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ALL INDIA TEST SERIES


NARAYANA FULL TEST 6 PAPER I&II
ANSWERS
PAPER I
MATHS PHYSICS CHEMISTRY
1. (A) 24. (A) 47. (A)
2. (C) 25. (D) 48. (D)
3. (C) 26. (C) 49. (D)
4. (A) 27. (A) 50. (A)
5. (D) 28. (B) 51. (A)
6. (B) 29. (C) 52. (C)
7. (A), (B), (C), (D) 30. (B), (C), (D) 53. (A), (B), (C), (D)
8. (B), (C) 31. (A), (C) 54. (A), (B), (C), (D)
9. (A), (B), (C) 32. (A), (B), (D) 55. (B), (C), (D)
10. (A, (B) 33. (A), (B), (C) 56. (A), (C)
11. (A) 34. (A) 57. (A)
12. (D) 35. (D) 58. (C)
13. (A) 36. (D) 59. (B)
14. (D) 37. (D) 60. (A)
15. (C) 38. (D) 61. (C)
16. (C) 39. (D) 62. (D)
17. (D) 40. (C) 63. (B)
18. (C) 41. (B) 64. (A)
19. (D) 42. (D) 65. (C)
20. (A) 43. (A) 66. (A)
21. (D) 44. (C) 67. (A)
22. (C) 45. (B) 68. (A)
23. (A) 46. (D) 69. (C)

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PAPER - II
MATHS PHYSICS CHEMISTRY
1. (D) 23. (D) 45. (B)
2. (C) 24. (C) 46. (A)
3. (A) 25. (B) 47. (A)
4. (B) 26. (C) 48. (C)
5. (B) 27. (D) 49. (C)
6. (C) 28. (D) 50. (A)
7. (B) 29. (A) 51. (B)
8. (C) 30. (C) 52. (D)
9. (B) 31. (D) 53. (B)
10. (C) 32. (C) 54. (B)
11. (D) 33. (A) 55. (B)
12. (A) 34. (D) 56. (A)
13. (A) 35. (D) 57. (B)
14. (C) 36. (A) 58. (B)
15. (D) 37. (C) 59. (A)
16. (D) 38. (D) 60. (A)
17. (C) 39. (C) 61. (B)
18. (D) 40. (A) 62. (A)
19. (C) 41. (C) 63. (D)
20. (A) (p) 42. (A) (p), (q), (r), 64. (A) (q)
(B) (r) (B) - (p), (q), (r), (B) (p)
(C) (q), (s), (C) (p), (s) (C) (r)
(D) (p), (r), (s) (D) - (p), (s) (D) (s)
21. (A) (s) 43. (A) (q) 65. (A) (r)
(B) (r) (B) (p) (B) (p), (s)
(C) (q) (C) (r) (C) (r)
(D) (p) (D) (p) (D) (q), (s)
22. (A) (q) 44. (A) (q) 66. (A) (p), (s)
(B) (s) (B) (p) (B) (p)
(C) (p) (C) (r) (C) (q), (r)
(D) (r) (D) (p) (D) (q)

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HINTS AND SOLUTION


PAPER - I

MATHEMATICS
1. (A)
Since PQ is of fixed length
1
PQR | PQ || RP |sin
2
This will be maximum,
if sin = 1 and RP is
maximum.
Since line y = mx + 7
rotates about (0, 7).
If PR ' is perpendicular
to the line then RR ' is
maximum value of PR.
4 0 4
m
4 7 3
2. (C)
The common roots must be roots of the equation 2x2 + (r q) = 0. So their sum is
0. Then the third root of the first equation must be 5 and that of second equation
is 7.
3. (C)
Let, a tan 2 and b tan 2
We have to determine the minimum value of
a 1 b 1 , where a, b 0 .
2 2

b a
a 1 b 1 a 2 1 b2 1 2 a b
2 2

We have,
b a b b a a b a
1/ 4 1/ 2
a 2 1 b 2 1 a b
4 . . . 4 . 8
b b a a b a
4. (A)
We have, A 2
B2 A B A 3 A 2 B AB2 B3
A 2
B2 A B 0
As det (A - B) 0. det(A2 + B2) = 0.
5. (D)
In order to have an equilateral triangle, the sides must be face diagonals. There
are three face diagonal coming out of each vertex. Any two of such three face

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diagonals are the sides of an equilateral triangle. Hence each vertex is the vertex
of three distinct equilateral triangles.
8 1
Thus the required probability =
C3 7
f ( x ) f ( x)
6. (B) f ( x) f ( x) f ( x) 4 1 1
( f ( x )) 4 1
a a
f ( x) f ( x)
0 ( f ( x)) 4 1dx dx
0

1 2 a
tan (( f ( x )) 2a
0

tan 1 ( 3 ) tan 1 (1) 2a



2a
3 4

a
24
3 1 5 1
7. (a, b, c, d) P( A B)
8 2 8 4
AC P( B) P( A B) 1
P
B P( B) 2
A P( A) P ( A B ) 1
P C

B P( B C ) 4
A P( A B) 1
P
B P( B) 2
AC 1 P( A B) 3
P
B
C
1 P( B) 4
B P( B) P( A B) 2
P C

A 1 P( A) 5

8. (b, c) Obviously A C and B D will be non-zero collinear
vectors
( A C ) . ( B D) 0 and similarly ( A B ), (C D ) will be non-zero
collinear vectors
Hence ( A B ) (C D ) 0
9. (A), (B), (C)
We can write,
m + (m + 1) + + (m + k) = 1000
k 1
2m k 1000
2
2m k k 1 2000 (1)
Since (2m + k) (k + 1) = 2m 1 = odd integer

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One of two terms on the left hand side is even and other is odd. Moreover it is
clear that
2m + k > k + 1.
Since 2000 = 24.53, its odd factor only 1, 5, 25 and 125. For odd k + 1 we need
consider only 1, 5 and 25 and for odd (2m + k) we can have only 125. Hence,
2m + k = 2000; k+1=1 m = 1000, k = 0
2m + k = 400; k + 1 = 5 m = 198, k = 4
2m + k = 80; k + 1 = 25 m = 28, k = 24
2m + k = 125; k + 1 = 16 m = 55, k = 15
10. (a, b)
Given circles touch externally at real axis. So, the Y
centre C of the desired circles lies on real axis, which
has radius r. thus CC1 = CC2 = 1 + r.
C1
C1C3 = C2C3 = 1
C C
CC3 = 2 r (1, 0)
3

(3, 0) X
(1 + r)2 = 12 + (2 r)2 r = 2/3
2 1 C2
So, the centre of desired circle is at 1
3 3
2 7
or t = 3 .
3 3
So, required equation of circles are
1 2 7 2
z and z
3 3 3 3
11. (A)
1
Let z r
z
3
1 1 1 1 1
Now z z3 3
3 z z 3 3 3 z 2 3r
z z z z z
r 3 3r 2 0
r 2 r 1 0
2

This implies r 2
12. (D)
Though | x 1| is non-differentiable at x = 1.
| x 1| (x - 1) is differentiable at x = 1, for which LMVT is applicable.
13. (A)
b b

Given that | g x | dx g x dx
a a

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y = g(x) cuts the x-axis at least once, then f(x)g(x) changes the sign at least
b

once in (a, b), hence f x g x dx can be equal to zero.


a

14. (D)
If f ' x exists, then f ' x may or may not be continuous.
For example,
2 1
x sin ; x0
f x x
0, x0

has a derivative at x = 0. but f ' x is discontinuous at x = 0.
1
15. (C) x i 1 x i
ln 2
y 1 dy
i.e. x 1 x
y ln 2
ln 2dx y

ln y x ln 2 c it passes through (0, 2)
c ln 2
y 21 x
x y
xi 1
16. (C) 2 y
xi 2
x
y
y
x
xy c

1 1 1
1 1
17. (D) c y x c
xi 1 xi x
y
c
x 2 y 1 y( x c) ln y ln x ln c1
x
c
y c xe x
1

18. (C)
Equation of tangent at point P(t) on the parabola y2 = 8x is
ty = x + 2t2 (1)
Equation of chord of contact of the circle x2 + y2 = 4 is,
x + y = 4 (2)
Q(, ) lies on (1)
Hence, t = + 2t2 (3)

x y 2t 4 0
t
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y
2 yt 2 x 0
t
y 2
For point of concurrency, x = and y
t t
locus is y2 + 2x = 0

19. (D)
Required point will lies on the director circle of the given circle as well as on
directrix of parabola.
x1 y1 8 and x1 + 2 = 0 point = 2, 2
2 2

20. (A)
Let circum centre be (h, k)
h = /2; k = /2 = 2h and = 2k
Also t = + 2t2 or
2 + 8 = 0
So therefore locus is, x 2y + 4 = 0.
21. (D)
a
b
c
3

1/3

3 4
22. (C)
If a 1 , then 1

2 3 1/6
2 2 3 3 3
2 3
6 2 .3
1

2 3 max

432
23. (A)
27 is essentially true.
3

27
3
is possible only
27
3

1
Whence,
4
3 3 9
a b =
4 16 16

PHYSICS
24. (A)
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2R
4s 28R 3Po
Wgas o r
24Rs
2
P 4 r dr
R
3
25. (D)
v

3R E R
v
COAM mvR = mv3R (i)
1 GMm 1 GMm
COE mv 2 mv '2 (ii)
2 R 2 3R
3 GM
v
2 R
26. (C)
Let total mass is 3m, from impulse momentum principle, we get
r r r

p t 3 p t 2 3mg m 4i 16j 2m i j 3m v 2x i v 2 y j 30mj
v 2x 2 m / s and v 2y 4 m / s
Now u x v 2x 2 m / s and v 2y u y g 2 u y 24 m / s
r
v 2i 24j
27. (A)
For standard clock
2 2
of minute hand = ; of hour hand =
60 min 12 60 min
2 2 rad 2 11 rad
rel
60 12 60 min 60
12
min
Relative angular displacement = 2
2 60 12
min min 65.45 min
Time after which they come together = 2 11 11
60 12
Watch will gain time by 0.45 min 27 s
28. (B)
A = A0 et and I = i0et/
A A 0 e t A 0 t 1
Given, t/ e
i i0e i0
i
for time independent value of .
A
1
0

1
=

1
Tmean = = = 0.4 s

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29. (C)
Net force on the system is zero hence
displacement of the centre of mass of the system will
be zero. Let x be the shift in P, then
l l
m o 1 T x m o 1 3T x
2 2
l T
x= o
2
(C)
30. (B), (C), (D)
Since water falls at maximum distance from wall so the hole should be made at h.
For toppling, av 2 h r 2 2hg r
a2gh h r 2 2hgr
r 3
h
a
(B), (C), (D)
31. (A), (C)
Let Q be the charge on the sphere at t = t and Ro be the initial separation between centre of
the sphere and charge q. So at t = t, potential of sphere
Q q
V 0
4o R 4 o R o vt
qR
Q
R o vt
dQ Rqv
i
R o vt
2
dt
(A), (C)
32. (A), (B), (D)
CE
Initially, Q A Q B , when dielectric is inserted.
2
2CE 2CE CE CE
Q 'A Q ' B , Q =
3 3 2 6
2
CE CE
Work done by battery = E
6 6
2 2 2
Q' Q 7CE
U A U f U i A A
2C 2C 72
33. (A), (B), (C)
For isothermal process Q = W.
Curve 3 corresponds to isothermal process, and Curves 1 and 2 correspond to isobaric
processes.
For isobaric process
W = pV = RT (n = 1)

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i 2 W 2
Q = CpT = RT ( i = degrees of freedom)
2 Q i2
2 W 2
For curve 1, i=5 (diatomic gas) (given tan1 = 2/7)
i2 Q 7
2 W 2
For curve 2, i = 3 (monatomic gas) (given tan 2 = 2/5)
i2 Q 5
34. (A)
r r r r r
p m B, p m iA
r r
Since statement-2 is true. with deformation area reduces, so does the p m and .
(A)
35. (C)
Conceptual.
36. (D)
Ring


ma
mg
Using work energy theorem.
Wpeudo force + Wgravity = KEf KEi
mg
Lsin mgL 1 cos 0 (1)
3
3 1 cos sin
Solving we get, = 60o.
(D)
37. (D)
q 1 1 q r2 r1
V1 V2
4o r1 r2 4o r1r2
qr
V k say
4o r1 r1 r
Obviously r is not constant. So equipotential surfaces differing by K volt (say) are not
equi-spaced. So statement 1 is wrong but statement 2 is correct.
38. (D)
dy dy
tan 60o 3, v p v 20 3 v 3
dx dx
v = 20 cm/s
(D)
39. (D)
From graph, A = 4 10-2 m, = (5.5 - 1.5) = 4 10-2 m
K = 2/ = 50, = Kv = 50 (1/5) = 10

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Hence equation of wave is y = (4 10-2)sin(10t + 50x + )


At x = 0, y = 2 2 102 2 2 102 4 102 sin
1 3
sin , ,
2 4 4
As the particle is moving up at t = 0, x = 0, hence = /4
(D)
40. (C)
Conceptual.
41. (B)
r dB
E
2 dt
FE qE
r q L qB L
FE cos q Bo cos Bo o
2 2 2 4
F cos qBo L
a E
m m4
Hence velocity at end A
qB L qBo
vA 2 o L L
m4 2m
Time taken to reach at end A
2s 2 L 4m 2m
t 2
a qBo L qBo
42. (D)
qBo L
N Fm FE cos 45o qv A B
4
qBo 2m qBo L 9
qL Bo 2 qBo L
2m qBo 4 4

43. (A)
qBo
m L
mv 2m L
Radius of curvature =
qB 2m 4
q Bo 2
qBo
44. (C)
mv sin
R vsin 1.2 107 m / s (Charge of -particle = 3.2 10-19 C)
qB
2m PqB
P vcos v cos 9 10 6 m / s
qB 2m

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V vsin 2 v cos 2 1.5 10 7 m / s


45. (B)
m y v y m v v y 2.715 105 m / s
TE released during an -decay of the nucleus X is,
1 1
E KE y KE m y v 2y m v 2 4.7 MeV
2 2
46. (D)
E
Mass lost during -decay, m 0.005 U
931
mass of nucleus X,
m x m y m m 225.038 U
mass defect in nucleus X,

m d 92m p 225 92 m n m x U 1.895 U
m 931
BE per nucleon in nucleus X = d 7.84 MeV
225

CHEMISTRY
47. (A)
Tb i m K b
2.08 = i 1 0.52
i = 4 (so number of particles are four)
Hence complex will be [Fe(CN)6]3
EAN of Fe = 26 3 + 12 = 35
48. (D)
Oxidation number of M = (2/x)
Let y atoms be in +2
So
2 y 3 100 y 2
100 x
2y + 300 3y = 200/x
y + 300 = 200/x
300 (200/x) = y
3x 2
y 100
x
1 x
(100 y) = 100 300 + (200/x) = -200 + (200/x) = 200
x
100 y 1 x 3x 2 2 1 x
so 200 100
y x x 3x 2
49. (D)
(A) stability increases with size
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(B) stability increases with increase in ionic character


(C) solubility decreases with increase in size
(D) solubility increases due to less lattice energy with increase in size of cation.
50. (A)
Flourine forms H2F2
H 2 F2 OH HF2 (acidic salt)
51. (A)
OMe is e donating.
NO 2 is e withdrawing (having major role at ortho and para position as compared to
meta)
52. (C)
IV forms aromatic ion
III form antiaromatic ion
IIs cation has less strain than Is cation
53. (A), (B), (C), (D)
Theoretical
54. (A), (B), (C), (D)
Due to inert pair effect down the group stability of lower oxidation state increases and
stability of higher oxidation state decreases.
55. (B), (C), (D)
dU an 2
(A) For real gas i.e. internal energy is volume dependent also.
dV V 2
(B) Z > 1 Vreal > Videal so forces of repulsion are dominant.
(D) For ideal gas U = 0 but for real gas U 0 .
56. (A), (C), (D)
O
OD

Me CH 2 CHO

OD / D 2 O
CD
Me 2 C H CN / D2 O
Me CD2 C CN
H
57. (A)
For hydrogen low molecular density causes repulsion at all pressure.
58. (C)
SO3 is S3O 9
O O
S
O O
O O
S S
O
O O
59. (B)
Both statements are independently true.
60. (A)
Mg3C2 + H2O Mg(OH)2 + C3H4
CaC2 + H2O Ca(OH)2 + C2H2
Be2C + H2O Be(OH)2 + CH4

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61. (C)
Al2O3 + 3C + N2 2AlN + 3CO
62. (D)
Theoretical.
63. (B)
Cryolite is Na3AlF6
64. (C)
Half cell will be
2Ag s 2Cl aq 2AgCl s 2e
Hg 2Cl 2 s 2e 2Hg l 2Cl aq
Both are metal insoluble salt.
65. C
E ocell E oOxd E oRe d
0.0591
E oOxd E oAg/Ag log K sp AgCl s
1
0.0591
E oRe d E oHg 2 /Hg l log K sp Hg 2 Cl 2 s
2
2

0.0591 0.0591
E ocell E ooxd E oRe d log1010 log10 18
1 2
= 0.0591 (9) + 10 0.0591 = 0.0591

66. (A)
G nFE 2 96500 0.0455 8780 J / mol .

HINTS AND SOLUTION


PAPER - II

MATHEMATICS
1. (D)
sin x
2 n

f x lim n
3
n

cos x
2 n

4

If x n , then f(x) does not exist and so it is discontinuous.
6

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n
3 0
f 0 lim 0
4 1
f lim lim 1; n n
3
1
n n n
3 n
3 1 n
1
1 4
4 4 3
1
f lim n

2 n
3
0
4
2. (C)
Q RBS RAS 90o
and ASB ARB 90o

So equation of circle with RS as a diameter is same circle with AB as diameter.


Equation of required circle

x 1
1
x y 1 y 5 0
3
3x 3y 4x 18y 16 0
2 2

3. (A)
Equation of the required plane is
1(x - 1) + 2(y - 2) + 3(z - 3) = 0
x + 2y + 3z = 14
4. (B)
We can assume that, circumcentre of ABC is at
origin. If R is the circumradius,
BC = 2R sin A = R.
Also, if z1, z2, z3 are the complex number
representing A, B, C respectively, then
z1 + z2 + z3 represents H and M is
z 2 z3
. If z represents T, then
2
z z1 z 2 z 3 z 2 z 3
z z1
2 2
AT = 2|z1| = 2R = 2BC

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6. (C) B ( I A) ( I A) 1
B T ( I AT ) 1 ( I AT ) ( I A) 1 ( I A),
BB T ( I A) ( I A) 1 ( I A) 1 ( I A)
( I A) ( I A) 1 ( I A) 1 ( I A) I
(As ( I A).( I A) ( I A)( I A))
7. (B)
2 tan x
Q 1 tan 2 x
tan 2x
2k
2 tan
2k 2 1
n

1 tan
2

2 1 2k 1
n
tan
2n 1
It follows the product to
2 2
2n tan n 2n.tan n
2 1 2 1 2n
2
n 1
2
tan n tan 2 n
2 1 2 1
8. (C)
10999 = 2999 .5999
So the number of positive divisor of 10999 is
= (999 + 1)(999 + 1) = 10002 (1)
Similarly, the number of positive divisor of
10998 is = 9992 .
So the number of positive number which divide 10999 but not 10998 is equal to
= 10002 9992 = (1000 + 999)(1000 999) = 1999
9. (B)
(1 + x)n = Co C1 x C2 x ...... C n x
n n n 2 n n

On integrating,
1 x 1 n C x n C x 2 n C x 3 ......
n 1

o 1 2
n 1 2 3
Multiplying with x and differentiating,
1 x x n 1 1 x 1 2. n C x 3. n C x 2 4. n C x 3 ......
n 1 n

n 1 o 1
2
2
3
3 n 4 5 2n n 3 1
Put x = 1 2 Co C1 n C 2 n C3 ....... =
n

2 3 4 n 1
10. (C)
Period of sin sin x is 2 and that of tan tan x is . Hence required period is 2.
1 1

12 x 6
2tanx + x = tan x =
5 2 5
From the graph only two solutions are possible.

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11. (D)
Statement-1 is false as consider the function f x max 0, x which is equivalent to
3

0; x0
f x 3
x ; x0
Here, f(x) is continuous and differentiable at x = 0.
However, statement-2 is obviously true.
12. (A)
R1: Point P(x, y) is nearer to (1, 0) than to x 1.
x 1
2
y 2 | x 1|
y 2 4x
point P lies inside parabola y 2 4x .
R2: Point P(x, y) is nearer to (0, 0) than to (8, 0).
| x | | x 8 | x < 4.
Point P is towards left side of line x = 4.
The area of common region of R1 and R2 in first quadrant is the area bounded by x = 4 and

y2 = 4x, and x 0 , y 0 .

This area is equal to the area bounded by x 2 y and y = 4. Now the area bounded by
x2 y
4
x 2
4
x 3 1 16 32
and y = 4 is A 4 dx 16 0
16 64 16
0
4 12 12 3 3
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13. (A)
Image of (4, 3) in the line x + y = 3
is
(0, 1).
Now points (0, 1), (1, 2) and (6, y)
are collinear.
y = 17.

x
1
14-16. f x 1
x
1
f(x) is defined if 1 0 x , 1 0,
x
x

1 1 x x 1

Now, f ' x 1 ln 1 2
x x 1 1 x
x
x
1 1 1
1 ln 1
x x 1 x
1 1
Let g(x) = ln 1
x 1 x
1 1 1 1
g ' x 2
1 x x 1 2
x x 1
2
(1)
1
x
For x > 0, g ' x 0
g(x) is monotonically decreasing for x 0, .
g(x) > lim g x g(x) > 0
x

And since g(x) > 0 f ' x 0


Now, for x , 1 , g ' x 0
g(x) is monotonically increasing for x , 1 .
g x xlim

g x g x 0 f ' x 0
Hence, f(x) is monotonically increasing in its domain.
x
1
Also, lim 1 e
x
x
x x
1 1
lim 1 1 and lim 1
x 0 x x 1 x
Ranger of f(x) is 1, ~ e
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/2

17-19. f x sin x cos t f t dt sin x


0
/2

f x sin x cos t f t dt sin x


0
/2

f x A sin x sin x f x A 1 sin x where A cos tf t dt


0
/2
A 1 /2
A 1
A cos t A 1 sin tdt sin 2tdt
0
2 0
2
2
A f x sin x
2 2
2
sin x 2 sin x 2
2
Q | 2 | 1 1 3
/2 /2
2
0 f x dx 3 0 2 sin xdx 3
2 4
3
2 3
20. (A) (p) ; (B) (r) ; (C) (q), (s), (t) ; (D) (p), (r), (s).
(A) Lines must be non-parallel and coplanar

b d 0 and [a c , b , d ] 0

(B) Lines must be coincident



b d 0 and ( a c ) b 0
(C) Either lines are skew or parallel

[a c , b , d ] 0 or (a c ) b 0 and bd 0,
(and if skew then lies in set of parallel planes)
(D) Either intersecting or parallel

[ a c , b , d ] 0, b d 0 or b d 0
21. (A) (s), (B) (r), (C) (q), (D) (p)

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

x3 x5
x ....... x
(A) sin x x 3! 5!
f 0 lim lim 2
0
x 0 x sin x x 0 x
1
1 1 1 1 dx 1
(B) lim ...... ln 3
n n
n2 n4 n 2n 0
1 2x 2
(C) = 0 k 1
(D) f x max 6

22. (A) (q), (B) (s), (C) (p), (D) (r)


(A) xy = c2 = ve (Q c is purely imaginary number)
If x is positive, then y must be negative real.
1 3

2
(B) 2b = a + c
Now, (a + c - b)s = kb2
b a b c 3b 2 3
kb 2 kb 2 k
2 2 2
3 0 4 0 2 3
2 2
(C) r


2
7 4 cos 0
2
(D) distance = 2 30 4sin 0 185 56 cos 16 30 sin


2
maximum distance = 185 56
2
16 30 17

PHYSICS
23. (D)
Charge is proportional to lines of force.
24. (C)
Event 1 Event 2
v v1 2v 2 v
2v 4 2v1 4v 2
2
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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

v v 2 v1 v
v v 2 v1
2 2
v2 v 5
3 v2 v
2 4 6
Fdt 2 v v
3 3 5 1 4
Fdt 4 v v v
6 2 3
Impulse imparted is same in both events so area in F-t should be same. So (C) may be a
possible solution.
25. (B)
When displaced by (dx) towards right, then
K
dx cos

dx
Elongation of left spring = dx cos
(kdxcos)cos kdx

Restoring force = Kdx Kdx cos K 1 cos dx


2 2

K
Acceleration = 1 cos dx
2

m
K
= 1 cos 2 2 rad / s
m
26. (C)
Fmax for no sliding between cone and plank is
1
(m + M)g = 2 10 = 5 N
4
For toppling of cone
N
ma
H/4
r fr
mg

T T
mF H r
i.e. mgr F 4 M m g F4
Mm 4 H
Toppling will occur before sliding.
Fmax for equilibrium = 4 N
27. (D)
P 0.99 50 kV 20 mA
Average rate of rise of temperature 2o C / sec
t ms 1kg 495 J kg C
1o 1

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

hc 12400
The minimum wavelength of the X-rays emitted min 0.248
eV 50 103
28. (D)
D 2 D dy 2 2
and y 2 v
d d dt d
29. (A)
2 1
1 2
v 2R R
v
After reflection from the spherical surface the ray become parallel to optic axis. Hence
after reflection from silvered surface it will retrace its initial path and image coincides
with object.
30. (C)
R 17R
P V 2 so PV 2 = constant, C C V
1 x 6
17R 17 17
Heat supplied Q = nCT = n 4To To nRTo Po Vo
6 2 2
31. (D)
V = i(G + H) I = V/(G + H) 50 10-6 = 50/(100 + R) R = 106
(A) is correct.
i G
S G 0.5A (B) is correct.
i ig
(C) is also correct, the incorrect option is (D).
32. (C)
Energy of individual m is not maximum but the total energy associated with m is
maximum.
33. (A)
34. (D)
Only those images appear in the photograph which are focused on to the film by the lens.
The lens does not form an image of the scratches on itself, so they do not appear in the
photograph. So statement - 1 is wrong.
However, they spoil the sharpness of the photograph by scattering some of the light
passing through the lens. So statement - 2 is correct.
35. (D)
In resonance condition when the energy across the capacitor is maximum, energy stored in
the inductor is zero, vice versa is also true. Hence statement-1 is false.
36. (A)
Conceptual.
37. (C)

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

Impulse momentum principle kmgt = m(vo r) kgt = vo r (1)


2 2 2
Angular impulse momentum principle kmgrt = mr k gt r (2)
5 5
2v o 2v o
From equation (1) and (2), t ,v due East
7 k g 7
38. (D)
In ground frame: work done by friction = change in KE
1 1 2
WG Mv 2 Mr 2 2 0 (3)
2 2 5
2v o 2v 1
From equation (1) and (2), t , v o , substituting in (3), we get WG Mv o2
7 k g 7 7
In Belt frame: Work done by friction = change in KE:
1 2 1 1
WB Mr 2 Mr 2 2 Mv 2o Mv 2o
2 5 2 7
39. (C)
a 3i 4j a z k
The acceleration of the block in the x-y plane for the block not to slip in that plane is
32 42 5m / s 2
Friction required = 5 1 = 0.9 1 [g + az]
5 5 10
10 a z az 10 4.44 m / s 2
0.9 9
40. (A)
N z m g a z 15 N
fs max N z 0.6 1`5 9 N ,
which is greater than force required to provide the same
acceleration as that of the box along the x-y plane.
Friction = 1 5 = 5 N
R N 2z friction 152 52 250
2

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41. (C) z
With respect to the box y
Max = 3 N, may = 4 N
Net pseudo force in x-y plane =
32 42 5 N
Friction will try to oppose this force, but
(fs)max = 0.2 1 (10 + 5) = 3 N max
mg
In X-Y plane may ma
z

Fnet = 5 3 = 2 N x
g =10m/s2
This force will be acting at an angle 53o in
anticlockwise direction from the (-)ve x-axis. F.B.D. of the block
r

a block w.r.t.box 2cos53 i 2sin 53 j 1.2i 1.6j
o o

42. (A) (p), (q), (r), (t), (B) (p), (q), (r), (t), (C) (p), (s), (D) (p), (s)
Conceptual
43. (A) (q), (B) (p), (C) (r), (D) (p)
Use concept of field of view.
44. (A) (q), (B) (p), (C) (r), (D) (p)
(A) In case of resistance (r) acceleration of rod, mg sin iBl ma
Bl
a g sin i
m
g sin
Blv B2l 2 v
Also i a g sin v when a = 0; B2l 2 = constant.
R mR
mR
dq dv
(B) In case of capacitance C: q C Blv i BCl BlC a
dt dt
g sin
mg sin BlCa Bl ma a
Again from Newton's law: B2l 2 C = constant
1
m
di dx
(C) In case of inductance only (L): L Bl Li = Blx , i (Bl/L)x
dt dt
Again mg sin - ilB = ma a = (g sin )
B l
2 2
B l2 2
x a x g sin
mL mL
equation of SHM.
(D) As induced emf in the rod is equal to external cell, so the current in the circuit is zero
and hence it acceleration with g sin .

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

CHEMISTRY
45. (A) I is preferentially oxidized to I2 farming a violet color layer.
1
46. (A) Moles of complex =
269.5
1
Moles of Cl formed = 2 = 0.0074
269.5
So, moles of HCl in 1 liter solution = 0.0074
If V is volume in litre of Ca(OH)2 then V 0.1 2 = 0.0074
V=0.037 Litre.
47. (A) NH 4Cl NH 4 Cl 130 ----------- (1)
NaOH Na HO 220 ----------- (2)
NaCl Na Cl 100 ----------- (3)
[(1) + (2)] [(3)]
NH 4 HO 250 NH 4OH
10 1
' 'of NH 4OH
250 25
1 1
HO C 4 104
100 25
pH 10 2 log 2 10.6
48. (C) (A) In NOCl it is NO+ hence B.O. is 3
(B) NCl3 hydrolysis to give NH3.
(C) In PF3Cl2 two chlorine & one Fluorine are equatorial & two fluorine are axial
(D)
O O

S S O
O
OH OH
49. (C) Intermediate formed clearing nucleophilic substitution is more stable because of
having cyclopentadienyl anion which is aromatic
F
OMe

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11


50. (A) CRT so, C= 4 104 M
RT
w1000
So, Mol . wt= 5 104 gm/mole
molarity volume
Mol wt of glucose = 180, on forming starch 18 gm of H2O is lost so average wt = 162
5 104
So, 310 units.
162
51. (B) OMe ( I) (+ R), Dominant effects (+R)
CH3 (+ I) (Hyper congregation)
- Cl, NO2, ( I) strong.
52. (D) HCl is halides
53. (B) Only B is unsymmetrical
54. (B) In water extent of Hydrogen bonding is more Hence boiling point is
more but strength of H-bonding is weak in H2O then HF.
R
55. (B) Cp Cv = M=Molar mass
M
R
0.125 0.075 = M=40
M
56. (B) Energy increases as the orbit numbers increases
57. (B) conceptual
58. (B) Meq of H3PO4 = 300 0.1 = 30
Meq of NaOH = 50 0.1 = 5
H3 PO4 + NaOH = NaH2 PO4 + H2O
30 5 0 0
25 0 5 5
Solution is buffer
5
pH = P ka1 + log 3 + log 1/5
25
2.3010
2
59. (A) At point C a buffer of H2 PO 4 & HPO4 exists.
60. (A) At Point D only Amphiprotic salt Na2HPO4 remains.
P ka2 P ka3 8 13
So, pH 10.5
2 2
61. (B)

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

Et Et
O O O
O
EtO H OMe or H C OEt
(-)

Et
H Et
O
O
C OMe

-O C H
O

62. (A)
Et Et Et
O && O O
R3 N Me
() Me
H H O
O O CHO O

63. (D) Loss of H2O is by E-1 CB mechanism

O OH
LiAlH 4 /H 2 O
64. (A) Br
Mg/Ether
MgBr
O O
MeO MeO

OMgBr OH
(B) MgBr
O
Me

Me
Mg/ether
(C) Br
MgBr LiAlH4
O O
MeO MeO O OH

Mg
(D) Br
ether MgBr
O O
Me Me
HO

65. (A) (r)


(B) (p), (s)

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This Key & Hints paper contains 28 Pages NFT_6 PAPER I & II DT : 16-01-11

(C) (r)
(D) (q), (s)
66. (A) (p), (s)
(B) (p)
(C) (q), (r)

(D) (q)

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