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Article history: A uniform temperature distribution is important to obtain better control and higher performance of
Received 11 May 2010 polymer electrolyte membrane fuel cells (PEMFCs). In PEMFCs, more than half of the chemical energy of
Accepted 5 January 2011 hydrogen is converted into heat during the electrochemical generation of electricity. If not being properly
Available online 2 February 2011
exhausted, this reaction heat overheats the PEMFCs and thus impairs their performance and durability. In
general, large-scale PEMFCs are cooled by liquid water that circulates through coolant ow channels in
Keywords:
bipolar plates or in dedicated cooling plates. In this study, detailed uid ow and heat transfer in large-
Polymer electrolyte membrane fuel cells
scale cooling plates with 18 cm 18 cm square area was simulated using a commercial computational
Cooling plate
Flow eld design
uid dynamics (CFD) code. Based on the CFD simulations, the performances of six different coolant ow
Temperature uniformity eld designs were assessed in terms of the maximum temperature, temperature uniformity, and pres-
Parallel Serpentine ow eld sure drop characteristics. The results demonstrated that multi-pass serpentine ow eld (MPSFF) designs
Multi-pass serpentine ow eld could signicantly improve the uniformity of temperature distribution in a cooling plate compared with
the conventional serpentine ow eld designs, while maintaining the coolant pressure drop similar.
2011 Elsevier Ltd. All rights reserved.
1359-4311/$ e see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2011.01.009
1428 S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434
ow elds (MPSFFs) which are characterized by closely-interlaced reaction, two gas diffusion layers (GDLs) for the uniform reactant
channels of different path-lengths from the inlet. diffusion, and two bipolar plates for the electron conduction and
The design concept of MPSFFs was, in fact, inspired by the ow distribution. Cooling is essential for the operation of a PEMFC
convection enhanced serpentine ow eld (CESFF) proposed by Xu stack to exhaust the heat produced by electrochemical reactions.
and Zhao [15]. The closely interlaced channel structure in the CESFF This is generally done by liquid water that circulates through coolant
was experimentally demonstrated to enhance the performance of ow channels formed in bipolar plates or in dedicated cooling plates.
direct methanol fuel cells (DMFCs) and also enable more stable Fig. 1(a) shows a dedicated cooling plate inserted between several
operation. Regarding the cooling performance of MPSFFs, Yu et al. unit cells to exhaust reaction heat from a PEMFC stack.
[16] investigated the temperature distribution in a small-scale For the steady-state operation of a PEMFC, the average heat ux
cooling plate (6 cm 6 cm square area) with several single-path at the surface of a dedicated cooling plate (two cooling surfaces), q,
MPSFFs using computational uid dynamics (CFD). The results in is determined as [9,11]
Yu et al. [16] clearly demonstrated better performances of MPSFFs
as coolant ow eld designs, compared to those of the conventional nI Dhof =2F V
serpentine ow elds. q (1)
2A
This study numerically investigated the performance of parallel
MPSFFs as coolant ow eld designs for a large-scale cooling plate where n is the number of unit cells per cooling plate, I is the cell
with 18 cm 18 cm square area. A commercial CFD code, STAR-CD current, V is the output cell voltage, A is the total cell area, Dhof is the
(CD-Adapco, Korea), was used to simulate the detailed uid ow formation enthalpy of water (241.8 kJ/mol for LHV, 285.8 kJ/mol
and heat transfer in the cooling plates employing different coolant for HHV), and F is the Faraday constant (96,487 C/mol). For the stack
ow eld designs. The conventional serpentine and parallel ow structure shown in Fig. 1(a), the number of unit cells per cooling
elds were also considered for comparison purposes. The cooling plate, n, is one since a cooling plate is installed between every unit
performance of each coolant ow eld design was quantitatively cell. However, an n of about 3e5 is generally used in real practice
evaluated in terms of the maximum surface temperature, temper- [9]. Note that the heat production rate in a PEMFC is similar or
ature uniformity, and coolant pressure drop characteristics. slightly larger than its output power because the thermal efciency
is around 40e50%.
2. Theory and calculations The grid structure used for the cooling plate simulations is
illustrated in Fig. 1(b), where the plate is discretized into either uid
2.1. Geometric model cells for coolant channel regions or solid cells for bounding struc-
ture regions. Only half domain of a cooling plate was considered to
In general, a PEMFC is constructed by stacking many unit cells reduce the computational costs by taking advantage of symmetry.
repeatedly to obtain a proper level of output power as shown in Fig.1 Thus, as shown in Fig. 1(b), a symmetry condition was imposed on
(a). For example, more than 100 unit cells are serially stacked in an the top boundary (the center-plane of the cooling plate) while
automotive PEMFC to generated a rated power of about 80e100 kW. a constant heat ux condition was imposed on the bottom
A repeating unit cell in Fig. 1(a) consists of a membrane electrode boundary (the heat ux surface). The surface heat ux, q, was
assembly (MEA) for the ion conduction and electrochemical prescribed to be 5000 W/m2 (0.5 W/cm2), which is a general value
encountered during the normal operation of PEMFCs.
In fact, the heat ux value of 0.5 W/cm2 was estimated by refer-
ring to the specication of a 1.2 kW Nexa PEMFC power module
a
e
ur
total cell area of 4700 cm2 (47 stacks of unit cells with 100 cm2 active
Cooling Plate area), the heat dissipation rate in a unit cell of a Nexa power module
amounts to 0.35 W/cm2. For n 3 assumed in this study, the heat
nt Cathode Bipolar ux at the surface of a cooling plate becomes about 0.5 W/cm2.
o la Plate
Co ir MEA
However, it should be noted that a constant heat ux condition is
A difcult to be achieved at the surface of a cooling plate during the
Anode Bipolar actual operation of PEMFCs. Nevertheless, the results from these
Plate idealized simulations are believed to provide essential information
en Cooling Plate regarding the performance of cooling plates in real situations.
rog The coolant ow eld designs considered in this study are
yd t
H lan nt shown in Fig. 2. The models A and B are the conventional serpen-
o o la et tine ow elds with three and ve parallel paths, and the models
Co Fluid
Symmetry BC (Top) Cell Co utl C and D are the MPSFFs with three and ve parallel paths. In
b O
addition, a straight ow eld with 45 parallel paths (model E) and
a spiral ow eld with ve parallel paths (model F) were also
considered for comparison purpose. Note that the MPSFFs were
initially proposed as reactant ow elds to enhance the under-rib
t
let lan
Fig. 2. Six coolant ow eld designs for a large-scale cooling plate with 18 cm 18 cm square area.
CD (CD-Adapco, Korea). This program solves the conservation transient terms in Eqs. (2)e(4) were not considered because this
equations for mass, momentum, and energy, based on the nite study focused only on the steady cooling performances. For solid
volume discretization method. For laminar, Newtonian, incom- regions, Eq. (4) was considered by setting uj 0 (pure conduction
pressible ow of liquid coolant through the cooling plate, the equation). The geometrical parameters and material properties
governing equations are expressed as used in the simulations are summarized in Table 1. The cooling
vuj plates were assumed to be made of graphite [18] and liquid water
0 (2) was assumed to ow through the plates.
vxj
A SIMPLE algorithm was adopted to treat the veloc-
! ! ityepressure coupling of the continuity equation, Eq. (2), and the
vui vu vp v vu
r uj i m i (3) NaviereStokes equation, Eq. (3). The numerical solution was
vt vxj vxi vxj vxj considered to converge when the residual became smaller than
! ! 2 105 for the continuity and momentum equations and smaller
vT vT v vT than 1 109 for the energy equation. The operating and
rcp uj k (4) boundary conditions are also listed in Table 1, where the inlet
vt vxj vxj vxj
temperature, Tin, was xed at 40 C while the volume ow rate of
where r is the density, m is the kinetic viscosity, cp is the specic liquid water, Q, was varied as 6 106, 4 106, 2 106 m3/s
heat, and k is the thermal conductivity of the cooling uid. The (6, 4, 2 ml/s).
1430 S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434
Table 1 temperature, Ts, along a straight channel (model E). From these
Parameters used for cooling plate simulations. data, the Darcy friction factor, f, was calculated as
Parameters Values
dp Dh
Plate geometries f (5)
Dimension, lp wp tp 180 180 2 mm3 dx ru2m =2
Channel and rib width, wch wrib 2 mm
Channel depth, tch 1 mm where Dh is the hydraulic diameter (1.33 mm in this study) and um
Hydraulic diameter, Dh 1.33 mm is the mean ow speed in the channel. Similarly, the Nusselt
Properties of plate (graphite) number, Nu, was calculated as
Density, rp 2250 kg/m3
Specic heat, cp,p 690 J/kg K dTm rcp um Ach Dh
Nu (6)
Thermal conductivity, kp 24.0 W/m K dx kPch Ts Tm
Properties of coolant (water) at 40 C
70 Pressure Drop designs (models A and B) and the parallel straight ow eld design
Pressure Drop p (kPa)
56
50
Table 2
Summary of the simulation results for six coolant ow eld designs at
40 Tmax 52 Q 6 106 m3/s.
Max. Temperature Flow Cell Tmax Tmin Tavg DT UT Dp
Optimal Range 48 eld number ( C) ( C) ( C) ( C) ( C) (Pa)
30
Model A 1,505,700 55.620 40.755 48.323 14.865 3.262 58,600
5 Model B 1,959,300 56.091 40.788 48.632 15.313 3.279 17,940
0 5 10 15 20 25 x 10
Model C 4,227,300 56.929 41.628 52.303 15.300 2.066 64,400
Cell Number Model D 4,227,300 57.613 41.567 51.690 16.046 1.810 17,900
Model E 825,300 56.532 41.363 49.964 15.169 3.437 135
Fig. 3. Results of the grid dependency test conducted for a coolant ow design
Model F 1,732,500 56.975 41.771 53.356 15.204 1.899 17,120
(model A).
S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434 1431
f Re
words, UT becomes zero when the temperature distribution is
perfectly uniform.
40 40 The quantitative results for the cooling performances at
Le 1 cm Q 6 106 m3/s are summarized in Table 2. The maximum
0 0 surface temperature, Tmax, is around 55e57 C for all parallel ow
0 4 8 12 16 18
Pathlength x p (cm ) eld designs, which is because the outlet temperature of the
cooling uid is xed at 53 C due to energy balance in the cooling
60
Temperature T (C)
25
plates (corresponding to the coolant temperature rise of 13 C).
Le ,t 4 cm b 20 Similarly, the minimum surface temperature, Tmin, is about
55
Ts 15 40e41 C near the coolant inlet temperature of 40 C. In Table 2, the
range of surface temperature distribution, DThTmax Tmin , for
Nu
50
Nu 5.7 10
Tm the parallel MPSFFs (models C and D) is slightly larger than those
45 5 for the conventional parallel serpentine ow elds (models A and B)
0
and the parallel straight ow eld (model E). However, the
40
0 4 8 12 16 18 temperature uniformity index, UT, for the parallel MPSFFs (models C
Pathlength x p (cm ) and D) is about 1.8e2.1 C, which corresponds to only about 60% of
UT for the conventional parallel serpentine ow elds (models A and
Fig. 4. Evolution of dimensionless numbers along the channel of the parallel straight B) and the parallel straight ow eld (model E). The parallel spiral
ow eld (model E) at Q 6 106 m3/s: (a) Darcy friction factor, f, and (b) Nusselt
ow eld design (model F) exhibits the second lowest UT, but its
number, Nu.
average surface temperature, Tavg, is highest among the ow eld
The parallel spiral ow eld design (model F) shows rather uniform designs considered in this study.
temperature distribution, but the average surface temperature is Fig. 7 shows the simulated effect of coolant ow rate, Q, on the
also higher than the other ow eld designs. temperature uniformity indices, DT and UT. It is clearly shown in
For more quantitative comparison of the cooling performances, Fig. 7 that DT and UT are inversely proportional to Q, which indicates
the uniformity index, UT, was dened as [9,11] that higher ow rate facilitates more uniform temperature distri-
bution. In Fig. 7, the surface temperature difference, DT, becomes
Z Z
relatively similar irrespective of ow eld designs when Q becomes
jT Tavg jdA T dA sufciently large, e.g., 6 106 m3/s. Fig. 7 clearly shows that the
UT A
Z and Tavg A
Z (7) parallel MPSFFs (models C and D) exhibit the smallest UT, indicating
dA dA their superior cooling performance. At all values of Q considered in
this study, the uniformity index, UT, for the parallel MPSFFs (models
A A
C and D) maintains about 60% of UT for the conventional parallel
where A is the surface area. Note that the integration in Eq. (7) is serpentine ow elds (models A and B) and the parallel straight
done only for the surface area at the constant heat ux boundary. ow eld (model E). The parallel spiral ow eld design (model F)
Thus, Tavg denotes the average surface temperature of the cooling has a uniformity index similar to the parallel MPSFFs.
Fig. 5. Center-plane temperature distribution in cooling plates with six coolant ow eld designs at Q 6 106 m3/s.
1432 S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434
Fig. 6. Surface temperature distribution in cooling plates with six coolant ow eld designs at Q 6 106 m3/s.
The pressure drop, Dp, across the coolant ow eld designs are the fact that both the uid velocity and the channel length are
compared in Fig. 8. The quantitative values for Dp at inversely proportional to the number of parallel paths when the
Q 6 106 m3/s are also provided in Table 2. It is found in Fig. 8 coolant ow rate is xed. In addition, Fig. 8 indicates that the Dp
that the pressure drop, Dp, is closely related to the number of across each coolant ow eld design is rather proportional to the
parallel paths in the ow elds. That is, the ow eld designs with volume ow rate, Q, but shows a slight nonlinearity as Q increases.
three parallel paths (models A and C) exhibit similarly higher Dp This slight nonlinearity of Dp with respect to Q is believed to be
(around 60,000 Pa at Q 6 106 m3/s), while the ow eld caused by the secondary pressure losses in many curved regions of
designs with ve parallel paths (models B, D, and F) exhibit simi- the coolant ow elds.
larly lower Dp (around 18,000 Pa at Q 6 106 m3/s). As expec- Better temperature uniformity for the parallel MPSFFs (models C
ted, the parallel straight ow eld design (model E) has Dp of only and D) is believed to be caused by the closely-interlaced structure
about 135 Pa at Q 6 106 m3/s due to the large number of of ow channels having different path-lengths measured from the
parallel paths (45 parallel paths). This trend is easily understood by inlet. However, this interlaced ow structure is also found to
S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434 1433
Fig. 7. Cooling performances of six coolant ow eld designs: (a) surface temperature
difference, DT, and (b) temperature uniformity indices, UT.
B
50 C parallel serpentine ow elds (models A and B), while the pressure
D drop characteristics were rather similar when the number of
40 E parallel paths maintained equal. The parallel straight ow eld
F
(model E) showed the smallest pressure drop but, at the same time,
30
the most non-uniform temperature distribution as expected.
20 In summary, the parallel MPSFFs (models C and D) were found
to be most effective coolant ow eld designs for maintaining more
10 uniform temperature throughout the active area. In addition, the
parallel MPSFFs were found to have the possibility of further
0
2 10
6
4 10
6
6 10
6 improving the temperature uniformity in PEMFCs (and also
Volume Flow Rate Q (m /s ) 3 relieving the overheating) when the coolant ow rate at each
parallel path is properly controlled. Considering the parasitic power
Fig. 8. Pressure drop characteristics of six coolant ow eld designs. required for pumping liquid coolant, the MPSFF with ve parallel
1434 S.M. Baek et al. / Applied Thermal Engineering 31 (2011) 1427e1434
paths (model D) was the best coolant ow eld design among [11] J. Choi, Y.H. Kim, Y. Lee, K.J. Lee, Y. Kim, Numerical analysis on the perfor-
mance of cooling plates in a PEFC, Journal of Mechanical Science and Tech-
considered in this study. The results of this study can be a useful
nology 22 (2008) 1417e1425.
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[14] J.H. Nam, K.J. Lee, S. Sohn, C.J. Kim, Multi-pass serpentine ow-elds to
Acknowledgement enhance under-rib convection in polymer electrolyte membrane fuel cells:
Design and geometrical characterization, Journal of Power Sources 188 (2009)
This work was supported by the second stage of the Brain Korea 14e23.
[15] C. Xu, T.S. Zhao, A new ow eld design for polymer electrolyte-based fuel
21 (BK21) Project in 2010, and also by the National Research
cells, Electrochemistry Communications 9 (2007) 497e503.
Foundation of Korea (NRF) funded by the Ministry of Education, [16] S.H. Yu, S. Sohn, J.H. Nam, C.J. Kim, A numerical study to examine the
Science and Technology (2010-0012613). performance of multi-pass serpentine ow elds for cooling plates in polymer
electrolyte membrane fuel cells, Journal of Power Sources 194 (2009)
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