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259270, 1998
1998 CNR
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H Y D R O T H E R M A L A L T E R A T I O N M I N E R A L O G Y AS AN
I N D I C A T O R OF H Y D R O L O G Y AT T H E N G A W H A
G E O T H E R M A L FIELD, N E W Z E A L A N D
INTRODUCTION
The geothermal system at Ngawha is the only known active high-temperature field occurring
outside the Taupo Volcanic Zone in New Zealand (TVZ) (Fig. 1). It is located within the
Quaternary-Holocene Kerikeri Volcanic Field, and is sited on the central axis of the
259
260 M. E. ('ox anti P. Browne
KEY
/ road
slump feature ~ - stream
fault 0 km 1
-- -- -- deduced fault I , I
We#orate
Ponds Ng5
-345
DNg3
-294
Ng8
Lake
/ '~NGAW-~ NORTH
/
?/
/ AU~ND~
Taupo ~ ~ .
-494
~/~'ELLINOTON~ ~00kmj
Fig. 1. Location of Ngawha in the North Island of New Zealand and the location of the Taupo
Volcanic Zone. Shown in the Ngawha area are the wells and main known faults. Additional numbers
at well sites are the thickness of the Cretaceous-Tertiary confining sequence (in meters relative to sea
level).
Northland Peninsula (Cox and Browne, 1992). A wide range of investigations to test the
energy potential of the system was carried out, largely by the different sections of the New
Zealand Department of Scientific and Industrial Research (DS|R) and the Ministry of
Works and Development (MWD), from ! 977 to 1983.
Fifteen deep geothermal bores were drilled, mostly to 1000-1300 m, with the deepest hole
(Ngl 3) to a true vertical depth of 2255 m. Cores and cuttings recovered from this drilling
were examined petrologically to determine their lithology and hydrothermal alteration
(Browne, 1981; Browne and Gardner, 1982), isotope composition (Blattner, 1980; Blattner,
Hydrotherrnal alteration mineralogy as an indicator of hydrology 261
1982) and rock geochemistry (Cox, 1985). Here we reassess the hydrothermal mineralogy
in general terms and relate it to the temperatures measured down wells.
1981; Skinner, 1981) that have experienced low-grade regional metamorphism to prehnite-
pumpellyite grade at temperatures of ~350C (Mayer, 1968). Individual beds range in
thickness from tens of centimeters to meters. In appearance the rocks are typically dark
gray-green, highly indurated, and fine-grained; they are cut by numerous narrow veins and
joints.
Permeability'
The overlying Cretaceous-Tertiary sedimentary units form a sequence of rocks with a
low bulk permeability due to their fine-grained nature and their high clay contents. This
sequence, therefore, acts as a partly effective confining layer upon the geothermal system.
Its permeability is locally variable and the fluid moving vertically within it is primarily
separated steam and gas but little, if any, liquid water derived directly from the reservoir.
Non-condensable gases ascend slowly along several linear zones but most steam probably
condenses in the subsurface where it forms bicarbonate waters.
The deep thermal fluids move within a myriad of joint channels produced by faulting.
These typically have a spacing of 15 per meter; individual joints may extend vertically for
at least 30 m and most are interconnected in 3 dimensions (Browne, 1980). Permeability is
thus highest in fracture zones but the rocks themselves have low inherent permeability and
near zero porosity. The overall porosity of the reservoir rocks at Ngawha has been estimated
as 3.7% (McGuiness, 1984) and this includes that provided by joints; by contrast, the
porosity of reservoir formations at the Ohaaki field in the TVZ is 10-40% (Mahon and
Finlayson, 1972).
The great abundance of veins in the reservoir rocks at Ngawha contrasts with geothermal
systems in the TVZ where veins are fewer and fluids can move via interconnected pores
(Browne and Gardner, 1982). The occurrence of hydrothermal minerals in veins at Ngawha
shows that fluids move via joint channels but the complexity of the vein textures and
relations testifies to the episodic nature of fluid flow on a very local scale; as older fractures
filled, others were created and new fluid paths developed.
At the unconformity between the basement rocks and the confining sequence, per-
meability is high in places, as revealed by circulation losses that occurred there during
drilling.
MINERALOGY
Methods
The petrology of the Ngawha system has been studied by examining thin sections of drill
cores and cuttings (Browne, 1981). A selection of cores and cuttings was also made for
chemical analysis (Cox, 1985). Samples of whole rock and some separated mineral phases
were also analyzed by X-ray diffraction (XRD) to aid the microscopy. The X R D results
were consistent with petrographic observations, at least for the more abundant minerals.
Selected samples of cores and cuttings with secondary mineralisation were also examined
by scanning electron microscopy (SEM). The origins of minerals present in the samples
were mainly deduced by petrographic observations.
The abundance of the minerals was estimated petrographically as a volume-% for the
whole rock (Table 1). A semi-quantitative scale from 1 to 5 (rare to common) was used to
indicate the relative abundance of each mineral. The modes of mineral occurrence were
divided, so far as it was possible, into (a) matrix (primary or metamorphic), (b) old veins
Hydrothermal alteration mineralogy as an indicator of hydrology 263
Table 1. D i s t r i b u t i o n of m a i n minerals within the N g a w h a rocks, distinguishing between rock matrix,
older a n d younger veins
Expressed as a m e a n % o f the whole rock (see text). Confining sequence is based o n 26 samples
a n d reservoir o n 35 samples.
- -= n o t seen ? = relative age u n c e r t a i n
( f o r m e d u n d e r m e t a m o r p h i c o r p r e v i o u s h y d r o t h e r m a l c o n d i t i o n s ) , a n d (c) y o u n g v e i n s
(very recent or a product of the current thermal regime). The points assigned were then
s u m m e d a n d a r e e x p r e s s e d as p e r c e n t a g e s o f a " t o t a l r o c k " . T h e r e s u l t s , t h e r e f o r e , r e p r e s e n t
a "mean" composition characteristic of the confining sequence and reservoir rocks.
T E M P E R A T U R E S IN T H E NGAWHA G E O T H E R M A L SYSTEM
Measured temperatures
Downhole temperatures were measured at Ngawha (MWD unpub, rep.). Typical profiles
are shown by Ngl3 and Ng20; a temperature inversion in Ng8 is evident at a depth of 900-
1000 m (Fig. 2). The measured temperatures can be compared with those deduced from the
mineralogy (Table 2) and show (Table 3) that hotter conditions prevailed in the southern
and eastern parts of the field at some time in the past, commonly 20-30'~C higher but as
much as 50~80C in some places.
This deduced cooling is interpreted as resulting from a change in hydrology within the
reservoir. This change was initiated by an inflow of cool groundwater from the east, which
is now seen in the temperature profile of Ng8 (Fig 3). This water flows westward across the
field affecting wells Ng3, 4 and 13 by causing temperature inversions in them; Ng9 and 12
appear to be similarly affected. More local, shallower lateral flows of cooler water have
also affected the southeast (seen in profiles of wells Ngl8, 20 and 11). These temperature
changes are confined to the reservoir rocks.
In some places, temperatures have remained nearly the same since the hydrothermal
266 M. E. Uox and P. Browne
Temperature ( * C )
o ~ 1~o 1p ~ ~ o p lOO 15o
1 ~ \1 ;',
s, _4\ 484e~.
c
..... ~T-
III !',
I ,
I
) 12
]
'l
14
le
M
Ng 8 Ng 13 Ng 20
Fig. 2. Measured downhole temperatures for geothermal wells Ng8, Ngl 3 and Ng20; conditions at
the time of measurement are noted. The two depth values for each well are drilled depth (upper), and
true vertical depth (lower). The main zones of permeability are indicated by arrows (M = main
feed). Boiling point-depth curves (open system) are shown for pure water (upper curve) and a fluid
of 0.1 m NaCI with 1.5 wt% CO2 (lower curve). The broken horizontal lines mark the base of the
confining sequence (data from MWD unpub, rep.).
Mineral Temperature
range (approx. C)
Kaolinite below 60
Siderite below 150
Smectite (140'-220~C gradation range of smectite-illite interlayering) below 140
Illite (increased crystallinity of clay minerals from 150C up to 220C) over 220
Titanite over 150
Prehnite 240-350
Biotite (hydrothermal) over 250
Epidote (hydrothermal) (increasing in crystal size and abundance with increasing over ~ 250
temperature)
Hydrothermal alteration mineraloyy as an indicator of hydroloyy 267
Table 3. Differences between mineralogy-deduced temperatures, determined from cores and cuttings,
and temperatures measured downhole.
In several wells, e.g. NgS, I I and 20, the observed alteration predicts temperature
inversions that were confirmed by the downhole measurements.
CONCLUSIONS
Rocks of the Ngawha geothermal system have experienced several thermal episodes. The
petrography of the rocks, mainly those from within the reservoir, suggests that a likely
chronology was: (1) a period with prolonged low-grade metamorphism, followed by (2)
several high-temperature hydrothermal episodes, and (3) the development, very recently,
of the current geothermal regime, which itself changed during its timespan; this is recorded
by the hydrothermal alteration and fluid inclusions.
The depth/temperature distribution of minerals can only be recognized in general terms
for Ngawha (as compared with TVZ systems), primarily because of the fracture control on
fluid movement. K-feldspar abundance in the reservoir rocks appears to have been reduced,
as some detrital K-feldspar formerly present has altered to illite. The widespread occurrence
of" CO2 dissolved in the fluid has been, and is still, high. This conclusion is also supported
by the scarcity of Ca-zeolites (e.g. laumontite, heulandite or wairakite).
The mineralogy-deduced temperatures reflect both existing and previous conditions. At
present, fluids are moving along open fractures, and hydrothermal alteration is largely
restricted to fractures/veins. These mineralogically indicated temperatures mostly agree
with the values currently measured. Previous conditions, which were slightly different
locally from those now prevailing, are recorded by minerals preserved in older fractures,
now blocked.
One feature of hydrothermal alteration mineralogy is that it can be used to recognize
relict conditions in a hydrologically complex system and so assist in understanding its
hydrological evolution.
Hydrothermal alteration mineraloyy as an indicator of hydrolo#y 269
Acknowledyements--The authors are grateful for the use of the unpublished reports (MWD, DSIR
and NZGS) referred to in this paper, particularly those on downhole temperature measurements
made by MWD. They also thank colleagues from these organizations for many helpful discussions
about Ngawha. Edwin Roedder and an anonymous reviewer improved the paper.
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