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The main lithology in the Kinta Valley is According to Waltham, Bell and Culshaw,(2007)
limestone. Foo(1983) has named the limestone the dissolution rate of a rock are generally affected
formation in Kinta valley with the name of Kinta by the solubility and specific solution rate constant
Limestone . According to Metcalfe(2013), Kinta of the constituent mineral, degree of saturation of
Valley limestone is also called as Kanthan the solvent, area presented to the solvent and the
Limestone by few other researchers. The Kinta motion of the solvent. Limestone has very low
Limestone is estimated to be aged between solubility in pure water and the key factor that
Devonian to Permian and deposited in a shallow increases its solubility is carbon dioxide. When the
marine environment(Suntharalimgam,1968).Much carbon dioxide dissolves in water, the solution
of the limestone is found beneath the surface where becomes acidic which later on produces bicarbonate
it underlies the tin ore bearing alluvium for which radical when it reacts with the limestone. The
the Kinta Valley is famous (Fatihah and Djin, 2003). bicarbonate radical produced are highly soluble in
Limestone hills at Kinta valley are featured with water (Waltham, et al., 2007). Most of the carbon
beautiful karstic morphology and the base of the dioxide content is obtained during the
hills are usually contains swamp and notches due to decomposition of organic material. Carbon dioxide
dissolution(Simon, et al., 2015). which is released during the decomposition is taken
into solution by rainwater and this is the prime
The Kinta Valley Schist occurs mainly below the source of chemically aggressive groundwater in
limestone though some parts are found to interbed limestone karst Waltham et al. (2007) claims that
with the Kinta Limestone. About the end of the karst features are developed better in tropical region
Permian, the limestone and schist were probably due to the higher amount of rainfall and high
folded and metamorphosed during this time of content of carbon dioxide in soil.
period. During very Late Triassic, these Paleozoic
rocks(limestone and schists) were intruded by the
Ford and Williams (1989) also states that an are mainly contributed by fracture formation.
organic complex (ion effect and mixing corrosion) Subsurface solution drainage and cave development
is an additional factor which affects the limestone are resulted from secondary permeability (Jain,
dissolution. When the saturation level is reached, 2014). Jain (2014) also states apart from fracture,
the dissolution of limestone become slow and faults and folds also contribute in karst
finally ceases. The site where aggressive development.According to Jain (2014) again karst
water( acidic water) first meets the rock surface and developments are also affected by topographic
rockhead beneath a soil cover is the place where the relief. Elevation difference between two points on a
dissolution process will occur at the maximum level surface is referred as topographic relief.
and this accounts for pinnacled rockheads and Topographic relief largely affects the hydraulic
sinkholes that narrow downwards into small gradient which controls the driving force of river as
fissures(Williams,1985). Continued dissolution at greater the hydraulic gradient, the better the karst
depth in a karst are due to rapid transmission of development.
unsaturated waters along open conduits which is the
impact of mixing corrosion where renewed Jain (2014) further states that karstification is
dissolution is possible after two saturated waters also affected by mechanical erosion by water apart
mix and become unsaturated(Bogli,1964). from the dissolution process. When it comes to
dissolution of carbonate rock, carbon dioxide,
calcium carbonate and water are the three
2.3 FACTORS AFFECTING KARST components that should be take count. Besides that,
DEVELOPMENT Jain (2014) also states that influx of fresh
aggressive water is the key reason for the most of
According to Jain(2014) karst development are limestone dissolution process. Apart from
largely affected by several factors. Among the atmospheric carbon dioxide, dissolution of
factors that have significant impact on karst limestone is also further aided by dissolved organic
development are lithology, structure, topographic acid from soil and vegetations.Jain (2014) also
relief, hydrology and climate.Karstification is states karst developments are also affected by
largely affected by lithology and it is primarily climate and he believes the ideal climate for
subjected to the carbonate content or other soluble karstification process to occur at the optimum level
mineral content of the rock (Jain,2014). Limestone is tropical climate. Karst is better developed in
and Dolomite are among the dominant rock type tropic and temperate environment due to greater
that undergoes karstification apart from gypsum and amount of rainfall in the region. Besides that, this
other soluble rock bodies. Besides that, the purity of environment also has high amount of carbon
the rock especially limestone also affects the karst dioxide level in atmosphere and soil.
development as purer the limestone, the better the
development of karst morphology (Jain, 2014). 2.4 CARBONATE RESERVOIR
Jain (2014) also states karst development is also According to Schlumberger (2008) carbonate
influenced by structure aspect mainly fracture. reservoir matters to oil company as the most of
Secondary permeability on limestone and dolomites world hydrocarbon are held in carbonate reservoir
and it is estimated 35-40% of world gas reserve and
55-60% of world oil reserve ids reserved in 3.1 FIELD OBSERVATION
carbonate reservoir all over the world. Besides that,
Dominguez(1992) states that discovery of the Karst features and factors affecting karstification
major oil resources in carbonate rocks in the Middle process were determined through the field
East after World War 1 has made carbonate observation. Photographs are taken to aid the
reservoir very important to the petroleum industry. interpretation of the karst features.
Carbonate reservoirs are made of by permeable and
porous rock. According to Afifi(2005) carbonate 3.2 X-RAY DIFFRACTION (XRD) ANALYSIS
reservoir that has undergone clastic sediment infill
or karstification can be found worldwide. The XRD analysis was used for mineral identification
porosity of the carbonate rocks includes three in order to determine the purity of the limestone.
genetic categories which is purely fractured When X-ray radiation passes through the matter,
porosity, purely diagenetic porosity and purely diffraction where X-rays are emitted at a certain
depositional porosity and each porosity type angles are based on the spaces between the atoms
distinctly represents different geological process organized in crystalline structures called planes. The
(Ahr, 2012). Carbonate reservoirs are largely XRD analysis required crushed rock sample taken
affected by secondary porosity (purely fractured from the outcrop in powder form.
porosity and purely diagenetic porosity).
Mazzullo(2004) states that cavernous and vuggy 3.3 PETROGRAPHY ANALYSIS
porosity are the major contributors in hydrocarbon
accumulation such as in Arbuckle Group reservoir Pore shape and pore types were determined
in Kansas. through the comprehensive petrography analysis.
All samples are stained with blue dyed epoxy using
Fluid flow in the carbonate reservoir are totally the vacuum technique to facilitate the recognition of
different from fluid flow in clastic reservoir as fluid pore spaces.
in the carbonate reservoir flow through cavernous ,
vugular and fractured limestone in carbonate 3.4 Scanning Electron Microscopy (SEM)
reservoir and this is due to carbonate which have
more complex pore system compared to other types In carbonate, SEM is used for analysis of
of rocks Dominguez(1992). Besides that, carbonate original depositional textures, structures, and
reservoirs with cavernous structure have better secondary features generated during diagenesis.
permeability compared to clastic reservoir model. Back scattered electron mode is particularly well
suited to the study pore shape and to measure the
pore size.
METHODOLOGY
3.5 MERCURY INJECTION
Throughout the area of study, field works are POROSIMETRY (MIP)
conducted. Rock samples were collected during the In carbonate, mercury injection porosimetry
field work and were used for analysis later on. analysis was used to determine porosity and the
permeability level generated during the dissolution carbonate rock is affected by the purity of the rock.
process. This analysis provides precise porosity and As the purity of carbonate rock (limestone or
permeability level in the rock sample, dolomite) increase the better the development of
karst morphology.
Base on the XRD result of two rock sample from
the study area, the carbonate rock at study area can
RESULT AND DISCUSSION be considered to have high purity level. From the
XRD peaks generated as shown in (figure 2) rock
samples consists mainly carbonate compounds. The
4.1 KARST DESCRIPTION AND
major peaks in the graph represents calcite and
CATEGORIZATION
dolomite compounds. Both samples have one
calcite peak at 29.43 and the rest major peaks
Table 1: Karst features in Kinta Valley
represents dolomite compound. Carbonate
Karst Stalactites Shawls Sinkholes
compounds counts makes up the major counts of
Tower
rock samples and this indicates the carbonate rock
Cave Stalagmite Flowstone Notches
at the study area have high level purity
s
Limestone Column Cave Rimstone .
Curtains pearls
4.2.3 Hydrogeology
4.2.4 Climate
CONCLUSION
Karst can be defined as a distinctive topography
in which the landscape is largely shaped by
dissolving action of water on carbonate rocks. This
process took about thousands of years to produce an
unusual surface and subsurface features. Base on
Figure 9: Pore size measurement the field observation, karst features at the study area
can be categorized into surface karst features and
4.3.2 Mercury Injection Porosimetry tropical karst features. Total of 12 karst morphology
have been discovered and described. Most of the
Rock sample where subjected for mercury karst feature discovered falls in cave deposit karst
injection porosimetry test to determine the porosity features. Factors as lithology, structure,
and the permeability level. Samples tested from the hydrogeology, climate and vegetation have a strong
study area indicate the porosity levels in the rocks influence on the karst formation. The dissolving
are in the fair quality reservoir range. A fair quality action of water on carbonate rock has induced
reservoirs porosity level ranges from 10-15% and fabric selective and non fabric selective secondary
the permeability is less than 1 millidarcy(figure 11 porosity in the karst features. Mercury Injection
Porosimetry results shows that porosity and Dominguez, G. C. (1992). Carbonate reservoir
permeability level of the karstified limestone are in characterization: a geologic-engineering analysis
fair level range, thus the reservoir quality of the (Vol. 30). Elsevier.
Kinta Limestone could be consider as potentially FATIHAH, R. and T. H. DJIN "The
fair quality and this results can be utilized as morphostructures of Kinta Valley karst
analog for Paleozoic limestone reservoir that has Foo, K. Y. (1983). The Paleozoic Sedimentary
undergone same deformational pattern as Kinta Rocks of Peninsular Malaysia-Stratigraphy and
Limestone. Correlation.Proceeding of the Workshop on
Stratigraphic Correlation of Thailand and Malaysia,
1, 1-19.
FURTHER STUDY
FORD, D.C. AND WILLIAMS, P.W., 1989.
In future, more research on karstification has to Karst Geomorphology and Hydrology, Unwin
be conducted at the study area. This is to understand Hyman, London, 60lp.
more about karstification in Kinta Valley. Besides Gobbett, DJ., 1965. The formation of limestone
that, analysis on calcite cement inside the secondary caves in Malaya.Malayan Nature Journal, 19:4-12.
pores should be conducted. This is to study the
Jain, S. (2014). Fundamentals of physical
impact of calcite cement on the permeability and
geology. Springer
the porosity of the secondary porosity. Besides that,
Meng, C. C., et al.(2014) "GEOLOGICAL
more understanding about karstification in Kinta
FEATURES OF THE KINTA VALLEY."
Valley is very important to preserve karst features
Metcalfe, I. (2013). Tectonic Evolution of the
and also to maintain Kinta Valley as a national
Malay Peninsula. Journal of Earth Sciences, 76:
heritage.
195-213
ACKNOWLEDGMENT Muhammad, R. F., & Konoo, I. (2003, March 3).
I would like to thank my supervisor, Dr.Haylay The Kinta Valley karst landscape - a national
Tsegab for the opportunity to conduct this study and heritage to ... Retrieved October 7, 2016, from
their guidances and supports they provided http://www.gsm.org.my/products/702001-100619-
throughout the course of my final year project. My PDF.pdf.
sincere appreciation also goes to Mr Choong Chee Mazzullo, S. J. (2004). Overview of porosity
Meng and Mdm Syazwani for their advices and evolution in carbonate reservoirs. Kansas
helpful comments on my works. Not to forget, my Geological Society Bulletin, 79(1/2), 20-28.
gratitude to all the lab technologists in assisting me Suntharalingam, T. (1968). Upper Palaeozoic
with the lab works. Last but not least, I would like stratigraphy of the area west of Kampar, Perak.
to thank all my family and friends for their endless Bull. Geol. Soc. Malaysia, 1, 1-15.
moral support.
Waltham, T., Bell, F. G., & Culshaw, M. (2007).
REFERENCES Sinkholes and subsidence: karst and cavernous
Ahr, W. M. (2011). Geology of carbonate rocks in engineering and construction. Springer
reservoirs: the identification, description and Science & Business Media.
characterization of hydrocarbon reservoirs in
carbonate rocks. John Wiley & Sons.