Professional Documents
Culture Documents
INDEX:
Sr.No Contain Page No
2. Abstract V
3. Declaration VI
4. List of table VII
5. Chapter:1 Introduction 1
6. 1.1 About Company 1
7. 1.2 Mission Statement 1
8. 1.3Environment and Safety 1
9. 1.4 Product Manufacturing in Company 2
10. 1.5Physical property 2
11. 1.6 Application 3
12. 1.7Problem Definition 3
1.8 Usefulness project to industry 3
13. Chapter: 2 History of Work 4
14 2.1 Row Material Requirement 4
15. 2.2 Table for a property of raw material 4
16. 2.3 Flow sheet of pigment Green7 5
17. 2.4 Process Description 6
18. 2.4.1 Chlorination Operation 6
19. 2.4.2 Dumping Operation 7
20. 2.4.3 Filtration Operation 8
21. 2.4.4 Pigmentation Process 9
22. 2.4.5 Scrubbing Operation 10
23. 2.4.6Chloromass Filtration 10
24. 2.4.7 Drying and Blending 10
25. Chapter: 3 Material & Energy Balance 11
26. 3.5 Calculation of Material Balance 11
27. 3.6 Calculation of Energy Balance 20
28. Chapter: 4 Design of gas induction type hollow
Agitator 24
29. 4.1 Advantage 29
30. 4.2 Disadvantage 29
31. Chapter: 5 Cost Estimation 30
32. 5.1 Cost Estimation (present plant) 30
33. 5.2 Cost Estimation (New plant) 36
34. Chapter:6 Plant layout 42
35. Chapter:7 Result & Conclusion 43
36. Chapter:8 Further development require for taking
innovation to user level or market 44
37. Chapter:9 Bibliography 45
LIST OF TABLE:
SR.NO Table No. Table Contain Page No
1 3.2 Table of Property of Raw material 4
2 3.5.1 Table of Material Balance for stage ' 1 13
3 3.5.2 Table of Material Balance for stage ' 2 14
4 3.5.3 Table of Material Balance for stage ' 3 15
5. 3.5.4 Table of Material Balance for stage ' 4 16
6. 3.5.5 Table of Material Balance for stage ' 5 17
7. 3.5.6 Table of Material Balance for stage ' 6 18
8. 3.5.7 Table of Material Balance for stage ' 7 19
9. 3.6.1 Table of component specific heat value & M.W 20
CHAPTER-1
INTRODUCTION:
1.1ABOUT COMPANY
Meghmani have many plants in Gujarat producing different products.
ATVATVA SITE:
Certified :ISO 9001 ' 2000
Established :1986
Land Area: 9900 Sq.m
Manufacturer: - Phthalocynine Green 7 more popularly known as Pigment green 7.
Production Capacity: 1150 ton/batch
1.2MISSION STATEMENT
It aims to be leading global player in the manufacturing and marketing of pigments and
agrochemical by:
Providing the highest quality of products and services.
Sustaining customer satisfaction through efficiency and reliability.
Ensuring the pride and satisfaction of our workforce.
Maintaining stringent standard of environmental safety and corporate responsibility.
1.3ENVIRONMENT & SAFETY
Have good records on Safety and loss prevention / minimization.
Have the necessary facilities to treat liquid / solid waste and air emission that contain pollution,
in accordance with the requirements of the Gujarat pollution Control Board ('GPCB').
Are complying with rules and regulations of Indian Government on Health, Safety and
Environment Protection.
Are ISO certified and also follow sound Health Safety and Environmental policy.
It is also found that following safe guards are in place at all the plants.
Fire fighting hand appliances are provided.
Work procedures and safety instructions provided.
Personal protective equipment is in place & in use.
Risk analysis is being carried out periodically.
Medical support is available to attend to occupational health related problems and supervision of
trained first aid providers.
Some of our products and raw materials are considered hazardous.
1.6APPLICATION:
It is used in most paint application. It satisfies the high standard of automotive OEM paints.
It is used in power coating application and has superior fastness properties compared to
phthalocynine blue.
In printing ink application it is used in almost all ink system.
This pigment is used in most plastic application and is suitable for the mass coloration of
synthetic fibre.
For rubber application low free copper content grades are used to avoid the rubber poisoning due
to ageing of rubber.
1.7PROBLEM DEFINATION:
To design an agitator which will have much less power consumption and will give a reduced
reaction time period than the existing one.
Use of gas induction type hollow agitator will provide better mixing of Cl2 gas than 3 blade
marine type agitator.
Gas induction type hollow agitator will reduce power consumption from 7hp to 5hp.
As the loss of Cl2 gas will reduce, the amount of Cl2 gas required at the initial stage of the
process will be less.
Also reaction time will decrease so that annual production capacity gets increased.
The annual profit of the company will also increase.
CHAPTER -2
BRIEF HISTORY OF WORK
A gas dispersion stirrer comprises a rotatable hollow shaft and at least one circular hollow
stirring member disposed thereon wherein the cavity in the stirring member communicates with
the hollow shaft. The stirring member has aeration apertures disposed in an outer peripheral
portion thereof. The stirring member has flow-inducing blades for radically directing the liquid
from the hollow shaft toward the aeration apertures. The gas dispersion stirrer effectively aerates
liquids and achieves an improvement in mass transfer.
The invention relates to a gas dispersion stirrer comprising a rotatable hollow shaft and at least
one hollow stirring member disposed thereon, where its cavity communicates with said hollow
shaft and has apertures towards the liquid to be aerated.
Such stirrers are in general already known as hollow stirrers. The stirring members of such
hollow stirrers are designed as tubular stirrers or triangular stirrers. Tubular stirrers consist of
hollow tubular members radically protruding from the rotatable hollow shaft, whereas the
triangular stirrer consists of a hollow triangular disk at whose corners corresponding apertures
are provided for the discharge of the gas. Such hollow stirrers are self-aerating stirring members,
i.e. as a result of the suction caused by the rotation of the stirrer they draw in gas from the space
above the liquid and distribute the same in the liquid. They are used in particular in low-viscosity
liquids for the case that the throughput of gas affected by them is sufficient for a desired reaction.
On the other hand, the gas dispersion does not start until a minimum rotational speed is
exceeded. The same is reached when the velocity pressure, which develops in the apertures of the
stirrer as a result of the rotational speed of the stirrer, overcomes the hydrostatic pressure. The
efficiency of the self-aeration in accordance with this known method is substantially influenced
on the one hand by the increasing hydrostatic pressure (filling level), and on the other hand by an
increasing viscosity of the liquid. As a result, such gas dispersion stirrers can in general not be
used, for instance, in fomenters.
A further possibility of self-aeration consists in increasing the rotational speed of a conventional
stirring member such that from the surface of the fluid to be stirred up to the stirring member a
spout is formed. Such a spout type gas dispersion is, however, not applicable in many cases for
process engineering reasons. Moreover, the same can also not be realized when high-viscosity
liquids are used.
As compared to self-aeration, larger amounts of gas can be dispersed by the principle of forced
aeration. In the forced aeration externally compressed gas is supplied to the stirring member in
particular from the bottom by means of static gas distributors. As static gas distributors there are
usually used open top tubes, single-ring or multi-ring sprinklers or also porous plates. The gas
supplied in this way is chiefly dispersed by means of radically acting stirring members. In the
process, the gas gets into the suction flow of the stirring member and is dispersed in particular in
the turbulent back end flow (wakes) caused by the stirrer blades or stirrer arms.
TERMINOLOGY :
1.GLASS VESSEL 7.SCRUBER-3 13. PUMP-2
2. CONDENSER 8. NaOCl STORAGE TANK 14. MCB STORAGE
3. HCL STORAGE TANK 9. DUMPING VESSEL 15. SEPRATOR
4. ABSORBER 10. FILTER PRESS-1 16. CONDENSER
5. SCRUBER-1 11. PUMP-1 17. FILTER PRESS-2
6. SCRUBER-2 12. PIGMENTATION VESSEL 18. DRYER
STAGE-1
2.4.1CHLORINATION OPERATION
STAGE-2
2.4.2DUMPING PROCESS
There are two numbers of drawing vessel for the dumping the process.
The dumping process is generally applied in MSRLTL (mild steel rubber lined tie lined) reactor,
in which the process material is dumped.
The capacity of these equipment is 35-40 m3.
During the dumping operation, the thick molten mixture, which is coming out through the glass
lined reactor, is directly dumped into the drawing vessel. In this operation first of all, drawing
vessel is filled with water & HCL of 2.0 PH..
The amount of water is almost 20,000 lit.at normal temperature.
Then after we should add, the chlorinated material into the drawing vessel.
The whole process is done in close system, because if the very light quantity of moisture or water
is touch with process material, then there be a chance of big an accident.
During the dumping process the molten mixture is stirrer by agitator 7 such type of harmful
gasses released from the top of the reactor in little quantity, which is necessary to shucks the
scrubbing method is applied.
Purpose of Dumping process :-
Dumping is applied for cools the chlorinated material from glass lined reactor & also remove the
impurities like Al, Cu etc.
Why HCL is applied before dumping process in water :-
During the dumping process, when the hot molten mixture is directly dumped into the water,
then the Aluminium Chloride does not dissolved in water & make a Precipitate which passed
through the filter press & at last it comes with final product which is impurity.
So for the remove the impurities of Aluminium Chloride the HCL is applied in water in little
quantity.
STAGE-3
2.4.3FILTRATION OPERATION
After the dumping process we get semi-solid product, which is filter in filter press.
The material for the construction of filter press is Polypropylenes.
The semi-solid product is passed through the filter-press to filter.
During the filtration, the material which is as it is as a wet cake (press cake) in the filter press &
mother liquor is passed through the nozzle to ETP.
After applying thick mass in to the filter press. We applied water, to wash it & remove the
impurities from it.
Water is also applied for remove the acidic nature from the wet cake. After applying water in wet
cake, we applied an air to press it to remove water from wet cake as well as (acidic nature)
excess acidity.
During the process almost all during this process almost all impurities are washed out with water,
then after this wet cake is collected in other storage tank & applied for the pigment.
STAGE-4
2.4.4PIGMENTATION PROCESS
STAGE-5
2.4.5SCRUBBING OPERATION
Due to the chlorination, bromination, oxidation, sulphonation, etc operations the harm full gasses
are released from the top of the glass lined reactor, which converted into the harmless gasses into
the scrubber, so scrubber is required for such type of operation.
In the scrubbing process, the HCl as well as the Cl2gas is scrubbed.
In the firstventuri scrubber almost 80% HCl gas is scrubbed in water due to the water circulation
by the pump.
As HCl is highly water soluble at low temperature of water.
Remaining 20% unconverted gasses is passed through the packed tower in which, remaining HCl
is absorb with the cold water.
In second scrubber 15% HCl is absorb & remaining 5% gas is absorbed into third scrubber.
But Cl2gas is insoluble in water, which is scrubbed at last because Cl2 will not scrubbed by
water.
HCl scrubbed by NaOH& react with it & make a hypo product in the fourth separator packed
tower & separate the caustic storage tank.
The caustic solution will be circulated in packed tower at 10 ' 15'c
Which will give hypo solution as per reaction mention below.
2NaOH + Cl2 ' NaOCl + NaCl +H2O
The air which is vent from the third packed tower is almost completely free from gasses.
STAGE-6
2.4.6CHLOROMASS FILTRATION
After the pigmentation process, we get wet cake from the S.S. reactor.
Now, the Filtration operation is applied which is known as Chloromass Filtration.
Chloromass is fed to the filter press at pressure of 2 kg/cm2& is washed to
neutralize the cake.
Then the cake is sent to the drying of blending.
STAGE-7
2.4.7DRYING AND BLENDING
After the Chloromass filtration it is goes for the Drying & Blending purpose.
According to fig of drying, the wet mass is dried with the help of hot air
generator.
There are spin flash type drier is applied for the drying purpose.
In this drier, the wet mass is heated by hot air & the atmospheric air is applied
with the help of HAG (Hot Air Generator)
In another side another blower is situated for creating vaccum.
Due to the creating the vaccum, the mass is passed through the separator &
bag filter.
First of all feed is charged in drying by conveyor to drier.
In which motor is applied for Rotate the disk of drier.
And Hot air is applied for the drying purpose.
Due to the vaccum the mass is passed at up side from the bottom side
CHAPTER:3
MATERIAL AND ENERGY BALANCE
CPC
AlCl3
Na Salt P P1 to drawing vessel
Molecular weight
CPC = 576
AlCl3 = 133.34
Cl2 = 70.91
Common salt(NaCl) =58.45
Mono ChloroBenzen(C6H5Cl) =113
Pigment green 7 (C32N8Cl16Cu) = 1058
NaOH = 40
Actual reacted CPC
M.W of CPC = M.W of P.G 7
576 = 1058
(?) = 1000
= 1000*576/1058
= 544.42 Kg
Here yield is Assumed to be 95% based on P.G7
Actual charged CPC = 544.4/.95 = 573.07 kg
Unreacted CPC = 573.07 ' 544.42 = 28.65kg
Actual reacted Cl2
M.W of Cl2= M.W of P.G 7
14*71 = 1058
(?) = 1000
= 1000*14*71/1058
=939.50 Kg
Take 60% Excess of Cl2 = 1.6*939.50=1503.2Kg
Here yield is Assumed to be 95% based on P.G7
Actual charged Cl2 =1503.2/.95=1582.31Kg
Unreacted Cl2= 1582.31 ' 939.50 = 642.81Kg
Product of HCl
M.W OfHCl = M.W of P.G7
14*36.5 = 1058
(?) = 1000
= 1000*14*36.5/1058 = 482.986 Kg Hcl
Catalyst:
AlCl3=1665kg
Cucl2= 62.5Kg
Na salt = 400kg
3.5.1 Table of Material Balance for stage-1
Component Material In(Kg) Material Out(Kg)
CPC 573.07 28.65
Cl2 1582.31 642.81
AlCl3 1655 1655
CuCl2 62.5 62.5
Na-Salt 400 400
HCl 0 482.986
P.G7 0 1000
Total 4272.88 4272.88
Stage 2
M.B around the Dumping kettle vessel
H2O
P1 to Reactor
P2 to filter press
Stage:3
M.B around the Filter Press:
Water
Stage 4:
M.B around the pigmentation vessel
MCB Water NaOH MCB+ Water vapour to condenser
Stage 5:
M.B around filter press 2:
Water
Stage-6:
M.B around the centrifuge:
P5 form filter press 2 P6 to Dryer P6 to
Dryer
Water
1222.22 kg water present in product of stage 5
60% water remove = 1222.22*0.60 = 773.33Kg.
Output cake :
P.G7 = 1000Kg
Water = 1222.22 ' 733.33 = 488.88Kg
Stage:7
M.B around the Dryer:
Saturated air at 55 ??C
Moisture evaporated
= (Moisture in entering cake) ' (Moisture in leaving product)
= 488.88 kg ' 1 kg
= 487.88kg of moisture is evaporated in air per batch
Stage : 1
E.B around the reactor:
Heat required in the reactor per batch
=(Enthalpy of reactant ' Enthalpy of product + Heat of reaction)
Water Cl2 Condensate
CPC
AlCl3
Na Salt P1 90??C to drawingvessel
Heating steam
Basis: 1000kg of P.G7.
Actual charged kmol of CPC=573.07/575=0.9949Kmol
Actual charged kmol of Cl2=1583.2/70.91=22.29Kmol
Actual charged kmol of Alcl3=1655/133.94=12.35Kmol
Actual charged kmol of Na-salt= 400/58.5=6.8376kmol
Actual charged kmol of H2O=7500/18=416.66Kmol
Kmol Product of P.G7 = 1000/1058 = 0.9451Kmol
Kmol Product of HCl = 482.986/36.5=13.232Kmol
'H= ('(Enthalpy of ractant ) + (Heat of reaction) ' (Enthalpy of product))
'H1= (sensible heat req. by each reactant to reach reaction Temp. 150??C )
=nCp'T (all reactant component CPC, Water, AlCl3 ,Na-salt ,Cl2 )
=(0.9949*60*1049.9)+(22.29*60*502.25)+(12.35*60*784.03.)+(6.8376*60*899.48)+
(416.66*60*4187)
=106357694.1 J/Kmol.K
=106357.6947KJ/Kmol.K
'H2= 619.85*10^3 KJ/Batch
'H3= Enthalpy of product at 90??C
=nCp'T (all product component P.G7 ,HCl solution)
= (0.9751*60*853.71)+ (13.232*60*2475)
=2013393.213 J/Kmol.K
=2013.393213 KJ/Kmol.K
'H = 'H3+'H2 - 'H1
= 2013.393+619850 ' 106357.6947
= 2526.885523 KJ/Kmol.K
This heat is provided by steam heating the steam used for the heating in jacket is saturated steam
of 1.2 atm pressure.
Latent heat of saturated steam at this pressure = 2240.9KJ/kg
Quality of steam required = 2526885.523/2240.9=1127.62 Kg per batch
Stage :2
E.B around pigmentation vessel
MCB Water NaOH MCB+ Water vapour to H.E.
Stage: 3
E.B around the Dryer
Saturated air at 55 ??C
P6 form 55 ??C Centrifuge P7 dried pigment
pulverization 45??C
Hot air at 70 ??C and 40% humidity
Chapter:4
DESIGN FOR GAS INDUSTION HOLLOW TYPE AGITATOR
4.1GAS INDUCTION TYPE HOLLOW AGITATOR
1. Gas induction type hollow agitator is new innovation for this application. Special type of
impeller is attached with hollow shaft. In the upper part of the hollow shaft, windows are
provided for gas suction. Gas enters from these windows and discharge through the lowest part
of the impeller. The agitator operates on the principle of water jet ejector. The suction so
generated blows the stirrer edges during the rotation and hence gas enters though windows and
discharge from e bottom of impeller to liquid pool. A Specially designed impeller vigorously
disperse the gas bubbles and creates a mixture akin to a boiling liquid. Gas bubbles react with
liquid as they rise. Unreacted gas is reinduced into the liquid through windows. Recirculation of
gas is important because bubbling of gas only once through the liquid does not use it up
completely.
DESIGN
Design of gas induction type hollow agitator:
Design Data:
Diameter of tank(vessel)=1600mm
Straight height=1755mm
Top height=460mm
Total height=2255mm
Shaft diameter dw =110 mm
Design condition:
Mixture density=1743.3 Kg/m3
Temperature =160 to 1265 '
Time = 48 Hour (Chlorination Process)
Pressure = 12 Kg/cm21
Mechanical data:
MOC:Mild Steel Glasslined
Solution:
Various Parameter of Design:
(1)h/d=1 (2)H/D=1 (3)D/S=10 (4)A=1.5 dw2
(5) d/dN =3 (6)d/dri =7.5 (7) d/dro=6 (8)W/Da=1/5
(9) D/d=3
Where,
d= Diameter of agitator
D= Diameter of tank
H=Height of bottom surface of tank and bottom surface of agitator.
A=Area under the hole.
dri= Inside diameter of blade
dro Outside diameter of blade.
S=thickness of baffles.
W=Width of blade.
(1)H/D=1
H=D=1600mm
(2) D/d=3
d= D/3 = 1600/3 = 533.33mm
(3) h/d =1
h= d= 533.33mm
(4) W/Da 1/5
W= Da =533.3/5 106.666mm
(5) ) d/dN =3
dN= d/3 = 533.3/3 = 177.776mm
(6) D/S =10
S=D/10 =1600/10= 160mm
(7) d/dro=6
dro = d/6 = 533.33/6 = 88.88mm
(8)d/dri =7.5
Dri=533.33/7.5 = 71.110mm
(9)A=1.5 dw2
=1.5(110)2
A=18150 mm2
(10) H* =H-h =1600-533.33= 1066.7mm
Power Calculation :
Frd/H*=1.80
Where
Fr=Frode Number = n2d/g
No of Power
Np=Ne=[.42+Exp(-.317 Fr-.616)] * (H*/d).25
=[.42+Exp(-1.757248)] * (1.0667/0.533).25
=.704618 =.70
Power Calculation :
Np= P gc/??n3d5
.704618 = P(9.81)/(1743)(8.166)3(.533)5
P= 2941.46KW
P= 3.870HP
Out Power of ElectricMotorRequired :
= 3.8070 * Power loss in transmition * Power loss in Sealing System
=3.8070 * 1.1 *1.2
= 5.2 HP
Calculation of Head transfer Co-efficient :
Calculate Jacket Head transfer Co-efficient=
hjDe/k =0 .027 Re0.8 Pr0.33[(??/??w)0.14(1+3.5(De/Dj)]
De=Equivalent diameter for cross section, m
De=4W
W=Width of jacket, m
Re=Dev??/??
Calculation:
dji= W=120mm
De=4 *0.12 = 0.48m
(??/??w)= 1
Cp= Specific Heat=2.95 Kj/Kg'
v = Velocity of oil= 1.5 m/s
??= Viscosity of oil = .5 Cp
??= Density of oil =710 Kg/m3
k = Thermal conductivity =.1 (W/m')
Re=Dev??/?? = 0.48 *1.5*710/ 0.5 *10-3 = 1022400>10,000
Pr = Prandlet Number
= Cp??/k
=2.95 * 0.5*10-3*10*3/.1
=14.75
Dj= Djo+Dji/2 Mean diameter of jacket m.
Djo = O.D. of Jacket =126mm
Dji= I.D. of Jacket =120mm
Dj= 126+120/2
= 246/2 =123mm
hj = k/De * 0 .027 Re0.8 Pr0.33[(??/??w)0.14(1+3.5(De/Dj)]
= .1/.48 * 0.027 * (1022400)0.8 * (14.75).33[1+3.5(.48/.123)
= 878.052 * 14.6585
=12863.47 W/m2'
hj = 12.863 KW/m2'
4.2Advantages:
1. It provides vigorous gas liquid mixing.
2. It substantially increases gas-liquid interfacial area of contact and enhance gas-liquid mass
transfer rate.
3.It provides very high vessel side coefficient which approaches a boiling coefficient .
4.It is also the best choice for the gas-liquid reaction with suspended solid catalyst.
5. It reduces reaction time considerably for the gas-liquid reaction in which overall reaction rate
governed by rate of mass transfer.
4.3Disadvantages:
1. Fixed cost is very high compare to other type agitator.
2. It is only used for special case.
3. It's fabrication is very difficult.
CHAPTER:5
COST ESTIMATION
5.1COST ESTIMATION (Plant with gas induction hollow type agitator):
An acceptable plant design must present a process that is capable of operating under conditions
which will yield a profit. Since net profit equals total income minus all expenses, it is essential
that the chemical engineer be aware of the many different types of costs involved in
manufacturing process.
In the analysis of costs in industrial processes, capital-investment costs, manufacturing costs and
general expenses including income taxes must be taken into consideration.
BASIS:
Plant Capacity: 2310Kg/day
Total Working Days: 360
Annual Capacity:831600Kg/year
Total production cost is the sum of raw material, manufacturing cost and general expenses.
= 457380000-306922754
= 150457246Rs/-
Total production cost is the sum of raw material, manufacturing cost and general expenses.
= 395010000-266120969.3
= 128889030.7Rs/-
CHAPTER:6
PLANT LAYOUT
6.1PLANT LAYOUT:
(PLANT LAYOUT)
CHAPTER:7
RESULTS AND CONCLUSION
7.1RESULT
Below table shows the results for the plant with old agitator (SIMPLE PROPELLER TYPE
AGITATOR) and new agitator (GAS INDUCTION TYPE HOLLOW AGITATOR):
SR.NO EXITING
PLANT NEW
PLANT
1 Annual Capacity 831600Kg/year 720000 kg/year
7.2CONCLUSION
The project aimed at designing the Gas Induction type hollow agitator as a replacement to the
existing one i.e., three-blade propeller, so that the power consumption and reaction time period
gets reduced.
To design, material balance and energy balance were carried out. The material balance with the
new agitator showed that the number of product batches gets increased which increases the
overall production. Due to the increase in overall production, cost estimation of the plant with
Gas Induction type hollow agitator showed an increase in Annual Profit, Net Profit, Gross Profit
and breakeven point of 28 months compared to the existing one.
Hence, it can be concluded that the plant with Gas Induction type hollow agitator will be
beneficial in many respects as well as economical to the industry.
CHAPTER-8
FURTHER DEVELOPEMENT REQUIRE FOR TAKING INNOVATION TO USER LEVEL
OR MARKET
The harmful acidic vent gas in atmosphere generated through chlorination process can be
minimized using scrubbing.
Better gas-solid mixing can be obtained if helical type agitator is used instead of gas induction
hollow type agitator.
CHAPTER-9
BIBLIOGRAPHY
RICHARDSON, J. F. (2001). Coulson & Richardson's Chemical Engineering
Process Heat Transfer - Donald Kern
Heat Transfer ' Gupta Prakashan
Perry's Chemical Engineering Handbook
Thakore S.B. and B.I Bhatt 'Introduction to Process Engineering and Design' Tata McGraw hill
Publications Co. Ltd., pg. 215, 681
Handbook of Chemical Processing Equipment by N.P.Cheremisinoff
Frank D. Kover, United States. Environmental Protection Agency. Office of Toxic Substance.
Chemical Process Industry, Dryden &Shrieve
WEBSITES:
http://pubchem.ncbi.nlm.nih.gov
http://en.wikipedia.org/wiki/agitator design
http://pubchem.ncbi.nlm.nih.gov
www.google.com/patents
www.freepatentsonline.com/
http://en.wikipedia.org/wiki/Pigment green 7.
http://www.engineeringtoolbox.com/pigment green 7.html
http://www.bt.cdc.gov/agent/pigment
http://www.nlm.nih.gov/medlineplus/ency/article/000774.htm
www.tutorvista.com
www.indindatabase.com