2015JEEADVP 1 Solutions

Vidyamandir Classes
CODE 5 PAPER 1
Time : 3 Hours Maximum Marks : 264
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QUESTION PAPER FORMAT AND MARKING SCHEME:
8. The question paper has three parts: Physics, Chemistry and Mathematics. Each part has three sections.
9. Carefully read the instructions given at the beginning of each section.
10. Section 1 contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme : +4 for correct answer and 0 in all other cases.
11. Section 2 contains 10 multiple choice questions with one or more than one correct option.
Marking scheme : +4 for correct answer, 0 if not attempted and -2 in all other cases.
12. Section 3 contains 2 match the following type questions and you will have to match entries in Column I with
the entries in Column II.
Marking scheme : for each entry in Column I, +2 for correct answer, 0 if not attempted and -1 in all other cases.
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VMC/Paper-1 1 JEE Entrance Exam-2015/Advanced

Vidyamandir Classes
PART I : PHYSICS
SECTION 1 (Maximum Marks : 32)

This section contains EIGHT questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
+4 If the bubble corresponding to the answer is darkened
0 In all the other cases
1. A bullet is fired vertically upwards with velocity v from the surface of a spherical planet. When it reaches its
maximum height, its acceleration due to the planets gravity is 1/4th of its value at the surface of the planet. If the
escape velocity from the planet is vesc v N , then the value of N is __________. (Ignore energy loss due to
atmosphere)
Ans.(2) For a particle at a distance r from the center of Earth, force is given by,
Gm1m2
F
r2
Force becomes one fourth, when r=2R (R=radius of Earth)
2GM
Escape velocity, Ve
R
Using conservation of energy for the given particle,
1 GmM GmM
mV 2
2 R 2R
This gives,
GM
V
R
Ve V 2
Hence, n = 2
2. Two identical uniform discs roll without slipping on two different surfaces AB and CD (see figure) starting at A
and C with linear speeds v1 and v2, respectively, and always remain in contact with the surfaces. If they reach B
and D with the same linear speed and v1 = 3m/s, then v2 in m/s is __________. (g = 10 m/s2)

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1 1 m 3
Ans.(7) Kinetic Energy of a purely rolling disc = mV 2 V 2 mV 2
2 2 2 4
Using conservation of energy on both discs and equating their final energies
3 3
mV12 mg . 30 mV22 mg . 27
4 4
3 2
3mg m V2 V1
4
2

4 g V22 9
V22 49
V2 7
3. Two spherical stars A and B emit blackbody radiation. The radius of A is 400 times that of B and A emits 104

times the power emitted from B. The ration A of their wavelengths A and B at which the peaks occur in
B
their respective radiation curves is __________.
Ans.(2) Let A be the surface area of smaller body then,

PA . 16 104 ATA4 PB A TB4
16 104 TA4
10 4
TB4
4
TA 1 TA 1

T
B 16 TB 2
By weins law,
A
T const ratio 2
B
4. A nuclear power plant supplying electrical power to a village uses a radioactive material of half life T years as
the fuel. The amount of fuel at the beginning is such that the total power requirement of the village is 12.5% of
the electrical power available from the plant at that time. If the plant is able to meet the total power needs of the
village for a maximum period of nT years, then the value of n is __________.
Ans.(3) Power available from the power plant rate of reaction
N
P = K.N
Power required by the city is 8 times less than the initial power output of plant.
P reduces 8 times in 3 half lives
n=3
5. A Youngs double slit interference arrangement with slits S1 and S2 is immersed in water (refractive index = 4/3)
as shown in the figure. The positions of maxima on the surface of water are given by x 2 p 2 m 2 2 d 2 , where
is the wavelength of light in air (refractive index = 1), 2d is the separation between the slits and m is an
integer. The value of p is __________.

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Ans.(3) Concept:
If light travels a distance x in medium, then the effective distance travelled in vaccum is x . For the given case,
consider two rays undergoing interference at a point P.
For S1 P : optical path : 1 x2 d 2
For S2 P : optical path : 2 x 2 d 2

Path difference : 2 1
1 x2 d 2
For maxima, m
1
m 1 x 2 d 2 a2 d 2
3
Solving this, we get
x 2 9.m 2 2 d 2
i.e. p = 3
6. Consider a concave mirror and a convex lens (refractive index = 1.5) of focal length 10 cm each, separated by a
distance of 50 cm in air (refractive index = 1) as shown in the figure. An object is placed at a distance of 15 cm
from the mirror. Its erect image formed by this combination has magnification M1. When the set-up is kept in a
M2
medium of refractive index 7/6, the magnification becomes M2. The magnitude is __________.
M1
1 1 1
Ans (7) In air : For mirror
V 15 10
1 1 1

V 15 10 30
V 30
30
m1 2
15
For lens : u 20
1 1 1

V2 20 10
1 1 1 1

V2 10 20 20
V2 20cm
|m2 | = 1
| M1 | | m1 | | m2 | 2
1 2 1 1
After the medium is changed, by lens makers formula: 1
F 1 R1 R2
1 1 1
1.5 1
10 R1 R2
1 3 6 1 1
1
F 27 R1 R2
Taking ratio, we get F as:
Vidyamandir Classes
70 35
F
4 2
Image formation by mirror remains unaffected by changing medium. Applying distance formula with new focal
length of lens,
1 2 1 2 1

V 20 35 V 35 20
5

20 25
V 140
140
m2 7
20
M 2 14
M 2 7 2 14 So, 7
M1 2
7. An infinitely long uniform line charge distribution of

charge per unit length lies parallel to the y-axis in the
3
y-z plane at z a (see figure). If the magnitude of
2
the flux of the electric field though the rectangular
surface ABCD lying in the x-y plane with its centre at the
L
origin is of the electric ( 0 =permittivity of free
n 0
space), then the value of n is __________.
Ans.(6) Concept:
Suppose that an infinite, charged wire is placed parallel to a
rectangular area. Then, number of field lines passing through the
rectangular area (denoted by ADC in figure) is equal to number of
field lines passing through portion ABC of cylindrical surface.
Hence flux through both of them will be same.
Let us redraw the figure from the point of view of an observer sitting y-axis.

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2 2
a a 3
Consider a cylindrical surface of length L, centred on the charged wire, having a radius r .
2 2

1
From the figure, it is clear that the flux passing through the rectangular area is equal to of the flux passing
6
through this cylindrical surface.
1 Q
So, . enc
6 0
1 L
.
6 0
n=6
8. Consider a hydrogen atom with its electron in the nth orbital. An electromagnetic radiation of wavelength 90 nm
is used to ionize the atom. If the kinetic energy of the ejected electron is 10.4 eV, then the value of n is (hc =
1242 eV nm)
13.6
Ans.(2) En
n2
hC 1242 eV nm 1242
eV
90nm 90 nm 90
1242 13.6
10.4
90 n2
13.6
13.8 10.4
n2
13.6
3 .4
n2
136
n2 4
34
n=2

This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are)
correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
2 In all other cases
9. A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at
temperature T. Assuming the gases are ideal, the correct statement(s) is(are) :
(A) The average energy per mole of the gas mixture is 2RT
(B) The ratio of speed of sound in the gas mixture to that in helium gas is 6/5
1
(C) The ratio of the rms speed of helium atoms to that of hydrogen molecules is
2
(D) The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1 / 2

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n1 f1 n2 f2
Ans.(ABD) For the mixture equivalent degrees of freedom is calculated using the relation Feq
n1 n2
53
feq 4
2
f
U nRT
2
4
For mixture, U nRT
2
U
Energy per mole: 2 RT
n
2 1 3
For mixture, 1 1
f 2 2
1 2 1 4
M mix 3
2
2 5
He 1
3 3
mix M He 6
Ratio of speed of sound =
M mix He 5
3 RT 2 1
Vrms ratio
M 4 2
10. In an aluminum (Al) bar of square cross section, a
square hole is drilled and is filled with iron (Fe) as
shown in the figure. The electrical resistivities of Al Q
8 7
and Fe are 2.7 10 m and 1.0 10 m,
respectively. The electrical resistance between the
two faces P and Q of the composite bar is :
50 mm
2475 1875 A1
(A) (B)
64 64 Fe
1875 2475 2 mm P
(C) (D)
49 132 7 mm
2.7 108 50 103

Ans.(B) R A = 30 .
A
7 2 22 10 6
1 107 50 10 3
RFe
4 10 6
5000
= .
4
Both the bars are in parallel.
R RFe
Req A
R A RFe
1875
=
64

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11. For photo-electric effect with incident photon wavelength , the stopping potential is V0 . Identify the correct
variation(s) of V0 with and 1/
(A) (B) (C) (D)
hc hc
Ans.(AC) eV0
0
1
if x

hc
eV0 hc x
0
A,C.
12. Consider a Vernier callipers in which each 1 cm on the main scale is divided into 8 equal divisions and a screw
gauge with 100 divisions on its circular scale. In the Vernier callipers, 5 divisions of the Vernier scale coincide
with 4 divisions on the main scale and in the screw gauge, one complete rotation of the circular scale moves it by
two divisions on the linear scale. Then:
(A) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the least count of the
screw gauge is 0.01 mm
(B) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the least count of the
screw gauge is 0.005 mm
(C) If the least count of the linear scale of the screw gauge is twice the least count of the Vernier callipers,
the least count of the screw gauge is 0.01 mm
(D) If the least count of the linear scale of the screw gauge is twice the least count of the Vernier callipers,
the least count of the screw gauge is 0.005 mm
Ans.(BC) For vernier Calliper.
1
1 MSD cm
8
4 1 1
1 V .S.D cm
5 8 10
h.C. 1 M .S.D 1V .S.D.
1 1 1
= cm
8 10 40
= 0.25 mm.
For screw gauge.
Let L.C. of linear scale be
Pitch = 2
pitch
L.C. =
100 100
If pitch = 2 L.C. of V.C. = 0.5 mm.
0.5
L.C. of screw gauge = 0.005 mm
100
If 2 L.C. of V .C. 0.5 mm
2 0 .5
L.C. of screw gauge = 0.01 mm
100

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13. Plancks constant h, speed of light c and gravitational constant G are used to form a unit of length L and a
unit of mass M . Then the correct option (s) is(are) :
(A) M c (B) M G (C) L h (D) L G
Ans.(ACD) For M
M h p C q G r
p q r
M M 1L2T 1 L1T 1 M 1L3T 2

M M p r L2 p q 3r T p q 2r
pr 1 (i)
2 p q 3r 0 (ii)
p q 2r 0 (iii)
On solving (i), (ii) & (iii) we get
1 1 1
p ,r and q M h
2 2 2
M C
1
M
G
Similarly For [ L ]
pr 0 (iv)
2p + q + 3r = 1 (v)
p q 2r 0 (vi)
On solving (iv), (v) & (vi)
1 3 1
p ,q ,r
2 2 2
L h
1
L 3/ 2
C
L G.
14. Two independent harmonic oscillators of equal mass are oscillating about the origin with angular frequencies
and 2 and have total energies E1 and E2 , respectively. The variations of their momenta p with position x
a a
are shown in the figures. If n 2 and n , then the correct equation(s) is(are) :
b R
2 E1 E2
(A) E1 1 E22 (B) n2 (C) 12 n 2 (D)
1 1 2
Ans.(BD) x Asin t
v A cos t
p1 m A11 b , A1 a From ellipse
p2 mA2 2 R, A2 R From circle

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a a R
Also, n2 & n n
b R b
p2
E1 1
2m
p22
E2
2m
2
E1 b 1 m12 A12 1 1 1
2
E2 R n m22 A22 n 2 2 n 2
E1 E2

1 2
15. A ring of mass M and radius R is rotating with angular speed about a
fixed vertical axis passing through its centre O with two point masses each of
M
mass at rest at O. These masses can move radially outwards along two
8
massless rods fixed on the ring as shown in the figure. At some instant the
8
angular speed of the system is and one of the masses is at a distance of
9
3
R from O. At this instant the distance of the other mass from O is :
5
2 1 3 4
(A) R (B) R (C) R (D) R
3 3 5 5
M 9 2 8
Ans.(D) MR 2 . MR 2 R I
8 25 9
9 9 MR 2
MR 2 MR 2 I
8 25 8
1 9
I MR 2
8 25 8
1 9
I MR 2 1
8 25
MR 2 16
I .
8 25
M 2 2
x MR 2
8 25
16 2
x2 R
25
4
x R .
5
16. The figure below depict two situations in which two

infinitely long static line charges of constant positive
line charge density are kept parallel to each other.
In their resulting electric field, point charges q and
q are kept in equilibrium between them. The point
charges are confirmed to move in the x direction
only. If they are given a small displacement about
their positions, then the correct statement(s) is(are)

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(A) Both charges execute simple harmonic motion.

(B) Both charges will continue moving in the direction of their displacement.
(C) Charge +q executes simple harmonic motion while charge q continues moving in the direction of its
displacement.
(D) Charge q executes simple harmonic motion while charge +q continues moving in the direction of its
displacement.
q q
Ans.(C) Frest
2 0 x 2 0 x
x q 2 x
=
+q
2 0 2 x 2
q x
Frest
2 0 2
It executes SHM.
q q
Frest
x 2 0 x 2 0 x

q x
q Frest
0 2
Force is towards right hence the particle keeps going towards right.
2
17. Two identical glass rod S1 and S2. (refractive index = 1.5) have one convex end of radius of curvature 10 cm.
They are placed with the curved surfaces at a distance d as shown in the figure, with their axis (shown by the
dashed line) aligned. When a point source of light P is placed inside rod S1 on its axis at distance of 50 cm from
the curved face, the light rays emanating from it are found to be parallel to the axis inside S2. The distance d is :
(A) 60 cm (B) 70 cm (C) 80 cm (D) 90 cm

2 1 2 1
Ans.(B)
V u R
1 1.5 0.5 1

V 50 10 20
1 1 3

V 120 100
V = 50 cm
2 1.0 0.5

u 10
1 1

u 20
u 20 cm
Hence d = 50 + 20 = 70.

18. A conductor (shown in the figure) carrying current I is kept in the x-y plane in a uniform magnetic field B . If F
is the magnitude of the total magnetic force acting on the conductor, then the correct statement(s) is(are) :

(A) If B is along z , F ( L R ) (B) If B is along x , F 0

(C) If B is along y , F ( L R ) (D) If B is along z , F 0

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Ans.(ABC) As B is uniform
Wire can be replaced by a straight current carrying conductor.
F i B
= 2 L R i B
if B is along X-axis F 0
otherwise F L R

This section contains TWO questions
Each question contains two columns, Column I and Column II
Column I has four entries (A), (B), (C) and (D)
Column II has five entries (P), (Q), (R), (S) and (T)
Math the entries in Column I with the entries in Column II
One or more entries in Column I may match with one or more entries in Column II
The ORS contains a 4 5 matrix whose layout will be similar to the one shown below:
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column I
matches with entries (Q), (R) and (T), then darken these three
Marking scheme:
For each entry in Column I :

+2 If only the bubble(s) corresponding to all the correct match(es) is(are) darkened
19. Match the nuclear processes given in column I with the appropriate option(s) in column II.
Column I Column II
(A) Nuclear fusion (P) Absorption of thermal neutrons by 235

92U
(B) Fission in a nuclear reactor (Q) 60

27 Co nucleus
(C) decay (R) Energy production in stars via hydrogen conversion

to helium
(D) ray emission (S) Heavy water
(T) Neutrino emission

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Ans (A) R, T
(B) P, S, T Heavy water is used as a moderator
60 60
(C) P, Q, R, S As 27 C0 undergoes decay & decay to form 28 Ni
(D) P, R, T
20. A particle of unit mass is moving along the x-axid under the influence of a force and it a total energy is
conserved. Four possible forms of the potential energy of the particle are given in column I (a and U0 are
constants) Match the potential energies in column I and to the corresponding statement(s) in column II.
Column I Column II
2 The force acting on the particle is zero at x = a
(A) U x 2 (P)
U1 ( x ) 0 1
2 a
2 The force acting on the particle is zero at x = 0
(B) U0 x (Q)
U 2 ( x)
2 a
2 x 2 The force acting on the particle is zero at x = -a
(C) U0 x (R)
U 3 ( x) exp
2 a a
3 The particle experiences and attractive force towards
(D) U0 x 1 x (S)
U 4 ( x) x = 0 in the region x a .
2 a 3 a
(T) U0
The particle with total energy can oscillate
4
about the point x = -a.
Ans The particle will experience an attractive force towards x = 0 in the region | x | < a
if 0 < x < a F ve & if, a < x < 0 F ve
U
The particle will oscillate about x a if U is min at x a & U at x a 0
4
dU
Also F
dx
2
2U 0 x x
(A) F 1
a a

U0 x
(B) F 2
a
x2
U x x2 a2
(C) F 02 1 2 e
a a
U x2
(D) F 0 1 2
2a a
Hence,
(A) P, Q, R, T
(B) Q, S
(C) P, Q, R, S
(D) P, R, T

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PART I : CHEMISTRY

Marking scheme:
21. The total number of lone pairs of electrons in N 2 O3 is _________.
Ans.(8) Total number of lone pairs = 8
22. For the octahedral complexes of Fe3 in SCN (thiocyanato-S) and in CN ligand environments, the difference
between the spin-only magnetic moments in Bohr magnetons [Atomic number of Fe = 26]
Ans.(4)
23. Among the triatomic molecules/ions, BeCl 2 , N3 , N 2 O, NO2 , O3 , SCl 2 , ICl 2 , I3 and XeF2 , the total number
of linear molecule(s)/ions(s) where the hybridization of the central atom does not have contribution from the
d-orbital(s) is _________.
Ans.(4) BeCl2 , N3 , N 2 O, NO 2 have sp hybridised central atom.
O3 has sp2 hybridised central atom ICl2 , I3 , XeF2 has sp3d hybridised central atom
24. Not considering the electronic spin, the degeneracy of the second excited state n 3 of H-atom is 9, while the
degeneracy of the second excited state of H is _________.

Ans.(3) For multi-electron system, the energy levels are decided by (n + ) rule. Therefore the second excited state for
H should be 2p.
Degeneracy should be (3)
25. All the energy released from the reaction X Y, r G 0 193kJ mol1 is used for oxidizing M as
M M3 2e , E 0 0.25 V .
Under standard conditions, the number of moles of M oxidized when one mole of X is converted to Y is
[ F 96500 C mol 1 ]
Ans.(4) For M
M 3 2e , G1 2 F 0.25
2 96500 0.25 J / mol = Energy required to oxidise 1 mol of M+
Magnitude of total energy released = 193 kJ = 193 1000 J

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193 1000
Number of moles of M+ oxidised = 4
2 96500 0.25
26. If the freezing point of a 0.01 molal aqueous solution of a cobalt(III) chloride-ammonia complex (which behaves
as a strong electrolyte) is 0.0558C , the number of chloride(s) in the coordination sphere of the
complex is _________. [K f of water = 1.86 K kg mol 1 ]
Ans.(1) Tf 0.0558 i 1.86 0.01 i3
n 1 n 1 n 1
Now, 1 n3
i 1 3 1 2
One molecule of complex gives 3 ions in water.
Complex is [Co(NH3 )5 Cl]Cl2
Number of Cl in the coordination sphere = 1
27. The total number of stereoisomers that can exist for M is _________.
Ans.(2) Although there are 2 chiral carbons but the number of stereo-isomers will not be 4.
The bridged carbon cant be oriented in opposite manner
So only 2 isomers are possible.
28. The number of resonance structure for N is :
Ans.(9)

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correct
Marking scheme :
29. Fe3 is reduced of Fe2 by using :

(A) H 2 O2 in presence of NaOH (B) Na 2 O2 in water
(C) H 2 O2 in presence of H 2SO 4 (D) Na 2 O2 in presence of H 2SO 4
3+
Ans.(CD) Fe cannot be reduced by peroxide in alkaline medium as it is highly precipitable in form of Fe(OH)3.
30. 2NH3 (g), H 0 at
The %yield of ammonia as a function of time in the reaction N 2 (g) 3H 2 (g)
P, T1 is given below :
If this reaction is conducted at P, T2 , with T2 T1 , the %yield of ammonia as a function of time represented
by:
(A) (B)
(C) (D)
Ans.(B) As synthesis of ammonia is exothermic hence its yield decreases on increasing temperature, however at higher
temperature equilibrium attained faster because of faster reaction rate at elevated temperatures.

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31. If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral
holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n,
respectively, are :
1 1 1 1 1 1 1
(A) , (B) 1, (C) , (D) ,
2 8 4 2 2 4 8
Ans.(A) Let the formula be MgxAlyO4
By inspection (or by solving 2x 3y 4 2 ) : x = 1, y = 2 MgAl2O4
For every 4 O2 ions there are 2 Al3 ions and 1Mg 2 ion.
and for every 4 O2 ions there are 4 octahedral voids and 8 tetrahedral voids.
2 1 1
m and n
4 2 8
32. Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is(are) :
(A) (B) (C) (D)

Ans.(BD)
33. The major product of the following reaction is :
(A) (B) (C) (D)

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Ans.(A) It is intramolecular aldol condensation.
34. In the following reaction, the major product is :
(A) (B) (C) (D)
Ans.(D) As reactant is conjugated diene so it can undergoes 1, 2-addition and 1, 4-addition reaction.
At and near room temperature major product is thermodynamically controlled product.
35. The structure of D-(+)-glucose is :
The structure of L-( )-glucose is :
(A) (B) (C) (D)

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Ans.(A)
36. The major product of the reaction is :
(A) (B) (C) (D)
Ans.(C)
37. The correct statement(s) about Cr2+ and Mn 3+ is(are) : [Atomic number of Cr = 24 and Mn = 25]
(A) Cr 2 is a reducing agent (B) Mn 3 is an oxidizing agent
(C) Both Cr 2 and Mn 3 exhibit d4 electronic configuration
(D) When Cr 2 is used as a reducing agent, the chromium ion attains d5 electronic configuration
Ans.(ABC) Cr 2 (3d 4 ) is reducing agent because its electronic configuration changes from 3d4 to 3d3 (more stable)
because t2g is half filled.
Mn 3 (3d 4 ) is an oxidizing agent because its electronic configuration changes from 3d4 to 3d5.
Note : Removing 4th electron from Mn 3+ is very difficult because energy equivalent to 4th I.E. has to be given.
38. Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is(are) :
(A) Impure Cu strip is used as cathode
(B) Acidified aqueous CuSO4 is used as electrolyte
(C) Pure Cu deposits at cathode
(D) Impurities settle as anode-mud

Vidyamandir Classes
Ans.(BCD) In refining of blister copper, impure Cu strip is used as anode while a strip of pure Cu is used as cathode
and acidified aqueous CuSO4 is used as electrolyte.
2
Cu(s)
Cu (aq) 2e (at anode)

Cu 2(aq) 2e
Cu(s) (at cathode)
Impurities settle as anode-mud below the anode.

Marking scheme:

39. Match the anionic species given in Column I that are present in the ore(s) given in Column II.
Column I Column II
(A) Carbonate (P) Siderite
(B) Sulphide (Q) Malachite
(C) Hydroxide (R) Bauxite
(D) Oxide (S) Calamine
(T) Argentite

Vidyamandir Classes
Ans [A-PQS] [B-T] [C-QR] [D-R]

(P) Siderite : FeCO3 Carbonate
(Q) Malachite : Cu(OH)2.CuCO3 Carbonate ; Hydroxide
(R) Bauxite : AlO x (OH)3 x (0 x 1) Oxide ; Hydroxide
(S) Calamine : ZnCO3 Carbonate
(T) Argentite : Ag2S Sulphide
40. Match the thermodynamic process given under Column I with the expressions given under Column II.
Column I Column II
(A) Freezing of water at 273 K and 1 atm (P) q0
(B) Expansion of 1 mol of an ideal gas into a vacuum under isolated (Q) w0
conditions
(C) Mixing of equal volumes of two ideal gases at constant (R) Ssys 0
temperature and pressure in an isolated container
(D) Reversible heating of H2(g) at 1 atm from 300 K to 600 K, (S) U 0

followed by reversible cooling to 300 K at 1 atm
(T) G 0
Ans [A-RT] [B-PQS] [C-PQS] [D-PQST]

(A) Freezing of water at 0C , 1 atm
Ssyst 0 (Randomness decreases)
G 0 (At-equilibrium)
(B) Expansion of ideal gas under vacuum, isolated
q0 (Since isolated)
w0 (Since Pext 0 )
U 0 (Since q w 0 )
(C) Mixing of ideal gases at constant T, isolated

q0 (Isolated)
U 0 (Isothermal)
w0 (By first law)
(D) Reversible heating of H2 at 1 atm, then cooling by the same path.
q0 (Heat absorbed = heat released)
w0 (Work done by the system = work done on the system)
U 0 (State function)
G 0 (State function)

Vidyamandir Classes
PART I : MATHEMATICS

Marking scheme:
41. The minimum number of times a fair coin needs to be tossed, so that the probability of getting at least two heads
is at least 0.96, is ________.
n n
1 1
Ans.(8) 1 n C0 n C1 0.96
2 2
n
1
1 n 1 0.96
2
n
1 4 1
n 1 0.04
2
100 25
2 n 25 n 1
n8
42. Let n be the number of ways in which 5 boys and 5 girls can stand in a queue in such a way that all the girls
stand consecutively in the queue. Let m be the number of ways in which 5 boys and 5 girls can stand in a queue
m
in such a way that exactly four girls stand consecutively in the queue. Then the value of is __________.
n
Ans. (5) 5 girls, 5 boys
6! 5! n
5C4 6! 4! 5C1 m
4 girls, 5 boys & 1 girl
m 5 6! 4! 5
5
n 6 ! 5!
43. If the normals of the parabola y 2 4 x drawn at the end points of its latus rectum are tangents to the circle
x 32 y 2 2 r 2 , then the value of r2 is _________.

Ans. (2) Equation of normal at (1, 2) is x + y = 3
Distance of ( 3, 2 ) from x y 3 0 is r
2
r
2
x , x 2
44. Let f : R R be a function defined by f x
0 , x 2
2

xf x 2
where [x] is the greatest integer less than or equal to x. If I 2 f x 1 dx , then the value of
1
4 I 1 is ________.

Vidyamandir Classes
0 x f x2 1

x f x 2 dx 2

x f x 2 dx 3

x f x 2 dx 2

x f x2
Ans. (0) I
2 f x 1 dx 2 f x 1 2 f x 1 2 f x 1 2 f x 1 dx

1 0 1 2 3
0 1 2 3 2
x 1 2 2 1 1
0 dx 0 dx 2 0 dx 0 dx 0 dx 4 x 2 1
1 4 4
1 0 1 2 3
= 4I 1 0
45 A cylindrical container is to be made from certain solid material with the following constraints: It has a fixed
inner volume of V mm3, has a 2 mm thick solid wall and is open at the top. The bottom of the container is a solid
circular disc of thickness 2 mm and is of radius equal to the outer radius of the container.
If the volume of the material used to make the container is minimum when the inner radius of the container is 10
V
mm, then the value of is_____________.
250
Ans(4) Total volume of material
2 2
r 2 h r 2 h r 2 2
2
r 2 h 2 r 2 h
2 V
T r 2 2 V
2
r
dT V 2 2V
2 r 2 2 r 2 0
2
dr r r3
For r = 10
V 2V
2 2 12 0
100 1000
V 200 12V
0
100 1000
10 V 200 12V 0
2V 2000
V 1000
V
4
250

x2
6
1 1
46. Let F x 2 cos 2 t dt for all x R and f : 0 , 0 , be a continuous function. For a 0, ,
2 2
x
if F ' (a) + 2 is the area of the region bounded by x = 0, y = 0, y = f (x) and x = a, then f (0) is_____________.
x2
6
Ans (3) F x 2 cos 2 t dt
x

F x 2 cos 2 x 2 2 x 2 cos 2 x
6
a
1
F a 2 f x dx, a 0, 2
0

Vidyamandir Classes
a

2 cos 2 a 2 2 a 2 cos 2 a 2 f x dx
6
0
Differentiating w.r.t. a

4 cos 2 a 2 2a cos a 2 sin a 2 2a 4 cos a sin a f a
6 6 6
a 0
3
f 0 4 cos 2 4 3
6 4
f 0 3, f 0 0
5
47. The number of distinct solutions of the equation cos 2 2 x cos 4 x sin 4 x cos 6 x sin6 x 2 in the interval
4
0 , 2 is_______________.
Ans (8)
cos4 x sin 4 x 1 2sin 2 x.cos 2 x
cos6 x sin 6 x 1 3sin 2 x.cos 2 x
eq n becomes
5
cos2 2 x 2 5sin 2 x.cos 2 x 2
4
5
cos2 2 x sin 2 2 x 0
4
cos 4 x 0

period
2
8 solutions in x 0, 2
48. Let the curve C be the mirror image of the parabola y2 = 4x with respect to the line x + y + 4 = 0. If A and B are
the points of intersection of C with the line y 5 , then the distance between A and B is______________.
Ans (4)
2

x t 2 y 2 t 2 t 2t 4

1 1 2
x t 2 t 2 2t 4
y 2t t 2 2t 4 t 2 4
5 t 2 4 t 1
t 1 x 6 t 1 x 2
A (-6, -5), B(-2, -5)
AB = 4

Vidyamandir Classes

correct
Marking scheme :
49. Let g : R R be a differentiable function with g 0 0, g' 0 0 and g' 1 0 .
x
g x, x 0
Let f x | x | and h (x) = e| x | for all x R . Let f o h x denote f h x and h o f x
0, x0

denote h (f (x)). Then which of the following is (are) true?
(A) f is differentiable at x = 0 (B) h is differentiable at x = 0
(C) f o h is differentiable at x = 0 (D) h o f is differentiable at x = 0
Ans (AD) g 0 0 g 0 0 , g 1 0
x g x x 0
g x x 0
f x | x | g x x 0
0 x 0 0 x 0

f 0 f 0 f 0 0 f 0 0
h x e|x| x R

g e|x| x0 g ex
x0

f h x

g e|x| x 0 g e x

x0
0 x 0 0 x 0

g 1
f h 0
f h 0 g 1

eg x g x 0 x 0

e e g x
|f x |
h f x g x 0 x 0

1 x0
1
h f 0
h f 0 1

g x .g x
e g x 0 x 0
h f x
g x

e g x g x 0 x 0

Vidyamandir Classes

50. Let f x sin sin sin x for all x R and g x sin x for all x R . Let (f o g) (x) denote f (g (x))
6 2 2
and (g o f) (x) denote g (f (x)). Then which of the following is (are) true?
1 1 1 1
(A) Range of f is , (B) Range of f o g is ,
2 2 2 2
f x
(C) lim (D) There is an x R such that (g o f ) (x) = 1
x0 g x 6

Ans (ABC) f x sin sin sin x
6
2

g x sin x
2
(A) Range of f (x)

sin x ,
2 2 2

sin sin x 1, 1
2

sin sin x ,
6 2 6 6
1 1
sin sin sin x ,
6 2 2 2
(B) Range of f g x

f g x sin sin sin sin x
6 2 2

sin x ,
2 2 2

sin sin x 1, 1
2

sin sin x ,
2 2 2 2

sin sin sin x 1, 1
2 2

sin sin sin x ,
6 2 2 6 6
1 1
f g x , Ans.B
2 2
f x
(C) Lt
x 0 g x

sin sin sin x
6 2
Lt
x0
sin x
2

Vidyamandir Classes

sin sin sin x sin sin x
6 2 6 2
Lt
x0
sin sin x sin x
6 2 2

sin sin x
Lt
6 2 Ans.C
x0 6
sin x
2

(D) g f x sin sin sin sin x
2 6 2

sin x ,
2 2 2

sin sin x 1, 1
2

sin x sin x ,
6 2 6 6
1 1
sin sin sin x ,
6 2 2 2
1 1
sin sin x sin x sin , sin
6 2 2 2
1 1
g f x sin , sin
2 2 2 2
Incorrect

51. Let PQR be a triangle. Let a QR b RP and c PQ . If | a | 12 | b | 4 3 and b.c 24 then which of
the following is (are) true?

| c |2 | c |2
(A) | a | 12 (B) | a | 30
2 2

(C) | a b c a | 48 3 (D) a . b 72

Ans (ACD) a 12, b 4 3 , b c 24

a b c 0

b c a
2
48 c 48 144
2
c 144 96 48

c 4 3
2
c
a 24 12 12
2
2
c
a 24 12 36
2

a b c a a b c 12 48 48 48 12 48 48 3

a b 48 24 0

a b 72

Vidyamandir Classes
52. Let X and Y be two arbitrary, 3 3 , non-zero, skew symmetric matrices and Z be an arbitrary 3 3 , non-zero,
symmetric matrix. Then which of the following matrices is (are) skew symmetric?
(A) Y 3 Z 4 Z 4Y 3 (B) X 44 Y 44 (C) X 4Z 3 Z 3 X 4 (D) X 23 Y 23
Ans (CD) X 3 3 , Y3 3 X,Y 0 X X , Y Y
X 0 Y
Z3 3 0, Z Z
Y Z 3 4
Z 4Y 3 Y Z Z Y Z
3 4 4 3 4
Y 3 Y 3 Z 4
Z 4Y 3 Y 3 Z 4 Y 3 Z 4 Z 4Y 3
Symmetric
X 44
X Y
Y 44
44 44
X 44 Y 44 Symmetric

X 4 3
Z Z X Z X
3 4 3 4
X
4
Z 3 Z 3 X 4 X 4 Z 3

X 4Z3 Z3 X 4 Skew symmetric
X 23
Y 23 X 23
Y
23
X 23 Y 23 X 23 Y 23
Skew Symmetric
1 2 1 2 2 1 3 2
53. Which of the following vales of satisfy the equation 2 2 2 2 2 2 3 2 648 ?
3 2 3 2 2 3 3 2
(A) 4 (B) 9 (C) 9 (D) 4
2 2 2
1 1 2 1 3 1 2 2 1 4 4 2 1 6 9 2
Ans (BC) 1 2 2 2 2 2 3 2 4 4 2 4 8 4 2 4 12 9 2
3 2 3 2 2 3 3 2 9 6 2 9 12 4 2 9 18 9 2
1 2 1 1 1 1 1 1 1 0 0 1 0 0
4 2 2
7 4 6 4 2 1 2 2 4 4 2 3 4 8 3
3 3
9 3 2 1 4 9 9 3 1 1 3 8 9 6 8
8 3 648
2 81 0 0, 9
54. In R3 consider the planes P1 : y = 0 and P2 : x + z = 1. let P3 be a plane, different form P1 and P2 , which passes
through the intersection of P1 and P2 . If the distance of the point (0, 1, 0) from P3 is 1 and the distance of a
point from P3 is 2, then which of the following relations is (are) true?
(A) 2 2 2 0 (B) 2 2 4 0
(C) 2 2 10 0 (D) 2 2 8 0
Ans (BD) Equations of all planes posting through intersection of p1 & p2 are of form
p2 kp1 0
or x z 1 ky 0
or x ky z 1 0 : Equation of p3
Distance of (0,1,0) from p3 is

Vidyamandir Classes
k 1
1
k2 2
k 2 1 2k k 2 2
1
k
2
y
Equation of p3 is x z 1 0 or 2 x y 2 z 2 0
2
Distance of from p3 2
2
2
3
2 2 6 or 2 2 2 6
2 2 8 0 or 2
55. In R 3 , let L be a straight line passing through the origin. Suppose that all the points on L are at a constant
distance from the two planes P1 x 2 y z 1 0 and P2 2 x y z 1 0 . Let M be the locus of the feet of
the perpendiculars drawn from the points on L to be plane P1 .
Which of the following points lie (s) on M ?
5 2 1 1 1 5 1 1 2
(A) 0 (B) (C) 0 (D) 0
6 3 6 3 6 6 6 3 3
i j k
Ans (AB) 1 2 1 i 3 j 5k
2 1 1
Equation of l is
x y z

1 3 5
, 3 , 5
Locus is
x

y 3

z 5

6 5 1
1 2 1 6
1 1 1
x , y 3 , z 5
6 3 6
1 1 1
x y z
or 6 3 6
1 3 5
(A) & (B) satisfies the locus
56. Let P and Q distinct points on the parabola y 2 2 x such that a circle with PQ as diameter passes through the
vertex O of the parabola. If P lies in the first quadrant and the area of the triangle OPQ is 3 2 , then which of
the following is (are) the coordinates of P?
1 1
(A) 4 2 2 (B) 9 3 2 (C)
4 2
(D) 1 2
Ans (AD) Equation of circle is
y 2at1 y 2at2 x at12 x at22 0
Since it passes through origin.
t1t 2 4 - (1)
1
Area of OPQ OP OQ
2

Vidyamandir Classes
1
3 2 4a 2 t12 a 2t14 4 a 2t22 a 2t24
2
4a 2t12 a2t14 4a 2t22 a2t24 72
4 t12 4 t22 72
t12 t22 10 - (2)
From (1) & (2)
t1 2 2 , 2 since P lies in First Quadrant
t1 2 2 , 2 ,

P 4 , 2 2 , 1, 2 .
56 A,D
57. Let y x be a solution of the differential equation 1 e y ye

x x
1. If y 0 2 , then which of the
following statements is (are) true?

(A) y 4 0
(B) y 2 0
(C) y x has a critical point in the interval 1 0
(D) y x has no critical point in the interval 1 0
Ans (AC)
dy y e x 1
x

dr 1 e 1 ex
ex
dx
x
I .F e 1 e 1 ex
Solution is

y 1 ex 1 ex 1
dx

y 1 ex x c
1 e x
0, 2 lies on it 22 o c c 4
x4
curve is y
1 ex
x x
dy 1 e 1 x 4 e e x x 3 1
y 4 0 and 2
2
dx 1 ex
1 ex
dy 1
For 0 x 3 e x 1 0 or e x
dx x 3
By plotting graph we get one solution in x (1, 0)
At x 1 e 1 1
e
1 1

x3 2
1 1

2 e

Vidyamandir Classes
58. Consider the family of all circles whose centres lie on the straight line y x . If this family of circles is
represented by the differential equation Py Qy 1 0 , where P, Q are functions of x, y and y (here
dy d2y
y y 2 ), then which of the following statements is (are) true?
dx dx
(A) P y x (B) P yx
2 2
(C) P Q 1 x y y y (D) P Q x y y y
Ans (BC)
( x )2 ( y ) 2 2 ......(1)
dy
2( x ) 2( y ). 0 .......(2)
dx
dy
x y.
dx .......(3)
dy
1
dx
Differentiate (2) w.r.t. x
2
d2y dy
1 (y ) 2
0 ......(4)
dx dx
dy
x y
Using (3) y y dx
dy
1
dx
yx
y .....(5)
dy
1
dx
Using (5), (4) becomes
2
( y x) d 2 y dy
1 . 0
dy dx 2 dx
1
dx
2
d2y dy dy dy
( y x) 2
1 1 0
dx dx dx
dx
2
d 2 y dy dy dy
( y x) 2 1 1 0
dx dx dx dx
comparing we get
2
dy dy
P yx Q 1
dx dx

Vidyamandir Classes

Marking scheme:

59. MATCH THE FOLLOWING :

Column I Column II
(A) In R 2 , if the magnitude of the projection vector of the vector (P) 1
i j on 3 i j is 3 and if 2 3 then possible value (s)

of | | is (are)
(B) let a and b be real numbers such that the function (Q) 2
3ax 2 2 x 1
f x
2
bx a x 1
Is differentiable for all x R . Then possible value(s) of is (are)
(C) 4n 3 (R) 3

Let 1 be a complex cube root of unity. If 3 3 2 2 0
then possible value(s) of n is (are)

(D) Let the harmonic mean of two positive real numbers a and b are 4. If q (S) 4
is a positive real number such that a, 5, q, b is an arithmetic
progression, then the value(s) of | q a | is (are)
(T) 5

Vidyamandir Classes
Ans (A)(PQ)

a.b i j
Projetions =

3i j
3

b 2
3 3
Since
2 3 3 2 3 0, 3
3 0 2, 2 3 3 1 1, 2
(B)(PQ) Continuity at x = 1
Lt bx a 2 b a 2
x 1
Lt 3ax 2 2 3a 2
x 1
b a 2 3a 2 .....(1)
Differentiability at x = 1
f 1 (1 ) b f 1 (1 ) 6a
b 6a .......(2)
from (1) & (2)
a 2 6 a 3a 2 a 2 3a 2 0
a 1, 2
(C)(PQST)
4 n 3 4 n 3 4 n 3
3 3 2 3 3 3 2 3
2 2 2
0
4 n 3
3 3 2 1 0
2 4 n 3 n
4 n 3
3 3 1 0
2 n n
1 n n 0 n 1, 2, 4, 5
(D)(QT)
2ab
4 .....(1)
ab
a ,5, q , b are in A.P.
q 10 a
b 15 2a (since d 5 a )
From (1)
2a (15 2a )
4
a 15 2a
2a 2 17 a 30 0
5
a 6,
2
q a 10 2 a 2,5

Vidyamandir Classes
60. MATCH THE FOLLOWING :

Column I Column II
(A) In a triangle XYZ , let a, b and c be the lengths of the sides opposite to (P) 1
the angles X, Y and Z, respectively. If
2 a b 2 2
c 2
and
sin X Y
, then possible values of n for which cos n 0 is (are)
sin Z
(B) In a triangle XYZ let a, b and c be the lengths of the sides opposite to the (Q) 2
angles X, Y and Z, respectively. If 1 cos 2 X 2 cos 2Y 2 sin X sinY
a
then possible value(s) of is (are)
b
(C) In R2 , let 3 i j i 3 j and i 1 j be the position vectors of (R) 3
X, Y and Z with respect to the origin O, respectively. If the distance of Z

3
from the bisector of the acute angle of OX with OY is , then possible
2
value(s) of | | is (are)
(D) Suppose that F denotes the area of the region bounded by (S) 5
x 0 x 2 y 2 4 x and y | x 1 | | x 2 | x where 0 1 .
8
Then the value(s) of F 2 when 0 and 1 , is (are)
3
(T) 6
a b c
Ans (A)(PRS) Let
sin x sin y sin z

z a2 b2 c2
sin x y 1

z sin 2 x sin 2 y sin 2 z
sin z

2

n
cos 0 n 1, 3, 5
2
B(P) 1 + cos2x 2 cos 2y = 2 sin x sin y

sin 2 x 2 sin 2 y sin x sin y a 2 2b 2 ab
a 2b a
1 1
b a b
C(PQ) The equation of bisector is y = x

1 3
2 1 3 1, 2
2 2
| | 1, 2

Vidyamandir Classes
(D)(ST)
Case I 0
2
4 3/ 2 2 8 2

F (0) 6 2 x 6
3
x 0
6
3
0
8 2
F (0) 6
3
Case II 1
3 x x 1
y x 1 x 2 x
x 1 1 x 2
1
ABC 2 1 1 F (1) F (0) 1
2
8 2
F (1) 5
3

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Vidyamandir Classes

READ THE INSTRUCTIONS CAREFULLY

VMC/Paper-1 1 JEE Entrance Exam-2015/Advanced

SECTION 1 (Maximum Marks : 32)

VMC/Paper-1 2 JEE Entrance Exam-2015/Advanced

VMC/Paper-1 3 JEE Entrance Exam-2015/Advanced

For S2 P : optical path : 2 x 2 d 2

7. An infinitely long uniform line charge distribution of

VMC/Paper-1 5 JEE Entrance Exam-2015/Advanced

SECTION 2 (Maximum Marks : 40)

VMC/Paper-1 6 JEE Entrance Exam-2015/Advanced

2.7 108 50 103

VMC/Paper-1 7 JEE Entrance Exam-2015/Advanced

(A) (B) (C) (D)

VMC/Paper-1 8 JEE Entrance Exam-2015/Advanced

VMC/Paper-1 9 JEE Entrance Exam-2015/Advanced

16. The figure below depict two situations in which two

VMC/Paper-1 10 JEE Entrance Exam-2015/Advanced

(A) Both charges execute simple harmonic motion.

(A) 60 cm (B) 70 cm (C) 80 cm (D) 90 cm

VMC/Paper-1 11 JEE Entrance Exam-2015/Advanced

SECTION 3 (Maximum Marks : 16)

For each entry in Column I :

(A) Nuclear fusion (P) Absorption of thermal neutrons by 235

(B) Fission in a nuclear reactor (Q) 60

(C) decay (R) Energy production in stars via hydrogen conversion

(D) ray emission (S) Heavy water

(T) Neutrino emission

VMC/Paper-1 12 JEE Entrance Exam-2015/Advanced

VMC/Paper-1 13 JEE Entrance Exam-2015/Advanced

SECTION 1 (Maximum Marks : 32)

21. The total number of lone pairs of electrons in N 2 O3 is _________.

Ans.(8) Total number of lone pairs = 8

degeneracy of the second excited state of H is _________.

Magnitude of total energy released = 193 kJ = 193 1000 J

VMC/Paper-1 14 JEE Entrance Exam-2015/Advanced

Number of Cl in the coordination sphere = 1

28. The number of resonance structure for N is :

VMC/Paper-1 15 JEE Entrance Exam-2015/Advanced

SECTION 2 (Maximum Marks : 40)

29. Fe3 is reduced of Fe2 by using :

VMC/Paper-1 16 JEE Entrance Exam-2015/Advanced

32. Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is(are) :

(A) (B) (C) (D)

33. The major product of the following reaction is :

(A) (B) (C) (D)

VMC/Paper-1 17 JEE Entrance Exam-2015/Advanced

Ans.(A) It is intramolecular aldol condensation.

34. In the following reaction, the major product is :

(A) (B) (C) (D)

At and near room temperature major product is thermodynamically controlled product.

35. The structure of D-(+)-glucose is :

The structure of L-( )-glucose is :

(A) (B) (C) (D)

VMC/Paper-1 18 JEE Entrance Exam-2015/Advanced

36. The major product of the reaction is :

(A) (B) (C) (D)

VMC/Paper-1 19 JEE Entrance Exam-2015/Advanced

SECTION 3 (Maximum Marks : 16)

For each entry in Column I :

(A) Carbonate (P) Siderite

(B) Sulphide (Q) Malachite

(C) Hydroxide (R) Bauxite

(D) Oxide (S) Calamine