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The molecular orbital (MO) treatment of bonding is now (oxygen and fluorine) and one for the earlier elements
well-ingrained in introductory chemistry courses withmost (boron through nitrogen). Unfortunately, the later dia-
elementary textbooks presenting MO diagrams for the grams are almost invariably incorrect. The purpose of the
second-row homonuclear diatomic molecules. Two dia- present contribution is to point out the error and to rectify
grams are usually presented: one for the later elements it.
Figure 1. Relative energies of 2s and 2p AO's and of resulting a and n: MO's. (a) Negligible s-p, mixing, correct diagram. (b) Substantial s-p,
mixing, incorrect diagram (see text).