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4. The velocities of two particles A and B are 0.05 and 0.02 ms 1 respectively.
The mass of B is five times the mass of A. The ratio of their de-Broglie's
wavelength.
5. Briefly discuss the energy of electron in Bohr atom theory based on the
Bohrs equation.
6. For the hydrogen atom , the energy of an electron in an orbital with quantum
number n is given by the equation:
En= -2.18 x 10-18(1/n2) J.
Derive the Rydbergs equation.
8. A certain green light has a wavelength of 6.26 x 10 14 Hz. (a) What is its
wavelength? (b) What is the energy of one photon of this light? (c) Of one
mole of photons?
1
b) Write the possible quantum numbers (n, l , ml ,ms ) for the electrons in
the 7s and and 7p orbitals.
11. Write the electron configuration and orbital diagram for Cr 3+.
Determine whether it is diamagnetic or paramagnetic. Why?
(Cr : atomic weight =52, atomic number = 24)
13. The maximum number of sub-levels, orbitals and electrons is 'N' shell
of an atom are respectively.
2
Answer:
Answer:
ii) The particle nature of light is characterized by the specific
quantity of energy carried in each photon.
Answer:
Determine the frequency: E = h
3
3.36 x 10-19 J = (6.626 x 1034 J s) (x)
= 5.071 x 1014 s1
Answer:
The velocity of a moving electron is related to its wavelength which is
given by The de Broglie relation
= h/m v
= wavelength, h= Plancks Const, m= mass,
v= velocity
17. The velocities of two particles A and B are 0.05 and 0.02 ms1
respectively. The mass of B is five times the mass of A. The ratio of
their de-Broglie's wavelength.
Answer : 2:1
18. Briefly discuss the energy of electron in Bohr atom theory based
on the Bohrs equation.
Answer:
En= (- bZ2/n2) = -2.18 x 10-18(1/n2) J.
4
b=-2.18 x 10-18
Z=1
E Eh El ( nb2 nb2 )
h l
b 1
nl2
1
nh2
with nh nl
The Planck equation
E hv hc 1 or 1
b 1
hc nl2 n12
h
b
R 1.097 10 7 m 1
hc
1 1 1
R 2
n f
2
ni R 1.097 10 7 m 1
= 397 nm
21. A certain green light has a wavelength of 6.26 x 1014 Hz. (a)
What is its wavelength? (b) What is the energy of one photon of this
light? (c) Of one mole of photons?
Solution:
2) Use E = h for (b). Note that you do not need the answer to (a) to solve part (b). This
answer is nornally given in units of J.
3) Multiply the answer to (b) by Avogadro's Number. This answer is normally given in
kJ/mol.
5
22. Ionization energy is the energy required to remove an electron
from an atom in the gas phase. The ionization energy of gold is 890.1
kJ/mol. Calculate the minimum wavelength of light that will ionize gold.
Solution:
a) We need the energy of one photon:
890100 J/mol divided by 6.022 x 1023 mol-1 = 1.478 x 10-18 J
Answer:
7s n=7, l=0, ml = 0 , ms= or - 2 electrons
(2,0,0, -) and (2,0,0, -)
7p n=7, l=1, ml = -1, 0, 1, , ms= or - 6 electrons
(3,1,-1, -) and (3,1,-1, -)
(3,1,0, -) and (3,1,0, -)
(3,1,1, -) and (3,1,1, -)
24. Write the electron configuration and orbital diagram for Cr3+.
Answer:
6
[Ar]
4s 3d
Paramagnetic 3 unpaired electrons
Answer : potassium K
Answer; 4, 16, 30