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CONTROL
OVERVIEW
Thermodynamics of Corrosion
Kinetics of electrodes
THERMODYNAMICS OF
CORROSION
NERNSTIAN CELL POTENTIALS
Spontaneous chemical
reactions release energy
All reactions can be
broken into two halves
Oxidation reactions which
release electrons.
Reduction Reactions which
Consume electrons
Instead of allowing the
two reactions to
happen in the same
place, we make a cell.
Electrons are forced
around a circuit.
STANDARD REDUCTION POTENTIALS
Horizontal: pH independent.
Ver tical: non redox reactions.
Sloping: dependant on E and pH.
Multiple: Depending on [metal ion].
Single: independent of [metal ion ].
REGIONS WHICH CAN BE IDENTIFIED
Immunity:
The metal exists as the solid metal, corrosion is impossible
Corrosion:
The metal exists as a soluble ion corrosion rates are expected to be
high.
Passivity:
The metal exists as a solid compound (usually an insoluble oxide).
The oxide acts as a barrier to the environment, preventing corrosion
of the underlying metal.
General Appearance of Eh pH Diagrams
Metal
0 7 14
pH
Iron Eh pH Diagram
1.5
Fe+3
1.0
0.769
Fe2O3
0.5
1.38
6.77
Fe+2
Eh
0.0
-0.185
-0.5
-0.586
Fe3O4 -0.613
Fe 8.47 -0.951
-1.0
-1.5
0 2 4 6 8 10 12 14
pH
Iron Eh pH Diagram
1.5
1.229
O2/H2O
0.5
0.402
Fe+2 Fe2O3
Eh
0.0
H+/H2
Deaerated Solution
-0.5 Fe3O4
-0.827
Fe
-1.0
-1.5
0 2 4 6 8 10 12 14
pH
NICKEL
ALUMINUM
TITANIUM
ZIRCONIUM
TANTALUM
ADVANTAGES/ DISADVANTAGES
Rate = K x W
AxT xD
Where Rate Units K
K= constant mpy 3.45x10 6
W= weight loss (g) ipy 3.45x10 3
A = Area (cm 2 ) mmyr -1 8.74x10 4
T = Time (hours)
D = Density (g/cm 3 )
PENETRATION RATE FROM CURRENT
DENSIT Y
Rate = k x Eqwt x i
d
Where: Rate Units k
k = constant mpy 0.129
Eqwt = equivalent weight mm yr -1 0.00327
i = corrosion current density mm yr -1 3.27
(mAcm -2 )
d = density (g/cm 3 )
PENETRATION RATE LEVELS