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Manolito E.
Bambase Jr
A
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Pr
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,
De
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of
Ch
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En
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AT
,
Un
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Ph
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Ba
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La
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16-1. Roasting of Iron
Pyrite Ore
4 FeS2 + 11
O2 ======>
2 Fe2O3 + 8
SO2
in order to produce
SO2. All the gangue
plus the Fe2O3 and
unreacted FeS2 end
up in the solid
waste product
(cinder). Analysis
shows the cinder
contains 4.0%
FeS2.
1
16-1. Roasting of Iron
Pyrite Ore
4 FeS2 + 11 O2 ======> 2
Fe2O3 + 8 SO2
2
16-1. Roasting of Iron
Pyrite Ore
Hin =
(Hgangue +
HFeS2 + HN2
+ HO2)1
The total enthalpy at the
outlet is:
3
16-1. Roasting of Iron
Pyrite Ore
Hence,
Q = (HSO2 +
HO2 + HN2 +
Hgangue + HFe2O3
+ HFeS2)2
(Hga
ngue
+
HFeS
2 +
HN2
+
HO2)
1
Q = (HSO2 + HO2 +
HFe2O3 + HFeS2)2
(HFeS2 + HO2)1
4
16-1. Roasting of Iron
Pyrite Ore
(
f
o
)
F
e
S
2
=
1
7
7
.
9
k
J
/
m
o
l
f
o
)
F
e
2
O
3
=
8
2
2
.
1
5
6
k
J
/
m
o
l
f
o
)
S
O
2
=
2
9
6
.
9
0
k
J
/
m
o
l
f
o
)
O
2
=
0
.
0
0
k
J
/
m
o
l
5
16-1. Roasting of Iron
Pyrite Ore
H
=
n
=
n
f
o
Also,
m3 /
(15.0 +
m2 +
m3 ) =
0.04
8
16-1. Roasting of Iron
Pyrite Ore
Hin = (85.0/120.0
kmol)(177.9
kJ/mol)(1000
mol/kmol) +
(5.8437)(0)
Hin = 126,007 kJ
9
16-1. Roasting of Iron
Pyrite Ore
Solving for Q:
Q = 691,641 (
126,007) = 565,634 kJ
per 100 kg of ore
Per kg of ore:
Q=
5,656
kJ per
kg of
ore
The negative sign
indicates that meat must
be removed during the
process in order to
maintain the temperature
0
at 25 C.
10
Example 16-2. Combustion of Carbon Monoxide
0
Carbon monoxide at 50 F is completely burned at 2 atm
0
pressure with 50% excess air that is at 1000 F. The products of
0
combustion leave the combustion chamber at 800 F.
0
1 lbmol CO, 50 F 0
Flue Gas, 800 F
0
Air, 1000 F Combustion
n3 lbmol CO2
n1 lbmol O2/lbmol Chamber
n4 lbmol O2 n5
n2 lbmol N2/lbmol lbmolN2
50% excess
11
Example 16-2. Combustion of Carbon
Monoxide
Q = H = Hout Hin
Q = (HCO2 + HN2 + HO2)2
(HCO + HN2 + HO2)1
12
Example 16-2. Combustion of Carbon
Monoxide
CP = + T +
2
T
13
Example 16-2. Combustion of Carbon
Monoxide
o
(f )CO = __________
o
Btu/lbmol (f )CO2 =
__________ Btu/lbmol
o o
(f )N2 = (f )O2 = 0
(CP)
2
________ T ___________ T
= __
__ = _____ + __________
2
T
___________ T
_ = _____ + __________ T
2
+ ___________ T
__ = _____ + __________ T
2
___________ T
14
Example 16-2. Combustion of Carbon
Monoxide
Products
___
H
CO 2 : CO2 169,179 ___ C P CO2 dT _________ Bt
___
N2: H
N2 (0)
___ CP dT _________ Btu / lbmo
N2
___
\O 2 : H
CO2 (0)
___ CP dT _________ Btu / lbmo
O2
15
Example 16-2. Combustion of Carbon
Monoxide
Reactants:
___
CO : H CO 47,515 ___ C P CO dT _________ Btu /
___
N2: (0) T
___ C P N2 dT _________ Btu / lbm
H
N2
___
H
\O 2 : CO2 (0) ___ C P O2 dT _________ Btu / lbm
16
Example 16-2. Combustion of Carbon
Monoxide