RANK BOOSTER

SECTION I
Straight Objective Type

This section contains 6 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.

1. Most stable conformation of glucose molecules is ?

H
H

HO
HO CH2-OH
CH2-OH

OH OH
H H
H HO H
HO
H OH
H H
OH H

a) b)

OH OH
H CH2-OH H H
c) H d) H
H CH2-OH

H OH OH
HO
H OH
OH H
OH H

A
2. Which of the following alkene have minimum heat of Hydrogenation ?
 H H

b)

a)

c) d)

A
3. products when the concentration of reactants is doubled the rate of
the reaction is increased by 3 times. Order of the reaction is

a) 23 b) 32 c) log2 3 d) log3 2
C
FeC2 o4 KMnO4
Medium
Acidic
Fe3 2CO2 Mn 2
4.
in the above unbalanced equation 10 mole FeC2O4 is completely reacting with KMnO4.
No.of moles of KMnO4 used is
a) 5 b) 9 c) 3 d) 6
D
5. 4 mole H2 and 4 mole I2 are made to react in a 5ltr vessel at 4400C. At equilibrium 6
mole HI is found in the absence of a catalyst. No.of moles of HI that will be found if
10 mole HI is made to react in a 10 lt vessel at 4400C in the presence of a catalyst is
a) 1.25 b)2.5 c) 7.5 d) 6
C
6. Which of the following covalent molecules is unlikely to exist?
a) Non-Polar molecule with polar bonds b) Polar molecule with polar
bonds
c) Non-polar molecule with nonpolar bonds d) Polar molecule with non-polar
bonds
D
SECTION II

Multiple Correct Answer Type

This section contains 4 multiple correct answer(s) type questions. Each question
has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.

7. In which of the following molecule the inter molecular forces are Vanderwall forces ?
a) CO2 b) NH3 c) SO2 d) CH4
A,C,D
8. Which of the following are exothermic reactions?

a) H+ (aq) +OH- (aq) H2O b) F(g)+e- F- (g)

c) O- (g)+e- O2- (g) d)CH4(g)+2O2(g) CO2(g)+2H2O(l)
A,B,D

9. In which of the following reaction (S) carbonion is formed.

a) Decarboxylation of carboxylic Acid by heating
b) Aldol condensation reaction
c) Elimination Unimolecular conjugate base (E1cb)
d) Dehydration of Alcohal in presence of Acid.
A,B,C
10. Hyper conjugation explain the stability of compounds and Reaction intermediate
choose the correct option(S) given below
gg

CH 2 CH O H
gg CH 2 CH CH CH 2
a) b)
CH3
C Cl3
c) CH3 CH d)

C
SECTION III
Reasoning Type
This Section contains 4 reasoning type questions. Each question has 4 choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.

Note :
A. Statement 1 is True, Statement 2 is True ;Statement 2 is a correct explanation for
Statement 1.
B. Statement 1isTrue, Statement 2 is True ; Statement 2 is NOT a correct explanation
for Statement 1.
C. Statement 1 is True, Statement 2 is False.
D. Statement 1 is False, Statement 2 is True.

O-H
H
O
O
CH2

OH
OH OH
11.STATEMENTI: The above compound is sufficiently acidic
and can react with NaHCO3 ( Aquous medium) to liberate the CO2
STATEMENT II: It is sufficiently acidic due to the ionization of the enolic
hydroxyl at C2 gives an anion that is stabilized by resonance much the
same way as carboxylate ion.
C

12.STATEMENT I: LiA1H4 can reduce the ester to alcohal but NaBH 4 cannot
 H

STATEMENT II: LiA1H4 are hydride ion donar

B
13.STATEMENT I : According to Heisenberg the energy of an electron in the
first orbit of H-atom is -13-6 ev
STATEMENT II: Heisenbergs theory can be understood as when the
position of electron is accurately taken, the energy of electron cannot be
determined accurately.
D
14.STATEMENT I : Zr and Hf have almost same atomic radius though of Hf
has 32 more protons than Zr.
STATEMENT II: The nuclear charge in Hf is not properly shielded due
to the presence of 14 inner- f-electrons
A

SECTION IV
Linked Comprehension Type

This Section contains 3 paragraphs. Based upon each paragraph, 3 multiple

choice questions have to be answered. Each question has 4 choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 15 to 17

Compound (A) C5H11 Br form a Grignard Reagent which on treatment with dil Acid
decomposed to give n-pentane. When ( A) is treated with aqueous KOH ,
compound (B), C5H12O is produced compound (B) gives a positive Lucas test.
When (B) is treated with K2Cr2O7 and dil H2SO4 compound (C) is produced.
Compound(C) gives negative Iodoform test
15.compound is
a) a primay Alkyl bromide b) 20 Alkyl bromide
c) t-alkyl bromide d) optically active Alkyl bromide
B
16.Compound (B)
a) more Acedic than ethanol b) can react with NaOH
c) it is optically active alcohol d) optically inactive alcohol
D
17.Compound (C )
a) can react with NaHSO3 b) can respond fehling solution
 c) can dipole moment more than compound (A)

H C H
d) can more reactive than
C

Paragraph for Question Nos. 18 to 20

The empirical formula of a cobalt (111) complex is Co(NH 3)x Cl3 . The
coordination no.of cobalt in the above complex is six. Needless to say that all
complexes ionize completely.

18. Kb of water 2K kg mole -1 , when one mole of the above complex is added to 1kg water
the rise in B.Pt is 6K. Then the value of x is
a) 4 b) 3 c) 5 d) 6
C
19. One mole of the above complex gave 143.5g white ppt with excess AgNO 3 solution.
Then x is
a) 4 b) 5 c) 6 d) 3
A
20. For what value of x the molar conductivity is maximum (ignoring the effect of ionic
radii)
a) 3 b) 4 c)5 d)6
D
Paragraph for Question Nos. 64 to 66
Gas (X) reacts with water producing three compounds (P), (Q) and ( R).
( P) is used in etching of glass (R ) is used in the detection of position of a
double bond.
(Q) and ( R) are allotropes

21. Gas (X) is

a) O2 b) Cl2 c)F2 D) SO2
C
Z
22. Carbon + Q
Z is also produced when carbon is heated with
a) F2 b) N2 c)N2O d)NO2
C
23. (P) is formed in the hydrolysis of
a) CF4 b) XeF2 c)SiCl4 d) Na2SiF6
B
MATHEMATICS PHYSICS CHEMISTRY

1. D 24. C 47. A
2. B 25. D 48. D
3. B 26. C 49. C
4. B 27. B 50. D
5. C 28. D 51. C
6. D 29. B 52. D
7. A,B,C 30. ABCD 53. A,C,D

8. B,C,D 31. CD 54. A,B,D

9. A,B,C 32. ACD 55. A,B,C
10. A,C 33. ABC 56. C
11. C 34. B 57. C
12. B 35. A 58. B
13. C 36. A 59. D
14. C 37. D 60. A
15. B 38. D 61. B

16. A 39. B 62. D

17. A 40. A 63. C
18. A 41. B 64. C
19. B 42. C 65. A
20. B 43. C 66. D
21. A 44. B 67. C
22. A 45. C 68. C
23. A 46. C 69. B

CHEMISTRY-SOLUTIONS

47. If the large group present on equatorial position it is anti confirmation, Axial
position gauche confirmation.
48. Most stable alkene have least heat of Hydrogenation
order
49. rate = K (Conc)
order
r1 C
K 1
r2 C2

50. 5FeC2O4 +3KMnO4

51. H2+I2 2HI
Initial 4 4 0
Area 1 1 6

At this time temp HI has the habit of 25% dissociation 25% of 10
mole(i.e) 2.5 mole will dissociate and 7.5 mole will remain volume change
and catalyst will not affect in this equilibrium.
52.
53. In Ammonia the intermolecular forces are due to H-bonding
54.
55.
56.
57. The ionization of enolic hydroxyl at C3 not C2 position

H
O
O
CH2

OH C2
C3
O OH

58.
61,62,63

R-Br+mg
ether
R-mgBr
H
R-H
A (5C) Alkane
(5C) (5C)

R-Br KOH R-OH

oxidation
Carbonyl compound
H2O (5C) which give negative
A B idoform test
+ve lucas test only posible structure is
O

CH3 -CH2 C CH2 -CH3 (C)

Hence B is
OH

CH3 -CH2 CH CH2 -CH3

Hence A is
Br

CH3 -CH2 CH CH2 -CH3

optically in active

64. Rise in B.pt is 6K

Kb = 2K kg mole-1
One mole is producing 3 mole ions

Formula of the complex
 Co NH 3 5 Cl Cl2

x=5

65. 143.5 g Agcl 1 molre PPt
One chloride ion is given by compelx

Co NH 3 4 Cl2 Cl

66. Max molar conductivity will be produced with 4 ions

Co NH 3 6 Cl3

67. F2+H2O HF + O2 + O3
(P) (Q) ( R)
O2 and O3 one are allotrope HF is used in etching of glass O 3 (R ) is used
in the detection of double bond

68. C+O2 Co2
(Q) (Z)

C+N2O Co2
(Z)

1
O2
2
69. XeF2 + H2O Xe+ 2HF +

PAPER-2

SECTION I

Straight Objective Type

This section contains 9 multiple-choice questions numbered 1 to 9. Each
question has 4 choices (A), (B), (C) and (D), out of which Only One is
correct

24. If the radius of first orbit of H-atom is a0, then de Broglie wavelength of electron in 4th
orbit is

a0
2 a0 16a0 4 8 a0
a) b) c) d)
D

25. M aqueous solution of CrCl3.6H2O freezes at -5.580C. Assuming complete ionization

of the hydrated complex, which of the following isomers confirms to observation
( Kf for water = 1.86 K kg mol-1)

Cr H 2 O 3 Cl3 3H 2O Cr H 2O 4 Cl4 Cl.2 H 2O

a) b)

Cr H 2 O 5 Cl Cl2 .H 2O Cr H 2 O 6 Cl3
c) d)

26. The pH of 0.5L of 1.0 M NaCl after the electrolysis for 965 s using 5.0A current
(100% efficiency) ,is

a) 1.00 b) 13.00 c) 12.70 d) 1.30

48. Which of the following sets does not represent the correct order of the property
indicated alongwith

a) Be(OH)2 <Mg(OH)2 <Ca(OH)2 <Ba(OH)2 - Basic character

b) Al2O3<MgO<Na2O<K2O - Basic character

c) Be<B<N<O - First ionization energy

d) NH3<PH3 <AsH3 <SbH3 - Acidic character

27. Phosphine is produced by adding water to

a) CaC2 b) HPO3 c) Ca3P2 d) P4O10

PbS Heat
in air
A+PbS
High temp
No air
Pb+SO 2
28. identify A

a) PbO b) PbSO4 c)none d) a or b

D
 29. Which of the following is an outer orbital complex

4 4 3 2
Fe CN 6 Mn CN 6 Co NH 3 6 Ni NH 3 6
a) b) c) d)

30. Which of the following ions are expected to be paramagnetic to the same extent?

i. [FeF6]3- ii.[MnCl4]2- iii.[NiCl4]2-

a) I,II and III b) I and II c) I and III d) II and III

Co( NH 3/ 6 2 Co(NH3 )(NO2 )5 3

31. The aqueous 0.01 m of is expected to have the
depression of freezing point (Kf for water = 1.86 K/m)

a) 0.0180C b) 0.0560C c) 0.0740C d) 0.0930C

SECTION II

Reasoning Type
This section contains 4 reasoning type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.

Code
(A) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is a correct explanation
for STATEMENT1
(B) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is NOT a correct
explanation for STATEMENT1
(C) STATEMENT1 is True, STATEMENT2 is False
(D) STATEMENT1 is False, STATEMENT2 is True
32. Statement I: Al is used as a reducing agent in aluminothermy
Statement II: Al has a lower melting point than Fe, Cr and Mn
B

Pt ( NH 2 )3 Cl2
33. Statement I: is tetrahedral
Statement II: The oxidation state of platinum is +2
 D
34. Statement I: When a finely divided active carbon or clay is stirred into a dilute
solution of a dye, the intensity of colour in the solution is decreased.
Statement II: The dye is adsorbed on the solid surface
A
35. Statement I: Acetaldehyde reduces Fehlings solution but benzaldehyde does not.
Statement II: Acetaldehyde is a stronger reducing agent than benzaldehyde.
A

SECTION III

Linked Comprehension Type

This Section contains 2 paragraphs. Based upon each paragraph, 3 multiple
choice questions have to be answered. Each question has 4 choices (A), (B),
(C) and (D) out of which ONLY ONE is correct

Paragraph for Questions Nos. 58 to 60

Grignard reagents are powerful nucleophiles and strong bases. They act as
nucleophiles by attacking a variety of compounds including saturated and

-+ (i)Het3hOr
unsaturated carbon atoms. Examples of reaction on saturated carbon include oxiranes
( epoxides) which form alcohols as the final product

R Mg X+H2 C - CH2 R-CH2-CH2OH

O

C=O,-C N, C=S etc.

Examples of reaction on unsaturated carbon are attack on

RR
R
R
R H3O+ R
C=O+ MgX C-OH

R
When R and =H, product is 10 alcohol
R
When R and =Alkyl group, product 30 alcohol.
R
When either R or is alkyl, and the second is H, product is 20 alcohol
 i)EHt32O+
58.
36.

C6H5MgBr+H2C - CH CH3 Product

O

C6 H5
Here the nucleophile attacks on
a) C1 b)C2 c) C3 d) Any of the three
A
37. Epoxides react with Grignard reagent to form
a) Primary alcohols b)Secondary alcohols c) Tertiary alcohol d) Any of the three
D

38. On the basic of above two passage, predict which of the reaction feasible
OH
Br CHC6H5 MgBr
i)Mg,ether O
i) ii) i) CH3CHO H
ii)C6H6CHO
N + ii) H3O
iii)H3O N
H H

O
HO CH2CH3

i) CH3CH2MgBr
iii)
ii) H3O+
OH OH

a) only (ii) b) (i) and (ii) c) All the three d) (ii) and (iii)
A

Paragraph for Questions Nos. 61 to 63

When methyl ketones react with halogens in the presence of a base, all = hydrogen
atoms are replaced by halogens, one after the other. Moreover.

O O O
-
X2,OH CH3 C CX3 X3 C CX3
CH3 C CH3 C
Trihaloketone

The trihaloketone also undergoes hydrolysis in presence of OH- forming

O O
OH- C O-+ CHX3
CH3 C CX3 CH3
 39. During formation of trihaloketone, which halogen is introduced most easily?
a)First b) Second c)Third d) All at the same rate
C
40. Acetone as well as trihaloacetene, both containC= O group, only the latter is
hydrolysed by alkali while the former does not undego hydrolysis. This is because
O O
a) CH3 C CH3 is stable, while CH3 C CX3 is unstable

b) -CX3 is stable, while -CH3 is unstable

O O
c) CH3 C CH3 under goes nucleophilic addition, while CH3 C CX3

under goes nucleophilic substitution

d) Size of bromine is more than that of H

B
41. Haloform reaction can be used for preparing COOH from methyl ketones, which
halogen is best suited for this purpose
a) Cl2 b)Br2 c)either of the two d) I2
C

SECTION IV

Matrix Match Type

p q r s
A
B
C
D

This section contains 3 questions. Each question contains statements given in two columns which
have to be matched. Statements in Column I are labeled as A, B, C and D whereas statements in
Column II are labeled as p, q, r and s. The answers to these questions have to be appropriately
bubbled as illustrate din the following examples. If the correct matches are A P, B Q, C R, D
P, then the correctly bubbled matrix will look like the following
42. Match the geometry and magnetic behaviour described in List II with the complex
ions in List I.
Column I Column II
(A MnCl 2-4 (P) Square planer
)
(B NiCl 2-4 (Q Tetrahedral
) )
(C CuCl 2-4 (R Diamagnetic
) )
(D Ni(CN) 2-4 (S) Paramagnetic
)
A Q,S
B Q,S
C P,S
D P,R

43. Observe the following lists

List-I List-II
(A) Hydrogen bonding (P) Ethyl acetoacetate
(B) amino acids (Q) Proteins
(C) O (R) Zwitterion
CH2 C OH
NH2

(D) Aniline (S) Diazotisation

A P,Q
B R,S
CR
DS

44. Observe the following lists

List-I List-II
(A CN- (P) Nucleophile
)
(B RCN (Q Eletrophile
) )
(C C6 H 6 (R Ambident nucleophile
) )
(D Benzyne (S) Aromatic
)
A P,R
B P,Q
C P,S
D Q,S

Chemistry
Q. No. Ans.

45 D

46 C

47 B

48 C

49 C

50 D

51 C

52 B

53 D

54 B

55 D

56 A

57 A

58 A

59 D

60 A

61 C

62 B

63 C
 A Q,S
B Q,S
64
C P,S
D P,R

A P,Q
B R,S
65
CR
DS

A P,R
B P,Q
66
C P,S
D Q,S

CHEMISTRY

45. rn = a0 x n2 , r4 = a0 x 42 = 16 a0
h 4h h h
8 a0
2 r4 2 x16a0 8 a0 mv
Mv = 4.
5.50 2
i 3; Cr H 2 O 5 Cl Cl2 .H 2O
Cr H 2O 5 Cl 2Cl
1.86
46.

47. Cathode : 2H2O +2e- H2+2OH- ; Anode : 2Cl- Cl2 +2e-
1x5 x965 0.05
0.05; OH - 1x101 ; H 1.0 x10 13
96500 0.5
Mol of OH- formed = zit =
48. The correct order is : B<Be<O<N. The fully filled 2s 2 subshell of Be is
extra stable and more closer to the nucleus. The half filled 2p 3 subshell of N
has also extra stability

49. Ca3 P2+6H2O 3Ca(OH)2 + PH3
Phosphine
4
Fe CN 6
51. : Fe(II) -3d6 ; inner orbital complex (d2sp3) ; n = 0
4
Mn CN 6
: Mn(II)-3d5 ; inner orbital complex (d2sp3); n = 1
 3
Co NH 3 6
: Co(III)-3d6; inner orbital complex(d2sp3); n= 0
2
Ni NH 3 6
: Ni(ii) -3d8 ; NH3, a strong ligand, can not make two
3d-orbital available by forcing the electrons paired up. Hence, outer orbital
complex (sp2d2);n = 2

FeF6
3

52. : Fe(III) -3d5 ; high spin complex (sp3d2) , n = 5

MnCl4
2

: Mn(II) 3d5 , high spin complex (sp3) , n = 5

NiCl4
2

: NI(II) -3d8 , high spin complex (sp3),n = 2

53. The compound dissociates into 5 ions as :
2
Co NH3 6 Co NH 3 NO 2 5 2 Co(NH 3 ) 6 3 Co NH 3 NO
2 5
3
2 3

The effective molality = 0.01x 5 = 0.05 ; Tf = 1.86x 0.05 = 0.0930C
54. Al is more electropositive than Fe, Cr and Mn.
55. The outer electronic configuration of platinum in ground state is 5d 96s1.
The Pt2+ ion formed by the loss of two electrons has outer electronic
configuration of 5d8. In the presence of strong ligands (NH 3 molecules) two
unpaired electrons in the 5d subshell pair up. This followed by dsp 2
hybridisation resulting in the formation of four hybridised vacant orbitals
which accommodate four pairs of electrons from four ligands (two from
ammonia and two from Cl-). As such the resulting complex is square
planar.
56. The surface of a solid ( or liquid ) tends to attract and retain other
molecules when it is brought in contact with a gas or a solution.
57. R is the correct explanation of A
58. Grignard reagents react primarily at the less- substituted ring carbon

i)EHt32O+
atom of substituted oxiranes because comparatively it is more
electrophilic.
C6H5MgBr+H2C - CH CH3 C6H5CH2CHCH3
O
OH
0
2 Alcohol

59. C6H5MgBr+H2C - C(CH3)2 C6H5CH2C(CH3)2

O
OH
0
3 Alcohol
60. a) As Grignard reagent is formed, it would instantaneously react with the NH
present in other molecules of the same substance.
b) The reagent used ( CH3CHO and H3O+) must be numbered, viz. (i) and (ii),
otherwise it indicates that the Grignard reagent is exposed to acidic
medium which will decompose it to alkane.
c) The Grignard reagent will immediately react with the OH part of the
reagent.
So none of the three options is feasible.
61. Introduction of the first halogen is slowest, while that of the last, i.e.third is
fastest because introduction of the halogen increase the acidity of the

remaining hydrogen.
:
62. CX3 is a better leaving group and stabilized due to dispersal of the
negative charge by three halogens.
63. Since chloroform and bromoform are water immiscible liquids, they can be
easily separated from the aqueous solution of the carboxylate anion.
Mn 2+in MnCl42-
64. A) : 3d5 sp3 hybridization ; 5 unpaired electrons
Ni 2+in NiCl 2-4
B) : 3d8 sp3 hybridization ; 2 unpaired electrons
Cu 2+in CaCl2-4
C) : 3d9 dsp2 hybridization ; 1 unpaired electrons
Ni 2+in NI CN 4
2-

D) : 3d8-dsp2 hybridization ; no unpaired electrons

65. A)Hydrogen bonding is possible in ethyl acetoacetate (due to the
presence of enolic group) and in proteins (due to the presence of CO-NH-
grouping )

B) -Amino acids, like - amino acids, from zwitterions and also
diazotization although the diazo salts, so formed , are unstable.

C) p- Amino benzoic acid, like - and - amino acids forms zwitterions and
being 10 aromatic amine also forms, well-known , diazonium salt.
D) Aniline undergoes diazotization easily
66. Species having two nucleophilic centres, one neutral (complete octet with at
least one lp of electrons ) and other negatively charged, are known as
nuleophiles. Organic compounds in which carbon is bonded with
electronegative atom by multiple bond behave as an elctrophile as well
as nucleophile.
 Electrophilic end
A) B) R-C N
:C N
Ambident nucleophile Nucleophilic end

C)
Nucleophile,aromatic Electrophile,aromatic