) = 15000.0 + 3.0 GIISFR F e
C(T) - 2.0 tfFe ' ' (298.15 K) H^cp~A 3(298.15
bcc ,3 para
K) = G(Fe:Ti) =
1440.0 6.75 + 2.0 GHSER Fc + GHSER Ti
C(T) - // K c b c c ' U p a r a (298.15 K) 2.0 //: h c p 4 3 (298.15 K) = G(Ti:Fe) =
15000.0 + GIISER Fc + 2.0 GHSER Ti
C(T) - 3.0 H^cp~A 3(298.15 ) = G(Ti:Ti) =
15000 + 3.0 GHSERT
rO,I^veC14 0,LaveCH
= /,T:Fe,Ti 60000
r O.I.avenCH 0,LavesCM
'le.'l'irFe /. Fe,T:T = 60000
206 Thermochemical Database for Light Metal A lloys
Phase liquid
4$Vid = 5491.468
Phase fcc-Al
Feho' = 42000
Phase hep A3
Lp^P 43 = 18500 15
Phase becA2
L^j-aA2 = - 52400.65 + 10.7268
J I I I I I I L
hcp-A 3 *
400 1 1 1 1 1 1 1 1
0.1 0.2 0.3 0.4 0.6 0.6 0.7 0.8 0.8 1.0
Fe Ti
System Fe-Ti 207
FeTi = bcc-B1
(Fe) W cI2
ImZm
(Ti) Mg hP2
P&i/mmc
(Ti) W cI2
ImZm
System Hf-Ti
Solution P h a s e s :
(stable) Liquid, bcc-,42, hcp-,43
(metastable) fcc-
Modelling:
Assessor and D a t e :
H. Bitterman, Univ. Wien, Austria, 1997
P h a s e liquid
L ^ " = -4993.5-7.10316
Phase fcc-Al
L^J-.o = l-OE -4
Phase hcp-,43
L
W7T77D3 = 13644 - 10.6383
P h a s e bcc-,42
L
wxo2 = 3003.24 -7.4114
System Uf-Ti 209
hep-A 3
800-
600 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.8 1.0
Hf XT, - Ti
(Hf) W cI2
ImZm
(Ti) Mg hP2
P&i/mmc
(Ti) W el2
ImZm
210 Thermochemical Database for Light Metal A lloys
System LiMg
Solution Phases:
(stable) Liquid, bcc,42, hcp,43
(metastable) fcc,41
Compounds:
(metastable) Ali 2 Mg,7, AlLi
Modelling:
Phase bcc,42
O.bcc,42
,i,Mg:0 18335 + 8.49
1,bcc,42
i,Mg:G 3481
2,bcc-A2
A.Mf.O 2658 0.114
.System Li Mg 211
Phase feeAl
/UM:G = 6856.0
Phase hcp,43
" = -6856.0
'S-3 = 4000.0
'K1 = 4000.0
Phase liquid
]/193 5 10 371 T
' = - +
Phase AlLi
1000- J I I I I I L
900-
Li ^Mg Mg
Table I - Invariant Reactions.
(Mg) Mg hP2
Pfa/mmc
System Li-Zr 213
System Li-Zr
Solution Phases:
(stable) Liquid, bcc-,42, hcp-,43
(metastable) fcc-,41
Modelling:
Assessor and D a t e :
N. Saunders, 1991
Phase bcc-,42
r0,bee-A7
'I.i,Zr:D = 100000
Phase fcc-,41
r0.frc-.41
''U.Zr.a = 100000
Phase hcp-,43
rO.hcp-,43
'., 100000
Phase liquid
r 0.liquid
''U.Zr = 100000
214 Thermochemical Database for Light Metal Alloys
2000-
5
+>
CD
i_
bcc-yl 2
Q_ 1500-
E
1000-
Liquid' hcp-yi 3 "
600
1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
Li Zr Zr
T a b l e I Invariant R e a c t i o n s .
(Zr) Mg hP2
PGa/mmc
(Zr) W cI2
ImZm
System Mg-Mn 215
System M g M n
Solution Phases:
Liquid, bcc,42, hcp,43, cbcc,412, cubA13, fcc,41
Modelling:
Assessor and D a t e :
J. Tibballs 1991
J I I I I I I A
1900-
Liquid' + Liquid"
1700-
^ 1600- DCC-.A 2
5 1300-
co cub-A 13
_
Q, 1100-
E
_ 900-
hcp,4 3 cbccyt 12
700-
BOO I 1 1 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.8 0.7 0.8 0.9 1.0
Mg ^Mn Mn
210 Thermochemical Database for Light. Metal A lloys
Phase bccA2
C M ^ = 70000.0
Phase cbccA12
fiXi2 = 70000.0
Phase cub,413
Clfv = 70000.0
Phase fcc,41
SES?' = 70000.0
Phase hep A3
= 32985.0 + 2.5
Phase liquid
Table I Invariant R e a c t i o n s .
c58 cbcc,412
/43m
7Mn Cu cF4
FmZm
Mn W c/2
/m3m
218 Thermochemical Database for Light Metal A lloys
System M g N i
Solution Phases:
Liquid, fcc,41
Compounds:
Mg 2 Ni, LavesC36
Modelling:
Comments:
M. Jacobs assumed the LavesC36 phase to be
stoichiometric. The thermodynamic description of
that phase was modified and is now consistent with
the one in the database.
Assessor and D a t e :
M. Jacobs September 1991 (LavesC36 modified by
I. Ansara December 1997).
P h a s e bcc,42
0,bcc/t
/. M g , N i : 0 2 = 80
P h a s e fcc,41
P h a s e hcp,43
rO.hcp A3
L
Mg,Ni:C = 80
System Mg-Ni 219
Phase liquid
,liquid
'"Mg,Ni - 42304.49 + 7.45704
r I .liquid
''Mg.NI - 15611.66 + 9.11885
Phase Laves-C36
rO.hcp A3(
G(T) - 3.0 //M,grp-/1J(298.15 K) = C(Mg:Mg) =
15000.0 + GHSF,RMg
C(T) - Il^gcp-A3(298.15 K) - 2.0 [{^"-" (298.15 ) =
-74136.0 + 293.9216 - 54.35385 - - 0.03329235 2
+ 5.14203F, 06 3 - 99.0 '1
hcp 43
C(T) - 2.0 /^ "' (298.15 ) - / * * - * ' - (298.15 ) =
104136.0 - 293.9216 + 54.35385 + 0.03329235 2
- 5.14203R-06 3 + 99.0 " 1
(7() - 3.0 Hcc-A liPm (298.15 ) = G(Ni:Ni) =
15000.0 + CHSERNI
r ,LavesC3f f O,LaveC36
'Mg,Ni:Mg = LMg,Ni:N = 50000
r 0,I,vrsC36 0,L*veC36A
'Mg:Mg,Ni = iNi:Mg,Ni = 50000
Phase Mg 2 Ni
J I I I I I I L
1750
1600
fcc,41
750
hcpA3
500 1 1 r^ 1 1 1 ~1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Mg Ni
(Ni) Cu cF4 M 4
FmZm
System MgSi
Solution Phases:
(stable) Liquid, hcp,43
(metastable) fee A l
Compound:
(stable) Mg2Si
(metastable) LavesC15
Modelling:
Publication:
IL Heufel, T. Gdecke, H.L. Lukas, and F. Sommer,
J. Alloys and Comp., 247, (12), 3142 (1997).
Phase liquid
r 0,liquid
' J MgSi 83864.26 + 32.44438
r 1 .liquid
'-Mg.Si 18027.41 19.61202
r 2,liquid
''Mg.Si 2486.67 0.31084
r 3,liquid
'Mg.Si 18541.17 2.317664
r 4,liquid
'"Mg.Si 12338.84 + 1.54236
Phase hcp,43
r 0,hcp-^3
L
Mg,Si:D 7148.79 + 0.89361
999 Thermochemical Database for Light Metal A lloys
Phase feeAl
rO,fcc/U
'Mg,Si:D 7148.79 + 0.89361
Phase Mg2Si
ro,hcp,43, ooe K I M _
C(T) 2.0 - (2985 ) //r^o.diamond
s
(298.15 K)
Phase LavesC 15
'T 5 = 80000
J I I I I I I L
1900
1700
hcp,4 3
700
500 1 r^ 1 1 1 1 1 1
0.0 0.1 0.2 0.3 0.4 0.5 . 0.7 0.8 0.9 1.0
Mg -* Si
System Mg-Si 223
System M g - Y
Solution Phases:
Liquid, bcc-,42, hep-A3
Compounds:
MgY, Mg 24 Y 5 , Mg 2 Y
Modelling:
A s s e s s o r and D a t e :
H.L. Lukas, 1991
Phase bcc-,42
rO,bcc-,42
/y
Mg,Y:a - 38570.0 + 15.0
rl,bcc-,42
L
Mg,Y:0 - 8204.21
P h a s e hep A3
rO,bcp-A3
- 16582.94 + 4.77482
r 1,hep-.43
^,:0 - 7077.87
Phase liquid
r O.liquid
"Mg,Y - 25802.51 + 4.30042
1 .liquid
''Mg, Y 19229.76 + 3.20497
System Mg-Y 225
Phase fcc-Al
fJ^A' = 0.0001
Phase Mg 24 Y 5
Phase Mg 2 Y
1750-
Mg -
226 Thermochemical Database for Light Metal Alloys
(Y) W ell M 4
ImZm
(Y) Mg hPI M 2
Pf>a/mmc
System Mg-Zn
Solution Phases:
(stable) : Liquid, hcp-Zn, Laves-C14
(metastable) : bcc-,42, bcc-B2, fcc-,41, hcp-,43
Compounds:
(stable) Mg 2 Zn n , MgZn, Mg 2 Zn 3 , Mg 5 iZn 20
(metastable) : AlMg-/?, AlMg-e, AlMg-7, AlMgZn-
(metastable) : Laves-C15, Laves-C36
Modelling:
Assessor and D a t e :
R. Agarwal, S.G. Fries, H.L. Lukas, G. Petzow,
F. Sommer, T.G. Chart, G. E ffenberg
Publication:
. fr Metallkde., 83, 4, 216-223 (1992).
Comments:
A rvaluation was performed in order to take into
account the non-stoichiometry of the Laves-(714 phase.
Mg "Zn Zn
Phase fcc-,41
O.fcc-,41 _
/. Mg,Zn:0 3056.82 + 5.63801
l.Ire-Al
-Mg,Zn:G 3127.26 + 5.65563
System Mg-Zn 229
Phase h c p Z n
Phase hcp,43
Phase liquid
'2MgqznH = 1588.15
P h a s e AlMg/?
Phase AlMge
P h a s e AlMg
Phase Mg 5 iZn 20
Phase MgZn
Phase Mg 2 Zn 3
Phase Mg 2 Zn,i
Phase AlMgZni
Phase LavesC l4
,ZnU = C ^ C 1 4
= 8000.0
System Mg-Zn 231
Phase Laves-C15
Phase Laves-C36
Phase b c c 2
GMg:Zn:0 = 0.0
0Mg,z = 2500.0
rO,bccB2 rO,bccB2 , , rO
^Mg,Zn:Zn:a ^:,: ''MgrZntG + ^Mg.Zn
232 Thermochemical Database for Light Metal A lloys
Phase bccB2
C Mg :Zn:a = 0.0
Mg,Z = 2500.0
P h a s e bccA T,
rO,bcc.42 _ . n ,0
^Mg.ZniO 4 U ^Mg.Zn
(Zn) Mg hP2 M 2
Ps/mmc
MgZn
Mg 2 Zn 3 mCllO
B2/m
Mg 7 Zn 3 Ta 3 B 4 0II42 designated as
Immm Mg5,Zn 20
234 Thermochemical Database for Light Metal A lloys
System MgZr
Solution Phases:
(stable) Liquid, bcc,42, hcp,43
(metastable) icc,41
Modelling:
Assessor a n d D a t e :
M. Hmlinen 1991
P h a s e bcc,42
0,bcc,42
I Mg.ZrrO 5720.44 + 50.11642
P h a s e fcc,41
OSee-Al
/. Mg,7,r:0 42063.55 + 1.01789
r 1,fee,41
'Mg.Z.rO - 2885.9
P h a s e hcp,43
r 0, hep A3
''Mg,Zr:D 42063.55 + 1.01789
r I,hep-A3
'JMt].7.r:0 2885.9
Phase liquid
0,liquid
I.Mg.Zr = 14003.84 + 29.34205
System Mg-Zr 235
1 1 1 1 1 1 1
2100-
1900-
1700- Liquid' bec-A 2 _ ^
CD 1500-
-
1300-
cx
E 1100-
03 hepA 3 ^
h 900-
Mg x Zr > Zr
Table I Invariant Reactions.
(Zr) Mg hP2
Ps/mmc
(Zr) W cI2
ImZm
236 Thermochemical Database for Light Metal A lloys
System MnSi
Solution Phases:
Liquid, bcc,42, cbcc,412, cub.413, fcc,41
Compounds:
(stable) Mn 6 Si, Mn 9 Si 2 , Mn 3 Si, Mn 5 S 3 MnSi, Mni,Sii9
(metastable) Al 8 Mn 5 >8,o
Modellin SI
P h a s e Mn 3 Si
rjo.diamonH/
C(T) - 3.0 tfM'fcc/,,2'par,,(298.15 K) *:s, (298.15 K) =
298.15 <T< 950.00 : 124189.87 + 782.4373 1 3 1 . 6 8 2
0.00777 2 + 1657200 " 1
950.00 < < 2000.00 : 119740.6 + 777.7538 131.682 - InT
0.00777 2 + 1657200 " 1
System M n-Si 237
Phase MnSi
Phase M n n S i 1 9
Phase Mn 6 Si
C(T) - 17.0 //' M , f cc ' 4,2 ' para (298.15 K) 3.0 /Y;diamond(298.15 K) =
298.15 < T < 1519.00 : 250180.6 + 84".8444 T 1 2 . 0 7 7 5 5 T I n T
0.02850984 T 2 + 7514 T" 1
+ 17.0 GHSERMn + 3.0 GHSERsi
1519.00 < T < 3000.00 : 282008.6 32.58304 T + 12.06754 T InT
0.05879165 T 2 + 3.928228E+31 T~9
+ 17.0 GHSER Mn + 3.0 GHSER.si
Phase Mn 9 Si 2
C(T) - 33.0 // M ' n bcc_/,,2 ' para (298.15 K) 7.0 //|; diamond (298.15 K) =
298.15 < T < 1519.00 : 578208.4 + 381.294 T 56.86988 T InT
0.0500355 T 2 + 1458600 T'1
+ 33.0 GHSER Mn + 7.0 GHSER si
298.15 < T < 1519.00 : 639992.0 + 153.3464 T - 10.0 T I n T
0.1 T 2 + 7.625384E+31 ~ 9
+ 33.0 GHSERwn + 7.0 GIISER S
Phase Mn 5 Si 3
Phase 1 8 5 ->8,
Phase bcc-,42
rO,bcc-.4 2
'Mn,Si:0
Mn^D2 = -7500.0
238 Thermochemical Database for Light Metal Alloys
Phase cbccA12
0,rhcc-/U2
Mn.ShO
= - 142743.62 + 22.3961
I.ebee-Al2
Mn.ShQ 16440.608 - 3.5300332
Phase fcc-,41
0,frc-/tl
Mn,Si:D - 95600 + 2.94097
Ucc-,41
Mn,Si:D -7500
Phase liquid
0.liquid
'Mn.Si - 139817 + 29.86137
r 1 .liquid
''Mn.Si - 34917.2 + 3.20488
r 2,liquid
''Mn.Si 46782.4 - 1.8.1897
3, liquid
''Mn.Si 16168.2
1700
Si
System Mn-Si 239
7Mn Cu cF4
Fm3m
<JMn W cI2
ImZm
Mn 5 Si 2 MnjSi 2 IP56
P4\2i2
240 Thermochemical Database for Light Metal A lloys
System M n T i
Solution Phases:
Liquid, bcc,42, fcc,41, hcp,43, cbcc,412, cub,413
Compounds:
Mn^Ti, Mn 3 Ti, MnTi, MnTi/? ,I,avesC14
Modellin
Assessor and P a t e :
N. Saunders, 1993
Phase bcc,42
1,~:0 = - 23200 + 20
'Mn.TirO 1000
Phase cbcc,412
,0,e\,ee-Al2
''Mn.TirD 29500 + 20
r l.ebee-A\2
''Mn,Ti: 3635 5
Phase cub,413
'Mn,Ti:0 34000 + 20
242 Thermochemical Database for Light Metal A lloys
Phase fcc,41
I$S& = - 26200 + 20
Phase hep A3
/o" = 22100
Phase liquid
Llfff = 1400
Phase Mn 4 Ti
G(T)- 0.815 /7'M,nbcc"A12,para(298.15
K) 0.185 /^| hcp ' 43 (298.15 K) =
2445.02.9 + 0.815 GHSERMn + 0.185 GHSERji
Phase Mn 3 Ti
C(T) - 3.0 ^ b c c / , 1 2 ' p a r a (298.15 K) H^cp~A3 (298.15 ) =
18552.0 9.12 + 3.0 GHSERM + GHSERT
Phase MnTi
C(T) - //Mnbcc"'412'para(298.15 K) r7.r;hcp/,3(298.15 K) =
11478.0 + GHSERMn + GHSERTi
Phase MnTi/?
G(T) - 0.515 /^ n b c c 4 l 2 p a r a (298.15 K) 0.485 //^hcp_'43(298.15 K) =
5540.0 2.29 + 0.515 GHSERMn + 0.485 GHSERT,
Phase LavesC 14
C(T) - 3.0 //M^bcc/"2'para(298.15 K) = G(Mn:Mn) = 3000.0 + 3.0 GHSERM
C7(T) 2.0 //^nbcc/,,2'para(298.15 K) H^cp~A 3 (298.15 K) = G(Mn:Ti) =
26400.0 + 2.0 GHSERMn + GHSERTi
C(T) - //^ ' (298.15 K) 2.0 tfhcp/,3(298.15 K) = G(Ti:Mn) =
bcc /112 para
O.LaveeC14 r O.LaveaC 1 4 07
Mn.TirMn ~ ^Mn,Ti:Ti ~ /UUU
System Mn-T 243
1900-
1700-
Mn Ti
(Ti) Mg h PI M 2
Pz/mme
(Ti) W cli M 2
ImZm
MnTi .58
MnT/3
Mn 3 Ti
Mn 4 Ti ~(Mo,N) 53
3
System Mn-Zr 245
System M n Z r
Solution Phases:
Liquid, bcc,42, cbcc,412, cub,413, fcc,41, hcp,43
Compound:
Mn 2 Zr
Modelling:
Phase Mn 2 Zr
o.cbcc 412,para
C(T) - 3.0 (298.15 K) = G(Mn:Mn) =
298.15 < < 1519.00 : 021345.84+390.177 70.3746 InT
0.02204304 2 + 209481.3 " 1
1519.00 < T < 2000.00 : 83200.23 + 936.7944 144
+ 4.970541+30 ~ 9
cc/,12,para
C(T) - 2.0 #M
' (298.15 ) H%rhcp-A 3 (298.15 ) = G(Mn:Zr) =
298.15 < < 1900.00 79282.375 + 386.94271 71.0782
0.01907327 2 + 174625.2 T" 1
1900.00 << 2000.00 119446.65 + 750.75589 120.1618
0.00437791 2 + 34971 '1
+ 3.313694+30 " 9
246 Thermochemical Database for Light Metal A lloys
C S , = 1066.4675 + 10.504933
l&' = -4084
Phase cbccA12
'ut" = 20000
Phase cub,413
'Aio-'3 = 24000
Phase fccAI
1
^ = 20000
Phase hcp A3
3
'a = 25000
Phase liquid
d
''Mn?zr = - 35187.553 + 2.6983563
MnqzrH = - 1305.986
System Mn-Zr 247
Mn
7-Mn Cu cF4
Fm3m
<5-Mn W cI2
ImZm
(Zr) Mg hP2 M 2
P6s/mmc
(Zr) W cI2 M 4
ImZm
System Mo-Ti
Solution Phases:
(stable) Liquid, bcc-,42, hcp-,43
(metastable) bcc-S2, fcc-,41
Compounds:
(metastable) AIM-DO19, A1M-D0 22 , AlTi-Llo
Modelling:
Phase liquid
r 0,liquid
''Mo.Ti 9000 + 2
Phase fcc-,41
r o,rrc-/ti
'Mo.Ti:G = 16500
250 Thermochemical Database for Light Metal A lloys
Phase hcp,43
3 = 22760 - 6
Phase bcc-,42
LMIJZ2 = 2000
L^TZO2 = 2000
Phase bcc? 2
Phase b c c 2
G'Mo:T,a = 5000
G(T) 0.5 H^cc-A2 (298.15 K) 0.5 H^cp~A3 (298.15 ) == G(Ti:Mo:D) == 2.0 GMo:Ti:D
Phase bcc,42
f e a ' = 2000
Mbo^o2 = 2000
System Mo-Ti 251
Phase A1MD0, 9
Phase A l T i i , l 0
(Ti) Mg hP2
P&i/mmc
(Ti) W cI2
ImZm
252 Thermochemical Database for Light Metal Alloys
3000-
2600-
2000-
4->
CD
l_ bcc-yl 2
CD
Q. 1500-
E
r-
1000 -I
600-1
Mo ^Tl Ti
System N-Ti 253
System N T i
Solution Phases:
Liquid, hcp,43, bcc,42, fcc,41 ( ^ , ^
Compound:
Ti 2 N, Ti 3 N 2 , Ti 4 N 3
Modelling:
Assessor and D a t e :
K. Zeng and R. SchmidFetzer, Univ. Clausthal,
Germany, 1997
Comments:
The value of G H S E R T N S taken from S. Jonsson,
Thesis, Royal Institute of Technology, Stockholm,
Sweden (1993)
Phase fcc,41
cp A 3
C(T) /70;f(298.15 K) H^ - (298.15 K) = GHSER TiN =
357905.0 + 330.498 52.4587 InT 9.28E04 2
2 . 4 1 E + 0 9 " 3 + 871000.0 " 1
1
.^ = 42704.41
r 1.ferAl
^ThCO 13989.34
Phase T i 4 N 3
C(T) - 0.315 ff0f(298.15 K) 0.685 II^cp-A 3 (298.15 K) =
5956.8633 3.2749 + 0.37 GHSER Ti + 0.315 GIISER T N
254 Thermochemical Database for Light Metal Alloys
4000- J I I I I I I L
3500- Liquid
Phase hcp-,43
Phase Ti 2 N
Phase Ti 3 N 2
P h a s e liquid
r 0,liquid
''N,Ti 376354.145
r 1,liquid
'N ; 98242.2945
Table I Invariant R e a c t i o n s .
fcc,41 = Ti r N,
(Ti) Mg h PI M 2
Pf3/mmc
(Ti) W ell M 2
ImZm
Ti 2 N anti0 2 Ti <P6 N 2
(rutile) P4'i/mnm Ti 4
T.4N3 Ti 7 S, 2 h RS N, 3
RZm N2 3
N3 6
Ti, 6
Ti 2 6
T13N0 not indicated in
[91 Vil] nor in [90Mas]
256 Thermochemical Database for Light Metal A lloys
System N b T i
Solution Phases:
(stable) Liquid, bcc,42, hcp,43
(metastable) bccB2, fcc,41
Compounds:
AIMDO,.,, A1MD0 22 , AlTil 0 ,Cr 3 Si/115
(metastable)
Modelling:
Substitutional, RedlichKister
Liquid Substitutional, RedlichKister
bcc,42 Sublattice model, (Nb,Ti)o.5(Nb,Ti)o. 5 (n) 3
bccS2 The thermodynamic description of the bccB2 takes
into account the ordering reaction bcc,42 ^ bcc? 2.
Two descriptions are given: one using equations
23 and 27, the other using equations 23 and 28.
For the latter, the parameters are given in a frame.
fcc,41 Substitutional, RedlichKister
hcp,43 Substitutional, RedlichKister
A1MD0 19 Sublattice model, (Nb,Ti)(Nb,Ti) 3
AM-DO22 Sublattice model, (Ti) 3 (Nb,Ti)
AlTiLlo Sublattice model, (Nb,Ti)(Nb,Ti)
Cr 3 Si,415 Sublattice model, (Nb,Ti) 3 (Nb)
Assessor a n d D a t e :
N. Saunders, 1995
P h a s e liquid
d
L^;
J
Nb,Ti = 8500
System Nb-Ti 257
Phase fcc,41
Nb,TT:o = 13600
LUC = 1E04
:' = 2500
Phase hcp,43
Nb^o 3 = 13600
r f = 1E04
r2.hcp.43 _ ocflfl
^Nb.TiiD Z0UU
Phase C r 3 SiAl5
C(T) 4.0 //Nbcc"'42(298.15 K) = G(Nb:Nb) =
20000 + 10 + 4.0 GFCCNb
G(T) - H^cc-A 2(298.15 K) 3.0 H^cp~A 3(298.15 K) = G(Ti:Nb)
20000 + 10 + 3.0 GFCCNb + GFCCT
Phase bcc,42
2
L\th%n 14000
N'b^ho2 = 10E4
^Nb.Tha 2500
Phase b c c 2
GNb:Ti:D = 5500
C(T) - H^cc-A 2(298.15 K) = G(Nb:NbO) = 0.0
C(T) - 0.5 /iN'bbcc42(298.15 K) 0.5 H^cp~A3 (298.15 ) =
G(Nb:Ti:D) = GNb:Ti:D
C(T) - 0.5 H^CC~A 2(298.15 K) 0.5 tfT;hcp_/13(298.15 ) =
G(Ti:Nb:) = G'Uh.,Ti:0
C(T) - H^cp-A 3(298.15 K) = G(Ti:Ti) = 0.0
rO,bccB2 rU,bccB2
^Nb.TiiNbiO ^Nb.TiiTiiG
rO,bccB2 _ rO,bccB2 _
^Nb:Nb,Ti:D ^Ti:Nb,Ti:D OOUU
258 Thermochemical Database for Light Metal A lloys
Phase b c c 2
G 550
Nb:Ti:a =
G(T) - 0.5 // N ' b cc/,2 (298.15 K) 0.5 // T ; hcp "' 43 (298.15 K) == G(Nb:Ti:D) = 2
0 G
Nb:Ti:0
Phase bcc,42
N b ^ D 2 = 14000
f e r f l.OE4
N'b, 2 = 2500
3000- J I I I I I I I L
Liquid
2600-
2000-
D
+->
03
bcc 2
) ~
Q. 1600-
E
r-
o
1000-
Nb Ti
System Nh-Ti 259
Phase A1MD0,9
C(T)-A.O H$A cc 2
- (298.15 K) = G(Nb:Nb) = 4.0 GHCP Nb
C(T) - 3.0 // N r c_ ' 42 (298.15 K) H^cp~A 3 (298.15 K) = G(Nb:Ti) =
10668 + 3.0 GHCPNb + GHSERTi
C(T) - lf^cc-A 2(298.15 K) 3.0 WT'ihcp43(298.15 K) = G(Ti:Nb) =
10668 + GHCPNb + 3.0 GHSERTi
C(T) - 4.0 //T'ihcp"/13(298.15 K) = G(Ti:Ti) = 4.0 + 4.0 GHSERT
''Nb,Ti:Ni. 30248
rl,AIM-DOie _
,0on
''Nb,Ti:Nb - - -
r2,AIM-DO _ r.,r.
J , D
''Nh,Ti:Nb '
,'^'0" = 302/|8
,1.A1M-D0,s _ , 9 9
''Nb,Ti:Ti ~~ ^ " u
r2,AlM-DOiB IIRA
J I D 1
'-Nb.Ti-Ti
rO.AiM-Dn19 _ ,
q4 yq 9
''Ni:Nb.ri -a
rl.AIM-00,9 ,(,Q
''NbiNb.Ti = 4b
r2.AIM-D0,9 _ , n
''Nb:Nb,TI 'U
r0.AlM-D0, 9 _ .gr,,
a
''Ti:NI,,Ti ^ - q
rl.AIM-D0, 9 _ ,rc,
'-Ti:NI..T ~ "
r2,AIM-DO,9 _ ,n
W
''Ti:Nb,TI
Phase A1MD022
G(T) - /C"" 42 (298.15 K) 3.0 //Thcp_/43(298.15 ) = G(Ti:Nb)
GFCCNb + 3.0 GFCCT
C(T) - 4.0 // Ti hcp ^ 3 (298.15 ) = G(Ti:Ti) = 4.0 GFCCT
Phase AlTi,l 0
C(T) - 2.0 H^cc-A 2 (298.15 K) = G(Nb:Nb) = 2.0 GFCCNb
C(T) - //.N^CC_ (298.15 K) //Thcp_'43(298.15 K) = G(Nb:Ti) =
13600 + GFCCNb + GFCCT
260 Thermochemical Database for Light Metal A lloys
(Ti) Mg hP2
Pfc/mmc
(Ti) W C2
ImZm
System N i-V 261
System N i V
Solution Phases:
Liquid, bcc,42, fcc,41,
Compounds:
Ni 2 V, N13V, Ni 2 V 7
Modellin
Publication:
J. Korb, and K. Hack, GTT, Germany (1997).
Phase bcc,42
r 0,b<c/12
''Ni,V:G : = 30513.8 + 12.6138
Phase fee.41
r0.lee-A\
''Ni,V:0 = 36365.6 + 3.75677
r l,tee-Al
''Ni,V:D = 11860.79.0302
r2.frc-^l
'Ni,V:D 10647.5 + 7.00954
Phase liquid
0.liquid
/.'N.V 51927 + 14.99
262 Thermochemical Database for Light Metal Alloys
Phase Ni 2 V
Phase Ni 3 V
Phase Ni 2 V 7
Phase
Ni 2 V MoPt 2 oIS
CrFe t 30 High and low forms
P4i/mnm given in [90Mas]
NiV 3 Cr3Si cP8 Cr 6 assumed to be Ni 2 V 7
PmZn Si 2 by the assessors
264 Thermochemical Database for Light Metal Alloys
System SiSn
Solution Phases:
Liquid, diamond
Modelling:
Assessor a n d D a t e :
J L J L
1800- Liquid
^ 1550-
2? 1300-
=3
*->
diamond
(0
105C
Q.
E
Q> 800-
r-
550-
bc\-A 5
300 1 1 1 1 1 1 1 1
0.0 0.1 02 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Si Xsn -* Sn
System Si Sn 265
Phase diamond
r 0,diamond
''Si.Sn = 25265.65 + 23.84
Phase liquid
r 0.liquid
'S.Sn 25364.6
r 1.liquid
'S.Sn 3148.8
2.liquid
'Si.Sn 4460.9
System SiTi
Solution Phases:
Liquid, bcc,42, hcp,43
Compounds:
Si 2 Ti, S'uTi 5 , SiTi, SiTi 3 , Si 3 Ti 5
Modelling:
P h a s e Si 2 Ti
P h a s e Si 4 Ti 5
P h a s e SiTi
Phase Si 3 Ti 5
s'hSi.TiT = 43024.293.44194
^Thsjn.Ti = 43024.293.44194
Phase SiTi 3
Phase bcc,42
Phase hepA3
/,^43 = 302731.04+69.08469
Phase liquid
/ 0,liquid
.Ut
''Si, 255852.17 + 21.87411
r 1 .liquid
''Si,Ti 25025.35 2.00203
r 2,liquid
''Si.Ti 83940.65 6.71526
3000
(Ti) Mg h PI
P&s/mmc
(Ti) W ell
ImZm
Ti 3 Si PT3 tPZI
P42/n
T5S3 Mn 5 Si 3 16 Si 6
P^/mcm Ti, 4
Ti 2 6
System SiV
Solution Phases:
Liquid, bcc,42
Compounds:
Si2V, Si3V5, Si5Ve, SiV3
Modelling:
Phase Si 2 V
Phase Si 3 V 5
Phase Si 5 V e
Phase SiV 3
r. = 9794.5 21.8
r^ = - 150000
n .SiV 3 _
''V:S,V
Phase bcc,42
L^y1M = - 164505 + 30.1
L^cA2 = 37000
Ll^cA2 = 20000
Phase liquid
^o.iiquid _ _ ]80gorj + 40
r^"'"1 = 37000
7, 2 i '7' iH = 20000
272 Thermochemical Database for Light Metal A lloys
1 1 1 1 I 1 1 1
-
2600- Liquid
-
\ ^^
<j> 2000-
atu
l_ >
O Vi
Q_ 1500- \
E :"- diamond > >" / bcc-A 2 - 4
>
1000-
/ -
1
600- 1 1 1 1 1 r
0.0 0.1 02 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Si
T a b l e I Invariant R e a c t i o n s .
(V) W eI2 M 2
ImZm
System SiY
Solution Phases:
Liquid, bcc,42, hcp,43
Compounds:
Si2YR, Si2YH, Si5Y3R, Si5Y3H, SiY,
Si3Y5, S4Y5
Modelling:
Phase Si 2 YH
Phase Si 2 YR
Phase Si 3 Y 5
Phase Si 4 Y 5
Phase SiY
Phase S i 5 Y 3 - H
Phase S i 5 Y 3 - R
Phase hcp,43
Ls-^PA3 = 80
Phase liquid
Uiquid _ 13977.0831.08941
2260 Liquid
i 2000
O 1750
CO 1500
>
Q 1260
*- diamond bcp-A 3 "
Q)
I 1000
750
SI S Y,R
600 1 r^ 1r 1 1 1
0.0 0.1 02 0.3 0.4 0.6 . 0.7 0.8 0.9 1.0
Si
T a b l e I Invariant Reactions.
(Y) Mg hP2 M 2
P6/mmc
(Y) W cI2 M 2
ImZm
S3Y5 Mn 5 Si 3 hP16 Si 6
P6i/mcm Y, 4
Y2 6
System SiZn
Solution Phases:
Modelling:
Assessor and D a t e :
M. Jacobs 1993
P h a s e diamond
- O,diamond
J
Si,Zn = 100
P h a s e hepZn
LO,hcp-Zn
Si.Zn 80
P h a s e liquid
LO,liquid
Si.Zn 7829.25
I Jiquid
L Si.Zn 3338.18
2,liquid
kSi.Zn 891.33
System Si-Zn 279
J I I I I I I L
1900-
1700. Liquid
700-
hcp-Zn "
600 I I I I I I I I I
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
S Xzr, > Zn
Table I Invariant Reactions.
(Zn) Mg hP2
P&i/mmc
280 Thermochemical Database for Light Metal A lloys
System SiZr
Solution Phases:
Liquid
Compounds:
Si 2 Zr, Si 2 Zr3, Si 3 Zrs, S4Zrs, SiZr, SiZr 2 , SiZr 3
Modelling:
Phase liquid
Phase Si2Zr
P h a s e SiZr
P h a s e Si 4 Zrs
P h a s e Si 2 Zr 3
Phase Si 3 Zr 5
P h a s e SiZr 2
P h a s e SiZr 3
3000- J L
2750^ Liquid
2600-
i
2260-
2000
*->
1760-^
CL 1500- bcc-^4 2
1250-jj - - diamond
\-
1000-
g E
750- hcp-A 3 r
500 I 1 ^ 1 1 I " 1 1
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Si x* - Zr
(Zr) Mg hP2 M 2
P63/mmc
(Zr) W cI2 M 4
ImZm
Si 2 Zr 3 Si 2 U 3 tPIO
P4/mbm
Si3Zr5 Mn 5 Si 3 hP16 Si 6
P(h/mcm Zr, 4
Zr2 6
S4Zr5-/3 Si 4 Zr 5
284 Thermochemical Database for Light Metal Alloys
System Sn-Ti
Solution Phases:
Liquid, bcc-,42, hcp-,43, bct-,45
Compounds:
Sn 5 Ti 6 , Sn 3 Ti 5 , SnTi 2 , SnTi 3
M o d e l l i n Si
Assessor a n d D a t e :
F. Hayes, 1992
Phase bcc-,42
rO,bee-A2
L,
Sn,T<:0 = - 115000.00 + 6.77583
rl,bec-,42
^Sn,Ti:0 = 45000.00 + 1.58018
Phase bct-,45
r0,bct-,45
^Sn.Ti = 50000.0
Phase hep A3
rO.hcp A3
^Sn.TiiO = - 111502.08 + 1.8068
j 1,hep-.43
^Sn.TliO = 43871.41 + 2.08175
System S n-Ti 285
Phase liquid
Phase SnTi 3
t & = 400000
Phase Sn 3 Ti 5
Phase Sn 5 Ti 6
1900
Sn , Ti
Table I Invariant R e a c t i o n s .
(Ti) Mg hP2 M 2
P6/mmc
(Ti) W c2 M 2
ImZm
Sn5T6-/J hP22 Sn 3
P&i/mmc Ti 6
Sn3T5 Mn 5 Si 3 hP16 Sn 6
Pb\/mcm Ti 4
System SnZn
Solution Phases:
(stable) Liquid, bct-,45, hcp-Zn
(metastable) bcc-,42
Modellin SI
Phase bct-,45
rO,bct-,45
^Sn.ZniO 6514.76 + 25.70957
P h a s e bcc-,42
r 0,bcc-,42 _
J
Sn,Zn:D 6514.76 + 25.70957
P h a s e hepZn
O.hcpZn
Sn,Zn:D 33433.94 - 11.14466
P h a s e liquid
O.liquid
Sn.Zn 19314.64 - 75.89939 + 8.751396 InT
r 1,liquid
^Sn.Zn - 5696.28 + 4.20198
L 2,liquid
Sn.Zn 1037.22 + 0.98362
System Sn-Zn 289
Sn Xzn -* Zn
(Zn) Mg hP2
P63/mmc
290 Thermochemical Database for Light Metal Alloys
System Sn Zr
Solution P h a s e s
Liquid, bcc-,42, bct-,45, hcp-,43
Compounds:
SnZr4, Sn 3 Zr5, Sn 2 Zr
Modellin S
Asessor a n d d a t e :
J. Korb, and K. Hack, GTT, Germany (1996).
Phase liquid
0,Sn.Zr
liquid
- 45520 - 95.46
1,Liquid
^Sn.Zr -80000 + 82.115
r 2,Liquid
^Sn.Zr - 120000 + 80.0273
Phase becA2
0,bcc-,42
Sn,Zr:G - 101200 - 71.13
1,bcc-,42
Sn.ZriO 55000
2,bcc-/12
Sn,Zr:D 26102.3
Sysfem Sn-Zr 291
Phase hcp-A3
rO,hep-A3
^Sn.ZriG = - 160000 --31 T
r l.hrp.43
^Sn.ZriO = 151800
r 2 ,hcp-.43
' v Sn,Zr:D = 129900
P h a s e SnZr 4
Phase Sn3Zr5
Phase Sn2Zr
2800
Sn ^Zr Zr
292 Thermochemical Database for Light Metal Alloys
Table I - Invariant R e a c t i o n s .
(Zr) Mg hP2 M 2
P&i/mmc
(Zr) W cl2 M 2
ImZm
Sn 3 Zr 5 Mn5S3 hP16
Pfk/mcm
System Ta-Ti
Solution Phases:
(stable) Liquid, bcc-,42, hcp-,43
(metastable) bcc-B2, fcc-Al
Compounds:
(metastable) A1M-D0,9, A1M-D022, AlTi-Lln
Modellin S
Phase f c c - A l
L%A1 = 8500
Phase hcp-,43
r 0,hcp-/t3
J
Ta,Ti:0 8500
294 Thermochemical Database for Light Metal A lloys
Phase liquid
Lj^d = 1000
L^qT";d = 7000
Phase A1MD0 l9
r0,AlMD0|9 rO,AlMDO,9 01 OQ
z i z
^TaiTa.T ^ThTa.Ti
Phase A1MD0 22
Phase AITiLl 0
f O,AITiLlo _ r O,AITiLlo _
4
^Ta.TiiTi ^TizTa.T 0U
Phase bcc-,42
LT^T7D2 = 12000
L^~A2 = - 2500
System Ta-Ti 295
Phase bccB2
2 5 0 0
C T i : T a:G =
QC A 2
C(T) - H^ - (298.15 K) = G(Ta:Ta:G) = 0.0
C(T) - 0.5 Hgcc-A 2(298.15 K) 0.5 //TJ,cp"/,3(298.15 K) = G(Ta:Ti:D) = GTa.Ta
C(T) - 0.5 r/ T r C_/,2 (298.15 K) 0.5 H^cp~A 3 (298.15 K) = G(Ta:Ti:) = GTi:Ta:D
C(T) r/T;hcp^(298.15 K) = G(Ti:Ti:G) = 0.0
rO,bccS2 rO.bcc82 .
^Ta.TirTaiG ^Ta,Ti:Ti:D ~ ''TiiTatG
rO,bccS2 _ rO,bccB2 _
s~i.
U
^TaiTa.TiiG ^TitTa.TiiG Ti:Ta:G
Phase bccS2
GTi:Ta:D = 2500
Phase bcc,42
Ta^TiTG42 = 12000
L^-rf2 = 2500
296 Thermochemical Database for Light Metal Alloys
3500 J I L J L
Ta Ti
(Ti) Mg hP2
P&s/mmc
(Ti) W cI2
ImZm
System Ti-V 297
System T i - V
Solution Phases:
Liquid, bcc-,42, hcp-,43
Modelling:
Assessor and D a t e :
N. Saunders (1990)
Phase bcc-,42
r0,bcc-,42
^, : = 10500 - 1.5
r l,bcc->t2
^Ti.ViD = 2000
r2,bcc-,42
^Ti.ViG = 1000
Phase hcp-,43
-O.hcp-,43
-^Ti.VlD 20000
Phase liquid
0,liquid
ru.i
^ TTi,V
i.V
1400
r 1,liquid
l .lien 4100
^Ti.V
298 Thermochemical Database for Light Metal A lloys
2500 J I I I I I I I L
2300
Liquid
2100
^ 1900
2 1700
=3
<J 1500
L. bccA 2
O
Q_ 1300
E
o noo
r
900
500
700
Ti
Table I Invariant Reactions.
(Ti) W cI2
ImZm
(V) W cI2
ImZm
System Ti-W 299
System T i W
Solution Phases:
(stable) Liquid, bcc,42, hcp,43
(metastable) : b c c 2 , fccAl
Compounds:
AIMDO.9, AlTiLlo
(metastable)
Modelling:
Substitutional, RedlichKister
Liquid see above
bccA2 Sublattice model, (Ti,W) 0 . 5 (Ti,W) 0 . 5 (a) 3
bccB2 The thermodynamic description of the bccB2 takes
into account the ordering reaction bccA2 # bcc? 2.
Two descriptions are given: one using equations
23 and 27, the other using equations 23 and 28.
For the latter, the parameters are given in a frame.
fccAl Substitutional, RedlichKister
hcpA3 Substitutional, RedlichKister
A1MD09 Sublattice model, (Ti,W)(Ti,W) 3
AlTiLlo Sublattice model, (Ti,W)(Ti,W)
Phase f c c A l
rO.fcc QQQOC:
Ti WG OOOZO
Phase h c p A 3
L O,hep 3 .77,
Ti,vv:G = 35774
300 Thermochemical Database for Light Metal A lloys
Phase liquid
".li^id = 28392
Llrf$id = 4282
Phase A1MD0,9
hcp_y,3
G(T) - 4.0 tfT; (298.15 K) = G(Ti:Ti) = 4.0 + 4.0 GHSERTi
C(T) - 3.0 //Thcp"3(298.15 K) H^hcc-A 2 (298.15 K) = G(Ti:W) =
26832 + 3.0 GHCPw + GHSERTi
C(T) - //T;hcp43(298.15 K) 3.0 tfwbcc_/l2(298.15 K) = G(W:Ti) =
26832 + GHCPw + 3.0 GHSERTi
C(T) - 4.0 //^bcc_>l2(298.15 K) = G(W:W) = 4.0 GHCPW
rr 0 , A !l M D 0 , 9 r O , A I M D r0 1 9 onAQO
v
,r; w.Ti
Ti,W:Ti W
^ T ;i . W
w iw
Wi oUiy
rO,AIMD0i9 _ rO,AlMD0ls _
^TiiTi.W ^W.Ti.W OHHt
Phase AlTiLl 0
hcp_ 43
G(T) - 4.0 //T; ' (298.15 K) = G(Ti:Ti) = 2.0 GFCCTi
Phase bccA2
2
L%w7o = 3957+13.033 T
L^;aA2 = 106404.464 T
Phase bccL? 2
GT:W:0 0
C(T) - H^cp-A 3(298.15 K) = G(Ti:Ti:D) = 0.0
C(T) - 0.5 H^cp~A 3 (298.15 K) 0.5 ^~2 (298.15 K) = G(Ti:W:G= GTi:W:D
C(T) - 0.5 /V T r p 43 (298.15 K) 0.5 tfwbcc_/,2(298.15 K) = G(W:Ti:D) = GTi:W:D
C(T) - //wbcc"'42(298.15 K) = G(W:W:0) = 0.0
rO,bccB2 rO,bccB2 .
^Ti.WiWiG ^Ti,W:Ti:0 ^TiiWiQ
rO,bccB2 rO,bccB2 /-,.
^W:Ti.W:G ^TirTi.WiG ""TiiWrQ
System Ti-W 301
Phase bccB2
GT:W:G = 0
G"(T) - 0.5 i/ w bcc_ ' 42 (298.15 K) 0.5 f/ T ' i hcp 43 (298.15 K) = G(W:Ti:D) = 2.0 G Ti:W:G
Phase bcc,42
L
Tlw7a2 = 3957+13.033
L
Tw7a2 = 106404.464
4000 J I I I I I I I L
3500-
3000-
2500-
Ti Xw > w
302 Thermochemical Database for Light Metal Alloys
(Ti) Mg hP2
Pfk/mmc
(Ti) W cI2
ImZm
System V-Zr 303
System VZr
Solution Phases:
Liquid, bccA2, hcpA3
Compound:
V 2 Zr
Modelling:
Assessor and D a t e :
J. Korb, and K. Hack, GTT, Germany (1995).
Phase V 2 Zr
ro,bcc A2 /
C(T) - 2.0 HyDCC~A i (298.15 K) H?^cp~A (298.15 K) =
63100 + 26.83 T + 2.0 GLIQv + GLIQZr
Phase liquid
O.liquid _ _ 2 3 9 8 6 + 19 3 3 8
Phase b c c A 2
Phase h c p - A 3
2500
2300-
2100
1900
700-
3
+- 1500-
<0
L_
d) 1300-
Q.
E 1100-
900-
-
700-
600
Zr
Table I - Invariant R e a c t i o n s .
(Zr) Mg hP2 M 2
P63/mmc
(Zr) W cI2 M 4
ImZm
System AlCSi
Comments:
Liquid and fcc-Al phases assumed to be ideal
Al and Si behave ideally in the AI4C3 phase
No ternary compounds
Assessor and Date:
J. Grbner, H. L. Lukas, and F. Aldinger.
Publication:
Calphad 20, 2 (1996) 247-254.
Phase AI4SC4
C(T) - 4.0 //'|fcc"'4I(298.15 K) - 4.0 /Y'graphite(298.15 K) - //s;diamond(298.15 K)
- 380700.0 + 1233 T - 193.902723 T InT - 0.017517573 T2
+ 3240000 T" 1 + 9E-07 T3
Phase Al 8 SiC 7
C(T) - 8.0 HA- ~ (298.15 K) - 7.0 //'graphite(298.15 K) - /Y;diamond(298.15 K)
cc Al
(C) graphite
AlgSiC7 hP16
System AlCuLi
Ternary C ompounds:
AlCuLiR, AlCuLiTl, AlCuLiT2, AlCuLiTB
Modelling:
Phase A l C u L i R
0 55 f{JccA
~ lfr>r\o
(298.15 X/\
o 1 17 H^rj,fee-
1 e K)
0.117 C AA l
~ ' (298.15 K)
C(T) 'Al
bcc
0 . 3 3 3 //,; ^(298.15 K) = G(Al:Cu:Li) =
20983.0 + 6.0 + 0.55 GHSER A , + 0.117 GIISRR C
+ 0.333 GHSERu
Phase A l C u L i T l
(Cu) Cu cF4 M 4
(Li) W cI2 M 2
ImZm
Al6CuL3 AICuLi-T2
quasicrystal
System A l - C u - M g
Ternary Compounds:
Laves-Cl4, Laves-G15, Laves-C36, Q-Phase,
S-Phase, , V-Phase
Modelling:
Assessor and D a t e :
T. Bhler, RWTH , Germany, (1997).
Phase Q - P h a s e
Phase Laves-G14
0,I.vr-C"14
Cu,Mg:AI 13011.35
0,Lve-Cl4
Cu:AI,Mg 8000
0,Lavee-C14
AI,Mg:Cu 15000
0,LaVM-C14
AhCu.Mg 6599.45
0,Lave-Cl4
AI,Cu:Mg - 224000 + 2.44
Phase Laves-Gl5
r0,LavM-C15
J
Cu,Mg:AI 13011.35
rO,Lv<!-C15
^CuiAI.Mg 8000
rO,Lavee-C15
^AI,Mg:Cu 15000
rO,Lves-C15
^AhCu.Mg 6599.45
rO,Lave-C15
'AI.CuiMg - 180000 - 1.615
Phase Laves-G36
0,Lave-C36
Cu,Mg:AI 13011.35
0,Lavce-C36
Cu:AI,Mg 8000
0,Lave-C36
AI,Mg:Cu 15000
0,Lave-C36
AI:Cu,Mg 6599.45
rO,LavM-C36
^AI,Cu:Mg - 227442 + 14.61
Phase S-Phase
C m - 2 . 0 HM
rO.fccA
'(298.15 ) - Hcc-M(298.15 )
>l3
- ffMg (298.15 K) = G(Al:Cu:Mg) =
63200 + 4.13 + 2.0 GHSERAI + GHSERc + GHSERMg
System A l-Cu-Mg 313
Phase VPhase
Phase
Mg:Mg:Cu,Mg:AI = "220000
314 Thermochemical Database for Light Metal Alloys
(Cu) Cu cF4 M 4
FmZm
(Mg) Mg hPI M 2
P6a/mme
System Al-Cu-Si
Modelling:
(Cu) Cu cF4 M 4
FmZm
System A l F e M n
Comments:
The data below are valid in the composition
range i M n < 0.25 (wt% Mn < 40.0) and
ZFe < 0.25 (wt%F(. < 40.0)
No ternary interaction coefficients for the liquid
phase. Interactions between Fe and Mn in
Al, 2 Mn,Al 2 Fe and Al 5 Fe 2 assumed to be ideal.
A s s e s s o r and D a t e :
. Jansson, and T.G. Chart (August 1997)
Phase f c c / U
0,fcc,41
L,
AI,F*,Mn:0 0.000
r ,fee41
^AI.Ft.MniO 63652
2.fee-Al
AI.Fr.Mn 26753
System A l-Fe-Mn _317
Phase Ali 3 Fe 4
I A I = 11987 + 6
LA:G = 11987 + 6
Phase 14
r ,,, _ infinn
^AlrFcMn ~ lUUUU
Phase Al 6 Mn
L'Sn = 32753 + 21 T
Phase Al 8 Mn 5 D8i 0
(Fe) Cu cF4 M 4
FmZm
(Fe) W cl2 M 2
ImZm
Al 5 Fe 2 oC*
Cmcm
System Al-Fe-Si
Comments:
No ternary interaction coefficients for the
substitutional solutions.
Assessor and Date:
P. Kolby, 1997.
Phase AlFeSi
Phase AlFeSi/?
Phase AlFeSi"
Phase AlFeSiy
Phase AlFeSi!
Phase AlFeSir 3
(Fe) Cu cF4 M 4
FmZm
(Fe) W eli M 2
ImZm
AlFeSi7 e**
AlFeSir, Fe 3 Al 3 Si 2
AlFeSiT3 Fe 5 Al 9 Si 5
322 Thermochemical Database for Light Metal Alloys
System Al-Li-Mg
Ternary C o m p o u n d s :
AlLi, AlLiMg-, AlMg-/?, Al, 2 Mg
Modelli ngi
Comments:
The data below are comptatible with Version I
of the -Mg system.
P h a s e Liquid
L OJIquid
AI.LI.Mg 20000
r 1.liquid
^AI.Li.Mg 15000
2,liquid
' y AI,l,i,Mg 20000
System A l-Li-Mg 323
Phase bcc,42
Phase fccAl
63650
AUMO = + 5 0
Phase hcp,43
ATMO = l.OE4
A = lOE4
Phase AlLi
LmU; = 3300.02.0 T
AhMM.
J
AI:Li,Mg = -25000.0 + 10.0 T
Phase AlMg/?
rO.AlMg- _ .,-r,
4Z0U
^AI:Li,Mg
Phase AlLiMg
CC M
C(T) - 0.53 HA ~ (298.15 K) 0.33 //L;bcc_/,2(298.15 K)
0.14 r Y ^ (298.15 K) = G(Al:Li:Mg) =
15500 + 23.93 T 3.0 T InT + 0.53 GHSERA,
+ 0.33 GHSERu + 0.14 GHSERMg
Phase Ali 2 Mg 17
(Li) W cI2 M 2
ImZm
(Mg) Mg hPI M 2
P/mme
System A l - M g - M n
Ternary C o m p o u n d :
AlMgMn-T
Modelling:
Comments:
The data are valid only in the Al-rich corner.
Very little information on the phase relationships
is known
Phase A l M g M n - T
rO.fcC
C(T) - 18.0 H"Alcc-Al(298.15 K) - 3.0 H^gp~A3(298.15 K)
2.0 // M ' c n bcc - /112 ' para (298.15 K) = G(Al:Mg:Mn) =
- 206402.0 + 11.85 + 18.0 GHSER A , + 3.0 GHSER M g
+ 2.0 GHSER Mn
326 Thermochemical Database for Light Metal A lloys
(Mg) Mg hPI M 2
P&3/mmc
M n Mn c58 cbcc,41
/43m
Cu cF4 M 4
Fm3m
Mn W eli M 2
ImZm
System AlMgSi
Modelling:
Publication:
Phase Liquid
0,liquid
J
A I , M g si = 4125.86 0.51573
L
A\X%i
I.Mg = 47961.64 + 5.9952
L liqui'
M'.MS%
I.Mg = 25813.8 - 3.22672
328 Thermochemical Database for Light Metal Alloys
System A l - M g - Z n
Compounds:
AlMg-/?, AlMg-7, Laves-G14
Modellin SI
Assessor and D a t e :
P. Liang, H. L. Lukas (1967)
Publication:
Phase Liquid
A. = 11475 + 11
= 11475 + 11
A = 11475 + 11
Phase hepA3
15* = lOE4
K = lOE4
I K = lOE4
Phase hcpZn
iXIn" = lOE4
i n " = lOE4
AS = lOE4
Phase LavesGl4
= 35000
C U
= 15000
4
Af' = 7500 18
0 " CU = 8000
CM = 8000
Phase AlMg/?
Phase AIMg7
0Mg:Mgg:A:Zn = "116000 + 58
Mg:SMg = 11310014.5
Phase
Mg:Mg:A.,z = 23100 + 11
Phase
MTg:A.:Mg,Zn:A. = 243000+81
Mg:Mg:Mg,z:A, = 243000 + 81
332 Thermochemical Database for Light Metal A lloys
(Mg) Mg hPI M 2
PGz/mmc
o*
Mg32(AI,Zn)49 c/162
7m3
System A l-Mn-Si 333
System AlMnSi
T e r n a r y Solution P h a s e s :
Liquid, fccAl, 185)8
Quasibinary phases:
AlMnSiQ, AlMnSi/?
Compounds:
AlMnSi<5
M o d e l l i n SI
Comments:
The data below are valid in the composition
range xsi < 0.2 and XMD < 0.05
The fccAl phase is assumed to be ideal
Assessor a n d D a t e :
P. Kolby, M.H. Rand, and T.G. Chart, 1997.
T h e r m o d y n a m i c p r o p e r t i e s of t h e solution a n d c o m p o u n d p h a s e s ( J . m o l ' )
P h a s e Liquid
r 0,Liquid
^Al.Mn.Si 37000
Phase Al8Mn5D810
o.cbcc 12,para
G(T) - lo.o //:, (298.15 K) 4.0 H^ (298.15 K)
dia
12.0 #s' (298.15 K)
10.0 G H S E R A I + 4.0 GHSER M n + 12.0 GHSER Si
334 Thermochemical Database for Light Metal A lloys
Phase AlMnSi
C(T)-18.0 H A
A fc- 1 (298.15 K) 4.0 tfM^bcc/ll2'plu'a(298.15 K)
diamond
//s (298.15 K) =
755772 + 3544.43 573.95
0.114419 2 + 9.7001306 3 + 3716760 " 1
G(T) - 16.0 HA CC-A l (298.15 ) 4.0 / / f cc_'412'para(298.15 )
3.0 r7s,diamond(298.15 ) =
698911 + 2958.7 493.78
0.17905 2 + 1.8723705 3 + 1822810 " 1
rO.AlMnSi-a 0 0001
^AhMniSiiAI.Si ~ U-UUU1
Phase AlMnSi/?
Phase AlMnSi"
(Mg) Mg 2 M 2
P63/mmc
7Mn Cu cF4 M 4
Fm3m
Mn W c/2 M 2
ImZm
Al 8 Mn 5 D8,o AlgCrs ft 26
RZm
336 Thermochemical Database for Light Metal Alloys
System A l - M o - T i
Solution P h a s e s :
Liquid, bcc-A2, fcc-Al, bcc-B2, hcp-A3
Ternary C o m p o u n d s :
A1M-D0.9, A1M-L>022, AlTi-Ll 0
Modellin S
Phase AIM-D0,9
r0,AIM-D0,9
^, 10656 - 1.332
rO,AlM-DO,j
^Al.TiiMoiO 32000 - 4
System ATMo-Ti 337
Phase AIM-D0 22
rO,AlM-D022
^AhMo.Ti = - 212000 + 120
Phase AlTi-Llo
rO,AITi-,lo rO,AlTi-Ll0
^Mo,Ti:AI = ^AhMo.Ti = - 13000
r 1,AlTi-Llo r l,AITI-Llo
^, = ^, = l.OE-4
r2,AlTi-Llo r2,AITi-Llo
^Mo.TirAI = ^, = - 13000
/O.AIT'i-Llo rO,AlTLlo
^MoiAl.Ti = ^, = - 15134 - 2.36
Phase b cc-A 2
l,bcc-A2
AI,Mo,Ti:D
2,bcc-,42
AI,Mo,TI:D
3,bee-A2
AI.Mo.TiiO
Phase bcc-L?2
rO,bcc-B2 rO,bcc-B2
v
Mo,TI:AI:D ^AhMo.TiiG -5000
rO,bcc-B2 0,bcc-B2
^Mo:AI,Ti:0 Al,Ti:Mo:D 8750- 1.25 T
r0,bcc-B2 0,bcc-B2
J
Ti:AI,Mo:a Al,Mo:ThO 14100 - 2 T
Phase bec-A2
r O.bcc-A2
, ,Ti:0 = 0
i-l.bcc- -A2
^, ,TI:D =0
j2,bee-A2
L
A\Mo,Tv.a = 0
338 Thermochemical Database for Light Metal A lloys
(Mo) W en M 2
ImZm
(Ti) Mg hP2 M 2
P&i/mmc
(Ti) W cI2 M 2
ImZm
System AlNTi
Ternary C ompounds:
AlNTi 2 , AlNTi 3 , Al 2 N 2 Ti 3
Modellin S
Phase b c c - A 2
rO,bcc>42
L
'A\,Ti:N = - 200000
rO,bccA2
^Al.ThN.G = - 200000
Phase h c p - A 3
r0.hcp.43
^Al.TiiN = - 100000
rO,hcp-A3
^.:,0 = - 80000
r l.hcp A3
L
AI,Ti:N,a = - 37300 + 100
340 Thermochemical Database for Light Metal A lloys
Phase AlNTi 2
Phase A1NT3
Phase Al 2 N 2 Ti 3
rO.fcC AI
C(T) 2.0 //AI (298.15 K) 2.0 //f". (298.15 K)
ncp_ A3
ro.hcp ,J
- 3.0 /7Ti ' (298.15 K) =
3405331.05 5217.37371 + 1.75061514 2 + 2.0 GHSERAI
+ 3.0 GHSERTI + 2.0 GHSERO.SN,
(Ti) Mg hP2 M 2
P3/mmc
(Ti) W cI2 M 2
ImZm
Al 2 N 2 Ti 3 Al 2 N 2 Ti 3 22 Al, 2
P31c Ti, 2
Al2 2
Ni 2
N2 2
N3 2
N4 2
Ti 2 2
Ti 3 2
Ti 4 2
Ti 5 2
342 Thermochemical Database for Light Metal A lloys
System AlNbTi
Solution P h a s e s :
Liquid, bccA2, fccAl, bccB2, hepA3
Ternary C o m p o u n d s :
A1MD0,9, A1MD0 22 , AlTiLl 0 , a,AlNb 3 A15
Modelling:
Assessor a n d D a t e :
N. Saunders, 1996
Phase A1MD0 2 2
bNb.T?0" = 20000
System A l-Nb-Ti 343
Phase AlMDOig
10656
NbVtrw" = L333 T
rO,AlMD0 19 _ 4nnf)
4UUU
^TiiAl.Nbi
-,DOi9 Qonnn
^AI.TirNbin
r0,AiMD0i9 _ lonnn
^Al.NbiTirD i^UUU
Phase AlTiLl 0
Jr O,AlTiLlo _ _ gerinn
AI,Nb,Ti:Al 10UUU
rO,AITILlo _ _ enfin
"AhAI.Nb.Ti 40UUU
Nb'Af10 = 18076
+ 12 T
NbtAl'.Tf10 = 15134
236 T
rO,AlTiLlo _ _ Q7f;nn
^ThAl.Nb o'OUU
^b" 1 0 = 15134 2 3 6 T
AhNb^f1 = 18076
+ 12 T
LJAl,Nb:Ti
ATP = 37600
Phase bccA2
rO,bee-A2
^AI.Nb.TiiO = 0
rl.bcc,42
^Al.Nb.Tii = 0
T2,bce-A2
^AI.Nb.TiiO = 0
Phase b c c 2
GA1:Nb:o = 8650 + T
G'AUTl,a = - 8750 + 1.35 T
'NbiTiiO
344 Thermochemical Database for Light Metal A lloys
rO,bccB2 0,bcc-B2
Nb,Ti:AI:a AI:Nb,TI:AI:D 'NbiTiiQ
0,bccB2 0,bccB2
Nb:AI,TI:0 AI,Ti:Nb:Q ^liTiiG
rO,bccB2 0,bcc-B2
' y Ti:AI,Nb:G AI,Nb:TI:n = -G\AI:Nb:G
Phase bccA2
rO,bcc-A2
J
AI,Nb,TI:G
r I,bcc-,42 n
U
^AI.Nb.TiiG
r 2,bcc-,42 _ r.
^AI.Nb.TitG U
Phase hcpA3
rO,hcp-A3
'JAI,Nb,Ti:a 10
Phase
rO,bee-A2/
G"() - 8.0 Z/, (298.15 ) 18.0 ff^'b ""(298.15 )
4.0 Htfcp-A 3(298.15 ) = G(Al:Ti:Nb) =
660000 + 79.5 + 8.0 GHSERAI + 18.0 GHSERNb
+ 4.0 GHSERT
C(T) 8.0 //'1fcc/"(298.15 ) 4.0 H^C-A 2(298.15 )
_ i o n . h r p - (298.15
/ n n j n i)
r \ _= n A l.MU.TH =
G(Al:Nb:Ti) _
18.0 /Yi
690000 + 148.5 + 8.0 GHSERAI + 4.0 GHSERNb
+ 18.0 GHSER
,
^AliNbtAI.TirG = 1680000 + 510
-,
^AhTiiAI.NbrG = 990000 + 270
I1" = 420000
^AliTliALNbrG
System A l-Nb-Ti 345
(Nb) W c/2 M 2
ImZm
(Ti) Mg hP2 M 2
Pe^/mmc
(Ti) W cI2 M 2
ImZm
CrFe tP30
P^/mnm
346 Thermochemical Database for Light Metal Alloys
System Al-Si-Zn
Modellin S
Assessor and D a t e :
M. Jacobs (1992).
Comments:
(Zn) Mg hPI M 2
P&s/mmc
System A TSn-Zn 347
System AlSnZn
Modelling:
Publication:
Phase Liquid
r 2,liquid
16198.13 + 3.46632
Phase h c p A 3
fc? = lOE4
Phase hcpZn
" = lOE4
348 Thermochemical Database for Light Metal Alloys
(Zn) Mg hPI M 2
PSs/mmc
System Al-Sn-Zr 349
System Al-Sn-Zr
Compound:
AlSn 2 Zr 5
Modelling:
Phase AlSn2Zr5
(Zr) Mg hP2 M 2
P&s/mmc
(Zr) W cl2 M 4
ImZm
System Al-Ta-Ti
Solution P h a s e s :
Liquid, bcc-A2, fcc-Al, bcc-B2, hcp-A3
Ternary Compounds:
A1M-D0.9, A1M-D0 22 , AlTi-Ll 0 ,
Modelling:
Assessor a n d D a t e :
N. Saunders, 1996
Phase h c p - A 3
r0.hrp-B3
^AI.Ta.TiiQ 40000
352 Thermochemical Database for Light Metal Alloys
Phase AlTi-Ll 0
rO,AiTi-Lio rO,AiTi-LiD iinnn
^Ta.TlrAI ^AlrTa.Ti ~ HUW
Phase A1MD0, 9
A
LT; ^, D o 0 " = 24000
" = 8000
L'|AT^fa?G'9 = 32000
O,AIM ,
AI:Ta,Ti:D
0 1 OQ
0
Phase bcc-A2
AMO",TI:O = - 10000
f f * = - 10000
AU^TI-O = - 10000
System A l -Ta-Ti 353
Phase
AhT:Al.Ta:D = 104
TI:AI,Ta:G = 300000
Table I C rystal Structure and Phase Description.
(Ta) W en M 2
ImZm
(Ti) Mg hP2 M 2
P6i/mmc
(Ti) W cI2 M 2
ImZm
CrFe IP30
P4i/mnm
354 Thermochemical Database for Light Metal Alloys
System Al-Ti-W
Solution P h a s e s :
Liquid, bcc-A2, fcc-Al, bcc-B2, hcp-A3
Ternary C o m p o u n d s :
-,, AlTi-Llo
Modelling:
Assessor and D a t e :
N. Saunders, 1996
Phase A1M-D0, 9
rO.AIM-DOn
^Ti.WrAhQ 73212
r 0,AIM-D0| 8
'Ti:AI.W:G - -2000
rO,AlM-DO|
^Al.TirWiQ 8000
r O,AIM-DOn
J
AI:Ti,W:G 8136
System A l-Ti-W 355
Phase AlTiLl 0
rO,AITiLlo rO,AITLlo
^Ti,W:AI ^AltTi.W : 16914
rO,AlTiLlo rO,AITiLlo
^WiAI.Ti ^AI.ThW = 15134 2.36
rO,AITLlo rO,AITiLlo
^Ti:Al,W ^AI.WiTI -- - 3000
Phase bccA2
,l,bee-A2
J
Al,Ti,W:G 0
f2,bccA2
^Al.Ti.WrG 0
r J.DCCA2 0
^AI.Ti.W.TirQ
Phase bccB2
875
G1:T.:Q = + l 2 5 T
rO,bccB2 rO,bcc-B2
^:|,:0 ^AI.TirWiQ ^l:Ti:0
Phase bcc A2
rO,bcc.42
^AI.TKWIO 0
l.bcc -A2
^, W:G - 0
r2,bcc- -A2
^, W:G - 0
356 Thermochemical Database for Light Metal A lloys
(W) W en M 2
/m3m
(Ti) Mg hP2 M 2
P6z/mmc
(Ti) W cl2 M 2
ImZm
System B-Hf-Ti
Comments:
No ternary compounds
Assessor and D a t e :
H. Bittermann, (1997)
Publication:
. Bittermann, and P. Rogl, J. Phase EquiL, 18,
24-47 (1997).
Phase Liquid
r 0,liquid
'yB.Hf,Ti 41733.1
j 0,liquid
^B.Hf.Ti 125.375
r U,liquid
Zv
B.Hf.Ti 93.6697
358 Thermochemical Database for Light Metal A lloys
Phase B 2 M
rO,B2M
^, = 7223.32 + 1.75379
Phase B<M 3
rO.B^Ma
^BrHf.Ti = 115124 49.5166
Phase B M
rO.BM _
^ Ti 19396.7 6.57772
(Hf) Mg hP2 M 2
Ps/mmc
(Hf) W clS M 2
ImZm
(Ti) Mg hP2 M 2
P6z/mmc
(Ti) W cI2 M 2
ImZm
BM BFe oP8 4
Pnma Ti 4
BM 3 B<Ta3 0II4
Immm
System Cu-Mg-Y 359
System Cu-Mg-Y
Modelling:
Assessor an d Date:
T. Bhler, RWTH, Aachen, Germany, (1997).
Comments:
No coefficents for the ternary solution phases.
No ternary compounds.
(Mg) Mg hP2 M 2
Pdz/mmc
(Y) W en M 4
ImZm
(Y) Mg hPI M 2
PSs/mmc
360 Thermochemical Database for Light Metal A lloys
System CuMgSi
Ternary C o m p o u n d s :
CuMgSio*, CuMgSiT, LavesC15
Modellin
SI
Liquid Substitutional, RedlichKister
bccA2 Substitutional, RedlichKister
fccAl Substitutional, RedlichKister
hcpA3 Substitutional, RedlichKister
hcpZn Substitutional, RedlichKister
CuMgSi Stoichiometric, (Cu)i6(Mg)e(S)7
CuMgSiT Stoichiometric, (Cu) 3 (Mg) 2 (Si)
LavesG15 Sublattice model, (Cu,Mg,Si) 2 (Cu,Mg,Si)
Assessor a n d P a t e :
T. Bhler, RWTH, Aachen, Germany, (1997).
Phase C u M g S i
Phase C u M g S i r
c A
C(T)- 3.0 H* - (298.15 K) 2 . 0 //MgCp_/13(298.15 K)
o.d
wo.damod(298 1 5 R ) G(u:Mg:Si)
Si =
r 1,liquid
^Cu.Mg.Si 141736
r2,liquld IFfM
^Cu.Mg.Si 1VU4
Phase h c p Z n
Oglilo = 50000
CXS"G = 50000
CKISG = 50000
Phase L a v e s C l 5
r 0,LavesCl 5
J
Mg,SI:Cu 15000
rO,LavMC15
L
Si:Cu.Mg 6599.45
rO,LaveeC15
L
Cu,Si:Mg 193131 + 20.69
S f " = 800
ci7' 5
= 13011.35
Table I:a C rystal Structure and Phase Description.
(Mg) Mg hP2 M 2
PGi/mmc
Cu 2 Mg Cu 2 Mg cF24 Cu 16 Laves-C15
FdZm Mg 8
Cu 3 Mg 2 Si MgZn2 12 Si 2 CuMgSi-r
P63/mmc Mg 4
Cu 6
System Cu Mg-Zn 363
System C u - M g - Z n
Ternary Solution P h a s e s :
Compounds:
Laves-C14, Laves-C15, Laves-G36, CuZn-7, MgZn,
Mg 2 Zn 3 , Mg 2 Zn n
Modelling:
Phase b c c 2
Gcu:Mg = 0.0
Cu.Mg - - 2500
Gcu:Zn = 0.0
cu.zn = - 1 2 8 9 8 . 9 7 + 3 . 2 6 5 9 8
Cu!zn = 945.265 0.80679
r l,bccB2 rl,bccB2
^Cu.Mg^nrG = ^ZnrCu.MgiD 05 C u , Z n
r0,bccB2 rO,bccB2
^Cu.ZniMgiQ = ^MgiCu.Zn 7
Cu:Zn ^Cu.Zn
rl,bccB2 rl,bccB2
^Cu.ZniMgiD = ^Mg:Cu,Zr.:0
Jl
^Cu.Zn
r2,bccB2 r2,bccB2
^Cu.Zr^Mg = ^Mg:Cu,Zn:D IC2 u.Zn
^
rO,bccB2 rO,bccB2
^Mg.ZniCuiO = ^CuiMg.ZmO ~ ^Mg:Zn + Mg.Zn + Cu.Zn + 0.5 L Cu.Zn
rl,bccB2 r l,bccB2
^Mg.ZmCurO = ^CuiMg.ZnrO 0.5 LC u,z
rO,bccB2 rO,bccB2
^Mg.ZnrCu.ZniQ = ^:,:0 5 C u.Zn
rO,bccB2 rO,bccB2
^Mg.ZnrCu.MgtD = ^Cu.MgMg.ZntO 2 Cu.Zn
rO,bccB2 rO,bccB2
^Cu.ZnrCu.MgiO = ^Cu.MgrCu.ZnrO 5 Cu.Zn
rO,bccB2 rO,bccB2
^Cu.Mg.ZrnCurO = ^Cuu.Mg.ZnrO ^Cu.Zn
rO,bccB2 rO,bccB2
^Cu.Mg.ZrrZnrO = ^Znu.Mg.ZniG 1.5 C u.Zn
System Cu-Mg-Zn 365
Phase bec - A 2
rO.bcc-,42
^Cu.Mg.ZniO = 0
r 1,bcc-,42
^Cu.Mg.ZniD = 0
r 2,bcc-,42
^Cu.Mg.ZniO = 0
Phase Mg2Znn
rO,Mg 2 Zn n _ T i l finn
Phase Laves-Cl4
O.Lavea-CH
Mg.ZntCu 35000.00
O.Laves-C
Cu:Mg,Zn 35000.00
CLavee-CH
Zn:Cu,Mg 6599.45
rO,Laves-CH
^Cu,Zn:Mg - 75305.48
Phase Laves-G15
rO,Laves-ri5
'JCu,Mg:Zn 13011.35
rO,Lave-C15
'^Zn:Cu,Mg 6599.45
rO,Lave-C15
^Mg,Zn:Cu 35000.00
r O.LavenCI5
^CuiMg.Zn 8000.00
O.Lavee-ClS
L Cu,Zn:Mg - 78824.62
rO,Lavr-CI5
L
Mg:Cu.Zn 25529.06
366 Thermochemical Database for Light Metal A lloys
Phase LavesC36
r 0,LavC TC 36
J
Mg,Zn:Cu 35000.00
rO,LveeC36
^CurMg.Zn 8000.00
0,LavwC36
Zn:Cu,Mg 6599.45
O.LaveeC36
Cu,Mg:Zn 13011.35
0,LaveC36
Cu,Zn:Mg - 90226.26
Phase Mg 2 Zn 3
rO,MgjZn 3
L
Mg:Cu,Zn 100000
Phase MgZn
rO.MgZn
^Mgu.Zn = - 575000
Phase CuZn7
K4 = 11552.71 1.67824
K5 = 15732.3 10.26575
K6 = 37289.2 13.05259
7 = 9000.0 1.50000
13 4 + 2 5 + 2 6 + 6 7 = 9857.77 77.4538
13 4 + 6 7 = 96185.23 30.81712
13 4 + 2 6 + 6 7 = 21606.83 56.9223
C(T)-5.0 /Y c ' u fcc /U (298.15K)6.0 /7^ cp_/,3 (298.15 )
hcp_Zn
2.0 //zn (298.15 ) = C(Zn:Cu:Cu:Mg) =
13.0 4 + 2.0 5 + 2.0 6 + 6 7 + 5.0 GHSERCu
+ 6.0 GHSERwg + 2.0 GHSERZ
C(T) - 5.0 Hccc~A l (298.15 ) 6.0 //^ cp " 43 (298.15 )
2.0 /7znhcp_Zn(298.15 ) = G(Cu:Zn:Cu:Mg) =
13.0 4 + 6.0 7 + 5.0 GHSERcu + 6.0 GHSERMg
+ 2.0 GHSERzn
C(T) - 3.0 //Cufcc_'41(298.15 K) 6.0 H^hgcp-A 3(298.15 K)
4.0 //znhcp_Zn(298.15 K) = G(Cu:Zn:Cu:Mg) =
13.0 K4 + 2.0 K6 + 6.0 K7 + 3.0 GHSERcu + 6.0 GHSERMg
+ 4.0 GHSERzn
System Cu-Mg-Zn 367
(Mg) Mg hP2 M 2
PSs/mmc
(Zn) Mg hP2 M 2
PGz/mmc
Cu 2 Mg Cu 2 Mg cF24 Cu 16 Laves-C 15
FdZm Mg 8
Laves-C36 MgNi2 hP14 Cr, 6 Laves-C36
PSi/mme Cr 2 6
Zr, 3
Zr2 3
Mg 2 Znn Mg 2 Zn n cP39
PmZ
MgZn
Mg 2 Zn 3 mCHO
B2/m
APPENDICES
Thermodynamic Properties of the FJements 371
ALUMINIUM
Aluminium fccAl
GHSERAI = ^ " " ' ( T ) H0Jcc~A l
(298.15 K) =
298.15 <T< 700.00 : 7976.15 + 137.093038 24.3671976 InT
1.884662E3 2 - 0.877664E6 32
+ 74092 " 1
700.00 << 933.47 : 11276.24+223.048446 - 38.5844296
+ 18.5319823 2 5.7642276 3
+ 74092 " 1
933.47 << 2900.00 : 11278.378 + 188.684153 - 31.748192
1230.52425 " 9
Aluminium bccA2
C C A 2
G B C C A I = GA { - (T) - HA icc-M(298.15 ) =
298.15 < < 2900.00 : 10083.00 4.813 + G H S E R A I
Aluminium cbccA12
G cbccAi2 ( r ) _ / / ^ " i ( 2 9 8 . i s ) =
'Scientific Group Thermodata Europe (S.G.T.E.) Data for Pure Elements, A.T. Dinsdale, CAL
PHAD, 15, 4, 317425 (1991).
372 Thermochemical Database for Light Metal A lloys
Aluminium cubA13
/^>cub Al3/rr>\ ijO,fccAl
G H
AI (' ) A -
BORON
Boron /?rhomboB
s~irhomboB/TI\ o.rhomboB(298 1 5 jg _
GHSERB
II
298.15 < T < 1100.00 7735.284 + 107.111864 - 15.6641 InT
0.006864515 2 + 6.18878E07 3
+ 370843 " 1
1100.00 < T < 2348.00 16649.474 + 184.801744 26.6047
7.980904 2 - 2.55608 3
+ 1748270 " 1
2348.00 < < 3000.00 36667.582 + 231.336244 31.5957527
0.00159488 2 + 1.3471907 3
+ 11205883 1
3000.00 << 6000.00 21530.653+222.396264 31.4 -
Thermodynamic Properties of the Elements 373
CARBON
Carbon graphite
GHSERc = G c r a p h i t e (T) // c g r a p h i l e (298.15 K) =
298.15 <T< 6000.00 : 17368.441 + 170.73 24.3 InT
4.723E04 2 + 2562600 " 1 - 2.643E+08 T~ 2
+ 1.2+10 -3
Carbon diamond
G c i a m o n d (T) /7 c ' graphite (298.15 ) =
298.15 <T< 6000.00 : 16359.441+175.61 24.31 -
4.72304 2 + 2698000 '1 - 2.61 +08 " 2
+ 1.11+10 " 3
374 Thermochemical Database for Light Metal Alloys
Carbon liquid
GLIQc = G c q u i d (T) - ffc-graphite(298.15 K) =
298.15 <T< 6000.00 : 117369-24.63 + GHSERc
CERIUM
Cerium f c c - A l
GHSER c = G c T ^ ' C n - -f/ c f c -'I4 (298.15 K) =
298.15 < < 1000.00 : -7160.519 + 84.23022 - 22.3664 I nT
-0.0067103 2 - 3.20773E-07 3 - 1 8 1 1 7 " '
1000.00 << 2000.00 : -79678.506 + 659.4604 -101.32248
+ 0.026046487 2 - 1.9302976-06 3 + 11531707
2000.00 << 4000.00 : -14198.639 + 190.370192 - 37.6978
Cerium b c c - A 2
GBCCcc = G%c-A2(T) - Hcc-M (298.15 K) =
298.15 <T< 1000.00 : -1354.69-5.21501 - 7.7305867
- 0.029098402 2 + 4.784299-06 3 - 196303 ' 1
1000.00 << 1072.00 : -12101.106 + 187.449688 - 37.6142 -
1072.00 << 6000.00 : -11950.375 + 186.333811 - 37.4627992
- 5.7145-05 2 + 2.348-09 3 - 25897 " ' 1
Cerium dhcp
Gc b c p (T) - Hcc-M(298.15 K) =
298.15 <T< 4000.00 : - 190.0 + 0.56886 + GHSERc.
Cerium h c p - A 3
GHCPc. = Ghccp-A3(T) - Hcicc-Ai (298.15 K) =
298.15 <T< 4000.00 : 50000 + GHSERC<;
Cerium liquid
GLIQc. = Glfd (T) - Hc',ccc-Al(298.15 K) =
298.15 <T< 1000.00 : 4117.865 - 11.423898 - 7.5383948 T I nT
- 0.02936407 2 + 4.827734E-06 3 - 198834 " 1
1000.00 < < 4000.00 : - 6730.605 + 183.023193 - 37.6978
Thermodynamic Properties of the Elements 375
CHROMIUM
C h r o m i u m bccA2(paramagnetic)
GHSERcr = Gbc-A 2-p&ra(T) // c ' b c c / l 2 ' p a r a (298.15 K) =
298.15 < T < 2180.00 : 8856.94 + 157.48 26.908 InT
+ 1.89435E3 2 1.47721E6 3 + 139250 " 1
2180.00 << 6000.00 : 34869.344 + 344.18 50
2885.2629 " 9
Chromium c b c c A 1 2
G c c b c c A , 2 p " r a (T) 7/ c 'r bcc " 42 ' para (298.15 ) =
298.15 <T< 6000.00 : 11087.0 + 2.7196 + GHSER Cr
Chromium cubA13
Gccf-A3(T) // c ; b c c 4 2 , p a r a (298.15 ) =
298.15 < T < 6000.00 : 15899.0 + 0.6276 + GHSER Cr
Chromium f c c A l (paramagnetic)
GFCCcr = Girft-M(T) - /7 c ' b c c 4 2 ' p a r a (298.15 K) =
298.15 << 6000.00 : 7284.0 + 0.163 + GHSER Cr +
Chromium hcpA3(paramagnetic)
GHCPcr = Ghccp~A 3(T) - tfCrbcc"42'para(298.15 K) =
298.15 << 6000.00 : 4438.00 + GHSER Cr +
C h r o m i u m liquid
GLIQcr = G c q r uid (T) // c ' r bcc_/,2 ' para (298.15 K) =
298.15 < T < 2180.00 : 24339.95511.420225 + 2.37615E21 7
+ GHSERcr
2180.00 << 6000.00 : 18409.36 8.563683 + 2.88526E+32 " 9
+ GHSERcr
Chromium LavesC l4
G Cr,Lav M Cl4 _ g Q / / o,bcc^2 ( 2 g g ^ R ) _
Chromium LavesG36
cCr.Lave.C3e _ 3 Q flb(298.15 K) =
298.15 < < 6000.00 : 15000.0 + 3.0 GHSERcr
COPPER
Copper feeAl
GHSERcu = GfrA 1(T) - Hctc~M (298.15 K) =
298.15 <T< 1357.77 : 7770.458 + 130.485235 24.112392 InT
2.65684E3 2 + 0.129223E6 3 + 52478 " 1
1357.77 << 3200.00 : 13542.026 + 183.803828 31.38
+ 364.16727 " 9
Copper bccA2
GBCCcu = G%TA 2(T) - ^~(2985 ) =
298.15 < < 3200.00 : 4017.00 1.255 + GHSERcu
Copper hcpA3
GHCPcu = Gccp~A 3(T) - H^ucc-A l(298.15 K) =
298.15 <T< 3200.00 : 600.0 + 0.2 + GHSERcu
Copper liquid
GLIQcu = G c T ^ T ) //C'urcc/11(298.15K) =
298.15 <T< 1357.77 : 12964.7369.511904 5.849E21 7
+ GHSERcu
1357.77 < < 3200.00 : 13495.481 9.922344 3.642E+29 9
+ GHSERc
IRON
Iron bccA2(paramagnetic)
GHSERpv = Gbcc,42,para^ _ ^^2,P"( 2 98.15 K) =
298.15 <T< 1811.00 : 1225.7 + 124.134 23.5143 InT
4.39752E3 2 - 0.058927E6 3 + 77359 "
Thermodynamic Properties of the Elements 377
HAFNIUM
Hafnium h c p - A 3
GHSERHf = G^rK3{T) - H^cp~A3 (298.15 K) =
298.15 <T< 2506.00 : -6987.297 + 110.744026 - 22.7075 - I n T
- 0.004146145 2 - 4.77E-10 3 - 22590 " 1
378 Thermochemical Database for Light Metal A lloys
LITHIUM
Lithium becA2
GHSERu = G\?~A 2(T) - H?cc-A 2(298.15 K) =
200.00 <T< 453.60 : 10583.817 + 217.637482 T 38.940488 T InT
+ 35.466931E3 T 2 19.869816E6 T 3 + 159994
453.60 < T< 500.00 : 559579.123 + 10547.879893 T
1702.8886493 T InT
+ 2258.329444E3 T 2 571.066077E 6 T 3
+ 33885874 T" 1
500.00 <T< 3000.00 : 9062.994 + 179.278285 T31.2283718 T InT
+ 2.633221E3 T 2 0.438058E6 T 3 102387 T"
Thermodynamic Properties of the Elements 379
Lithium f c c - A l
GFCCu = G i p 4 1 () - ^-2(298.15 ) =
200.00 < < 3000.00 : - 108 + 1.3 + GHSER Li
Lithium hepA3
GHCPi.i = Ghp-A3(T) - ^-2(298.15 ) =
200.00 < < 3000.00 : - 154 + 2 + GHSER L
Lithium liquid
GLIQLi = G L quid (T) - H^cc-A2 (298.15 K) =
200.00 <T< 250.00 : -7883.612 + 211.841861 - 38.940488 -
+ 35.466931 E-3 2 - 19.869816E-6 3
+ 159994 " 1
250.00 < < 453.60 : 12015.027 - 362.187078 + 61.6104424 -
- 182.426463-3 2 + 63.955671 -6 3
- 559968 " 1
453.60 << 3000.00 : -6057.31 + 172.652183 -31.2283718 -
+ 2.633221 -3 2 - 0.438058-6 3
- 102387 " 1
MAGNESIUM
M a g n e s i u m hepA3
GHSER Mg = G^-A3(T) - Hgcp-A3(298.15 ) =
298.15 <T< 923.00 : -8367.34 + 143.675547 - 26.1849782
+ 0.4858-3 2 - 1.393669-6 3 + 78950 " 1
923.00 < < 3000.00 : - 14130.185 + 204.716215 - 34.3088 -
+ 1038.19225 ~ 9
Magnesium b c c - A 2
GBCC M g = G-A2(T) - HMhgp-A3(298.15 ) =
298.15 <T< 3000.00 : 3100.00-2.1 + GI I SER M s
Magnesium c b c c - A 1 2
G cbcc-A.2(T) _ //^-3(298 15 K ) =
MANGANESE
Manganese c b c c A l 2 ( p a r a m a g n e t i c )
G H S E R M I , = G^ b n cc A12 ' para (T) #M^ bcc A,2 ' para (298.15 K) =
298.15 <T< 1519.00 : 8115.28 + 130.059 23.4582 InT
7.34768E3 2 + 69827 T~l
1519.00 < < 3000.00 : 28733.41 + 312.2648 48
+ 1656.847+27 " 9
Manganese bccA2(paramagnetic)
GBCCwn = G^cn-A 2-pm(T) //^ b c c _ A 1 2 ' p a r a (298.15 ) =
298.15 < < 1519.00 : 3235.3 + 127.85 23.7
7.44271 3 2 + 60000 " 1
1519.00 < < 3000.00 : 23188.83 + 307.7043 48
+ 1265.15227 " 9
Manganese f c c A l ( p a r a m a g n e t i c )
G F C C M = GtM-A 'pm(T) - //^ n b c c A 1 2 ' p a r a (298.15 ) =
298.15 <T< 1519.00 : 3439.3 + 131.884 24.5177 -
- 63 2 +69600 " 1
298.15 << 1519.00 : 26070.1+309.6664 48 -
+386.19628 " 9
Manganese LavesCl5
G&n015 3 0
^Mn bcc " A12 ' par, '(298.15 ) =
298.15 << 3000.00 : 3000.0 + 3.0 GHSER Mn
Thermodynamic Properties of the Elements 381
Manganese cubA13
Gf~M3(T) - //MCncbcc"AI2'para(298.15 K) =
298.15 < T < 1519.00 : +2314.88 + 5.936 1.4203 - InT
+ 1.51409E03 2 + 442.0 " 1 + GHSERM
1519.00 3000.00 : + 442.65 0.9715 + 2.3107229E+30 T~9
+ GHSERMn
Manganese hcp/13(paramagnetic)
GHCPM = G^rA 3-fm{T) - /7M'nbcc_A12'para(298.15 K) =
298.15 < < 1519.00 : 4439.3 + 133.007 24.5177 InT
6E3 2 + 69600 " 1
1519.00 << 6000.00 : 27070.1+310.7894 48
+386.19628 ~9
Manganese liquid
GLIQMH = G'Zd(T) - //jcnbccA12'para(298.15 ) =
298.15 <T< 1519.00 : 17859.9112.6208 4.41929E21 7
+ GHSERMn
1519.00 << 3000.00 : 18739.5113.2288 1.656847+30 " 9
+ GHSERMn
MOLYBDENUM
Molybdenum bccA2
GHSERMO = Gf-A 2(T) - Hb0cc-A 2(298.15 ) =
298.15 << 2896.00 : 7746.302 + 131.9197 23.56414
0.003443396 2 + 5.6628307 3 + 65812 " 1
1.3092710 4
2896.00 < < 5000.00 : 30556.41 + 283.559746 42.63829 -
4.849315+33 ~9
Molybdenum fccAl
GFCCMO = G$-A 1(T) - Hhcc-A 2(298.15 ) =
298.15 << 2896.00 : 7453.698 + 132.5497 23.56414
0.003443396 2 + 5.6628307 3 + 65812 ~'
1.3092710 4
2896.00 < < 5000.00 : 15356.41 + 284.189746 42.63829
4.849315+33 ~9
382 Thermochemical Database for Light Metal A lloys
Molybdenum hepA3
GHCPMO = GhrA 3(T) - Hubcc-A 2(298.15 K) =
298.15 <T< 5000.00 : 11550 + GHSERMo
Molybdenum liquid
GLIQMO = GlZ'd(T) - //MO C C _ / , 2 (298.15 K) =
298.15 <T< 2896.00 : 34085.045 + 117.224788 23.56414 InT
0.003443396 2 + 5.66283E07 3 + 65812 "1
1.3092710 4 + 4.2451922 7
2896.00 << 5000.00 : 3538.963+271.6697 42.63829
NITROGEN
Nitrogen gas
GHSERN = Gf(T) - ff0e.5Nj(298.15 K) =
298.15 <T< 950.00 : 3750.6759.45425 12.7819 InT
0.00176686 2 + 2.681E09 3 32374 " 1
950.00 < < 3350.00 : 7358.85 + 17.2003 16.3699
6.510704 2
+ 3.009708 3 + 563070 " 1
3350.00 < < 6000.00 : 16392.8 + 50.26 20.4695
+ 2.3975404 2 8.33309 3 + 4596375 1
Nitrogen liquid
GLIQN = Gquid(T) # 5 ,(298.15 ) =
298.15 < < 6000.00 : 29950 + 59.02 + GHSERN
NEODYMIUM
Neodymium dhcp
GHSERNd=GdJhdcp /^ dhcp (298.15 ) =
298.15 <T< 900.00 : 8402.93 + 111.10239 27.0858
+ 5.5612504 2 2.692306 3+34887 " 1
900.00 << 1128.00 : 6984.083 + 83.662617 22.7536
0.00420402 2 1.80206 3
1128.00 << 1799.00 : 225610.846 + 1673.04075 238.182873
+ 0.078615997 2 6.04820706 3 + 38810350 " 1
1799.00 << 2000.00 : 25742.331+276.257088 48.7854
Thermodynamic Properties of the Elements 383
N e o d y m i u m bccA2
GBCC N d=G b J c d c 42 H^cc-A 2(298.15 K) =
298.15 <T< 400.00 : 6965.635 + 110.556109 27.0858 InT
+ 5.56125E04 2 2.6923E06 3 + 34887 " 1
400.00 << 1128.00 : +7312.2153.033976 + 14.9956777
0.050479 2 + 7.28721706 3 8 3 1 8 1 0 " 1
1128.00 << 1289.00 : 18030.266+239.677322 44.5596
1289.00 << 1800.00 : +334513.0172363.9199 + 311.409193
0.156030778 2 + 1.2408421 05 3 64319604 "
N e o d y m i u m liquid
GLIQ N M=G^ d c 42 H$CC~A 2
(298.15 ) =
298.15 <T< 300.00 : 3351.187 + 109.517314 27.0858
+ 5.5612504 2 2.692306 3 + 34887 " 1
300.00 << 1128.00 : +5350.0186.593963 + 5.357301
0.046955463 2 + 6.86078206 3 374380 " 1
1128.00 << 1800.00 : 16335.232 + 268.625903 48.7854
NICKEL
Nickel f c c A l (paramagnetic)
G H S F . R N i = G r / U p a r a //^ c c A 1 ' p a r a (298.15 ) =
298.15 <T< 1728.00 : 5179.159 + 117.854 22.096
0.0048407 2
1728.00 << 3000.00 : 27840.655+279.135 43.1
+ 1 .12754+31 " 9
Nickel bccA2(paramagnetic)
G B C C N I = G ^ 4 2 //^ f c c 4 1 ' p a r a (298.15 ) =
298.15 < < 1300.00 : + 8715.084 3.556 + GHSER Ni
Nickel hcpA3(paramagnetic)
G H C P N I = GhNcrA 3 - ^ f c c 4 1 p a r a ( 2 9 8 . 1 5 K) =
298.15 < < 3000.00 : + 1046 + 1.2552 + GHSER Ni
Nickel liquid
GLIQNi = G'r,quid /Y^ i fcc /Upara (298.15 K) =
298.15 <T< 1300.00 : 16414.686 9.397 3.82318E21 7
+ GHSERN
1728.00 <T< 3000.00 : 18290.8810.537 1.127554+31 "9
+ GHSERTi
384 Thermochemical Database for Light Metal A lloys
NIOBIUM
N i o b i u m becA2
GHSERNb = G N c b c_A2 (T) H^C~A 2
(298.15 K) =
298.15 <T< 2750.00 : 8519.353 + 142.045475 2 6 . 4 7 1 1 - InT
+ 2.03475E04 2 3.5012E07 3 + 93399 1
2750.00 < < 1000.00 : 37669.3 + 271.720843 41.77
+ 1.528238+32 "9
N i o b i u m feeAl
GFCC N b = Gfa-M(T) - H^CC~A 2(298.15 K) =
298.15 < < 6000.00 : 13500 + 1.7 + GHSER N b
Niobium hcpA3
GHCP N b = G N c b p_A3 (T) H^cc-A 2
(298.15 K) =
298.15 < < 5000.00 : 10000 + 2 . 4 + GHSER N b
N i o b i u m liquid
GLIQ N b = G N r d ( T ) H^CC~A 2
(298.15 K) =
298.15 <T< 2750.00 : 29781.55510.816417
3.06098E23 7
+ GHSERNb
298.15 <T< 2750.00 : 30169.910.9647 1.52824E+32 "9
+ GHSERNb
SILICON
Silicon d i a m o n d
GHSERsi = G d > m o n d (T) tf|;diamond(298.15 K) =
298.15 <T< 1687.00 : 8162.609 + 137.236859 22.8317533
1.912904E3 2 0.003552E6 3 + 176667 " 1
1687.00 << 3600.00 : 9457.642 + 167.281367 27.196
420.36928 " 9
Silicon b c c A 2
GBCCsi = G?C~A 2(T) - tf|di,m,ond(298.15 K) =
298.15 < < 1687.00 : 47000.0 22.5 + GHSER S
Silicon ebeeA12
Thermodynamic Properties of the Elements 385
G cbccAi2 ( r ) _ H:di&mond(298.15 K) =
298.15 <T< 6000.00 : 50208.0 20.377 + GHSER S
Silicon cubA13
G|V b ' 413 (T) tf|;diamond(298.15 ) =
298.15 <T< 6000.00 : 47279.0 20.377 + GHSER s i
Silicon f c c A l
fee-Al^ _ ^o.diamond^gg ^ jg _
TANTALUM
Tantalum bec.42
GHSERxa = G^ C " A 2 (T) //Tkbcc_/12(298.15 K) =
298.15 <T< 1300.00 : 7285.889 + 119.139858 23.7592624 InT
0.002623033 2 + 1.70109E07 3 3293 " 1
1300.00 < < 2500.00 : 22389.955 + 243.88676 41.137088
+ 0.006167572 2 6.5513607 3 + 2429586 " 1
2500.00 < < 3258.00 : + 229382.886 722.59722 + 78.5244752
0.017983376 2 + 1.9503307 3 93813648 " 1
3258.00 < < 6000.00 : 963392.734 + 2773.7774 337.227976
+ 0.039791303 2 9.74251 07 3
+ 5.09949511+08 " 1
Tantalum f c c A l
GFCCja = Gm~M(T) - H0^cc-A 2(298.15 ) =
298.15 << 6000.00 : 16000 + 1.7 + GHSER Ta
386 Thermochemical Database for Light Metal A lloys
Tantalum hepA3
GHCPTa Gjcp~A 3(T) - H^c-A 2(298.15 K) =
298.15 < < 6000.00 : 12000 + 2.4 + GHSERT.
Tantalum liquid
CLIQxa = GTquid(T) H^C~A 2(298.15 K) =
298.15 < < 1000.00 : 29160.975 7.578729
+ GHSERTa
1000.00 <T< 1300.00 : 51170.228181.121652 + 23.7872147 InT
0.009707033 2 + 4.4449E07 3 3520045 " 1
+ GHSERT.
1300.00 < < 2500.00 : 66274.294 305.868555 + 41.1650403
0.018497638 2 + 1.26973506 3 5952924 " 1
+ GHSERja
2500.00 < < 3290.00 : 185498.547 + 660.615425 78.4965229
+ 0.00565331 2 + 4.1956607 3 + 90290310 ~
+ GHSERTa
3290.00 << 6000.00 : 1036069.472727.38037 + 320.319132
0.043117795 2 + 1.05514806 3
5.54714342+08 " 1 + GHSERTa
TIN
Tin bctA5
GHSERsn = Gf-A *(T) - H^ci~A 5
(298.15 ) =
100.00 <T< 250.00 : 7958.517 + 122.765451 25.858
+ 0.511853 2 3.1927676 3 + 18440 ~
250.00 < < 505.078 : 5855.135 + 65.443315 15.961
18.87023 2 + 3.1211676 3 61960 " 1
505.078 < < 800.00 : 2524.724 + 4.005269 8.2590486
16.8144293 2 + 2.6231316 3 1081244
123.0723 ~9
800.00 << 3000.00 : 8256.959 + 138.99688 28.4512
123.0723 " 9
Tin bccA2
GBCCsn = Gl'c-A 2(T) - ;-(298.15 ) =
100.00 << 3000.00 : 4400.00 6.0 + GHSERSn
Thermodynamic Properties of the Elements 387
Tin f c c A l
GFCCsn = &~1() H'bct~A b
(298.15 K) =
100.00 < < 3000.00 : 5510.08.46 + GHSER Sri
Tin h c p A 3
GHCPsn = Glcnc-A 2(T) - H'bctA' 5
(298.15 K) =
100.00 < 3000.00 : 3900.00 4.4 + GHSER S
Tin liquid
GLIQsn = G^ quid (T) // s ' bct 45 (298.15 K) =
100.00 <T< 505.078 : 7103.09214.087767 + 1.47031E18T 7
+ GHSERsn
505.078 <T< 3000.00 : 6971.58713.814382 + 1.2307E+25 " 9
+ GHSERsn
TITANIUM
T i t a n i u m hepA3
_ /ihcp A3
GHSERTI (T) - H^cp-A3 (298.15 K) =
- ^Tl
298.15 900.00 : 8059.921 + 133.615208 23.9933 InT
<T <
4.777975E3 2 + 0.106716E6 3 + 72636 " 1
900.00 <T< 1155.00 7811.815 + 132.988068 23.9887
4.20333 2 0.0908766 3 + 42680 " 1
1155.00 <T< 1941.00 908.837 + 66.976538 14.9466
8.14653 2 + 0.2027156 3 1477660 " 1
1941.00 <T< 4000.00 124526.786 + 638.806871 87.2182461 -
+ 8.2048493 2 0.3047476 3
+ 36699805 " 1
Titanium bccA2
GBCCT = Gbcc-A2/rp\
T
tfT:hcp'43(298.15 ) =
Titanium cbccA12
(jebce-An^ _ tf.hcp3(298 1 5 Rj =
TUNGSTEN
Tungsten b c c A 2
GHSERw = Gy5c-A 2(T) - Htfcc~A 2(298.15 K) =
298.15 <T< 3695.00 : 7 6 4 6 . 3 1 1 + 1 3 0 . 4 24.1 InT
0.001936 2 + 2.07E07 3 + 44500 " 1
5.3311 4
3695.00 < < 6000.00 : 82868.801 + 389.362335 54
+ 1.528621+33 '9
Tungsten f c c A l
GFCCw = G%C~A (T) - Htfcc~A 2(298.15 ) =
298.15 <T< 3695.00 : 11653.689 + 131.03 24.1
0.001936 2 + 2.0707 3 + 44500 " 1
5.3311 4
3695.00 < < 6000.00 : 63568.801 + 389.992335 54
+ 1.528621+33 '9
Tungsten h c p A 3
GHCPw = Gw'f'^T) // w b c c ' 4 2 (298.15 ) =
298.15 <T< 3695.00 : 7103.689 + 130.4 24.1
0.001936 2 + 2.0707 3 + 44500 " 1
5.3311 4
3695.00 << 6000.00 : 68118.801+389.362335 54
+ 1.528621 +33 " 9
Tungsten liquid
GLIQw = G^ quid (T) Hhcc-A 2(298.15 ) =
298.15 < < 3695.00 : 44514.273 + 116.29001 24.1
0.001936 2 + 2.0707 3 + 44500 " 1
5.3311 4 2.71346824 7
3695.00 < < 6000.00 : 30436.051 + 375.175 54
VANADIUM
Vanadium bec2
GHSERv = G 0 / 0 "' 42 () // v ' bcc ' 42 (298.15 K) =
298.15 <T< 790.00 : 7930.43 + 133.346053 T 24.134 T InT
3.098E3 T 2 + 0.12175E6 T 3 + 69460 T'1
390 Thermochemical Database for Light Metal A lloys
YTTRIUM
Yttrium hcpA3
GHSERy = GyCP~A 3(T) - ~3 (298.15 K) =
298.15 <T < 1500.00 : -7347.055 + 117.532124 - 23.8685 InT
- 0.003845475 2 + 1.1125E-08 3 - 16486 '1
1500.00 <T < 1799.00 : -15802.62+229.831717 - 40.2851
+ 0.0068095 2 - 1.14182-06 3
1799.00 <T < 3700.00 : - 72946.216 + 393.885821 - 58.2078433
+ 0.002436461 2 - 7.2627-08 3 + 20866567 "
Yttrium bccA2
GBCCY =
_ /~<bee-A2
(T) 1Ho,bep-A3^298 15 ) _
Yttrium liquid
GLIQY = GYquid(T) //Y'hcp'43(298.15 K) =
298.15 <T< 1799.00 : 3934.121+59.921688 14.8146562 InT
0.015623487 2 + 1.442946E06 3
140695 " 1
1799.00 << 3700.00 : 13337.609+258.004539 43.0952
0.019918739 2 + 8.4130807 3
31549963 " 1
ZINC
Zinc hcpZn
GHSERzn = G Zn p_Zn (T) //^ hcp_Zn (298.15 K) =
298.15 <T< 692.68 : 7285.787 + 118.470069 23.701314
1.712034E3 2 1.2649636 3
692.68 << 1700.00 : 11070.559 + 172.34566 31.38
+ 470.51424 '9
Zinc hepA3
GzP~A3{T) - //zr,hcp_Zn(298.15 ) =
298.15 <T< 1700 : 2970 1.57 + GHSERZn
Zinc bccA2
GBCCzn = G\^-A 2(T) - ^-(298.15 ) =
298.15 < < 6000.00 : 2886.96 2.5104 + GHSERZn
Zinc bctA5
G bet A5/rr,\ W
rjo, hepZn
Zn U ) - Zn =
Zinc liquid
G z quid Cn ^znhcp_/13(298.15 K) =
298.15 < T < 692.68 : 7157.21310.29299 3.5896E19 7
+ GHSERzn
692.68 < < 1700.00 : 7450.16810.737066 4.7051 +26 " 9
+ GHSERMn
ZIRCONIUM
Zirconium hcpA3
GHSERZr = G; hcp A3 (T) H*cp-A 3(298.l5 K) =
298.15 < < 2128.00 : 7827.595 + 125.64905 24.1618
4.377913 2 + 34971 " 1
2128.00 << 4000.00 : 26085.921+262.724183 42.144
1342.89528 ~9
Zirconium bccA2
GBCCzr = Gz r bccA2 (T) //^hcp'43(298.15 ) =
298.15 <T< 2128.00 : 7302.0560.70335 1.445606
+ 4.0378263 2 9.72897359 3
7.614289411 4 9737.0 ~ + GHSERZr
2128.00 << 4000.00 : 4620.034 + 1.55998 + 1.41035+32 " 9
Zirconium fccAl
GFCCzr = G%rA l(T) - H^cp-A 3(298.15 ) =
130.00 < < 4000.00 : 7600.00 0.9 + GHSERZr
Zirconium liquid
GLIQzr = G z quid (T) J/hcp'*3(298.15 K) =
130.00 < < 2128.00 + 18147.703 9.080762 + 1.6275E22 7
+ GHSERzr
2128.00 <T< 4000.00 + 17804.649 8.91153 + 1.343E+31 " 9
+ GHSERzr
Zirconium LavesGl4
GZr,LavMC14 _ ^Q ^P-A S^g 15 R j _
Zirconium Laves-Gl5
CznZ?VM~C15 - 3 0 ^z;hcp_/,3(298.15 K) =
298.15 < < 6000.00 : 15000.0 + 3.0 GHSERZr
Zirconium Laves-C36
ClnzT" - 0 3 6 - 3.0 H^cp-A3 (298.15 K) =
298.15 < < 6000.00 : 15000.0 + 3.0 GHSERZr
Magnetic Parameters of the Elements 395
A P P E N D I X II: M A G N E T I C C O N T R I B U T I O N TO T H E G I B B S E N
E R G I E S OF T H E P U R E E L E M E N T S (S.I. units) '
Chromium
Chromium bccA2
Nickel
Nickel b c c - A 2
bcc-A2
cbcc-Al2
fcc-Al
hcp-A3
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