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3. X mL of 0.05 M solution of a double salt Na2CO3 NaHCO3 2H2O is titrated against 0.05 M
HCl. When phenolphthalein is used as indicator A mL of HCl is required and B mL of the
same acid is required (separately) when methyl orange is the indicator. Find the ratio B/A.
1
(a) 3 (b)
3
(c) 5 (d) 2
5. The cubic unit cell of Al(molar mass 27 g mol1) has an edge length of 405 pm. Its density is
2.7 g cm3. The cubic unit cell is
(a) face centered (b) body centered
(c) primitive (d) hcp
6. How many isomeric bromides having molecular formula C6H13Br on conversion into
Grignard reagent followed by treatment with water would yield 2, 3-dimethylbutane?
(a) 1 (b) 2
(c) 3 (d) 4
8. In the reaction,
2CuCl2 + 2H2O + SO2 A + H2SO4 + 2HCl
A is
(a) Cu2Cl2 (b) Cu
(c) CuSO4 (d) CuS
9. Statement-1: Ortho-substituted anilines are normally weaker base than aniline whether the
substituent is electron releasing or electron withdrawing in nature.
Statement-2: Substituent at ortho position hinders the approach of H2O molecule to solvate
the conjugate acid due to steric crowding.
(a) A (b) B (c) C (d) D
11. Statement-1: The acidic character of hydrides of the group 16 elements increases in the
order H2O < H2S < H2Se < H2Te
Statement-2: Oxygen is more electronegative than sulphur.
(a) A (b) B (c) C (d) D
SECTION III
Linked Comprehension Type
This section contains 2 paragraphs C13 C18. Based upon the paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.
PassageI
The electrons in a poly-electronic atom are filled one by one in order of increasing energy
level. The energy of subshells and orientation of orbitals depends upon the values of three
quantum numbers (i.e., n, l and m respectively) derived from Schrodinger wave equation.
However, the different orbitals of a subshell possess same energy level and are called
degenerate orbitals but their energy level changes in presence of magnetic field and the
orbitals are non-degenerate. A spectral line is noticed if an electron jumps from one level to
other. The paramagnetic nature of element is due to the presence of unpaired electron(s).
13. Which in each pair is electronically most stable ion: Cu+ or Cu2+ and Fe2+ or Fe3+
(a) Cu+, Fe3+ (b) Cu2+, Fe3+
2+ 2+
(c) Cu , Fe (d) Cu+, Fe2+
Passage-II
Any nucleophilic substitution reaction proceeds via two processes:
(a) SN1 i.e. substitution nucleophilic unimolecular
(b) SN2 i.e. substitution nucleophilic bimolecular
The examples which serve for these are the solvolysis of alkyl halides. Let solvolysis of tert-
butyl bromide takes place via two conditions given below.
Reaction A: Here tert-butyl bromide was refluxed with ethanol containing small amount of
sodium ethoxide. The reaction was proceeding with a half life of only a few minutes and this
resulted in products (A) an ether and (B) C4H8. The rate for the reaction is given by the
expression,
Rate = k1 [tert-butyl bromide] + k2 [tert-butyl bromide] [C2H5O]
Reaction B: Here tert-butyl bromide was refluxed with a mixture of solvents containing 70%
ethanol and 30% water.
17. Here the two constants k1 and k2 respectively for the reaction A are for
(a) SN1 and SN2 respectively. (b) SN1 and E2 respectively.
(c) E1 and SN2 respectively. (d) E1 and SN1 respectively.
18. During substitution reactions with weak base via carbocation mechanism
(a) SN1 predominates (b) SN2 predominates
(c) E1 predominates (d) E2 predominates
1.
Column I Column II
(A) Variation of equilibrium constants with 1. Kirchoffs equation
temperature
(B) Hneutralisation of HCl. 2. Hesss law
(C) Law of conservation of energy. 3. Vant Hoff equation
(D) Variation of heat of reaction with 4. 57.2 kJ/equivalent
temperature
2.
Column I Column II
(A) Cellulose 1. Anomers
(B) -D glucose and -D-glucose 2. Epimers
(C) Glucose and Mannose 3. Polymer
(D) Protein 4. can be hydrolysed
1. How many mole of electrons are required to reduce 1.5 mole of nitro-benzene into aniline,
if current efficiency, in this experiment is 50%.
2. What is the pH of a mixture obtained by mixing 75 ml M/5 HCl and 25 ml M/5 NaOH
aqueous solution?