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CH-12andCH-13RevisionAssignment:
1. Arrangethefollowinginincreasingorderoftheirstability:
-
CH2CH2-CH2CF3, -
CH2CH2-CF2CH3,
-
CH2CF2-CH2CH3
2. Arrangethefollowinginincreasingorderoftheiracidstrength:
Cl3CCOOH,Cl2CHCOOH,ClCH2COOH
3. Whatishomolyticandheterolyticfission?Whataretherespectiveproductsformed
inthese?
4. WriteashortnoteonprocessofColumnChromatography
5. WriteresonancestructuresofCH2 =CH CHO.Indicaterelativestabilityofthe
contributingstructure.
6. (a)Whateffectdoesbranchingofanalkanechainhasonitsboilingpoint?
7. GiveIUPACNamesforthefollowing:
(a)CH3CH=CHCH=CHCCCH3
(b)
(c)
8. GiveFunctionalgroupisomerofthefollowing: and
9. Whatarethedifferenttypesofelectromericeffect?
10. (a)WhatisWurtzreaction.Explainwithanexample.Whataretheproductsformedwith
ethylbromideandmethylbromide.Whatisitsdisadvantage.
11. Whatarethetwomethodsinvolvedtopreparealkanesfrom carboxylicacids.Explain
withmechanism andexampleforeach.
12. (a)GiveresonatingstructuresofC6H5NH2molecule.
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13. WhichofthegivenNumberingforthemoleculeiscorrect?WritethecorrectIUPAC.
14. Arrangethefollowinginincreasingorderoftheirstability:
+
CH2CH2-CH2CF3, +
CH2CH2-CF2CH3,
+
CH2CF2-CH2CH3
15. Arrangethefollowinginincreasingorderoftheiracidstrength:
CH3CHBrCH2COOH,(CH3)2CHCOOH,CH3CH2CHBrCOOH,CH3CH2CH2COOH
16. Howdoelectrophilesandnucleophilesdifferfrom eachother?Give2featuresofeach
withanexample.
17.
ArrangethefollowinginIncreasingorderoftheirBoilingpoint.GiveReasontoo.npentane,
isopentaneandneopentane
AnswerKeyHint
1. Ans:
-
CH2CH2-CH2CF3<
-
CH2CH2-CF2CH3<
-
CH2CF2-CH2CH3(EWGisnearest)
2. Ans:Cl3CCOOH(morenoofEWG)>Cl2CHCOOH>ClCH2COOH
3. Ans:homolytic:Thebreakingofabondinacompoundinwhichthetwoelectronsin
acleavedcovalentbondaredividedequally.thefragmentsareunchargedfreeradicals.
Forexample,Cl2 Cl+Cl.
heterolytic:thebondbreaksinsuchafashionthattheoriginally-sharedpairof
electronsremainwithoneofthefragments.thedissociationofamoleculegivetwo
ionswithoppositecharges.
4. Ans:Columnchromatographyinvolvesseparationofamixtureoveracolumn
ofadsorbent(stationaryphase)packedinaglasstube.Thecolumnisfittedwitha
stopcockatitslowerend.Themixtureadsorbedonadsorbentisplacedonthetopof
theadsorbentcolumnpackedinaglasstube.Anappropriateeluantwhichisaliquidor
amixtureofliquidsisallowedtoflowdownthecolumnslowly.Dependinguponthe
degreetowhichthecompoundsareadsorbed,completeseparationtakesplace.The
mostreadilyadsorbedsubstancesareretainednearthetopandotherscomedownto
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variousdistancesinthecolumn.
5.
6. Ans:
Ethylcarbocation: Propene:
7. (a)Ans:Branchingtendstolowertheboilingpointsincethebranchingdecreases
thesurfacearea.Withdecreaseinsurfacearea,VanderWaalsforcesofattraction
decreases,henceB.ptdecreases.
(b)Ans:ButanoicAcid
8. Ans:CH3CH2CH2CH2CHOandCH3CH2OH
9. Ans:Therearetwodistincttypesofelectromericeffect.
(i)PositiveElectromericEffect(+Eeffect)Inthiseffecttheelectronsofthe
multiplebondaretransferredtothatatom towhichthereagentgetsattached.
NegativeElectromericEffect(Eeffect)Inthiseffectthe-electronsofthemultiple
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bondaretransferredtothatatom towhichtheattackingreagentdoesnotgetattached.
10. (a)Ans:Alkylhalidesontreatmentwithsodium metalindryethereal(freefrom
moisture)solutiongivehigheralkanes.ThisreactionisknownasWurtzreaction.
Itcanbeusedforthepreparationofhigheralkanescontainingevennumberofcarbon
atomsonly.
Productsformedareethane,butaneandpropane.
(b)Ans:F2>Cl2>Br2>I2.
(c)Ans:3>2>1
11. Ans:
Pg371,NCERT
12. Massofthesubstance=0.3780gMassofAgCl=0.5740g
MolarmassofAgCl=143.5g143.5gofAgClcontains35.5gofCl
%ofCl=(35.5/143.5)x(MassofAgClformed/Massoforgcmpd)x100
=(35.5/143.5)x(0.5740/0.3780)x 100=37.56%
13. CorrectAnswer:2,3dimethyl cyclopentene.
14.
+
CH2CH2-CH2CF3>
+
CH2CH2- CF2CH3>
+
CH2CF2-CH2
CH3
15. CH3CHBrCH2COOH>CH3CH2CHBrCOOH>CH3CH2CH2COOH>(CH3)2CHCOOH
16. Electrophilesaree-deficient/e-seeking.Theyare+velychargedorneutralwithvacant
orbital.Nucleophilesaree-rich/+vecentre-seeking.Theyare-velychargedorneutral
withlonepairofe-s.
17. (a)n-pentane>isopentane>neopentane