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Newtonian ferrofluids in the presence of an applied uniform
magnetic field. Non-Newtonian flow of dilute ferrofluids in 1
+ m h0 .
h0 h0I/8 + e 2 7
wide ranges of and should be studied extensively. In 2
this paper, we study the planar flow of dilute ferrofluids with
finite magnetic anisotropy in a stationary uniform magnetic Here, d / dt is the material derivative, T is the stress tensor, I
field oriented in the perpendicular direction of vorticity. The is the Kronecker , e is the third-order alternating pseudot-
main goal is to obtain a mathematical model and to under- ensor, v is the velocity vector, is the angular velocity
stand the physical aspects of general viscometric flows. A vector, p is the pressure, is the density, is the shear
magnetoviscosity expression describing the non-Newtonian viscosity, is the vortex viscosity, related to by
behavior is first derived from the MRSh model by the EF = 3 / 2, j is the moment of inertia per unit mass, is the
method. The corresponding fully developed field equations effective relaxation time, m is the magnetization vector un-
with respect to shear and pressure driving mechanisms are der the applied external magnetic field vector h0 and the flow
further analytically derived. By comparing with available vorticity vector = v / 2, b is the induction field vector,
Newtonian-fluid models, the applicability of the EF magne- related to h0 and m by b = h0 + 4m, and he is the effective
toviscosity for small and moderate values of is discussed. field vector, related to m by
According to the stress-strain relation, the fluid regime is
determined. The non-Newtonian effect on the flow fields and m = msL = NmL , ,
N = /V = mhe/kBT,
characteristics, including the velocity, angular velocity,
cross-flow magnetization, streamwise magnetization, flow 8
rate, and flow drag, is studied.
where ms is the saturation magnetization, L is the Langevin
function, = is the Langevin argument of the effective
II. PROBLEM FORMULATIONS field vector dimensionless effective field vector, N is the
A. Field equations
particle number per unit volume, is the particle volume
fraction, V is the mean volume per particle,
m
m = m is
The set of hydrodynamic equations for incompressible di- the mean magnetic moment vector per particle, kB is the
lute ferrofluids under the effective-field method 17 consists Boltzmann constant, and T is the absolute temperature. The
of the mass balance equation momentum balance equations 2 and 3 can be found in
Hubbard and Stiles 27, and the magnetization equation 5
v = 0, 1
can be obtained from Shliomis et al. 18.
the linear momentum balance equation The dynamics of magnetization is linked with two thermal
fluctuation mechanisms. The first is the Brownian mecha-
dv 1 nism. In this mechanism, the relaxation occurs by particle
= p + + 2v + 2 + h0 m rotation 28 with the characteristic time 29:
dt 2
1
3V
m h0 , 2 B = . 9
2 k BT
the angular momentum balance equation The second is the Nel mechanism. In this mechanism, the
relaxation is due to rotation of the magnetic moment within
d the particle 30. According to Brown 31, the characteristic
j + m h0 ,
= 4 3 time has the form
dt
dt he2 Ahe2
e 1 /
1
N = D + 21 . 11
where 2 1+
2L Here, 0 is the extinction time of the Larmor precession, V
A = . 6 m
L L2 is the mean volume of the magnetic phase per particle, m
= ml / 6 is the magnetic viscosity ml is the saturation mag-
The companion constitutive relation is netization of the ferromagnet, is a dimensionless attenua-
056305-2
NON-NEWTONIAN FLOW OF DILUTE FERROFLUIDS IN A PHYSICAL REVIEW E 78, 056305 2008
uw = 0,0, zx,
x
uy m = mxx,myx,0. 13
y The constitutive equation described by Eq. 7 then reduces
-z
to
056305-3
WENG, CHEN, AND CHEN PHYSICAL REVIEW E 78, 056305 2008
1 1
f
*o f Vof f *of
(
Morozov et al. (2006)
ZW , Non-Newtonian fluids
(
Stepanov (2003)
ZW , Non-Newtonian fluids
(
Miguel & Rubi (1995)
f
0.4 0.4
0.2 0.2
0 0
0 5 10 15 20 25 30 0 5 10 15 20 25 30
[ [
FIG. 2. Variation of the reduced magnetoviscosity MV with the FIG. 3. Variation of the reduced magnetoviscosity MV with the
dimensionless magnetic field strength for different Newtonian- dimensionless magnetic-field strength for different values of the
fluid weakly nonequilibrium models with different values of the shear deformation with three assigned values of the magnetic-
magnetic-anisotropy parameter . The limit of Stepanovs model is anisotropy parameter .
/ 2.
3
mv =
L 2
0.
for
uy =
1
1 dp 2
2 1 + 23 MV dy
x + 2A1x + A0 , 22
2 + 1 + 1L L2
C. Viscometric flow
1 MV 1 dp
A fundamental understanding of viscometric flow fields my = NmB x + A1 , 25
1 + 2 MV dy
3
and characteristics in ferrohydrodynamic systems is neces-
sary. In this section, we obtain the mathematical model first where A1 and A2 are arbitrary constants. An important pa-
for the shear-driven plane flow and then for the pressure- rameter for flow characteristics is the flow rate, given by
driven plane flow. By using the form shown in Eq. 13, the
governing equations 15 can be reduced to q = w
uydx =
1 1 dp 3
6 1 + 23 MV dy
w + 3A1w2 + A0w.
0
3 d uy p 2
p
+ MV = 0, = 0, 26
2 dx2 y x
Another important parameter for flow characteristics is the
1 duy friction force exerted on the wall flow drag, defined as
z = 1 MV ,
2 dx txy0 + txyw
t =
2
mx = LNm ,
=
1
2
3
1 + MV
2
A1 +
1+
1
2 MV
3
dp
dy
w + A1 .
27
MV duy
my = NmB , 21 Consider the flow with dp / dy = 0 between a stationary
dx
plate and a moving plate at a constant velocity uw, as shown
where the dimensionless magnetoviscosity MV in Fig. 1a. The dimensionless general solutions with no-slip
= mv / 3 / 2. The general solutions of these equations are velocity boundary conditions are
056305-4
NON-NEWTONIAN FLOW OF DILUTE FERROFLUIDS IN A PHYSICAL REVIEW E 78, 056305 2008
uy t 3
Us = = X, 28 Ts = = 1 + MV . 34
uw uw/w 2
Consider the flow driven by a pressure gradient dp / dy
z between two stationary parallel plates, as shown in Fig. 1b.
=s
= 1 MV , 29
uw/2w The dimensionless general solutions with no-slip velocity
boundary conditions are
mx
M sx = = L, 30
Nm
uy 4
Up = = X X2, 35
w2/8dp/dy 1 + 23 MV
my MV
M sy = = , 31
NmBuw/w
where
x
p =
z
w/4dp/dy
= 1 MV
2 1
1 + 2 MV 2
3 X ,
X= . 32
w 36
s = q = 1 , mx
Q 33 M xp = = L, 37
u ww 2 Nm
056305-5
WENG, CHEN, AND CHEN PHYSICAL REVIEW E 78, 056305 2008
M yp =
my
NmBw/8dp/dy
=
MV 8 1
1 + 2 MV 2
3 X . = 8.85 102, the mean magnetic moment strength per par-
ticle m = 4.12 1019 A m2, and the mean volume per par-
ticle V = 1.77 1024 m3. Calculations yield = 2.18
38 B
10 s and D = 6.26 109 s. The parametric study has
6
The corresponding flow rate and flow drag are, respectively, been performed over the ranges 0 30, 0 2, and
0.01 2.741 . Note that 0 means that
p= q 2/3 the value of is much smaller than 0.01 and represents the
Q = , 39
w3/8dp/dy 3 Newtonian flow and that means that the value of is
1 + MV
2 much greater than 100 and represents the hard-dipole flow.
First, we compare the calculated results of our magneto-
t viscosity expression with those of available expressions. Two
T p = = 4. 40 well-known expressions, obtained phenomenologically by
w/8dp/dy Shliomis 11 and microscopically from the Fokker-Planck
equation by Martsenyuk et al. 12, are limited to the case of
III. RESULTS AND DISCUSSION hard dipoles. A number of microscopic expressions based on
the FP equation were further developed for the case of par-
We pay attention to the non-Newtonian influence of mag- ticles with finite magnetic anisotropy. Raikher and Shliomis
netoviscosity on plane flow for a kerosene-based ferrofluid 36 proposed the FP equation for the limit , in which
with magnetite particles Fe3O4 stabilized by a chemisorbed the dipoles are rapidly oriented toward the field direction,
monomolecular layer of pure oleic acid at room temperature and gave calculations of the magnetoviscosity for strong
T = 298.15 K. The ferrofluid possesses the following prop- magnetic fields. Shliomis and Stepanov 37 deduced the
erties: shear viscosity = 1.69 103 kg/ m s, the dimension- general FP equation for the case of arbitrary values of and
less attenuation constant = 4.00 102, the gyromagnetic obtained the expressions for the weak and strong magnetic
ratio = 2.00 10111 / T s, the particle volume fraction fields 1 and :
1 1 2
1 + 2F2 + 1 F2 2 for 1,
4 3 +1 3 + G
mv =
3
G
14 + 5F2 + 16F4 + 35 1
G 2
F 2 41
for ,
2 2
1+ 14 + 5F2 + 16F4 35 F 2
G G
where
G =
2 + F2
4 1 F 2
3/2e, R=
0
1
expx2dx, F 2 =
2
3 dR/d 1
R
,
3
F 4 =
1
8
3 30
dR/d
R
+ 35
d2R/d2
R
.
42
The limits 1 and greatly reduce the applicability of Eq. 41 in the most interesting and widely used region
10. Miguel and Rub 38 used a Green-Kubo equation proposed from linear response theory to obtain the general expres-
sion
where
R01 =
L
, R02 =
L
Q, R03 =
1
2
13
L
3Q 1, Q =
1
2
2 exp
/Erfi
1 ,
056305-6
NON-NEWTONIAN FLOW OF DILUTE FERROFLUIDS IN A PHYSICAL REVIEW E 78, 056305 2008
G2 + L + 2Q 2G
2 Bs + 2 + L + 0
Aij = GL + 1/Q 1 G . 44
LQ 2 Bs + 2 +
L1 3Q + Q 2 Bs + 6 + L
Here, Erfi is the imaginary error function. Stepanov 39 re- be found from Eqs. 28, 29, 35, and 36 that, except for
cently derived an expression coming from the extension of the velocity Us, the field distributions are influenced by the
the study of Raikher and Shliomis in the range / 2: parameter . From the plot, the non-Newtonian effect in-
creases slowly with the value of and leads to enhance-
3 35L22F22 ment of these flow fields. Note that, on the contrary, the
mv = , 45
2 14 + 5L2F2 + 16L4F4 non-Newtonian effect leads to a reduction of the magnetiza-
tion, described by Eqs. 30, 31, 37, and 38. In addition,
where
the results reveal that the finite-magnetic-anisotropy effect is
2n + 1Ln to increase the magnitudes of s, U p, and p and to reduce
L0 = 1, L1 = L, Ln+1 = Ln1 . the magnitudes of M sy and M yp.
The shear-thinning non-Newtonian effect on the flow
46 characteristics is plotted in Fig. 4b. It is clear from the plot
Morozov et al. 40 later derived a phenomenological ex- and Eqs. 33 and 34 that Ts is a function of , , and ,
pression proceeding from simple physical arguments, so as s
but Q is a constant. The magnetic-field effect is to increase
to improve the applicability. The simple and compact expres- the magnitude of Ts, but the non-Newtonian and finite-
sion is given by magnetic-anisotropy effects are to reduce the magnitude of
3 2F2L2 Ts. These variations imply that, for shear-driven flow, a com-
mv = . 47 parison between the calculated results of the flow-drag solu-
2 2F2L2 + L + 3
tion 34 and experimental measurements provides a simple
The works of Miguel and Rub, Stepanov, and Morozov et manner to determine material constants. In opposition to
al. are special cases of this study when the fluid is Newton- shear-driven flow, the pressure-driven flow rate is a function
ian weakly nonequilibrium. In Fig. 2, we check the results of these parameters. The magnetic-field effect is to reduce
0 in terms of the reduced magnetoviscosity
for the case the magnitude of Q p, but the non-Newtonian and finite-
MV = mv / 3 / 2 with the corresponding data obtained by magnetic-anisotropy effects are to increase the magnitude of
them. The figure shows that the four theoretical curves do p. For pressure-driven flow, comparison between the calcu-
not appear alike for small and moderate values of , espe- Q
cially at small values of the magnetic-anisotropy parameter lated results of the flow-rate solution 39 and experimental
or . Greater values than their solutions are obtained for measurements provides another simple way to determine ma-
the hard-dipole case , but smaller values may be ob- terial constants.
tained for finite values of . This means that our magneto-
viscosity expression could explain a wide-ranging distribu-
IV. CONCLUSIONS
tion of experimental data.
In Fig. 3, the reduced magnetoviscosity MV, calculated A magnetoviscosity expression for dilute ferrofluids with
from Eq. 18, is plotted as a function of the dimensionless finite magnetic anisotropy has been derived by using the
magnetic field strength for the shear deformation 0, effective-field method. It has further been employed to de-
1, and 2 with the magnetic-anisotropy parameter , 0.1, velop a mathematical model of non-Newtonian flow in a
and 0.01. It is found that MV decreased with increase of . planar Couette-Poiseuille system with an applied stationary
According to the stress-strain relation 15, the phenomenon uniform magnetic field oriented in the perpendicular direc-
is found to be shear thinning. The shear-thinning non- tion of vorticity. Comparison with available Newtonian-fluid
Newtonian effect causes linear viscosity variation. Decreas- models showed that our effective-field expression can ex-
ing the value of leads to increase in the effect first and then plain a wide-ranging distribution of experimental data. The
to a decrease. The maximum non-Newtonian effect was stress strain relation showed that the fluid regime is shear
found at of the order of 0.1. thinning and that the maximum non-Newtonian effect could
Now, we pay attention to the shear-thinning non- be found at the relaxation time ratio the Nel time to the
Newtonian effect on the flow fields and characteristics. In Brownian time of the order of 0.1. It was found that the
Fig. 4, the solid line denotes the non-Newtonian case non-Newtonian effect tends to increase the velocity and an-
= 0.1, and the dash-dotted line denotes the hard-dipole, gular velocity but to decrease the magnetization strength;
Newtonian case , 0. Figure 4a illustrates the moreover, flow rate enhancement and flow drag reduction
flow fields for 0, 1, and 2 with = 0.1 and = 5. It can may be obtained.
056305-7
WENG, CHEN, AND CHEN PHYSICAL REVIEW E 78, 056305 2008
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