2015JEEADVP 2 Solutions

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CODE - 5 PAPER 2
Time: 3 Hours Maximum Marks: 240
READ THE INSTRUCTIONS CAREFULLY
GENERAL:
1. This sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the left hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the questions.
4. The ORS CODE is printed on its left part as well as the right part. Ensure that both these codes are identical and
same as that on the question paper booklet. If not, contact the invigilator.
5. Blank spaces are provided within this booklet for rough work.
6. Write your name and roll number in the space provided on the back cover of this booklet.
7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions
along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME:
8. The question paper has three parts: Physics, Chemistry and Mathematics. Each part has three sections.
9. Carefully read the instructions given at the beginning of each section.
10. Section 1 contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: + 4 for correct answer and 0 in all other cases.
11. Section 2 contains 8 multiple choice questions with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
12. Section 3 contains 2 paragraph type questions. Each paragraph describes an experiment, a situation or a
problem. Two multiple choice questions will be asked based on this paragraph. One or more than one option can
be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
OPTICAL RESPONSE SHEET:
13. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet).
14. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at
the corresponding place on the carbon-less copy.
15. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
16. You will be allowed to take away the carbon-less copy at the end of the examination.
17. Do not temper with or mutilate the ORS.
18. Write you name, roll number and the name of the examination center and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
VMC/Paper-2 1 JEE Entrance Exam-2015/Advanced

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PART I : PHYSICS
SECTION 1 (Maximum Marks : 32)

This section contains EIGHT questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
For each question, darken the bubble corresponding to the correct integer in the ORS.
Marking scheme:
+4 If the bubble corresponding to the answer is darkened
0 In all the other cases
1. The densities of two solid spheres A and B of the same radii R vary with radial distance r as
5
r r
A r k and r k , respectively, where k is a constant. The moments of inertia of the
R
B R
I n
individual spheres about axes passing through their centres are IA and IB, respectively. If B , the value of n
I A 10
is _________.
Ans.(6) Moment of inertia of a hollow sphere is
2
I 0 mR 2
3
Here, for sphere A :
R
2 2 r
IA 3r . 4 r 2 dr K
R
0
R
8K 5
r dr
3R
0
8 K R 6

3R 6
Also, for sphere B :
R
2 2 K
IB 3r . 4 r 2 dr .r 5
R5
0
8 K R10
.
3R 5 10
IB 6
Ratio,
IA 10
2. Four harmonic waves of equal frequencies and equal intensities I0 have phase angle 0, / 3 , 2 / 3 and .
When they are superposed, the intensity of the resulting wave in nI0. The value of n is _________.

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Ans.(3) Using phasor method of superposition,
Resultant amplitude = A0 3
Resultant intensity = 3I 0
dN dA
3. For a radioactive material, its activity A and rate of change of its activity R are defined A and R ,
dt dt
where N(t) is the number of nuclei at time t. Two radioactive sources P (mean life ) and Q (mean life 2 ) have
RP n
the same activity at t = 0. Their rates of change of activities at t 2 are RP and RQ, respectively. If ,
RQ e
then the value of n is _________.
Ans.(2) N N 0 e t
A A0 e t
R R0 e t
For P:
2
at t 2

R0 P R0 1
RP .
2
e e2
For Q:
R0 Q R 1
RQ 0.
e e 2
RP 2

RQ e
4. A monochromatic beam of light is incident at 60 on one

face of an equilateral prism of refractive index n and
emerges from the opposite face making an angle n
with the normal (see the figure). For n 3 the value of

d
is 60 and m . The value of m is _________.
dn
Ans.(2) 1.0 sin 60 = n sin r 1 (i)
r1 r2 60 (ii)
n sin r2 1.0 sin (iii)
For n 3 , r1 30 , r2 30 , 60
Also, differentiating (i).
dr 3 1
cos r1 1 2
dn 2 n
dr1 1

dn 3
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dr2 dr 1
Also, 1
dn dn 3
Differentiating (iii),
dr d
1. sin r2 ncos r2 2 cos
dn dn
1 3 1 1 d
3
2 2 3 2 dn
1 d
1
2 dn
d
2
dn
5. In the following circuit, the current through the resistor R 2 is I Amperes. The value of I is _________.
Ans.(1)
8 can be removed by Wheatstones bridge concept
So,
10 can now be removed using Wheatstones bridge concept again
6.5
Current I
6.5
= 1 Amp
6. An electron in an excited state of Li 2 ion has angular moment 3h / 2 . The de Brogile wavelength of the
electron in this state is p a0 (where a0 is the Bohr radius). The value of p is _________.

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3h
Ans.(2) Angular momentum: mvr
2
n 3
Also, Li Z 3
We know that radius of n th orbit for a hydrogen like atom is given by:
a n2
rn 0
Z
Here, r3 3ao
De-Broglie wave length :
h

mv
hr

mvr
h 3 ao

3h

2
2 ao
p2
7. A large spherical mass M is fixed at one position and two identical point masses m are kept on a line passing
through the centre of M (see figure). The point masses are connected by a rigid massless rod of length l and this
assembly is free to move along the line connecting them. All three mass interact only through their mutual
gravitational interaction. When the point m is nearer to M is at a distance r = 3l from M, the tension in the rod is
M
zero for m k . The value of k is _________.
288
Ans.(7)
GMm Gm 2
FBD of middle mass:
9 2 2
2
GMm Gm
Since T 0 , ma .... (i)
2
9 2
Also, for the right most mass :
GMm Gm 2
ma .... (ii)
162 2
Equating (i) & (ii)
GMm GMm 2Gm 2

9 2 16 2 2
7M
Solving : m
288
8. The energy of a system as a function of time t is given as E(t) = A2 exp ( t ), where 0.2 s 1 . The
measurement of A has an error of 1.25% . If the error in the measurement of time is 1.50% , the percentage error
in the value of E(t) at t = 5s is _________.
Ans.(4) E A2 e t
ln E 2 ln A t

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E A
100 2 . 100 t 100 ..(i)
E A
t
For time : 100 1.5
t
1.5 5 7.5
At t = 5s, t
100 100
Using Eq(i)
7.5
% error in E 2 1.25 100
100
= 2.5 + 1.5
=4

This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are)
correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
2 In all other cases
9. A parallel plate capacitor having plates of area S and plate separation d, has
capacitance C1 in air. When two dielectriecs of different relative
permittivities 1 2 and 2 4 are introduced between the two plates as
C2
shown in the figure, the capacitance becomes C2. The ratio is :
C1
(A) 6/5 (B) 5/3
(C) 7/5 (D) 7/3
Ans.(D) .(D) The given capacitor can be divided into three capacitors as shown.
d/2 d/2
2C1 4C1
1 2
2
1
3
C
7 2 1
This gives : C2 C1 . 2
3
10. An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the figure).
Initially the gas is at temperature T1, pressure P1 and volume V1 and the spring is in its relaxed state. The gas is
then heated very slowly to temperature T2, pressure P2 and volume V2. During this process the piston moves out
by a distance x. Ignoring the friction between the piston and the cylinder, the correct statement(s) is(are) :

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1
(A) If V2 2V1 and T2 3T1 , then the energy stored in the spring is PV
1 1
4
(B) If V2 2V1 and T2 3T1 , then the change in internal energy is 3PV1 1
7
(C) If V2 3V1 and T2 4T1 , then the work done by the gas is PV
1 1
3
17
(D) If V2 3V1 and T2 4T1 , then the heat supplied to the gas is PV
1 1
6
Ans(A,B,C)
We will assume that the gas on the side of container having spring is connected to atmosphere. Hence, its
pressure remains constant at P1.
In final position of Piston, force balance gives:
Kx P1 A P2 A
Where A = cross sectional area of piston.
So, Kx P2 P1 A (i)
PV
1 1 P2V2
Also,
T1 T2
3
If V2 2V1 , T2 3T1 , then P2 P1 .
2
Also, V2 V1 Ax (ii)
(i) & (ii) give:
V V
Kx P2 P1 2 1
x
1 2 1
Kx P2 P1 V2 V1 (iii )
2 2
1 P PV
1 V1 1 1
2 2 4
Hence, (A) is correct.
f
U P2V2 PV 1 1
2
3 3
2 PV 1 1 PV
1 1
2 2
3PV
1 1
Hence, (B) is correct as well.
Net work done on piston by all forces is zero. So,
1
Wgas Kx 2 P1 V2 V1 0
2
PV
Wgas 1 1 2 PV 1 1
3
7
Wgas PV 1 1
3
So, (c) also turns out to be correct.
Q DU W
3
U P2V2 PV 1 1
2

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3 4
P1.3V1 PV
1 1
2 3
9
U PV
1 1
2
9 7
Q 1 1 PV
PV 1 1
2 3
41
Q PV 1 1
6
Hence (D) is not correct.
236 140 94 236
11. A fission reaction is given by 92 U 54 Xe 38 Sr x y , where x and y are two particles. Considering 92 U
to be at rest, the kinetic energies of the products are denoted by K Xe , K Sr , K x (2MeV) and K y (2 MeV) ,
236 140 94
respectively. Let the binding energies per nucleon of 92 U 54 Xe and 38 Sr be 7.5 MeV, 8.5 MeV and 8.5
MeV respectively. Considering different conservation laws, the correct option(s) is(are)
(A) x n, y n, KSr 129 MeV, K Xe 86 MeV
(B) x p , y e , KSr 129 MeV, K Xe 86 MeV

(C) x p, y n, KSr 129 MeV, K Xe 86MeV
(D) x n, y n, KSr 86 MeV, K Xe 129 MeV
236
Ans.(A) 92 U 140 94
54 Xe 38 Sr X Y
236 > 140 + 94
92 = 54 + 38
Total charge on x + y = 0
and mass of x + y should be around 2 amu.
Hence options B and C are ruled out.
Also, B.E. of reactants = 236 7.5 = 1770 MeV
B.E. of products = 140 8.5 + 94 8.5
= 1190 + 799 = 1989 MeV
Hence, difference in B.E. of reactant and products:
E 1989 1770 MeV
= 219 MeV.
This energy can appear as the K.E. of products.
As Kx + Ky = 4 MeV
K Sr K Xe 215 MeV
From law of conservation of momentum.
pSr pXe
2mSR K SR 2 mXe K Xe .
94 KSR = 140 KXe
& KSR = 129 MeV.
12. Two spheres P and Q of equal radii have densities 1 and 2 ,

respectively. The spheres are connected by a massless string and
placed in liquids L1 and L2 of densities 1 and 2 and
viscosities 1 and 2 , respectively. They float in equilibrium with
the sphere P in L1 and sphere Q in L2 and the string being taut (see

figure). If sphere P alone in L2 has terminal velocity VP and Q

alone in L1 has terminal velocity VQ , then

| VP | 1 | VP | 2
(A) (B) (C) VP .VQ 0 (D) VP .VQ 0
| VQ | 2 | VQ | 1

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1V
Ans.(AD) 1V 1V T
T 2V 2V .
1V T 1 2 1 2
T
2 V
2V
62 rV
2V
2r 2
VP 1 2
92
P L2 2r 2
2V VQ 2 1
91
1V
61rV
1V
VP
1 & VP VQ 0
VQ 2
Q L1 as if 1 2 0
2V 2 1 0
13. In terms of potential difference V, electric current I, permittivity 0 , permeability 0 and speed of light c, the
dimensionally correct equation(s) is(are)
(A) 0 I 2 o V 2 (B) 0V (C) I 0 cV (D) 0 cI 0V
Ans.(AC) [V ] [ M 1 L2T 3 A1 ]
[ I ] [ A]
[c] [ L1T 1 ]
[ 0 ] [ M 1 L3T 4 A2 ]
[ 0 ] [M 1 L1T 2 A2 ]
Option A
[ 0 I 2 ] [ M 1L1T 2 ] ; [ E0V 2 ] [ M 1 L1T 2 ]
Option B
[ 0 I ] [ M 1 L3T 4 A3 ]
[ 0V ] [M 2 L3T 5 A3 ]
Option C
[ I ] [ A]
[ 0cV ] [ A]
Option D
[ 0 cI ] [M 1L2T 3 A1 ]

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[ 0V ] [ L1TA]
Option A and C correct
14. Consider a uniform spherical charge distribution of radius R1 centred at the origin O. In this distribution, a
spherical cavity of radius R2 centred at P with distance OP a R1 R2 (see figure) is made. If the electric field

inside the cavity at position r is E (r ) , then the correct statement(s) is(are)

(A) E is uniform, its magnitude is independent of R2 but its direction depends on r

(B) E is uniform, its magnitude depends on R2 and its direction depends on r

(C) E is uniform, its magnitude is independent of a but its direction depends on a

(D) E is uniform and both its magnitude and direction depend on a
Ans.(D) Since the sphere carries a uniform volume charge density it will be a non-conducting sphere. Hence, no concept
of conducting sphere/cavity should be used.
For a spherical cavity, in a uniformly charged sphere, we use the standard result that :

a
E
3 0

Where a = position vector of center of cavity WRT center of sphere
Hence(D)
15. In plotting stress versus strain curves for two materials

P and Q, a student by mistake puts strain on the y-axis
and stress on the x-axis as shown in the figure. Then
Strain
the correct statement(s) is (are)

(A) P has more tensile strength than Q P
Q
(B) P is more ductile than Q
(C) P is more brittle than Q
Stress
(D) The Youngs modulus of P is more than that of Q
Ans.(AB) As (Breaking Stress)P > (Breaking Stress)Q

P is more tensile than Q.
We can increase the length of P by a larger amount than Q P is more ductile than Q.
P is less brittle than Q.
Stress
By checking the value of at any particular value of strain YQ YP
Strain
16. A spherical body of radius R consists of a fluid of constant density and is in equilibrium under its own gravity. If
P (r) is the pressure at r (r < R), then the correct option (s) is(are)
P r 3R / 4 63 P r 3R / 5 16 P r R / 2 20
(A) P (r = 0) = 0 (B) (C) (D)
P r 2 R / 3 80 P r 2 R / 5 21 P r R / 3 27
4G
Ans.(BC) Gravitational field at a distance r from the centre of a uniform sphere is r
3
Balancing the forces on a thin spherical shell at a distance r.
4 r 2 dP g r . dm

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4pGr
4r 2 dP .r. 4 r 2 dr.
3
4G 2 rdr
dP
3 r
2 2 P P + dP
4G r
P r . C
3 2
At surface P = O
dm
2G 2 R 2
So, C
3
2G 2
P r
3

R2 r 2
2
3R 2G 9 2 G 2 7 2
P 1 R . R
4 3 16 3 16
2
2 R 2G 4 2 G 2 5 2
P 1 R . R
4 3 9 3 9
63
ratio Hence (B)
80
2
3R 2G 9 16
P 1 constant
5 3 25 25
2
2 R 2G 4 21
P 1 constant
5 3 25 25
16
ratio . Hence (C)
21
R 1
P 1
2 4 3 9 27 Hence NOT (D)
R 1
1 4 8 32
P
3 9

This section contains TWO questions.
Based on each paragraph, there will be TWO questions.
correct.
Marking scheme :

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Paragraph for Questions 17 - 18

In a thin rectangular metallic strip a constant current I flows along the positive x-direction, as shown in the figure.

The length, width and thickness of the strip are l, w and d, respectively. A uniform magnetic field B is applied on the
strip along the positive y-direction. Due to this the charge carriers experience a net deflection along the z-direction. This
results in accumulation of charge carriers on the surface PQRS and appearance of equal and opposite charges on the face
opposite to PQRS. A potential difference along the z-direction is thus developed. Charge accumulation continuous until
the magnetic force is balanced by the electric force. The current is assumed to be uniformly distributed on the cross
section of the strip and carried by electrons. y
l
I K
w I
S R x
d M z
P Q
17. Consider two different metallic strips (1 and 2) of the same material. Their lengths are the same, width are w1
and w2 and thickness are d1 and d2, respectively. Two points K and M are symmetrically located on the opposite
faces parallel to the x-y plane (see figure). V1 and V2 are the potential differences between K and M in strips 1
and 2, respectively. Then, for a given current I flowing through them in a given magnetic field strength B, the
correct statement (s) is (are)
(A) If w1 = w2 and d1 = 2d2, then V2 = 2V1 (B) If w1 = w2 and d1 = 2d2, then V2 = V1
(C) If w1 = 2w2 and d1 = d2, then V2 = 2V1 (D) If w1 = 2w2 and d1 = d2, then V2 = V1
Ans.(AD) qVB Eq
E = VB i = n 0eAVd
i
E B
n0eA
iB
E
n0 e Wd
Potential difference : VKM = W.E.
iB 1
V1
n0e d1
iB 1
V2
n0e d 2
V1 d 2

V2 d1
Hence, (A) and (D)
18. Consider two different metallic strips (1 and 2) of same dimensions (length l, width w and thickness d) with
carried densities n 1 and n2 , respectively. Strip 1 is placed in magnetic field B1 and strip 2 is placed in magnetic
field B2, both along positive y-direction. Then V1 and V2 are the potential differences developed between K and
M in strips 1 and 2, respectively. Assuming that the current I is the same for both the strips, the correct option(s)
is (are)
(A) If B1 = B2 and n 1 = 2n2 , then V2 = 2V1 (B) If B1 = B2 and n 1 = 2n2 , then V2 = V1
(C) If B1 = 2B2 and n1 = n2 , then V2 = 0.5 V1 (D) If B1 = 2B2 and n1 = n2 , then V2 = V1
V1 n2 B1
Ans.(AC) In this case,
V2 n1 B2
Hence (A) and (C).

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Light guidance in an optical fiber can be understood by considering a structure comprising of thin solid glass cylinder of
refractive index n 1 surrounded by a medium of lower refractive index n 2. The light guidance in the structure takes place
due to successive total internal reflections at the interface of the media n 1 and n 2 as shown in the figure. All rays with the
angle of incidence i less than a particular value im are confined in the medium of refractive index n1 . The numerical
aperture (NA) of the structure is defined as sin im.
n1 > n2
Air Cladding n2
Core
i n1
19. For two structures namely S1 with n1 45 / 4 and n 2 = 3/2, and S2 with n 1 = 8/5 and n 2 = 7/5 and taking the
refractive index of water to be 4/3 and that of air to be 1, the correct option(s) is (are)
16
(A) NA of S1 immersed in water is the same as that of S2 immersed in a liquid of refractive index
3 15
6
(B) NA of S1 immersed in liquid of refractive index is the same as that of S2 immersed in water
15
4
(C) NA of S1 placed in air is the same as that of S2 immersed in liquid of refractive index
15
(D) NA of S1 placed in air is the same as that of S2 placed in water
Ans.(AC)
im is the angle of incidence for which r 90 C
n2
sin c
n1
n0 sin(im ) n1 sin(90 C )
n1 cos(C )
N A sin(im )
n0
n12 n22

n0
45 9

For S1 , NA1 16 4 3
n0 4 n0
64 49

For S 2 , NA2 25 25 15
5n0
3 3 9
For (A) NA1
4 4 16
15 3 15 9
NA2
5 16 16
Hence (A) is correct

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3 15 15
For (B) NA1
4 6 8
15 3 15 3
NA2
5 4 20
Hence (B) is incorrect
3 3
For (C) NA1
4 1 4
15 15 3
NA2
5 4 4
Hence (C) is correct
3 3
For (D) NA1
4 1 4
3 9
NA2
4 4 16
Hence (D) is incorrect
20. If two structures of same cross-sectional area, but different numerical apertures NA1 and NA2 (NA2 < NA1 ) are
joined longitudinally, the numerical aperture of the combined structure is.
NA1 NA2
(A) (B) NA1 NA2
NA1 NA2
(C) NA1 (D) NA2
Ans.(D)
It a ray enters a structure at i then it also places at i

In order to focus through both the structures i im1 , as well as i im2
And as NA1 NA2 im1 im2
Hence i im2 NA NA2

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PART I : CHEMISTRY

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
21. In the complex acetylbromidodicarbonylbis (triethylphosphine) iron(II), the number of Fe C bond(s) is ______.
Ans.(3)
Hence there are 3 Fe C bonds.
3
22. Among the complex ions, Co NH 2 CH 2 CH 2 NH 2 Cl2 , CrCl2 C2 O 4 ,
2 2
2
Fe H 2 O OH , Fe NH3 CN , Co NH 2 CH 2 CH 2 NH 2 NH3 Cl and
4 2 2 4 2
2
Co NH3 H 2 O Cl , the number of complex ions(s) that show(s) cis-trans isomerism is ______.
4
Ans.(6) Given complexes are of M(AA)2 b2 , Ma4b2, M(AA)2bc, Ma4 bc types and are capable of showing cis-trans
isomerism.
23. Three moles of B2 H6 are completely reacted with methanol. The number of moles of boron containing products
formed is ______.
Ans.(6) 1B2 H6 6 CH3OH
2B(OCH3 )3 6H 2
1 mole 2 moles
3 moles 6 moles
24. The molar conductivity of a solution of a weak acid HX 0.01M is 10 times smaller than the molar conductivity
of a solution of a week acid HY 0.10 M . If 0 0 , the difference in their pK a values,

x y
pK a HX pK a HY , is ______. (Consider degree of ionization of both acids to be << 1)
Ans.(3) (0m ) ( 0m ) (0m )HX ( m

0
)HY
X Y
m
Now,
0m
HX ( m ) HX (K a )HX . CHY ( m )HX

HY ( m ) HY (K a ) HY . CHX ( m )HY

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2 2
(K a )HX CHX ( m )HX 0.01 1
. 2
103
(K a )HY CHY ( m )HY 0.1 10
pK a (HX) pK a (HY) 3
238
25. A closed vessel with rigid walls contains 1 mol of 92 U and 1 mol of air at 298 K. Considering complete decay
238 206
of 92 U to 82 Pb , the ratio of the final pressure to the initial pressure of the system at 298 K is ______.
238 206
Ans.(9) 92 U
82 Pb 8 6
on getting neutralized forms He gas.
238
So 1 mole 92 U produces 8 moles He
Initial number of mole of gases = 1 mole
Final number of mole of gases = 1 + 8 = 9 moles
9
Ratio of final pressure to initial 9 (P n)
1
26. In dilute aqueous H 2SO 4 , the complex diaquodixalatoferrate(II) is oxidized by MnO 4 . For this reaction, the
ratio of the rate of change of H to the rate of change of MnO 4 is ______.

2
Ans.(8) Balanced reaction is Fe H 2 O 2 C 2 O4 2 MnO4 8H Fe3 4CO 2 Mn 2 6H 2O

1 H MnO4

8 t t
H
8
t
MnO 4

t
27. The number of hydroxyl group(s) in Q is :
Ans .(4)
KMnO4
28. Among the following, the number of reaction(s) that produce(s) benzaldehyde is ______.
I II
III IV d

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Ans.(4)

correct
Marking scheme :
29. Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination,
respectively, are :
(A) CH3SiCl3 and Si CH3 4 (B) CH3 2 SiCl2 and CH3 3 SiCl
(C) CH3 2 SiCl2 and CH3SiCl3 (D) SiCl4 and CH3 3 SiCl
Ans.(B) CH3 2 SiCl2 is used for preparation of linear polymer and CH3 3 SiCl is used for chain termination.
30. When O2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O2 . The TRUE
statement(s) regarding this adsorption is (are) :
(A) O2 is physisorbed (B) Heat is released

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(C) Occupancy of *2p of O2 is increased (D) Bond length of O 2 is increased
Ans.(BCD) M O 2 M O2
It is an example of chemisorptions and it is exothermic process.
Electronic configuration:
2 *2 2
O2 1s , 1s , 2s , *2 2 2 2 *1 *1
2s , 2Pz , 2Px , 2Py , 2Px , 2Py
O2 1s
2 *2
, 1s , 22s , *2 2 2 2 *2 *1
2s , 2Pz , 2Px , 2Py , 2Px , 2Py
Bond order of O2 is 2
Bond order of O2 is1.5
1
Bond length
Bond order
31. One mole of a monoatomic real gas satisfies the equation p V b RT where b is a constant. The relationship
of interatomic potential V r and interatomic distance r for the gas is given by :
(A) (B) (C) (D)
Ans.(C) As the given gas equation is P(V b) RT .

According to this equation inter particle forces is ignored/neglected.
Hence particles of gas can not get attracted so inter-atomic potential can not be negative.
Now, on further compression particles cant come closer than a certain distance.
So answer must be (C).
32. In the following reactions, the products S is :
(A) (B) (C) (D)
Ans.(A)

Vidyamandir Classes
33. The major product U in the following reactions is :
(A) (B) (C) (D)

Ans.(B)
34. In the following reactions, the major product W is

Vidyamandir Classes
Ans.(A)
35. The correct statement(s) regarding, (i) HClO , (ii) HClO2 , (iii) HClO3 and (iv) HClO4 , is (are)
(A) The number of Cl O bonds in (ii) and (iii) together is two
(B) The number of lone pairs of electrons on Cl in (ii) and (iii) together is three
(C) The hybridization of Cl in (iv) is sp 3
(D) Amongst (i) to (iv), the strongest acid is (i)
Ans.(BC)
The number of lone pair in (ii) and (iii) together is 3

Amongst (i) and (iv), the strongest acid is (iv).
36. The pair(s) of ions where BOTH the ions are precipitated upon passing H2S gas in presence of dilute
HCl, is(are)
(A) Ba 2 , Zn 2 (B) Bi 3 , Fe3 (C) Cu 2 , Pb 2 (D) Hg 2 , Bi3
Ans.(CD) Pb 2 , Cu 2 , Hg 2 and Bi3 belong to group 2 of basic radicals which have low Ksp values (of
corresponding metal sulphides) and hence are precipitated even in low concentration sulphides (which is there
when H2S is passed in presence of dilute HCl)

correct.
Marking scheme :

Vidyamandir Classes

In the following reactions
Pd-BaSO
4 C H
2 6 i. B H
C8 H6 8 8 X
H2 ii. H 2O 2 , NaOH, H 2O
2 H O 2 Y i. EtMgBr, H O

C8 H8 O

HgSO4 , H 2SO4 ii. H , heat
37. Compound X is :
Ans.(C)
Compound X is (C)
38. The major compound Y is :
Ans.(D)

Vidyamandir Classes

When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a
temperature increase of 5.7C was measured for the beaker and its contents (Expt.1). Because the enthalpy of
neutralization of a strong acid with a strong base is a constant 57.0kJ mol , this experiment could be used to
1
measure the calorimeter constant.

In a second experiment (Expt. 2) 100 mL of 2.0 M ACETIC ACID K a 2.0 105 was mixed with 100 mL of 1.0 M
NaOH (under identical conditions to Expt.1) where a temperature rise of 5.6C was measured. (Consider heat capacity of
all solutions as 4.2J g 1 K 1 and density of all solutions as 1.0g mL1 )
39.
Enthalpy of dissociation in kJ mol1 of acetic acid obtained from the Expt. 2 is
(A) 1.0 (B) 10.0 (C) 24.5 (D) 51.4

57 103 0.1 (4.2 200 5.7)
Ans.(A) Heat capacity of calorimeter = 1000 840 160 J / K
5.7
Energy required to dissociate 0.1 moles of CH3COOH (100 ml, 2M)
(57 103 0.1) (4.2 200 5.6) (160 5.6)
(57 103 0.1) (1000 5.6) 1000 0.1 100 J

100 J
Enthalpy of dissociation = 1000 J / moles 1kJ / mol (A)
0.1moles
40. The pH of the solution after Expt.2 is

(A) 2.8 (B) 4.7 (C) 5.0 (D) 7.0
Ans.(B) CH3COO H 2O
CH3COOH OH
t0 200 100
(m.moles)
100 x 100 x
t t eq 100
x 100
[CH3COO ][H ] 100 y

CH3COO H
CH3COOH Ka
[CH3COOH] 100
t t eq 100 100 y
(m.moles)
[H ] y K a 2 105 100.3 105 10 4.7
pH = 4.7

Vidyamandir Classes
PART I : MATHEMATICS

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
41.
The coefficient of x9 in the expansion of 1 x 1 x 2 1 x3 ...... 1 x100 is _________.
Ans .(8) (1 x )(1 x 2 )(1 x3 )......(1 x100 )
(1 x x 2 x3 )(1 x 3 ).........(1 x )
1 x x 2 2 x3 3x 4 4 x5 5 x 6 6 x 7 7 x8 8 x9 .........
Coefficient of x9 8
x2 y 2
42. Suppose that the foci of the ellipse 1 are (f1, 0) and (f2, 0) where f1 > 0 and f2 < 0.
9 5
Let P1 and P2 be two parabolas with a common vertex at (0, 0) and with foci at (f1, 0) and (2f2, 0), respectively.
Let T1 be a tangent to P1 which passes through (2f2, 0) and T2 be a tangent to P2 which passes through (f1, 0). If
1
m1 is the slope of T1 and m2 is the slope of T2, then the value of m22 is _________.
m12

5 2
Ans . (4) e 1
9 3
f1,0 2, 0 f 2 , 0 2, 0
2
P1 : y 4.2 x
p2 : y 2 4 4 x
T1 : ty x 2t 2 4, 0 satisfies it
2 2
0 4 2t t 2
t 2
1
m1
2
T2 : ty x 4t 2 2, 0 satisfies it
1 1
0 2 4t 2 t 2 t
2 2
m2 2
ecos( n ) e
43. Let m and n be two positive integers greater than 1. If lim e then the value of m is
m
2 n

Ans (2)
lim e

cos n 1 n
1 cos 1
0 e

n
cos 1

m

Vidyamandir Classes
n n
2
2sin 2
e lim0 1 2
n 2 m

2
1 n
e lim
0 1 1 2
4 m
e m
if 2n m or 2
2 n
1 2
If e9 x 3tan
1 x 12 9 x
44.
1 x2
dx

0
3
where tan 1 x takes only principal values, then the value of log e 1 is _________.
4
Ans .(9) 9 x 3tan 1 x t
3
9 2 dx dt
x
1 1
et dt et e9 x 3tan x
0
3
9
e 4 1
3
9
1 e 4
1
45. Let f : be a continuous odd function, which vanishes exactly at one point and f 1 . Suppose that
2
x x
F ( x) 1
F ( x) f (t ) dt for all x 1, 2 and G ( x) t f ( f (t )) dt for all x 1,2. If lim
, then
x 1 G ( x ) 14
1 1
1
the value of f is _________.
2
F( x ) F '( x )
Ans .(7) lim lim [ F (1) 0, G (1) 0]
x 1 G( x ) x 1 G'( x )
f ( x) 1
lim
x 1 x | f ( f ( x) | 14
f (1) 1 f (1) 1

| f [ f (1)] | 14 1 14
f
2
1 1
f 14 f (1) 14 7
2
2

46. Suppose that p, q and r and three non-coplanar vectors in 3 . Let the components of a vector s along

p, q and r be 4, 3 and 5, respectively. If the components of this vector s along

p q r , p q r and p q r are x, y and z, respectively, then the value of 2x y z is
_________.

Vidyamandir Classes

Ans .(9) s 4 p 3q 5r

Also s x p q r y ( p q r ) z p q r
x y z 4 ......(1)
x y z 3 ......(2)
x y z 5 ....(3)
Solving 1 , 2 , and 3
9 7
x 4, y , z
2 2
2x y z 9
k k
47. For any integer k, let k cos i sin , where i 1.
7 7
12
k 1 k
k 1
The value of the expression 3
is _________.
4k 1 4k 2
k 1
12 k
i i
e 7 . e 7 1
k 1 12
4
Ans .(4) 3 i 4k 2

i 1 3
e 7 e 7
k 1
48. Suppose that all the terms of an arithmetic progression (A.P.) are natural numbers. If the ratio of the sum of the
first seven terms to the sum of the first eleven terms is 6 : 11 and the seventh term lies in between 130 and 140 ,
then the common difference of this A.P is _________.
Ans .(9) Let common diff. be d.
7
tr 6
r 1
11

11
tr
r 1
7
2 a 7 1 d 6
2

11 11
2 2 a 11 1 d

2 a 6d 6

2a 10d 7
a 3d 6

a 5d 7
a 9d
130 t7 140
a 6d 130, 140
15d 130, 140
d 9
a 81

Vidyamandir Classes

correct
Marking scheme :
49. Let f , g : 1, 2 be continuous functions which are twice differentiable on the interval 1, 2 . Let the
values of f and g at the points 1, 0 and 2 be as given in the following table:
x 1 x0 x2
f x 3 6 0
g x 0 1 1
In each of the intervals 1, 0 and 0, 2 the function f 3g " never vanishes. Then the correct
statements(s) is(are) :
(A) f ' x 3 g ' x 0 has exactly three solution in 1, 0 0, 2
(B) f ' x 3 g ' x 0 has exactly one solution in 1, 0
(C) f ' x 3 g ' x 0 has exactly one solution in 0, 2
(D) f ' x 3 g ' x 0 has exactly two solutions in 1, 0 and exactly two solutions in 0, 2
Ans .(BC) Let h x f x 3g x
h 0 h 1
h c1
0 1
At least one c1 1 0
For at least one c1 1 0 h c1 0
Exactly one c1 1 0 h c1 0 .
f c1 3g c1 0
h x 0
Similarly exactly one c2 in (0, 2)
For which f c2 3g c2 0

50. Let f x 7 tan 8 x 7 tan 6 x 3 tan 4 x 3 tan 2 x for all x , . Then the correct expression (s) is (are)
2 2
/4 /4
1
(A) xf ( x )dx (B) f x dx 0
0
12 0
/4
1
(C) xf x dx (D) f x dx 1
6
0 0
8 6 4 2
Ans (AB) f ( x) 7 tan x 7 tan x 3tan x 3tan x

7 tan 6 x 3 tan 2 x sec2 x

/4
0 0
xf ( x)dx x f ( x)dx 4 4 f ( x)dx
0
(1)

Vidyamandir Classes
f ( x)dx 7 tan
6
x 3 tan 2 x sec2 xdx
tan 7 x tan3 x
From (1),

0
4 xf ( x )dx 0
x tan 7 x tan 3 x 4 4 tan 3 x tan 4 x 1 dx
0

4 tan 5 x tan 3 x sec2 xdx
0

tan 6 4
x tan x 4
4 xf ( x) dx
0 6 4
0
1 1 1
(A)
6 4 12

4
0
4
f ( x )dx tan 7 x tan 3 x 0 0 (B )
1
192 x3 1
51. Let f '( x) for all x with f 0. If m f x dx M , then the possible values of m
4 2
2 sin x 1/ 2
and M are :
1 1
(A) m 13, M 24 (B) m ,M
4 2
(C) m 11, M 0 (D) m 1, M 12
1
Ans .(D) As f x achieve its min value at x as numerator attains minimum and denominator attains
2
1
maximum & similarly maximum value at x 1 in the interval , 1
2
8 f ' x 96
x x x
1/ 2 8 dx 1/ 2 f ' x dx 1/ 2 96 dx 8 x 4 f x 96 x 48
1 1 1
1/ 2 8x 4 dx 1/ 2 f x dx 1/ 2 96 x 48 dx
1
4 x 2 4 x 11/ 2 f x dx 48 x 2 48 x 1/
1
2
1/ 2
1
1 f x dx 12
1/ 2
52. Let S be the set of all non-zero real numbers such that the quadratic equation ax 2 x 0 has two
distinct real roots x1 and x2 satisfying the inequality | x1 x2 | 1. Which of the following intervals is(are) a
subset(s) of S ?
1 1 1 1 1 1
(A) , (B) , 0 (C) 0, (D) ,
2 5 5 5 5 2
Ans (AD) x 2 x
x1 x2 1
x1 x2 2 1

Vidyamandir Classes
x1 x2 2 4 x1x2 1
1
41
2
1
5
2
5 2 1
1 1
, ,
5 5
6 4
53. If sin 1 and cos1 , where the inverse trigonometric functions take only the principal
11 9
values, then the correct option(s) is(are) :
(A) cos (B) sin (C) cos 0 (D) cos
Ans (BCD)

cos cos3 3cos
3 3
3
4 4 44 3 4 92 256 972
4 3 0
9 9 93 93

sin 3sin 4 sin 3
3 3
3
65 65 65 65
3 4 3 4 0
9 9 9 81
3
85 85
cos cos3 3cos 4 3
3 3 11 11
85 85
4 3 0
11 121
cos cos cos sin sin as sin 0
54. Let E1 and E2 be two ellipses whose centers are at the origin. The major axes of E1 and E2 lie along the x-axis
2
and the y-axis, respectively, Let S be the circle x 2 y 1 2. The straight line x y 3 touches the curves
2 2
S, E1 and E2 at P, Q and R, respectively. Suppose that PQ PR If e1 and e2 are the eccentricities of E1
3
and E2, respectively, then the correct expression(s) is(are) :
43 7 5 3
(A) e12 e22 (B) e1e2 (C) e12 e22 (D) e1e2
40 2 10 8 4
Ans (AB) P 2 cos , 1 2 sin
2 cos 2 sin 3

sin cos 2
4
P 1, 2
2 2 2 2 1 8
R 1 cos 135, 2 sin135 R , x2 y2
3 3 3 3
2 2 2 2 5 4
Q 1 cos135, 2 sin135 Q , x1 y1
3 3 3 3
x2 y 2 2 x 2 y dy
E1 : 2 2 1 a b 21 21 0
a b a b dx

Vidyamandir Classes
dy x1 b 2 b 2 x1 b 2 5
1
dx a 2 y1 a 2 y1 a2 4
5b 2 4a 2

5a 2 1 e12 4a 2
5 5e12 4
1
e12
5
x2 y2
E2 : 1 p q
2
p q2
x q2 7

dy
dx
2
p 2 y2
1 q 2 x2 p 2 y2
q2 8 p 2 8q 2 1 e22 e22
8
1 7 8 35 43
e12 e22
5 8 40 40
1 7 7
e1e2
5 2 10 8
1 7 27
e12 e22
5 8 40
55. Consider the hyperbola H : x 2 y 2 1 and a circle S with center N ( x2 , 0) . Suppose that H and S touch each
other at a point P ( x1 , y1 ) with x1 1 and y1 0 . The common tangent to H and S at P intersects the x-axis at
point M. If (l , m) is the centroid of the triangle PMN , then the correct expression(s) is(are) :
dl 1 dm x1
(A) 1 for x1 1 (B) for x1 1
dx1 3 x12 dx1 3 x 2 1
1

dl 1 dm 1
(C) 1 for x1 1 (D) for y1 0
dx1 3x12 dy1 3
Ans .(ABD) ( x x2 ) 2 y 2 r 2
x2 y 2 1
( x x2 ) 2 x 2 r 2 1
2 x 2 2 x2 x x22 r 2 1 0
4 x22 8( x22 r 2 1)
x22 2( x22 r 2 1)
x22 2 x22 2( r 2 1)
x22 2( r 2 1) Condition for circle touching hyperbola
x12 y12 1 y1 x12 1

dy dy x1 x2 x1
2 x1 2 y1 0
dx dx y1 y1
x1 x y1 y 1 Equation of tangent
1
M , 0
x1
1
x1 2 x1
x1 y 00 1 2
l , m 1 x1 1
3 3 3

Vidyamandir Classes
1 dm 1 2 x1 x1
l x1
3 x1 dx1 3 2 x 2 1 3 x 2 1
1 1
dl 1 dm 1
1
dx1 3x12 dy1 3
56. The option(s) with the values of a and L that satisfy the following equation is(are) :
4 t 6 4
0 e (sin at cos at )dt L ?
t 6 4
0 e (sin at cos at )dt
e 4 1 e 4 1
(A) a 2, L (B) a 2, L
e 1 e 1
e 4 1 e 4 1
(C) a 4, L (D) a 4, L
e 1 e 1
4
e sin
t 6
Ans .(AC) I1 at cos 4 at dt . . . .(i)
0
4
f t dt
0

I 2 et sin 6 at cos 2 at dt . . . . (ii)
0
2 3 4
I1 f t dt f t dt f t dt f t dt
0 2 3
I1 I 2 e I 2 e 2 I 2 e3 I 2 for a 2 4
I1
1 e e2 e3 for a 2 4
I2
1 e4 1
for a 2 4
I2 e 1

correct.
Marking scheme :

Let n1 and n2 be the number of red and black balls, respectively, in box I. Let n3 and n4 be the number of red and black
balls, respectively, in box II.

Vidyamandir Classes
57. One of the two boxes, box I and box II, was selected at random and a ball was drawn randomly out of this box.
1
The ball was found to be red. If the probability that this red ball was drawn from box II is , then the correct
3
option(s) with the possible values of n1, n2, n3 and n4 is(are) :
(A) n1 3, n2 3, n3 5 , n4 15 (B) n1 3, n2 6 , n3 10 , n4 50
(C) n1 8, n2 6 , n3 5 , n4 20 (D) n1 6 , n2 12 , n3 5, n4 20
Box I Box II
Ans .(AB) n1 Re d n3 Re d
n2 Black n4 Black
A event of getting red ball
E1 event of selecting box I
E2 event of selecting box II
According to Bayes Theorem
P E2 / A

p A / E2 . P E 2
P A / E1 P E1 P E2 . P A / E2
1 n3

2 n3 n4

1 n3 1 n1

2 n3 n4 2 n1 n2
n3
n3 n4 1

n3 n1 3

n3 n4 n1 n2
3n3 n3 n1

n3 n1 n3 n4 n1 n2
2n3 n1
According to options A, B
n3 n4 n1 n2
58. A ball is drawn at random from box I and transferred to box II. If the probability of drawing a red ball from box
1
I, after this transfer, is , then the correct option(s) with the possible values of n1 and n2 is(are)
3
(A) n1 4 and n2 6 (B) n1 2 and n2 3
(C) n1 10 and n2 20 (D) n1 3 and n2 6
Ans .(CD) A Red ball drawn from box I
E1 Red ball transferred from I
E2 Black ball transferred from I
According to Total Probability Theorem,
A A
P ( A) P .P( E1 ) P .P E2
E
1 E2
n1 n1 1 n2 n1

n1 n2 n1 n2 1 n1 n2 n1 n2 1
n12 n1n2 n1 1

n1 n2 n1 n2 1 3
According to the options C and D

Vidyamandir Classes

Let F : be a thrice differentiable function. Suppose that F(1) = 0, F(3) = -4 and F(x) < 0 for all x (1 / 2 , 3) .
Let f (x ) xF (x) for all x .
59. The correct statement(s) is (are)

(A) f '(1) 0 (B) f (2) 0
(C) f '( x) 0 for any x (1, 3) (D) f '( x) 0 for some x (1, 3)
Ans .(ABC) f x xF x
f x xF x F x
f 1 F 1 F 1 0 . . . . (A)
f 2 2F 2 2F 1 0 (since F(x) is decreasing in (1, 3))
f(2) < 0
f x xF x F x
For x 1 3 , F x 0
f x F x F 1 0
f x 0 for x 1 3 . . . . . (C)
3 2 3 3
60. If 1 x F '( x) dx 12 and 1 x F ''( x)dx 40 , then the correct expression(s) is(are) :
3
(A) 9 f '(3) f '(1) 32 0 (B) 1 f ( x) dx 12
3
(C) 9 f '(3) f '(1) 32 0 (D) 1 f ( x)dx 12
3
2
Ans .(CD) x F x dx 12
1
3
3
x 2
F x 2xF x dx 12
1
1
3
9 F 3 F 1 2 2 x dx 12

1
3
36 0 2 f x dx 12
1
3
f x dx 12 . . . . . .(D)
1
f x xF x
f x F x xF x
f x F x xF x F x
x3 F x x 2 f x 2 F x
3
3
x F x dx 40
1

Vidyamandir Classes
3 3
x 2 f x dx 2 x 2 F x dx 40

1 1
3
2
x f x dx 16
1
3
3
2
x f x 2 x f x dx 16
1
1
3
3
9 f 3 f 1 2 xf x 2 f x dx 16

1
1
3
2

9 f 3 f 1 2 x 2 F x
1
2 xF x dx 16

1
3
9 F 3 f 1 2 36 2 xF x dx 16

1
9 f 3 f 1 72 24 16
9 F 3 f 1 32 0 (C)

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READ THE INSTRUCTIONS CAREFULLY

VMC/Paper-2 1 JEE Entrance Exam-2015/Advanced

SECTION 1 (Maximum Marks : 32)

VMC/Paper-2 2 JEE Entrance Exam-2015/Advanced

Ans.(3) Using phasor method of superposition,

4. A monochromatic beam of light is incident at 60 on one

with the normal (see the figure). For n 3 the value of

8 can be removed by Wheatstones bridge concept

10 can now be removed using Wheatstones bridge concept again

VMC/Paper-2 4 JEE Entrance Exam-2015/Advanced

VMC/Paper-2 5 JEE Entrance Exam-2015/Advanced

SECTION 2 (Maximum Marks : 40)

VMC/Paper-2 6 JEE Entrance Exam-2015/Advanced

VMC/Paper-2 7 JEE Entrance Exam-2015/Advanced

(B) x p , y e , KSr 129 MeV, K Xe 86 MeV

12. Two spheres P and Q of equal radii have densities 1 and 2 ,

VMC/Paper-2 8 JEE Entrance Exam-2015/Advanced

VMC/Paper-2 9 JEE Entrance Exam-2015/Advanced

Option A and C correct

15. In plotting stress versus strain curves for two materials

the correct statement(s) is (are)

Ans.(AB) As (Breaking Stress)P > (Breaking Stress)Q

VMC/Paper-2 10 JEE Entrance Exam-2015/Advanced

SECTION 3 (Maximum Marks : 16)

VMC/Paper-2 11 JEE Entrance Exam-2015/Advanced

Paragraph for Questions 17 - 18

VMC/Paper-2 12 JEE Entrance Exam-2015/Advanced

Paragraph for Questions 19 - 20

VMC/Paper-2 13 JEE Entrance Exam-2015/Advanced

It a ray enters a structure at i then it also places at i

VMC/Paper-2 14 JEE Entrance Exam-2015/Advanced

SECTION 1 (Maximum Marks : 32)

Hence there are 3 Fe C bonds.

of a solution of a week acid HY 0.10 M . If 0 0 , the difference in their pK a values,

pK a HX pK a HY , is ______. (Consider degree of ionization of both acids to be << 1)

Ans.(3) (0m ) ( 0m ) (0m )HX ( m

VMC/Paper-2 15 JEE Entrance Exam-2015/Advanced

ratio of the rate of change of H to the rate of change of MnO 4 is ______.

27. The number of hydroxyl group(s) in Q is :

VMC/Paper-2 16 JEE Entrance Exam-2015/Advanced

SECTION 2 (Maximum Marks : 40)

VMC/Paper-2 17 JEE Entrance Exam-2015/Advanced

(C) Occupancy of *2p of O2 is increased (D) Bond length of O 2 is increased

(A) (B) (C) (D)

Ans.(C) As the given gas equation is P(V b) RT .

32. In the following reactions, the products S is :

(A) (B) (C) (D)

VMC/Paper-2 18 JEE Entrance Exam-2015/Advanced

33. The major product U in the following reactions is :

(A) (B) (C) (D)

34. In the following reactions, the major product W is

VMC/Paper-2 19 JEE Entrance Exam-2015/Advanced

The number of lone pair in (ii) and (iii) together is 3

SECTION 3 (Maximum Marks : 16)

VMC/Paper-2 20 JEE Entrance Exam-2015/Advanced

Paragraph for Questions 37 - 38

38. The major compound Y is :

VMC/Paper-2 21 JEE Entrance Exam-2015/Advanced

Paragraph for Questions 39 - 40

measure the calorimeter constant.

(A) 1.0 (B) 10.0 (C) 24.5 (D) 51.4

(57 103 0.1) (1000 5.6) 1000 0.1 100 J

40. The pH of the solution after Expt.2 is