Professional Documents
Culture Documents
ln k = ln A Ea/RT
2. The rate constant, k, was determined for a reaction at various temperatures. The
results are given below.
Temperature /0C Second order rate constant, k/mol-1dm3s-1
5 6.81 x 10-6
15 1.40 x 10-5
25 2.93 x 10-5
35 6.11 x 10-5
b) Calculate the gradient (slope) of your Arrhenius plot and use it to determine a value
for the activation energy, Ea, in kJmol-1.
c) Calculate an approximate value for the Arrhenius constant, A, using the Arrhenius
plot.
A= 1x1014 s-1
Ea= 7.5x104 J/mol
R= 8.314 J mol/K
4. Find the rate constant if the temperature is 289K, Activation Energy is
200kJ/mol and pre-exponential factor is 9 M-1s-1 .
k1=7.78x10-7 at T1=273 K
k2=3.46x10-5 at T2=298 K
7. Find the new rate constant at 310K if the rate constant is 7 M-1s-1 at 370K, Activation
Energy is 900kJ/mol .
8. Find the new temperature if the rate constant at that temperature is 15M-1s-1 while
at temperature 389K the rate constant is 7M-1s1, the Activation Energy is 600kJ/mol.
10. The rate constant for a reaction increases by a factor of 1.65 when the
temperature is increased from 200C to 400C. Calculate the activation energy.
11. A catalyst provides a mechanism with lower activation energy. The lower
activation energy means a faster reaction rate.
The Activation Energy (EA) for the uncatalysed overall reaction is 14.0 kJ while that for
the reaction with the catalyst is 11.9 kJ.
Use the expression relating the rate constant and EA to calculate the ratio of the rate
constant of the catalysed reaction to that for the uncatalysed reaction at 25C.
Assume that the frequency factor is the same for each reaction. What do you notice
about the rate of catalysed reaction?
12. Determine the activation energy for the decomposition of organic peroxide
Temp (K) 410 417 426 436
-1
k (s ) 0.0193 0.0398 0.0830 0.2170