Professional Documents
Culture Documents
de
Projekat:
Saradnja sa Naftnom industrijom Srbije
Collaboration with Petroleum Industry of Serbia
Project:
RiskNIS: Risk management and use of risk-based approaches
in inspection, maintenance and HSE analyses
of NIS a. d. plants
(http://www.risknis.risk-technologies.com/)
TECHNICAL REPORT
RBI STUDY
Gas Refinery Elemir (RGE)
Version 1.0,
Status: Draft
Risk before
Risk after
Stuttgart
March 2009
Contacts
Executive Summary
The overall proposed inspection plan for the equipment based on screening results (Table 10 API 581 qualitative risk
assessment results, for year 2009), shows overall reduction of almost 50% of equipment to be inspected pro year in
next 3 years.
On the other hand, about 10% of equipment has to be inspected more intensively with more adequate methods
and scope than it was practiced so far.
5 0 - 0%
4 D-101 D-102 2 - 2%
1 0 - 0%
A B C D E
CONSEQUENCES
Figure 1 Results of API Qualitative Analysis Component based applied on RGE equipment
5 0 - 0%
1 0 - 0%
A B C D E
CONSEQUENCES
Figure 2 Preliminary results of API quantitative (detailed) Analysis Component based applied on selected RGE
equipment
Table of Contents
Contacts 2
List of Acronyms.................................................... 9
Introduction......................................................... 10
Objective 10
Scope 10
Deliverables 10
METHODOLOGY .................................................... 11
RBI Methodology Overview .................................... 11
Preparation of Database ........................................ 11
HAZOP Study Procedure ........................................ 11
Identifying the Damage Mechanisms ....................... 15
Calculating the Likelihood of Failure ........................ 17
Calculating the Consequence of Failure.................... 18
Calculating the Risk .............................................. 18
Remaining Life Assessment ................................... 20
Developing an Inspection Plan ............................... 21
References .......................................................... 53
List of Figures
Figure 1 Preliminary results of API Qualitative Analysis Component
based applied on prioritization of pump purchase for
selected RNP units .............................................. 3
Figure 17 API 581 Qualitative risk matrix for component level, for
year 2009 ........................................................ 41
List of Tables
Table 1 HAZOP Guide Words and Parameters ..................... 14
Table 5 CUI for Carbon and Low Alloy Steels Inspection Categories
...................................................................... 22
Table 10 API 581 qualitative risk assessment results, for year 2009
...................................................................... 41
List of Acronyms
Acronyms referred in the document are given below. Explanation of these acronyms can
be found from the text, where it is referred. Symbols used in the document are explained
in the text.
Term Definition
API American Petroleum Institute
CoF Consequence of failure
MTBF Mean Time Between Failure
NFPA National Fire Protection Association, USA
NDT Non-destructive testing/inspection
P&ID Process and Instrumentation Diagram
PoF Probability of failure
QRA Quantitative Risk Analysis
RBI Risk Based Inspection: methods to plan, implement and evaluate
inspections using risk based approach
Introduction
Objective
The objective of the study was to assess the risk profile of the RGE equipment through the application of the Risk
based inspection methodology and to prioritise equipment for inspection. Moreover, the goal was to demonstrate the
applicability of the overall approach to the NIS units.
Scope
The scope of the RBI study covered all the equipment items and related piping as originally agreed prior to the project.
The scope of work covered the following activities:
1. Understanding the system
This includes activities like HAZOP analysis, review of design assumptions, process flow diagrams, P& IDs,
survey of all maintenance, inspection documents (location, nature and criticality of flaws, thickness
measurements, corrosion rates etc.), repair and modification records, operating conditions, PSV settings,
stream data, materials of fabrication, vessel coating and insulation details. Review of financial data including
cost of plant shut down and averages cost of process plant.
2. Preparation of Simplified Process Flow Diagrams (PFDs) with all data essential to the RBI analysis of the
equipment items.
3. Development of corrosion circuits and determination of expert corrosion rates.
4. Data entry and analysis using Steinbeis R-Tech iRIS-Petrol software.
5. Preparation of documentation of corrosion rates and assessment of damage mechanisms and mode of failure.
6. Review of inspection records.
7. RBI analysis and results checking.
8. Preparation of RBI analysis report.
Deliverables
The deliverables of the RBI project include:
1) Database of equipment for the process units studied.
2) RBI analysis report for the units include the followings:
a) Six (6) sets of process flow diagrams showing the basic information used in the analysis.
b) Inspection plan guidelines for selected high risk items based on a plan period agreed with RGE. This
consist of tables and reports indicating the overall risk, likelihood and consequence factors, the
recommended inspection methods and coverage for each equipment item and the active or
potential damage mechanisms identified per equipment item.
c) The assumptions and conclusions of the RBI analysis.
METHODOLOGY
Preparation of Database
The summaries of process description and PFDs for the entire plant were first reviewed to obtain a preliminary
understanding of the process and the equipment functions. The equipment and piping items were identified from the
PFDs. Each item was entered in the master workspace in process order. This database was supported by piping
specifications, equipment data sheets, process stream compositions, operating conditions and other relevant
documents.
The preparation of this database was an extensive process. The datasheets in Excel format were used to gather the
data.
The key data are also marked on the PFDs for easy reference.
2. Define the design intent of the node and the normal operating parameters.
3. Apply a HAZOP deviation (e.g. NO/LESS FLOW) to the node.
4. Identify all possible causes for the deviation.
5. Identify for each cause all possible consequences, without regard for the safeguards in place.
6. Identify all available safeguards to prevent the cause or to limit the consequences.
7. Recommend any new safeguards where judged necessary.
8. Repeat steps 4 to 7, using the next HAZOP deviation.
9. Repeat steps 3 to 8 until all HAZOP deviations have been applied to the node.
10. Select the next node to be studied, repeating steps 1 to 9.
Steps 3 and 4 are repeated until all the guide-words have been applied and discussed and the team is satisfied that all
meaningful deviations have been considered. The team then goes back to Step 1 and repeats the process for the next
section or node. Figure 3illustrates the normal workflow of a HAZOP study.
Table 1gives the typical list of parameters, associated guidewords and their interpretations.
When a recommendation was proposed, the risk was ranked based on consequences and frequency, using the
COMPANY Risk Ranking Matrix.
Select a P&ID
Select a node/section
Select a guideword
Record findings in
Identify the safety HAZOP worksheets
measures in place
Not sufficient
Recommend improvement
measures
Yes
Yes
More guideword?
No
Yes
More node?
No
No
Yes
More P&ID Completed
Deviations Interpretations
Guidewords Parameters
OTHER THAN FLOW The flow is not the product(s) intended (or wrong
grade/spec)
OTHER THAN SPECS & BREAKS Location of spec breaks wrt maximum pressure /
temp / etc
FAILURE SERVICES
PROBLEMS MAINTENANCE
REQUIREMENTS INSPECTION
AVAILABILITY ACCESSIBILITY
ABNORMAL OPERATIONS
SUPPLEMENTARY[1]
HIGH VACUUM
Deviations Interpretations
Guidewords Parameters
MORE VIBRATION
SOURCES IGNITION
VENTILATION LESS
RELIABILITY LOW
PROBLEMS SAMPLING
LOSS CONTAINMENT
PROBLEMS CONSTRUCTION
CONCERNS ENVIRONMENTAL
CONCERNS HEALTH
HIGH NOISE
HIGH RADIATION
HIGH VELOCITY
Continuous
improvement and INITIAL ANALYSIS AND PLANNING
management change Objectives, system, criteria
Acceptance
Hazard identification
Redefinition of the
scope of analysis
Feedback
DATA COLLECTION AND VALIDATION
RISK SCREENING
Selection of systems, equipments, and components
Determination of possible failure modes and consequences
Integrity related,
Integrity related Safety system related or Functionality related
Functionality related?
Apply Limit State Analysis and Reliability Index methods to calculate the
damage factors. Calculate inventories and consequences of failure
ACTION PLANS:
Inspect: Other:
Consider the age (Note - in this study a (5) years look ahead was made to give a risk profile for June 2012), this is to
identify equipment with risk that could exceed the inspection targets between the upcoming and the following plant
shut down).
When the likelihood of failure is being assessed, the calculation routine is based on the simple premise that unexpected
catastrophic failures occur when degradation happens faster than expected. The routine therefore looks at the what
if scenarios of the corrosion rate being either twice or even four times the predicted rate and calculates the likelihood
of failure compared with the operational conditions.
It also takes into account the current confidence in the condition based on the nature of the inspections previously
performed and their ability to characterise the extent and rate of the different damage mechanisms.
These factors are combined by the software to produce a value for the likelihood of failure for each damage
mechanism. This is expressed as a Likelihood Factor, which is a number to be applied to the generic failure frequency
of the particular item. If no damage mechanisms have been identified, the Likelihood Factor may be 0.5 indicating that
the component is 50% less likely to fail than the industry average for such components. If a severe damage
mechanism is found and the item has not been thoroughly inspected for some time the Likelihood Factor may be in the
thousands indicating that the component may be much more likely to fail than the industry average and that an
inspection is needed urgently.
The general approach is to address those items in the order of the decreasing Likelihood Factor, as indicated in Table 2.
Table 2 Proposed action for different category of Likelihood Factor
1<Likelihood Factor<10 Address these items last. Since values in this range
indicate a potential, but not necessarily severe, problem.
Action on these items may be delayed until all other
items have been addressed or until a convenient time,
such as a scheduled shutdown within the time frame
considered in the RBI analysis.
The consequences are calculated taking into account the nature and amount of the fluid released. The amount and
rate of fluid released depends upon factors such as the size of the hole, the fluid viscosity and density and the
operating pressure. The rupture of a large diameter high-pressure pipe or vessel obviously has a different
consequence than a pinhole leak at a small diameter low-pressure pipe and this method quantifies that difference.
Each piece of equipment or piping has a certain generic (industry average) probability of failing either by a pinhole type
leak, a medium size hole, a large hole or a rupture. The consequence of each type of failure is calculated and combined
with the probability for that failure; to calculate the overall risk associated with each piece of equipment.
Consequence of failure
Understanding the two-dimensional aspect of risk allows new insight into the use of risk as an inspection prioritization
tool.
The consequences are calculated based on fluid properties, temperatures, pressures and inventory.
An analysis is then performed considering important failure mechanisms for each piece of equipment to determine if it
is more, or less likely to fail than average. The result is then used to modify the likelihood of failure in this study. The
consequence and the likelihood are then combined to give a risk value for each piece of equipment.
A high-risk item may be high risk due to either a high likelihood of failure or a low consequence of failure or conversely
a high consequence of failure and a low likelihood of failure.
An inspection program can only influence the value of the likelihood of failure, not the consequence. No matter how
much inspection is performed the consequence is unchanged.
Therefore, where a high-risk item is driven by the consequence value, other actions such as more precise analysis such
as Quantitative Risk Assessment and upgrading of mitigation system may be considered.
The overall ranking is then done according to the RIMAP risk matrix, shown in the Figure 6. Alternatively, the risk can
be represented in the NIS risk matrix, as shown in Figure 7.
<1
Very probable
year
>110-1 5 Very high risk
1-5 110-1 to
Examples of PoF scales
5-10 110-2 to
Possible 3 Medium risk
years 110-3
10-50 110-3 to
Unlikely 2 Low risk
years 110-4
CoF category
ptive
MTBF
PoF
Descri
A B C D E
Limited impact on Serious impact on
Warning issued Warning issued Temporary health
Health (Long term visibility) public health, threat public health, life
No effect Possible impact problems, curable
of chronical illness threatening illness
No aid needed First aid needed Temporary work Permanent work
Safety (Instant visibility) Fatality(ies)
Work disruption No work disability disability disability
Impact (e.g. spill) Minor impact On-site Off-site damage
Environment Negligible impact
contained (e.g. spill) damage Long term effect
Security None On-site (Local) On-site (General) Off site Society threat
Image Loss None Minor Bad publicity Company issue Political issue
using the Design Corrosion Allowance taken from design documents (which is a default option)
using User-defined Minimum Thickness taken from local codes or other considerations such as structural
stability.
PR
t min
E jo int S 0.6 P
and
in which,
Steinbeis R-Tech iRIS-Petrol also provides an alternative calculation for remaining life known as the probabilistic
remaining life. It is based on a weighted average of the nominal remaining life for all possible thinning scenarios. For
internal thinning, 3 states are assumed and the probabilistic remaining life equation is as follows:
3
Probabilis tic Remaining Life ( Nominal Remaining Life)i X Pi
i 1
Whereby
A more complex equation is used when external thinning is included or where liner is involved.
Since an inspection needs to be tailored to fit the particular type of damage expected at a particular piece of
equipment, the key considerations are:
As agreed with NIS, inspection planning targets are adopted for this inspection planning.
For each equipment item, the driving damage mechanism is identified for inspection. Based on the inspection planning
targets, the Likelihood Factor for the relevant driving damage mechanism is then reduced by assigning appropriate
number and effectiveness of inspection. This is generated by software as inspection.
The actual inspection scope to satisfy the assigned effectiveness is then developed based on API inspection guideline
for each relevant damage mechanisms, as given in the tables below.
Table 3 Effectiveness of Inspection for General Thinning
Inspection
Intrusive Non-intrusive
Effectiveness
Inspection Inspection
Category
Inspection
Intrusive Non-intrusive
Effectiveness
Inspection Inspection
Category
Usually Effective internals removed), and spot external coverage (automated or manual), or
ultrasonic thickness measurements profile radiography, or external spot
thickness (statistically validated)
Inspection
Intrusive Non-intrusive
Effectiveness
Inspection Inspection
Category
B 100% visual examination (with partial 20% coverage using automated ultrasonic
Usually Effective removal of the internals) including scanning, or 50% manual ultrasonic
manways, nozzles, etc. and thickness scanning, or 50% profile radiography in
measurements areas specified by a corrosion engineer or
other knowledgeable specialist
Table 5 CUI for Carbon and Low Alloy Steels Inspection Categories
Inspection
Insulation Insulation Not
Effectiveness
Removed Removed
Category
Remove >95% of the insulation
A For the total surface area:
Highly Effective AND
>95% profile or real-time
visual inspection of the exposed radiography
surface area with follow-up by UT, RT
or pit gauge is required
B For the total surface area: For the total surface area:
Usually Effective
>95% external visual inspection prior >95% external visual inspection
to removal of insulation
Inspection
Insulation Insulation Not
Effectiveness
Removed Removed
Category
AND AND
remove >60% of total surface area of follow-up with profile or real
insulation including suspect areas time radiography of >60% of
total surface area of insulation
AND
including suspect areas
visual inspection of the exposed
surface area with follow-up by UT, RT
or pit gauge as required
C For the total surface area: For the total surface area:
Fairly Effective
>95% external visual inspection prior >95% external visual inspection
to removal of insulation
AND
AND
follow-up with profile or real
remove >30% of total surface area of time radiography of >30% of
insulation including suspect areas total surface area of insulation
including suspect areas
AND
visual inspection of the exposed
surface area with follow-up by UT, RT
or pit gauge as required
>95% external visual inspection prior
D For the total surface area:
to removal of insulation
Poorly Effective
>95% external visual inspection
AND
AND
remove >5% of total surface area of
insulation including suspect areas follow-up with profile or real
time radiography of >5% of
AND
total surface area of insulation
visual inspection of the exposed including suspect areas
surface area with follow-up by UT, RT
or pit gauge as required
<5% insulation removal and inspection
E No inspection or ineffective
Ineffective OR inspection technique or <95% visual
inspection
no inspection or ineffective inspection
technique
D For the total surface area: For the total surface area:
Poorly Effective
>5% dye penetrant or eddy >30% automated or manual
current testing with UT follow-up of ultrasonic scanning
all relevant indications
OR
>60% radiographic testing
E Less than D effectiveness or no Less than D effectiveness or no
Ineffective inspection or ineffective inspection inspection or ineffective inspection
technique used technique used
A Visual inspection of >95% of the exposed surface area with follow-up by UT, RT or
Highly Effective pit gauge as required
B Visual inspection of >60% of the exposed surface area with follow-up by UT, RT or
Usually Effective pit gauge as required
C Visual inspection of >30% of the exposed surface area with follow-up by UT, RT or
Fairly Effective pit gauge as required
D Visual inspection of >5% of the exposed surface area with follow-up by UT, RT or
Poorly Effective pit gauge as required
E Visual inspection of >5% of the exposed surface area with follow-up by UT, RT or
Ineffective pit gauge as required
E Visual
Ineffective
7. Data collection and assessment performed by NIS RGE team, extended with the
representatives of NIS, RNP and RNS in two sessions:
a. October 2008
b. December 2008
Figure 8 Web-based tool implementing API 581 Qualitative RBI Workbook (English)
List of inputs
1. Input PFD diagrams from RGE
2. Description of the process and systems as discussed during the Workshop Dec. 2007
4. Detailed data collection for the selected equipment types October and Dec. 2008
Outputs: refined gas, Propane 45 t/day, n-Butane 34 t/day, iso-Butane 38 t/day, Debutanised gasoline 60 t/day,
process oil 5 t/day and Gasoline Gt 4,2 t/day
Design life time- not given in the project documentation, most of the equipment has been designed according to the
ASME Section VIII, edition valid at the time of construction. This is equivalent to approx. ASME Section VIII, Division 1
according to the current standard edition. Re-qualification of the equipment to the latest code of construction (ASME)
has not been performed. Analysis of the design and qualification to the current regulation of pressure vessels in Serbia
has been performed on several occasions, mostly by the local Universities.
Temperature range: 36 in summer to -30C in winter, corresponding to the -30 to -5 class in API 581
Process stability: from 0-1 unplanned shutdowns per year, from 0-1 planned shutdowns per year. Process is very
stable
Detection systems: Process instrumentation i.e. high level of liquid propane detector, regulation and automation
system for operating parameter maintenance, security system AMOT for automatic shutdown of compressors,
high concentration of hydrocarbon detectors, 24 hour human supervision of the process parameters with
hand logging and hourly walk-around, local detectors, visual detection.
Insulation systems: Most of the insulation systems are manually activated, on the spot. The only exception is the
AMOT system for automatic shutdown of the compressors, AMOT, that can automatically shut down the compressor in
cases of high number of rotation, high level registered in D-1, increased vibrations, low pressure of the fluid (oil), high
temperature of cooling water.
Fire-fighting equipment: Portable fire-fighting equipment S-9, S-250,CO2-10,CO2-30, water cannons with foam
Temporary repairs and signs of deterioration: some signs of deterioration are present, however, they are logical
consequence of the overall equipment age. Temporary repairs and repairs with inappropriate materials have been
made during the 1990s, mainly due to the fact that it was not possible to obtain better equipment
Change of the working fluid instead of the proprietary oil, refining-generated oil is used
History of incidents:
Propane leakage on the compressor, and auto-ignition of the fluid. Apart from material damage, there was no
other damage to the people or environment mainly due to an early detection of the incident and fast fire
extinguishing
Leakage of propane, butane and gasoline from the underground lines due to the corrosion of the underground
lines. Consequences propane and butane was easily spotted, and quickly fixed. Gasoline leakage was
discovered at a relatively late stage, due to the fact that it did not evaporate. Soil remediation has been done
by pumping up the gasoline from the soil, the whole operation lasted 2,5 months
Problems at the furnace firing the firing process is manual and can in some cases lead to the explosive
concentrations inside the furnace and consequent injury of the person performing firing. So far no serious
injuries have happened.
Safety and relief valves: the process is inherently clean, there is a potential for some corrosion mainly from the
outside. No significant fouling of the RV has been registered, however, in the general process of control, some of the
valves have been found not to be functioning.
Fluid information:
Natural and refined gas - 3,8-17,0% vol explosive concentration, Auto ignition temperature 640-645C, gas
with no smell or color, flammable and explosive, in higher concentration might cause suffocation. Danger
mark 23, F+, Risk mark R12, information marks S9,S16,S36/37/39
Approx. fluid composition: methane ~ 93%, ethane ~ 2,50%, propane ~ 0,30%, butane ~0,03%, other
carbon and nitrogen maximum 3,50%,mostly containing fractions C1-C4, daily throughput of 1200000 m3 per
day (or 500t)
Propane - 2,1-9,5% vol explosive concentration, Auto ignition temperature 465C, gas with no smell or color,
flammable and explosive, in higher concentration might cause suffocation. Danger mark 23, F+, Risk mark
R12, information marks S9,S16,S36/37/39
Present quantities on site:
Butane - 1,5-8,5% vol explosive concentration, Auto ignition temperature 365C, gas with no smell or color,
flammable and explosive, in higher concentration might cause suffocation. Danger mark 23, F+, Risk mark
R12, information marks S9,S16,S36/37/39
Present quantities on site:
Debutanized gasoline - 1,3-7,6% vol explosive concentration, Auto ignition temperature 257C, liquid with no
color, flammable and polluting for soil and water. Danger mark 33 Xn,F, Risk marks
R11,R22/21,R52/53,R58,R65, information marks S36/39,S45,S61,S62
Present quantities on site:
Heavy gasoline - 1,3-8,0% vol explosive concentration, Auto ignition temperature 205-220C, liquid with no
color, flammable and polluting for soil and water. Danger mark 33 Xn,F, Risk marks
Methyl-alcohol 7,3-36% vol explosive concentration, Auto ignition temperature 455C, liquid with no color,
flammable and poisonous. Danger mark T,F, Risk marks R11 R11,R23/24,25, information marks S-2,7,16,24
Present quantities on site:
Figure 11 shows the overall PFD diagram for RGE, whereas Figure 12, Figure 13 and Figure 14 show the same diagram
in more readable form.
br. Naz iv
1 P os lovna z grada
2 Laboratorija
3 S tara portirnic a
4 S tanic a z a om ek avanje vode
5 M ehani ars k a radionic a
6 G enerators k a z grada
7 Zgrada arhive
8 Ras hladne k ule
9 Ulaz na ahta
10 A uto punili te
11 P P baz en - velik i
12 P P c entar
13 P P baz en - m ali
14 P roiz vodni rez ervoari
15 Trafo s tanic a
16 M agac in
17 M agac in
18 Hangar
19 B ravars k a radionic a
20 S prem i te z a tehni k e gas ove
21 E lek tri ars k a i M RT radionic a
22 G ara a
23 P ortirnic a I
24 portirnic a II
25 P os trojenje
26 M as eni m era i protok a
27 P lanirana lok ac ija nove bak lje
D-300 D-101 T-1 T-101 T-9 D-16 E-102 E-2 E-1 A/B E-120 D-120 D-102 T-2 E-104 E-3 D-1 E-5 D-104 E-103 E-6 A/B E-7 D-5 D-103 E-15 D-121 D-4 E-116 E-4 C-1,2 A/B C-102 D-122 F-1; F-201 E-24 A/B T-3 E-9 E-11 E-10 E-12 E-16 E-17 D-6 E-18 D-7 E-20 A/B T-8 E-21 E-22 E-23 D-8 F-302
F-301 E-110 E-101 A/B SC-1 T-4 D-2 T-7 E-19
TROFAZNI SEPARATOR DEHIDRATACIONA DEHIDRATACIONA KOLONA ZA SEPARATOR PROPANSKI PROPANSKI PROPANSKI SEPARATOR SEPARATOR APSORBER PROPANSKI PRIHVATNI IZMENJIVAC SEPARATOR PROPANSKI PROPANSKI PRIHVATNI PRIHVATNI VODENI CENTRIFUGALNI SEPARATOR ZA PRIHVATNA VODENI VODENI KOMPRESORI KOMPRESOR KOALESCER PEC DEETANIZER RIBOJLER KONDENZATOR IZMENJIVAC RIBOJLER PRIHVATNA IZMENJIVAC PRIHVATNA POSUDA ZA KONDENZATOR DEIZOBUTANIZER RIBOJLER VODENI KONDENZATOR PRIHVATNA FILTER ZA
FILTER ZA IZMENJIVAC IZMENJIVAC IZMENJIVAC IZMENJIVAC IZMENJIVAC PROPANSKI IZMENJIVAC IZMENJIVAC DESTILATOR PRIHVATNA DEBUTANIZER RIBOJLER
SEPARATOR POSUDA KOLONA POSUDA HLADNJAK HLADNJAK HLADNJAK POSUDA POSUDA HLADNJAK SUD TOPLOTE POSUDA HLADNJAK HLADNJAK SUD ZA SUD ZA PARE HLADNJAK RABLJENO ULJE POSUDA ZA HLADNJAK HLADNJAK WEIR KLARK COOPER-BESSEMER TOPLOTE POSUDA ZA TOPLOTE HLADNJAK POSUDA ZA SIROVI
GASNI TOPLOTE KOLONA SUENJE TOPLOTE TOPLOTE TOPLOTE TOPLOTE SEPARATOR HLADNJAK TOPLOTE TOPLOTE POSUDA SMEU N-BUTANA I
PROPAN PROPANA PROPAN PROPAN IZO-BUTAN GAZOLIN
KONDENZAT KONDENZATA IZO-BUTANA
1
E-103 PRC
PRC
151 3
LC
131 E-20A E-20B
HCV
150
E-12 E-18
HO HO E-1A E-120 I C-102 II 1
E-104
204 T-3 FRC PRC 9 TRC
1 1 1 E-6A FRC
6 9 4 10
KA T -3 PC T-6
E-110 5 E-24B E-9
15
HIC
PRC
PREMA TS 150
PRC
T-7 8
1
PC
301 T-101 E-2
PC
TIC 18
16
TS FRC
13
7
E-2 E-3 4B E-110 150 10
T-1 E-7
6 TIC
6
25
PCV FRC
301B E-6B E-11 FRC 13
19 29
10 LC od C-2A C-1A C-2B C-1B F-201 11
T-8
PCV
D-120 151
D-104 LC
E-2
23
19
6 208
301A C3 E-3 24
CW FRC
C3 C3 E-7 7
LC LC 26
E-102 35 D-8
1 154 FIQ
E-7 C-2A C-1A C-2B C-1B E-116 T-4 D-7
102
T-2 E-3 D-2 F-1 35 D-6 E-22
PCV
24
E-4 29 30
LC
10
OD/PREMA
PRC CW CW TRC
PREMA E-5
152 TRC 9
C-1A/B 8
UV
154
E-101A E-5
C3 C3
D-101 od E-4
TRC
E-19 E-21
LC LC C3 5
2 152 TRC CW 35
3 E-10 LC
LI LC
D-103 E-15 8
LC
101 LC LC
D-16 19 19
13
3 153
LC
E-101B LC CW CW
LG
155
SC-1
LG D-121 D-4 LC 11
7
GS ELEMIR
156
20 5 LC
LI TRC SV TRCAH
129
LCV
LC
D-1 6
7 7 160
101 D-102 114 TSH
163 FRC
E-102 FRC
FS
8
SV
6
P RCA
160
14
5
LS
157
FRC
PREMA E-2 PREMA E-3 PREMA E-7 8
TRC PRIHVATNA POSUDA ZA RABLJENO ULJE
LOIVI GAS
128 C3
KA D -9
103
GAS
AS
150
FIQ
D-122 NORMALNI
IZOBUTAN
LCV BUTAN
OD
101 F-302 PS-4 GAZOLIN PROPAN
D-9 SMEA SMEA
U PRELIVNI PREMA PENTANA P-9A/B BUTANA
GR-1/GR-102
OD E-25
P-120A/B P-1A/B/C P-11 P-7A/B P-8A/B
AHT P-2A/B P-4A/B/C P-5A/B
D-300 LAH
301
LAL
301
LIC
301 P- 30
F-301
SIROVI GAZOLIN IZ
PROIZVODNIH
REZERVOARA
Legenda:
24.08. 2006
Propan U PRELIVNI
D-27A
N-butan AHT Jain/Subotin
Izobutan
Gazolin
Prirodni gas
S.Josipovic
Preradeni gas
A.Ilic
Apsorpciono ulje Projektni zadatak za izr. URP
Kondezat ugljovodonika
Toplo ulje rekonstr. sist. za prikupljanje i spaljivanje
Rashladni propan
Bogato ulje
fluida u pogonu za proizv. NTG El.
Rashladna voda
NIS Naftagas
TEHNOLOKA EMA POGONA TNG
TEG
Loivi gas 1
Pogon za proizv. NTG ELEMIR
http://www.risknis.risk-technologies.com
No safety problem,
Feed entrance shut down or Two Safety
1 Flow Less Less Gas Supply FALSE
to D-300 continuation valves on D-300
depending on flow
PV 401 is an
overflow valve and
Feed entrance Supply changes, will mitigate Two Safety
5 Composition Less TRUE
to D-300 Less C1-C2 Gas increase of level. valves on D- 300
Storage tank D-
27A.
Filter has to be
Feed entrance Filter in F-301 cleaned. Indication: Two Safety
6 Pressure Higher TRUE
to D-300 dirty. . Pressure increase valves on D- 300
continuously
Technical discussions
Technical problem 1
On the top of column T-5 sometimes a valve has to be opened. In some cases the gas (Decane) ignites and a flame
appears on the top of the valve. In this case the valve will be closed again.
Discussion: The temperature of the gas is 260 0C. There are two possible ignition sources. The first possibility is
electrostatic ignition. The second possibility is an ignition by hot surfaces. More probable is the ignition by a hot surface.
The gas will heat up the surface of the gas. Autoignition temperature of Decane is about 210 0C. By turbulence at the
end of the valve an explosive air/Decane mixture will be formed which ignites at the hot surface and lead to the flame.
Technical solution: This has not been discussed during the meeting. A possibility to mitigate the formation of an
explosive air/Decane mixture is to use a three way valve instead of the existing one. The third line will be connected to
a steam line. Both lines have to be opened instead of only the Decane line. This will have two effects. The surface will
be cooled down under the autoignition temperature and the explosive atmosphere will be inerted. Therefore an ignition
on the surface will not took place.
Technical problem 2
In combination with a pressure drop it may be that there is no liquid phase of Decane at the bottom of T4 (distillation
unit). This will lead to a gas flow to the connected pumps instead of a liquid flow. The gas will be ignited in the pumps.
Same problem will arise if no cooling is available for the pumps (will be cooled by water and cold oil). Normally two
pumps are in operation and one is stand by. A flow indicator for Decane is responsible for the flow of the cooling liquids
to the pumps.
Discussion: The reason for the ignition is the hot surface of the pumps where an air/Decane mixture will be ignited.
Technical solution: This has not been discussed during the meeting. A possible solution is as first a temperature
measurement at the pumps. In the line between distillation T4 and pump a valve can be integrated. This has to be
opened if the flow indicator for Decane and the temperature indicator at the pump indicate that there is no flow of
liquid Decane. The open line can be connected to the flare. The valve can be closed again if the flow indicator gives a
signal for liquid Decane flow.
Technical problem 3
Once per year the gas pipelines outside the establishment will be cleaned. Different kind of liquids and dusts has been
accumulated over the period of one year. The Naftagas plant is responsible for the collecting of these wastes. The
waste is delivered by a pressure wave through the incoming line for gas and is collected in the separator D-300. The
technical problem is twofold. In the loop1 discussed during the Hazop analysis a pressure surges occur (e.g. water
hammer, cavitational hammer). These pressure surges can lead to damages of plant's equipment (valves, pumps, pipe
bends) up to leakage of the pipe system. After the cleaning the gaseous line will be opened again. Again pressure
surges occur and parts of the equipment can be obstructed completely or partly by remaining particles. This is actual
the case for the heat exchanger E-110.
Discussion: There was only a general discussion on the hammer effect on the lines where the liquid phase is in. A more
detailed discussion was about the pressure wave which took place when the gaseous line will be reopened. As the heat
exchanger is not really working at the moment based on pollution with dust particles the questions raised up what can
happen furthermore in other parts of the plant.
It has been proposed not to concentrate on the possible damages and instead to concentrate of a mitigation of the
pressure wave. At the moment a valve in a 12 inch line with a 3 inch pipepass will be opened, It has been proposed to
include another valve in a 6 inch line with a 2 inch bypass to reduce the pressure wave.
The typical scenarios for the origin of pressure surges are fast closing valves triggered by the breakdown of auxiliary
power and fast acting control devices. The fast deceleration of the liquid results in high pressure surges upstream the
valve, because kinetic energy is transformed into potential energy. This effect is called water hammer that is explained
by the following example. In a horizontally installed 500 m long pipeline of the size DN 200 which transports water with
a velocity of 3 m/s at ambient temperature, the pressure increases by a fast closing valve from a stationary pressure of
6 bar up to 40 bar. Hereby the forces induced to pipe supports exceed the design criteria from 1-5 kN to 125 kN. Due
to liquid inertia, the transported liquid continues to flow downstream the valve with the initial speed, the pressure
decreases and a large expanding vapour bubble is formed directly downstream the valve. The pressure falls up to
saturation pressure of the liquid and is thus lower than the pressure in the system. Thereby the liquid stream is
decelerated and finally accelerated towards the closed valve (back flow). As a result of fast re-condensation of the
vapour bubble, the liquid flows against the closed valve and is stopped rapidly. The resulting pressure surge is referred
to as cavitational hammer. The amplitude of the first cavitational hammer downstream the valve is nearly as high as
the amplitude of the first water hammer upstream the valve.
Well-known methods for the prevention of water hammer in pipeline systems are e.g. the application of air vessels,
surge shafts, bladder accumulators, as well as the prolongation of closing and opening times of valves. The latter is the
easiest and the most favourable method. Due to technical and legal requirements for pipeline operation within the
chemical industries and power plants it is not always possible to decelerate the closing process undefined.
Air vessels, surge shafts or bladder accumulators are used if the pipeline system is not designed on the same level.
These applications are installed upstream the closing valve in its immediate proximity. When shutting off the medium
flows in to the loft and is braked by this.
Another possibility is the expansion of valve gears with facilities which decelerate the closure as soon as the last third
of the flow cross section is nearly reached. These can be dampers (often used with swing check valves) or
programmable positioners..
Technical problem 4
There is a leakage in the product lines C3 and C4 to the tanks. As the lines are underground the leakage and the size
of the leakage can not be detected. There is no leak detection system installed.
Discussion: Leakage is visible by bubbles on the ground if it is raining and by parts of non growing grass.
Technical solution: This has not been discussed during the meeting. As the amount of gas is unknown there is the
hazard of an explosion. The only possible solution is to repair or to exchange the lines or to build new lines on the
ground and to close the old ones.
Technical problem 5
There is a compressor in use where gaseous Propane will be compressed from 1.7 to 13-15 bars. There are two
problems. The first problem is in the case of a leakage in the compressor (Jet fire, explosion). Hot surfaces near by
have a temperature of 500 0C. The volume of the compressor is about 0.5 cbm. The second problem may occur if
liquid propane flows into the compressor. This will normally be mitigated by a measurement of gaseous and liquid
phase in the separator before. If this is not working an explosion is possible.
Technical solution: There will be possibilities by using quick closing valves. This will mitigate the flow of liquid Propane
to the compressor. Further technical specification possible but not done.
The results are given in the table below and shown on Figure 16.
Table 9 Management System Evaluation results with audit comments
10. Emergency Response 65 51 40 Not all elements needed for safety report
1. Size of the refinery it is rather small compared with other refineries or other units that are supposed to be
benchmarked by the same methodology
3. On the other hand, the process fluids (natural gas, propane, butane, gasoline) are both explosive and
flammable, therefore giving the C consequence class
4. The age of the equipment and the history of damage mechanisms result in the likelihood ranking of 3.
4
L
I
K
E
L RGE-1 Procesno
3
I postrojenje
H
O
O
D
2
A B C D E
CONSEQUENCES
Figure 17 Risk matrix showing the position of the RGE in qualitative unit analysis matrix
The preliminary matrix for qualitative analysis is shown on Figure 18. The risk assessment results are shown in Table
10.
According to the ranking in the risk matrix, the inspection plan can be constructed, for next two years. According to the
risk assessment, the equipment having high and medium high risk should be inspected at least once a year.
Furthermore, for items with high risk, it is recommended to increase the inspection efficiency from class D (spot
testing) to class C, in order to have better risk control.
For the equipment that has annual maintenance tasks (heat exchangers cleaning, filters, condensers), the same
inspection interval has been maintained (i.e. each year), although according to the risk ranking this interval might be
increased. This is in line of maximization of the effort invested, i.e. to use the opportunity to inspect the equipment
when normal maintenance tasks are done.
The resulting inspection plan will result in increase of inspection on equipment identified as critical (6 pieces of
equipment), while decreasing the number of equipment to be inspected each year (i.e. in 2009 from 99 to 51).
5 0 - 0%
4 D-101 D-102 2 - 2%
1 0 - 0%
A B C D E
CONSEQUENCES
Figure 18 API 581 Qualitative risk matrix for component level, for year 2009
Table 10 API 581 qualitative risk assessment results, for year 2009
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
trofazni Pressure
D-102 separator vessel 1969 2009 High 2 0.5 1 1 1
ulazni
T-1 separator Column 1962 2009 High 2 0.5 1 1 1
kolona za
T-101 suenje gasa Column 1988 2009 High 2 0.5 1 1 1
apsorpciona
T-2 kolona Column 1962 2009 High 2 0.5 1 1 1
preista
T-5 posnog ulja Column 1962 2009 High 2 0.5 1 1 1
Pressure Medium
D-101 separator vessel 1962 2009 High 4 1 1 1 1
Pressure Medium
D-1 prihvatni sud vessel 1962 2009 High 5 1 1 1 1
Medium
T-3 deetanizer Column 1962 2009 High 5 1 1 1 1
Medium
T-4 Column 1963 2009 High 5 1 1 1 1
Medium
T-6 depropanizer Column 1962 2009 High 5 1 1 1 1
Medium
T-8 deizobutanizer Column 1962 2009 High 5 1 1 1 1
Medium
T-9 Column 1962 2009 High 5 1 1 1 1
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
KOMPRESORS Pressure
C1A/B (potis) KE BOCE vessel 1962 2009 Medium 7 2 1
KOMPRESORS Pressure
C1A/B (usis) KE BOCE vessel 1962 2009 Medium 7 2 1
KOMPRESORS Pressure
C2A/B (potis) KE BOCE vessel 1962 2009 Medium 7 2 1
KOMPRESORS Pressure
C2A/B (usis) KE BOCE vessel 1962 2009 Medium 7 2 1
Pressure
D-103 meusakuplja vessel 1962 2009 Medium 7 2 1
trofazni Pressure
D-104 separator vessel 1962 2009 Medium 7 2 1
Pressure
D-11 posuda vessel 1962 2009 Medium 7 2 1
Pressure
D-111 posuda vessel 1962 2009 Medium 7 2 1
Pressure
D-112 posuda vessel 1962 2009 Medium 7 2 1
Pressure
D-12 posuda vessel 1962 2009 Medium 7 2 1
Pressure
D-120 separator vessel 1962 2009 Medium 7 2 1
Pressure
D-121 separator vessel 1962 2009 Medium 7 2 1
Pressure
D-122 separator vessel 1962 2009 Medium 7 2 1
trofazni Pressure
D-16 separator vessel 1962 2009 Medium 7 2 1
sakuplja Pressure
D-2 refluksa vessel 1962 2009 Medium 7 2 1
Pressure
D-27A rezervoar vessel 1963 2009 Medium 7 2 1
Pressure
D-27D rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-27F rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28A rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28B rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28C rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28D rezervoar vessel 1962 2009 Medium 7 2 1
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
Pressure
D-28E rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28F rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-28G rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-29A rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-29B rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-29C rezervoar vessel 1962 2009 Medium 7 2 1
Pressure
D-4 prihvatni sud vessel 1962 2009 Medium 7 2 1
Pressure
D-5 ispariva vessel 1962 2009 Medium 7 2 1
sakuplja Pressure
D-6 refluksa vessel 1962 2009 Medium 7 2 1
sakuplja Pressure
D-7 refluksa vessel 1962 2009 Medium 7 2 1
sakuplja Pressure
D-8 refluksa vessel 1962 2009 Medium 7 2 1
Pressure
D-9 prihvatni sud vessel 1962 2009 Medium 7 2 1
Pressure
D-27B rezervoar vessel 1962 2009 Medium 8 2 1
Pressure
D-27C rezervoar vessel 1962 2009 Medium 8 2 1
Pressure
D-27E rezervoar vessel 1962 2009 Medium 8 2 1
Boiler -
Furnace
Tubes for
Fired
E-10 rebojler Heater 1962 2009 Medium 8 2 1
propanski
E-102 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
propanski
E-103 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-104 izmenjiva lote Exchanger 1962 2009 Medium 8 1 1 1 1
Boiler -
Furnace
E-11 predgreja 1962 2009 Medium 8 2 1
Tubes for
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
Fired
Heater
Heat
E-110 izmenjiva Exchanger 1962 2009 Medium 8 1 1 1 1
Heat
E-113 izmenjiva Exchanger 1962 2009 Medium 8 1 1 1 1
Heat
E-116 izmenjiva Exchanger 1962 2009 Medium 8 1 1 1 1
kondenzator
E-12 para Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-120 Exchanger 1962 2009 Medium 8 1 1 1 1
vodeni
E-13 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-14 izmenjiva lote Exchanger 1962 2009 Medium 8 1 1 1 1
kondenzator
E-15 propana Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-16 predgreja Exchanger 1962 2009 Medium 8 1 1 1 1
Boiler -
Furnace
Tubes for
Fired
E-17 rebojler Heater 1962 2009 Medium 8 2 1
kondenzator
E-18 para Condenser 1962 2009 Medium 8 1 1 1 1
Boiler -
Furnace
Tubes for
Fired
E-19 rebojler Heater 1962 2009 Medium 8 2 1
propanski
E-2 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
kondenzator
E-20B para Condenser 1962 2009 Medium 8 1 1 1 1
Boiler -
Furnace
Tubes for
Fired
E-21 rebojler Heater 1962 2009 Medium 8 2 1
vodeni
E-22 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
kondenzator
E-23 para Condenser 1962 2009 Medium 8 1 1 1 1
propanski
E-24/A hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
propanski
E-24/B hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-25 izmenjiva lote Exchanger 1962 2009 Medium 8 1 1 1 1
propanski
E-3 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
vodeni
E-4 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Heat
E-5 izmenjiva lote Exchanger 1962 2009 Medium 8 1 1 1 1
Heat
E-6A/B izmenjiva lote Exchanger 1962 2009 Medium 8 1 1 1 1
propanski
E-7 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
vodeni
E-8 hladnjak Condenser 1962 2009 Medium 8 1 1 1 1
Boiler -
Furnace
Tubes for
Fired
E-9 meubojler Heater 1962 2009 Medium 8 2 1
Heat
E-101/A izmenjiva lote Exchanger 1963 2009 Low 10 1 1 1 1
Heat
E-101/B izmenjiva lote Exchanger 1963 2009 Low 10 1 1 1 1
Heat
E-1A/B izmenjiva lote Exchanger 1962 2009 Low 10 1 1 1 1
kondenzator
E-20A para Condenser 1962 2009 Low 10 1 1 1 1
Filter sa
aktivnim
FT-104 ugljem Filter 1962 2009 Low 10 1 1 1 1
Hidroforska Other
HP-1 posuda Equipment 1962 2009 Low 10 3 1
Hidroforska Other
HP-2 posuda Equipment 1962 2009 Low 10 3 1
Jono Other
JI-1 izmenjiva Equipment 1962 2009 Low 10 3 1
Jono Other
JI-2 izmenjiva Equipment 1962 2009 Low 10 3 1
Recomme Recommen
nded ded
Servic
Inspection Inspection
Componen e Evaluati
Name Description Risk Interval Interval 2009 2010 2011
t Type Start on Date
(Class A (Class D
Date
inspection inspection
type) type)
Peani filter-
PF-2 bona filtrac. Filter 1962 2009 Low 10 1 1 1 1
Other
SP-1 Posuda za so Equipment 1962 2009 Low 10 3 1
Total to be inspected: 51 94 56
5 0 - 0%
1 0 - 0%
A B C D E
CONSEQUENCES
Figure 19 Preliminary results of API quantitative (detailed) Analysis Component based applied on selected RGE
equipment
Presented results so far have DRAFT status; further refinement is planned for the level
of detailed analysis in order to obtain results that are acceptable for plant personnel.
References
[1] Contract No: 45/609 of September 8, 2006
[2] API PUBL 581, Risk-Based Inspection Base Resource Document, 2000 Edition
[3] CEN CWA 15740 RIMAP, 2008