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Abstract
In this study some of the important properties of experimentally manufactured woodplastic composites (WPC) were determined.
Specimen having 60% and 80% particle and ber of radiata pine (Pinus radiata ) were mixed with polypropylene (plastic) and four
different additives, namely Structor TR 016 which is coupling agent, CIBA anti-microbial agent (IRGAGUARD F3510) as fungicide,
CIBA UV lter coating (TINUVIN 123S), CIBA blue pigment (Irgalite), and their combinations. Based on the initial nding of this
work static bending properties of the samples enhanced as above chemicals were added into both particle and ber-based specimens.
Thickness swelling of the samples were also improved with having additives in the panels. Micrographs taken on scanning electron
microscope (SEM) revealed that coupling agent and pigment resulted in more homogeneous mixture of wood and plastic together. Two
surface roughness parameters average roughness (Ra) and maximum roughness (Rmax) used to evaluate surface characteristics of the
samples showed that particle based samples had rougher surface characteristics than those of ber based ones. No signicant inuence of
chemicals added in the samples was found on surface roughness values of the samples manufactured from particle and ber of radiata
pine.
r 2006 Elsevier Ltd. All rights reserved.
0360-1323/$ - see front matter r 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.buildenv.2006.06.018
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2638 A. Wechsler, S. Hiziroglu / Building and Environment 42 (2007) 26372644
effect of particle size is one of the most important excellent prime source for pulp and paper manufacture in
parameters affecting overall products properties. The use Chile and many other countries. Additional products from
of optimum size of particle might improve the mechanical radiate pine include interiors and exteriors panels, furniture
properties of a composite, but the incorporation of a manufacture, trimming, and structural lumber. Although
preservative should also be considered if it will be used for research and technological development in the area of
an application where biological resistance of this product is WPC in Chile has been increasing but there is still no
important [10]. comprehensive work has been done in this area [1].
Radiata pine is one of the main species having with an Therefore, the main objective of this work is to investigate
annual production of 27 million of cubic meters in Chile. It some of the properties of WCP panels manufactured from
Table 1
List of the chemicals used as additive in panel manufacture
Radiata pine ber Wf Subproduct of Radiata pine furniture manufacture Catem, Concepcion Chile (wood high technology
process. 50 mesh center)
Radiata pine particles Wp Subproduct of Radiata pine furniture manufacture Catem, Concepcion Chile (wood high technology
process. 1050 mesh center)
Polypropylene Pp Virgin polypropylene pallets Petroquim, Polypropylene producer, Talcahuano,
Chile
Eastmann Epolene maleated polyethylene E 43 Maleated polypropylene wax Eastman chemical companies, USA
(polypropylene)E 43
Struktol TR016 Tr 016 A blend of fatty acid metal soap and an amide. Struktol chemical companies, USA
CIBA Antimicrobial agent IRGAGUARD F3510 Irg Contains a broad-spectrum fungicide that is highly Ciba chemical company
effective against mold, rot, blight and stain.
CIBA Plastic UV lter TINUVIN 123S Tn UV plastic ber. Liquid hindered amine light Ciba chemical company
stabilizer (HALS) based on aminoether
functionality, absorbed into highly porous
polypropylene.
CIBA Wood UV lter lignostab Lg Lignin stabilizer for color stabilization of natural, Ciba chemical company
tinted or stained wood and for the durability
improvement of wood substrates coated with clear
and transparent pigmented nishes.
Ciba irgalite blue pigment Bp Concentrate powder pigment Ciba chemical company
Table 2
Ratio of the raw material and additive agents used for panel manufacture
A 60% wood ber 80% wood ber 60% wood particles 80% wood particles
40% polypropylene 20% polypropylene 40% polypropylene 20% polypropylene
B 60% wood ber 80% wood ber 60% pine wood 80% wood particles
40% polypropylene 20% polypropylene 40% polypropylene 20% polypropylene
2% TR016 2%TR016 2% TR016 2% TR016
C 60% wood ber 80% wood ber 60% wood particles 80% wood particles
40% polypropylene 20% polypropylene 40% polypropylene 20% polypropylene
2% TR016 2% TR016 2% TR016 2% TR016
6% IRG 6% IRG 6% IRG 6% IRG
D 60% wood ber 80% wood ber 60% wood particles 80% wood particles
40% polypropylene 20% polypropylene 40% polypropylene 20% polypropylene
2% TR016 2%TR016 2% TR016 2% TR016
1.2% LG 1.6% LG 1.2% LG 1.6% LG
1.2%TN 0.6% TN 1.2% TN 0.6% TN
E 60% wood ber 80% wood ber 60% wood particles 80% wood particles
40% polypropylene 20% polypropylene 40% polypropylene 20% polypropylene
2% TR016 2%TR016 2% TR016 2% TR016
0.05 g BP 0.05 g BP 0.05 g BP 0.05 g BP
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radiata pine furnish and plastic which is virgin polypropy- 165 1C for 2 min followed by adding the chemicals for each
lene with addition of various chemicals to provide an initial type of material. In the next step particles or bers were
data in this area. added into the mixture and rotated for another 3 min
completing a total mixing time to 5 min. Fig. 1 illustrates
2. Materials and methods the mixer used for panel manufacture. Mixed samples then
were pressed in a hot press with a 20 by 20 cm platen
Commercially produced polypropylene in the form of capacity. Each batch of sample was pressed using a
pallets and wood material of radiate pine (Pinus radiate) temperature of 165 1C and a pressure of 40 bar for 5 min.
were used to manufacture experimental panels. Wood The press was cooled off while the samples were still under
particles were manually screened on a sieve and classied compression before they were removed and conditioned in
into two portions, 10 mesh particles and 50 mesh ber. a climate chamber with a temperature of 20 1C and a
Four different types of chemicals Structor TR 016 which is relative humidity of 55%. Average target thickness of the
coupling agent, CIBA anti-microbial agent (IRGA- panel was 2.5 mm. Modulus of elasticity (MOE) and
GUARD F3510) as fungicide, CIBA UV coating (TINU- modulus of rupture (MOR) of the samples were deter-
VIN 123S) and CIBA blue pigment (Irgalite) were added mined on a Comten Testing Unit equipped with a load cell
into the samples. Tables 1 and 2 show the list of the with a capacity of 2000 kg Figs. 2A,B and 3 show some of
chemicals and their percentages used for panel production. ber- and particle-based samples and bending test set-up,
Wood particles and bers were dried in an oven before they respectively.
were mixed with polypropylene. First plastic material was
put into mixer rotating at 75 rpm having a temperature of
3. Results
elasticity of the samples made using wood particles also ber and plastic along with coupling agent resulted in a
had similar trend to above panels. Fiber-based panels had better bounding between the elements in contrast to
only 3.3% higher MOE values than that of particle-based particle types of panels which can also be seen in
samples at 95% condence level. However, ber-based Figs. 9A and B which were taken from the cross section
panels containing coupling agent had signicantly higher of the samples using SEM. Once chemicals, fungicides, UV
MOE than those of specimens manufactured from particle- lter, and pigments were added into particle-based panels
based using the same chemicals as can be seen in Table 3 their MOE characteristics also enhanced and become
and Fig. 6. This nding may suggest homogeneous mix of similar to the values of the samples manufactured from
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Table 3
Mechanical and physical test results
Panel type Static bending (MPa) Water absorption (%) Thickness swelling (%) Surface roughness (mm)
Fiber-based samples
Fig. 6. Average modulus of elasticity of the samples made from 60% and 80% bers and particles.
ber-based samples. Overall MOR values of both particle based samples had lower values than those of ber type of
and ber types of sample followed similar trend of MOE the samples. Separation between bers as a result of water
values. TS of the samples as a result of 2- and 24-hr water soaking for 24 hr was observed on the micrographs taken
soaking test are presented in Table 3 and Fig. 7. The on SEM as illustrated in Figs. 9C and D.
highest TS value was 18.6% for the wood ber base panels Based on the roughness parameters obtained from the
without addition of any chemicals for 24-hr water soaking. surface of the samples ber-based panels resulted in
It appears that when coupling agent, UV lter, and signicantly different Ra and Rmax values than those of
fungicides had relatively positive inuence on TS on particle-based ones. For example particle type samples
ber-based samples as can be seen on Fig. 7. When made without having any chemical had 5.84 mm Ra which
coupling agent was added into the samples their TS was is 3 times higher than ber-based panels as illustrated in
reduced more than half in the case of ber-based panels. Fig. 8. In a previous study it was determined that
Dimensional stability of the ber-based panel types B, C, commercially produced berboard panels had much
D, and E did not show any signicant difference at 95% smoother surface than particleboard panels [11]. Even if
condence level. Overall TS characteristics of the particle- very ne particles are used on the face layer of the
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particleboard pits and falls due to larger geometry of experimental WPC panels. In the light of the preliminary
particle than bers resulted in rougher surface character- results of this study both physical and chemical properties
istics [11]. This concept was also reected in particle, ber- of the samples were improved with addition of four
and plastic-based experimental panels made in this study. types of chemicals into the panels. It seems that using less
It appears that as coupling agent, UV lter, and pigment than 1.2% anti-microbial agent as fungicide would yield
were added into both types of panels their surface better properties of the samples. Initial data from the study
roughness increased due to not having well-developed would assist to develop WPC panel manufacture in Chile.
contact between wood-based material and plastic on the In further studies, manufacturing of the panels by
surface layers. (Fig. 9, Table 3). extrusion method with more than two particle and
ber percentages would be desirable to have a better
4. Conclusion understanding of panel properties. Also linear expansion,
tension parallel to the surface of the samples should be
In this work, particles and bers from radiata pine along tested to have more comprehensive information about the
with different chemicals as additives used to make samples.
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Fig. 9. Photographs taken from the cross-section of the samples on scanning electron microscope. (A). Sample with 60% particle without any additives.
(B). Sample with 60% particle with pigment and coupling agent. (C). Dry sample with 60% ber with no additive. (D). Water soaked sample with 60%
ber with no additive.