annual 45000 ton/year AA 72

day 330 day ET 46

hour 24 hour EA 100
capacity 5681.81818 kg/hour W 18

product purity mass mol

C3H4O2 0.150% 8.52272727 0.11837121 5681.818182
C2H5OH 0.020% 1.13636364 0.02470356
C5H8O2 99.83% 5672.15909 56.7215909

C3H4O2 + C2H5OH C5H8O2 + H2O X 98%

M 57.8791744 63.6670918 0 0 ratio 1.1
R 56.7215909 56.7215909 56.7215909 56.7215909
S 1.15758349 6.94550093 56.7215909 56.7215909
TRIAL
AA Tank purity kmol mass (kg) AA Tank
C3H4O2 99.70% 57.8791744 4167.30056 C3H4O2
H2O 0.30% 0.69664001 12.5395202 H2O

ET Tank purity kmol mass (kg) ET Tank

C2H5OH 96.30% 63.6670918 2928.68622 C2H5OH
H2O 3.70% 6.25137823 112.524808 H2O

C3H4O2 +
M 58.49709706
R 57.32715511
S 1.169941941

Reactor
C3H4O2
C2H5OH
C5H8O2
H2O

comp
C3H4O2
C2H5OH
C5H8O2
H2O

Decanter
 component
C3H4O2
C2H5OH
C5H8O2
H2O

comp
C3H4O2
C2H5OH
C5H8O2

P
T
comp
C3H4O2
C2H5OH
C5H8O2

mol ET D
ln (Di/Bi)
ln (i)

mol EA D

comp
C3H4O2
C2H5OH
C5H8O2

y=ax+b
(1) 5,293305 = 0,771638 a
(2) -8,844532 = 0 a + b
b
a

AA
ln (Di/Bi)
(Di/Bi)
(1) Di = 4,78E-16 x Bi
(2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,76
mol AA D

Colomn 1
component
C3H4O2
C2H5OH
C5H8O2

comp
C3H4O2
C2H5OH
C5H8O2

P
T
comp
C3H4O2
C2H5OH
C5H8O2

mol EA D
ln (Di/Bi)
ln (i)

mol AA D

comp
C3H4O2
C2H5OH
C5H8O2

y=ax+b
(1) 5,293305 = 1,422524 a
(2) 0,051017 = 0 a + b
b
a
 ET
ln (Di/Bi)
(Di/Bi)
(1) Di = 3524,637 x Bi
(2) Di + Bi = 0,017616
3524,637Bi + Bi = 0,01
mol ET D

Colomn 2
C3H4O2
C2H5OH
C5H8O2
mass (kg) purity kmol
4211.79099 99.70% 58.4970971 2959.953111
12.6733931 0.30% 0.7040774

mass (kg) purity kmol

2959.95311 96.30% 64.3468068
113.726132 3.70% 6.31811844

C2H5OH C5H8O2 + H2O X 98%

64.3468068 0 7.02219584 ratio 1.1
57.3271551 57.32715511 57.3271551
7.01965165 57.32715511 64.349351

input output
mol mass mol mass
58.4970971 4211.790988 1.16994194 84.23581976
64.3468068 2959.953111 7.01965165 322.9039757
0 0 57.3271551 5732.715511
7.02219584 126.3995251 64.349351 1158.288317
129.8661 7298.143624 129.8661 7298.143624

ASPEN PLUS DATABANK

0.02498111
0.13760505
0.05250388
1

input light key output heavy key output

 mol mass mol mass mol mass
1.16994194 84.23581976 0.76806244 55.30049591 0.401879498 28.93532385
7.01965165 322.9039757 3.55473159 163.517653 3.464920059 159.3863227
57.3271551 5732.715511 56.7190088 5671.900885 0.608146265 60.81462647
64.349351 1158.288317 0 0 64.34935095 1158.288317
129.8661 7298.143624 61.0418029 5890.719034 68.82429678 1407.42459
129.8661 7298.143624 129.8661 7298.143624

vpa vpb vpc vpd vpe YAWS

23.0607 -3134.7 -4.8813 0.0004369 -4.9161E-013
23.8442 -2864.2 -5.0474 3.7448E-011 2.7361E-007
55.0109 -3590.4 -17.694 0.008051 -4.8864E-013

1 atm light key C2H5OH 99.15%

370.894365 K heavy key C5H8O2 99.15%
xi Puap (atm) K = Puap/P yi = Ki xi i = Ki / K
0.01258256 0.223314177 0.22331418 0.002809865 0.236296572
0.05823438 2.04445167 2.04445167 0.119057377 2.163306101
0.92918305 0.945058893 0.94505889 0.878132709 1
0.999999951
3.52451637 mol ET B 0.03021522
4.75915278
0.77163765

0.013899 mol EA B 56.7051098

ln (Di/Bi) -8.3138027
ln (i) 0

ln(D/B) [y] ln () [x]

-1.4426676
4.75915278 0.771637654
-8.3138027 0

305 = 0,771638 a + b
4532 = 0 a + b
-8.3138027
16.9418319

-32.755235
5.951E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.571E-015 mol AA B 0.76806244

input distillate output bottom output

mol mass mol mass mol mass
0.76806244 55.30049591 4.571E-015 3.2909E-013 0.768062443 55.30049591
3.55473159 163.517653 3.52451637 162.127753 0.030215218 1.389900051
56.7190088 5671.900885 0.013899 1.389900051 56.70510985 5670.510985
61.0418029 5890.719034 3.53841537 163.517653 57.50338751 5727.201381
61.0418029 5890.719034 61.0418029 5890.719034

vpa vpb vpc vpd vpe YAWS

23.0607 -3134.7 -4.8813 0.0004369 -4.9161E-013
23.8442 -2864.2 -5.0474 3.7448E-011 2.7361E-007
55.0109 -3590.4 -17.694 0.008051 -4.8864E-013

1 atm light key C5H8O2 99.85%

373.045008 K heavy key C3H4O2 99.85%
xi Puap (atm) K = Puap/P yi = Ki xi i = Ki / K
0.01335682 0.243401975 0.24340197 0.003251077 1
0.00052545 2.20222214 2.20222214 0.00115716 9.047675737
0.98611773 1.009607409 1.00960741 0.995591765 4.147901475
1.000000002
56.6200522 mol EA B 0.08505766
6.50078904
1.42260254

0.11813565 mol AA B 0.6499268

ln (Di/Bi) -1.7050262
ln (i) 0

ln(D/B) [y] ln () [x]

-1.7050262 0
2.2025079
6.50078904 1.422602538

305 = 1,422524 a + b
017 = 0 a + b
-1.7050262
5.76817141
 10.9994169
59839.2366
3524,637 x Bi
Bi = 0,017616
637Bi + Bi = 0,017616
0.03021471 mol ET B 5.049E-007

input distillate output bottom output

mol mass mol mass mol mass
0.76806244 55.30049591 0.11813565 8.505766477 0.649926798 46.79472943
0.03021522 1.389900051 0.03021471 1.389876824 5.0493E-007 2.3227E-005
56.7051098 5670.510985 56.6200522 5662.005218 0.085057665 8.505766477
57.5033875 5727.201381 56.7684025 5671.900862 0.734984967 55.30051914
57.5033875 5727.201381 57.5033875 5727.201381
5662.005218
163 & 167
163 & 167
 R HKD LKD DC1D
C3H4O2 1.1542089 2.0559058 0.9387733 2.01E-013
C2H5OH 4.4244673 11.324679 2.7758522 99.15
C5H8O2 78.550325 4.3209865 96.285375 0.85
H2O 15.870999 82.298428 0 0
100 100 100 100
DC1B DC2D DC2B
0.965576 0.150 84.61897
0.024268 0.025 4.200E-005
99.01016 99.826 15.380988
0 0 0
100 100 100
 component MW
C3H4O2 72
C2H5OH 46
C5H8O2 100
H2O 18

TT-01
Ethanol Storage Tank (TT-01)

ET ET1

component mass (kg) purity mol (kmol)

C2H5OH 2965.129 96.30% 64.459317
H2O 113.9250 3.70% 6.3291657

Acrylic Acid Storage

TT-02 Tank (TT-02)
reaction
C3H4O2 +
AA AA1 M 58.59938
R 57.42739
component mass (kg) purity mol (kmol) S 1.171988
C3H4O2 4219.155 99.70% 58.599379
H2O 12.69555 0.30% 0.7053085

R-01 input output

from TT-02 from TT-01 to FL-01
component mol mass (kg) mol mass (kg) mol
C3H4O2 58.59938 4219.1553 0 0 1.171988
C2H5OH 0 0 64.459317 2965.1286 7.031925
C5H8O2 0 0 0 0 57.42739
H2O 0.705308 12.695553 6.3291657 113.92498 64.46187
total 59.30469 4231.8508 70.78848 3079.0536 130.0932
BALANCE 130.0932 7310.90440743341 130.0932 7310.90440743341

FL-01 input output

from R-01 to light key (DC-01) to heavy key
component mol mass (kg) mol mass (kg) mol
C3H4O2 1.171988 84.383106 0.7694054 55.397189 0.402582
C2H5OH 7.031925 323.46857 3.5609470 163.80356 3.470978
C5H8O2 57.42739 5742.7391 56.818182 5681.8182 0.609210
H2O 64.46187 1160.3136 0 0 64.46187
total 130.0932 7310.9044 61.148534 5901.0189 68.94464
BALANCE 130.0932 7310.90440743341 130.0932 7310.90440743341
 R-01
Reactor (R-01)

component mol (kmol) mass (kg)

C3H4O2 1.1719876 84.383106
C2H5OH 7.0319255 323.46857
C5H8O2 57.427391 5742.7391
H2O 64.461866 1160.3136

X 98%
C2H5OH C5H8O2 + H2O solubility in H2O data at 298,15 K
64.45932 0 7.034474 component kg/kg H2O
57.42739 57.42739 57.427391 C3H4O2 0.024981
7.031925 57.42739 64.461866 C2H5OH 0.137605
C5H8O2 0.052504
H2O 1

output DC-01 input o

to FL-01 from FL-01 to distillate (MP-01)
mass (kg) component mol mass (kg) mol
84.38311 C3H4O2 0.7694054 55.397189 0
323.4686 C2H5OH 3.5609470 163.80356 3.530679
5742.739 C5H8O2 56.818182 5681.8182 0.013923
1160.314 H2O 0 0 0
7310.904 total 61.148534 5901.0189 3.544602
310.90440743341 BALANCE 61.148534 5901.01893931120

DC-02 input o
to heavy key from DC-01 to distillate (TT-03)
mass (kg) component mol mass (kg) mol
 28.98592 C3H4O2 0.7694054 55.397189 0.118342
159.6650 C2H5OH 0.0302680 1.3923303 0.030268
60.92096 C5H8O2 56.804259 5680.4259 56.71905
1160.314 H2O 0 0 0
1409.885 total 57.603932 5737.2154 56.86766
310.90440743341 BALANCE 57.603932 5737.2153761445
 FL-01
Decanter (FL-01)
component mol (kmol) mass (kg)
C3H4O2 0.7694054 55.39719
C2H5OH 3.5609470 163.8036
ata at 298,15 K C5H8O2 56.818182 5681.818
H2O 0 0

LIGHT OUTPUT

HEAVY OUTPUT

component mol (kmol) mass (kg)

C3H4O2 0.4025822 28.985917
C2H5OH 3.4709785 159.66501
C5H8O2 0.6092096 60.920961
H2O 64.461866 1160.3136

output
to distillate (MP-01) to bottom (DC-02)
mass (kg) mol mass (kg)
0 0.7694054 55.397189
162.41123 0.0302680 1.3923303
1.3923303 56.804259 5680.4259
0 0 0
163.8036 57.603932 5737.2154
61.148534 5901.01893931120

output
to distillate (TT-03) to bottom (MP-02)
mass (kg) mol mass (kg)
8.5206388 0.6510632 46.876550
1.3923070 0 0
5671.9052 0.0852064 8.5206388
0 0 0
5681.8182 0.7362701 55.397212
57.603932 5737.2153761445
 DC-01
Distillation Colomn 1 (FL-01)

vapor pressur
component
C3H4O2
C2H5OH
C5H8O2

P DC-01 1 atm light key C2H5OH

T 370.89436 K heavy key C5H8O2
component xi Pi (atm) K = Pi/P yi = Kixi
C3H4O2 0.0125826 0.223314 0.223314 0.0028099
C2H5OH 0.0582344 2.044452 2.044452 0.1190574
C5H8O2 0.9291831 0.945059 0.945059 0.8781327
0.999999951
C2H5OH
mol ET D 3.5306790 mol ET B 0.030268
ln (Di/Bi) 4.7591528
ln (i) 0.7716377

C5H8O2
mol EA D 0.0139233 mol EA B 56.80426
ln (Di/Bi) -8.313803
ln (i) 0
 component ln(D/B) [y] ln () [x]
C3H4O2 -1.4426676
C2H5OH 4.7591528 0.771638
C5H8O2 -8.31380267 0

y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b -8.31380267
a 16.941832

C3H4O2
ln (Di/Bi) -32.7552347
(Di/Bi) 5.951E-15
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D 4.579E-15 mol AA B 0.769405
 component mol (kmol) mass (kg)
C3H4O2 0 0
C2H5OH 3.5306790 162.41123
C5H8O2 0.0139233 1.3923303

to mixed point 1

vapor pressure data of each component

vpa vpb vpc vpd vpe
23.0607 -3134.7 -4.8813 0.0004369 -4.916E-013
23.8442 -2864.2 -5.0474 3.7448E-011 2.736E-007
55.0109 -3590.4 -17.694 0.008051 -4.886E-013

99.15% component mol (kmol) mass (kg)

99.15% C3H4O2 0.7694054 55.39719
i = Ki/Kb C2H5OH 0.0302680 1.392330
0.236297 C5H8O2 56.804259 5680.426
2.163306
1

P DC-02
T
component
C3H4O2
C2H5OH
C5H8O2

C5H8O2
mol EA D
ln (Di/Bi)
 ln (i)

C3H4O2
mol AA D

component
C3H4O2
C2H5OH
C5H8O2

y=ax+b
eq (1) 5,293305 = 0,771638 a +
eq (2) -8,844532 = 0 a + b
b
a

C2H5OH
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,7612
mol ET D
 component
C3H4O2
C2H5OH
DC-01 C5H8O2
Distillation Colomn 2 (FL-02)

vapor pressure data of each componen

component vpa vpb
C3H4O2 23.0607 -3134.7
C2H5OH 23.8442 -2864.2
C5H8O2 55.0109 -3590.4

1 atm light key C5H8O2 99.85%

373.04500 K heavy key C3H4O2 99.85%
xi Pi (atm) K = Pi/P yi = Kixi i = Ki/Kb
0.0133568 0.243402 0.243402 0.0032511 1
0.0005255 2.202222 2.202222 0.0011572 9.047676
0.9861177 1.009607 1.009607 0.9955917 4.147902
0.999999907

56.719052 mol EA B 0.085206

6.5007890
 1.4226026

0.1183422 mol AA B 0.651063

ln (Di/Bi) -1.705026
ln (i) 0

ln(D/B) [y] ln () [x]

-1.70502624 0
2.202508
6.5007890 1.422603

305 = 0,771638 a + b
4532 = 0 a + b
-1.70502624
5.7681713

10.999417
59839.227
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
0.0302675 mol ET B 5.058E-07
 mol (kmol) mass (kg)
0.1183422 8.5206388
0.0302675 1.3923070 Ethyl Acrylate Storage Tank (TT-03)
56.719052 5671.9052
TT-03

EA

ta of each component
vpc vpd vpe
-4.8813 0.0004369 -4.916E-013
-5.0474 3.7448E-011 2.736E-007
-17.694 0.008051 -4.886E-013

component mol (kmol) mass (kg)

C3H4O2 0.6510632 46.87655
C2H5OH 0 0
C5H8O2 0.0852064 8.520639
rage Tank (TT-03)

component mol (kmol) mass (kg) purity

C3H4O2 0.1183422 8.5206388 0.14996%
C2H5OH 0.0302675 1.3923070 0.02450%
C5H8O2 56.719052 5671.9052 99.8255%
5681.8182

to mixed point 2
 vapor pressure data of each component
component vpa vpb vpc vpd
C3H4O2 23.0607 -3134.7 -4.8813 0.0004369
C2H5OH 23.8442 -2864.2 -5.0474 3.7448E-011
C5H8O2 55.0109 -3590.4 -17.694 0.008051

P DC-01 1 atm light key C2H5OH

T 370.8943659769 K heavy key C5H8O2
component xi Pi (atm) K = Pi/P yi = Kixi
C3H4O2 0.0125825648 0.22331419 0.22331419 0.002809865
C2H5OH 0.0582343807 2.04445177 2.04445177 0.119057383
C5H8O2 0.9291830545 0.94505894 0.94505894 0.878132749
0.999999997

input C2H5OH
component mol mass (kg) mol ET D
C3H4O2 0.7694053982 55.3971887 ln (Di/Bi)
C2H5OH 3.5609470254 163.803563 ln (i)
C5H8O2 56.8181818748 5681.81819
C5H8O2
mol EA D

component
C3H4O2
C2H5OH
C5H8O2

y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b
a

C3H4O2
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D
Dew Point Temperature
P DC-01 1 atm
T 351.6938714287 K
component mol yi Pi (atm) K = Pi/P
C3H4O2 4.57865290E-015 1.2917E-015 0.0981291 0.098129099
C2H5OH 3.5306789756 0.99607197 1.00392694 1.003926936
C5H8O2 0.0139233029 0.00392803 0.50217517 0.50217517

Boiling Point Temperature

P DC-01 1 atm
T 351.6442900289 K
component mol xi Pi (atm) K = Pi/P
C3H4O2 4.57865290E-015 1.2917E-015 0.09790803 0.097908026
C2H5OH 3.5306789756 0.99607197 1.00196679 1.001966785
C5H8O2 0.0139233029 0.00392803 0.50130269 0.501302686

Boiling Point Temperature

P DC-01 1 atm
T 373.0449938715 K
component mol xi Pi (atm) K = Pi/P
C3H4O2 0.7694053982 0.01335682 0.24340184 0.243401838
C2H5OH 0.0302680497 0.00052545 2.20222108 2.202221076
C5H8O2 56.8042585719 0.98611773 1.00960698 1.009606976
 vapor pressure data of ea
vpe component vpa
-4.9161E-013 C3H4O2 23.0607
2.7361E-007 C2H5OH 23.8442
-4.8864E-013 C5H8O2 55.0109

99.15% P DC-01 1
99.15% T 373.0449938715
i = Ki/Kb component xi
0.2362965757 C3H4O2 0.0133568208
2.1633061137 C2H5OH 0.0005254511
1 C5H8O2 0.9861177281

input
3.5306789756 mol ET B 0.03026805 component mol
4.7591527845 C3H4O2 0.7694053982
0.7716376597 C2H5OH 0.0302680497
C5H8O2 56.8042585719

0.0139233029 mol EA B 56.8042586

ln (Di/Bi) -8.3138027
ln (i) 0

ln(D/B) [y] ln () [x]

-1.4426676
4.7591527845 0.77163766
-8.313802675 0

305 = 0,771638 a + b
4532 = 0 a + b
-8.313802675
16.941831823

-32.75523429
5.95090E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.57865E-015 mol AA B 0.7694054
 Dew Point Temperature
P DC-01 1
T 372.9365591154
xi = yi/Ki i = Ki/Kb component mol
1.31635E-014 0.19540811 C3H4O2 0.1183422054
0.99217576 1.99915686 C2H5OH 0.0302675439
0.0078220308 1 C5H8O2 56.719052184
0.9999977908

Boiling Point Temperature

P DC-01 1
T 372.7631369513
yi = Ki xi i = Ki/Kb component mol
1.26470E-016 0.1953072 C3H4O2 0.1183422054
0.9980310298 1.99872615 C2H5OH 0.0302675439
0.0019691318 1 C5H8O2 56.719052184
1.0000001616

Boiling Point Temperature

P DC-01 1
T 406.0447240612
yi = Ki xi i = Ki/Kb component mol
0.0032510747 0.24108573 C3H4O2 0.651063
0.0011571595 2.18126571 C2H5OH 5.05814704E-007
0.9955913374 1 C5H8O2 0.0852063879
0.9999995716
pressure data of each component
vpb vpc vpd vpe
-3134.7 -4.8813 0.0004369 -4.9161E-013
-2864.2 -5.0474 3.7448E-011 2.7361E-007
-3590.4 -17.694 0.008051 -4.8864E-013

atm light key C2H5OH 99.85%

K heavy key C5H8O2 99.85%
Pi (atm) K = Pi/P yi = Kixi i = Ki/Kb
0.24340184 0.24340184 0.003251075 0.2410857335
2.20222108 2.20222108 0.001157159 2.1812657089
1.00960698 1.00960698 0.995591337 1
0.999999572

C5H8O2
mass (kg) mol EA D 56.719052184 mol EA B 0.08520639
55.3971887 ln (Di/Bi) 6.5007890447
1.39233029 ln (i) 0
5680.42586
C3H4O2
mol AA D 0.1183422054 mol AA B 0.651063
ln (Di/Bi) -1.705026
ln (i) -1.4226027

component ln(D/B) [y] ln () [x]

C3H4O2 -1.705026 -1.4226027
C2H5OH 0.77990531
C5H8O2 6.5007890447 0

y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b 6.5007890447
a 5.7681708767

C2H5OH
ln (Di/Bi) 10.999416133
(Di/Bi) 59839.193393
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol ET D 0.0302675439 mol ET B 5.058E-007
atm
K
yi Pi (atm) K = Pi/P xi = yi/Ki i = Ki/Kb
0.00208101 0.24235363 0.242353627 0.0085866698 1
0.00053225 2.19403541 2.194035408 0.0002425874 9.0530331
0.99738674 1.00627084 1.006270839 0.9911712684 4.15207666
1.0000005256

atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.00208101 0.24068514 0.240685143 0.0005008683 1
0.00053225 2.18099552 2.180995523 0.0011608245 9.06161259
0.99738674 1.00095349 1.000953492 0.9983377445 4.15876726
0.9999994374

atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.88427223 0.80162286 0.801622859 0.7088528346 0.3186394
6.8700E-007 6.13873119 6.138731189 4.21728E-006 2.44010212
0.11572708 2.51576815 2.515768151 0.2911425043 1
0.9999995561
 Heat Capacity Components
component A B C D
C3H4O2 84.154 0.52899 -0.0013617 1.7294E-006
C2H5OH 59.342 0.36358 -0.0012164 0.000001803
C5H8O2 102.928 0.55475 -0.0016152 2.3569E-006
H2O 92.053 -0.039953 -0.00021103 5.3469E-007
Tref 298.15 K yaws
TT-01
Ethanol Storage Tank (TT-01) Heat Exchanger (E-01)
E-01
ET ET1
steam

component mol (kmol) H Q (kJ)

C2H5OH 64.459317 538.50192 34711.466
H2O 6.3291657 377.48638 2389.1738
T 303.15 K 37100.640

Acrylic Acid Storage Tank (TT-02)

TT-02
Heat Exchanger (E-02)
steam E-01

AA AA1

component mol (kmol) H Q (kJ)

C3H4O2 58.599379 835.54293 48962.297
H2O 0.7053085 377.48638 266.24434
T 303.15 K 49228.541

E-01 input output

from ET tank to R-01
component mol Q (kJ) mol Q (kJ)
C3H4O2 0 0 0 0
C2H5OH 64.459317 34711.466 64.459317 320195.89
C5H8O2 0 0 0 0
H2O 6.3291657 2389.1738 6.3291657 21424.621
total 70.788483 37100.640 70.788483 341620.51
BALANCE 70.788483 37100.640 70.788483 341620.51

E-02 input output

from AA tank to R-01
component mol Q (kJ) mol Q (kJ)
C3H4O2 58.599379 48962.297 58.599379 450488.37
C2H5OH 0 0 0 0
C5H8O2 0 0 0 0
H2O 0.7053085 266.24434 0.7053085 2387.5133
total 59.304688 49228.541 59.304688 452875.88
BALANCE 59.304688 49228.541 59.304688 452875.88
 component mol (kmol) H Q (kJ)
C2H5OH 64.459317 4967.4106 320195.89
H2O 6.3291657 3385.0625 21424.621
T 343.15 K 341620.51
at Exchanger (E-01)
E-01 steam

at Exchanger (E-02)
E-01

steam

component mol (kmol) H Q (kJ)

C3H4O2 58.599379 7687.5963 450488.37
H2O 0.7053085 3385.0625 2387.5133
T 343.15 K 452875.88

STEAM R-01 input

from E-01
Q (kJ) component mol Q (kJ)
 C3H4O2 0 0
C2H5OH 64.459317 320195.89
C5H8O2 0 0
H2O 6.3291657 21424.621
total 70.788483 341620.51
304519.87 BALANCE 130.09317 794496.39694313400

STEAM E-03 input

from R-01
Q (kJ) component mol Q (kJ)
C3H4O2 1.1719876 9009.7674
C2H5OH 7.0319255 34930.461
C5H8O2 57.427391 497599.19
H2O 64.461866 218207.44
total 130.09317 759746.86
403647.34 BALANCE 130.09317 759746.86
 R-01
Reactor (R-01) component mol (kmol) H
C3H4O2 1.1719876 7687.5963
C2H5OH 7.0319255 4967.4106
C5H8O2 57.427391 8664.8405
H2O 64.461866 3385.0625
T 343.15 K

reaction
C3H4O2 + C2H5OH C5H8O2 + H2O
Enthalpy of Formation Component HF
component A B C Hf
C3H4O2 -325.0380 -0.044058 2.093E-05 -336.313709
C2H5OH -216.9610 -0.069572 3.174E-05 -234.882059
C5H8O2 -327.0440 -0.089230 4.497E-05 -349.650387
H2O -238.4100 -0.012256 2.766E-06 -241.818283

HF (298,15 K) -20.27290 kJ/kmol

QR (343,15 K) -35913.75 kJ

input output REACTION COOLING

from E-02 to E-03
mol Q (kJ) mol Q (kJ)
 58.599379 450488.4 1.171988 9009.7674
0 0 7.031925 34930.461
0 0 57.42739 497599.19
0.7053085 2387.513 64.46187 218207.44
59.30469 452875.9 130.0932 759746.86
4496.39694313400 130.0932 759746.86184094800 -35913.75 -70663.29

output COOLING
to FL-01
mol Q (kJ) Q (kJ)
1.1719876 979.24594
7.0319255 3786.7054
57.427391 53914.809
64.461866 24333.476
130.09317 83014.236
130.09317 83014.236 -676732.6
 Q (kJ)
9009.7674
34930.461
497599.19
218207.44
759746.86 Heat Exchanger (E-03)
CWS E-01

CWR

component mol (kmol) H

C3H4O2 1.1719876 835.54293
C2H5OH 7.0319255 538.50192
C5H8O2 57.427391 938.83437
H2O 64.461866 377.48638
T 303.15 K

FL-01 input output

from E-03 to E-04
component mol Q (kJ) mol
C3H4O2 1.1719876 979.24594 0.7694054
C2H5OH 7.0319255 3786.7054 3.5609470
C5H8O2 57.427391 53914.809 56.818182
H2O 64.461866 24333.476 0
total 130.09317 83014.236 61.148534
BALANCE 130.09317 83014.236 130.09317

E-04 input output

from FL-01 to DC-01
component mol Q (kJ) mol
C3H4O2 0.7694054 642.87124 0.7694054
C2H5OH 3.5609470 1917.5768 3.5609470
C5H8O2 56.818182 53342.862 56.818182
H2O 0 0 0
total 61.148534 55903.310 61.148534
BALANCE 61.148534 55903.310 61.148534
 FL-01
Decanter (FL-01)

component
C3H4O2
C2H5OH
Q (kJ) C5H8O2
979.24594 H2O
3786.7054 T
53914.809
24333.476
83014.236 HEAVY OUTPUT

component mol H Q (kJ)

C3H4O2 0.4025822 835.54293 336.37470
C2H5OH 3.4709785 538.50192 1869.1286
C5H8O2 0.6092096 938.83437 571.94692
H2O 64.461866 377.48638 24333.476
T 303.15 K 27110.927

output DC-01
to E-04 to heavy key
Q (kJ) mol Q (kJ) component
 642.87124 0.4025822 336.37470 C3H4O2
1917.5768 3.4709785 1869.1286 C2H5OH
53342.862 0.6092096 571.94692 C5H8O2
0 64.461866 24333.476 H2O
55903.310 68.944636 27110.927 total
130.09317 83014.236 BALANCE

output STEAM DC-02

to DC-01
Q (kJ) Q (kJ) component
9718.4036 C3H4O2
29168.437 C2H5OH
811412.92 C5H8O2
0 H2O
850299.76 total
850299.76 794396.45 BALANCE
 mol H Q (kJ)
0.7694054 835.54293 642.87124
3.5609470 538.50192 1917.5768
56.818182 938.83437 53342.862
0 377.48638 0
303.15 K 55903.310
steam
LIGHT OUTPUT

component
C3H4O2
C2H5OH
C5H8O2
H2O
T

input output
from E-04 to E-05 to DC-02
mol Q (kJ) mol Q (kJ) mol
0.7694054 9718.4036 0 0 0.7694054
3.5609470 29168.437 3.5306790 20970.561 0.0302680
56.818182 811412.92 0.0139233 144.24202 56.804259
0 0 0 0 0
61.14853 850299.76 3.544602 21114.803 57.603932
61.14853 850299.76 61.14853 867903.430

input output
from DC-01 to E-06 to E-07
mol Q (kJ) mol Q (kJ) mol
0.769405 10018.77 0.6510632 12471.295 0.1183422
0.030268 255.68 0 0 0.0302675
56.804259 836514.18 0.0852064 1854.673 56.719052
0 0 0 0 0
57.60393 846788.6 0.7362701 14325.975 56.867662
57.60393 846788.6 57.60393 848059.201

eq (1)
eq (2)
 DC-01
Distillation Colomn 1 (D

Heat Exchanger (E-04)

E-01

steam

mol H Q (kJ)
0.7694054 12631.057 9718.4036
3.5609470 8191.2021 29168.437
56.818182 14280.867 811412.92
0 5472.7078 0
370.89437 K 850299.76

STEAM E-07 input

to DC-02 from DC-02
Q (kJ) Q (kJ) component mol Q (kJ)
 10018.768 C3H4O2 0.1183422 1534.924
255.68286 C2H5OH 0.0302675 254.6611
836514.18 C5H8O2 56.719052 831943.6
0 H2O 0 0
846788.63 total 56.867662 833733.2
867903.430 17603.667 BALANCE 56.867662 833733.2

STEAM
to E-07
Q (kJ) Q (kJ)
1534.9241
254.66110
831943.64
0
833733.23
848059.201 1270.574
 component mol H Q (kJ)
C-01 C3H4O2 0 9183.4055 0
C2H5OH 3.5306790 5939.5263 20970.561
tion Colomn 1 (DC-01) C5H8O2 0.0139233 10359.756 144.24202
H2O 0 4023.1925 0
T 351.64429 K 21114.803

to mixed point 1

component mol H Q (kJ)

C3H4O2 0.7694054 13021.442 10018.768
C2H5OH 0.0302680 8447.2857 255.68286
C5H8O2 56.804259 14726.258 836514.18
H2O 0 5635.1059 0
T 373.04499 K 846788.63

output COOLING
to TT-03
mol Q (kJ) Q (kJ)
0.118342 98.879993
0.030268 16.299130
56.71905 53249.796
0 0
56.86766 53364.975
56.86766 53364.975 -780368.3
 component mol
C3H4O2 0.1183422
DC-01 C2H5OH 0.0302675
Distillation Colomn 2 (DC-02) C5H8O2 56.719052
H2O 0
T 372.763137

component mol
C3H4O2 0.6510632
C2H5OH 0
C5H8O2 0.0852064
H2O 0
T 406.0447241
 H Q (kJ)
12970.218 1534.9241
8413.6693 254.66110
14667.799 831943.64
5613.8157 0
K 833733.23
Heat Exchanger (E-03)
CWS E-01

to mixed point 2

H Q (kJ)
19155.276 12471.295
12507.864 0
21766.836 1854.6735
8146.7365 0
K 14325.975
 TT-03 Tank (TT-03)
Ethyl Acrylate Storage

EA
CWR

component mol H Q (kJ)

C3H4O2 0.1183422 835.54293 98.879993
C2H5OH 0.0302675 538.50192 16.299130
C5H8O2 56.719052 938.83437 53249.796
H2O 0 377.48638 0
T 303.15 K 53364.975
 vapor pressure data of each component
component vpa vpb vpc vpd
C3H4O2 23.0607 -3134.7 -4.8813 0.0004369
C2H5OH 23.8442 -2864.2 -5.0474 3.7448E-011
C5H8O2 55.0109 -3590.4 -17.694 0.008051

P DC-01 1 atm light key C2H5OH

T 370.8975241734 K heavy key C5H8O2
component xi Pi (atm) K = Pi/P yi = Kixi
C3H4O2 0.0125610932 0.22334263 0.22334263 0.002805428
C2H5OH 0.0581300071 2.04467649 2.04467649 0.118857059
C5H8O2 0.9293088996 0.94515125 0.94515125 0.878337472
0.999999959

input C2H5OH
component mol mass (kg) mol ET D
C3H4O2 0.7679872307 55.2950806 ln (Di/Bi)
C2H5OH 3.5540775720 163.487568 ln (i)
C5H8O2 56.818125230 5681.81252
C5H8O2
mol EA D

component
C3H4O2
C2H5OH
C5H8O2

y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b
a

C3H4O2
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D
Dew Point Temperature
P DC-01 1 atm
T 351.6938095675 K
component mol yi Pi (atm) K = Pi/P
C3H4O2 4.54901098E-015 1.2858E-015 0.09812882 0.098128823
C2H5OH 3.5238679126 0.99607197 1.00392449 1.003924488
C5H8O2 0.0138964433 0.00392803 0.50217408 0.50217408

Boiling Point Temperature

P DC-01 1 atm
T 351.6442858772 K
component mol xi Pi (atm) K = Pi/P
C3H4O2 4.54901098E-015 1.2858E-015 0.09790801 0.097908007
C2H5OH 3.5238679126 0.99607197 1.00196662 1.001966621
C5H8O2 0.0138964433 0.00392803 0.50130261 0.501302613

Boiling Point Temperature

P DC-01 1 atm
T 373.0444435889 K
component mol xi Pi (atm) K = Pi/P
C3H4O2 0.7679872307 0.01333255 0.24339651 0.243396509
C2H5OH 0.0302096594 0.00052445 2.20217947 2.202179473
C5H8O2 56.8042287867 0.986143 1.00959002 1.009590024
 vapor pressure data of ea
vpe component vpa
-4.9161E-013 C3H4O2 23.0607
2.7361E-007 C2H5OH 23.8442
-4.8864E-013 C5H8O2 55.0109

99.15% P DC-01 1
99.15% T 373.0444353511
i = Ki/Kb component xi
0.23630358 C3H4O2 0.0133325576
2.1633325632 C2H5OH 0.0005244515
1 C5H8O2 0.9861429909

input
3.5238679126 mol ET B 0.03020966 component mol
4.7591527845 C3H4O2 0.7679884946
0.771649886 C2H5OH 0.0302097114
C5H8O2 56.804290370

0.0138964433 mol EA B 56.8042288

ln (Di/Bi) -8.3157331
ln (i) 0

ln(D/B) [y] ln () [x]

-1.4426379
4.7591527845 0.77164989
-8.315733122 0

305 = 0,771638 a + b
4532 = 0 a + b
-8.315733122
16.944065104

-32.75988438
5.92329E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.54901E-015 mol AA B 0.76798723
 Dew Point Temperature
P DC-01 1
T 372.9366140177
xi = yi/Ki i = Ki/Kb component mol
1.31036E-014 0.19540798 C3H4O2 0.1183422716
0.992178179 1.99915632 C2H5OH 0.0302092059
0.0078220478 1 C5H8O2 56.7190839349
1.0000002268

Boiling Point Temperature

P DC-01 1
T 372.7631983819
yi = Ki xi i = Ki/Kb component mol
1.25894E-016 0.1953072 C3H4O2 0.1183422716
0.9980308665 1.99872611 C2H5OH 0.0302092059
0.0019691315 1 C5H8O2 56.7190839349
0.999999998

Boiling Point Temperature

P DC-01 1
T 406.0322075135
yi = Ki xi i = Ki/Kb component mol
0.0032450962 0.2410845 C3H4O2 0.649646
0.0011549356 2.18126113 C2H5OH 5.05457805E-007
0.9956001333 1 C5H8O2 0.0852064356
1.0000001651
pressure data of each component
vpb vpc vpd vpe
-3134.7 -4.8813 0.0004369 -4.9161E-013
-2864.2 -5.0474 3.7448E-011 2.7361E-007
-3590.4 -17.694 0.008051 -4.8864E-013

atm light key C2H5OH 99.85%

K heavy key C5H8O2 99.85%
Pi (atm) K = Pi/P yi = Kixi i = Ki/Kb
0.24339643 0.24339643 0.003245097 0.2410844847
2.20217885 2.20217885 0.001154936 2.1812610584
1.00958977 1.00958977 0.995599875 1
0.999999908

C5H8O2
mass (kg) mol EA D 56.719083935 mol EA B 0.08520644
55.29517 ln (Di/Bi) 6.5007890447
1.389647 ln (i) 0
5680.429
C3H4O2
mol AA D 0.1183422716 mol AA B 0.649646
ln (Di/Bi) -1.702847
ln (i) -1.4226078

component ln(D/B) [y] ln () [x]

C3H4O2 -1.702847 -1.4226078
C2H5OH 0.77990318
C5H8O2 6.5007890447 0

y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b 6.5007890447
a 5.7666179517

C2H5OH
ln (Di/Bi) 10.998192704
(Di/Bi) 59766.02916
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol ET D 0.0302092059 mol ET B 5.055E-007
atm
K
yi Pi (atm) K = Pi/P xi = yi/Ki i = Ki/Kb
0.00208101 0.24235416 0.242354157 0.0085866598 1
0.00053122 2.19403955 2.194039546 0.0002421195 9.05303038
0.99738777 1.00627253 1.006272526 0.9911706239 4.15207455
0.9999994032

atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.00208101 0.24068573 0.240685732 0.0005008701 1
0.00053122 2.18100013 2.181000131 0.0011585901 9.06160955
0.99738777 1.00095537 1.000955372 0.9983406436 4.15876488
1.0000001039

atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.88404902 0.80129418 0.801294183 0.708383341 0.31860886
6.8784E-007 6.13657379 6.136573787 0.000004221 2.44001118
0.11595029 2.51497773 2.514977733 0.2916123909 1
0.9999999528
 Heat Capacity Components
component A B C D
C3H4O2 84.154 0.52899 -0.0013617 1.7294E-006
C2H5OH 59.342 0.36358 -0.0012164 0.000001803
C5H8O2 102.928 0.55475 -0.0016152 2.3569E-006
H2O 92.053 -0.039953 -0.00021103 5.3469E-007
Tref 298.15 K yaws
TT-01
Ethanol Storage Tank (TT-01)

ET ET1 mixed point 1

component mol (kmol) H Q (kJ)

C2H5OH 60.823149 538.50192 32753.383
H2O 6.3291657 377.48638 2389.1738
T 303.15 K 35142.556

Acrylic Acid TT-02

Storage Tank (TT-02)

AA AA1 mixed point 2

component mol (kmol) H Q (kJ)

C3H4O2 57.847648 835.54293 48334.193
H2O 0.7053085 377.48638 266.24434
T 303.15 K 48600.437

MP-1 input output

 from ET tank from recycle to E-01
component mol Q (kJ) mol Q (kJ) mol
C3H4O2 0 0 0 0 0
C2H5OH 60.82315 32753.383 3.52387 15507.987 64.347023
C5H8O2 0 0 0.01390 106.67808 0.0138965
H2O 6.329166 2389.1738 0 0 6.3291657
total 67.15232 35142.556 3.53777 15614.665 70.690085
BALANCE 70.69009 50757.22173690360 70.69009 50757.2218063358

MP-1 input output

from AA tank from recycle to R-01
component mol Q (kJ) mol Q (kJ) mol
C3H4O2 57.847648 48334.193 0.6496462 4426.7414 58.497294
C2H5OH 0 0 0 0 0
C5H8O2 0 0 0.0852064 654.09857 0.0852064
H2O 0.7053085 266.24434 0 0 0.7053085
total 58.55296 48600.437 0.7348527 5080.8400 59.287809
BALANCE 59.28781 53681.27729343870 59.28781 53681.2772912616
 component mol (kmol) H Q (kJ)
C2H5OH 3.5238740 4400.8348 15507.987
C5H8O2 0.0138965 7676.6334 106.67808
T 338.15 K 15614.665
Heat Exchanger (E-01)
E-01
steam
mixed point 1
steam

component mol (kmol) H Q (kJ)

C2H5OH 64.347023 737.72693 47470.532
C5H8O2 0.0138965 1286.2361 17.874138
H2O 6.3291657 516.46863 3268.8155
T 304.99265 K 50757.222

Heat Exchanger (E-02)

steam E-01
mixed point 2
steam

component mol H Q (kJ)

C3H4O2 58.497294 911.21764 53303.766
C5H8O2 0.0852064 1023.8911 87.242111
H2O 0.7053085 411.54906 290.26904
T 303.60153 K 53681.277

component mol H Q (kJ)

C3H4O2 0.6496462 6814.0801 4426.7414
C5H8O2 0.0852064 7676.6334 654.09857
T 338.15 K 5080.8400

output E-01 input output

 to E-01 from MP-01 to R-01
Q (kJ) component mol Q (kJ) mol
0 C3H4O2 0 0 0
47470.532 C2H5OH 64.347023 47470.532 64.347023
17.874138 C5H8O2 0.0138965 17.874138 0.0138965
3268.8155 H2O 6.3291657 3268.8155 6.3291657
50757.222 total 70.690085 50757.222 70.690085
0757.22180633580 BALANCE 70.690085 50757.222 70.690085

output E-02 input output

to R-01 from MP-02 to R-01
Q (kJ) component mol Q (kJ) mol
53303.766 C3H4O2 58.497294 53303.766 58.497294
0 C2H5OH 0 0 0
87.242111 C5H8O2 0.0852064 87.242111 0.0852064
290.26904 H2O 0.7053085 290.26904 0.7053085
53681.277 total 59.287809 53681.277 59.287809
3681.27729126160 BALANCE 59.287809 53681.277 59.287809
 component mol (kmol) H Q (kJ)
C2H5OH 64.347023 4967.4106 319638.08
C5H8O2 0.0138965 8664.8405 120.41067
H2O 6.3291657 3385.0625 21424.621
T 343.15 K 341183.12

component mol (kmol) H Q (kJ)

C3H4O2 58.497294 7687.5963 449703.58
C5H8O2 0.0852064 8664.8405 738.30018
H2O 0.7053085 3385.0625 2387.5133
T 343.15 K 452829.39

component mol H Q (kJ)

C3H4O2 0.6496462 6814.0801 4426.7414
C5H8O2 0.0852064 7676.6334 654.09857
T 338.15 K 5080.8400

output STEAM R-01 input

to R-01 from E-01
Q (kJ) Q (kJ) component mol
0 C3H4O2 0
319638.08 C2H5OH 64.347023
120.41067 C5H8O2 0.0138965
21424.621 H2O 6.3291657
341183.12 total 70.690085
341183.12 290425.89 BALANCE 129.97789

output STEAM E-03 input

to R-01 from R-01
Q (kJ) Q (kJ) component mol
449703.58 C3H4O2 1.1699459
0 C2H5OH 7.0196753
738.30018 C5H8O2 57.426451
2387.5133 H2O 64.361822
452829.39 total 129.97789
452829.39 399148.12 BALANCE 129.97789
 Heat Exchanger (E-0
E-01

CWR

component mol H Q (kJ)

C2H5OH 3.523874 4400.8348 15507.987
C5H8O2 0.013896 7676.6334 106.67808
T 338.15 K 15614.665

R-01
Reactor (R-01)
component mol (kmol) H
C3H4O2 1.1699459 7687.5963
C2H5OH 7.0196753 4967.4106
C5H8O2 57.426451 8664.8405
H2O 64.361822 3385.0625
T 343.15 K

reaction
C3H4O2 + C2H5OH C5H8O2 + H2O
T 343.15 K
Enthalpy of Formation Component HF
component A B C Hf
C3H4O2 -325.0380 -0.044058 2.093E-05 -337.692426
C2H5OH -216.9610 -0.069572 3.174E-05 -237.096715
C5H8O2 -327.0440 -0.089230 4.497E-05 -352.367971
H2O -238.4100 -0.012256 2.766E-06 -242.289992

HF (298,15 K) -19.86882 kJ/kmol

QR (343,15 K) -35828.03 kJ

Heat Exchanger (E-06)

E-01 CWS

CWR component mol

C3H4O2 0.6496462
C5H8O2 0.0852064
T 406.0322075

input output REACTION

from E-01 from E-02 to E-03
Q (kJ) mol Q (kJ) mol Q (kJ)
0 58.497294 449703.6 1.1699459 8994.0716
319638.08 0 0 7.0196753 34869.609
120.41067 0.0852064 738.3002 57.426451 497591.04
21424.621 0.7053085 2387.513 64.361822 217868.79
341183.12 59.28781 452829.4 129.97789 759323.51
794012.50999423800 129.9779 759323.51154965500 -35828.03

input output COOLING

from R-01 to FL-01
Q (kJ) mol Q (kJ) Q (kJ)
8994.0716 1.1699459 977.5400
34869.609 7.0196753 3780.109
497591.04 57.426451 53913.93
217868.79 64.361822 24295.71
759323.51 129.97789 82967.29
759323.51 129.97789 82967.29 -676356.23
at Exchanger (E-05)
E-01 CWS

component mol H Q (kJ)

C2H5OH 3.5238740 5939.5258 20930.141
C5H8O2 0.0138965 10359.755 143.96400
T 351.64429 K 21074.105

Q (kJ)
8994.0716
34869.609
497591.04
217868.79
759323.51 Heat Exchanger (E-03)
E-01
CWS

component mol (kmol) H

C3H4O2 1.1699459 835.54293
C2H5OH 7.0196753 538.50192
C5H8O2 57.426451 938.83437
H2O 64.361822 377.48638
T 303.15 K

H Q (kJ)
19152.895 12442.61
7676.6334 654.0986
K 13096.70

COOLING FL-01 input

 from E-03
component mol Q (kJ)
C3H4O2 1.1699459 977.54001
C2H5OH 7.0196753 3780.1086
C5H8O2 57.426451 53913.926
H2O 64.361822 24295.711
total 129.97789 82967.286
-70517.02 BALANCE 129.97789 82967.286

E-04 input
from FL-01
component mol Q (kJ)
C3H4O2 0.7679885 641.68736
C2H5OH 3.5540837 1913.8809
C5H8O2 56.818187 53342.867
H2O 0 0
total 61.140259 55898.435
BALANCE 61.140259 55898.435
 FL-01
Decanter (FL-01)
component
C3H4O2
CWR C2H5OH
C5H8O2
Q (kJ) H2O
977.54001 T
3780.1086
53913.926 LIGHT OUTPUT
24295.711
82967.286 HEAVY OUTPUT

component mol H Q (kJ)

C3H4O2 0.4019574 835.54293 335.85265
C2H5OH 3.4655916 538.50192 1866.2277
C5H8O2 0.6082641 938.83437 571.05927
H2O 64.361822 377.48638 24295.711
T 303.15 K 27068.851

output
 to E-04 to heavy key
mol Q (kJ) mol Q (kJ)
0.7679885 641.68736 0.4019574 335.85265
3.5540837 1913.8809 3.4655916 1866.2277
56.818187 53342.867 0.6082641 571.05927
0 0 64.361822 24295.711
61.140259 55898.435 68.837635 27068.851
129.97789 82967.286

output STEAM
to DC-01
mol Q (kJ) Q (kJ)
0.7679885 9700.9463
3.5540837 29113.552
56.818187 811450.09
0 0
61.140259 850264.59
61.140259 850264.59 794366.16
 mol H Q (kJ)
0.7679885 835.54293 641.68736
3.5540837 538.50192 1913.8809
56.818187 938.83437 53342.867
0 377.48638 0
303.15 K 55898.435
steam
LIGHT OUTPUT

component
C3H4O2
C2H5OH
C5H8O2
H2O
T

DC-01 input output

 from E-04 to E-05
component mol Q (kJ) mol Q (kJ)
C3H4O2 0.7679885 9700.9463 0 0
C2H5OH 3.5540837 29113.552 3.5238740 20930.141
C5H8O2 56.818187 811450.09 0.0138965 143.96400
H2O 0 0 0 0
total 61.14026 850264.59 3.537770 21074.105
BALANCE 61.14026 850264.59 61.14026

E-05 input output

from DC-01 to MP-01
component mol Q (kJ) mol Q (kJ)
C3H4O2 0 0 0 0
C2H5OH 3.5238740 20930.141 3.5238740 15507.987
C5H8O2 0.0138965 143.96400 0.0138965 106.67808
H2O 0 0 0 0
total 3.5377704 21074.105 3.5377704 15614.665
BALANCE 3.5377704 21074.105 3.5377704 15614.665
 DC-01
Distillation Colomn 1 (DC-01)

Heat Exchanger (E-04)

E-01

steam

mol H Q (kJ)
0.7679885 12631.630 9700.9463
3.5540837 8191.5775 29113.552
56.818187 14281.520 811450.09
0 5472.9462 0
370.89752 K 850264.59

output STEAM DC-02 input

 to DC-02 from DC-01
mol Q (kJ) Q (kJ) component mol
0.7679885 10000.241 C3H4O2 0.767988
0.0302097 255.18808 C2H5OH 0.030210
56.804290 836508.16 C5H8O2 56.80429
0 0 H2O 0
57.602489 846763.59 total 57.60249
867837.693 17573.103 BALANCE 57.60249

COOLING E-06 input

from DC-02
Q (kJ) component mol
C3H4O2 0.649646
C2H5OH 0
C5H8O2 0.085206
H2O 0
total 0.734853
-5459.44 BALANCE 0.734853
 component mol H Q (kJ)
C3H4O2 0 9183.4048 0
C2H5OH 3.523873983 5939.5258 20930.141
C5H8O2 0.013896467 10359.755 143.96400
H2O 0 4023.1922 0
1 (DC-01) T 351.64429 K 21074.105
DC

component mol H Q (kJ)

C3H4O2 0.7679885 13021.342 10000.241
C2H5OH 0.0302097 8447.2200 255.18808
C5H8O2 56.804290 14726.144 836508.16
H2O 0 5635.0643 0
T 373.04444 K 846763.59

input output STEAM

from DC-01 to E-06 to E-07
Q (kJ) mol Q (kJ) mol Q (kJ) Q (kJ)
10000.24 0.6496462 12442.606 0.1183423 1534.9263
255.1881 0 0 0.0302092 254.17049
836508.2 0.0852064 1854.4402 56.719084 831944.83
0 0 0 0 0
846763.6 0.7348532 14297.053 56.86764 833733.93
846763.6 57.60249 848030.978 1267.390

input output COOLING

from DC-02 to MP-02
Q (kJ) mol Q (kJ) Q (kJ)
12442.61 0.6496462 4426.7414
0 0 0
654.0986 0.0852064 654.09857
0 0 0
13096.71 0.7348532 5080.8463
13096.71 0.7348532 5080.8463 -8015.86
 component mol
DC-01 C3H4O2 0.1183423
C2H5OH 0.0302092
Distillation Colomn 2 (DC-02) C5H8O2 56.719084
H2O 0
T 372.7631984

component mol H
C3H4O2 0.6496462 19152.895
C2H5OH 0 12506.273
C5H8O2 0.0852064 21764.086
H2O 0 8145.7748
T 406.0322075 K

E-07 input output

 from DC-02 to TT-03
component mol Q (kJ) mol Q (kJ)
C3H4O2 0.1183423 1534.9263 0.1183423 98.880048
C2H5OH 0.0302092 254.17049 0.0302092 16.267715
C5H8O2 56.719084 831944.83 56.719084 53249.825
H2O 0 0 0 0
total 56.867635 833733.93 56.867635 53364.973
BALANCE 56.867635 833733.93 56.867635 53364.973
 H Q (kJ)
12970.229 1534.9263
8413.6766 254.17049
14667.811 831944.83
5613.8203 0
K 833733.93
Heat Exchanger (E-07)
CWR
E-01
CWS

Q (kJ)
12442.606
0
1854.4402
0
14297.053

COOLING
Q (kJ)

-780369.0
 Ethyl Acrylate TT-03
Storage Tank (TT-03)

EA

component mol H Q (kJ)

C3H4O2 0.1183423 835.54293 98.880048
C2H5OH 0.0302092 538.50192 16.267715
C5H8O2 56.719084 938.83437 53249.825
H2O 0 377.48638 0
T 303.15 K 53364.973
 component mol mass (kg) component
C3H4O2 1.1699459 84.23610 C3H4O2
C2H5OH 7.0196753 322.90506 C2H5OH
C5H8O2 57.426451 5742.6451 C5H8O2
H2O 64.361822 1158.5128 H2O

Tdecanter 298.15 K
P 1 atm

density data of each component

component A B n Tc (K)
C3H4O2 0.3465 0.25822 0.30701 615.00
C2H5OH 0.2657 0.26395 0.2367 516.25
C5H8O2 0.31019 0.25833 0.28571 553.00
H2O 0.3471 0.274 0.28571 647.13
yaws

viscosity data of each component

component A B C D
C3H4O2 -15.9215 2440.8 0.034383 -2.768E-05
C2H5OH -6.4406 1117.6 0.013721 -1.547E-05
C5H8O2 -5.596 810.55 0.012995 -1.427E-05
H2O -10.2158 1792.5 0.01773 -1.263E-05
yaws

solubility in H2O data at 298,15 K

component kg/kg H2O
C3H4O2 0.024981
C2H5OH 0.137605
C5H8O2 0.052504
H2O 1
Aspen Databanks

1. Determining heavy key liquid and light key liquid

1.1 Heavy Key Liquid
component mass (kg)
C3H4O2 28.94093
C2H5OH 159.41721
C5H8O2 60.82641
H2O 1158.5128

1.2 Light Key Liquid

component mass (kg)
C3H4O2 55.29517
C2H5OH 163.48785
C5H8O2 5681.8187
H2O 0.00000

2. Determining dispersion phase

2.1 Light Key Density
component mass (kg) (kg/m3) m/ (m3)
C3H4O2 55.29517 1045.512225 0.052888116
C2H5OH 163.48785 787.3043458 0.207655211
C5H8O2 5681.8187 917.7815982 6.190817831
H2O 0.00000 1027.452915 0
5900.6017 6.451361158

light key density 914.6289536 kg/m3

2.2 Heavy Key Density

component mass (kg) (kg/m3) m/ (m3)
C3H4O2 28.94093 1045.512225 0.027681103
C2H5OH 159.41721 787.3043458 0.202484863
C5H8O2 60.82641 917.7815982 0.066275476
H2O 1158.5128 1027.452915 1.127558045
1407.6974 1.423999487

heavy key density 988.5518702 kg/m3

2.3 Light Key Viscosity

component mass (kg) Xmass (kg/ms) Xmass
C3H4O2 55.29517 0.009371107 1.137552657 0.010660128
C2H5OH 163.48785 0.027706979 1.056885984 0.029283118
C5H8O2 5681.8187 0.962921913 0.535129926 0.515288332
H2O 0.00000 0 0.911299516 0
5900.6017 1 0.555231578

light key viscosity 0.555231578 kg/ms

2.4 Heavy Key Viscosity

component mass (kg) Xmass (kg/ms) Xmass
C3H4O2 28.94093 0.020559058 1.137552657 0.023387011
C2H5OH 159.41721 0.113246794 1.056885984 0.119688949
C5H8O2 60.82641 0.043209865 0.535129926 0.023122892
H2O 1158.5128 0.822984283 0.911299516 0.749985179
1407.6974 1 0.916184031
 heavy key viscosity 0.916184031 kg/ms

3. Determining time separation

time 0.124205508 jam
447.1398283 detik

4. Decanter sizing
4.1 Calculating Liquid Volume
decanter 10 minutes
Vl 1.312560108 m3

4.2 Calculating Decanter Volume

safety 20%
Vt 1.575072129 m3
Vt 416.146544 gallon

4.3 Calculating Decanter Diameter and Height

L/D 3
3.142857143
Dt 0.874255113 m
L 2.622765339 m

4.4 Calculating Decanter Shell Thick

Material 316-SS
Fall 16500 Psi
114312 kPa
Corrosion 0.15 mm/year
Time 10 year
C" 1.5 mm
0.0015 m
0.85
Pdesign 1.5 atm
151.9875 kPa
Penvirontmwnt 101.325 kPa
Pgauge 50.6625 kPa
ro 0.437127556 m
tshell 0.001727873 m
0.068026509 in
tshell 0.1875 in

4.5 Calculating Decanter Head Thick

P < 15 bar torispherical dishead
Do 0.874255113 m
34.41949263 in
tshell 0.1875 in
0.0047625 m
cr 36 in
icr 2.25 in
0.05715 m
straight flange 2 in
0.0508 m
Di 0.864730113 m
AB 0.375215056 m
BC 0.817105113 m
b 0.634587832 m
OA 0.690150332 m
Lt 4.003066003 m
 MW
72
46
100
18

1.04551222
0.78730435
0.9177816
1.02745291

1.13755266
1.05688598
0.53512993
0.91129952
 component MW
C3H4O2 72
C2H5OH 46
C5H8O2 100
H2O 18 component
Aspen Databanks TT-01 C2H5OH
Ethanol Storage Tank (TT-01) C5H8O2

ET ET1
mixed point 1

component mass (kg) mol (kmol) component

C2H5OH 2797.865 60.823149 C2H5OH
H2O 113.9250 6.3291657 C5H8O2
H2O

Acrylic Acid Storage

TT-02 Tank (TT-02)

AA AA1 mixed point 2

component mass (kg) mol (kmol) component

C3H4O2 4165.031 57.847648 C3H4O2
H2O 12.69555 0.7053085 C5H8O2
H2O

component
C3H4O2
C5H8O2

MP-1 input output

from ET tank from recycle to R-01
component mol mass (kg) mol mass (kg) mol
C3H4O2 0 0 0 0 0
C2H5OH 60.82315 2797.8649 3.52387 162.0982 64.347023
C5H8O2 0 0 0.01390 1.389647 0.0138965
H2O 6.329166 113.92498 0 0 6.3291657
total 67.15232 2911.7899 3.53777 163.4878 70.690085
BALANCE 70.69009 3075.27770191028 70.69009 3075.27770191028

MP-2 input output

from AA tank from recycle to R-01
component mol mass (kg) mol mass (kg) mol
C3H4O2 57.84765 4165.0306 0.6496462 46.77453 58.497294
C2H5OH 0 0 0 0 0
C5H8O2 0 0 0.0852064 8.520644 0.0852064
H2O 0.705308 12.695553 0 0 0.7053085
total 58.55296 4177.7262 0.7348527 55.29517 59.287809
BALANCE 59.28781 4233.02135979029 59.28781 4233.02135979029
 trial mol mol eror mass (kg)
3.5238740 3.5238740 0 162.0982
0.0138965 0.0138965 0 1.389647

R-01
mixed point 1 Reactor (R-01)

mol (kmol) mass (kg)

64.347023 2959.9631
0.0138965 1.3896467
6.3291657 113.92498

reaction X 98%
C3H4O2 + C2H5OH C5H8O2 +
mixed point 2 M 58.49729 64.34702 0.099103
R 57.32735 57.32735 57.32735
mol (kmol) mass (kg) S 1.169946 7.019675 57.42645
58.497294 4211.8052
0.0852064 8.5206436
0.7053085 12.695553

trial mol mol eror mass (kg)

0.6496462 0.6496462 0 46.87655
0.0852064 0.0852064 0 8.520639

output R-01 input

to R-01 from MP-01 from MP-02
mass (kg) component mol mass (kg) mol
0 C3H4O2 0 0 58.49729
2959.9631 C2H5OH 64.34702 2959.963 0
1.3896467 C5H8O2 0.013896 1.389647 0.085206
 113.92498 H2O 6.329166 113.9250 0.705308
3075.2777 total 70.69009 3075.278 59.28781
075.27770191028 BALANCE 129.9779 7308.29906170057

output FL-01 input o

to R-01 from R-01 to light key (DC-01)
mass (kg) component mol mass (kg) mol
4211.8052 C3H4O2 1.169946 84.23610 0.767988
0 C2H5OH 7.019675 322.9051 3.554084
8.5206436 C5H8O2 57.42645 5742.645 56.81819
12.695553 H2O 64.36182 1158.513 0
4233.0214 total 129.9779 7308.299 61.14026
233.02135979029 BALANCE 129.9779 7308.29906170057
 component mol mass (kg)
C3H4O2 1.1699459 84.23610
C2H5OH 7.0196753 322.9051 FL-01
C5H8O2 57.426451 5742.645 Decanter (FL-01)
H2O 64.361822 1158.513

H2O solubility in H2O data at 298,15 K

7.034474 component kg/kg H2O
57.32735 C3H4O2 0.024981
64.36182 C2H5OH 0.137605
C5H8O2 0.052504
H2O 1 HEAVY OUTPUT
Aspen Databanks
component
C3H4O2
C2H5OH
C5H8O2
H2O

output DC-01 input

from MP-02 to FL-01 from FL-01
mass (kg) mol mass (kg) component mol
4211.805 1.1699459 84.236103 C3H4O2 0.7679885
0 7.0196753 322.90506 C2H5OH 3.5540837
8.520644 57.426451 5742.6451 C5H8O2 56.818187
 12.69555 64.361822 1158.5128 H2O 0
4233.021 129.97789 7308.2991 total 61.140259
129.9779 7308.29906170057 BALANCE 61.140259

output DC-02 input

o light key (DC-01) to heavy key from DC-01
mass (kg) mol mass (kg) component mol
55.29517 0.4019574 28.940932 C3H4O2 0.7679885
163.4878 3.4655916 159.41721 C2H5OH 0.0302097
5681.819 0.6082641 60.826413 C5H8O2 56.804290
0 64.361822 1158.5128 H2O 0
5900.602 68.837635 1407.6974 total 57.602489
129.9779 7308.29906170057 BALANCE 57.602489
 FL-01
ecanter (FL-01)
component mol mass (kg)
C3H4O2 0.767988 55.29517
C2H5OH 3.554084 163.4878
C5H8O2 56.81819 5681.819
H2O 0 0

LIGHT OUTPUT

HEAVY OUTPUT

mol mass (kg)

0.401957 28.940932
3.465592 159.41721 P DC-01
0.608264 60.826413 T
64.36182 1158.5128 component
C3H4O2
C2H5OH
C5H8O2

input output
from FL-01 to distillate (MP-01) to bottom (DC-02)
mass (kg) mol mass (kg) mol mass (kg)
55.29517 4.549E-15 3.275E-13 0.767988 55.29517
163.4878 3.5238740 162.09820 0.030210 1.389647
5681.819 0.0138965 1.3896467 56.80429 5680.429
 0 0 0 0 0
5900.602 3.5377704 163.48785 57.60249 5737.114
5900.60170530468 61.140259 5900.60170530468

input output
from DC-01 to distillate (TT-03) to bottom (MP-02)
mass (kg) mol mass (kg) mol mass (kg)
55.29517 0.1183423 8.5206436 0.649646 46.77453
1.389647 0.0302092 1.3896235 5.05E-07 2.33E-05
5680.429 56.719084 5671.9084 0.085206 8.520644
0 0 0 0 0
5737.114 56.867635 5681.8187 0.734853 55.29519
5737.1138553759 57.602489 5737.1138553759
 component
C3H4O2
DC-01 C2H5OH
C5H8O2
Distillation Colomn 1 (FL-01)

vapor pressure data of each compon

component vpa vpb
C3H4O2 23.0607 -3134.7
C2H5OH 23.8442 -2864.2
C5H8O2 55.0109 -3590.4
Yaws

1 atm light key C2H5OH 99.15%

370.89720 K heavy key C5H8O2 99.15%
xi Pi (atm) K = Pi/P yi = Kixi i = Ki/Kb
0.0125611 0.2233397 0.2233397 0.0028054 0.236303
0.0581300 2.0446532 2.0446532 0.1188557 2.163330
0.9293089 0.9451417 0.9451417 0.8783286 1.000000
0.9999897

C2H5OH
mol ET D 3.5238740 mol ET B 0.030210
ln (Di/Bi) 4.7591528
ln (i) 0.7716486

C5H8O2
mol EA D 0.0138965 mol EA B 56.80429
 ln (Di/Bi) -8.315732
ln (i) 0

component ln(D/B) [y] ln () [x]

C3H4O2 -1.44264102
C2H5OH 4.7591528 0.7716486
C5H8O2 -8.315732 0

y=ax+b
eq (1) 4,7591528 = 0,7716486 a + b
eq (2) -8,315732 = 0 a + b
b -8.315732
a 16.944092

C3H4O2
ln (Di/Bi) -32.75997
(Di/Bi) 5.923E-15
eq (1) Di = 5,923E-15 x Bi
eq (2) Di + Bi = 0,767988
5,923E-15 Bi + Bi = 0,767988
mol AA D 4.549E-15 mol AA B 0.767988
 mol mass (kg)
0 0
3.5238740 162.0982
0.0138965 1.389647

ta of each component
DC-01
vpc vpd vpe Distillation Colomn 2 (FL-
-4.8813 0.0004369 -4.916E-013
-5.0474 3.745E-011 2.736E-007
-17.694 0.008051 -4.886E-013

component mol mass (kg)

C3H4O2 0.767988 55.29517
C2H5OH 0.030210 1.389647
C5H8O2 56.80429 5680.429

P DC-02 1 atm
T 373.04447 K
component xi Pi (atm)
C3H4O2 0.0133326 0.243397
C2H5OH 0.0005245 2.202181
C5H8O2 0.9861430 1.009591
 C5H8O2
mol EA D 56.719084 mol EA B
ln (Di/Bi) 6.5007890
ln (i) 1.4226075

C3H4O2
mol AA D 0.1183423 mol AA B
ln (Di/Bi)
ln (i)

component ln(D/B) [y] ln () [x]

C3H4O2 -1.702847 0
C2H5OH 2.202511
C5H8O2 6.5007890 1.422608

y=ax+b
eq (1) 6,500789 = 1,422608 a + b
eq (2) -1,702847 = 0 a + b
b -1.702847
a 5.7666192

C2H5OH
ln (Di/Bi) 10.998194
(Di/Bi) 59766.128
eq (1) Di = 59766,128 x Bi
eq (2) Di + Bi = 0,030210
59766,128 Bi + Bi = 0,030210
mol ET D 0.0302092 mol ET B
 component mol
C-01 C3H4O2
C2H5OH
0.11834
0.03021
ation Colomn 2 (FL-02) C5H8O2 56.7191

vapor pressure data of each component

component vpa vpb vpc vpd
C3H4O2 23.0607 -3134.7 -4.8813 0.0004369
C2H5OH 23.8442 -2864.2 -5.0474 3.74E-011
C5H8O2 55.0109 -3590.4 -17.694 0.008051
Yaws

component mol
C3H4O2 0.64965
C2H5OH 0
C5H8O2 0.08521

light key C5H8O2 99.85%

heavy key C3H4O2 99.85%
K = Pi/P yi = Kixi i = Ki/Kb
0.243397 0.0032451 1.000000
2.202181 0.0011549 9.047702
1.009591 0.9956009 4.147922
1.0000009
0.085206

0.649646
-1.702847
0

5.055E-07
mass (kg)
8.520644 Ethyl Acrylate Storage Tank (TT-03)
1.389623 TT-03
5671.908 component mol
C3H4O2 0.11834
EA C2H5OH 0.03021
C5H8O2 56.7191

vpe
-4.916E-013
2.736E-007
-4.886E-013

mass (kg)
46.77453
0
8.520644
mass (kg) purity
8.5206436 0.14996%
1.3896235 0.02446%
5671.9084 99.8256%
5681.8187
 component mass (kg) kmol Xmol
C3H4O2 55.295172 0.7679885 0.013
C2H5OH 163.48785 3.5540837 0.058
C5H8O2 5681.8187 56.818187 0.929
H2O 0 0 0
5900.6017 61.1403

vapor pressure data of each component

component vpa vpb vpc vpd
C3H4O2 23.0607 -3134.7 -4.8813 0.0004369
C2H5OH 23.8442 -2864.2 -5.0474 3.745E-011
C5H8O2 55.0109 -3590.4 -17.694 0.008051

density data of each component

component A B n Tc (K)
C3H4O2 0.3465 0.25822 0.30701 615.00
C2H5OH 0.2657 0.26395 0.2367 516.25
C5H8O2 0.31019 0.25833 0.28571 553.00
H2O 0.3471 0.274 0.28571 647.13

heat capacity data of each component

component A B C D
C3H4O2 -18.242 1.2106 -0.0031 3.14E-06
C2H5OH 59.342 0.36358 -0.0012 1.80E-06
C5H8O2 66.535 0.91312 -0.0028 3.54E-06
H2O 92.053 -0.039953 -0.000211 5.35E-07

1. operation condition
1.1 feed key component
light key C2H5OH
heavy key C5H8O2

1.2 recovery
each key 99.15%

1.3 feed boiling point

T 370.8975231 K
Pt 1 atm
component Xmol Puap Ki yi = Ki xi
C3H4O2 0.012561 0.223 0.223 0.003
C2H5OH 0.058130 2.045 2.045 0.119
C5H8O2 0.929309 0.945 0.945 0.878
Total 1 0.99999993

1.4 distillate and bottom composition

distillate LK 3.523873983 kmol
bottom LK 0.029952929 kmol
Ln (Di/Bi) 4.767689115
Ln (i) 0.771649882

distillate HK 0.013896467 kmol

bottom HK 56.804290 kmol
Ln (Di/Bi) -8.315732484
Ln (i) 0

component Ln (Di/Bi) Ln (i)

C3H4O2 -1.442637955
C2H5OH 4.767689115 0.7716498819
C5H8O2 -8.315732484 0

y=ax+b
eq (1). 4,7676891 = 0,7716486 a + b
eq (2). -8,315732 = 0 a + b
b -8.315732
a 16.955127

C3H4O2
ln (Di/Bi) -32.77584
(Di/Bi) 5.830E-15
eq (1). Di = 5,830E-15 x Bi
eq (2). Di + Bi = 0,7679885
5,830E-15 Bi + Bi = 0,7679885

bottom AA 0.767988 kmol

distillate AA 4.477E-15 kmol

1.5 top colom operation condition

Tdew 351.6938171 K
Pt 1 atm
component kmol yi Puap Ki
C3H4O2 0 0 0.098129 0.098
C2H5OH 3.523873983 0.996072 1.003925 1.004
C5H8O2 0.013896467 0.003928 0.502174 0.502
Total 3.53777045 1

Tboiling 351.64365 K
Pt 1 atm
component kmol xi Puap Ki
C3H4O2 0 0 0.097905 0.098
C2H5OH 3.5238740 0.9960719703 1.001942 1.002
C5H8O2 0.0138965 0.0039280297 0.501291 0.501
Total 3.53777045 1

1.6 bottom colom operation condition

Tboiling 374.057143 K
Pt 1 atm
component kmol yi Puap Ki
C3H4O2 0.767988495 0.013332617 0.253 0.253
C2H5OH 0.029952929 0.000519996 2.280 2.280
C5H8O2 56.80429037 0.986147387 1.041 1.041
Total 57.60223179 1

2. number of minimum plate

average 2.092023195
Nmin 18.78686262
Nmin 19

3. minimum reflux
3.1 Underwood constant
2.024896435
component Xf f i -
C3H4O2 0.012561093 0.2363035776 0.236 -1.789
C2H5OH 0.058130007 2.1633325543 2.163 0.138
C5H8O2 0.9293089 1 1.000 -1.025
Total 1 3.3996361319

3.2 Minimum reflux ratio

component Xd i = Ki / Kb i Xi i -
C3H4O2 0 0.1953059016 0 -1.830
C2H5OH 0.99607197 1.9987205865 1.99087 -0.026
C5H8O2 0.00392803 1 0.003928 -1.025
Total 1 3.194
 component MW
C3H4O2 72
C2H5OH 46
C5H8O2 100
H2O 18

surface tension data of each component

component A Tc (K)
vpe C3H4O2 65.495 615.00
-4.9161E-013 C2H5OH 67.036 516.25
2.7361E-007 C5H8O2 58.960 553.00
-4.8864E-013 H2O 132.674 647.13

viscosity data of each component

component A B
C3H4O2 -15.922 2440.8
C2H5OH -6.4406 1117.6
C5H8O2 -5.596 810.55
H2O -10.2158 1792.5

enthalpy vaporation data component

component A Tc (K)
C3H4O2 62.977 615
C2H5OH 43.122 516.25
C5H8O2 47.28 559
H2O 52.053 647.13

i = Ki / Kb
0.236
2.163
1.000
xi = yi / Ki i = Ki / Kb
0 0.195407997
0.992 1.999156389
0.008 1
0.9999999307

yi = Ki xi i = Ki / Kb
0 0.195305902
0.9980058487 1.998720587
0.0019690876 1
 0.9999749363

xi = yi / Ki i = Ki / Kb
0.0526206146 0.243
0.0002280848 2.190
0.9471505439 1.000
0.9999992433

i - / xF/B
-7.569 -0.001659534
0.064 0.908393978
-1.025 -0.906734444
-1.0436E-014

i Xi / i -
0
-76.0574973312
-0.0038326113
-76.0613299425
ponent
n
1.25
1.22
1.13
0.96

C D
0.03438 -2.77E-05
0.01372 -1.55E-05
0.01300 -1.43E-05
0.01773 -1.26E-05

ent
n
0.351
0.079
0.306
0.321