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The H f of FeCl 2 (s) = -399.4 kJ. FeCl3(s) forms when 1 mole of FeCl2 reacts with mole of
o
4.
Cl2(g). The enthalpy change of that reaction (Ho) is -57.7 kJ. What is the H f of FeCl3 (s)?
o
Ans: -457.1 kJ
SK027 / CHAPTER 1 : THERMOCHEMISTRY / amalkebajikan05 / HESSS LAW
5. Use the thermochemical equations shown below to determine the molar enthalpy of combustion for
methane. Ans: -890.36 kJ
6. Use the thermochemical equations shown below to determine the enthalpy of the reaction of iodine
and hydrogen to produce hydrogen iodide. I2(s) + H2(g) 2HI(g) Ans: 51.8 kJ
Ans: -890.36 kJ
7. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2H2O(l) 2H2(g) + O2(g) Ans: 2288 kJ
8. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
C(s) + 2H2(g) CH4(g), Ans: -74.8 kJ
9. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ans: 3484 kJ
10. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
3Fe2O3(s) 2Fe3O4(s) + O2(g) Ans: 465 kJ
11. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
cis-C4H8(g) + 6O2(g) 4CO2(g) + 4H2O(g) Ans: -675.7 kJ
12. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
H2O(l) H2(g) + O2(g) Ans: 143.0 kJ
13. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
Ans: H = -57.09 kJ
o
NO(g) + O2(g) NO2(g)
Given:
N2(g) + O2(g) NO(g) Hfo = +90.29 kJ
Given:
3C + 4H2 C3H8 Hfo = -103.8 kJ
C + O2 CO2 Hfo = -393.5 kJ
H2 + O2 H2O Hfo = -285.8 kJ
Given:
8C + 9H2 C8H18 Hfo = -219.9 kJ
C + O2 CO2 Hfo = -393.5
H2 + O2 H2O Hfo = -285.8 kJ
16. Calculate the enthalpy change for the reaction C2H4(g) + H2(g) C2H6(g)
Ans: -137.0kJ
Given:
C2H4(g) + 3O2(g) 2CO2(g) + 2H2O(l) H = -1410.9kJ
2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(l) H = -3119.4kJ
2H2(g) + O2(g) 2H2O(l) H = -571.6kJ
SK027 / CHAPTER 1 : THERMOCHEMISTRY / amalkebajikan05 / HESSS LAW
17. Calculate the enthalpy change for the reaction ; PbCl2 + Cl2 PbCl4
Ans: H = +30.2kJ
Given:
Pb + 2Cl2 PbCl4 H = -329.2 kJ
19. Calculate the enthalpy change for the reaction ; 2P + 5Cl2 2PCl5
Ans: H =-749.8 kJ
Given:
21. Calculate the enthalpy change for the reaction ; H2S(g) + 4F2(g) 2HF(g) + SF6(g)
Ans: H =+1745 kJ
Given:
Sr (s) C(graphite) 3
2 O2 (g) SrCO3 (s)
The information available is
(1) Sr (s) 1
2 O2 (g) SrO (s) H -592 kJ
(2) SrO (s) CO2 (g) SrCO3 (s) H -234 kJ
(3) C(graphite) O2 (g) CO2 (g) H -394 kJ
-1220 kJ
2) The combination of coal and steam produces a mixture called coal gas, which can be used as a fuel or as a starting
material for other reactions. If we assume coal can be represented by graphite, the equation for the production of
coal gas is:
+ 15.3 kJ
3) One reaction involved in the conversion of iron ore to the metal is:
FeO (s) CO (g) Fe (s) CO2 (g)
Calculate the standard enthalpy change for this reaction from these reactions
of iron oxides with CO :
(1) 3 Fe2O3 (s) CO (g) 2 Fe3O4 (s) CO2 (g) H - 47 kJ
(2) Fe2O3 (s) 3 CO (g) 2 Fe (s) 3 CO2 (g) H - 25 kJ
(3) Fe3O4 (s) CO (g) 3 FeO (s) CO2 (g) H 19 kJ
-14 kJ
4) Find the H for the reaction below, given the following steps and subsequent H values:
N2H4(l) + H2(g) 2NH3(g)
-18kJ
SK027 / CHAPTER 1 : THERMOCHEMISTRY / amalkebajikan05 / HESSS LAW
5) Find the H for the reaction below, given the following steps and subsequent H values:
H2SO4(l) SO3(g) + H2O(g)
72kJ
6) Find the H for the reaction below, given the following steps and subsequent H values:
H2(g) + Cl2(g) HCl(g)
-230kJ
7) Find the H for the reaction below, given the following steps and subsequent H values:
C2H2(g) + 5/2O2(g) 2CO2(g) + H2O(g)
-705kJ
8) Find the H for the reaction below, given the following steps and subsequent H values:
HCl(g) + NaNO 2(s) HNO2(l) + NaCl(s)
-78kJ
9) Find the H for the reaction below, given the following steps and subsequent H values:
Zn(s) + 1/8S8(s) + 2O2(g) ZnSO4(s)
10) Calculate the Hformation and give the overall reaction of CS2 from its elements, given the steps involved are as
follows: