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So for an acid-base equilibrium, such as the one shown, decreasing the pH amounts
to increasing the H+ concentration, which would cause the equilibrium to shift to the
left.
In each square in the table to the right, think about whether imposing the change at
the left will increase the concentration of the species at the top or if imposing the
change will decrease the concentration.
For example, in the first box you should think about what will happen to the concentration of HA
when adding HCl. Remember Le Chateliers principle. The equilibrium will shift in the direction
that counteracts the change imposed. For each change imposed, figure out which direction the
equilibrium must shift in order to counteract it, and then decide what effect shifting in that
direction will have on the concentrations of the other species in the reaction.
Let's walk through one together. Adding HA will increase the concentration of a reactant. The
equilibrium will therefore shift to the right to reduce it. This will cause the concentrations of
H3O+ and A- to increase. Since the H3O+ ion concentration increases, the pH decreases. Although
the concentration of HA will also go down when the equilibrium shifts, if will not decrease all
the way back to what it was before the additional HA was introduced. So, adding HA does, in
fact, increase the concentration of HA, but, because of the resulting equilibrium shift, it does not
increase by as much as was added.
decrease (equilibrium is
Add decrease (reacts with increase (gets
shifting right to make up for increase
NaOH the OH-) more basic)
less H3O+)
decrease (equilbrium is
Remove
shifting right to make up for increase decrease decrease
A-
less A-)
Buffers
A buffer solution makes use of Le Chateliers principle to prevent its pH from
changing very much when acid or base is added
The equation on your screen describes the behavior of buffer systems in general.
The value of the acid dissociation constant, K a, depends on what acid HA represents.
This equation also correctly predicts Le
Chateliers Principle. Suppose, for
example, that the system is at equilibrium (the equation is satisfied) and then some
H+ is added. With the extra H+ ions, the value of [H+][A-]/[HA] is too high. To return it
to its correct value, [H+] and [A-] must decrease and [HA] must increase, that is, the
equilibrium must shift to the left, just as Le Chateliers principle predicts.
To maximize the buffering capacity against both added acid and base, the
concentrations of A- and HA must both be high and, in fact, approximately equal.