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AIR. 3541 Students from Long Term Classroom/ Integrated School Program & 4423
FIITJEE JEE (Advanced), 2017
CONCEPT RECAPITULATION TEST II
Paper 2
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
Students from All Programs have qualified in JEE Advanced, 2016
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has two sections: Section-A & Section-C.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
Enrolment No.
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Useful Data
PHYSICS
2
Acceleration due to gravity g = 10 m/s
CHEMISTRY
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Physics PART I
SECTION A
(One or More than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE is/are correct.
2L
(D) Ball hits the top of container at end Q after a time t =
3g
2. A non-conducting ring of mass m and radius R has a charge Q uniformly distributed over
its circumference. The ring is placed on a rough horizontal surface such that plane of the
ring is parallel to the surface. A vertical magnetic field B = B0t2 tesla is switched on. After
2s from switching on the magnetic field the ring is just about to rotate about vertical axis
through its centre:
2B0RQ
(A) Friction coefficient between the ring and the surface is .
mg
B RQ
(B) Friction coefficient between the ring and the surface is 0 .
2mg
(C) If magnetic field is switched off after 4s, then the angle rotated by the ring before
2B0Q
coming to stop after switching off magnetic field is .
m
(D) If magnetic field is switched off after 4s, then the angle rotated by the ring before
BQ
coming to stop after switching off magnetic field is 0 .
m
Space for rough work
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100F
6. In the given circuit, the AC source has = 100 rad/s. 100
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Paragraph type
This section contains TWO paragraphs. Based on each paragraph, there will be TWO
questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE
of these four option(s) is(are) correct.
1
Y sec 1
30
Z
(stable)
Initially the sample contains nucleus of X only and its population is N0 = 1020. Further,
the population of Y as a function of time is given by
N t
Ny t 0 x e y e x t
x y
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SECTION C
(One Integer Value Correct Type)
This section contains 8 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).
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Chemistry PART II
SECTION A
(One or More than One Options Correct Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE is/are correct.
1. Which of the following statement(s) is/are correct regarding the structure of XeF4?
(A) The hybridization of Xe is sp3d2
(B) The lone pairs occupy the axial positions of a tetrahedron
(C) Two types of bond angles are observed in the molecule
(D) The bond pair dipole moments cancel the lone pair dipole moments
HI
2. CH3OC2H5 Pr oduct s
Which of the following product(s) is/are formed in the above reaction?
(A) CH3OH (B) CH3I
(C) C2H5OH (D) C2H5I
3. Which of the following reaction(s) take(s) place during rusting of the surface of iron?
(A) Fe s Fe 2 aq 2e
(B) O 2 g 4 H 4 e 2H2O l
(C) 4Fe2 aq O2 g 4 H2O l
2Fe2O3 s 8H
(D) Fe2O3 s xH2O l Fe2O3 .xH2O
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4. O
O
Choose correct statement about the above compound?
(A) It reacts with CH3MgBr followed by hydrolysis to form a tertiary diol.
(B) It exhibits tautomerism.
(C) Oxidation of it with acidified permanganate solution followed by heating forms
cyclohexan-1, 4-dione
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8.
CaCO3(s)
CaO(s) + CO2 (g) Kp = 2 atm at 300 K
20 gram CaCO3(solid) is heated in a closed container of volume 1 litre at 300 K. Which
is/are the correct option(s)?
(A) On addition of small amount of CaCO3, pressure of CO2 will increase
(B) On increasing temperature, the decomposition of CaCO3 becomes faster
(C) Amount of CaO should decrease on addition of CaCO3.
(D) Equilibrium constant depends on temperature.
Paragraph type
This section contains TWO paragraphs. Based on each paragraph, there will be TWO
questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE
of these four option(s) is(are) correct.
The rate of chemical reactions are strongly affected by temperature. The rate of certain
reactions increases by 2 or 3 times by 10oC rise in temperature. The relation between rate
constant and temperature is given by Arrhenius equation.
k Ae Ea /RT
The constant A is called Arrhenius constant or pre- exponential factor. Taking logarithm of the
equation, we have
Ea
logk log A
2.303RT
The rate constant of a reaction is given as:
1.25 10 4 K
logk sec 1 14
T
Answer the following questions on the basis of the above write up.
9. The pre-exponential factor or frequency factor(A) of the reaction under consideration is:
(A) 10-14sec-1 (B) 1014 sec-1
(C) 14 sec-1 (D) ln14 sec-1
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10. At what temperature, the rate constant of the reaction is equal to the pre-exponential
factor?
1.25 10 4
(A) T = 0 K (B) T K
14
14
(C) T = K (D) T K
1.25 10 4
11. The tertiary alcohol in the above question is formed by the reaction of
O
(A)
PhCH2MgBr
Ph H
O
(B) PhMgBr
Ph CH3
O
(C) PhCH2MgBr
Ph CH3
O
(D) PhMgBr
Ph H
CH2Ph
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SECTION C
(One Integer Value Correct Type)
This section contains 8 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).
7. SiO2
HF
A H2O
HF
B
How many total number of atom(s) or species is/are present in one molecule of (B)?
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SECTION A
Multiple Correct Choice Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out of which only ONE OR MORE THAN ONE is/are correct
1. Let S = {1, 2, 3, 4,..,n} and f n be the number of those subsets of S which do not
contain consecutive elements of S, then
n n 1 n 2
(A) fn (B) fn 2fn 1
6
(C) fn fn 1 fn 2 (D) f4 8
8 3
3. Let f x x x tan x , where 0 x , then
9 6
(A) f ' x 0 (B) f " x 0
(C) f "' x 0 (D) f x 0
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6. Given that x1, x 3 are roots of the equation ax 2 4x 1 0 and x 2 , x 4 are roots of the
equation bx 2 6x 1 0 . If x1, x 2 , x3 , x 4 are in harmonic progression, then
(A) 3a b 1 (B) a 2 b2 73
1 1
(C) 2a 3b (D)
a b
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Paragraph type
This section contains TWO paragraphs. Based on each paragraph, there will be TWO
questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE
of these four option(s) is(are) correct.
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In a triangle if the sum of two sides is x and their product is y x 2 y such that
x z x z y , where z is the third side of the triangle.
11. Greatest angle of the triangle is
(A) 105o (B) 120o
(C) 135o (D) 150o
SECTION C
(One Integer Value Correct Type)
This section contains 8 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).
1. An urn contain 3 red balls and n white balls. Mr. A draws two balls together from the urn.
The probability that they have the same colour is 1/2. Mr. B draws one ball from the urn,
notes its colour and replaces it. He then draws a second ball from the urn and finds that
5
both balls have the same colour is . The possible value of n is_________
8
1, r (i 2aj k)
2 and r (a i a 2 j k)
3. If planes r (i j k) 3 intersect in a line,
then find the number of real values of a.
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4. The 20th term of an arithmetic sequence is log10 20 and the 32nd term is log10 32 . If
exactly one term of the arithmetic sequence is a rational number which in lowest form is
p
; p,q N then (p + q) = _____
q
1 1
1 2
6. If f : 0,1 R is a continuous function satisfying f x dx
0
f x2
3 0
dx , then the
1
reciprocal of f is __________
4
7. Any chord of conic x 2 y 2 xy 1 passing through origin is bisected at point (p, q), then
p q equals __________
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