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CODE : ORANGE
28721/QB/
VIJ-
ONCS-C /
IITJEE /
22-1-
2011 /
IITJEE
Time :3:00
GRAND TEST-12 Max Marks :243
PAPER II
ID.NO :
MATHEMATICS
1) B 2) C 3) C 4) C 5) D 6) B
7) A 8) A 9) C 10) A 11) C 12) D
13) A 14) A 15) C 16) C 17) A 18) D
19) C 20) (A) (q) 21) (A) (s) 22) (A) (s)
(B) (p) (B) (q) (B) (s)
(C) (s) (C) (p) (C) (s)
(D) (r) (D) (q) (D) (q)
PHYSICS
23) B 24) A 25) D 26) D 27) C 28) C
29) D 30) C 31) B 32) D 33) A 34) D
35) D 36) A 37) C 38) A 39) B 40) A
41) C 42) A-R 43) A-P,Q,S 44) A-P,R,S
B-R B-P,S B-P,R,S
C-P C-R,S C-R
D-Q D-Q,S D-R
CHEMISTRY
45) A 46) A 47) B 48) C 49) C 50) C
51) C 52) C 53) A 54) D 55) C 56) C
57) B 58) C 59) D 60) D 61) D 62) C
63) D 64) A p, q, s 65) (A r) 66) (A p, s)
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B p, q, r (B s) (C (B q) (C
C p, q, r p) q)
D p, q, r (D q) (D q, r)
HINTS
MATHEMATICS
1)
Area of triangle
but
Area
2)
tossing a coin, die, score 3
3)
x intercept is
Let
4) Let be the number of one rupee coins then the number of 50 paise coins may be even
or odd. If number of 50 paise coins is then number of 25 paise coins must be a
multiple of 4.
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where
Number of ways
If number of 50 paise coins is then 25 paise coins must be of the form
Number of ways
Number of selections
5)
Number of hyperbolas
6)
We have
But
7)
8)
where
9) Image of one focus w.r.t the tangent lies on the line by solving the tangent and
10)
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11) Conceptual
12) Conceptual
13) Conceptual
P)
14) The scores of can be reached in the following two mutually exclusive events
i) by throwing head when the score is
ii) by throwing tail when score is
15)
But and a score of 2 can be obtained by throwing a tail at a single toss or a head at
the first toss as well as second toss.
16)
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P)
17)
18)
19)
Area
20) Conceptual
21) Conceptual
22) Conceptual
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PHYSICS
23)
Force required to move m2 = stretch in the spring (1)
25) conceptual
26)
I = 3A
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After distributing current in different branches we get current through CD
29)
and
30)
For refraction at 1st surface .. (1)
(1)
C.M.E at P and Q, we have
(2)
From (1) and (2) we have
r = 3.323 R
h = r R = 2.323 R
32) Conceptual
33) Conceptual
34) Conceptual
35) Conceptual
P)
36) Once the switch is closed, the capacitor is charged through resistance R 1 by the batterys
emf. Time constant is C.
37)
Using
= 10.4 V
38) At any moment in the circuit
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= 1.6 V
P)
39)
40)
41)
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42)
Given
43) Conceptual
44) Solve using proper steps
CHEMISTRY
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45) Conceptual
46) Conceptual
47) Conceptual
48) Conceptual
49) Conceptual
50)
IE1 of N2 is larger than that of O2 because, as per MOT, HOMO of N2 is a BMO i.e
while that of O2 is an ABMO i.e. t is easier to remove an electron from an
ABMO than to remove and electron from a BMO. Again, as per MOT an electron is
always
removed from the ABMO while it is added to the LUMO. However, if the HOMO is
partly
filled, then the added electron goes to HOMO instead of LUMO. Both in the case of O 2
and
N2, the added electron goes to ABMO and hence the addition lowers the bond order of O2
from 2 to 1.5 and of N2 from 3 to 2.5. In both the cases, addition of an electron lowers the
stability of the respective species. But in case O2, the addition of an electron leads to
lowering of the spin while in case of N2 the addition raises the spin. Hence, addition of an
electron to N2 is more energy consuming than that needed for O2 . So, EA of O2 is higher
than N2. EA is conventionally measured in terms of energy released.
Electronegativity of an atom is directly proportional to its bond multiplicity. Because, the
higher the bond multiplicity smaller is the size and hence more is the electronegativity.
This is why EN of Carbon atom in different hybrid state is
Both in N2 and CO, the bond order is 3. Still then the bond energy of the two species
differs
because radii of Rather, the correct order of these radii is
(Radii along period always decreases) Therefore, CO is slightly less stable than N2.
51) Conc. of
Ksp of
52) 2
[ Cl ]
Cl2 2Cl (fast) Kc1 =
Cl
2
[ COCl ]
Cl CO COCl (fast) Kc 2 =
[ Cl ][ CO ]
Hence,
k 1K c2 K c1 k another constant
53) T = K molality i
f f
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59)
60)
P)
61) Conceptual
62) Conceptual
63) Conceptual
64) All halogens react with NaOH. Fluorine reacts with NaOH in a different way. F2 with
conc. NaOH gives off O2 while with dil. NaOH it gives off OF2 gas. Similarly, with hot
and conc. NaOH, Cl2, Br2 and I2 give NaXO3 & NaX and with cold and dil. NaOH they
give NaX and NaOX. Fluorine does not form due to absence of vacant d-orbital,
other halogens do. F2 gas is pale yellow, Cl2 is greenish, Br2 is reddish brown and I2 is
dark violet in colour
65) Conceptual
66) A p, s
B p, q
Cq
D q, r
Crystals class Axial distances Angles
Cubic
Tetragonal
Orthorhombic
Hexagonal
Trigonal and
rhombohedral a = b = c
Monoclinic
Triclinic
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