1

Modul A, paper 2

No Mark scheme Sub Total

Mark mark

1. (a) (i) 2 1 1

(ii) Y/ Cl / Chlorine 1 1

(b) (i) Z / Fe / iron / Ferum / Besi 1 1

(c ) 1. No. of proton//positive charges of nucleus of atom Y is 1

more than in atom X
Bil proton/ cas positif nucleus atom Y lebih banyak
berbanding atom X
1
2. the forces of attraction of the nucleus towards of atom Y is
stronger
Daya tarikan antara nukleus terhadap elektron atom Y
lebih kuat 2
(d)

1 1
(e) (i) 1. Correct formulae of reactant and product
2. Balance equation

2X + 2H2O 2XOH + H2 // 1
2Na + 2H2O 2NaOH + H2 1 2
(ii) A is more reactive than X
A lebih reaktif dari X 1 1

TOTAL 9
2
 3

2 (a) (i) CnH2n+2 1 1

3 a i. C14H2
(ii) 11 11
Ii
(iii) Solid / pepejal 1 1
b i YZ2 H H H H 1 1
ii 1.The melting point and the boiling point is low 1
2.The C particles/molecules
= C C C are attracted
H together by aweak
Van der Waals / intermolecular force // theforces of
attraction
H between particles
H H is weak 1
3.Low heat energy is required to overcome the forces. 1 13
(b) (i) zinc oxide and carbon dioxide 1+1 2
1.takat
Zink oksida lebur
dan dan dioksida
karbon takat didih rendah
2.zarah/molekul
(ii) yellow ditarik
when hot, white whenoleh daya tarikan Van der
cold 1 1
Kuningwaals/daya
bila panas, dalam molekul
putih bila sejukyang lemah// daya tarikan
antara zarah yang lemah
3. tenaga haba yang rendah diperlukan untuk mengatasi
daya3 ZnO + CO2
(iii) ZnCO

c i of 1.
No. Correct
mole/ formula
bil. mol = 5of reactant
= 0.04 and
mol product 1
2 . Balance equation
125 1
1 mol ZnCO3 produced 1 mol gas Y 1
1.formula bahan dan hasil yang betul 2
Volume/2.persamaan seimbang
isipadu = 0.04 mol x 24 dm3 mol-1
3
= 0.96 dm = 960 cm 3
1 3
4X + Z2 2X2Z// 4 Na + O2 2Na2O
Total 9
ii

1.Correct number of shells and nucleus 1

2.Correct number of electrons and charges 1 2
1.bilangan petala dan nukleus yang betul
2.bilangan electron dan cas yang betul

Total 10

4. a. A substance that ionizes in water to produce hydrogen ions 1 1

Bahan yang mengion dalam air untuk menghasilkan ion hidrogen

b. S 1 1

c. i. P 1 1

ii. Solution P has the highest concentration of hydrogen ions. 1 1

Larutan P mempunyai kepekatan ion hidrogen yang paling
tinggi
 4

d. i. 60 cm3 1 1

ii. 1. Correct formula of reactant and product 1

2 . Balance equation 1
1.formula bahan dan hasil yang betul
2.persamaan seimbang 2

H2SO4 + 2NaOH Na2SO4 + 2H2O

iii. Molarity of the sulphuric acid /

Kepekatan asid sulfurik 1

Mol H2SO4 = (1.0)(15) = 0.015

1000
1
From equation,
1 mole sulphuric acid react with 2 mole of sodium hydroxide
0.015 mole of sulphuric acid react with 0.03 mole of sodium
hydroxide 1 3
Dari persamaan,
1 mol asid sulfurik bertindak balas dengan 2 mol natrium
hidroksida
0.015 mol asid sulfurik bertindak balas dengan 0.03 mol
natrium hidroksida

Molarity/ = 0.03 X 1000

KepekatanNaOH 20
= 1.5 mol dm-3

10
Total

5 (a) 2-methylbut-1,3-diene / 2-metilbut-1,3-diena 1 1

(b) (i) Polymerization/ pempolimeran 1 1
(ii)

1 1

(c) (i) A: ethanoic acid//any suitable asid 1

Asid etanoik// apa-apa asid yang sesuai 1 2

B: ammonia solution//any suitable alkali

Ammonia // apa-apa alkali yang sesuai

(ii) 1.Reaction of bacteria in the air produce an acid. 1

 5

2.Presence of H+ ion neutralize the negative charge of latex 1 2

particles

1.Tindak balas bakteria dalam udara menghasilkan suatu

asid
2.kehadiran ion H+ meneutralkan cas negatif pada zarah
getah
(d) (i) L 1 1

(ii) Vulcanised rubber is :

- harder
- high resistant to heat
- not easily oxidized.
Getah tervulkan 2
- lebih kuat
- mempunyai daya ketahanan terhadap haba
- tidak mudah dioksidakan.
(Any two)
2 2
(iii)

1 1
Total 11

6. (a) Allows the flow of ions 1 1

Membenarkan ion-ion mengalir.
(b) (i) +6 to +3 1 1
+6 kepada +3
(ii) Reduction 1 1
Penurunan
(c) (i) Fe2+Fe3+ + e 1 1
(ii)- Add a few drops of sodium hydroxide solution into the
solution at carbon electrode X. 1
- Brown precipitate form. 1

- Tambahkan beberapa titis larutan natrium hidroksida

ke dalam larutan pada elektrod karbon X. 1
- Mendakanperangterbentuk. 1 2

Note:
Accept any suitable reagents and correct observation
respectively.
 6

(d) (i) P, Q, S, H, R 1 1

(ii) - Copper 1
- Oxidizing agent 1
- Kuprum
- Agen pengoksidaan 2

(iii)

Sulphuric acid
Asid sulfurik

Flat-bottomed
flask
Kelalang berdasar
rata

Zinc
Zink

Functional diagram 1
Correct label 1 2
Gambarajah berfungsi
Label yang betul

TOTAL 11
 7

7 (a) Hydrocarbon A Hydrocarbon B

Hidrokarbon A Hidrokarbon B
Functional group Single bond Double bond
Kumpulan Ikatan tunggal Ikatan ganda 1
befungsi dua
Chemical formula C3H8 C3H6
Formula kimia 1
Homologous series Alkane Alkene
Siri homolog Alkana Alkena 1
General formula CnH2n CnH2n+2
Formula am 1 4

(b) Molecular formula / formula molekul

CnH2n = 28
12n + 1(2n) = 28
14 n = 28
n=2 1

Q = C2H4 1

Homologous series = alkene / alkene 1

Because it contains double bond / mengandungi ikatan ganda 1
dua

C2H4 + H2O C2H5OH 1

Ethanol / etanol 1 6

(c) CH3COOH 1
-COOH, carboxyl group 1

L= ethanoic acid / asid etanoik 1

X= hydrogen gas / gas hidrogen 1
K= ethyl ethanoate / etil etanoat 1
Y= carbon dioxide gas / gas karbon dioksida 1

Esterification / pengesteran 1

1. Correct formula of reactant and product 1

2. Balance equation 1

CH3COOH + C2H5OH CH3COOC2H5 + H2O

Catalyst / mangkin : concentrated sulphuric acid / asid 1 10

sulfurik pekat

Total 20
 8

8 (a) (i) Rate of reaction is the change in the volume of hydrogen gas 1
released per unit time taken
Concentration 1

1.Correct formula of reactants and products 1

2.Balanced chemical equation 1 4

Zn + 2HCl ZnCl2 + H2

(ii) Experiment I = 50 // 2.5 cm3s-1 1

20

Experiment II = 50 // 1.0 cm3s-1 1 2

50

-Rate of reaction in experiment I is higher than higher 1

Experiment II
-The concentration of acid in Experiment I higher than in 1
Experiment II // Number of hydrogen ions per unit volume in
Experiment I bigger than in Experiment II. 1
-Frequency of collision between hydrogen ions and zinc
atoms in Experiment I is higher 1 4
-Frequency of effective collision between particles in
Experiment I is higher than in Experiment II.

-kadar tindak balas dalam eksperimen 1 lebih tinggi

daripada eksperimen II
-kepekatan asid dalam eksperimen I lebih tinggi daripada
eksperimen II// bilangan ion hidrogen per unit isipadu dalam
eksperimen I lebih tinggi daripada eksperimen II
-frekuensi perlanggaran di antara ion hidrogen dengan atom
logam zink dalam eksperimen I lebih tinggi daripada
eksperimen II
-frekuensi perlanggaran berkesan di antara zarah dalam
eksperimen I lebih tinggi daripada eksperimen II

(b) (i) A 1
Manganese (IV) oxide/lead (II) oxide/lead (IV) oxide
Mangan (IV)oksida/ plumbum (II) oksida/ plumbum 1 2
(IV)oksida

(ii) 1.Label of energy on vertical axis 1

2.The position of the energy level of the reactants is higher 1
than the energy level of the product.
3.Correct position for Ea 1
4.Correct position for Ea
1.label Tenaga pada paksi menegak
2.kedudukan aras tenaga bagi bahan lebih tinggi daripada 1 4
aras tenaga hasil
3.kedudukan yang betul bagi Ea
4.kedudukan yang betul bagi Ea
 9

Energy

Ea
Ea
Zn + 2HCl

ZnCl2 +
H2

Reaction
path

1. the presence of catalyst provide an alternative pathway 1

2. with a lower activation energy in created 1
3. number of colliding particles which are able to overcome 1
the lower activation energy increases
4. frequency of effective collision increase 1 4

1. dengan kehadiran mangkin, satu laluan alternatif

2. dengan tenaga pengaktifan lebih rendah terbentuk
3. maka, bilangan zarah berlanggar yang dapat mengatasi
tenaga pengaktifan yang lebih rendah ini bertambah
4. kadar tindak balas bertambah.

Total 20

9 (a)

Nickel

Nikel
 10

Spoon

sudu Nickel (III) nitrate

Nikel (III) nitrat

1
1.functional diagram : anode and cathode correct,solution
shaded,whole spoon immersed

2.label : nickel,spoon,nickel(III) nitrate solution 1

1.gambarajah berfungsi : anod dan katod betul,larutan
dilorek,sudu direndam sepenuhnya
2.label : Nikel,sudu ,larutan nikel(III) nitrat

[a:any solution with nickel(II) /nickel(III) ion] 1

1
3.anode : Ni Ni2+ +2e // Ni Ni3+ +3e 4
[refer solution]
4.cathode : Ni2+ +2e Ni // Ni3+ +3e Ni
[rujuk larutan]

(b) Experiment I

1.product = oxygen 1
Hasil =oksigen
2.hydroxide ion is discharged 1
Ion hidroksida dinyahcaskan
3.hydroxide ion is lower than iodide ion in the 1
electrochemical series
Ion hidroksida di bawah ion iodida dalam siri elektrokimia.

Experiment II
4. product = iodine 1
Hasil =iodin
2.iodide ion is discharged
1
Ion iodida dinyahcaskan
3.iodide ion is more concentrated
Ion iodide lebih pekat. 1 6

(c) 1.Zn 1
2.Cu 1
3.CuSO4 solution 1

Procedure :
4. Zinc strip and copper strip are cleaned with sand paper 1
jalur zink dan jalur kuprum digosok dengan kertas pasir
5.A beaker is filled with 0.1 mol dm-3 of copper(II) sulphate 1
solution until half full
Sebuah bikar diisi dengan larutan kuprum(II) sulfat 0.1 mol
dm-3 sehinggaseparuh bikar
 11

6.Zinc strip and copper strip are dipped into the solution 1
jalur zink dan kuprum dicelup ke dalam larutan
7.both strips are connected to voltmeter via connecting wire 1
kedua-dua jalur disambungkan ke voltmeter melalui wayar
penyambung
8.Zinc release electron to form zinc ion 1
zink menderma elektron dan membentuk ion zink
9. copper(II) ion receive electron to form copper 1 10
ion kuprum(II) menerima elektron dan membentuk kuprum
10.when electron move from zinc to copper pointer of 1
voltmeter deflect
apabila elektron bergerak dari zink ke kuprum jarum
voltmeter terpesong

Total 20

10 (a) (i)

energy

Pb 2+ (aq) + SO42-

(aq)

H = -50 kJmol-1

PbSO4

1. Y-axes : energy 1
2. Two different level of energy
1. Paksi Y : tenaga 1 2
2. Dua aras tenaga berbeza

(ii) 1.energy content of reactants is higher // products have less 1

energy content
Bahan mempunyai tenaga yang lebih banyak//hasil
mempunyai tenaga yang sedikit
1 2
2.heat is released during the experiment // this is exothermic
 12

reaction
haba dibebaskan semasa eksperimen// ini ialah tindak balas
eksotermik

(b) (i) 1. heat of neutralization of exp. I is higher than exp. II 1

Haba peneutralan eks.I lebih tinggi daripada eks. II
2.HCl is strong acid and CH3COOH is weak acid 1
HCl ialah asid kuat dan CH3COOHialah asid lemah
3
3.strong acid / HCl ionized completely and weak
acid/CH3COOH ionized partially in water
Asid kuat/HCl mengion dengan lengkap dalam air dan asid 1
lemah/CH3COOHmengion separa dalam air
4. some of the heat released are absorbed to ionizes ethanoic
acid inthe molecules completely
sebahagian haba dibebaskan akan diserap untuk mengion
molekul asid etanoik dengan lengkap

(ii) 1. Value of Heat of neutralization is same 1

2. both experiments contain same number of hydrogen ion
1
1. Nilai Haba peneutralan adalah sama 1 3
2. Ini kerana kedua-dua eksperimen mengandungi
kepekatan ion hidrogen yang sama banyak

(c)
Apparatus : Polystyrene cup, thermometer, measuring 1
cylinder, spatula.
Radas : cawan polisterin, termometer, silinder penyukat,
spatula

Materials : 0.2 mol dm-3 copper(II) sulphate solution, zinc 1 2

powder.
Bahan kimia : 0.2 mol dm-3 larutan kuprum (II) sulfat, serbuk
zink

Procedure/kaedah :

1. Measure 25 cm3 of 0.2 mol dm-3 copper (II) sulphate 1

solution and pour it into a polystyrene cup.
Sukat 25 cm3 larutan kuprum (II) sulfat 0.2 mol dm-3 dan
tuangkan ke dalam cawan polisterin
2. Put the thermometer in the polystyrene cup and record
1
the initial temperature of the solution.
Letakkan thermometer ke dalam cawan polisterin dan
rekodkan suhu awal larutan
3. Add half a spatula of zinc powder quickly and carefully 1
into the polystyrene cup.
Dengan cepat dan berhati-hati,tambahkan setengah
spatula serbuk zink ke dalam cawan polisterin
 13

4. Stir the reaction mixture with the thermometer to mix the 1

reactants.
Kacau campuran tindak balas dengan menggunakan
termometer untuk memastikannya bercampur
1 5
5. Record the highest temperature reached.
Suhu tertinggi yang dicapai direkodkan.

Tabulation of data:

Initial temperature of CuSO4 solution (oC) 1

Suhu awal larutan CuSO4 (oC)
Highest temperature of the reaction mixture (oC) 2
Suhu tertinggi cmpuran tindak balas (oC)
Temperature change (oC) 2 - 1 1
Perubahan suhu (oC) 1

Calculation/ pengiraan :

Number of mole of CuSO4

Bilangan mol CuSO4

= MV/1000 = (0.2)(25)/1000 = 0.005 mol 1

Heat change/ perubahan haba = mc(2 - 1) = x J

Heat of displacement/Haba penyesaran

= x / 0.005 kJ mol-1
1 2
= y kJ mol-1

Total 20