SUCCESS STUDY CIRCLE

MONTHLY TEST SUB- CHEMISTRY ( 1st year) F.M-70 TIME

3HRS

Q1. Answer all the questions [15=5]

i. The effective atomic numbers of cobalt in the complex [CO(NH 3)6]3+is

a. 30 b. 24 c. 27 d. non of these
ii. Which of the following does not show linkage Isomerism

a. CN- b. NO2 c. H2O d. SCN-

iii. Which metal can be extracted by hydro-metallurgy?

a. Na b. Fe c. Cu d. Mg
iv. The possible number of isomers for the comlex [MCl 2 Br2]SO4
a.1 b.2 c.4 d.5

v. Which one is an Organometallic compound

a. sodium acetate b. Calcium carbide c. Methyl Cadmium chloride d. Sodium ethoxide

Q2. answer all the questions [110=10]

i. Lanthanoid elements are difficult to separate in the pure form due to.................
ii. General electronic configuration of lanthanoid elements is.................
iii. The bond exist in a double bond is...........
iv. Metal atom in a double bond is..............
v. Valency bond theory is based on concept of ...................
vi. ................ complex does not show geometrical isomerism.
vii. Co- ordination number of cobalt in [Co(en) 3 ] Br3 is....
viii. The energy difference between t2g and lg is called ......
ix. The IUPAC name of Ferriferro-Cyanide is...............
x. EDTA4- is a .............type of ligands

Q3. Answer any five [25=10]

i. Define with examples airibid entate ligands

ii. Define with examples ionisation isomerism.
iii. Most of the transition metal ions show characteristic colour . Explain.
iv. Give the structure ,magnetic colour properties of the [Cr (NH 3)6]3+
v. Write the difference between double salts and compleses.
vi. Find the oxidation number , co-ordination number and EAN of Co in [ Co (en) 3]3+
vii. Explain comles ion with examples.
viii. How co-ordination compound are used in analytical chemistry?write the application of
Co-ordinate compounds in industry.
ix. Discuss the stability of constant of complex.
x. Which aldehyde cant be prepared Rosennsund reduction and why?
xi. How can you preparepropanone from acid chloride?
xii. Convert propanone into mesityloxide

Q4answer any two [35]

i. Explain structural isomerism

ii. Write notes on valency bond Theory
iii. Write notes on Crystalfied Theory
iv. Explain the Werner s theory for the complex K4[Fe(CN)6]
v. Write the different types of complexes .Give some examples.
vi. Explain with suitable examplenucleophilic addition reaction
vii. What is Rosenmunds reduction?
viii.

Q5. Answer all [3+2+1+1+2=9]

i. Describe the preparation of potassium dichromate

ii. A solid block compound A fused with KoH in the presence of air gives a green coloure
compound B which on electrolysis produces a purple colour compound C . Identify
A,B,C.
iii. What is lanthanoid contraction?
iv. Write the structure of edta.
v. Between tetrahedral and square planner complexes ,which one does not show optical
isomerism and why ?

Q6. i. Discuss Werners Co-ordination theory with examples [4]

ii. Give evidences in support of Warners Co-ordination theory. [3]

Q7 i. What is isomerism ? [2]

ii. Discuss structural isomerism in Co-ordinate chemistry giving suitable examples.

[5]

Q8. a. Give two methods of preparation of Ketone/Acetone

b. How does react with (i) HCN (II) Phenyl hydrazine