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 Ncert Solutions Class 12th Cbse Class XII Chemistry Project

NCERT Solutions for Class 12th Chemistry

Chapter 9 Coordination Compounds
August 6, 2014 by Anand Meena

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NCERT Solutions for Class 12th Chemistry Chapter 9

Coordination Compounds
National Council of Educational Research and Training (NCERT) Book Solutions for class XII
Subject: Chemistry
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 Chapter: Chapter 9 Coordination Compounds

Class XII Chemistry Chapter 9 Coordination Compounds NCERT Solution is given below.

Question 9.1:
Explain the bonding in coordination compounds in terms of Werners postulates.
Answer
Werners postulates explain the bonding in coordination compounds as follows:
(i) A metal exhibits two types of valencies namely, primary and secondary valencies.
Primary valencies are satisfied by negative ions while secondary valencies are satisfied by both negative
and neutral ions.
(In modern terminology, the primary valency corresponds to the oxidation number of the metal ion,
whereas the secondary valency refers to the coordination number of the metal ion.
(ii) A metal ion has a definite number of secondary valencies around the central atom.
Also, these valencies project in a specific direction in the space assigned to the definite geometry of the
coordination compound.
(iii) Primary valencies are usually ionizable, while secondary valencies are non-ionizable.

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