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Abstract
Environmental problems caused by recycling wasted paper at a board paper mill provide the material of this study. Two scenarios have been
investigated: The first being the treatment of the end-of-pipe, and the second being the control and management of pollution problems through
the application of in-plant control and pollution prevention measures. Comparison between the two alternatives, based on a cost-benefit analysis
and compliance with National Environmental Laws was done. From this study it was apparent that the implementation of the pollution preven-
tion measures such as the recovery of fiber, reduction of fresh water consumption, and optimization of white water usage proved to be very cost
effective. All the implemented solutions have short payback periods and resulted in great savings compared with the treatment of the end-
of-pipe.
2006 Elsevier Ltd. All rights reserved.
Keywords: Board paper mill; Cleaner production; Pollution prevention; Recovery of fiber; Dissolved air flotation
0959-6526/$ - see front matter 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jclepro.2006.07.045
S.I. Abou-Elela et al. / Journal of Cleaner Production 16 (2008) 330e334 331
Fig. 1. Process, water usage and wastewater discharged from the board paper mill.
The objective of this study was two folds: carried out for almost two months. Composite samples from
the end-of-pipe were collected and analyzed according to
To technically and economically evaluate the treatment of Standard Methods [6].
the end-of-pipe approaches in order to comply with the
Egyptian Environmental Legislations. 2.3. Treatability studies
To evaluate the implementation of the pollution prevention
and cleaner production approaches versus the treatment of End-of-pipe was treated via physico-chemical processes
the end-of-pipe. namely; coarse screen, screening followed by sedimentation
for two hours or screening followed by chemical coagula-
2. Materials and methods tion/floatation under pressure. Screening was already available
in the factory. It is a cylindrical in shape with a diameter of
In this study two approaches have been investigated to 1.25 meters, 2.40 meters length and mesh size 20/cm2. The co-
manage and control the industrial effluent produced from agulant used for chemical coagulation was alum aided with
this plant. The first approach was the treatment of the end- cationic polymer. The optimum coagulant doses and the pH,
of-pipe, while the second approach was the implementation were determined.
of any possible pollution prevention measures.
3. Results and discussions
2.1. Pollution prevention measures
3.1. Characteristics of wastewater
In order to determine the opportunities for any pollution
prevention measure, industrial auditing of the plant under Analysis of the end-of-pipe indicated that it carries signifi-
investigation has been carried out. The audit was conducted cant quantities of fiber, fines, filler and other wet-end additives
using a systematic review of the companys processes and that contribute to the total suspended solids (TSS), chemical ox-
operations designed to identify and provide information about ygen demand (COD) and biological oxygen demand (BOD).
opportunities to reduce waste, reuse and recycling of water, re- Their average corresponding values were 242 Kg TSS/ton
covery and reuse of materials, and to improve the operational product, 411 Kg COD/ton product and 124 Kg BOD/ton prod-
efficiency [4]. The industrial auditing guidelines were prepared uct, respectively. It is noteworthy that the concentration of TSS
for application in Egypt as presented in Guidelines for Indus- in the final effluent discharged from any paper mill varies based
trial Audits, prepared by Entec/TCOE [5]. on the first pass retention time, white water system design, clar-
All the improvement measures were documented by a cost/ ification equipment, equipment arrangement and system con-
benefit analysis whenever possible. straints in terms of water reuse [7].
2.2. Collection of samples and analysis 3.2. First approach: treatment of end-of-pipe
Due to the great variation in the quality and quantity of The efficiency of the different treatment processes of the
wastewater produced, a continuous monitoring program was end-of-pipe is shown in (Table 1). It is obvious that utilization
332 S.I. Abou-Elela et al. / Journal of Cleaner Production 16 (2008) 330e334
Table 1
Comparison of the efficiency of the different treatment processes
Parameters* Raw wastewater 1 % Removal 2 % Removal 3 % Removal Ministerial
decree 4/2000**
pH range 7.1e7.4 7.1e7.4 e 7.1e7.4 e 6.6e6.3 e 6.0e9.5
COD, mgO2/1 10,265 2591 75 1533 85 712 93 1100
BOD, mgO2/1 3100 1065 65.6 800 74.2 432 86 600
Total suspended 6046 1702 72 610 89.9 19.7 99.7 800
solid, mg/l
*Average of 6 results. **Ministerial decree for discharge into public sewerage system. 1- Screening only. 2- Screening followed by sedimentation. 3- Screening
followed by chemical treatment.
of the available screen in the factory proved to be very effi- The technologies applied for pollution control in the mill
cient in removing most of the particulates and organic matters, were:
as indicated by the percentage removal of TSS (72%), COD
(75%) and BOD (65.6%). The screened effluent was subjected Recovery of fiber.
then to a plain sedimentation for two hours. Although the Reuse of clarified/unclarified white water at appropriate
results indicated a great improvement in the quality of the areas.
primary treated effluent, the residual values of TSS, COD Minimization of fresh water consumption without affect-
and BOD still did not comply with the National regulatory ing runability or quality.
standards for wastewater discharge into the public sewage
network. The proposed solutions were already implemented at the
Screening followed by chemical coagulation/sedimentation factory. The economic return was calculated. Evaluation of
process using the pre-determined optimum doses of alum the quality of the end-of-pipe vs. pollution prevention was
(130 w 150 mg/l), aided with 5 mg/l cationic polymer and at also determined.
the optimum pH of w6.2 0.2 resulted a good quality of
the treated effluent. However, in some cases, some particulates 3.3.1. Recovery of fiber
were floated during the sedimentation process. Accordingly, Wastewater discharged from the factory is almost 1000 m3/
dissolved air flotation using alum and the cationic polymer day. It contains high concentration of suspended solids (fibers)
has been recommended [8]. Fig. 2 shows the schematic dia- and organic materials as indicated by, TSS, COD and BOD
gram of the proposed treatment train. values. Also, the wastewater contains plastic particles and
sand.
3.3. Second approach: implementation In order to recover the fiber, it was found necessary to re-
of pollution prevention measures move the plastic particles as well as sand. This was carried
out using a sand filter of 18 m3 capacity and a vibration screen,
Industrial auditing at the factory revealed that all the pro- which separated the plastic particles and other contaminants
cesses are operated in an open circuit. To apply the scenario larger than 3 mm. The recovered fibers amounted to 0.4 mt/
of pollution minimization and waste reduction, most of the mt product and are recycled to stock chest. A great benefit
open circuit processes have been changed to closed circuit was gained out of this solution (L.E. 1,350,000/year) with
type operation. a payback period not exceeding 10 days.
(D)
(E)
(1) (3) (C)
(2) (2)
(A)
1 - Slow down chamber
2 - Approach channel
3 - Coarse screen chamber
Settled solids Treated
(B) A - Alum. Sulfate tank
water
B - Polymer tank
C - Flash mixing tank
D - Dissolved air floatation unit Thickened
overflow
E - Compressed air
Table 2 Table 4
Fresh water consumption before and after the implementation of in plant con- Quality of the end-of-pipe after implementation of the in-plant control
trol measures measures
Point of use Fresh water usage m3/day Parameters* Raw End-of % Removal Permissible
Before modifications After modifications wastewater pipe limits