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* 1: Identification
1.1 Product identifier
Trade name: Penetrant DP-50
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture Penetrant
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Sherwin Incorporated
5530 Borwick Ave
South Gate, CA 90280
Phone: (562) 861-6324
Fax: (562) 923-8370
https://www.sherwininc.com/
Information department: Product safety department
1.4 Emergency telephone number:
Chemtrec +1-800-424-9300 in U.S.A.; outside U.S.A. 001-703-527-3887
Chemtrec contract number 20103
* 2: Hazard(s) identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
Eye Dam. 1 H318 Causes serious eye damage.
Skin Irrit. 2 H315 Causes skin irritation.
Suspected of damaging fertility or the unborn child.- NOT listed as carcinogenic by IARC, NTP or OSHA-Ca
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS05 GHS08
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P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 2
1 Fire = 1
2 0 Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH *2
Health = *2
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0
* 3: Composition/information on ingredients
3.2 Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 64742-47-8 Distillates (petroleum), hydrotreated light 25-50%
EINECS: 265-149-8
CAS: 68131-40-8 Secondary alcohol ethoxylates (3) 25-50%
CAS 64742-52-5 Distillates, hydrotreated heavy naphthaenic 10-20%
CAS: 92257-31-3 C.I.Solvent Red 164 (eq) 1-10%
EINECS: 296-120-8
CAS: 64742-94-5 Solvent naphtha (petroleum), heavy arom. 1-10%
EC number: 919-284-0
Most important ingredients
CAS: 64742-47-8 Distillates (petroleum), hydrotreated light 25-50%
EINECS: 265-149-8
CAS: 68131-40-8 Secondary alcohol ethoxylates (3) 25-50%
CAS 64742-52-5 Distillates, hydrotreated heavy naphthaenic 10-20%
Additional information:
Metabolic studies on some Azo-dyes have detected reduction of azo bonds to aromatic amines. It is prudent to
assume that the product could metabolise to o-toluidine, which have been identified as animal carcinogens.
* 4: First-aid measures
4.1 Description of first aid measures
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
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Take affected persons into fresh air and keep quiet.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Do not induce vomiting; immediately call for medical help.
A person vomiting while lying on their back should be turned onto their side.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
Water haze
Foam
ABC powder
For safety reasons unsuitable extinguishing agents: Water spray
5.2 Special hazards arising from the substance or mixture Carbon monoxide and carbon dioxide
5.3 Advice for firefighters
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
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Information about protection against explosions and fires:
Use explosion-proof apparatus / fittings and spark-proof tools.
Containers may be hazardous when empty since residue liquid and vapors may be present
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
7.3 Specific end use(s) No further relevant information available.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
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Eye protection:
Safety glasses
Tightly sealed goggles
Body protection:
Protective work clothing
Use protective suit.
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*
12 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
Information on hazardous ingredients (Contd. on page 7)
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68131-40-8 Secondary alcohol ethoxylates (3)
EC50/ 48 h 3.1 mg/l (daphnia)
LC50/ 96 h 1-10 mg/l (Fish)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark:
Secondary alcohol ethoxylates: This surfactant complies with the biodegradability criteria as laid down in
Regulation (EC) No. 648/2004 on detergents
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
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14.5 Environmental hazards:
Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO)
DOT: US Department of Transportation
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Carc. 2: Carcinogenicity, Hazard Category 2
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
* Data compared to the previous version altered.
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