GT 2 Paper 1 Solutions

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GRAND TEST ay
2d
Sec: Sr.IPLCO
Time: 9.00 AM to 12.00 Noon Max Marks:180
bs
Syllabus
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Physics : Total Syllabus

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Chemistry : Total Syllabus

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Maths : Total Syllabus

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JEE-Adv_GT_P1_QPaper
Paper-I
JEE-ADVANCE-2013-P1-Model
Time: 3:00 IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec I(Q.N : 1 10) Questions with Single Correct Choice 2 0 10 20
Questions with Multiple Correct
Sec II(Q.N : 11 15) 4 -1 5 20
Choice
Sec III(Q.N : 16 20) Questions with Integer Answer Type 4 -1 5 20
Total 20 60
CHEMISTRY:
.in
Sec II(Q.N : 31 35) 4 -1 5 20
Sec III(Q.N : 36 40)

Choice ay
Questions with Integer Answer Type 4 -1 5 20
2d
Total 20 60
MATHEMATICS:
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Sec II(Q.N : 51 55) 4 -1 5 20
Choice
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Sec III(Q.N : 56 60) Questions with Integer Answer Type 4 -1 5 20

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Total 20 60
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Sr.IPLCO space for rough workPage Page 2

PHYSICS Max Marks: 60

Section-I
(Only one option correct Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE IS correct.
1. A time varying magnetic field B B 0 tk is confined in a cylindrical region. cutting the XY
plane on a circle of radius x2 + y2 = 4. We have placed a wire frame as shown.
Segment A1A2 and A3A4 are identical quarter circles. The net emf induced in the wire
frame is equal to
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ay
2d
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a) zero b) 2 B0 c) 4 B0 d) B0
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2. Two particles A and B start moving from the same point on the X-axis. The velocity
versus time graph for the particle is as shown in figure. The maximum relative
separation between the two particles will be equal to
VA VB
2 m/s
2 m/s
1 m/s
1s 2s 1s 2s time
time
1 3 5
a) m b) m c) m d) None
2 4 4
3. A ray of light is incident at the origin at an angle 60 with Y-axis as shown in figure.
2
The refractive index is a function of y according to the relation . What is the
1 y
2
value of H, shown in figure?
.in
Y
H ay
2d
X
The path of the light
followed after successive
bs
60 refraction is as shown

2 2
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a) 1 b) c) 3 1 d) None
3 3
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4. Dimensionally power of lens is equivalent to :

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E LC E B LC B
a) b) c) d)
B B LC E E LC
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5. The potential in certain region is given as V = 2x2, then the charge density of that
region is
4x 4
a) b) c) 4 0 d) 2 0
0 0
6. A disc of mass m1 radius r is released from rest in the fig shown. If the cylinder is on
the verge of slipping as well as toppling then coefficient of friction between cylinder
and table surface is :
.in
1 1
a) 1 b) c) 3 d)
2 3
7. ay
At time t = 0, some radioactive gas is injected into a sealed vessel. At time T, some
more of the same gas is injected into the same vessel. The graph representing the
2d
variation of the logarithm of the activity A of the gas with time t is
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a) b) c) d)
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8. The diagram shows an AC circuit with two voltage sources of same frequency. Find out
the value of current I shown in the fig.
V 0 cos t V 0 cos t / 2
a) I b) I
R R
V 0 cos t 3V 0 cos t
c) I d) I
R R
9. A resistor is formed in the shape of a hollow, quarter cylinder from a material of

resistivity . The length of cylinder is L, inner and outer radii are R1 and R2
.in
respectively. The resistance of this resistor between the shown terminals P and Q is
ay
2d
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2 L 2 R1
a) b) c) d)
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R 2
2
R1
2
R
L ln 2
R
2 L ln 2
L R 2 R1
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R1 R1

10. Standing waves are set up in a string of length 240 cm clamped horizontally at both
ends. The separation between any two consecutive points where displacement
amplitude is 3 2 cm is 20 cm. The standing waves were set by two traveling waves of
equal amplitude of 3 cm. The overtone in which the string is vibrating will be
a) 2nd b) 3rd c) 4th d) 5th
Section-II
(One or More options correct Type)
This section contains 5 multiple choice question. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct.
11. In the diagram shown, both the capacitors have the same capacitance C. One capacitor
has charge +q and other is uncharged. The switch is closed at time t =0. The graph
shows the variation of the charge on C1 as a function of time. Then
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charge
+q -q q1
C1 = C C2 = C S
ay
q
2d
R V time
bs
q
V
C
a) Initial value of current in the circuit is
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CV q
b) Charge present in second capacitor in steady state is
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2
CV q
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c) Value of q1 in steady state is

2
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d) Heat energy will be generated in the circuit on closing the switch

12. A uniform magnetic field B 0 k exists to the right of the plane y x tan as shown. At t =
0 a particle of mass m and positive charge q with velocity v 0 i enters in magnetic field at
origin. Then
y

(q, m)

x

Magnetic

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a) particle will come out from magnetic field after t
qB 0
2 m
b) particle will come out from magnetic field after time ay t
qB 0
2d
c) Co-ordinate of point from which particle will come out is
m v0 m v0
sin 2 , 1 cos 2 , 0
qB 0 qB 0
bs
m v0 m v0
d) Co-ordinate of point from which particle will come is sin , 1 cos , 0
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qB 0 qB 0
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13. In the shown circuit reading of voltmeter V1 and V3 are 300 volt each then choose
correct option/options if reading of ammeter is 10A :
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a) V2 = 300 V b) V2 = 400 V c) R 10 d) R 20
ay
2d
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14. Two large on conducting plates having surface charge densities and ,
respectively, are fixed d distance apart. A small test charge q of mass m is attached to
two non conducting identical springs of spring constant k as shown in the adjacent fig.
The charge q is now released from rest with springs in natural length. Then q will
[neglect gravity]
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a) perform SHM with angular frequency
2k
ay
2d
m
q
b) perform SHM with amplitude
bs
2 k 0
c) not perform SHM, but will have a periodic motion if charges are removed on plates
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as well as on m
d) remain stationary
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15. A satellite close to the earth is in orbit above the equator with a period of rotation
1.5hours. If it is above a point P on the equator at some time, it will be above P again
after time
a) 1.5 hours
b) 1.6 hours if it is rotating from west to east
c) 24/17 hours if it is rotating from east to west
d) 24/17 hours if it is rotating from west to east
Section-III
.in
(Integer value correct Type)
This section contains 5 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive) ay
16. A metal rod AB of length L rotates with a constant angular velocity about an axis
2d
passing through O and normal to its length. The magnitude of emf induced between
mL
2 2
bs
ends A and B in the absence of external magnetic field is . Hence m is mass of

ke
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electron and e is charge on electron. Find the value of k.

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8
17. The centre of mass of a disc of radius m is moving with a velocity of 4 m/s on a
5
horizontal plane. The angular velocity of the disc about it's centre is 5 rad / s . Find the
radius of curvature of the point 'P shown in the figure in meter?
5 rad / s
4 m/s
P
18. A uniform vertical cylinder is released from rest when its lower end just touches the
liquid surface of a deep lake. Calculate maximum displacement of cylinder (in meter).
1
Take 4 m and
2
.in

ay

2d
19. A sample of radioactive nuclide A150 is having half life 2 hours and it produce B146
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after emitting particle. Initially in sample only A was present having mass 50 gm.
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After four hours difference in mass of sample (A + B) is x gm then value of x is.

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20. 0.01 moles of an ideal diatomic gas is enclosed in an adiabatic cylinder of cross
sectional area A = 104m2. In the arrangement shown, a block of mass M = 0.8 kg is

placed on a horizontal support, and another block of mass m = 1kg is suspended from a
spring of stiffness constant k = 16 N/m. Initially, the spring is relaxed and the volume
of the gas is V = 1.4 104 m3. What is the angular frequency (in rad.s1) of the
suspended system ? (P0 = 105 N/m2, g = 10 m/s2)
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2d
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CHEMISTRY Max Marks: 60

Section-I
21. Standard enthalpy and standard entropy of vaporization of water are + 40 kJ mol -1 and
+ 120 J mol-1 K-1 respectively. Vapour pressure of water at 27C expressed as
ln PH
2O
will be (consider Standard temp. to be 300K)
(A) 1.6 (B)1.6 (C) 6.1 (D) 3.2

22. Copper I chloride (CuCl) used in fireworks emits blue light of wave length 450 nm
when heated to high temperature. What is the increment of energy that is emitted at
this wave length?
.in
23 23
(A) 44 10 J (B) 44 10 kJ (C) 4 .4 1 0 2 3 J (D) 4 .4 1 0
23
kJ
23. In an alloy of Mn Si, atoms of Mn are at 50% of corners and that of Si are at
ay
remaining 50% corners of a primitive cubic crystal lattice. If Mn also occupies cubical
2d
void, atomic % of Mn in the alloy will be
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(A) 25% (B) 50% (C) 75% (D) 33.33%

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24. For the cell representation A g ( s ) | A g B r( s ) | K B r( aq ) C 1

|| K C l ( aq ) C | A g C l ( s ) | A g ( s ) ;
2
which of the
following facts are TRUE?

P: It is an example of concentration cell, if the concentration of metal ion used in
both the half cells is identical
Q: This cell can also be represented as A g | A g K A gB r
|| A g

K sp
| Ag
sp
A gC l
Br
Cl

R: It is an example of electrolytic concentration cell

S: The cell reaction would be spontaneous if K sp A gB r C l K sp A gC l B r
A) P (B) R (C) QS (D) PQRS

25. Aqueous solution of which of the following halide is oxidising
.in
a) PC l3 b) N C l3 c) PC l5 d) AsC l3
26. Which of the following pair of salts forms precipitate with excess of N H 4 OH
a) C uSO 4 , C dSO 4 b) C u N O3 2 , Z nSO 4 c)

ay
FeC l3 , AlC l3 d) all the above
2d
3 2 2
27. I: C o H O ; II : C u H O ; III : P t F IV : C o H O F The correct
2 6 2 6 6 2 3 3

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statement about the hybridisation of underlined atom of above complexes :

a) I, II, III, IV sp d b) I, II, III, IV d 2 sp 3
3 2
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c) I & III d sp d) I & IV sp d

2 3 3 2
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28. Consider the following sequence of reactions. The products (X) and (Y), respectively,
are:

C 2 H 5 C l D X 3 Y
KCN H O
M SO , heat prolonged heat
a) C 2 H 5C N and C 2 H 5C H 2 N H 2 b) C 2 H 5C N and C 2 H 5 CONH 2
c) C2H 5 NC and C 2 H 5 NHCH 3 d) C 2 H 5C N and C 2 H 5C O O H
29. Consider the following reactions. Their final product C is:

CH 3
C O B
C
CH 3
P h3 P C H 3 C H 2 B r
A :, A C 2 H 5O N a
B :,
Ph3 PCH 2CH 3 Br

a) b) Ph3 P C H C H 3
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CH 3 CH 3
c)
CH 3
C CH CH 3
d)
CH 3
ay CH CH CH 2
2d
bs
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OMe 'X'.
30. What should be ' X '?
O
O
OMe OMe
a) b)
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:O:
OMe
c)
ay
d) The reaction will not proceed.
2d
bs
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Section-II
31. Which of the following is/are CORRECT?
(A) One mole of a liquid mixture containing one mole each of liquid A and liquid B is
PT
o o
vaporized. Total vapour pressure is found to be PA PB
(B) A solution of HCl in water forms higher boiling azeotrope which can be distilled
with same composition.
(C) A 0.1 M solution of H gCl 2 in water freezes at 0.186C.It concludes that H gCl 2
does not ionise in water ( K f ) H O 1.86 Kkgm ol 1

2
(D) Ideal solutions can be distilled to separate the pure components.
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32. Which of the following is/are TRUE?
A) In acid medium SnO 2 ay
forms a positively charged colloidal sol containing S n O 2 S n 4
B) In basic medium forms a negatively charged colloidal sol
2d
SnO 2
containing SnO 2 SnO 32

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C) SnO 2 is amphoteric in nature

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(D) SnO 2 neither reacts with acid nor with base

33. Which of the Hydrohalic acid cannot form acidic salt
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a) HF b) HCl c) HBr d) HI
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34. In which of the following reaction t-butylbenzene is formed?

a) Benzene + iso-butyl chloride, A lC l 3
b) Benzene + C H 3 2 C C H 2 3
BF .HF

H SO
c) Benzene + t-butyl alcohol 2 4
d) Benzene + C H 3 2 C C H 2 3

A lC l
35. Which of the following compound will give positive Tollens test?
O OH
a) b)
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C H 3 C HO
OCH 3
CH 3CH 2CH 2CH 2CH OCH 3

ay
CH 3 CH
2d
OH OCH 3
c) d)
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Section-III
from 0 to 9 (both inclusive)
dp
36. For the reaction 2 NO H 2 N 2 O H 2 O , value of changes from 1.5 torr s-1 to
dt
0.25 torr s-1 when pressure is changed from 360 torr to 150 torr with respect to
NO keeping pressure of hydrogen to be constant. If pressure of NO is kept constant, it
dp
is observed that value of changes from 1.6 torr s-1 to 0.8 torr s-1 with respect to
dt
pressure of hydrogen from 300 torr to 150 torr. Order of the reaction will be
.in
log 2 0.301; log 3 0.477; log 5 0.699; log 7 0.845
37. The no. of stereo isomers of P t gly

3

ay
is _____
2d
38. Among N F3 , C C l4 , SF6 , PC l5 , SiF4 , BC l3 . The no. of halides which cant under go
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hydrolysis at ordinary conditions ___

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39. How many of the following would produce a tertiary alcohol on treatment with
C H 3 C H 2 M gBr ?
O O
(i) O ii) Ph iii) Cl
O O
O
iv) O v) H C H vi)
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O
vii)
CH 3 C N
viii) C O2
ay ix)
2d
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40. How many enentiomeric forms are possible for glucose molecule?
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MATHEMATICS Max Marks: 60

Section-I
1
41. Range of the function f ( x) x x
is (where . represents fractional part
3 9 1
function)
a) 1, 2 b) 1, 2 c) 1, 2 d) none of these
42. A circle touches two of the smaller sides of ABC and has its centre on the greatest
side where a > b > c. If r is the radius of the incircle and r1 is the radius of the given
circle, then
.in
r1 r1 r1 r1
a) 0 1 b) 1 2 c) 2 3 d) 3 4
r r r r
43. If f : 0,1 0, then the number of mappings f such that

ay 1
0
f ( x ) dx 1,
1
xf ( x ) dx
0
2d
1
and x 2 f ( x ) dx 2 is
bs
a) 2 b) 1 c) 0 d) Infinite
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44. Five numbers out of 1, 2, 3,.......,9 are written randomly at four vertices and centroid of
a regular tetrahedron. The probability that 6 is written at centroid of tetrahedron is
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a) 5/9 b) 4/9 c) 8/9 d) 1/9

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45. Let A, B, C, D be distinct points on a circle with centre at O. If there exists non zero
real numbers x and y such that xO A yO B xO B yO C xO C yO D xO D yO A then
a) ABCD is a rectangle b) ABCD is a square

c) ABCD is a rhombus d) nothing can be said
46. The number of values of k for which x 2 k 2 x 2 k x 2 kx 2 k 4 is a perfect
square is
a) 1 b) 2 c) 0 d) none of these
2 sin 2 x cos x
47. The values of a and b which satisfy dx a log sin x 1 b log sin x 3 c ,
4 cos x 4 sin x
2
are respectively
3 11 3 11 3 11 3 11
a) b) c) , d) ,
.in
, ,
2 2 2 2 2 2 2 2
48. The number of natural numbers less than or equal to 2012, which are relatively prime
to 2012 is
ay
2d
a) 1004 b) 1006 c) 1005 d) 4
49. Let O be an interior point of ABC such that O A 2 O B 3O C 0 . Then the ratio of area
bs
of ABC to area of AOC is

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a) 2 b) 3/2 c) 3 d) 5/3
50. Let p( x) x x 1 has zeroes and g ( x ) x 2. Then the product
5 2 2
x1 , x 2 , x3 , x 4 , x 5
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g ( x1 ) g ( x 2 ) g ( x 3 ) g ( x 4 ) g ( x 5 ) is equal to
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a) 1/23 b) 23 c) -23 d) none of these

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Section-II
51. Let f x x 1 x x 1 . Then which of the following is/are true?
a) f 1 3 b) f is continuous at x 1
c) f is not differentiable at x = 0 d) Rf 1 5
52. Let a1 a2 a3 a4 a5 a6
p a1 a 2 a 3 ........ a 6
q a1 a 3 a 3 a 5 a 5 a1 a 2 a 4 a 4 a 6 a 6 a 2
r a1 a 3 a 5 a 2 a 4 a 6 . Then the equation 2 x px qx r 0 has

3 2
a) one root between a1 , a 2 b) two roots between a1 , a 3
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c) two roots between a1 , a 4 d) two roots between a 3 , a 5
53. If f : N 2 , 2 such th a t f ( x ) sin x cos x ,

ay
then f(x) is
2d
a) one-one b) onto c) many-one d) into
A hyperbola has center C and one focus at P(6,8). If its two directrices are
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54.
3x+4y+10 = 0 and 3x+4y-10 = 0, then
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a) CP = 10 b) eccentricity = 5
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c) CP = 8 d) eccentricity = 5 /2
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55. If n different objects are distributed at random among n +2 persons so that each person
can get any number of things (i.e., 0, 1, 2, ., n things) then the probability that
n 1 !
a) exactly 2 persons will get none of the objects is n 1
2. n 2
C 3 n 1 C 2 n 2 !
n2 n
b) exactly 3 persons will get none of the objects is

n 2
n
n. n 1 . n 1
2
c) exactly 3 persons will get none of the objects is n 1

12 n 2
n . n 1
2 2
d) exactly 2 persons will get none of the objects is n 1

n 2
Section-III
.in
from 0 to 9 (both inclusive)
56. The least positive integral value of real
ay
so that the equation
2d
x a x c x e x b x d 0, a b c d e has distinct real roots is______
bs
57. Let z1 , z 2 , ......., z n be equi-modular non-zero complex numbers such that

n n zj
z1 z 2 ....... z n 0 . Then Re is equal to____________
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j 1 k 1 z k
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2
1 1 1
58. The number of distinct terms in the expansion of x yz is m and that
xy yz xz
2
1 1 1
in the expansion of x y z is n, then m n _________
x y z
59. Let A be a 3 3 matrix with real entries. If AA T I, then the value of det( A I 3 ) _____
2
60. Number of divisors of a natural number n is 105 and n is divisible by exactly 3 distinct
prime numbers and is having the least value. The number of divisors of 4k +1 form
(where kN ) of the number n is ____
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ay
2d
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Physics : Total Syllabus

Chemistry : Total Syllabus

Maths : Total Syllabus

Sec III(Q.N : 36 40)

+Ve - Ve No.of Total

Sec I(Q.N : 41 50) Questions with Single Correct Choice 2 0 10 20

Sec III(Q.N : 56 60) Questions with Integer Answer Type 4 -1 5 20

Sr.IPLCO space for rough workPage Page 2

PHYSICS Max Marks: 60

plane on a circle of radius x2 + y2 = 4. We have placed a wire frame as shown.

Sr.IPLCO space for rough workPage Page 3

value of H, shown in figure?

4. Dimensionally power of lens is equivalent to :

Sr.IPLCO space for rough workPage Page 4

Sr.IPLCO space for rough workPage Page 5

9. A resistor is formed in the shape of a hollow, quarter cylinder from a material of

Sr.IPLCO space for rough workPage Page 6

a) 2nd b) 3rd c) 4th d) 5th

c) Value of q1 in steady state is

d) Heat energy will be generated in the circuit on closing the switch

Sr.IPLCO space for rough workPage Page 8

correct option/options if reading of ammeter is 10A :

Sr.IPLCO space for rough workPage Page 9

Sr.IPLCO space for rough workPage Page 10

b) 1.6 hours if it is rotating from west to east

c) 24/17 hours if it is rotating from east to west

d) 24/17 hours if it is rotating from west to east

ends A and B in the absence of external magnetic field is . Hence m is mass of

electron and e is charge on electron. Find the value of k.

Sr.IPLCO space for rough workPage Page 11

After four hours difference in mass of sample (A + B) is x gm then value of x is.

Sr.IPLCO space for rough workPage Page 12

sectional area A = 104m2. In the arrangement shown, a block of mass M = 0.8 kg is

suspended system ? (P0 = 105 N/m2, g = 10 m/s2)

Sr.IPLCO space for rough workPage Page 13

CHEMISTRY Max Marks: 60

(A) 1.6 (B)1.6 (C) 6.1 (D) 3.2

(A) 25% (B) 50% (C) 75% (D) 33.33%

Sr.IPLCO space for rough workPage Page 14

24. For the cell representation A g ( s ) | A g B r( s ) | K B r( aq ) C 1

following facts are TRUE?

R: It is an example of electrolytic concentration cell

A) P (B) R (C) QS (D) PQRS

a) C uSO 4 , C dSO 4 b) C u N O3 2 , Z nSO 4 c)

statement about the hybridisation of underlined atom of above complexes :

c) I & III d sp d) I & IV sp d

Sr.IPLCO space for rough workPage Page 15

a) C 2 H 5C N and C 2 H 5C H 2 N H 2 b) C 2 H 5C N and C 2 H 5 CONH 2

c) C2H 5 NC and C 2 H 5 NHCH 3 d) C 2 H 5C N and C 2 H 5C O O H

29. Consider the following reactions. Their final product C is:

Ph3 PCH 2CH 3 Br

Sr.IPLCO space for rough workPage Page 16

30. What should be ' X '?

Sr.IPLCO space for rough workPage Page 17

does not ionise in water ( K f ) H O 1.86 Kkgm ol 1

(D) Ideal solutions can be distilled to separate the pure components.

containing SnO 2 SnO 32

C) SnO 2 is amphoteric in nature

(D) SnO 2 neither reacts with acid nor with base

Sr.IPLCO space for rough workPage Page 18

34. In which of the following reaction t-butylbenzene is formed?

CH 3CH 2CH 2CH 2CH OCH 3

Sr.IPLCO space for rough workPage Page 19